文部科学省科学研究費補助金「新学術領域研究（研究領域提案型）」（平成23～27年度）
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注意事項
本新学術領域研究の科研費により実施された研究につきましては、下記のように謝辞(Acknowledgment)を記載ください。
This work was (partially) supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Advanced Molecular Transformations by Organocatalysts” from The Ministry of Education, Culture, Sports, Science and Technology, Japan.
*文部科学省は「MEXT」に省略可
| 分類 | 内容 | 共同研究者 |
|---|---|---|
| A01 寺田 眞浩 | ||
| Original papers |
"Brønsted Base-Catalyzed Three-Component Coupling Reaction of α-Ketoesters, Imines, and Diethyl Phosphite Utilizing [1,2]-Phospha-Brook Rearrangement
" Kondoh, A.; *Terada, M. Org. Biomol. Chem. 2016, 14 (20), pp.4704-4711. DOI:10.1039/C6OB00739B  |
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"Novel Methodology for the Efficient Synthesis of 3-Aryloxindoles: [1,2]-Phospha-Brook Rearrangement–Palladium-Catalyzed Cross-Coupling Sequence
" Kondoh, A.; Takei, A.; *Terada, M. Synlett 2016, Accepted Manuscript. DOI:10.1055/s-0035-1561859 |
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"Enantioselective Intramolecular Cyclization of Alkynyl Esters Catalyzed by Chiral Brønsted Base
" Kondoh, A.; Tran, H. T. Q.; Kimura, K.; *Terada, M. Chem. Commun. 2016, 52 (33), pp.5726-5729. DOI:10.1039/C6CC01690A |
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"Construction of Vicinal Quaternary Stereogenic Centers by Enantioselective Direct Mannich-Type Reaction Using a Chiral Bis(guanidino)iminophosphorane Catalyst
" Takeda, T.; Kondoh, A.; *Terada, M. Angew. Chem. Int. Ed. 2016, 55 (15), pp.4734-4737. DOI:10.1002/anie.201601352 |
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"Study of Stereocontrolling Elements in Chiral Phosphoric Acid Catalyzed Addition Reaction of Vinylindoles with Azlactones
" Kanomata, K.; *Terada, M. Synlett 2016, 27 (4), pp.581-585. DOI:10.1055/s-0035-1561677 |
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"Perfluorinated Aryls in the Design of Chiral Brønsted Acid Catalysts: Catalysis of Enantioselective [4+2] Cycloadditions and Ene–Reactions of Imines with Alkenes by Chiral Mono-Phosphoric Acids with Perfluoroaryls
" Momiyama, N.;* Okamoto, H.; Kikuchi, J.; Korenaga, T.; *Terada, M.
ACS Catal. 2016, 6 (2), pp.1198-1204. DOI:10.1021/acscatal.5b02136 |
是永敏伸 | |
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"Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Brønsted Acid Catalyst
" Momiyama, N.;* Funayama, K.; Noda, H.; Yamanaka, M.; Akasaka, N.; Ishida, S.; Iwamoto, T.; *Terada, M. ACS Catal. 2016, 6 (2), pp.949-956. DOI:10.1021/acscatal.5b02079 |
山中正浩 | |
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"Enantioselective Aza Michael-Type Addition to Alkenyl Benzimidazoles Catalyzed by Chiral Phosphoric Acid
" Wang, Y.-Y.; Kanomata, K.; Korenaga, T.; *Terada, M. Angew. Chem. Int. Ed. 2016, 55 (3), pp.927-931. DOI:10.1002/anie.201508231 |
是永敏伸 | |
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"Chiral Brønsted acid-catalyzed enantioselective Friedel–Crafts reaction of 2-methoxyfuran with aliphatic ketimines generated in situ
" Kondoh, A.; Ota, Y.; T. Komuro.; Egawa, F.; Kanomata, K.; *Terada, M. Chem. Sci. 2016, 7 (2), pp.1057-1062. DOI:10.1039/c5sc03175c |
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"Enantioselective Addition of a 2-Alkoxycarbonyl-1,3-dithiane to Imines Catalyzed by a Bis(guanidino)iminophosphorane Organosuperbase
" Kondoh, A.; Oishi, M.; Takeda, T.; *Terada, M. Angew. Chem. Int. Ed. 2015, 54 (52), pp.15836-15839. DOI:10.1002/anie.201508178 Highlighted at the front cover |
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"Design of a Brønsted Acid with Two Different Acidic Sites: Synthesis and Application of Aryl Phosphinic Acid-Phosphoric Acid as a Brønsted Acid Catalyst
" Momiyama, N.;* Narumi, T.; *Terada, M. Chem. Commun. 2015, 51 (95), pp.16976-16979. DOI:10.1039/C5CC06787A |
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"Ring Expansion of Epoxides under Brønsted Base Catalysis: Formal [3+2] Cycloaddition of β,γ-Epoxy Esters with Imines Providing 2,4,5-Trisubstituted 1,3-Oxazolidines
" Kondoh, A.; Odaira, K.; *Terada, M. Angew. Chem. Int. Ed. 2015, 54 (38), pp.11240-11244. DOI:10.1002/anie.201505893 |
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"Synthesis of Phenanthrene Derivatives by Intramolecular Cyclization Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Brønsted Base" Kondoh, A.; Aoki, T.; *Terada, M. Chem. Eur. J. 2015, 21 (36), pp.12577-12580. DOI:10.1002/chem.201501377 |
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"Synthetic Method for 2,2'-Disubstituted Fluorinated Binaphthyl Derivatives and Application as Chiral Source in Design of Chiral Mono-Phosphoric Acid Catalyst
" *Momiyama, N.; Okamoto, H.; Shimizu, M.; *Terada, M. Chirality 2015, 27 (8), pp.464-475. DOI:10.1002/chir.22429 |
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"Skeletal Rearrangement of O-Propargylic Formaldoximes by a Gold-Catalyzed Cyclization/Intermolecular Methylene Transfer Sequence " *Nakamura, I.; Gima, S.; Kudo, Y.; Terada, M. Angew. Chem. Int. Ed. 2015, 54 (24), pp. 7154-7157. DOI:10.1002/anie.201501856 |
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"Brønsted Base-catalyzed α-Oxygenation of Carbonyl Compounds Utilizing the [1,2]-Phospha-Brook Rearrangement " Kondoh, A.; *Terada, M. Org. Chem. Front. 2015, 2 (7), pp.801-805. DOI:10.1039/C5QO00108K |
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"Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by a Chiral Brønsted Acid " Yamanaka, T.; Kondoh, A.; *Terada, M. J. Am. Chem. Soc. 2015, 137 (3), pp.1048-1051. DOI:10.1021/ja512238n |
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"Synthesis of Intermediary P3 Phosphazenium Framework and Its Derivatization to Chiral Cationic Macrocycles Including Two P3 Phosphazenium Units with Hydrogen Bond Donor Sites" *Terada, M.; Goto, K.; Ikehara, T.; Kondoh, A. Heterocycles 2015, 90 (2), pp.1396-1404. DOI:10.3987/COM-14-S(K)98 |
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"Copper-Catalyzed Cascade Transformation of O-Propargylic Oximes with Sulfonyl Azides to α,β-Unsaturated N-Acylamidines" Zhang, D.; *Nakamura, I.; Terada, M. Org. Lett. 2014, 16 (19), pp.5184-5187. DOI:10.1021/ol502541w. |
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"Efficient Synthesis of N-Alkylated α,β-Unsaturated Ketonitrones via Cu-Catalyzed Rearrangement " *Nakamura, I.; Onuma, T.; Kanazawa, R.; Nishigai, Y.; Terada, M. Org. Lett. 2014, 16 (16 ), pp.4198-4200. DOI:10.1021/ol501889g |
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"Efficient synthesis of eight-membered nitrogen heterocycles from O-propargylic oximes by rhodium-catalyzed cascade reactions " *Nakamura, I.; Sato, Y.; Takeda, K.; Terada, M. Chem. Eur. J. 2014, 20 (33), pp.10214-10219. DOI:10.1002/chem.201403637 |
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"N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates " *Nakamura, I.; Jo, T.; Zhang, D.; Terada, M. Org. Chem. Front. 2014, 1 (8 ), pp.914-918. DOI:10.1039/C4QO00156G |
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"Intramolecular Cyclization of Alkynyl α-Ketoanilide Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Phosphazene Base " Kondoh, A.; Aoki, T.; *Terada, M. Org. Lett. 2014, 16 (13 ), pp.3528-3531. DOI:10.1021/ol501479t |
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"Synthesis of Bulky Aryl Group-Substituted Chiral Bis(guanidino)iminophosphoranes as Uncharged Chiral Organosuperbase Catalysts" Takeda, T.; *Terada, M. Aust. J. Chem. 2014, 67 (7 ), pp.1124-1128. DOI:10.1071/CH14195 |
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"Secondary Stereocontrolling Interactions in Chiral Brønsted Acid Catalysis: Study of a Petasis-Ferrier-Type Rearrangement Catalyzed by Chiral Phosphoric Acids" Kanomata, K.; Toda, Y.; Shibata, Y.; Yamanaka, M.; Tsuzuki, S.; Gridnev, I. D.; *Terada, M. Chem. Sci. 2014, 5 (9 ), pp.3515-3523.. DOI:10.1039/C4SC00611A |
山中正浩・都築誠二 | |
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"Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid" *Terada, M.; Komuro, T.; Toda, Y.; Korenaga, T. J. Am. Chem. Soc. 2014, 136 (19), pp.7044-7057. DOI:10.1021/ja5017206 |
是永敏伸 | |
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"Synthesis of 1,6-Dihydropyrimidines via Copper-catalyzed Multistep Cascade Reactions between O-Propargylic Aldoximes and Isocyanates" *Nakamura, I.; Onuma, T.; Zhang, D.; Terada, M. Tetrahedron Lett. 2014, 55 (6), pp.1178-1182. DOI:10.1016/j.tetlet.2013.12.105 |
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"Cu-Catalyzed Skeletal Rearrangement of O-Propargylic Electron-Rich Arylaldoximes into Amidodienes" *Nakamura, I.; Ishida, Y.; Terada, M. Org. Lett. 2014, 16 (9), pp.2562-2565. DOI:10.1021/ol5009608 |
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"Binaphthol-Derived Phosphoric Acid as an Efficient Chiral Organocatalyst for the Enantiomer-Selective Polymerization of rac-Lactide" Makiguchi, K.; Yamanaka, T.; Kakuchi, T.; *Terada, M.; *Satoh, T. Chem. Commun. 2014, 50 (22), pp.2883-2885. DOI:10.1039/C4CC00215F |
佐藤敏文 | |
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"Chiral Silver Phosphate Catalyzed Transformation of ortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence" *Terada, M.; Li, F.; Toda, Y. Angew. Chem. Int. Ed. 2014, 53 (1), pp.235-239. DOI:10.1002/anie.201307371 |
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"Design and Synthesis of Helically Chiral Spirocyclic P3 Phosphazenes and Characterization of Their Onium Salts" Terada, M.; Goto, K.; Oishi, M.; Takeda, T.; Kwon, E.; Kondoh, A. Synlett 2013, 24 (19), pp.2531-2534. DOI:10.1055/s-0033-1340058 |
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"Development of a Chiral Bis(guanidino)iminophosphorane as an Uncharged Organosuperbase for the Enantioselective Amination of Ketones" Takeda, T.; *Terada, M. J. Am. Chem. Soc. 2013, 135 (41), pp.15306-15309. DOI:10.1021/ja408296h |
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"Phosphazene-Catalyzed Intramolecular Cyclization of Nitrogen-Tethered Alkynyl Esters" Kondoh, A.; Ando, K.; *Terada, M. Chem. Commun. 2013, 49 (87), pp.10254-10256. DOI:10.1039/C3CC46100A |
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"Brønsted Base Catalyzed [2,3]-Wittig/Phospha-Brook Tandem Rearrangement Sequence" Kondoh, A.; *Terada, M. Org. Lett. 2013, 15 (17), pp.4568-4571. DOI:10.1021/ol402144q |
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"Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" *Terada, M.; Yamanaka, T.; Toda, Y. Chem. Eur. J. 2013, 19 (41), pp.13658-13662. DOI:10.1002/chem.201302486 |
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"Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reaction between O-Propargylic Oximes and Dipolarophiles " *Nakamura, I.; Kudo, Y.; Terada, M. Angew. Chem. Int. Ed. 2013, 52 (19), pp.7536-7539. DOI:10.1002/anie.201302751 |
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"Relay Catalysis by a Ruthenium Complex/Chiral Brønsted Acid Binary System for Ternary Reaction Sequence Involving Enantioselective Pictet−Spengler-Type Cyclization as the Key Step" Toda, Y.; *Terada, M. Synlett 2013, 24 (6), pp.752-756. DOI:10.1055/s-0032-1318302 |
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"Synthesis of Azepine Derivatives by Rhodium-Catalyzed Tandem 2,3-Rearrangement/Heterocyclization" *Nakamura, I.; Okamoto, M.; Sato, Y.; Terada, M. Angew. Chem. Int. Ed. 2012, 51 (43), pp.10816-10819. DOI:10.1002/ange.201207154 |
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"Copper-catalyzed skeletal rearrangement of O-propargylic aryloximes into four-membered cyclic nitrones - chirality transfer and mechanistic insight" *Nakamura, I.; Kudo, Y.; Araki, T.; Zhang, D.; Kwon, E.; Terada, M. Synthesis 2012, 44 (10), pp.1542-1550. DOI:10.1055/s-0031-1290819 |
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"Guanidine/Azole Binary System as an Efficient Catalyst for Morita-Baylis-Hillman Reaction" *Terada, M.; Fukuchi, S.; Amagai, K.; Nakano, M.; Ube, H. ChemCatChem. 2012, 4 (7), pp.963-967. DOI:10.1002/cctc.201200149 |
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"Synthesis of Unsymmetrically Substituted 2,2’-Dihydroxy-1,1’-biaryl Derivatives Using Organic-Base-Catalyzed Ferrier-Type Rearrangement as the Key Step" *Terada, M.; Dan, K. Chem. Commun. 2012, 48 (46), pp.5781-5783. DOI:10.1039/C2CC31594G |
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"Relay Catalysis via a Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" *Terada, M.; Toda, Y. Angew. Chem. Int. Ed. 2012, 51 (9), pp.2093-2097. DOI:10.1002/anie.201107805 |
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"Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Alkylaldoximes via N-O Bond Cleavage" *Nakamura, I.; Iwata, T.; Zhang, D.; Terada, M. Org. Lett. 2012, 14 (1), pp.206-209. DOI:10.1021/ol203001w |
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"Chiral Brønsted Acid-Catalyzed Stereoselective Addition of Azlactones to 3-Vinylindoles for Facile Access to Enantioenriched Tryptophan Derivatives " *Terada, M.; Moriya, K.; Kanomata, K.; Sorimachi, K. Angew. Chem. Int. Ed. 2011, 50 (52), pp.12586-12590. DOI:10.1002/anie.201105562 |
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"Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3’-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels-Alder Reaction of α,β-Unsaturated Aldehydes with Amidodienes" *Momiyama, N.; Konno, T.; Furiya, T.; Iwamoto, T.; *Terada, M. J. Am. Chem. Soc. 2011, 133 (48), pp.19294-19297. DOI:10.1021/ja2081444 |
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"Thermally-induced Skeletal Rearrangement of (Z)-O-Propargylic α,β-Unsaturated Aldoximes to Multisubstituted Pyridine Oxides" *Nakamura, I.; Zhang, D.; Terada, M. Tetrahedron Lett. 2011, 52 (48), pp.6470-6472. DOI:10.1016/j.tetlet.2011.09.107 |
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"Platinum-catalyzed Cycloisomerization of 1,4-Enynes via 1,2-Alkenyl Rearrangement" Sato, T.; Onuma, T.; *Nakamura, I.; Terada, M. Org. Lett. 2011, 13 (19), pp.4992-4995. DOI:10.1021/ol202104c |
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"Direct Enantioselective Amination of α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Amagai, K.; Ando, K.; Kwon, E.; Ube, H. Chem. Eur. J. 2011, 17 (33), pp.9037-9041. DOI:10.1002/chem.201101076 |
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"Regioselective Transformation of O-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement" *Nakamura, I.; Araki, T.; Zhang, D.; Kudo, Y.; Kwon, E.; Terada, M. Org. Lett. 2011, 13 (14), pp.3616-3619. DOI:10.1021/ol2012583 |
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"Chiral Brønsted Acid Catalysis for Enantioselective Hosomi-Sakurai Reaction of Imines with Allyltrimethylsilane" *Momiyama, N.; Nishimoto, H.; *Terada, M. Org. Lett. 2011, 13 (8), pp.2126-2129. DOI:10.1021/ol200595b |
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"Enantioselective Direct Vinylogous Michael Addition of Functionalized Furanones to Nitroalkenes Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Ando, K. Org. Lett. 2011, 13 (8), pp.2026-2029. DOI:10.1021/ol200415u |
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"Metal-Free Chiral Phosphoric Acid or Chiral Metal Phosphate as Active Catalyst in the Activation of N-Acyl Aldimines" *Terada, M.; Kanomata, K. Synlett 2011, (9), pp.1255-1258. DOI:10.1055/s-0030-1260545 |
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"Highly Stereoselective [4+2] Cycloaddition of Azlactones to β,γ-Unsaturated α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Nii, H. Chem. Eur. J. 2011, 17 (6), pp.1760-1763. DOI:10.1002/chem.201003015 |
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| Books |
「CSJカレントレビュー第13号：キラリティ（キラル化学）―その起源から最新のキラル材料研究まで」 高田十志和, 門出健次, 八島栄次 "第10章 キラル触媒最前線2（有機触媒～キラル触媒の新たな潮流～）" *寺田眞浩 化学同人 (京都) 2013, pp119-125. |
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「Asymmetric Synthesis II」 M. Christmann, S. Braese "Asymmetric C-C bond formation using chiral guanidine catalysts" 2013, pp273-278. |
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「Science of Synthesis, Asymmetric Organocatalysis 2, Brønsted Base and Acid Catalysts, and Additional Topics」 K. Maruoka "Phosphoric Acid Catalysis of Reactions not Involving Imines" M. Terada, N. Momiyama Georg Thieme Verlag KG (New York) 2012, pp219-278. |
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「Science of Synthesis, Stereoselective Synthesis 3 」 P. A. Evans "Ene Reactions" Terada、M. Thieme (New York) 2011, pp309-346. |
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「触媒調整ハンドブック」 岩本正和 "第４編 均一系触媒 有機触媒" 寺田眞浩 エヌ・ティー・エス (東京) 2011, pp397-409. ISBN:978-4-86043-377-2 |
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| Reviews / Accounts |
"Copper-Catalyzed Skeletal Rearrangements of O-Propargylic Oximes via Cleavage of a Carbon-Oxygen Bond" *Nakamura, I.; Terada, M. Chem. Record. 2015, 15 (2 ), pp.429-444. DOI:10.1002/tcr.201402088 |
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"キラルブレンステッド酸触媒並びに塩基触媒の設計開発" *寺田眞浩 化学と工業 2014, 67 (6), pp.474-476. |
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"有機分子触媒の躍進" *寺田眞浩 ファインケミカル 2014, 43 (6), pp.5-6. |
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"「モノづくり」に思うこと" *寺田眞浩 有機合成化学協会誌 2014, 72 (2), pp.117-117. DOI:10.5059/yukigoseikyokaishi.72.117 |
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"Heterocyclic Synthesis by π-Acidic Metal Catalyzed Reactions via N-O Bond Cleavage" *Nakamura, I.; Terada, M. Heterocycles 2014, 89 (4), pp.845-868. DOI:10.3987/REV-13-791 |
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"キラルBrønsted酸を用いた不斉触媒反応" 寺田眞浩 有機合成化学協会誌 2013, 71 (5), pp.480-490. DOI:10.5059/yukigoseikyokaishi.71.480 |
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"最新のトピックス：触媒の”ハイブリッド”―金属触媒と有機触媒の組み合わせによる触媒反応" 近藤梓, 寺田眞浩 化学 2012, 67 (6), pp.66-67. |
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"Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acid Catalysts" *Terada, M. Curr. Org. Chem. 2011, 15 (13), pp.2227-2256. |
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| Conference / Symposium / Lecture |
招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen (Germany) 2016-03-22～2016-03-22 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of Westfälishe Wilhelms-Universität Münster, Münster (Germany) 2016-03-21～2016-03-21 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of RWTH Aachen University, Aachen (Germany) 2016-03-18～2016-03-18 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Max‐Planck‐Institut für Kohlenforschung, Mulheim an der Ruhr (Germany) 2016-03-17～2016-03-17 |
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招待講演 "New Aspects of Enantioselective Catalysis by Chiral Phosphoric Acid" 〇*Terada, M. 5th UK-Japanese Symposium on Asymmetric Catalysis, Manchester (UK) 2016-03-14～2016-03-15 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Université de Genève, Genève (Switzerland) 2016-03-11～2016-03-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of École Polytechnique Fédérale de Lausanne, Lausanne (Switzerland) 2016-03-10～2016-03-10 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of ETH Zurich, Zurich (Switzerland) 2016-03-09～2016-03-09 |
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招待講演 "Enantioselective Transformation of Cationic Intermediates Mediated by Chiral Phosphoric Acid Catalyst
" 〇*Terada, M. Pacifichem 2015 (#122 Recent Trends in Organocatalysis), Honolulu (USA ) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Enantio-convergent Nucleophilic Substitution Reaction of Racemic Alkyne-Cobalt Complex Catalyzed by Chiral Brønsted Acid: Asymmetric Synthesis of Enantio-enriched Thioethers
" 〇*Terada, M.; Ota, Y.; Li, F.; Toda, Y.; Kondoh, A. IKCOC-13, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M.; Yamanaka, T.; Kondoh, A. The 10th International Conference on Cutting-Edge Organic Chemistry in Asia, Kaohsiung (Taiwan) 2015-11-02～2015-11-06 |
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招待講演 "New Aspect of Organosuperbase Catalyst" 〇*Terada, M. Perspectives on Synthetic Organic Chemistry , Singapore (Singapore) 2015-09-30～2015-09-30 |
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招待講演 "Chiral Brønsted Acid-Catalyzed Transformations for Multistep Sequence " 〇*Terada, M. First Symposium DOMINOCAT @RWTH Aachen, Institute of Organic Chemistry, Aachen (Germany) 2015-09-09～2015-09-11 |
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招待講演 "Development of Chiral Bis(guanidino)iminophosphorane as Uncharged Organosuperbase Catalyst for Enantioselective Transformations" 〇*Terada, M. IUPAC World Chemistry Congress 2015 Molecular Synthesis Symposia, Busan (Korea) 2015-08-09～2015-08-14 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. Golden Jubilee Chemistry Conference, Singapore (Singapore) 2015-08-06～2015-08-08 |
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招待講演 "Enantioselective Transformation of Cationic Intermediates Mediated by Chiral Phosphoric Acid Catalyst" 〇*Terada, M. The 39th Naito Conference “The Chemistry of Organocatalyst”, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. 2nd Organic Chemistry Frontiers International Symposium, Hangzhou (China) 2015-04-21～2015-04-21 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Michigan State University, Michigan (USA) 2014-12-12～2014-12-12 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of University of Michigan, Michigan (USA) 2014-12-11～2014-12-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Rutgers University, The State University of New Jersey, New Jersey (USA) 2014-12-09～2014-12-09 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Columbia University, New York (USA) 2014-12-08～2014-12-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Vanderbilt University, Tennessee (USA) 2014-12-15～2014-12-15 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Colorado State University, Colorado (USA) 2014-12-04～2014-12-04 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of University of California-Berkeley, California (USA) 2014-12-01～2014-12-01 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Toyko (Japan) 2014-11-21～2014-11-21 |
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招待講演 "Development of Chiral Bis(guanidino)iminophosphoranes as Uncharged Organosuperbase Catalysts for Enantioselective Transformations" 〇*Terada, M. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-29 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Taiwan Normal University (國立台湾師大), Taipei (Taiwan) 2014-10-17～2014-10-17 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of Institute of Chemistry, Academia Sinica, Taipei (Taiwan) 2014-10-16～2014-10-16 |
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受賞講演 "Lectureship Award:Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Tsing Hua University (國立精華大), HsinChu, (Taiwan) 2014-10-15～2014-10-15 |
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受賞講演 "Lectureship Award:Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Chung Cheng University (國立中正大學), ChiaYi (Taiwan) 2014-10-14～2014-10-14 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Chiral Brønsted Bases" 〇*Terada, M. Molecular Complexity in Modern Chemistry” MCMC2014, Moscow (Russia ) 2014-09-13～2014-09-19 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite de Rouen, Rouen (France ) 2014-09-12～2014-09-12 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite Pierre et Marie Curie-Paris 6 (UPMC), Paris (France) 2014-09-11～2014-09-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite Paris Sud, Orsay (France) 2014-09-10～2014-09-10 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Dalian University of Technology, Dalian (China) 2014-04-11～2014-04-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Dalian Institute of Chemical Physics CAS, Dalian (China) 2014-04-09～2014-04-09 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Zhejiang University, Hangzhou (China) 2014-04-08～2014-04-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Zhejiang University of Technology, Hangzhou (China) 2014-04-08～2014-04-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Nanjing University, Nanjing (China) 2014-04-04～2014-04-04 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Shanghai Jiao Tong University, Shanghai (China) 2014-04-03～2014-04-03 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Chiral Brønsted Bases" ○*Terada, M. 1st Organic Chemistry Frontiers Symposium, Shanghai (China) 2014-04-03～2014-04-03 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of East China Normal University, Shanghai (China) 2014-04-01～2014-04-01 |
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受賞講演 "Lectureship Award: Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of National University of Singapore, Singapore (Singapore) 2014-03-14～2014-03-14 |
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受賞講演 "Lectureship Award: Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Nanyang Technological University, Singapore (Singapore) 2014-03-13～2014-03-13 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. C&FC (Catalysis & Fine Chemicals) 2013, Beijing (China) 2013-12-01～2013-12-05 |
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口頭発表／ポスター発表 "Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation" ○*Terada, M. ICCEOCA-8 and NICCEOCA-4, Osaka (Japan) 2013-11-25～2013-11-28 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Kwangwon National University, Chun Cheon (Korea) 2013-10-31～2013-10-31 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Seoul National University, Seoul (Korea) 2013-10-30～2013-10-30 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Sungkyunkwan University, Suwon (Korea) 2013-10-29～2013-10-29 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. Beijing Symposium 2013 on “New Frontiers in Organic Chemistry: New Reagents, New Reactions”, Beijing (China) 2013-10-09～2013-10-12 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. 25th ISCD (International Symposium on Chirality), Shanghai (China) 2013-07-07～2013-07-10 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. 5th Gratama Workshop, Tokyo (Japan) 2013-05-29～2013-06-01 |
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招待講演 "Chiral Anion Catalysis in Enantioselective Transformation of Carbocation Intermediates" ○*Terada, M. Advanced Molecular Transformations by Organocatalysts, First International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. The 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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招待講演 "Chiral Anion Catalysis in Enantioselective Transformation of Carbocation Intermediates" ○*Terada, M. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-08-19～2013-08-20 |
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招待講演 "Chiral Anion Catalysis in Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" ○*Terada, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" ○*Terada, M., T. Yamanaka, Y. Toda ICCEOCA-7, Singapore (Singapore) 2012-12-11～2012-12-15 |
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口頭発表／ポスター発表 "Relay Catalysis via Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" ○*Terada, M., Y. Toda IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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受賞講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Nagoya Medal of Organic Chemistry 2012, Nagoya (Japan) 2012-11-08～2012-11-08 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. Molecular Chirality ASIA2012, Fukuoka (Japan) 2012-03-17～2012-03-18 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. 4th Novel Chiral Chemistries Japan 2012, Tokyo (Japan) 2012-03-15～2012-03-16 |
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招待講演 "Enantioselective Transformations via Activation of Electron-Rich Double Bonds Using Chiral Phosphoric Acids" ○*Terada, M. International Symposium of Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Shanghai Institute of Materia Medica, Shanghai (China) 2011-11-30～2011-11-30 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at East China Normal University, Shanghai (China) 2011-11-30～2011-11-30 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Shanghai Institute of Organic Chemistry, Shanghai (China) 2011-11-29～2011-11-29 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Science & Technology of China, Hefei (China) 2011-11-28～2012-11-28 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Sichuan University, Chengdu (China) 2011-11-25～2011-11-25 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of South Florida, Tampa (USA) 2011-11-14～2011-11-14 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations, M. Terada, , Nov. 9 (2011), , （招待講演）" ○*Terada, M. Departmental Seminar at University of Miami, Miami (USA) 2011-11-09～2011-11-09 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Vanderbilt University, Nashville (USA) 2011-11-08～2011-11-08 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Texas at Austin, Austin (USA) 2011-11-07～2011-11-07 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of New Mexico, Albuquerque (USA) 2011-11-04～2011-11-04 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at California Institute of Technology, Los Angeles (USA) 2011-11-03～2012-11-03 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong University, Hong Kong (China) 2011-10-21～2011-10-21 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Peking University, Shenzhen Graduate School, Shenzhen (China) 2011-10-19～2011-10-19 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong Baptist University, Hong Kong (China) 2011-10-18～2011-10-18 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong University of Science & Technology, Hong Kong (China) 2011-10-17～2011-10-17 |
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招待講演 "Enantioselective Transformations via Activation of Electron-Rich Double Bonds Using Chiral Phosphoric Acids" ○*Terada, M. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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招待講演 "Chiral Phosphoric Acids as a Versatile Catalyst for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Cambridge, Cambridge (UK) 2011-04-19～2011-04-19 |
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招待講演 "Binaphthol-derived Phosphoric Acid as a Versatile Catalyst for Enantioselective Carbon-Carbon Bond Forming Reactions" ○*Terada, M. 3rd UK-Japan Symposium on Catalytic Asymmetric Synthesis, Oxfordく反対 (UK日本) 2011-04-15～2011-04-16 |
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| Patent |
"ビス－リン酸化合物及びそれを用いる不斉合成" 発明者：寺田眞浩、椴山儀恵、今野徹 出願者：国立大学法人東北大学、株式会社エーピーアイ コーポレーション共同出願 WO2011JP55296 20110308 2011-03-08, WO2011111677 (A1) 2011-09-15, (国外) |
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| Prize |
"Molecular Chirality Award 2015" *Terada, M. 2015-06 Molecular Chirality Research Organization Development of Chiral Organocatalysts and Its application to Catalytic Asymmetric Synthesis |
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"Asian Core Program Lectureship Award (Thailand)" *Terada, M. 2013-11 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation |
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"Asian Core Program Lectureship Award (Taiwan)" *Terada, M. 2013-11 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation |
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"Asian Core Program Lectureship Award (Singapore)" *Terada, M. 2012-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate |
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"Asian Core Program Lectureship Award (Korea)" *Terada, M. 2012-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate |
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"Nagoya Silver Medal" 寺田眞浩 2012-11 万有生命科学振興国際交流財団 水素結合を戦略的相互作用とする有機分子触媒の創製 |
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"第一三共・創薬有機化学賞
" 寺田眞浩 2012-02 有機合成化学協会 水素結合を戦略的相互作用とする有機分子触媒の創製 |
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| Media |
"Angew. Chem. Int. Ed. 誌に掲載された「Enantioselective Addition of a 2-Alkoxycarbonyl-1,3-dithiane to Imines Catalyzed by a Bis(guanidino)iminophosphorane Organosuperbase」がFront Cover Pictureに採用された。" Kondoh, A.; Oishi, M.; Takeda, T.; Terada, M. Angew. Chem. Int. Ed. 2015-12-21  PDF |
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"ChemCatChem. 2012, 4, 963-967に掲載された「Guanidine/Azole Binary System as an Efficient Catalyst for Morita-Baylis-Hillman Reaction」が「A Binary Coupling」としてChemistry Viewsに紹介された。" M. Terada, S. Fukuchi, K. Amagai, M. Nakano, H. Ube Chemistry Views 2013-06-18 |
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"Relay Catalysis via a Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" M. Terada, Y. Toda Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 538 2012-04-18 |
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"Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3’-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels-Alder Reaction of ,-Unsaturated Aldehydes with Amidodienes" N. Momiyama, T. Konno, T. Furiya, T. Iwamoto, M. Terada Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 209 2012-01-19 |
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"Chiral Brønsted Acid Catalyzed Stereoselective Addition of Azlactones to 3-Vinylindoles for Facile Access to Enantioenriched Tryptophan Derivatives" M. Terada, K. Moriya, K. Kanomata, K. Sorimachi Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 99 2011-12-19 |
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"Enantioselective Direct Vinylogous Michael Addition of
Functionalized Furanones to Nitroalkenes Catalyzed by an Axially Chiral
Guanidine Base" M. Terada, K. Ando Synfact ‘Highlights in Current Synthetic Organic Chemistry’2011, 680 2011-05-19 |
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"Highly Stereoselective [4+2] Cycloaddition of Azlactones to ,-Unsaturated -Ketoesters Catalyzed by an Axially Chiral Guanidine Base" M. Terada, H. Nii Synfact ‘Highlights in Current Synthetic Organic Chemistry’2011, 330 2011-02-16 |
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| A01 秋山 隆彦 | ||
| Original papers |
"Cluster Preface: BINOL Phosphates for Chemistry" *Akiyama, T. Synlett 2016, 27 (4), pp.542-545. DOI:DOI: 10.1055/s-0035-1561678 |
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"Chiral Phosphoric Acid Catalyzed Kinetic Resolution of Indolines Based on a Self-Redox Reaction" Saito. K.; *Akiyama, T. Angew. Chem. Int. Ed. 2016, 55 (9), pp.3148-3152. DOI:DOI: 10.1002/anie.201510692 |
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"Why Benzothiazoline Cannot Be as Effective as Hantzsch Ester as a Hydrogen Donor in Chiral Phosphoric Acid-Catalyzed Asymmetric Reductive Amination of Ketones" Kim, K.-H.; *Akiyama, T.; *Cheon, C.-H. Chem. Asian J. 2016, 11 (2), pp.274-279. DOI:DOI: 10.1002/asia.201501020 |
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"Transformation of Trifluorotoluenes Triggered by Titanium Chloride(IV) Catalyzed Hydrodefluorination Using Hydrosilanes" Yamada, T.; Saito, K.; *Akiyama, T. Adv. Synth. Catal. 2016, 358 (1), pp.62-66. DOI:DOI: 10.1002/adsc.201500920 |
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"Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Cyclic Secondary Amine Derivatives including Tetrahydroquinolines by Hydrogen Transfer to Imines" Saito, K; Miyashita, H.; *Akiyama, T. Chem. Commun. 2015, DOI:DOI: 10.1039/C5CC06436H |
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"Enantioselective Synthesis of Fused Heterocycles with Contiguous Stereogenic Centers by Chiral Phosphoric Acid Catalyzed Symmetry Breaking" Mori, K.; Miyake, A.; *Akiyama, T. Chem. Commun. 2015, DOI:DOI: 10.1039/C5CC05508C |
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"B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes – Metal-Free Reduction of Sulfides" Saito, K.; Kondo, K.; *Akiyama, T. Org. Lett. 2015, 17 (13), pp.3366-3369. DOI:DOI: 10.1021/acs.orglett.5b01651 |
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"Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of 2-Substituted 2,3-Dihydro-4-quinolones by a Protecting-Group-Free Approach" Saito, K.; Moriya, Y.; *Akiyama, T. Org. Lett. 2015, 17 (13), pp.3202-3205. DOI:DOI: 10.1021/acs.orglett.5b01654 |
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"Synthesis of 3-Aryl-1-trifluoromethyltetrahydroisoquinolines by Bronsted Acid Catalyzed C(sp3)-H Bond Functionalization" Mori, K.; Umehara, N.; *Akiyama, T. Adv. Synth. Catal. 2015, 357 (5), pp.901-906. DOI:10.1002/adsc.201400775 |
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"γ-Silylboronates in the Chiral Brønsted ACid-catalysed Allylboration of Aldehydes" *Pablo, B.; Rodriguez, E.; Saito, K.; Fustero, S.; *Akiyama, T. Chem. Commun. 2015, 51 (25), pp.5246-5249. DOI:10.1039/C4CC08598A |
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"Enantioselective Synthesis of Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy" Mori, K.; Kobayashi, M.; Itakura, T.; Akiyama, T. Adv. Synth. Catal. 2015, 357 (1), pp.35-40. DOI:10.1002/adsc.201400611 |
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"Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable, Hydrogen Donor" Saito, K.; Miyashita, H.; Akiyama, T. Org. Lett. 2014, 16 (20), pp.5312-5315. DOI:10.1021/ol502486f |
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"Chiral Phosphoric-Acid-Catalyzed Transfer Hydrogenation of Ethyl Ketimine Derivatives by Using Benzothiazoline" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Chem. Eur. J. 2014, 20 (25), pp.7616-7620. DOI:10.1002/chem.201402763 |
山中正浩 | |
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"Phosphoric Acid Bridged Cobalt Bis(dicarbollide) Ion as a Highly Efficient Catalyst for the Organocatalytic Hydrogenation of Ketimines" *Akiyama, T.; Saito, K.; Janczak, S.: Lesnikowski, Z. Synlett 2014, 25 (6), pp.795-798. DOI:10.1055/s-0033-1340847 |
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"Stereoselective Construction of All Carbon Quaternary Center by Chiral Phosphoric Acid: Highly Enantioselective Friedel-Crafts Reaction of Indoles with beta,beta-Disubstituted Nitoroalkenes" Mori, K.; Wakazawa, M.; *Akiyama, T. Chem. Sci. 2014, 5 (5), pp.1799-1803. DOI:10.1039/C3SC53542H |
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"Double C(sp3)-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles" Mori, K.; Kurihara, K.; Yabe, S.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2014, 136 (10), pp.3744-3747. DOI:10.1021/ja412706d |
山中正浩 | |
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"Expeditious Synthesis of 1-Aminoindane Derivatives Achieved by [1,4]-Hydride Shift Mediated C(sp3)-H Bond Functionalization" Mori, K.; Kurihara, K.; *Akiyama, T. Chem. Commun. 2014, 50 (28), pp.3729-3731. DOI:10.1039/C4CC00894D |
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"Enantioselective Fluorination of beta-Ketoesters Catalyzed by Chiral Sodium Phosphate: Remarkable Enhancement of Reactivity by Simultaneous Utilization of Metal Enolate and Metal Phosphate
" Mori, K.; Miyake, A.; *Akiyama, T. Chem. Lett. 2014, 43 (1), pp.137-139. DOI:org/10.1246/cl.130934 |
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"Chiral Copper(II) Phosphate Catalyzed Enantioselective Synthesis of Isochromene Derivatives by Sequential Intramolecular Cyclization and Asymmetric Transfer Hydrogenation of o-Alkynylacetophenones" Saito, K.; Kajiwara, Y.; *Akiyama, T. Angew. Chem. Int. Ed. 2013, 52 (50), pp.13284-13288. DOI:10.1002/anie.201308303 |
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"Enantioselective Transfer Hydrogenation of Difluoromethyl Ketimines Using Benzothiazoline as a Hydrogen Donor in Combination with Chiral Phosphoric Acid" Sakamoto, T.; Horiguchi, K.; Saito, K.; Mori, K.; *Akiyama, T. Asian J. Org. Chem. 2013, 2 (11), pp.943-946. DOI:10.1002/ajoc.201300174 |
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"Prediction of Suitable Catalyst by 1H NMR: Asymmetric Synthesis of Multisubstituted Biaryls by Chiral Phosphoric Acid Catalyzed Asymmetric Bromination" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. Chem. Sci. 2013, 4 (11), pp.4235-4239. DOI:10.1039/C3SC52142G |
山中正浩 | |
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"Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines" Saito, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (32), pp.11740-11743. DOI:doi:10.1021/ja406004q |
山中正浩 | |
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"Molecular iodine catalyzed transfer hydrogenation: reduction of aldimines, ketimines, and alpha-imino esters" Bachu, P.; Zhu C.; *Akiyama, T. Tetrahedron Lett. 2013, 54 (30), pp.3977-3981. DOI:org/10.1016/j.tetlet.2013.05.071 |
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"Hydrodefluorinations of Trifluorotoluenes by LiAlH4 and TiCl4" *Akiyama, T.; Atobe, K.; Shibata, M.; Mori, K. J. Fluorine Chem. 2013, 152 pp.81-83. DOI:org/10.1016/j.jfluchem.2013.03.001 |
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"Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (10), pp.3964-3970. DOI:DOI: 10.1021/ja311902f |
山中正浩 | |
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"Kinetic Resolution in Chiral Bronsted Acid Catalyzed Aldol Reaction: Enantioselective Robinson-type Annulation Reaction" Yamanaka, M.; Hoshino, M.; Katoh, T.; Mori, K.; *Akiyama, T. Eur. J. Org. Chem. 2012, (24), pp.4508-4514. DOI:10.1002/ejoc.201200338 |
山中正浩 | |
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"Phopshoric Acid Catalyzed Enantioselective Transfer Deruteration of Ketimines by Use of Benzothiazoline as a Deuterium Donor: Synthesis of Optically Active Deuterated Amines" Sakamoto, T.; Mori, K.; *Akiyama, T. Org. Lett. 2012, 14 (13), pp.3312-3315. DOI:10.1021/ol3012869 |
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"Enantioselective Organocatalytic Reductive Amination of Aliphatic Ketones by Benzothiazoline as Hydrogen Donor" Saito, K.; *Akiyama, T. Chem. Commun. 2012, 48 (38), pp.4573-4575. DOI:10.1039/C2CC31486J |
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"Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp3)-H Bond Functionalization and Its Application to Formal Synthesis of (+-)-Tetrahydropalmatine" Mori, K.; Kawasaki, T.; *Akiyama, T. Org. Lett. 2012, 14 (6), pp.1436-1439. DOI:10.1021/ol300180w |
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"Carboxyl-Tailed Benzothiazoline: A Readily Removable Hydrogen Donor for the Transfer Hydrogenation of Imines" Zhu, C.; *Akiyama, T. Tetrahedron Lett. 2012, 53 (4), pp.416-418. DOI:10.1016/j.tetlet.2011.11.061 |
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"Rapid Access to 3-Aryltetraline Skeleton via C(sp3)–H Bond Functionalization: Investigation on the Substituent Effect of Aromatic Ring Adjacent to C–H Bond in Hydride Shift/Cyclization Sequence" Mori, K.; Sueoka, S.; *Akiyama, T. Chem. Lett. 2011, 40 (12), pp.1386-1388. DOI:10.1246/cl.2011.1386 |
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"Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation: A Facile Synthetic Access to Highly Optically Active Trifluoromehylated Amines" Henseler, A.; Kato, M.; Mori, K.; *Akiyama, T. Angew. Chem. Int. Ed. 2011, 50 (35), pp.8180-8183. DOI:10.1002/anie.201103240 |
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"Brønsted Acid Catalyzed Reductive Amination with Benzothiazoline as a Highly Efficient Hydrogen Donor" Zhu, C.; *Akiyama, T. Synlett 2011, (9), pp.1251-1254. DOI:10.1055/s-0030-1260539 |
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"Selective Activation of Enantiotopic C(sp3)-Hydrogen by Means of a Chiral Phosphoric Acid: Asymmetric Synthesis of Chiral Tetrahydroquinoline Derivatives" Mori, K.; Ehara, K.; Kurihara, K.; *Akiyama, T. J. Am. Chem. Soc. 2011, 133 (16), pp.6166-6169. DOI:10.1021/ja2014955 |
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"Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of β-Amino-α,α−difluoro Carbonyl Compounds," Kashikura, W.; Mori, K.; *Akiyama, T. Org. Lett. 2011, 13 (7), pp.1860-1863. DOI:10.1021/ol200374m |
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"Expeditious Construction of a Carbobicyclic Skeleton via a sp3-C–H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process
" Mori, K.; Sueoka, S.; *Akiyama, T. J. Am. Chem. Soc. 2011, 133 (8), pp.2424-2426. DOI:10.1021/ja110520p |
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| Books |
「Comprehensive Organic Synthesis, 2nd Edition, Volume 2」 Molander, G. A.; Kochel, P. "The Bimolecular and Intramolecular Mannich and Related Reactions" Akiyama, T. Elsevier (Oxford) 2014, pp629-681. |
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「Comprehensive Enantioselecitve Organocatalysis Volume 2」 Dalko, P. I. "Chiral Phosphoric Acid Catalys in Asymmetric Synthesis" Mori, K.; Akiyama, T. Wiley-VCH (Weinheim) 2013, pp289-314. |
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「「CSJカレントレビュー」未来を拓く元素戦略 - 持続可能な社会を実現する化学」 日本化学会 "有機分子触媒" 秋山隆彦 化学同人 2013, pp45-50. |
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「Volume 6: Synthetic Methods V -Organocatalysis, Comprehensive Chirality」 Keiji Maruoka "C-C Bond Formation : Mannich Reaction" Akiyama, T. Elsevier 2013, pp69-96. |
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「Asymetric Synthesis II」 Mathias Christmann and Stephan Bräse "Asymmetric C-C Bond Formation Using Chiral Phoshoric Acid" Akiyama, T. Wiley-VCH (Weinheim) 2012, pp261-266. |
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「Handbook of Green Chemistry」 Chao-Jun Li "Synthesis without Metals" Akiyama, T Wiley-VCH (Weinheim) 2012, pp307-334. |
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「Asymmetric Organocatalysis, Science of Synthesis」 Keiji Maruoka "Phosphoric Acid Catalyzed Reactions of Imines" Akiyama, T.* Georg Thieme Verlag KG (Stuttgart) 2013, pp169-217. |
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| Reviews / Accounts |
"The Bimolecular and Intramolecular Mannich and Related Reactions" Akiyama, T. Comprehensive Organic Synthesis II 2014, 2 pp.629-681. |
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"Stronger Brønsted Acids: Recent Progress" *Akiyama, T.; Mori, K. Chem. Rev. 2015, 115 (17), pp.9277-9306. DOI:DOI: 10.1021/acs.chemrev.5b00041 |
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"Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation" Zhu, C.; Saito, K.; Yamanaka, M.; *Akiyama, T. Acc. Chem. Res. 2015, 48 (2), pp.388-398. DOI:10.1021/ar500414x |
山中正浩 | |
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"キラルブレンステッド酸の開発と不斉合成反応への展開" 秋山隆彦 有機合成化学協会誌 2011, 69 (11), pp.913-925. DOI:org/10.5059/yukigoseikyokaishi.69.913 |
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| Conference / Symposium / Lecture |
招待講演 "Stereoselective Synthesis of Heterocycles Based on the Internal Redox Reaction"" ○Akiyama, T. DOMINOCAT 1 Symposium, Aachen (ドイツ) 2015-09-09～2015-07-11 |
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招待講演 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation Reactions" ○Akiyama, T. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, 仙台 (日本) 2015-09-06～2015-09-09 |
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招待講演 "Stereoselective Synthesis of CF3-containing Heterocycles based on the Internal Redox Reaction" ○Akiyama, T. 9th French-Japanese Seminar on Fluorine, Nice (フランス) 2015-08-31～2015-09-01 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Phosphoric Aicd" ○Akiyama, T. 21st International Symposium on Fluorine Chemistry, Como (イタリア) 2015-08-23～2015-08-28 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. IUPAC 2015, 45th World Chemistry Congress,, 釜山 (韓国) 2015-08-08～2015-08-14 |
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口頭発表／ポスター発表 "Asymmetric Synthesis of 2-Substituted Dihydroquinolones by The Aza-Michael Reaction of N-Unprotected Amines" ○Moriya, Y.; Saito, K.; *Akiyama, T. The 3rd International Symposium on Process Chemistry, 京都 (日本) 2015-07-13～2015-07-15 |
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招待講演 "Transfer hydrogenation reactions of ketimines by means of chiral phosphoric acid" ○Akiyama, T. The 39th Naito Conference on the Chemistry of Organocatalysts, 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. XIV ICSN Smposium, Gif-sur-Yvette (フランス) 2015-06-18～2015-06-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at National Chiao Tung University（國立交通大學）, 新竹 (台湾) 2015-06-08～2015-06-08 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at University of Alicante, Alicante (Spain) 2015-05-19～2015-05-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at University of Valencia, Valencia (Spain) 2015-05-14～2015-05-14 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Department Seminar at New York University, New York (USA) 2015-03-03～2015-03-03 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Department Seminar at Rutgers University, Piscataway (USA) 2015-03-02～2015-03-02 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at the University of Pennsylvania, Philadelphia (USA) 2015-02-27～2015-02-27 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Phosphoric Acid" ○Akiyama, T. Japan/Russian Conference on Fluorine Chemistry and Friends, Nagoya (Japan) 2014-12-09～2014-12-09 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Trifluoromethylated N-H Ketimine Using Benzothiazoline " ○Noda, H.; Akiyama, T.; Yamanaka, M. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
山中正浩 | |
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口頭発表／ポスター発表 "Theoretical Study on the Mechanism of Stereoselectivity in Chiral Phosphorus Acid Catalyzed Asymmetric Hydrogenation of 1, 5-benzodiazepine Using benzothiazoline " ○Yamamoto, E.; Horiguchi, K.; Saito, K.; Akiyama, T.; Yamanaka, M. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Enantioselective Route to Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy" ○Itakura, T.; Kobayashi, M.; Mori, K.; Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2015-01-22～2015-01-22 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid-Catalyzed Hydrogen Transfer Reaction of Indoline to Imines " ○Miyashita, H.; Saito, K.; Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Friedel-Crafts Alkylation of Indoles by Means of Chiral Phosphoric Acid" ○Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Oxidative Kinetic Resolution of Indolines Based on the Enantioselective Transfer Hydrogenation of Ketimines by Means of Phosphoric Acid" ○Akiyama, T. Vietnam Malaysian International Chemical Congress (VMICC)), Hanoi (Vietnam) 2014-11-07～2014-11-09 |
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招待講演 "Enantioselective Synthesis of Chiral Biaryl Skeleton base on the Bromination of Cs-Symmetric Biaryls by Means of Phosphoric Acid " ○Akiyama,T. 18th Malaysian International Chemical Congress (18MICC)), Kuala Lumpur (Malaysis) 2014-11-04～2014-11-05 |
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基調講演 "Chiral Phosphoric Acid Catalyzed Enantioselective Reactions" ○Akiyama, T. Chiral China 2014, Hefei (China) 2014-09-29～2014-09-30 |
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口頭発表／ポスター発表 "Oxidative Kinetic Resolution of Indolines Based on the Enantioselective Transfer Hydrogenation of Ketimines by Means of Chiral Phosphoric Acid" ○Akiyama, T.; Saito, K. 5th EuCheMS Chemistry Congress, Istanbul (Turkey) 2014-08-31～2014-09-04 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Asymmetrci Reactions" ○Akiyama, T. Gordon Research Conferences on Natural Products, Andover (USA) 2014-07-20～2014-07-25 |
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基調講演 "Enantioselective Synthesis of Fluorinated Compoudns by Means of Chiral Phosphoric Acid " ○Akiyama, T. Bordeaux Fluorine Days, Bordeaux (France) 2014-07-06～2014-07-11 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at Ecole Polytechnique, Paris (France) 2014-07-04～2014-07-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at the University of Lyon, Lyon (France) 2014-07-03～2014-07-03 |
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基調講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. 20th International Conference on Phosphorus Chemistry, Dublin (Ireland) 2014-06-28～2014-07-02 |
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口頭発表／ポスター発表 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" Akiyama, T. Asymmetric Synthesis Conference (Zing Conference), Nerja (Spain) 2014-02-25～2014-02-28 |
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招待講演 "Development of Enantioselective Reactions Catalyzed by Chiral Phosphoric Acid" Akiyama, T. Indo-Japanese Conference on Process Chemistry R&D, Mumbai (India) 2014-01-30～2014-01-31 |
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招待講演 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" ○Akiyama, T.; Saito, K. International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), Beijing (China) 2013-12-01～2013-12-05 |
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招待講演 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" ○*Akiyama, T.; Saito, K. International Symposium on Organic Reactions 2013 (ISOR 2013), 台北 (台湾) 2013-11-19～2013-11-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of Texas at Austiin, Austin (USA) 2013-08-23～2013-08-23 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of California at Los Angeles, Los Angeles (USA) 2013-08-21～2013-08-21 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of California, Berkeley, Berkeley (USA) 2013-08-20～2013-08-20 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at ICSN (Institute de Chimie des Substances Naturelles), , Gif-sur-Yvette (France) 2013-07-26～2013-07-26 |
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口頭発表／ポスター発表 "Enantioselective Transfer Hydrogenation of CF3-substituted Ketimines by Means of Chiral Phosphoric Acid" *Akiyama, T. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the Delft University of Technology, Delft (The Netherland) 2013-07-19～2013-07-17 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Use of Benzothiazoline as a Hydrogen Donor" Akiyama, T. Advance Molecular Transformations by Organocatalysts, First International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The University of Hong Kong, Hong Kong (Hong Kong) 2013-03-13～2013-03-13 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The Hong Kong University of Science and Technology, Kowloon (Hong Kong) 2013-03-12～2013-03-12 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Chung Hsing University, Taichiung (Taiwan) 2013-03-07～2013-03-07 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Chung Cheng University, ChiaYi (Taiwan) 2013-03-06～2013-03-06 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Tsing Hua University, HsinChu (Taiwan) 2013-03-05～2013-03-05 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama. T. Department Seminar at National Taiwan Normal University, Taipei (Taiwan) 2013-03-04～2013-03-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at University of Texas Southwestern Medical Center, Dallas (USA) 2013-01-22～2013-01-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at University of South Florida, Tampa (USA) 2013-01-18～2013-01-18 |
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招待講演 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Trifluorimethylated Ketimines" Akiyama, T. 21st Winter Fluorine Conference, St. Pete Beach (USA) 2013-01-13～2013-01-18 |
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招待講演 "Enantioselective Transfer Hydrogenation by Use of Benzothiazoline" Akiyama, T. Japan-US Organocatalytic Symposium in Hawaii (2012),, Honolulu (USA) 2012-12-16～2012-12-18 |
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依頼講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Japan-Singapore Bilateral Symposium on Synthetic Organic Chemistsry, Singapore (Singapore) 2012-10-30～2012-10-30 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Use of Benzothiazoline as a Novel Hydrogen Donor" Akiyama, T. Cambodian Malaysian Chemical Conference (CMCC) 2012, Siem Reap (Cambodia) 2012-09-19～2012-09-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis
" Akiyama, T. Department Seminar at Zhejiang Sci-Tech University, Hangzhou (China) 2012-09-22～2012-09-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Zhejiang University, Hangzhou (China) 2012-09-20～2012-09-20 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at East China University of Science and Technology, Shanghai (China) 2012-09-19～2012-09-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Shanghai Institute of Organic Chemistry, Shanghai (China) 2012-09-19～2012-09-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at East China Normal University, Shanghai (China) 2012-09-18～2012-09-18 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at McGill University, Montreal (Canada) 2012-08-08～2012-08-08 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimines" Akiyama, T. Gordon Research Conferences on Stereochemistry, Newport (USA) 2012-07-29～2012-08-03 |
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口頭発表／ポスター発表 "Addition Reaction of Niobium Fluorocarbenoid Species Generated from Trifluorotoluene " ○Ito, R.; Atobe, K.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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口頭発表／ポスター発表 "Low-valent Titanium-catalyzed Reduction of Trifluorotoluene Derivatives" ○Shibata, M.; Atobe, K.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Trifluoromethyl Imines: Facile Synthetic Access to Highly Optically Active Trifluoromethylated Amines" ○Sato, T.; Henseler, A.; Kato, M.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Bronsted Acid Catalyt" Akiyama, T. Valencia Fluorine Days: Symposium on Fluorine Chemistry, Valencia (Spain) 2012-05-20～2013-05-24 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions " Akiyama, T. Department Seminar at Institute of Chemical Research of Catalonia, Tarragona (Spain) 2012-05-18～2012-05-18 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Enantioselective S(sp3)-H Bond Activation " Akiyama, T. The 47th Burgenstock Conference, Brunnen (Switzerland) 2012-04-29～2012-05-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The University of Sydney, Sydney (Australia) 2012-03-09～2012-03-09 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Griffith University, Brisbane (Australia) 2012-03-08～2012-03-08 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Means of Benzothiazoline as Novel Hydrogen Donor " Akiyama, T. International Symposium on Catalysis and Fine Chemicals 2011 (C&FC2011), Nara (Japan) 2011-12-04～2011-12-08 |
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口頭発表／ポスター発表 "Efficient Approach to Optically Active Tetrasubstituted Biaryl Skeleton by Chiral Phosphoric Acid-Catalyzed Asymmetric Bromination " ○Ichikawa, Y.; Mori, K.; Kobayashi, M.; *Akiyama, T. 10th International Symposium on Organic Reactions (ISOR 10), Yokohama (Japan) 2011-11-23～2011-11-24 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid catalyzed Enantioselective Deuteride Reduction of Ketimines " ○Sakamoto, T.; Zhu, C.; Mori, K.; *Akiyama, T. Yokohama (Japan) 2011-11-23～2011-11-24 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. 10th International Symposium on Organic Reactions (ISOR 10), Yokohama (Japan) 2011-11-23～2011-11-24 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed C(sp3)-H Bond Functionalization: Asymmetric Synthesis of Tetrahydroquinoline Derivatives" ○Mori, K.; Ehara, K.; Kurihara, K.; *Akiyama, T. 1st International Symposium on Molecular Activation, Awaji (Japan) 2011-11-09～2013-11-10 |
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招待講演 "Chiral Phosphoric Acid Catalyzed C(sp3)-H Bond Activation" Akiyama, T. First German-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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招待講演 "Low-valent Niobium Mediated Activation of C-F/C-H Bonds" Akiyama, T. The 5th Asian Network of Metal Chemistry, The 14th Asian Chemical Congress, Bangkok (Thailand) 2011-09-05～2011-09-08 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid-Catalyzed Enantioselective C-H Bond Functionalization: Construction of Chiral Tetarhydroquinoline Skeleton" ○Kurihara, K.; Ehara, K.; Mori, K.; *Akiyama, T. The 2nd International Symposium on Process Chemistry, Kyoto (Japan) 2011-08-11～2011-08-12 |
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口頭発表／ポスター発表 "Efficient Approach to Optically Active Tetrasubstituted Biaryl Skeleton by Chiral Phosphoric Acid-Catalyzed Asymmetric Bromination" ○Kobayashi, M.; Ichikawa, Y.; Mori, K.; *Akiyama, T. The 2nd International Symposium on Process Chemistry, Kyoto (Japan) 2011-08-11～2011-08-12 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Aachen University, Aachen (Germany) 2011-08-03～2011-08-03 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Munster University, Munster (Germany) 2011-08-01～2011-08-01 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at the MaxPlanck Institute, Muelheim an der Ruhr (Germany) 2011-07-29～2011-07-29 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Boston College, Chestnut Hill (USA) 2011-07-22～2011-07-22 |
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口頭発表／ポスター発表 "Chiral Bronsted Acid Catalyzed Asymmetric Reactions" Akiyama, T. Gordon Research Conferences on Organic Reactions & Processes, Smithfield (USA) 2011-07-17～2011-07-22 |
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招待講演 "Chiral Bronsted Acid Catalyzed Asymmetric Reactions" Akiyama, T. Department Seminar at North Dakota State University, Fargo (USA) 2011-07-15～2011-07-15 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Enantioselective Reactions" Akiyama, T. TrostCon, Stanford (USA) 2011-06-25～2013-06-25 |
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| Prize |
"Arthur C. Cope Scholar Award" 2016-08 American Chemical Society |
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"Humboldt Research Award" Akiyama, T. 2016-03 Alexander von Humboldt Foundation |
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"名古屋シルバーメダル2012" 秋山隆彦 2012-11 公益財団法人万有生命科学振興国際交流財団 |
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| Media |
"Isochromenes Synthesis by Cyclization and Asymmetric Transfer Hydrogenation" Saito, K.; Kajiwara, Y.; Akiyama, T. Synfacts 2014-02-17 |
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"Phosphoric Acid Catalyzed Transfer Hydrogenation of Ethyl Ketimines" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Synfacts 2014-07-18 |
山中正浩 | |
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"Asymmetric Organocatalytic Synthesis of Tetrasubstituted Chiral Biaryl Compounds" Mori, K.; Ichikawa,Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Synfacts 2013-04-16 |
山中正浩 | |
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"Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimines" Henseler, A.; Kato, M.; Mori, K.; Akiyama, T. Synfacts 2011-09-20 |
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"2016 Cope and Cope Scholar Award Winners" Akiyama, T. Chemical & Engineering News 2016-01-11 PDF |
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| A01 浦口 大輔 | ||
| Original papers |
"Independence from the Sequence of Single-Electron Transfer of Photoredox
Process in Redox-Neutral Asymmetric Bond-Forming Reaction" Tomohito Kizu, Daisuke Uraguchi, and *Takashi Ooi J. Org. Chem. 2016, DOI:DOI: 10.1021/acs.joc.6b00445 |
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"Fenton reagent-catalyzed trifluoromethylation of enamines of 3-oxocarboxylates with CF3I" Yuhki Ohtsuka, Daisuke Uraguchi, Kyoko Yamamoto, Kenji Tokuhisa, *Tetsu Yamakawa J. Fluorine Chem. 2016, 181 pp.1-6. DOI:DOI: 10.1016/j.jfluchem.2015.10.013 |
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"Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines" Daisuke Uraguchi, Natsuko Kinoshita, Tomohito Kizu, and *Takashi Ooi J. Am. Chem. Soc. 2015, 137 pp.13768-13771. DOI:DOI: 10.1021/jacs.5b09329 |
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"Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes" Matthew A. Horwitz, Naoya Tanaka, Takuya Yokosaka, Daisuke Uraguchi, *Jeffrey S. Johnson and *Takashi Ooi Chem. Sci. 2015, 6 DOI:10.1039/C5SC02170G |
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"Highly E-Selective and Enantioselective Michael Addition to Electron-Deficient Internal Alkynes Under Chiral Iminophosphorane Catalysis" Daisuke Uraguchi, Kohei Yamada and *Takashi Ooi Angew. Chem. Int. Ed. 2015, 54 (34), pp.9954-9957. DOI:10.1002/anie.201503928 |
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"Vinylogy in Nitronates: Utilization of α-Aryl Conjugated Nitroolefins as a Nucleophile for Highly Stereoselective Aza-Henry Reaction" Keigo Oyaizu, Daisuke Uraguchi, *Takashi Ooi Chem. Commun. 2015, 51 (21), pp.4437-4439. DOI:10.1039/C4CC10261D |
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"Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines" Daisuke Uraguchi, Keigo Oyaizu, Haruhiro Noguchi, *Takashi Ooi Chem. Asian J. 2015, 10 (2), pp.334-337. DOI:10.1002/asia.201402943 |
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"Enantioselective Protonation of α-Hetero Carboxylic Acid-Derived Ketene Disilyl Acetals under Chiral Ionic Brønsted Acid Catalysis" Daisuke Uraguchi, Tomohito Kizu, Yuki Ohira, *Takashi Ooi Chem. Commun. 2014, 50 (88), pp.13489-13491. DOI:10.1039/C4CC06081D |
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"Enantioselective Formal α-Allylation of Nitroalkanes through Chiral Iminophosphorane-Catalyzed Michael Reaction/Julia-Kocienski Olefination Sequence" Daisuke Uraguchi, Shinji Nakamura, Hitoshi Sasaki, Yuki Konakade, and *Takashi Ooi Chem. Commun. 2014, 50 (26), pp.3491-3493. DOI:10.1039/C3CC49477B |
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"Practical Preparation of Chiral N-Sulfonyl Oxaziridines by Catalytic Asymmetric Payne Oxidation" Ryosuke Tsutsumi, Seonwoo Kim, Daisuke Uraguchi, *Takashi Ooi Synthesis 2014, 46 (7), pp.871-878. DOI:10.1055/s-0033-1340818 |
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"Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: application to the synthesis of N-sulfonyl oxaziridines" Daisuke Uraguchi, Ryosuke Tsutsumi, *Takashi Ooi Tetrahedron 2014, 70 (8), pp.1691-1701. DOI:10.1016/j.tet.2013.12.086 |
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"Catalytic Asymmetric Oxidation of N-Sulfonyl Imines with Hydrogen Peroxide–Trichloroacetonitrile System" Daisuke Uraguchi, Ryosuke Tsutsumi, and *Takashi Ooi J. Am. Chem. Soc. 2013, 135 DOI:10.1021/ja403491j |
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"Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis: Importance of Protonation Pathway" Uraguchi, Daisuke; Ueki, Yusuke; Sugiyama, Atsushi; *Ooi, Takashi Chem. Sci. 2013, 4 (3), pp.1308-1311. DOI:10.1039/C2SC22027J |
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"Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles" Daisuke Uraguchi, Ken Yoshioka, Yusuke Ueki, and *Takashi Ooi J. Am. Chem. Soc. 2012, 134 (47), pp.19370-19373. DOI:10.1021/ja310209g |
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"Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins" Uraguchi, Daisuke; Kinoshita, Natsuko; Nakashima, Daisuke; *Ooi, Takashi Chem. Sci. 2012, 3 (11), pp.3161-3164. DOI:10.1039/C2SC20698F |
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"Nitroolefins as a Nucleophilic Component for Highly Stereoselective Aza-Henry Reaction under the Catalysis of Chiral Ammonium Betaines" Uraguchi, Daisuke; Oyaizu, Keigo; *Ooi, Takashi Chem. Eur. J. 2012, 18 (27), pp.8306-8309. DOI:10.1002/chem.201201259 |
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"Ionic Nucleophilic Catalysis of
Chiral Ammonium Betaines for Highly Stereoselective Aldol Reaction from
Oxindole-Derived Vinylic Carbonates" Uraguchi,
D.; Koshimoto, K.; *Ooi, T. J. Am. Chem. Soc. 2012, 134 (16), pp.6972-6975. DOI:10.1021/ja3022939 |
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"Base-Catalyzed Direct
Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates" Corbett, M. T.; Uraguchi,
D.; *Ooi, T.; *Johnson, J. S. Angew. Chem. Int. Ed. 2012, 51 (19), pp.4685-4689. DOI:10.1002/anie.201200559 |
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"Highly Stereoselective Catalytic
Conjugate Addition of Acyl Anion Equivalent to Nitroolefins" Uraguchi, D.; Ueki, Y.;
*Ooi, T. Chem. Sci. 2012, 3 (3), pp.842-845. DOI:10.1039/C1SC00678A |
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"Enantioselective Aza-Michael
Addition to Conjugated Nitroenynes Catalyzed by Chiral Arylaminophosphonium
Barfates" Uraguchi,
D.; Kinoshita, N.; Kizu, T.; *Ooi, T. Synlett 2011, (9), pp.1265-1267. DOI:10.1055/s-0030-1260541 |
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"Precise Control of Spontaneous
Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide–Arylhydroxide(s)
in Solution" Uraguchi,
D.; Ueki, Y.; *Ooi, T. Angew. Chem. Int. Ed. 2011, 50 (16), pp.3681-3683. DOI:10.1002/anie.201007752 |
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| Books |
「CSJカレントレビュー「有機分子触媒の化学」」 寺田眞浩 "イオン対を中心とした不斉塩基触媒" 浦口大輔、大井貴史 日本化学会 2016, |
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「Topics in Current Chemistry: Site Selective Catalysis」 T. Kawabata "Site-Selective Conjugate Addition through Catalytic Generation of Ion-Pairing Intermediates" Daisuke Uraguchi, Takashi Ooi Springer 2016, |
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「Comprehensive Enantioselective Organocatalysis」 Peter I. Dalko "Axially Chiral C2-Symmetric Catalysts" Uraguchi, Daisuke; Kohsuke, Ohmatsu; Ooi, Takashi Wiley-VCH 2013, ISBN:3527332367 |
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「Stereoselective Synthesis of Drugs and Natural Products」 Vasyl Andrushko, Natalia Andrushko "Asymmetric Phase-Transfer Catalysis" Kohsuke, Ohmatsu; Uraguchi, Daisuke; Ooi, Takashi Wiley 2013, ISBN:1118032179 |
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「ELECTRONIC ENCYCLOPEDIA OF REAGENTS FOR ORGANIC SYNTHESIS (e-EROS)」 "1,4,6,9-Tetraaza-5λ5-phosphaspiro[4.4]non-5-ene, 3,8-bis(1-methylethyl)-2,2,7,7-tetrakis(4-methylphenyl)-, hydrochloride (1:1), (3R,5R,8R)-" Uraguchi, Daisuke; Ooi, Takashi Wiley 2012, ppRN01546-. |
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「COMPREHENSIVE CHIRALITY」 Hisashi Yamamoto, Erick M Carreira "C–C Bond Formation: Alkylation" Uraguchi, Daisuke; Ooi, Takashi Elsevier Science 2013, pp1-36. ISBN:0080951678 |
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「Science
of Synthesis: Asymmetric Organicatalysis 2」 Maruoka, K. "Hydrogen-Bonding Catalysts Other than Ureas and Thioureas" Uraguchi, D.; Ooi, T. Georg Thieme Verlag KG (Stuttgart) 2012, pp413-435. |
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| Reviews / Accounts |
"Lectureship Award MBLA 2014受賞講演ツアーを終えて" 浦口大輔 J. Synth. Org. Chem. Jpn 2015, 73 (6), pp.653-662. |
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| Conference / Symposium / Lecture |
依頼講演 "Asymmetric catalysis of P-spiro chiral tetraaminophosphonium salts" ○Daisuke Uraguchi Pacifichem 2015, Honolulu (USA) 2015-12-18～2015-12-18 |
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依頼講演 "Catalysis of P-Spiro Chiral Aminophosphonium Salts" ○Daisuke Uraguchi Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Stanford (USA) 2014-10-29～2014-10-29 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lectrure, Berkeley (USA) 2014-10-28～2014-10-28 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, PASADENA (USA) 2014-10-27～2014-10-27 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Cambridge (USA) 2014-10-24～2014-10-24 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Cambridge (USA) 2014-10-23～2014-10-23 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Rahway (USA) 2014-10-21～2014-10-21 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Princeton (USA) 2014-10-20～2014-10-20 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Zurich (Switzerland) 2014-10-17～2014-10-17 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Dusseldorf (Germany) 2014-10-15～2014-10-15 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Munchen (Germany) 2014-10-13～2014-10-13 |
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口頭発表／ポスター発表 "Chiral tetraaminophosphonium salts mediated highly regio- and stereoselective 1,6- and 1,8-additions" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "E/Z-Selective Asymmetric Conjugate Addition to Electron-Deficient Internal Alkynes" ○Kohei Yamada, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Betaine-Type Electron-Transfer Catalyst: Design and Application" ○Masahiro Torii, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Regio-, Stereo-, and Enantioselective Conjugate Addition of Azlactones to Enynyl N-Acylpyrazoles ligands" ○Ryo Shibazaki, Daisuke Uraguchi, *Takashi Ooi The 13th International Kyoto Conference, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Betaine-Type Electron-Transfer Catalyst: Design and Application" ○Masahiro Torii, Daisuke Uraguchi, *Takashi Ooi The 13th International Kyoto Conference, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of Dialkyl Phosphite Mediated Formal Asymmetric Cross Pinacol-Type Reaction Under the Catalysis of Chiral Triaminoiminophosphorane" ○Naoya Tanaka, Matthew A. Horwitz, Daisuke Uraguchi, *Takashi Ooi, *Jeffrey S. Johnson The 16th Tetrahedron Symposium, Berlin (Germany) 2015-06-17～2015-06-19 |
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口頭発表／ポスター発表 "Synthesis of α-Hetero Carboxylic Acids via Protonation under Chiral Ionic Brønsted Acid Catalysis" ○Tomohito Kizu, Daisuke Uraguchi, *Takashi Ooi the 19th International Symposium on Homogeneous Catalysis (ISHC-XIX), Ottawa (Canada) 2014-07-06～2014-07-13 |
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口頭発表／ポスター発表 "Enantioselective Formal α-Allylation of Nitroalkanes through Chiral Iminophosphorane-Catalyzed Michel Reaction/Julia-Kocienski Olefination Sequence" ○Hitoshi Sasaki, Shinji Nakamura, Yuki Konakade, Daisuke Uraguchi, *Takashi Ooi IGER International Symposium on Chemical Science in Asia, Nagoya (Japan) 2014-05-26～2014-05-28 |
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口頭発表／ポスター発表 "Chiral Asymmetric Oxidation of N-Sulfonyl α-Imino Ester with Hydrogen Peroxide" ○Naoya Tanaka, Daisuke Uraguchi, *Takashi Ooi The 2nd International Symposium on Transformative Bio-Molecules 2014, Nagoya (Japan) 2014-05-12～2014-05-12 |
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口頭発表／ポスター発表 "Chiral Tetraaminophosphonium Salts Mediated Highly Vinylog of Michel Addiions" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi The 2nd International Symposium on Transformative Bio-Molecules 2014, Nagoya (Japan) 2014-05-12～2014-05-12 |
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口頭発表／ポスター発表 "Diastereoselectivity Ambivalence in 1,6-Selective Conjugate Additions under the Catalysis of Chiral Aminophosphonium Aryloxides" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 第3回 キャンパスアジアシンポジウム, Seoul (Korea) 2013-11-07～2013-11-08 |
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口頭発表／ポスター発表 "Diastereodivergent Catalysis of Chiral Aminophosphonium Aryloxides for Highly Regio- and Stereoselective 1,6-Addition to δ-Aryl Dienyl N-Acylpyrroles" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 第10回カルバニオン化学国際シンポジウム（ISCC-10）, Kyoto (Japan) 2013-09-23～2013-09-26 |
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口頭発表／ポスター発表 "Development of a Vinylog of Stereoselective Michael Addition to δ-Substituted Dienyl N-Acylpyrroles" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 有機分子触媒による未来型分子変換第1回 国際会議 (兼) 第6回有機触媒シンポジウム , Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Precise Structural Control of Spontaneous Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide-Arylhydroxide(s)" ○Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi Nagoya University Global COE International Symposium on on Elucidation and Design of Materials and Molecular Functions & 7th and 8th Yoshimasa Hirata Memorial Lecture, Nagoya (Japan) 2011-11-28～2011-11-30 |
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口頭発表／ポスター発表 "Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis" ○Atsushi Sugiyama, Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi Nagoya University Global COE International Symposium on on Elucidation and Design of Materials and Molecular Functions & 7th and 8th Yoshimasa Hirata Memorial Lecture, Nagoya (Japan) 2011-11-28～2011-11-30 |
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口頭発表／ポスター発表 "Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton" ○Natsuko Kinoshita, Daisuke Uraguchi, *Takashi Ooi International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
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口頭発表／ポスター発表 "Catalytic Enantioselective Oxidation of N-Sulfonyl Imines Using Hydrogen Peroxide" ○Ryosuke Tsutsumi, Daisuke Uraguchi, *Takashi Ooi IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Highly Regio-, Diastereo-, and Enantioselective Vinylogous Michael Reaction" ○Ken Yoshioka, Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Late-Stage Activation Strategy for Asymmetric Oxidation with Hydrogen Peroxide: Application to the Synthesis of Chiral Oxaziridines" ○Ryosuke Tsutsumi, Daisuke Uraguchi, *Takashi Ooi 1st Japan-USA Organocatalytic Symposium in Hawaii (2012), (USA) 2012-12-16～2012-12-18 |
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招待講演 "Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins" ○Daisuke Uraguchi 1st Japan-USA Organocatalytic Symposium in Hawaii, (USA) 2012-12-16～2012-12-18 |
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| Prize |
"Lectureship Award MBLA 2013" Daisuke Uraguchi 2014-02 公益財団法人 万有生命科学振興国際交流財団 反応性イオン種の制御を志向したキラル有機イオン対触媒の創製と応用 |
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"Thieme Chemistry Journal Award 2014" Daisuke Uraguchi 2013-12 Thieme |
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"Banyu Chemist Award（BCA）" 浦口大輔 2012-10 公益財団法人 万有生命科学振興国際交流財団 反応性イオン種の制御を志向したキラル有機イオン対触媒の創製と応用 |
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"平成２３年度科学技術分野の文部科学大臣表彰若手科学者賞" 浦口大輔 2011-04 文部科学省 分子認識型キラル有機イオン対触媒の創製と応用の研究 |
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| Media |
"「Enantioselective Reductive Multicomponent Coupling Reactions between Isatins and Aldehydes」が、Chemical Science誌のBack Coverに選定" 2016-04-29 |
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""「Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines」が、Chem. Asian J.誌のInside Coverに選定" 2015-01-22" 2015-01-22 |
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|
"「Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: application to the synthesis of N-sulfonyl oxaziridines」が、Tetrahedron誌のCoverに選定" 2014-02-01 |
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|
"「Chiral Ionic Brønsted Acid-Achiral Brønsted Base
Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to
Nitroolefins」が、Chemical Science誌のBack Coverに選定" 2012-10-29 |
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| A01 山中 正浩 | ||
| Original papers |
"Dynamic Kinetic Resolution Approach for the Asymmetric Synthesis of Tetrahydrobenzodiazepines Using Transfer Hydrogenation by Chiral Phosphoric Acid" Horiguchi, K.; Yamamoto, E.; Saito, K.; Yamanaka, M.; *Akiyama, T. Chem. Eur. J. 2016, 22 (in press), DOI:10.1002/chem.201601611 |
T. Akiyama |
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"Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular crossaldol reactions" Baba, T.; Yamamoto, J.; Hayashi, K.; Sato, M.; Yamanaka, M.; Kawabata, T.; *Furuta, T. Chem. Sci. 2016, DOI:10.1039/C5SC04594K |
Kawabata, T. | |
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"Insights into the Molecular Recognition Process in Organocatalytic ChemoselectiveMonoacylation of 1,5-Pentanediol" Imayoshi, A.; *Yamanaka, M.; Sato, M.; Yoshida, K.; Furuta, T.; Ueda, Y.; *Kawabata, T. Adv. Synth. Catal. 2016, 358 (8), pp.1337-1344. DOI:10.1002/adsc.201600010 |
Kawabata, T. | |
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"Synthesis of (+)-trans-Dihydrolycoricidine by an Organocatalytic Enantioselective Friedel-Crafts Reaction" Kato, M.; Yasui, K.; Yamanaka, M.; *Nagasawa, K. Asian J. Org. Chem 2016, 5 (3), pp.380-388. DOI:10.1002/ajoc.201500469 |
Nagasawa, K. | |
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"Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Bronsted Acid Catalyst" *Momiyama, N.; Funayama, K.; Noda, H.; Yamanaka, M.; Akasaka, N.; Ishida, S.; Iwamoto, T.; *Terada, M. ACS. Catalysis 2016, 6 pp.949-956. DOI:10.1021/acscatal.5b02079 |
Terada, M. | |
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"Entropy-Driven 1,2-Type Friedel-Crafts Reaction of Phenols with N-tert-Butoxycarbonyl Aldimines" Kato, M.; Hirao, S.; Nakano, K.; Sato, M.; Yamanaka, M.; *Sohtome, Y.; *Nagasawa, K. Chem. Eur. J. 2015, 21 pp.18606-18612. DOI:10.1002/chem.201503280 |
Nagasawa, K. | |
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"Catalytic Asymmetric Iodocyclization of N-Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8-Oxa-6-Azabicyclo[3.2.1]octanes" *Arai, T.; Watanabe, O.; Yabe, S.; Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 pp.12767-12771. DOI:10.1002/anie.201505748 |
Arai, T. | |
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"Development of Guanidine-Bisurea Bifunctional Organocatalysts with a Chiral Pyrrolidine Moiety and Application to α-Hydroxylation of Tetralone-Derived β-Keto Esters" Odagi, M.; Takayama, K.; Sato, M.; Yamanaka, M.; *Nagasawa, K. Molecules 2015, 20 pp.12590-12598. DOI:10.3390/molecules200712590 |
Nagasawa, K. | |
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"PyBidine-Cu(OTf)2-catalyzed asymmetric [3+2] cycloaddition usingimino esters: Harmony of Cu-Lewis acid and imidazolidine-NHhydrogen-bonding in concerto catalysis" *Arai, T.; Ogawa, H.; Awata, A.; Sato, M.; Watabe, M.; *Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 (5), pp.1595-1599. DOI:10.1002/anie.201410782 |
Arai, T. | |
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"Origin of High E-Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α’-Alkenediol: A Computational and Experimental Study" *Yamanaka, M.; Yoshida, U.; Sato, M.; Shigeta, T.; Yoshida, K.; Furuta, T.; *Kawabata, T. J. Org. Chem. 2015, 80 (6), pp.3075-3082. DOI:10.1021/jo5029453 |
Kawabata, T. | |
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"Origin of stereocontorol in guanidine-bisurea bifunctional organocatalyst that promotes α-hydroxyaltion of tetralone-derived β-ketoesters: Asymmetric synthesis of β- or γ-substituted tetralone derivatives via organocatalytic oxidative kinetic resolution" Odagi, M.; Furukori, K.; Yamamoto, Y.; Sato, M.; Iida, K.; Yamanaka, M.;*Nagasawa, K. J. Am. Chem. Soc. 2015, 137 (5), pp.1909-1915. DOI:10.1021/ja511149y |
Nagasawa, K. | |
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"Secondary Stereocontrolling Interactions in Chiral Brønsted Acid Catalysis: Study of a Petasis-Ferrier-Type Rearrangement Catalyzed by Chiral Phosphoric Acids" Kanomata, K.; Toda, Y.; Shibata, Y.; Yamanaka, M.; Tsuzuki, S.; Gridnev, I. D.; *Terada, M. Chem. Sci. 2014, 5 (9), pp.3515-3523. DOI:10.1039/C4SC00611A |
Tsuzuki, S.; Terada, M. | |
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"DFT Studies of Mechanism and Origin of Stereoselectivity of Palladium-Catalyzed Cyclotrimerization Reactions Affording syn-Tris(norborneno)benzenes" *Yamanaka, M.; Morishima, M.; Shibata, Y.; Higashibayashi, S.; *Sakurai, H. Organometallics 2014, 33 (12), pp.3060-3068. DOI:10.1021/om500322b |
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"Chiral Phosphoric-Acid-Catalyzed Transfer Hydrogenation of Ethyl Ketimine Derivatives by Using Benzothiazoline" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. Chem. Eur. J. 2014, 20 (25), pp.7616-7620. DOI:10.1002/chem.201402763 |
Akiyama, T. | |
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"Trinuclear Zn3(OAc)4-3,3’-bis(aminoimino)binaphthoxide Complex for Highly Efficient Catalytic Asymmetric Iodolactonization" *Arai, T.; Sugiyama, N.; Masu, H.; Kado, S.; Yabe, S.; Yamanaka, M. Chem. Commun. 2014, 42 pp.8287-8290. DOI:10.1039/C4CC02415J |
Arai, T. | |
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"Prediction of suitable catalyst by 1H NMR:
asymmetric synthesis of multisubstituted biaryls by chiral phosphoric acid
catalyzed asymmetric bromination" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.;
Yamanaka, M.; *Akiyama, T. Chem. Sci. 2013, 4 pp.4235-4239. DOI:10.1039/c3sc52142g |
Akiyama, T. | |
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"Asymmetric Michael Addition of β-Ketoesters to Enones Catalyzed by the Lithium Salt of a Primary β-Amino Acid" *Yoshida, M.; Kubara, A.; Nagasawa, Y.; Hara, S.; *Yamanaka, M. Asian J. Org. Chem 2014, 3 (4), pp.523-529. DOI:10.1002/ajoc.201400024 |
Yoshida, M. | |
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"Mechanistic study of asymmetric Michael addition of malonates to enones catalyzed by a primary amino acid lithium salt " *Yoshida, M.; Nagasawa, Y.; Kubara, A.; Hara, S.; *Yamanaka, M. Tetrahedron 2013, 69 (47), pp.10003-10008. DOI:10.1016/j.tet.2013.09.066 |
Yoshida, M. | |
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"Double C(sp3)-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles" Mori, K.; Kurihara, K.; Yabe, S.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2014, 136 (10), pp.3744-3747. DOI:10.1021/ja412706d |
Akiyama, T. | |
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"Chiral Phosphoric Acid-Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines" Saito, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (32), pp.11740-11743. DOI:10.1021/ja406004q |
Akiyama, T. | |
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"Investigation of the Carboxylate Position during the Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal Carboxylate" Nishino, R.; Furuta, T.; Kan K.; Sato, M.; Yamanaka, M.; Sasamori, T.; Tokitoh, N.; *Kawabata, T. Angew. Chem. Int. Ed. 2013, 52 pp.6445-6449. DOI:10.1002/anie.201300665 |
Kawabata, T. | |
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"DFT Study of Mechanism and Origin of Enantioselectivity in Chiral BINOL-Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimine and α-Imino Ester Using Benzothiazoline" Shibata, Y.; *Yamanaka, M. J. Org. Chem. 2013, 78 pp.3731-3736. DOI:10.1021/jo4002195 |
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"Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 pp. 3964-3970. DOI:10.1021/ja311902f |
Akiyama, T. | |
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"Theoretical Study on the Regioselectivity of Baeyer-Villiger Reaction of α-Me-, -F-, -CF3-Cyclohexanones" Itoh, Y.; Yamanaka, M.; *Mikami, K. J. Org. Chem. 2013, 78 pp.146-153. DOI:10.1021/jo302151r |
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"Chiral Zn(II)-Bisamidine Complex as a Lewis-Brønsted Combined Acid Catalyst: Application to Asymmetric Mukaiyama Aldol Reactions of α-Ketoesters" Gotoh, R.; *Yamanaka, M. Molecules 2013, 17 pp. 9010-9022. DOI:10.3390/molecules17089010 |
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"Kinetic Resolution in Chiral Brønsted Acid Catalyzed Aldol Reaction: Enantioselective Robinson-type Annulation Reaction" *Yamanaka, M.; Hoshino, M.; Katoh, T.; Mori, K.; *Akiyama, T. Eur. J. Org. Chem. 2012, 24 pp.4508-4514. DOI:10.1002/ejoc.201200338 |
Akiyama, T. | |
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"DFT Study of Chiral Phosphoric Acid Catalyzed Enantioselective Friedel-Crafts Reaction of Indole with Nitroalkene: Bifunctionality and Substituent Effect of Phosphoric Acid" Hirata, T.; *Yamanaka, M. Chem. Asian J. 2011, 6 (2), pp.510-516. |
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| Reviews / Accounts |
"Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation" Zhu, C.; Saito, K.; Yamanaka, M.; *Akiyama, T. Acc. Chem. Res. 2015, 48 (2), pp.388-398. DOI:10.1021/ar500414x |
Akiyama, T. |
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"Theoretical Studies on
Mechanisms and Origins of Stereocontrol in Chiral Phosphoric Acid Catalyzed
Asymmetric Reactions" *Yamanaka, M.; Shibata, Y J. Synth. Org. Chem. Jpn 2014, 72 pp.580-595. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Transition-State Stabilization through Multiple Hydrogen Bonds and Dispersion Interactions in Organocatalysis" ○*Yamanaka, M. 39th NAITO Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Theoretical study on chiral bis-phosphoric acid catalyzed asymmetric Diels-Alder reaction" ○Noda, H.; *Yamanaka, M. Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "DFT study of chiral phosphoric acid catalyzed 1, 4-reduction of α,β-unsaturated ketones" ○Yamamoto, E.; *Yamanaka, M. PACIFICHEM2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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依頼講演 "Transition-state stabilization through multiple attractive non-covalent interactions in organocatalysis: A computational study" ○*Yamanaka, M. PACIFICHEM2015, Honolulu (USA) 2015-12-15～2016-05-20 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Trifluoromethylated N-H Ketimine Using Benzothiazoline" ○Noda, H.; Akiyama, T.; *Yamanaka, M. 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Akiyama | |
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口頭発表／ポスター発表 "Theoretical Study on the Mechanism of Stereoselectivity in Chiral Phosphorus Acid Catalyzed Asymmetric Hydrogenation of 1,5-Benzodiazepine Using Benzothiazoline" ○Yamamoto, E.; Horiguchi, K.; Saito, K.; Akiyama, T.; *Yamanaka, M 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Akiyama | |
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口頭発表／ポスター発表 "Theoretical Study of Asymmertic Desymmetrization of 4-Nosylamino-1,7-heptanediol via 4PPY-Catalyzed Enantioselective Acylation" ○Sato, M.; *Yamanaka, M.; Shigeta, T.; Huruta, T.; Kawabata, T. 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Kawabata | |
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口頭発表／ポスター発表 "Multifunctional Bisamidine
Ligand: Applications in Asymmetric Catalysis" ○*Yamanaka, M. 13th Tateshina Conference on Organic Chemistry, Tateshina (Japan) 2013-11-08～2013-11-10 |
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口頭発表／ポスター発表 "Theoretical
Study on Asymmetric Michael Addition of Malonate to Enone Catalyzed by Primary b-Amino Acid Lithium Salt" ○Nagasawa, Y.; *Yamanaka, M. 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "The
Origin of Enantioselectivity in Chiral Phosphoric Acid-Catalyzed Transfer
Hydrogenation of Imines" ○*Yamanaka, M. 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Theoretical Study on 4-Pyrrolidinopyridine Catalyzed Chemoselective Monoacylation of 1,5-pentanediol" ○Sato, M.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Theoretical Study on Asymmetric Synthesis of Tetrahydroquinoline Derivatives by Chiral Phosphoric Acid Catalyzed Intramolecular Redox Reaction" ○Nagasawa, Y.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Dinuclear Zn-Bisamidinate Catalyzed Asymmetric Hydrophosphonylation of α-Ketoesters" ○Kaizu, K.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 " Theoretical Study on 4-Pyrrolidinopyridine Catalyzed Chemoselective Monoacylation of Linear Diols " ○Sato, M.; *Yamanaka, M.First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Magnesium Phosphate-Catalyzed Phosphination of Imine" ○Shibata, Y.; *Yamanaka, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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招待講演 "Theoretical Studies on Chiral Phosphoric Acid-catalyzed Transfer Hydrogenation of Ketimine Using Benzothiazoline" ○*Yamanaka, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| A01 内丸 忠文 | ||
| Original papers |
"Photooxidation studies on indene-C-60 adducts " Yamane, S.; Mizukado, J.; Uchimaru, T.; Suzuki, Y.; Chen, L.; Suda, H. Solar Energy Materials and Solar Cells 2015, 143 pp.135-140. DOI:10.1016/j.solmat.2015.06.045 |
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"Kinetics of gas-phase reactions of cyc-CF2CF2CF2CHFCH2- and trans-cyc-CF2CF2CF2CHFCHF- with OH radicals between 253 and 328K" Zhang, N.; Chen, L.; Uchimaru, T.; Qing, F. Y.; Mizukado, J.; Quan, H. D.; Suda, H. Chem. Phys. Lett. 2015, 639 pp.199-204. DOI:10.1016/j.cplett.2015.09.020 |
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"Asymmetric Nitrocyclopropanation of alpha-Substituted alpha,beta-Enals Catalyzed by Diphenylprolinol Silyl Ether for the Construction of All-Carbon Quaternary Stereogenic Centers" Hayashi, Y.; Yamazaki, T.; Nakanishi, Y.; Ono, T.; Taniguchi, T,; Monde, K.; Uchimaru, T. Eur. J. Org. Chem. 2015, (26), pp.5747-5754. DOI:10.1002/ejoc.201500838 |
林雄二郎 | |
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"Two Reaction Mechanisms via Iminium Ion Intermediates: The Different Reactivities of Diphenylprolinol Silyl Ether and Trifluoromethyl-Substituted Diarylprolinol Silyl Ether" Gotoh, H.; Uchimaru, T.; Hayashi, Y. Chem. Eur. J. 2015, DOI:10.1002/chem.201500326 |
林雄二郎 | |
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"A Theoretical and Experimental Study of the Effects of Silyl Substituents in Enantioselective Reactions Catalyzed by Diphenylprolinol Silyl Ether" Hayashi, Y.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Gotoh, H.; Tsuzuki, S.; Uchimaru, T.; Seebach, D. Chem. Eur. J. 2014, 20 (51), pp.17077-17088. DOI:10.1002/chem.201403514 |
Hayashi, Y.; Tsuzuki, S. | |
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"ESR study of singlet oxygen generation and its behavior during the photo-oxidation of P3HT in solution " Chen, L.; Yamane, S.; Mizukado, J.; Suzuki, Y.; Kutsuna, S.; Uchimaru, T.; Suda, H. Chem. Phys. Lett. 2015, 624 pp.87-92. DOI:10.1016/j.cplett.2015.02.019 |
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"CCSD(T) Level Interaction Energy for Halogen Bond between Pyridine and Substituted Iodobenzenes: Origin and Additivity of Substituent Effects " Tsuzuki, S.; Uchimaru, T.; Wakisaka, A.; Ono, T.; Sonoda, T. Phys. Chem. Chem. Phys. 2013, (15-16), pp.6088-6096. DOI:10.1039/C3CP43693D |
都築誠二 | |
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"Equatorenes: Synthesis and Properties of Chiral Naphthalene, Phenanthrene,
Chrysene, and Pyrene Possessing Bis(1-adamantyl) Groups at the Peri-Position " Yamamoto, K.; Oyamada, N.; Sheng, X.; Kobayashi, Y.; Yamaguchi, M.; Maeda, H.; Nishihara, H,; Uchimaru, T.; Ensang, K. J. Am. Chem. Soc. 2013, 135 (44), pp.16526-16532. DOI:10.1021/ja407800e |
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"Organocatalytic 1,4-Addition Reaction of alpha,beta-gamma,delta-Diunsaturated Aldehydes versus 1,6-Addition Reaction" *Hayashi, Y.; Okamura, D.; Umrmiya, S.; *Uchimaru, T. ChemCatChem. 2012, 4 (7), pp.959-962. DOI:10.1002/cctc.201200161 |
林雄二郎 | |
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"Kinetics and mechanism of gas-phase reaction of CF3CF2CF2CF2CF2CF2CF2CF2H with OH radicals in an environmental reaction chamber at 253-328 K " *Chen, L.; Uchimaru, T.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A,; Okamoto, H. Chem. Phys. Lett. 2011, 501 (4-6), pp.263-266. DOI:10.1016/j.cplett.2010.12.009 |
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"Kinetics and mechanism of gas-phase reactions of n-C4F9OCH3, i-C4F9OCH3, n-C4F9OC(O)H, and i-C4F9OC(O)H with OH radicals in an environmental reaction chamber at 253-328 K " *Chen, L.; Uchimaru, T.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A. Chem. Phys. Lett. 2011, 514 (4-6), pp.207-213. DOI:10.1016/j.cplett.2011.08.049 |
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"Organocatalytic, Enantioselective Intramolecular [6 + 2] CycloadditionReaction for the Formation of Tricyclopentanoids and Insight on ItsMechanism from a Computational Study" *Hayashi, Y.; Gotoh, H.; Honma, M.; Sankar, K.; Kumar, I.; Ishikawa, H.; Konno, K.; Yui, H.; Tsuzuki, S.; *Uchimaru, T. J. Am. Chem. Soc. 2011, 133 (50), pp.20175-20185. DOI:10.1021/ja108516b |
林雄二郎 都築誠二 石川勇人 | |
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes" Tsuzuki, S; Uchimaru, T. 有機分子触媒による未来型分子変換第１回国際会議, 大津 (日本) 2013-05-27～2013-05-28 |
都築誠二 |
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口頭発表／ポスター発表 "Effects of the Silyl Substituent of Diphenylprolinol Silyl Ether in the OrganoCatalyst-Mediated Asymmetric Reactions: Computational and Experimental Investigations" Uchimaru, T.; Tsuzuki, S.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Goto, H.; Hayashi, Y. 5th JCS International Symposium on Theoretical Chemistry, 奈良 (日本) 2013-12-02～2013-12-06 |
林雄二郎 都築誠二 | |
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口頭発表／ポスター発表 "Effects of the Silyl Substituent of Diphenylprolinol Silyl Ether in the Organocatalyst-Mediated Asymmetric Reactions: Computational and Experimental Investigations" Uchimaru, T.; Tsuzuki, S.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Gotoh, H.; Hayashi, Y. 有機分子触媒による未来型分子変換第１回国際会議, 大津 (日本) 2013-05-27～2013-05-27 |
林雄二郎 都築誠二 | |
| A01 都築 誠二 | ||
| Original papers |
" Synthesis of Novel Ionic Liquids with Aromatic Trifluoroborate Anions "
K. Iwasaki, K. Yoshii, S. Tsuzuki, T. Tsuda, and S. *Kuwabata ECS Transactions 2014, 64 (4), pp.83-93. DOI:10.1149/06404.0083ecst |
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"
Lithium Redox in Imidazolium Ionic Liquids Composed
of Five-Membered Cyclic Amide "
*H. Matsumoto, S. Tsuzuki, K. Kubota ECS Transactions 2014, 64 (4), pp.223-230. DOI:10.1149/06201.0223ecst |
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"
Effects of Non-Equimolar Lithium Salt Glyme Solvate
Ionic Liquid on the Suppression of Interfacial Degradation for High-Voltage
Operation of Lithium- Secondary Batteries "
*S. Seki, N. Serizawa, K. Takei, Y. Umebayashi, Y.
Katayama, M. Takashi, K. Dokko, M. Watanabe, S. Tsuzuki RSC Advance 2016, 6 (39), pp.33043-33047. DOI:10.1039/c6ra04404b |
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Origin of attraction and directionality of hydrogen bond and halogen bond: Analysis by ab initio MO calculations "S. Tsuzuki AIP Conference Proceedings 2015, 1702 pp.090044. DOI:10.1063/1.4938852 |
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Li+ Local Structure in Hydrofluoroether Diluted Li-Glyme Solvate Ionic Liquid " S. Saito, H. Watanabe, K. Ueno, T. Mandai, S. Seki, S. Tsuzuki, Y. Kameda, K. Dokko, M. Watanabe, *Y. UmebayashiJ. Phys. Chem. B 2016, 120 (13), pp.3378-3387. DOI:10.1021/acs.jpcb.5b12354 |
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"
Construction of Chiral Polar Crystals from Achiral Molecules by Stacking Control of Hydrogen-bonded Layers Using Type II Halogen Bonds " *T. Sasaki, Y. Ida, I. Hisaki, S. Tsuzuki, N. Tohnai, G. Coquerel, H. Sato, *M. MiyataCrystal Growth & Design, in press. 2016, DOI:DOI: 10.1021/acs.cgd.5b01724 |
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Thermal and Electrochemical Stability of Tetraglyme-Magnesium Bis(trifluoromethanesulfonyl)amide Complex: Electric Field Effect of Divalent Cation on Solvate Stability " S. Terada, T.o Mandai, S. Suzuki, S. Tsuzuki, K. Watanabe, Y. Kamei, K. Ueno, *K. Dokko, M. WatanabeThe Journal of Physical Chemistry C 2016, 120 (3), pp.1353-1365. DOI:DOI: 10.1021/acs.jpcc.5b09779 |
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Synthesis, ion recognition ability, and metal-assisted aggregation behavior of dinuclear metallohosts having a bis(saloph) macrocylic ligand " *Shigehisa Akine, Fumihiko Utsuno, Shunjin Piao, Hideo Orita, Seiji Tsuzuki, *Tatsuya NabeshimaInorganic Chemitry 2016, 55 (2), pp.810-821. DOI:DOI: 10.1021/acs.inorgchem.5b02288 |
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"
Design, synthesis and optical properties of unsymmetrical subphthalocyanine trimer connected by phloroglucinol via axial positions " S. Mori, N. Ogawa, E. Tokunaga, S. Tsuzuki and *N. ShibataDalton Trans 2016, 45 (3), pp.908-912. DOI:DOI: 10.1039/C5DT04500B. |
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Photo-Fries rearrangement of phenyl salicylate studied by Two-dimensional Infrared spectroscopy " *Hideyuki Shinzawa, Yuki Matsumoto, Seiji Tsuzuki, Yukihiro Shimoi, Hiroyuki SudaVibrational Spectroscopy 2015, 81 pp.131-135. |
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Reinforcement of guest selectivity through the self-assembly of host molecules: selective recognition of lithium ions by dimerizable tricarboxylic acids " Shoichi Minodani, Masaki Owaki, Shuhei Sano, Seiji Tsuzuki and *Masamichi YamanakaChem. Commun. 2015, 51 (65), pp.12920-12923. DOI:DOI: 10.1039/c5cc05227k |
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"
Ester-Linked Alkyl Chain Effect on 2D Structures of Isobutenyl Compounds: Scanning Tunneling Microscopic Study " *Y. Kikkawa, M. Ishitsuka, K. Omori, A. Kashiwada, S. Tsuzuki, K. HirataniBull. Chem. Soc. Jpn 2015, 88 (6), pp.834-842. DOI:DOI: 10.1246/bcsj.20150018 |
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"
Simulation of metal-organic framework self-assembly "*M. Yoneya, S. Tsuzuki, M. Aoyagi Phys. Chem. Chem. Phys. 2015, 17 (14), pp.8649-8652. DOI:DOI: 10.1039/C5CP00379B |
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"
Li Solvation in Glyme-Li Salt Solvate Ionic Liquids "K. Ueno, R. Tatara, S. Tsuzuki, S. Saito, H. Doi, K. Yoshida, T. Mandai, M. Matsugami, Y. Umebayashi, K. Dokko, *M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (14), pp.8248-8257. DOI:DOI: 10.1039/C4CP05943C |
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"
Effect of Ionic Size on Solvate Stability of
Glyme-Based Solvate Ionic Liquids "
T. Mandai, K. Yoshida, S. Tsuzuki, R. Nozawa, H. Masu, K. Ueno, Dokko, *M. Watanabe J. Phys. Chem. B 2015, 119 (4), pp.1523-1534. DOI:DOI: 10.1021/jp508100s J |
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"
Pentaglyme-K Salts Binary Mixtures: Phase Behavior, Solvate Structures, and Physicochemical Properties "*T. Mandai, S. Tsuzuki, K. Ueno, K. Dokko, M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (4), pp.2838-2849. |
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"
ハロゲン結合の引力の原因と方向性 "*都築誠二、内丸忠文 J. Comput. Chem. Jpn 2014, 13 (6), pp.328-329. DOI:DOI: 10.2477/jccj/2014-0062 |
内丸忠文 | |
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"
Upper Limit of Nitrogen Content in Carbon Materials "S. Zhang, S. Tsuzuki, K. Ueno, K. Dokko and *M. Watanabe Angew. Chem. Int. Ed. 2015, 54 (4), pp.1302-1306. DOI:DOI: 10.1002/ange.201410234 |
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"
Structures of [Li(glyme)]+ complexes and their interactions with anions in equimolar mixtures of glymes and Li[TFSA]: analysis by molecular dynamics simulations "*S. Tsuzuki, W. Shinoda, M. Matsugami, Y. Umebayashi, K. Ueno, T. Mandai, S. Seki, K. Dokko and M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (1), pp.126-129. DOI:DOI: 10.1039/C4CP04718D |
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"
Bicomponent blend-directed amplification of the alkyl chain effect on the 2D structures "*Y. Kikkawa, M. Ishitsuka, A. Kashiwada, S. Tsuzuki and K. Hiratani Chem. Commun. 2014, (50), pp.13146-13149. DOI:DOI: 10.1039/C4CC04624B |
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"
Static, Transport, and Diffusive Properties of Alkyl-trimethylammonium Cation-based Room-temperature Ionic Liquids " *S. Seki, S. Tsuzuki, K. Hayamizu, N. Serizawa, S. Ono, K. Takei, H. Doi, Y. UmebayashiJ. Phys. Chem. B 2015, 118 (17), pp.4590-4599. DOI:DOI: 10.1021/jp500123q |
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"
Transport and Electrochemical Properties of Three Quaternary Ammonium Ionic Liquids and Lithium Salts Doping Effects Studied by NMR Spectroscopy "*K. Hayamizu, S. Tsuzuki, S. Seki J. Chem. Eng. Data 2014, 59 (6), pp.1944-1954. DOI:DOI: 10.1021/je500065k |
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"
Studies on the C/O-regioselectivity in Electrophilic Fluoromethylations of β-Ketoesters based on Thermodynamics by Ab initio Calculations "Y.-D. Yang, X. Wang, S. Tsuzuki, E. Tokunaga, *N. Shibata Bull. Korean Chem. Soc. 2014, 35 (6), pp.1851-1854. DOI:DOI: 10.5012/bkcs.2014.35.6.1851 |
N. Shibata | |
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Physicochemical properties of pentaglyme-sodium bis(trifluoromethanesulfonyl)amide solvate ionic liquid "S. Terada, T. Mandai, R. Nozawa, K. Yoshida, K. Ueno, S. Tsuzuki, K. Dokko, *M. Watanabe Phys. Chem. Chem. Phys. 2014, 16 (23), pp.11737-11746. DOI:DOI: 10.1039/c4cp00746h |
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"Cation and anion dependence of stable geometries and stabilization energies of alkali metal cation complexes with FSA-, FTA- and TFSA- anions: Relationship with physicochemical properties of molten salts"
*S. Tsuzuki, K. Kubota, H. Matsumoto J. Phys. Chem. B 2013, 117 (50), pp.16212-16218. DOI:DOI: 10.1021/jp409113z |
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"
Coordination-Directed Self-Assembly of M12L24 Nanocage: Effects of Kinetic Trapping on the Assembly Process "*M. Yoneya, S. Tsuzuki, T. Yamaguchi, S. Sato, M. Fujita ACS NANO 2014, 8 (2), pp.1290-1296. DOI:DOI: 10.1021/nn404595j |
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"
Interactions in ion pairs of protic ionic liquids: Comparison with aprotic ionic liquids "*S. Tsuzuki, W. Shinoda, M. S. Miran, H. Kinoshita, T. Yasuda, M. Watanabe J. Phys. Chem. B 2013, 117 (50), pp.16212-16218. DOI:DOI: 10.1021/jp409113z |
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"
Phase Diagrams and Solvate Structures of Binary Mixtures of Glymes and Na Salts " T. Mandai, R. Nozawa, S. Tsuzuki, K. Yoshida, K. Ueno, K. Dokko, *M. WatanabeJ. Phys. Chem. C, 2013, 117 (48), pp.15072-15085. DOI:DOI: 10.1021/jp407582m |
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"
Comparative Study on Physicochemical Properties of Protic Ionic Liquids Based on Allylammonium and Propylammonium Cations " T. Yasuda, H. Kinoshita, M. S. Miran, S. Tsuzuki, *M. WatanabeJ. Chem. Eng. Data 2013, 58 (10), pp.2724-2732. DOI:DOI: 10.1021/je301284x |
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"
Unusual Li+ Ion Solvation Structure in Bis(fluorosulfonyl)amide Based Ionic Liquid " K. Fujii, H. Hamano, H. Doi, X. Song, *S. Tsuzuki, K. Hayamizu, S. Seki, Y. Kameda, K. Dokko, M. Watanabe, *Y. Umebayashi J. Phys. Chem. C, 2013, 117 (38), pp.19314-19324. DOI:DOI: 10.1021/jp4053264 |
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" Origin of Attraction in Chalgogen-Nitrogen Interaction of 1,2,5-Chalcogenadiazole Dimers "*Tsuzuki, S.; N. Sato, N. J. Chem. Phys. B 2013, 117 pp.6849-6855. DOI:10.1021/jp403200j |
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" Intermolecular Interactions in Li+-glymes and Li+-glymes-TFSA- complexes: Relationship with Physicochemical Properties of [Li(glymes)][TFSA] Ionic Liquids "*Tsuzuki, S.; Shinoda, W.;. Seki, S.; Umebayashi, Y.; Yoshida, K.; Dokko, K.; Watanabe, M. ChemPhysChem 2013, 14 pp.1993-2001. DOI:10.1002/cphc.201200843 |
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" Linkage Control between Molecular and Supramolecular Chirality in 21-Helical Hydrogen-bonding Networks by Using Achiral Components "Sasaki, T.; Hisaki, I.; Miyano, T.; Tohnai, N.; Morimoto, K.; Sato, H.; Tsuzuki, S.; *Miyata, M. Nature Commun. 2013, (4), pp.1787. DOI:10.1038/ncomms2756 |
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" CCSD(T) Level Interaction Energy for Halogen Bond between Pyridine and Substituted Iodobenzenes: Origin and Additivity of Substituent Effects "*Tsuzuki, S.; Uchimaru, T.; Wakisaka, A.; Ono, T.; Sonoda, T. Phys. Chem. Chem. Phys. 2013, 15 (16), pp.6088-6096. DOI:10.1039/C3CP43693D |
Uchimaru, T. | |
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" Encapsulation-Induced Remarkable Stability of Hydrogen-Bonded Heterocapsule "Ichihara, K.; Kawai, H.; Togari, Y.; Kikuta, E.; Kitagawa, H.; *Tsuzuki, S.; Yoza, K.; Yamanaka, M.; *Kobayashi, K. Chem. Eur. J. 2013, 19 (11), pp.3685-3692. |
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" Crystal Structure of Quinine: The Effects of Vinyl and Methoxy Groups on Molecular Assemblies of Cinchona Alkaloids Cannot Be Ignored "*Hisaki, I.; Hiraishi, E.; Sasaki, T.; Orita, H.; Tsuzuki, S.; Tohnai, N.; Miyata, M. Chem. Asian J. 2013, 7 (11), pp.2607-2614. |
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" Multinuclear NMR Studies on Translational and Rotational Motion for Two Ionic Liquids Composed of BF4 Anion "*Hayamizu, K.; Tsuzuki, S.; Seki, S.; Umebayashi, Y. J. Chem. Phys. B 2012, 116 (36), pp.11284-11291. |
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" Halogen bond effect on bundling of hydrogen bonded 2-fold helical columns "Sasaki, T.; *Hisaki, I.; Tsuzuki, S.; Tohnai, N.; *Miyata, M. CrystEngComm 2013, 14 (18), pp.5749-5752. |
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" Physicochemical and Electrochemical Properties of 1-Ethyl-3-Methylimidazolium Tris(pentafluoroethyl)trifluorophosphate and 1-Ethyl-3-Methylimidazolium Tetracyanoborate "*Seki, S.; Serizawa, N.; Hayamizu, K.; Tsuzuki, S.; Umebayashi, Y.; Takei, K.; Miyashiro, H. J. Electrochem. Soc. 2012, 159 (7), pp.A967-A971. |
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" Comprehensive Refractive Index Property for Room-Temperature Ionic Liquids "*Seki, S.; *Tsuzuki, S.; Hayamizu, K.; Umebayashi, Y., Serizawa, N.; Takei, K.; Miyashiro, H. J. Chem. Eng. Data 2012, 57 (8), pp.2211-2216. |
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" Comparative Study of Imidazolium- and Pyrrolidinium- Based Ionic Liquids: Thermodynamic Properties "*Shimizu, Y.; Ohte, Y.; Yamamura, Y.; Tsuzuki, S.; Saito, K. J. Phys. Chem. B 2012, 116 (18), pp.5406-5413. |
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" Interactions between dehydrobenzo[12]annulene (DBA) and gas molecules: do the preorganized acetylenes work cooperatively? "*Hisaki, I.; Yasumiya, D.; Shigemitsu, H.; *Tsuzuki, S.; Tohnai, N.; *Miyata, M. Phys. Chem. Chem. Phys. 2012, 14 (40), pp.13918-13921. |
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" Preference of the monodentate contact in the CH/π interaction between an alkyl group and a single phenyl ring: Stable structure of the benzene-ethane cluster " *Fujii, A.; Hayashi, H,; *Tsuzuki, S.Chem. Phys. Lett. 2012, 537 (1), pp.11-15. |
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" Magnitude of CH/O Interactions between Carbohydrate and Water "*Tsuzuki, S.; Uchimaru, T.; Mikami, M. Theor. Chem. Acc. 2012, 131 (3), pp.1192. |
Uchimaru, T. | |
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" Magnitude and Origin of Attraction and Directionality of Halogen Bonds of C6F5X and C6H5X (X = I, Br, Cl and F) with Pyridine "*Tsuzuki, S.; Wakisaka, A.; Ono, T.; Sonoda, T. Chem. Eur. J. 2012, 18 (3), pp.951-960. |
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" Organocatalytic, Enantioselective Intramolecular [6+2] Cycloaddition Reaction for the Formation of Tricyclopentanoids and Insight on Its Mechanism from a Computational Study "*Hayashi, Y.; Gotoh, H.; Honma, M.; Sankar, K.; Kumar, I.; Ishikawa, H.; Konno, K.; Yui, H.; Tsuzuki, S.; *Uchimaru, T. J. Am. Chem. Soc. 2011, 133 (50), pp.20175-20185. |
Hayashi, Y.; Uchimaru, T. | |
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" Liquid structure of and Li+ ion solvation in bis(trifluoromethanesulfonyl)amide based ionic liquids composed of 1-ethyl-3-methylimidazolium and N-methyl-N-propylpyrrodilinium cations "*Umebayashi, Y.; Hamano, H.; Seki, S.; Fujii, K.; Hayamizu, K.; Tsuzuki, S.; kameda, Y.; Kohara, S.; Watanabe, M. J. Phys. Chem. B 2011, 115 (42), pp.12179-12191. |
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" Magnitude and Nature of Carbohydrate-Aromatic Interactions in Fucose-Phenol and Fucose-Indole Complexes: CCSD(T) level interaction energy calculations "*Tsuzuki, S.; Uchimaru, T.: Mikami, M J. Phys. Chem. A 2011, 115 (41), pp.11256-11256. |
Uchimaru, T. | |
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" Nuclear magnetic resonance studies on the rotational and translational motions of ionic liquids composed of 1-ethyl-3-methylimidazolium cation and bis(trifluoromethanesulfonyl)amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts "*Hayamizu, K.; Tsuzuki, S..; Seki, S.; Umebayashi Y. J. Chem. Phys. 2011, 135 (8), pp.084505. |
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" Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme-Lithium Salt Equimolar Complexes "Yoshida, K.; Nakamura, M.; Kazue, Y.; Tachikawa, N.; Tsuzuki, S.; Seki, S.; Dokko, K.; *Watanabe, M. J. Am. Chem. Soc. 2011, 133 (33), pp.13121-13129. |
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" Physicochemical Properties and Application of Ionic Liquids with N-P Bonds as Lithium Secondary Battery Electrolytes "*Serizawa, N.; Seki, S.; Tsuzuki, S.; Hayamizu, K.; Umebayashi, Y.; Takei, K.; Miyashiro, H. J. Electrochem. Soc. 2011, 158 (9), pp.A1023-A1030. |
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" Experimental and theoretical determination of the accurate CH/pi interaction energies in benzene-alkane clusters: correlation between interaction energy and polarizability "*Fujii, A.; Hayashi, H.; Park, J. W.; kazama, T.; Mikami, N.; *Tsuzuki, S. PHys. Chem. Chem. Phys. 2011, 13 (31), pp.14131-14141. |
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" Effects of conformational flexibility of alkyl chain of cations on diffusion of ions in ionic liquids "*Tsuzuki, S. Matsumoto, H.; Shinoda, W.; Mikami, M. Phys. Chem. Chem. Phys. 2011, 13 (13), pp.5987-5993. |
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" Temperature-dependent (11)B spin-lattice relaxation time for BF(4) and CF(3)BF(3) anions in room-temperature ionic liquids "*Hayamizu, K.; Tsuzuki, S.; Seki, S. Magnetic Resonance in Chemistry 2011, 49 (1), pp.6-8. |
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| Books |
「
Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015 」 R. Tamura, M. Miyata"Analysis of intermolecular interactions by ab initio molecular orbital calculations: Importance for studying organic crystals" S. Tsuzuki et al. Springer 2016, pp187-200. |
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「
有機分子の分子間力： Ab initio 分子軌道法による分子間相互作用エネルギーの解析 」都築誠二 東京大学出版会 (東京) 2015, ISBN:978-4-13-062510-4 |
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| Reviews / Accounts |
"
イオン間相互作用がイオン液体の液体構造や輸送物性に与える影響：Ab initio 分子軌道法、分子動力学を用いた解析 " 都築誠二日本結晶学会誌、in press. 2016, |
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"
分子軌道法を使った分子間力の解析 " 都築誠二化学と教育 2015, 63 (8), pp.376-379. |
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"
Origin of attraction and directionality of hydrogen bond and halogen bond: Analysis by ab initio MO calculations " S. TsuzukiAIP Conference Proceedings 2015, 1702 pp.090044. DOI:doi: 10.1063/1.4938852 |
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"
グライム系リチウム溶媒和イオン液体の化学と応用 "都築誠二、渡邉正義 Electrochemistry 2014, 82 (12), pp.1079-1084. |
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"
計算化学によるイオン液体電解質の研究 "Tsuzuki, S. Electrochemistry 2013, 81 (12), pp.1001-1005. DOI:JOI:DN/JST.JSTAGE/electrochemistry/81.1001 |
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" ハロゲン結合の性質と作用機構 "*Tsuzuki, S. Fluorine 2013, 5 (1-2), pp.11-18. |
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"
Factors controlling the diffusion of ions in ionic liquids "*Tsuzuki, S. ChemPhysChem 2012, 13 (7), pp.1664-1670. |
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"
Analysis of weak intermolecular interactions by ab initio molecular orbital calculations " Tsuzuki, S.Journal of Synthetic Organic Chemistry Japan 2012, 70 (8), pp.831-841. DOI:10.5059/yukigoseikyokaishi.70.831 |
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"CH/π interactions" Tsuzuki, S. Annu. Rep. Prog. Chem., Sect. C: Phys. Chem., 2012, 108 pp.69-95. DOI:DOI: 10.1039/C2PC90003C |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "
Battery performances of lithium solvated ionic liquid
as electrolyte materials "
○関志朗、芹沢信幸、竹井勝仁、都築誠二、梅林
泰宏、獨古薫、渡邉正義 Joint EMLG/JMLG Annual Meeting 2015 in Rostock Molecular Liquids Meet Ionic Liquids From Fundamentals to Applications, Rostock (ドイツ) 2016-03-10～2016-03-10 |
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口頭発表／ポスター発表 "
Why Stable Glyme-Li Complex Exists in Solvate Ionic Liquid? " ○Seiji Tsuzuki, Wataru Shinoda, Kazuhide Ueno, Toshihiko Mandai, Shiro Seki, Soushi Saito, Hiroyuki Doi, Yasuhiro Umebayashi, Kaoru, Dokko, Masayoshi Watanabe34th international conference on solution chemistry, プラハ (チェコ) 2015-08-31～2016-09-03 |
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招待講演 "
Relationship between interionic interaction and transport properties of ionic liquids: Analysis by ab initio MO calculations and MD simulations " Seiji Tsuzuki7th International Symposium on “Molecular Thermodynamics and Molecular Simulation (MTMS15), 福岡 (日本) 2016-08-04～2016-08-06 |
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口頭発表／ポスター発表 "
Analysis of chalcogen-chalcogen and halogen-halogen interactions in crystals by ab initio molecular orbital calculations " ○Seiji Tsuzuki、Yoshiki Higuchi, Naoki Satothe 22nd International Conference on the Chemistry of the Organic Solid State (ICCOSS XXII), 新潟 (日本) 2015-07-06～2015-07-10 |
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口頭発表／ポスター発表 "
Origin of directionality of hydrogen bond and halogen bond: Effects of anisotropic charge distributions on atoms " Seiji TsuzukiICQC 2015 Satellite Symposium in Kobe, 神戸 (日本) 2015-06-09～2015-06-12 |
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招待講演 "
Origin of attraction and
directionality of hydrogen bond and halogen bond: Analysis by ab initio MO
calculations "
S. Tsuzuki Computational Chemistry Symposium in 11TH INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING (ICCMSE 2015), アテネ (ギリシア) 2015-03-20～2015-03-24 |
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口頭発表／ポスター発表 "
Chromatographic Behavior in Reversed-Phase Liquid Chromatography Using Water as the Mobile Phase Solvent "○島崎裕紀、都築誠二、望月祐志、宮部寛志 PITTCON Confelence & Expo 2015, New Orleans (アメリカ) 2015-03-06～2015-03-09 |
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口頭発表／ポスター発表 "
Stability of Glyme-Li Complex in Solvate Ionic Liquid "○都築誠二、篠田渉、上野和英、万代俊彦、関志朗、齊藤蒼思、土井寛之、梅林泰宏、獨古薫、渡邉正義 4th Asia-Pacific Conference on Ionic Liquids and Green Processes & the 6th Australasian Symposium on Ionic Liquids (APCIL-4/ASIL-6 2014), シドニー (オーストラリア) 2014-09-27～2014-09-30 |
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口頭発表／ポスター発表 "
Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes "○都築 誠二、内丸 忠文 Computational Science Workshop 2014, Tsukuba (Japan) 2014-08-19～2014-08-21 |
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口頭発表／ポスター発表 "
Static and Transport Properties of Ionic Liquids and Their Binary Mixtures "
○関志朗、芹沢信幸、竹井勝仁、早水紀久子、都築誠二、梅林 泰宏 EUCHEM2014, Molten Salts and Ionic Liquids XXV, Tallinn (エストニア) 2014-07-05～2014-07-09 |
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招待講演 "
Origin of attraction and directionality of intermolecular interactions between organic molecules "Seiji Tsuzuki Joint Congress of Asian Crystallization Technology Symposium-2014 and 11th International Workshop of Crystal Growth of Organic Materials, Nara (Japan) 2014-06-18～2014-06-20 |
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口頭発表／ポスター発表 "
Molecular simulation of boron isotope effect influenced by pressure enhancing dehydration of boron hydrates "○Ichikawa, H.; Musashi, M.; Mikami, M.; Tsuzuki, S.; Ooi, T. The 4th International Symposium on Innovative nuclear energy systems, Tokyo (Japan) 2013-11-06～2013-11-08 |
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"
Computational and Experimental Approach for Halogen Bonds of Pyridine with Organic Compounds in Gas-phase and Solution "Tsuzuki, S.; Wakisaka, A.; Ono, T.; ○Sonoda, T. Prague (Czech Republic) 2013-09-01～2013-09-06 |
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口頭発表／ポスター発表 "
Physicochemical Properties of Imidazolium-Based Ionic Liquid-Glyme Mixtures "○Takuya Shimomura, Daisuke Kodama, Takashi Makino, Mitsuhiro Kanakubo, Seiji Tsuzuki International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan, Sendai (Japan) 2013-09-28～2013-09-30 |
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"
Li+ ion speciation in Li-glymes ionic liquids toward rechargeable batteries "○Saito, S.; Doi, H.; Mandai, H.; Tsuzuki, S.; Shinoda, W.; Seki, S.; Dokko, K.; Watanabe, M.; Umebayashi, H. 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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"
Liquid and Li+ Local Structures in Li-glymes Complex Ionic Liquids Revealed by Raman and X-ray Scattering Techniques with the Aid of Theoretical Calculations "○Saito, S.; Doi, H.; Tsuzuki, S.; Shinoda, W.; Dokko, K.; Watanabe, M.; Umebayashi, H. 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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招待講演 "
First principle approach for studying intermolecular interactions "Tsuzuki, S. 6th APCTCC (Asian-Pacific Conference of Theoretical and Computational Chemistry), Gyeongju (Korea) 2013-07-10～2013-07-13 |
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"
Mixiing state of imidazolium-based ionic liquid-diglyme solutions studied by NMR and MD simulations "○T. Shimomura, D. Kodama, M. Kannakubo, S. Tsuzuki 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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"
Origin of attraction and directionality of
nonbonding interactions of halogen atoms
" Tsuzuki, S. 7th Molecular Quantum Mechanics, Lugano (Switzerland) 2013-06-02～2013-06-07 |
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口頭発表／ポスター発表 " Tetrabutylammonium Salts as Templates for Stereoselective Norrish Type II Reactions of 2-Benzyloxyacylbenzenes "○Yamada, S.; Iwaokoa, A.; Tsuzuki, S. 1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Yamada, S. | |
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口頭発表／ポスター発表 " Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes "○Tsuzuki, S.; Uchimaru, T. 1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Uchimaru, T. | |
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口頭発表／ポスター発表 " Intermolecular interactions and liquid properties of protic ionic liquids: Comparison with aprotic ionic liquds "○Tsuzuki, S.; Shinoda, W.; Miran, M. S.; Kinoshita, H.; Yasuda, T.; Dokko, K.; Watanabe, M. 5tn International congress on ionic liquids (COIL-5), Algarve (Portugal) 2013-04-21～2013-04-25 |
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招待講演 " Factors controlling the diffusion of ions in ionic liquids " Tsuzuki, S.243rd ACS National Meeting, San Diego (United State) 2012-03-25～2012-03-29 |
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口頭発表／ポスター発表 " Importance of Low Coordinating Anion for Developing Lithium Secondary Batteries Using Ionic Liquids "○Matsumoto, H.; Terasawa, N.; Sakaebe, H.; Tsuzuki, S.; Hubert, V.; Kohyama, M.; Tatsumi, K. The first Electrochemical Energy Summit, Boston (United State) 2011-10-09～2011-10-14 |
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口頭発表／ポスター発表 " Effects of Conformational Flexibility on Diffusion of Ions in Ionic Liquids "○ Tsuzuki, S.; Matsumoto, H.; Shinoda, W.; Mikami, M. the 62nd Annual Meeting of theInternational Society of Electrochemistry, Nigata (Japan) 2011-09-11～2013-09-15 |
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口頭発表／ポスター発表 " NMR Relaxation Studies on 1-Alkyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide "○Kanakubo, M.; Harris, K. R.; Tsuzuki, S.; Umecky, T.; Makino, T.; Suzuki, A. 32nd International Conference on Solution Chemistry (ICSC2011), La Grande Motte (France) 2011-08-28～2013-09-02 |
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| Media |
" アキラル成分を用いた2回らせん水素結合ネットワークにおける分子キラリティーと超分子キラリティーの間のつながり制御 "Sasaki, T.; Hisaki, I.; Miyano, T.; Tonai, K.; Morimoto, K.; Sato, H.; Tsuzuki, S.; Miyata, M. Nature communications ホームページ、注目の論文 2013-05-27PDF キラル分子は、分子の絶対配置を反映して片方のキラリティーの超分子集合体を優先的に形成する。しかし、特定の条件下では、結合長の柔軟性と非共有結合相互作用の可逆性のために、キラリティーが逆の超分子集合体も得られる。このキラリティーの選択性やスイッチング現象の機構はまだよくわかっておらず、ほとんどの現象は偶然観察される。今回我々は、結晶学的研究に基づいて結晶状態でのキラリティーを制御した、キラルな水素結合2回らせん集合体の構造構築を実証する。得られた結晶構造を詳細に調べることで、キラリティーのスイッチング機構を明らかにし、これに基づきアキラルな要素を導入して超分子集合体のキラリティーの制御に成功した。この研究によって、結晶状態における分子キラリティーと超分子キラリティーのつながりが明確になった。 |
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" ２回らせんの右巻き・左巻きの選択機構を解明 左右変換可能なキラル材料の開発へ "Sasaki, T.; Hisaki, I.; Miyano, T.; Tonai, K.; Morimoto, K.; Sato, H.; Tsuzuki, S.; Miyata, M. 大阪大学ホームページ、最新研究成果リリース 2013-05-15PDF 大阪大学産業科学研究所の宮田幹二招へい教授、同大学院工学研究科の藤内謙光准教授・久木一朗助教・佐々木俊之氏(博士後期課程3年)、愛媛大学理学研究科の佐藤久子教授、産業技術総合研究所の都築誠二上級主任研究員らの研究グループは共同で、キラルなアミンとアキラルなカルボン酸から成る数多くの有機塩結晶の単結晶X線構造解析を通して、結晶中の水素結合2回らせんの右巻きと左巻きの選択機構を解明し、その制御に成功しました。このようならせんの左右の制御は医薬品の開発だけでなく、円偏光を利用した3Dディスプレイなどの光学デバイスへの応用が期待されます。 本研究成果は2013年4月30日(ロンドン時間)に英国Nature Publishing GroupのNature Communicationsのオンライン速報版で公開されました。 |
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| A01 小笠原 正道 | ||
| Original papers |
"Concise Asymmetric Construction of C2-Symmetric 1,9-Diarylnonanoids Using Hypervalent Silicon Complex: Total Synthesis of (–)-Ericanone" *Kotani, S.; Kai, K.; Shimoda, Y.; Hu, H.; Gao, S.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Chem. Asian J. 2016, 11 pp.376-379. DOI:10.1002/asia.201501080 |
中島誠教授（熊本大学） |
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"Kinetic Resolution of Planar-Chiral Ferrocenylphosphine Derivatives by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis and Their Application in Asymmetric Catalysis" *Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. ACS Catal. 2016, 6 pp.1308-1315. DOI:10.1021/acscatal.5b02692 |
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"Ring-Closing Metathesis of (η5-Alkenylcyclopentadienyl)(alkenylphosphine)manganese(I) Dicarbonyl Complexes" Tseng, Y.-Y.; *Kamikawa, K.; Wu, Q.; Takahashi, T.; *Ogasawara, M. Adv. Synth. Catal. 2015, 357 pp.2255-2264. DOI:10.1002/adsc.201500343 |
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"Enantioselective Synthesis of Macrocyclic Heterobiaryl Derivatives of Molecular Asymmetry by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" Okayama, Y.; Tsuji, S.; Toyomori, Y.; *Mori, A.; Arae, S.; Wu, W.-Y.; Takahashi, T.; *Ogasawara, M. Angew. Chem. Int. Ed. 2015, 54 pp.4927-4931. DOI:10.1002/anie.201500459 |
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"Simultaneous Induction of Axial and Planar Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis" *Kamikawa, K.; Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. Chem. Eur. J. 2015, 21 pp.4954-4957. DOI:10.1002/chem.201500226 |
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"Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library" *Ogasawara, M.; Wada, S.; Isshiki, E.; Kamimura, T.; *Yanagisawa, A.; *Takahashi, T.; *Yoshida, K. Org. Lett. 2015, 17 pp.2286-2289. DOI:10.1021/acs.orglett.5b01044 |
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"Enantioselective Desymmetrization of 1,2,3-Trisubstituted Metallocenes by Molybdenum-Catalyzed Asymmetric Intraannular Ring-Closing Metathesis" Arae, S.; Nakajima, K.; *Takahashi, T.; *Ogasawara, M. Organometallics 2015, 34 pp.1197-1202. DOI:10.1021/om5011484 |
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"Catalytic Asymmetric Synthesis of Planar-Chiral Transition-Metal Complexes" Arae, S.; *Ogasawara, M. Tetrahedron Lett. 2015, 56 pp.1751-1761. DOI:10.1016/j.tetlet.2015.01.130 |
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"Phosphine-Olefin Ligands Based on a Planar-Chiral (π-Arene)chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis" *Ogasawara, M.; Tseng, Y.-Y.; Arae, S.; Morita, T.; Nakaya, T.; Wu, W.-Y.; *Takahashi, T.; *Kamikawa, K. J. Am. Chem. Soc. 2014, 136 pp.9377-9384. DOI:10.1021/ja503060e |
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"Phosphine Oxide-Catalyzed Enantioselective Intramolecular Aldol Reaction via Regioselective Enolization of Unsymmetrical Diketones with Tetrachlorosilane" *Kotani, S.; Aoki, S.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Org. Lett. 2014, 16 pp.4802-4805. DOI:10.1021/ol502269w |
中島誠教授（熊本大学） | |
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"Hybrid Sponge Comprised of Galactosylated Chitosan and Hyaluronic Acid Mediates the Co-culture of Hepatocytes and Endothelial Cells" Shang, Y.; Tamai, M.; Ishii R.; Nagaoka, N.; Yoshida, Y.; Ogasawara, M.; Yang, J.; *Tagawa, Y. J. Biosci. Bioeng. 2014, 117 pp.99-106. DOI:10.1016/j.jbiosc.2013.06.015 |
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"Helically Chiral Diene in Asymmetric Catalysis: C2-Symmetric (Z,Z)-2,3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as Highly Active Lewis-Base Organocatalyst" *Ogasawara, M.; Kotani, S.; Nakajima, H.; Furusho, H.; Miyasaka, M.; Shimoda, Y.; Wu, W.-Y.; Sugiura, M.; *Takahashi, T.; *Nakajima, M. Angew. Chem. Int. Ed. 2013, 52 pp.13798-13802. DOI:10.1002/anie.201308112 |
中島誠教授（熊本大学） | |
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"Asymmetric Aldol Reaction on Water using an Organocatalyst Tethered on a Thermoresponsive Block Copolymer" *Suzuki, N.; Inoue, T.; Asada, T.; Akebi, R. Kobayashi, G.; Rikukawa, M.; Masuyama, Y.; Ogasawara, M.; Takahashi, T.; Thang, S. Chem. Lett. 2013, 42 pp.1493-1495. DOI:10.1246/cl.130711 |
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"Inter- versus Intraannular Ring-Closing Metathesis on Polyallylferrocenes: Five-Fold RCM within a Single Molecule" *Ogasawara, M.; Wu, W.-Y.; Arae, S.; Nakajima, K.; *Takahashi, T. Organometallics 2013, 32 pp.6593-6598. DOI:10.1021/om400936b |
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"Enantioselective Morita-Baylis-Hillman Reaction Catalyzed by a Chiral Phosphine Oxide" *Kotani, S.; Ito, M.; Nozaki, H.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Tetrahedron Lett. 2013, 54 pp.6430-6433. DOI:10.1016/j.tetlet.2013.09.067 |
中島誠教授（熊本大学） | |
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"Synthesis and Characterization of Benzo[b]phosphaferrocene Derivatives" *Ogasawara, M.; Arae, S.; Watanabe, S.; Subbarayan, V.; Sato, H.; *Takahashi, T. Organometallics 2013, 32 pp.4997-5000. DOI:10.1021/om400496b |
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"Kinetic Resolution of Planar-Chiral 1,2-Disubstituted Ferrocenes by Molybdenum-CatalyzedAsymmetric Intraannular Ring-Closing Metathesis" *Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. Chem. Eur. J. 2013, 19 pp.4151-4154. DOI:10.1002/chem.201300116 |
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"Kinetic Resolution of Planar-Chiral (eta6-Arene)chromium Complees by Molybdenum-CatalyzedAsymmetric Ring-Closing Metathesis" *Ogasawara, M.; Wu, W.-Y.; Arae, S.; Watanabe, S.; Morita, T.; *Takahashi, T.; *Kamikawa, K. Angew. Chem. Int. Ed. 2012, 51 pp.2951-2955. DOI:10.1002/anie.201108292 |
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"Effects of Silyl Substituents on the Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Their SE2' Chirality Transfer Reactions" *Ogasawara, M.; Ge, Y.; Okada, A.; *Takahashi, T. Eur. J. Org. Chem. 2012, pp.1656-1663. DOI:10.1002/ejoc.201101634 |
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"Preparation of C2-Symmetric Allenes by Palladium-Catalyzed Double Nucleophilic Substitution on 3-Bromopenta-2,4-dienyl Acetate" *Ogasawara, M.; Suzuki, M.; *Takahashi, T. J. Org. Chem. 2012, 77 pp.5406-5410. DOI:10.1021/jo300511e |
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| Reviews / Accounts |
"メタセシス反応による面不斉遷移金属錯体の触媒的不斉合成" *小笠原正道 ファインケミカル 2016, 45 pp.15-23. |
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"
面不斉遷移金属錯体の触媒的不斉合成
" 荒江祥永、*小笠原正道 J. Synth. Org. Chem. Jpn 2012, 70 pp.593-605. |
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| Conference / Symposium / Lecture |
招待講演 "Catalytic Asymmetric Synthesis of Planar-Chiral Zirconocene Derivatives and Their Application in Carbometallation Reactions" *Ogasawara, M. Pure and Applied Chemistry International Conference 2016 (PACCON 2016), Bangkok (Thailand) 2016-02-09～2016-02-11 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Zirconocenes and Application in Asymmetric Catalysis" *Ogasawara, M. International Science & Nature Congress (ISNaC2015), Kuala Lumpur (Malaysia) 2015-09-21～2015-09-23 |
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招待講演 "Design, Synthesis, and Application of Atropisomeric Chiral Dienes in Asymmetric Catalysis" *Ogasawara, M. The 8th Singapore International Chemical Conference, Singapore (Singapore) 2014-12-14～2014-12-17 |
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招待講演 "Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library" *Ogasawara, M. Vietnam Malaysia International Chemical Conference, Hanoi (Vietnam) 2014-11-07～2014-11-09 |
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招待講演 "Development of Enantioselective Transformations on (η6-Arene)chromium Templates by Molybdenum-Catalyzed Asymmetric Metathesis Reactions" *Ogasawara, M. The 18th Malaysian International Chemical Congress, Kuala Lumpur (Malaysia) 2014-11-03～2014-11-05 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes and Their Application in Organic Transformations" *Ogasawara, M. The 8th Asian European Symposium on Metal-Mediated Efficient Organic Synthesis, Cesme/Izmir (Turkey) 2014-09-07～2014-09-10 |
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招待講演 "Development of Catalytic Enantioselective Transformations Utilizing (η6-Arene)chromium Templates and Chiral Molybdenum-Alkylidene Catalysts" *Ogasawara, M. 41st International Conference on Coordination Chemistry, Singapore (Singapore) 2014-07-21～2014-07-25 |
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依頼講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Lecture at Dept. of Chemistry, The Univ. of Chicago, Chicago (USA) 2014-03-21～2014-03-21 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral (η6-Arene)chromium Complexes" ○*Ogasawara, M. The 247th ACS National Meeting, Dallas (USA) 2014-03-16～2014-03-20 |
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依頼講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Lecture at Dept. of Chemistry, Tsinghua Univ., Beijing (China) 2013-12-06～2013-12-06 |
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招待講演 "Atropisomeric Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of C2-Symmetric (Z,Z)-1,2-Bis[1-(diphenylphosphino)ethylidene]cycloalkane Derivatives" ○*Ogasawara, M. International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), Beijing (China) 2013-12-01～2013-12-05 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Invited Lecture at Charles University in Prague, Prague (Czech Republic) 2013-11-04～2013-11-04 |
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基調講演 "Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Application to Synthesis of Allenic Natural Products" ○*Ogasawara, M. The 48th Advances in Organic, Bioorganic and Pharmaceutical Chemistry (Liblice 2013), Špindlerův Mlýn (Czech Republic) 2013-11-01～2013-11-03 |
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口頭発表／ポスター発表 " Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes by Asymmetric RCM " ○*Ogasawara, M.International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis" *Ogasawara, M.; ○Wu, W.-Y.; Nakaya, T.; Morita, T.; Arae, S.; Tseng, Y.-Y.; *Takahashi, T.; *Kamikawa, K. International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Catalytic Induction of Planar Chirality in Functional Metallocenes by Mo-Catalyzed Asymmetric Ring-Closing Metathesis" *Ogasawara, M.; ○Arae, S.; Watanabe, S.; Oana, A.; Nakajima, K.; *Takahashi, T. International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Concomitant Catalytic Induction of Planar- and Axial-Chirality in [h6-(N-Indolyl)arene]chromium Complexes by Mo-Catalyzed Asymmetric Ring-Closing Metathesis" *Kamikawa, K.; ○Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. The 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2014-04-11 |
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口頭発表／ポスター発表 "Catalytic Enantioselective Synthesis of Planar-Chiral Metallocenylphosphines by Mo-Catalyzed Asymmetric Ring-Closing Metathesis and Their Application as Chiral Ligands" *Ogasawara, M.; ○Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. 25th International Conference on Organometallic Chemistry, Lisbon (Portugal) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Kinetic Resolution of Planar-Chiral (π-Arene)chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" ○*Ogasawara, M.; Wu, W.-Y.; Arae, S.; Watanabe, S.; Morita, T.; *Takahashi, T.; *Kamikawa, K. 25th International Conference on Organometallic Chemistry, Lisbon (Portugal) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Helically Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of 1,4-Bis(phosphino)-1,3-butadiene Derivatives Having C2-C3-Fused Cyclic System
" ○*Ogasawara, M.; Nakajima, H.; Nakajima, K.; *Takahashi, T. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Synchronous Induction of Planar- and Axial-Chirality in [η6-(N-indolyl)arene]chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" *Kamikawa, K.; ○Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Greg Fu’s Planar-Chiral Fc*-DMAPs" *Ogasawara, M.; ○Wada, S.; Isshiki, E.; *Yanagisawa, A.; *Takahashi, T.; *Yoshida, K. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Helically Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of 1,4-Bis(phosphino)-1,3-butadiene Derivatives Having C2-C3-Fused Cyclic System" ○*Ogasawara, M. The 17th Malaysian Chemical Congress, Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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招待講演 "Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis" ○*Ogasawara, M. Cambodian Malaysian Chemical Conference, Siem Reap (Cambodia) 2012-10-19～2012-10-21 |
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招待講演 "Herically Chiral Dienes in Asymmetric Catalysis: C2-Symmetric (Z, Z)-1,2-Bis(1-diphenylphosphinylethylidene)cyclohexanes as Highly Acitve Lewis-Base Organocatalysts" ○*Ogasawara, M. The 1st Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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招待講演 "Pd-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Their Application in Organic Transformations
" ○*Ogasawara, M. Invited Lecture at National Taiwan University (the Chemistry Research Promotion Center, Taiwan), Taipei (Taiwan) 2012-12-28～2012-12-28 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes
" ○*Ogasawara, M. Invited Lecture at National Tsing Hua University (the Chemistry Research Promotion Center, Taiwan), Hsinchu (Taiwan) 2012-12-26～2012-12-26 |
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招待講演 " Pd-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Their Application in Organic Transformations
" ○*Ogasawara, M. Invited Lecture at National Taiwan Normal University (the Chemistry Research Promotion Center, Taiwan), Taipei (Taiwan) 2012-12-24～2012-12-24 |
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招待講演 "Catalytic Asymmetric Synthesis of Planar-Chiral Ferrocenes and Their Applications in Optically Active Metallocene-Polymers" ○*Ogasawara, M. The 3rd Molecular Materials Meeting, Singapore (Singapore) 2013-01-14～2013-01-16 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. The 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2013-04-11 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes" ○*Ogasawara, M. The 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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| A01 是永 敏伸 | ||
| Original papers |
"Synthesis of highly refractive and highly fluorescent rigid cyanuryl polyimines with polycyclic aromatic hydrocarbon pendants" Kotaki,T.; Nishimura, N.; Ozawa, M.; Fujimori, A.; Muraoka, H.; Ogawa, S.; Korenaga, T.; Suzuki, E.; Oishi, Y.; *Shibasaki, Y. Polymer Chemistry 2016, 7 pp.1297-1308. |
T. Kotaki, N. Nishimura, M. Ozawa, A. Fujimori, H. Muraoka, S. Ogawa, T. Korenaga, E. Suzuki, Y. Oishi, and Y. Shibasaki |
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"Enantioselective acyl transfer catalysis by a combination of common catalytic motifs and electrostatic interactions" *Mandai, H.; Fujii, K.; Yasuhara, H.; Abe, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Nat. Commun. 2016, 7 pp.11297. |
菅誠治 | |
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"Perfluorinated Aryls in the Design of Chiral Bronsted Acid Catalysts: Catalysis of Enantioselective [4 + 2] Cycloadditions and Ene Reactions of Imines with Alkenes by Chiral Mono-Phosphoric Acids with Perfluoroaryls" *Momiyama, N.; Okamoto, H.; Kikuchi, J.; Korenaga, T.; *Terada, M. ACS Catal. 2016, 6 (2), pp.1198-1204. DOI:10.1021/acscatal.5b02136 |
寺田 眞浩 | |
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"EnantioselectiveAza Michael-Type Addition to AlkenylBenzimidazoles Catalyzed by aChiral PhosphoricAcid" Wang,Y.Y.; Kanomata, K.; Korenaga, T.;*Terada, M. Angew. Chem. Int. Ed. 2016, 55 (3), pp.927-931. DOI:10.1002/anie.201508231 |
寺田 眞浩 | |
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"Development and Application of a Multielectron-Accepting Organic Oxidant for the Catalytic Transition-Metal-Free Oxidative Homocoupling of Grignard Reagents in Air" *Korenaga, T.; Nitatori, K.; Muraoka, H.; Ogawa, S.; Shimada, K. Org. Lett. 2015, 17 (21), pp.5500-5503. DOI:10.1021/acs.orglett.5b02887 |
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"Enantioselective Steglich Rearrangement of Oxindole Derivatives by Easily Accessible Chiral N,N-4-(Dimethylamino)pyridine Derivatives" *Mandai, H., Fujiwara, T.; Noda, K.; Fujii, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Org. Lett. 2015, 17 (18), pp.4436-4439. DOI:10.1021/acs.orglett.5b02089 |
菅 誠治 | |
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"Highly Electron-poor Buchwald-type Ligand: Application for Pd-catalysed Direct Arylation of Thiophene Derivatives and Theoretical Consideration of the Secondary Pd0-arene Interaction" *Korenaga, T.; Sasaki, R.; Shimada, K. Dalton Trans. 2015, 44 pp.19642-19650. DOI:10.1039/C5DT01991E |
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"Ligand Effect on Direct Arylation by CMD Process" *Korenaga, T.; Suzuki, N.; Sueda, M.; Shimada, K. J. Organomet. Chem. 2015, 780 pp.63-69. |
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"Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid" *Terada, M.; Komuro, T.; Toda, Y.; Korenaga, T. J. Am. Chem. Soc. 2014, 136 (19), pp.7044-7057. |
寺田眞浩 | |
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"Low-Temperature Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds" *Korenaga, T.; Ko, A.; Shimada, K. J. Org. Chem. 2013, 78 (19), pp.9975-9980. |
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"The Shielding Effect of Fluoroaromatic Rings in NMR" *Korenaga,T.; Kobayashi, F.; Nomura, K.; Sakai, T.; Shimada, K. J. Fluorine Chem. 2013, 156 pp.1-4. |
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"Biogenous Iron Oxide-immobilized Palladium Catalyst for the Solvent-free Suzuki-Miyaura Coupling Reaction" Mandai, K.; Korenaga, T.; Ema, T.; Sakai, T.; Furutani, M.; Hashimoto, H.; *Takada, J. Tetrahedron Lett. 2012, 53 (3), pp.329-332. |
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| Books |
「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "[(S)-6,6'-ジメトキシ-1,1'-ビフェニル-2,2'-ジイル]- ビス[1,1-ビス(3,4,5-トリフルオロフェニル)ホスフィン]" 是永敏伸 三共出版 (東京) 2015, pp348-351. ISBN:978-4-7827-0727-2 |
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「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "ペンタフルオロフェニルベンゼン" 是永敏伸 三共出版 (東京) 2015, pp326-329. ISBN:978-4-7827-0727-2 |
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「触媒の設計･反応制御 事例集」 "電子不足な不斉ジホスフィン配位子を用いた触媒反応の高効率化" *是永敏伸 科学技術情報社 2013, pp703-711. |
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| Reviews / Accounts |
"金属錯体触媒を超高活性化する新型リン配位子の開発" *是永敏伸 化学工業 2013, 63 (5), pp.329-336. |
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"遷移金属をルイス酸として用いるFrustrated Lewis Pairs " *是永敏伸 Oraganometallic News 2012, (2), pp.68. |
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"高度に電子不足な含フッ素アリールホスフィン配位子を用いた高効率的金属錯体触媒反応" *是永敏伸 有機合成化学協会誌 2013, 71 (1), pp.55-65. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Oxidative homocoupling reaction of aryl Grignard reagents using perfluorocyclopentene derivatives" ○*Korenaga, T.; Nitatori, K.; Shimada, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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依頼講演 "Highly active transition metal catalysts bearing electron-poor phosphine ligand" ○*Korenaga, T. The 95th CSJ Annual Meeting，Asian International Symposium -Organic Chemistry/Green Chemistry-, Narashino (Japan) 2015-03-26～2015-03-26 |
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口頭発表／ポスター発表 "High Efficiency Rh-Catalyzed Asymmetric 1,4- or 1,2-Additions of Arylboronic acids using Highly Electron-Poor Chiral Diphosphine Ligands" ○*Korenaga, T.; Ko, A.; Shimada, K. XXVI International Conference on Organometallic Chemistry, Sappro (Japan) 2014-07-13～2014-07-18 |
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依頼講演 "Highly Electron-Poor Phosphine Ligands Bearing Fluoro-Functional Groups for Rh or Pd Catalysts" ○*Korenaga, T. ICOMC2014 Pre-Symposium in Sendai, Sendai (Japan) 2014-07-11～2014-07-11 |
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口頭発表／ポスター発表 "RHODIUM CATALYZED-ASYMMETRIC ADDITION OF ARYLBORONIC ACID USING HIGHLY ELECTRON-POOR CHIRAL DIPHOSPHINE BEARING FLUORO-FUNCTIONAL GROUPS" ○*Korenaga, T.; Ko, A.; Osaki, K.; Maenishi, R.; Sakai, T. The 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2013-07-27 |
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| Patent |
"含フッ素有機化合物及びこれとグリニャール試薬によるビアリール化合物の製造方法" 発明者：是永敏伸、似鳥馨 出願者：国立大学法人岩手大学 特願2015-119781 2015-06-12, 2015-08, (国内) |
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| Media |
"レアメタル代替新触媒" 是永 敏伸 岩手日報 2015-11-29 PDF 研究成果の紹介記事 |
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| A01 小西 玄一 | ||
| Original papers |
"Highly twisted N,N-dialkylamines as a design strategy to tune simple aromatic hydrocarbons as steric environment-sensitive fluorophores" Sasaki, S.; Suzuki, S.; Sameera, W. M. C.; *Morokuma, K.; *Konishi, G. J. Am. Chem. Soc. 2016, 138 (26), pp.8194-8206. DOI:10.1021/jacs.6b03749 |
諸熊奎治（A01班) |
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"Amphiphilic gels of solvatochromic fluorescent poly(2-oxazoline)s containing D–π–A pyrenes" Chen, C.-H.; Niko, Y.; *Konishi, G. RSC Adv. 2016, 6 (49), pp.42962-42970. DOI:10.1039/C6RA06251B |
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"Recent advances in Twisted Intramolecular Charge Transfer (TICT) fluorescence and related phenomena in materials chemistry" Sasaki, S.; *Drummen, G. P. C.; Konishi, G J. Mater. Chem. C 2016, 4 (14), pp.2731-2742. DOI:DOI: 10.1039/C5TC03933A |
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"Bright and photostable push-pull pyrene dye visualizes lipid order variation between plasma and intracellular membranes" Niko, Y.; Didier, P.; Mely, I.; Konishi, G.; *Klymchenko, A. S. Sci. Rep. 2016, 6 pp.18870. DOI:DOI: 10.1038/srep18870 |
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"1-, 3-, 6-, and 8-Tetrasubstituted Asymmetric Pyrene Derivatives with Electron-Donors and -Acceptors: High Photostability and Regioisomer-Specific Photophysical Properties" Niko, Y.; Sasaki, S.; Narushima, K.; Sharma, D. K.; Vacha, M.; *Konishi, G. J. Org. Chem. 2015, 80 (21), pp.10794-10805. DOI:DOI: 10.1021/acs.joc.5b01987 |
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"The effect of regioisomerism on the solid-state fluorescence of bis(piperidyl)anthracenes: structurally simple but bright AIE luminogens" Sasaki, S.; Igawa, K.; *Konishi, G. J. Mater. Chem. C 2015, 3 (23), pp.5940-5950. DOI:10.1039/C5TC00946D |
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"Directional Control of π-Conjugation Enabled by Distortion of the Donor Plane in Diarylaminoanthracenes: A Photophysical Study" Sasaki, S.; Hattori, K.; Igawa, K.; *Konishi, G. J. Phys. Chem. A 2015, 119(20) pp.4898-4906 . DOI:10.1021/acs.jpca.5b03238 |
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"Novel pyrene-based two-photon active fluorescent dye efficiently excited and emitting in the ‘tissue optical window (650–1100 nm)’" Niko, Y.; Sugihara, H.; Moritomo, H.; Suzuki, Y.; Kawamata, J.; *Konishi, G. J. Mater. Chem. B 2015, 3 (2), pp.184-190. DOI:10.1039/C4TB01404A |
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"Disassembly-driven fluorescence turn-on of cross-linked micelles by reductive stimuli in living cells" Niko, Y.; Arntz, Y.; Mely, Y.; Konishi, G.; *Klymchenko, A. S. Chem. Eur. J. 2014, 20 (50), pp.16473-16477. DOI:10.1002/chem.201405040 |
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"Design of donor-acceptor geometry for tuning of excited state polarization: fluorescence solvatochromism of push-pull biphenyls with various torsional restrictions on their aryl-aryl bonds" Sasaki, S.; Niko, Y.; Klymchenko, A. S.; *Konishi, G. Tetrahedron 2014, 70 (41), pp.7551-7559. DOI:10.1016/j.tet.2014.08.002 |
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"Pyrene-based D-π-A dyes that exhibit solvatochromism and high fluorescence brightness in apolar solvents and water" Niko, Y.; Cho, Y.; Kawauchi, S.; *Konishi, G. RSC Adv. 2014, 4 (69), pp.36480-36484. DOI:10.1039/C4RA06282E |
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"Aggregation-induced emission active D-π-A binaphthyl luminophore with dual-mode fluorescence" Sasaki, S.; Niko, Y.; Igawa, K.; *Konishi G. RSC Adv. 2014, 4 (63), pp.33474-33477. DOI:10.1039/C4RA05871B |
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"Design of Weak-Donor Alkyl–Functionalized Push–Pull Pyrene Dyes Exhibiting Enhanced Fluorescence Quantum Yields and Unique On–Off Switching Properties" Niko, Y.; Sasaki, S.; Kawauchi, S.; Tokumaru, K.; *Konishi, G Chem. Asian J. 2014, 9 (7), pp.1797-1807. DOI:10.1002/asia.201402088 |
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| A01 山田 眞二 | ||
| Original papers |
"
A pyridinium cation–pi
interaction sensor for the fluorescent detection of alkyl halides
"
Chen, W.; Elfeky, S. A.;
Nonne, Y.; Male, L.; Ahmed, K.; Amiable, C.; Axe, P.; Yamada, S.; James, T. D.; Bull, S. D.; *Fossey,
J. S.
Chem. Commun. 2011, 47 pp.253-255. |
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"
2,4-dihydroxy-2,5-dimethyl-3(2H)-thiophenone
as low-molecular-weight yellow pigment in soy sauce
"
Satoh, M.; Nomi, Y.; Yamada, S.; Takenaka, M.; Ono, H.; *Murata,
M.
Biosci. Biotechnol. Biochem. 2011, 75 pp.1240-1244. |
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"
Regiospecific [2+2]
photocyclodimerization of trans-4-styrylpyridines templated by
cucurbit[8]uril
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*Nakamura, A.; Irie, H.; Hara, S.; Sugawara, M.; Yamada, S.
Photochem. Photobiol. Sci. 2011, 10 pp.1496-1500. |
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"
Water-assisted assembly of (E)-arylvinylpyridine
hydrochlorides: effective substrates for solid-state [2+2] photodimerization
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*Yamada,
S.; Nojiri, Y.
Chem. Commun. 2011, 47 pp.9143-9145. |
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"
Nitrogen cation-pi interactions
in asymmetric organocatalytic synthesis
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*Yamada,
S.; Fossey, J. S.
Org. Biomol. Chem. 2011, 9 pp.7275-7281. |
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"[2+2] Photodimerization of ( E )-styrylthiazoles through cation-π-controlled preorientation" *Yamada, S.; Yamagami, K.; Oaku, S. Tetrahedron Lett. 2016, 57 pp.2451-2454. DOI:10.1016/j.tetlet.2016.04.085 |
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"Porous organic hydrate crystals: structure anddynamic behaviour of water clusters" *Yamada, S.; Sako, N.; Yamada, K.; Deguchi, K.; Shimizu, T. CrystEngComm 2015, 17 pp.5629-5633. DOI:10.1039/c4ce02517b |
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"Vapochromism associated with the changes in themolecular arrangement of organic crystals" *Yamada, S.; Katsuki, A.; Nojiri, Y.; Tokugawa, Y. CrystEngComm 2015, 17 pp.1416-1420. DOI:10.1039/c4ce01314 |
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"A Molecular Seesaw Balance: Evaluation of Solvent andCounteranion Effects on Pyridinium−π Interactions" *Yamada, S; Yamamoto, N; Takamori, E. Org. Lett. 2015, 17 pp.4862-4865. DOI:10.1021/acs.orglett.5b02420 |
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"Isolation, identification, and formation conditions of a novel Maillardyellowish pigment, pyrrolothiazolate" Noda, K.; Yamada, S.; *Murata, M. Biosci. Biotechnol. Biochem. 2015, 79 pp.1350-1355. DOI:10.1080/09168451.2015.1018127 |
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"Tetrabutylammonium-assisted diastereoselective [6π]-photocyclization of acrylanilides" *Yamada, S.; Okuda, M.; Yamamoto, N. Tetrahedron Lett. 2015, 56 pp.2098-2101. |
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"[2+2] photodimerization of 1-aryl-4-pyridylbutadienes through cation-pi interactions" *Yamada, S.; Azuma, Y.; Aya, K. Tetrahedron Lett. 2014, 55 pp.2801-2804. |
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"Tetraalkylammonium-Templated Stereoselective Norrish-Yang Cyclization" *Yamada, S.; Iwaoka, A.; Fujita, Y.; Tsuzuki, S. Org. Lett. 2013, 15 (23), pp.5994-5997. DOI:10.1021/ol4028732 |
Tsuzuki, S. | |
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"
Cascade reactions in crystals through cation-pi-controlled
reorientation on exposure to HCl gas
"
*Yamada, S.; Tokugawa, Y. Nojiri, Y.; Takamori, E.
Chem. Commun. 2012, 48 pp.1763-1765. DOI:10.1039/c2cc17019a |
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"
[2
+ 2] Photodimerization of bispyridylethylenes by a controlled shift of the
protonation equilibrium"
*Yamada, S.; Kusafuka, M.; Sugawara, M. Tetrahedron Lett. 2013, 54 pp.3997-4000. DOI:10.1016/j.tetlet.2013.05.075 |
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"
A dual-synthon in pyridinium chloride: formation of ladder-like and columnar motifs through hydrogen bonds and cation–pi interactions
" *Yamada, S.; Sako, N.; Okuda, M.; Hozumi, A. CrystEngComm 2013, 15 (1), pp.199-205. DOI:10.1039/C2CE26547H |
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"[4 + 4] Photodimerization of Azaanthracenes in Both Solution and Solid Phase Controlled by Cation-π Interactions" *Yamada, S.; Kawamura, C. Org. Lett. 2012, 14 (6), pp.1572-1575. DOI:10.1021/ol3003089 |
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"Contribution of Cation-pi Interactions in Iminium Catalysis" Mori, Y.; *Yamada, S. Molecules 2012, 17 pp.2161-2168. DOI:10.3390/molecules17022161 |
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| Reviews / Accounts |
"ピリジン誘導体と気体の反応による分子配列変化：カチオン−π相互作用による制御" 山田眞二 日本結晶学会誌 2013, 55 pp.63-68. |
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| Conference / Symposium / Lecture |
依頼講演 "
カチオンーπ相互作用に基づく有機触媒設計：イオン液体の有機触媒としての利用
"
○*山田眞二 第５回有機触媒シンポジウム, 東京 (日本) 2012-10-27～2012-10-28 |
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口頭発表／ポスター発表 "
テトラアルキルアンモニウム塩をテンプレートとするNorrish-Yang環化反応 " ○藤田結香、*山田眞二、都築誠二第６回有機触媒シンポジウム, 札幌 (日本) 2014-06-20～2014-06-21 |
都築誠二 | |
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"
テトラアルキルアンモニウム塩を用いる芳香族ケトン類の立体選択的Norrish-Yang 反応
"
〇大島 有貴・*山田 眞二・都築 誠二
日本化学会第９５春期年会, 船橋 (日本) 2015-03-26～2015-03-29 |
都築誠二 | |
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口頭発表／ポスター発表 "
テトラアルキルアンモニウム塩を触媒とする立体選択的Norrish-Yang反応
"
○大島有貴・藤田結香・*山田眞二・都築誠二
第８回有機触媒シンポジウム, 沖縄 (日本) 2016-05-10～2016-05-11 |
都築誠二 | |
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口頭発表／ポスター発表 "Synthesis of Molecular Seesaw Balance and Its Application to a Molecular Switch" ○Yamamoto, N.; *Yamada, S CMES International Symposium on Supramolecular Chemistry and Functional Materials 2016 (CEMSupra) 2016, 東京 (日本) 2016-01-13～2016-01-14 |
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口頭発表／ポスター発表 "Cation-π Interactions between Pyridinium and Benzene Rings:A Powerful Tool for Arrangement of Organic Molecules" ○*Yamada, S. The 22nd International Conference on the Chemistry of Organic Solid State (ICCOSS XXII), 新潟 (日本) 2015-07-12～2015-07-17 |
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招待講演 "Diastereoselective Photocyclization Reactions throughTetraalkylammonium-π Interactions " ○*Yamada, S. Advanced Molecular Transformationsby Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, 東京 (日本) 2014-11-21～2014-11-22 |
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招待講演 "Tetraalkylammonium-Templated Stereoselective Norrish-Yang Cyclization of 2-Benzyloxyacylbenzenes" ○*Yamada, S.; Iwaoka, A.; Fujita, Y.; Tsuzuki, S. International Sympsium on Organic Reaction-11 (ISOR-11), Taipei (Taiwan) 2013-11-19～2013-11-22 |
Tsuzuki, S. | |
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口頭発表／ポスター発表 "
[2+2] Photodimerization of Bispyridylethylene through Cation-π Interaction "○*Yamada, S.; Kusafuka, M.; Sugawara, M. 7th Asian Photochemistry Conference 2012, Osaka (Japan) 2012-11-12～2012-11-15 |
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口頭発表／ポスター発表 "
アンモニウム塩との相互作用による２-アルコキシ芳香族ケトン類の立体選択的 Norrish Type II 反応"
○*山田眞二・岩岡梓・都築誠二 日本化学会第93春季年会, 草津 (日本) 2013-03-24～2013-03-24 |
都築誠二 | |
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口頭発表／ポスター発表 "
Tetrabutylammonium Salts as Templates for
Stereoselective Norrish Type II Reactions of 2-Benzyloxyacylbenzenes
"
*○Yamada, S.;
Iwaokoa, A.; Tsuzuki, S.
1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Tsuzuki, S. | |
| Media |
"
Making an Azaanthracene Sandwich? Use Cation-pi! "Yamada, S.; Kawamura, C. 10.1055/s-0031-1291133 2012-06-01PDF （Synfacts誌, 2012, 8(6),0615 に掲載） アザアントラセンの光二量化では、異性体混合物を与え、固相反応では二量体を与えない。しかし、酸を触媒として用いることで、溶液中では選択的にanti-HT二量体を与えた。さらに塩酸塩の固相光反応によって定量的にanti-HT体を与えた。ピリジニウムとベンゼンとのカチオン−π相互作用が立体選択的[4+4]光二量化を可能にした。 |
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| A01 鳴海 哲夫 | ||
| Original papers |
"A minimally cytotoxic CD4 mimic as an HIV entry inhibitor" Mizuguchi, T.; Harada, S.; Miura, T.; Ohashi, N.; Narumi, T.; Mori, H.; Irahara, Y.; Yamada, Y.; Nomura, W.; Matsushita, S.; Yoshimura, K.; Tamamura, H. Bioorganic & Medicinal Chemistry Letters 2016, 26 (2), pp.397-400. DOI:10.1016/j.bmcl.2015.11.103 |
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"Utilization of the Heavy Atom Effect for the Development of a Photosensitive 8-Azacoumarin-Type Photolabile Protecting Group" Takano, H; *Narumi, T.; Nomura, W.; Furta, T.; *Tamamura, H. Org. Lett. 2015, 17 (21), pp.5372-5375. DOI:10.1021/acs.orglett.5b02720 |
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"Remote Stereoinduction in the Organocuprate-Mediated Allylic Alkylation of Allylic gem-Dichlorides: Highly Diastereoselective Synthesis of (Z)-Chloroalkene Dipeptide Isosteres" Kobayakawa, T.; *Narumi, T.; *Tamamura, H. Org. Lett. 2015, 17 (10), pp.2302-2305. DOI:10.1021/acs.orglett.5b00611 |
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"Imidazolium Salt-Catalyzed Friedel–Crafts-Type Conjugate Addition of Indoles: Analysis of Indole/Imidazolium Complex by High Level ab Initio Calculations" Narumi, T.; Tsuzuki, S.; *Tamamura, H. Asian J. Org. Chem 2014, 3 (4), pp.497-503. |
都誠二 | |
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"Development of the 8-aza-3-bromo-7-hydroxycoumarin-4-ylmethyl group as a new entry of photolabile protecting groups" Takano, H.; *Narumi, T.; Takano, H.; Ohashi, N.; Suzuki, A.; Furuta, T.; *Tamamura, H. Tetrahedron 2014, In Press |
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"Isostere-Based Design of 8-Azacoumarin-Type Photolabile Protecting Groups: A Hydrophilicity-Increasing Strategy for Coumarin-4-ylmethyls" Narumi, T.; Takano, H.; Ohashi, N.; Suzuki, A.; Furuta, T.; *Tamamura, H. Org. Lett. 2014, 16 (4), pp.1184-1187. |
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"A CD4 Mimic as an HIV Entry Inhibitors: Pharmacokinetic" Hashimoto, C.; Narumi, T.; Otsuki, H.; Hirota, Y.; Arai, H.; Yoshimura, K.; Harada, S.; Ohashi, N.; Nomura, W.; Miura, T.; Igarashi, T.; Matsushita S.; *Tamamura, H. Bioorg. Med. Chem. 2013, 21 (24), pp.7884-7889. |
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"Generation of a Replication-competent Simian-human Immunodeficiency Virus, the Neutralisation Sensitivity of Which can be Enhanced in the Presence of a Small Molecule CD4 Mimic" Otsuki, H.; Hishiki, T.; Miura, T.; Hashimoto, C.; Narumi, T.; Tamamura, H.; Yoshimura, K.; Matsushita, S.; *Igarashi, T. J. Gen. Virol. 2013, 94 (12), pp.2710-2716. |
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"Peptide-based Ligand Screening and Functional Analysis of Protein Kinase C" Ohashi, N.; Nomura, W.; Narumi, T.; *Tamamura, H. Biopolymers: Peptide Science 2013, 100 (6), pp.613-620. |
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" Low Molecular Weight CXCR4 Ligands with Variable Spcers " Narumi, T.; Aikawa, H.; Tanaka, T.; Hashimoto, C.; Ohashi, N., Nomura, W.; Kobayakawa, T.; Takano, H.; Hirota, Y.; Murakami, T.; Yamamoto, N.; *Tamamura, H.ChemMedChem 2013, 8 (1), pp.118-124. DOI:10.1002/cmdc.201200390 |
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"CD4 Mimics as HIV Entry Inhibitors: Lead Optimization Studies of the Aromatic Substituents" Narumi, T.; Arai, H.; Yoshimura, K.; Harada, S.; Hirota, Y.; Ohashi, N.; Hashimoto, C.; Nomura, W.; Matsushita, S.; *Tamamura, H. Bioorg. Med. Chem. 2013, 21 (9), pp.2518-2526. DOI:10.1016/j.bmc.2013.02.041 |
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"Conjugation of Cell-penetrating Peptides Leads to Identification of Anti-HIV Peptides from Matrix Proteins" Narumi, T.; Komoriya, M.; Hashimoto, C.; Wu, H.; Nomura, W.; Suzuki, S.; Tanaka, T.; Chiba, J.; Yamamoto, N.; Murakami, T.; *Tamamura, H. Bioorg. Med. Chem. 2013, 20 (4), pp.1468-1474. DOI:10.1016/j.bmc.2011.12.055 |
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"Synthetic C34 Trimer of HIV-1 gp41 Shows Significant Increase of Inhibition Potency" Nomura, W.; Hashimoto, C.; Ohya, A.; Miyauchi, K.; Urano, E.; Tanaka, T.; Narumi, T., Nakahara, T.; Komano, J. A.; Yamamoto, N.; *Tamamura, H. ChemMedChem 2012, 7 (2), pp.205-208. DOI:10.1002/cmdc.201100542 |
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"Evaluation of a Synthetic C34 Trimer of HIV-1 gp41 as AIDS Vaccines." Hashimoto, C.; Nomura, W.; Ohya, A.; Urano, E.; Miyauchi, K.; Narumi, T.; Aikawa, H.; Komano J. A.; Yamamoto, N.; *Tamamura, H. Bioorg. Med. Chem. 2012, 20 (15), pp.3287-3291. DOI:10.1016/j.bmc.2012.03.050 |
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"Pharmacophore-Based Small Molecule CXCR4 Ligands. " Narumi, T.; Tanaka, T.; Hashimoto, C.; Nomura, W.; Aikawa, H.; Sohma, A.; Itotani, K.; Kawamata, M.; Murakami, T.; Yamamoto, N.; *Tamamura, H. Bioorg. Med. Chem. Lett. 2012, 22 (12), pp.4169-4172. DOI:10.1016/j.bmcl.2012.04.032 |
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"Stereoselective Formation of Trisubstituted (Z)-Chloroalkenes Adjacent to a Tertiary Carbon Stereogenic Center by Organocuprate-Mediated Reduction/Alkylation" Narumi, T.; Kobayakawa, T.; Aikawa, H.; Seike, S.; *Tamamura, H. Org. Lett. 2012, 14 (17), pp.4490-4493. DOI:10.1021/ol301988d |
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| Books |
「Peptide Newsletter Japan」 林 良雄; 中馬 吉郎 "焦らず、たゆまず、楽しんで" 鳴海哲夫 日本ペプチド学会 2015, pp3-6. |
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「最新ペプチド合成技術とその創薬研究への応用」 木曽良明 "α-ケト酸とヒドロキシアミンの化学選択的なライゲーション反応によるペプチド合成" 鳴海哲夫, Jeffrey W. Bode 株式会社 メディカル ドゥ (大阪) 2012, pp68-75. ISSN:1349-2527 |
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| A01 飯田拡基 | ||
| Original papers |
"Allosteric Regulation of Unidirectional Spring-Like Motion of Double-Stranded Helicates" Y. Suzuki, T. Nakamura, H. Iida, N. Ousaka, E. Yashima* J. Am. Chem. Soc. 2016, 138 (14), pp.4852-4859. DOI:10.1021/jacs.6b00787 |
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"Helical Poly(phenylacetylene)s Bearing Chiral and Achiral Imidazolidinone-Based Pendants that Catalyze Asymmetric Reaction due to Catalytically Active Achiral Pendants Assisted by Macromolecular Helicity" Takata, L. M. S.; *Iida, H.; Shimomura, K.; Hayashi, K.; dos Santos, A. A.; *Yashima, E. Macromol. Rapid Commun. 2015, 36 (23), pp.2047-2054. DOI:10.1002/marc.201500456 |
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"Enantioseparation on Riboflavin Derivatives Chemically Bonded to Silica Gel as Chiral Stationary Phases for HPLC" Kumano, D.; Iwahana, S.; Iida, H.; Shen, C.; Crassous, J.; *Yashima, E. Chirality 2015, 27 (8), pp.507-517. DOI:10.1002/chir.22452 |
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"Chirality- and Sequence-Selective Successive Self-Sorting via Specific Homo- and Complementary-Duplex Formations" Makiguchi, W.; Tanabe, J.; Yamada, H.; Iida, H.; Taura, D.; Ousaka, N.; *Yashima, E. Nature Commun. 2015, pp.6:7236. DOI:10.1038/ncomms8236 |
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"Homo-Double Helix Formation of an Optically Active Conjugated Polymer Bearing Carboxy Groups and Amplification of the Helicity upon Complexation with Achiral and Chiral Amines" Makiguchi, W.; Kobayashi, S.; Furukawa, K.; Iida, H.; Furusho, Y.; *Yashima, E. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 pp.990-999. DOI:10.1002/pola.27527 |
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"Flavin-Catalyzed Aerobic Oxidation of Sulfides and Thiols with Formic Acid/Triethylamine" *Murahashi, S.-I.; Zhang, D.; Iida, H.; Miyawaki, T.; Uenaka, M.; Murano, K.; Meguro, K. Chem. Commun. 2014, 50 (71), pp.10295-10298. |
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"Synthesis and Chiral Recognition Ability of Helical Polyacetylenes Bearing Helicene Pendants" Anger, E.; Iida, H.; Yamaguchi, T.; Hayashi, K.; Kumano, D.; *Crassous, J.; Vanthuyne, N.; Roussel, C.; *Yashima, E. Polym. Chem. 2014, 5 (17), pp.4909-4914. |
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"Absolute Stereochemistry of a 4 a-Hydroxyriboflavin Analogue of the Key Intermediate of the FAD-Monooxygenase Cycle" Iwahana, S.; Iida, H.; *Yashima, E.; Pescitelli, G.; *Di Bari, L.; Petrovic, A. G.; *Berova, N. Chem. Eur. J. 2014, 20 (15), pp.4386-4395. DOI:10.1002/chem.201304393 |
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"Riboflavin-Based Fluorogenic Sensor for Chemo- and Enantioselective Detection of Amine Vapors" Iida, H.; Miki, M.; Iwahana, S.; *Yashima, E. Chem. Eur. J. 2014, 20 (15), pp.4257-4262. DOI:10.1002/chem.201400234 |
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| Reviews / Accounts |
"Biomimetic flavin-catalysed reactions for organic synthesis" Iida, H.; Imada, Y.; *Murahashi, S.-I. Org. Biomol. Chem. 2015, 13 pp.7599-7613. DOI:10.1039/C5OB00854A |
Imada, Y. |
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of a Novel Optically Active Polymer Containing a π-Conjugated Riboflavin-Dimer Unit as the Main-Chain and Its Application to Organic Vapor Sensing" ○Nakajima, Y.; Iwahana, S.; Iida, H.; Yashima, E.* Molecular Chirality Asia 2014 (MCA2014), Beijing (China) 2014-10-29～2014-10-31 |
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口頭発表／ポスター発表 "Synthesis and Application of a Novel Optically Active Polymer Containing a π-Conjugated Dimeric Riboflavin Derivative as the Main-Chain" ○Nakajima, Y.; Iwahana, S.; Iida, H.; Yashima, E.* 2014 International Symposium on Integrated Molecular/Materials Science and Engineering (IMSE2014), Nanjing (China) 2014-11-01～2014-11-03 |
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口頭発表／ポスター発表 "Optical Detection of an Organic Vapor with a Dimeric Rboflavin-Containing Redox Active Polymer" Nakajima, Y.; Iwahana, S.; ○Iida, H.; Yashima, E.* IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering, Yokohama (Japan) 2015-10-18～2016-10-22 |
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口頭発表／ポスター発表 "Synthesis of Helical Poly(phenylacetylene)s Bearing Imidazolidinone Pendants and Their Application to Asymmetric Catalysis" ○Shimomura, K.; Takata, L. M. S.; Iida, H.; Hayashi, K.; dos Santos, A. A.; Yashima, E.* The 8th International Forum on Chemistry of Functional Organic Chemicals, Tokyo (Japan) 2015-11-15～2016-11-16 |
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口頭発表／ポスター発表 "Poly(phenylacetylene)s Bearing Chiral and Achiral Imidazolidinone Pendants and Their Application to Asymmetric Organocatalysis" ○Shimomura, K.; Takata, L. M. S.; Iida, H.; Hayashi, K.; dos Santos, A. A.; Yashima, E.* Pacifichem2015, Honolulu (USA) 2015-12-15～2016-12-20 |
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| A01 波多野 学 | ||
| Original papers |
"Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds" Hatano, M.; Hayashi, K.; Sakamoto, T.; Makino, Y.; *Ishihara, K. Synlett 2016, 27 (7), pp.1061-1067. DOI:10.1055/s-0035-1561362 |
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"Enantioselective Cyanosilylation of Ketones with Lithium(I) Dicyanotrimethylsilicate(IV) Catalyzed by a Chiral Lithium(I) Phosphoryl Phenoxide" Hatano, M.; Yamakawa, K.; Kawai, T.; Horibe, T.; *Ishihara, K. Angew. Chem. Int. Ed. 2016, 55 (12), pp.4021-4025. DOI:10.1002/anie.201510682 |
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"Remote Tris(pentafluorophenyl)borane-Assisted Chiral Phosphoric Acid Catalysts for the Enantioselective Diels–Alder Reaction" Hatano, M.; Ishihara, H.; Goto, Y.; *Ishihara, K. Synlett 2016, 27 (4), pp.564-570. DOI:10.1055/s-0035-1560369 |
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"Boron Tribromide-Assisted Chiral Phosphoric Acid Catalyst for a Highly Enantioselective Diels–Alder Reaction of 1,2-Dihydropyridines" Hatano, M.; Goto, Y.; Izumiseki, A.; Akakura, M.; *Ishihara, K. J. Am. Chem. Soc. 2015, 137 (42), pp.13472-13475. DOI:10.1021/jacs.5b08693 |
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"C- and N-Selective Grignard Addition Reactions of α-Aldimino Esters in the Presence or Absence of Zinc(II) Chloride: Synthetic Applications to Optically Active Azacycles" Hatano, M.; Yamashita, K.; *Ishihara, K. Org. Lett. 2015, 17 pp.2412-2415. DOI:10.1021/acs.orglett.5b00927 |
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"C-Selective and Diastereoselective Alkyl Addition to beta,gamma-Alkynyl-alpha-imino Esters with Zinc(II)ate Complexes" Hatano, M.; Yamashita, K.; Mizuno, M.; Ito, O.; *Ishihara, K. Angew. Chem. Int. Ed. 2015, 54 (9), pp.2707-2711. DOI:10.1002/anie.201408916 |
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"Chiral Supramolecular Magnesium(II) Binaphtholate Catalysts for the Enantioselective Direct Mannich-Type Reaction and Hetero-Diels–Alder Reaction" Hatano, M.; Horibe, T.; Yamashita, K.; *Ishihara. K. Asain J. Org. Chem. 2013, 2 (11), pp.952-956. DOI:10.1002/ajoc.201300190 |
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"Synthesis of Optically Pure 3,3′-Diaryl Binaphthyl Disulfonic Acids via Stepwise N–S Bond Cleavage" Hatano, M.; Ozaki, T.; Nishikawa, K.; *Ishihara, K. J. Org. Chem. 2013, 78 pp.10405-10413. DOI:10.1021/jo401848z |
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"Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones" Hatano, M.; Horibe, T.; *Ishihara, K. Angew. Chem. Int. Ed. 2013, 52 (17), pp.4549-4553. DOI:10.1002/anie.201300938 |
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"Lanthanum(III) Catalysts for Highly Efficient and Chemoselective Transesterification" Hatano, M.; *Ishihara, K. Chem. Commun. 2013, 49 (20), pp.1983-1997. DOI:10.1039/C2CC38204K |
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"In Situ Generated "Lanthanum(III) Nitrate Alkoxide" as a Highly Active and Nearly Neutral Transesterification Catalyst" Hatano, M.; Kamiya, S.; *Ishihara, K. Chem. Commun. 2012, 48 (76), pp.9465-9467. DOI:10.1039/C2CC34987F |
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"Enantioselective Direct Aminalization with Primary Carboxamides Catalyzed by Chiral Ammonium 1,1’-Binaphthyl-2,2’-disulfonates" Hatano, M.; Ozaki, T.; Sugiura, Y.; *Ishihara, K. Chem. Commun. 2012, 48 (41), pp.4986-4988. DOI:10.1039/C2CC31530K |
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"Conformationally Flexible Chiral Supramolecular Catalysts for Enantioselective Diels-Alder Reactions with Anomalous Endo/Exo Selectivities" Hatano, M.; *Ishihara, K. Chem. Commun. 2012, 48 (36), pp.4273-4283. DOI:10.1039/C2CC00046F |
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| Books |
「RSC Green Chemistry No. 38, Sustainable Catalysis: With Non-endangered Metals, Part 1」 North, M. "Chapter 2. Alkali metal (Li, Na, K)-based Catalysts " Hatano, M.; Ishihara, K The Royal Society of Chemistry 2016, pp15-48. |
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「超分子材料の設計と応用展開」 監修：原田 明 "テーラーメード型超分子触媒" 波多野学、石原一彰 シーエムシー出版 2014, pp162-175. ISBN:978-4-7813-0973-6 |
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「Science of Synthesis Knowledge Updates 2013/1」 Fuertner, A. (Vol. 9), Ishihara, K. (Vol. 7), Li, J. J. (Vol. 16), Moloney, M. G. (Vol. 5) "7.7 Product Class 7: Calcium Compounds" Hatano, M. Georg Thieme Verlag KG 2013, pp113-156. |
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| Reviews / Accounts |
"リン酸の酸・塩基協奏機能を活用したホウ素Lewis酸-キラルリン酸複合高活性触媒の開発" 波多野 学; *石原 一彰 月刊ファインケミカル 2016, 45 (2), pp.24-32. |
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"高機能触媒の超分子設計" 波多野学; 石原一彰 化学工業 2015, 66 (5), pp.381-388. |
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"アルキルZ試薬：亜鉛(II)アート錯体を用いるケトン及びイミノエステルへの高効率Grignard付加反応の開発" 波多野学; 石原一彰 和光純薬時報 2015, 83 (2), pp.2-5. |
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"キラルビナフチルジスルホン酸を鍵とする分子触媒設計の新機軸" 波多野学, 西川圭祐, *石原 一彰 TCIメール 2014, 160 pp.2-23. |
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"Chiral 1,1′-Binaphthyl-2,2′-Disulfonic Acid (BINSA) and Its Derivatives for Asymmetric Catalysis" Hatano, M.; *Ishihara, K. Asian J. Org. Chem. 2014, 3 (4), pp.352-365. DOI:10.1002/ajoc.201300256 |
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"テーラーメイド型超分子触媒の設計" Hatano, M.; *Ishihara, K. ケミカルエンジニヤリング 2012, 9 (57), pp.656-661. |
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"Design of Tailor-Made Conformationally Flexible Chiral Supramolecular Catalysts Beyond Enzymes (酵素を凌駕するテーラーメイド型配座柔軟性キラル超分子触媒の精密設計)" *Hatano, M. J. Synth. Org. Chem. Jpn 2012, 12 (70), pp.1242-1254. |
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"「飛翔する若手研究者」キラルジスルホン酸を鍵とする酸・塩基触媒化学" 波多野 学 化学と工業 2012, 65 (10), pp.782-783. |
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| Conference / Symposium / Lecture |
招待講演 "Synthesis of 3,3'-diaryl-1,1'-binaphthalene-2,2'-disulfonic acids and design of chiral 3,3'-Ar2-BINSA salt catalysts" ○*Ishihara, K.; Hatano, M.; Nishikawa, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Boron tribromide-assisted chiral phosphoric acid catalysts for highly enantioselective Diels–Alder reaction of 1,2-dihydropyridines (Paper #: 1544)" ○Hatano, M.; Goto, Y.; *Ishihara, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development of Chiral 3,3’-Diaryl-1,1’-Binaphthyl-2,2’-Disulfonic Acids (BINSA) as Chiral Brønsted Acid Catalysts" ○Hatano, M.; Nishikawa, K.; *Ishihara, K. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones" Hatano, M.; Horibe. T.; *Ishihara, K Gordon Research Conferences (GRC) 2013; Heterocyclic Compounds, Newport (USA) 2013-06-16～2013-06-21 |
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招待講演 "Design of Chiral Tailor-Made Supramolecular Catalysts for Higher-Ordered Stereoselective Diels-Alder Reaction" ○*Hatano, M. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Conformationally Flexible Chiral Supramolecular Catalysts for Enantioselective Diels-Alder Reactions with Anomalous Endo/Exo Selectivities" ○Hatano, M.; *Ishihara, K. Gordon Research Conferences (GRC) 2012; Heterocyclic Compounds, Newport (USA) 2012-06-24～2012-06-29 |
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| Prize |
"Thieme Chemistry Journal Award 2015" *Hatano, M. 2015-01 Thieme Chemistry (The editorial boards of Synlett, Synthesis, and Synfacts) |
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"平成25年度科学技術分野の文部科学大臣表彰若手科学者賞" 波多野学 2013-04 文部科学省 酸塩基協奏型高次機能触媒を用いる精密有機合成法の研究 |
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| Media |
"Enantioselective Cyanosilylation of Ketones with Extremely Reactive Lithium(I) Dicyanotrimethylsilicate(IV) Catalyzed by Chiral Lithium(I) Phosphoryl Phenoxide" Hatano, M.; Yamakawa, K.; Kawai, T.; Horibe, T.; Ishihara, K. Angew. Chem. Int. Ed. 2016-02-05 PDF ■Cover pictureに採用 http://onlinelibrary.wiley.com/doi/10.1002/anie.201601600/epdf ■名古屋大学記者発表(2016年2月5日(金) 名古屋大学広報プラザ2階)「ケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 〜構造多様性四置換不斉炭素の構築とキラル合成素子ライブラリーの拡充〜」http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20160208_engg.pdf ■「日本の研究.com」に研究成果掲載(2016年2月8日(月))「ケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 〜構造多様性四置換不斉炭素の構築とキラル合成素子ライブラリーの拡充〜」https://research-er.jp/articles/view/43198 ■化学工業日報 2016年2月9日(火)、第5面「キラル化合物 ケトン由来 効率合成 名大、新不斉触媒を開発」■中日新聞朝刊 2016年3月4日(金)、第6面「有機化合物の合成に新手法 名大グループが開発」■AlphaGalileoにハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (22 February 2016) http://www.alphagalileo.org/ViewItem.aspx?ItemId=161259&CultureCode=en ■ResearchSEAにハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (Article Released Mon-22nd-February-2016) http://www.researchsea.com/index.php ■EurekAlert! にハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (Article Released Mon-22nd-February-2016) http://www.eurekalert.org/pub_releases/2016-02/nu-bim022216.php ■ワイリー・サイエンスカフェに論文紹介 (2016年3月1日)「名古屋大・石原 一彰教授らがケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 (ACIE)」http://www.wiley.co.jp/blog/pse/ ■名大・学術研究・産学官連携推進本部NU Research論文ハイライトに掲載(2016年3月18日)http://www.aip.nagoya-u.ac.jp/public/nu_research_ja/highlights/detail/0003356.html ■Synfacts 2016, 12(4), 0395に論文紹介(Synfacts Contributors: Mark Lautens and Kosuke Yamamoto) |
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""C-Selective and Diastereoselective Alkyl Addition to beta,gamma-Alkynyl-alpha-imino Esters with Zinc(II)ate Complexes"" Hatano, M.; Yamashita, K.; Mizuno, M.; Ito, O.; *Ishihara, K. Angew. Chem. Int. Ed. 2015, 54, ASAP 2015-01-23 PDF ■日刊工業新聞（2015年1月23日（金）23面） 「人工アミノ酸産出多彩 名大が新合成法 光学活性物質ほぼ100% 副作用軽減、創薬開発に応用」(ウェブ版 http://www.nikkan.co.jp/news/nkx1020150123eaaj.html) ■中日新聞（2015年1月23日（金）3面） 「安価に高純度アミノ酸 名大開発、新薬の原料に」 ■化学工業日報（2015年1月30日（金）9面） 「α-第四級2置換アミノ酸 名大が高純度合成技術 アルキル化の新規錯体開発 安価で調整容易 医薬原料や機能材向け」 |
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"Supramolecular Catalysts from Simple Components" Hatano, M.; Horibe, T.; Yamashita, K.; *Ishihara. K. ChemistryViews 2013-11-18 Since Jean-Marie Lehn received the Novel Prize for supramolecular chemistry in 1987, chiral supramolecular catalysts have been attractive in organic synthesis. However, their practical use has been limited, as a precise synthesis of a sole designed species is difficult because of undesired aggregation of the catalysts. |
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""In Situ Generated "Lanthanum(III) Nitrate Alkoxide" as a Highly Active and Nearly Neutral Transesterification Catalyst"" Hatano, M.; Kamiya, S.; Ishihara, K. Chem. Commun. 2012, 48(76), 9465-9467. DOI: 10.1039/C2CC34987F 2012-08-08 PDF ・日刊工業新聞21面に記事掲載(2012年8月28日)「名大、ランタン触媒でエステル合成－医薬品製造の効率化へ」 |
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""Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones"" Hatano, M.; Horibe, T.; Ishihara, K.* Angew. Chem. Int. Ed. 2013-04-08 PDF Front Coverに選定 (Angew. Chem. Int. Ed. 2013, 52, 4549-4553.) ■中日新聞 2013年3月7日朝刊第29面「混ぜるだけで不斉触媒、有機物×金属「黄金比」発見、名大グループ、アルツハイマー薬に道」 ■朝日新聞 2013年3月7日朝刊第30面「薬合成「触媒」の自由設計法、名大院研究室が開発」 ■日刊工業新聞 2013年3月7日第19面「光学活性リン化合物、安価な合成技術開発」 ■日刊工業新聞 2013年3月7日(Web版)「名大、光学活性リン化合物を安価に合成する技術開発」 ■化学工業日報 2013年3月7日第4面「名大 超分子錯体で不斉触媒 ２物質混ぜるだけ 高収率・選択性を確認」 ■化学工業日報 2013年3月7日(Web版)「名古屋大学 超分子錯体で不斉触媒 ２物質混ぜるだけ」 ■名古屋大学ーJST共同発表：プレスリリース http://www.jst.go.jp/pr/announce/20130307/ ■日経プレスリリース http://release.nikkei.co.jp/detail.cfm?relID=332308&lindID=5 ■名古屋大学研究教育成果情報(PDF資料) http://www.nagoya-u.ac.jp/research/pdf/activities/20130307_engg.pdf?20130307 |
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| A01 中村 修一 | ||
| Original papers |
"Catalytic Enantioselective Reaction of α-Aminoacetonitriles Using Chiral Bis(imidazoline)-Pd Catalysts " Masaru Kondo, Tomoki Nishi, Tsubasa Hatanaka, Yasuhiro Funahashi, *Shuichi Nakamura Angew. Chem. Int. Ed. 2015, 54 (28), pp.8198-8202. DOI:10.1002/anie.201503098 |
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"Organocatalytic Enantioselective Peroxidation of Ketimines Derived from Isatins" *Shuichi Nakamura, Shun Takahashi Org. Lett. 2015, 17 (11), pp.2590-2593. DOI:10.1021/acs.orglett.5b00805 |
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"Catalytic enantioselective reaction of a-phenylthioacetonitriles using chiral bis(imidazoline)-Pd catalysts" Masaru Kondo, Natsumi Kobayashi, Tsubasa Hatanaka, Yasuhiro Funahashi, *Shuichi Nakamura Chem. Eur. J. 2015, 21 (25), pp.9066-9070. DOI:10.1002/chem.201501351 |
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"Direct Enantioselective Vinylogous Mannich Reaction of Ketimines with g-Butenolide by Using Cinchona Alkaloid Amide/Zinc(II) Catalysts" *Shuichi Nakamura, Ryota Yamaji, Masashi Hayashi Chem. Eur. J. 2015, 21 (27), pp.9615-9618. DOI:10.1002/chem.201500599 |
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"Direct Enantioselective Three-Component Synthesis of Optically Active Propargylamines in Water " Mutsuyo Ohara, Yoshichika Hara, Tohru Ohnuki, Shuichi Nakamura* Chem. Eur. J. 2014, 20 (9), pp.8848-8851. DOI:10.1002/chem.201402384 |
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"Organocatalytic Enantioselective Decarboxylative Reaction of Malonic Acid Half Thioesters with Cyclic N-Sulfonyl Ketimines Using N-Heteroarenesulfonyl Cinchona Alkaloid Amides" Shuichi Nakamura*, Masahide Sano, Ayaka Toda, Daisuke Nakane, Hideki Masuda Chem. Eur. J. 2015, 21 (10), pp.3929-3932. DOI:10.1002/chem.201406270 |
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"Organocatalytic Enantioselective Addition of Thiols to Ketimines Derived from Isatins" Shuichi Nakamura,* Shun Takahashi, Daisuke Nakane, Hideki Masuda Org. Lett. 2015, 17 (1), pp.106-109. DOI:10.1021/ol503309s |
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"Desymmetrization of meso-Aziridines with TMSNCS Using Metal Salts of Novel Chiral ImidazolinePhosphoric Acid Catalysts" Shuichi Nakamura,* Mutsuyo Ohara, Madoka Koyari, Masashi Hayashi, Kengo Hyodo, Nadaf Rashid Nabisaheb, and Yasuhiro Funahashi Org. Lett. 2014, 16 (17), pp.4452-4455. DOI:10.1021/ol501990t |
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"Direct Asymmetric Mannich-Type Reaction of a-Isocyanoacetates with Ketimines using Cinchona Alkaloid Amide/Copper(II) Catalysts" Masashi Hayashi, Masaru Iwanaga, Noriyuki Shiomi, Daisuke Nakane, Hideki Masuda, Shuichi Nakamura* Angew. Chem. Int. Ed. 2014, 53 (32), pp.8411-8415. DOI:10.1002/anie.201404629 |
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| Reviews / Accounts |
"Enantioselective Reaction Using Palladium Pincer Complexes with C2-Symmetric Chiral Bis(imidazoline)s" Shuichi Nakamura J. Synth. Org. Chem. Jpn 2016, 73 (12), pp.1062-1071. DOI:http://doi.org/10.5059/yukigoseikyokaishi.73.1062 |
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"イミノホスホランを利用する不斉有機分子触媒 －部位別の開発が新たな道を拓く" 中村修一 月間「化学」 2014, 69 (4), pp.66-67. |
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"Catalytic enantioselective decarboxylative reactions using organocatalysts " Shuichi Nakamura Org. Biomol. Chem. 2014, 12 (3), pp.394-405. DOI:10.1039/C3OB42161A |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Enantioselective Reaction of a-Heteroacetonitriles Using Palladium Pincer Complexes with Chiral Bis(imidazoline)s" ○Masaru Kondo, Natsumi Kobayashi, Tomoki Nishi, *Shuichi Nakamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM),, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Desymmetrization of meso-Aziridines Catalyzed by Cinchona Alkaloid amides-Metal Complexes " ○Noriyuki Shiomi, Masashi Hayashi, *Shuichi Nakamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM),, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "N-Heteroarenesulfonylated cinchona alkaloid amide catalysts: Asymmetric reaction of some nucleophiles with ketimines" ○*Shuichi Nakamura, Masahide Sano, Shun Takahashi, Ayako Toda, Noriyuki Hara, Ryota Tamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM), , Hawaii (USA) 2015-12-15～2015-12-20 |
N-Heteroarenesulfonylated cinchona alkaloid amide catalysts: Asymmetric reaction of some nucleophiles with ketimines | |
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口頭発表／ポスター発表 "Asymmetric Mannich-type Reaction of α-Phenylthioacetonitriles to Imines Using Chiral Bis(imidazoline)–Palladium Catalysts " ○Natsumi Kobayashi, Masaru Kondo, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry,, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Organocatalytic Enantioselective Aza-Friedel-Crafts Reaction of Cyclic Ketimines with Pyrroles " ○Nazumi Matsuda, Mutsuyo Ohara, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Enantioselective Decarboxylative Mannich-type Reaction Using N-Heteroarenesulfonyl Cinchona Alkaloid amide Catalyst " ◯Ayaka Toda, Masahide Sano, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry,, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Synthesis of Optically Active Sultams Using N-Heteroarenesulfonyl Cinchona Alkaloid Amide Catalyst " Ayaka Toda, Masahide Sano, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Enantioselective Three-component Synthesis of propargylamines accompanied by the dehydration in water " ○Yoshichika Hara, Mutsuyo Ohara, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Efficient Synthesis of Chiral Diaminonitriles Using Chiral Bis(imidazoline)-Pd Catalysts" ○Masaru Kondo, Tomoki Nishi, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Cinchona Alkaloid Picolinamide Catalysts: Asymmetric Reactions of Aziridines or Ketimines " ◯Noriyuki Shiomi, Shuichi Nakamura 内藤コンファレンス 有機分子触媒の化学 , 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "Enantioselective Nucleophilic Addition to Ketimines Using N-Heteroarenesulfonylated Cinchona Alkaloid Amide Catalysts " Shuichi Nakamura 第５回日英触媒的不斉合成コンフェレンス (5th UK-Japan Conference on Asymmetric Catalysis) , マンチェスター (イギリス) 2016-03-14～2016-03-15 |
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口頭発表／ポスター発表 "Development of Chiral Imidazoline-Phosphoric Acid Catalyst and Application to
Desymmetrization of meso-Aziridine with TMSNCS " ○Mutsuyo Ohara, Madoka Koyari, Masashi Hayashi, Kengo Hyodo, Nadaf Rashid
Nabisaheb, Shuichi Nakamura Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Enantioselective Addition of Thiols to Ketimines Derived from Isatins Using
N-Heteroarenesulfonylated Organocatalysts" ○Shun Takahashi, Shuichi Nakamura* Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Organocatalytic Decarboxylative Reaction with Cyclic Ketimines Using
N-Heteroarenesulfonyl Cinchona Alkaloid Amides " ○Ayaka Toda, Masahide Sano, Shuichi Nakamura* Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 " Cinchona Alkaloid amides/Copper(II) Ctalyzed Asymmetric Mannich-Type Reaction of
α-Isocyanoacetates with Ketimines " ◯Noriyuki Shiomi, Masashi Hayashi, Masaru Iwanaga, Shuichi Nakamura Nagoya (Japan) 2014-05-26～2014-05-28 |
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口頭発表／ポスター発表 "Catalytic Asymmetric Synthesis of Chiral a-Aminonitrile Using Palladium Pincer
Complexes with C2-Symmetric Chiral Bis(imidazoline)s" ◯Masaru Kondo, Kengo Hyodo, Shuichi Nakamura* Nagoya (Japan) 2014-05-26～2015-05-28 |
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招待講演 "Enantioselective reaction using chiral organocatalysts having heteroaryl groups" Shuichi Nakamura 8th Singapore International Chemistry Conference (シンガポール) 2014-12-14～2014-12-17 |
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招待講演 "Enantioselective reaction using chiral organocatalysts having heteroaryl groups" Shuichi Nakamura 青島 (中国) 2014-09-20～2014-09-24 |
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| Patent |
"光学活性なα－チオ－β－アミノニトリル類の製造方法" 発明者：中村修一・近藤 健・小林奈津美 出願者：名古屋工業大学長 特願2015-40258 2015-03-02, 2015-04, |
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"光学活性なα，β－ジアミノニトリル類の製造方法" 発明者：中村修一・近藤 健・西 友暉 出願者：名古屋工業大学長 特願2015-40217 2015-03-02, 2015-04, (国内) |
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| A01 柴富 一孝 | ||
| Original papers |
"Highly stereoselective cyclopropanation of diazo Weinreb amides catalyzed by chiral Ru(II)–Amm–Pheox complexes" Chanthamath, S.; Mandour, H. S. A.; Tong, T. M. T.; Shibatomi, K.; *Iwasa, S. Chem. Commun. 2016, Advance Article DOI:10.1039/C6CC02498J |
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"Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters" *Shibatomi, K.; Kotozaki, M.; Sasaki, N.; Fujisawa, I.; Iwasa, S. Chem. Eur. J. 2015, 21 (40), pp.14095-14098. DOI:10.1002/chem.201502042 |
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"Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C-F bond cleavage" *Shibatomi, K.; Kitahara, K.; Okimi, T.; Abe, Y.; Iwasa, S. Chem. Sci. 2016, 7 (2), pp.1388-1392. DOI:10.1039/C5SC03486H |
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"Ru(II)–Pheox-Catalyzed Asymmetric Intramolecular Cyclopropanation of Electron-Deficient Olefins" Nakagawa, Y.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2015, 17 (11), pp.2792-2795. DOI:10.1021/acs.orglett.5b01201 |
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"Organocatalytic asymmetric Michael addition of α-branched aldehydes to vinyl ketones: synthesis of 5-ketoaldehydes possessing a stereo-controlled all-carbon quaternary stereogenic center" *Yoshida, M.; Ukigai, H.; Shibatomi, K.; Hara, S. Tetrahedron Lett. 2015, 56 (25), pp.3890-3893. DOI:10.1016/j.tetlet.2015.04.107 |
吉田雅紀 准教授 | |
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"Highly Regio- and Stereoselective Synthesis of Alkylidenecyclopropanes via Ru(II)-Pheox Catalyzed Asymmetric Inter- and Intramolecular Cyclopropanation of Allenes" Chanthamath, S.; Chua, H. W.; Kimura, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2014, 16 (12), pp.3408-3411. DOI:10.1021/ol5014944 |
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"Highly Stereoselective Synthesis of Cyclopropylphosphonates Catalyzed by Chiral Ru(Ⅱ)-Pheox Complex" Chanthamath, S.; Ozaki, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2014, 16 (11), pp.3012-3015. DOI:10.1021/ol501135p |
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"Highly Enantioselective Synthesis of Halogenated Compounds Utilizing Lewis Acid or Organocatalyst" *Shibatomi, K 有機合成化学協会誌 2014, 72 (3), pp.232-245. DOI:10.5059/yukigoseikyokaishi.72.232 |
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*Shibatomi, K.; Okimi, T.; Abe, Y.; Narayama, A.; Nakamura, N.; Iwasa, S. Beilstein J. Org. Chem. 2014, 10 pp.323-331. DOI:10.3762/bjoc.10.30 |
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"Organocatalytic Enantioselective Diels–Alder Reaction of 4,4,4-Trifluorocrotonaldehyde" *Shibatomi, K.; Kawasaki, Y.; Iwasa, S. J. Fluorine Chem. 2015, 179 pp.77-82. DOI:10.1016/j.jfluchem.2015.05.011 |
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| Reviews / Accounts |
"Catalytic Enantioselective Constructions of Trifluoromethylated Chiral Stereogenic Centers via the Conjugate Addition to CF3-Alkenes: Overview of Current Progress" *Shibatomi, K. Curr. Org. Chem. 2015, 19 (16), pp.1619-1637. |
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| Conference / Symposium / Lecture |
招待講演 "Asymmetric Synthesis of Halogenated Compounds Directed Toward Drug Development" ○*Shibatomi, K. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Williamson ether synthesis at a tertiary stereogenic carbon: a new synthetic route to anti-diabetic drugs" ○Sasaki, N.; Kotozaki, M.; *Shibatomi, K.; Iwasa, S. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Highly enantioselective fluorination of branched aldehydes and its
application for the synthesis of fluorinated biologically active
molecules" ○Kitaharam K.; Okimi, T.; Abe, Y.; *Shibatomi, K.; Iwasa, S. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Organocatalytic enantioselective fluorination of α,α-disubstituted aldehydes" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Narayama, A.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Favorskii Rearrangement of α-Chloro-β-keto Esters" ○Sasaki, N.; Kotozaki, M.; *Shibatomi, K.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly enantioselective fluorination of α-branched aldehydes with a newly developed chiral primary amine catalyst" ○Kitahara, K.; Okimi, T.; *Shibatomi, K.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly Stereoselective Cyclopropanations of Weinreb Amide Derivatives Using Novel Ru(Ⅱ)-Pheox Catalysts" ○H. S. A. Mandour; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Ru(Ⅱ)-Pheox catalyzed carbene transfer reactions of diethyldiazomethylphosphonate" ○Ozaki, S.; Chanthamath, S.; Shibatomi K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly enantioselective synthesis of cyclopropane ring fused γ-lactones via intramolecular carbene transfer reactions" ○Nakagawa. Y.; Chanthamath, S.; Nakayama, N.; Goto, H.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly Enantioselective C−H Insertion Reaction of N-Alkyldiazoacetamides by using Ru(Ⅱ)-Pheox Complex" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Ru(II)-Pheox Catalyzed Stereoselective Cyclopropanation of Allylsilanes" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Ru(II)-Pheox Catalyzed Enantioselective Si-H Insertion Reaction of Diazoacetates" ○Nakagawa, Y.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of New Chiral Primary Amine Catalyst and Its Application to
the Enantioselective Halogenation of α-Branched Aldehydes" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Abe, Y.; Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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依頼講演 "Organocatalytic Enantioselective Fluorination of α,α-Disubstituted Aldehydes" ○*Shibatomi, K. 21st International Symposium on Fluorine Chemistry, Como (Italy) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "Computational Chemical Analysis for Ru(Ⅱ)-Pheox Catalyzed Enantioselective Intramolecular Cyclopropanation" ○Nakagawa, Y.; Chanthamath, S.; Nakayama, N.; Goto, H.; Shibatomi, K.; *Iwasa, S. 250th ACS National Meeting, Boston (USA) 2015-08-16～2015-08-20 |
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口頭発表／ポスター発表 "Asymmetric synthesis of α-heteroatom-substituted β-keto esters via SN2 substitution of tertiary chlorides" ○*Shibatomi, K.; Kotozaki, M.; Sasaki, N.; Iwasa, S 250th ACS National Meeting, Boston (USA) 2015-08-16～2015-08-20 |
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口頭発表／ポスター発表 "Development of New Chiral Primary Amine Catalyst and Its Use for Enantioselective Fluorination of α-Branched Aldehydes" ○*K. Shibatomi The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Copper(II)-Catalyzed Enantioselective Chlorination of β-Keto Esters and
Subsequent SN2 Displacement of Chiral Tertiary Chlorides Using Oxygen
Nucleophiles" ○Kotozaki, M.; Narayama, A.; Shibatomi, K.; *Iwasa, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Ru(Ⅱ)-Pheox Catalyzed Asymmetric Cyclopropanation of Diethyl Diazomethylphosphonate with Various Alkenes" ○Chanthamath, S.; Ozaki, S.; Shibatomi, K.; *Iwasa, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Highly Stereoselective Synthesis of trans- and cis-Cinnamic Weinreb Amides via 1,2-Hydride Migration" ○Ozaki, S.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Computational Chemical Analysis for Catalytic Asymmetric Spiral Cyclization and their Application" ○Nakagawa, Y.; Chanthamath, S.; Nakayama, T.; Goto, T.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "A Synthesis of Novel Three Member Ring System via Carbene Transfer Reactions" ○Mandour, H. S. A.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "A Synthesis of Novel Ru(Ⅱ) Complex and its Application for Synthesis of Bioactive Molecules via Carbene Transfer Reactions" ○Chanthamath, S.; Mandour, H. S. A.; Shibatomi, K; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Highly Enantioselective Synthesis of beta-Lactam Derivatives via Catalytic Asymmetric C-H Insertion" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Primary Amine-Catayzed Enantioselective Fluorination of α-Branched
Aldehydes and Subsequent Stereospecific C-F Bond Cleavage at Tertiary
Carbon" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Iwasa, S. 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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依頼講演 "Enantioselective synthesis of chiral fluorinated molecules" ○*Shibatomi, K. The 5th China-Japan-Korea Joint Seminar on Fluorine Chemistry, Shanghai (China) 2014-10-19～2014-10-21 |
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口頭発表／ポスター発表 "Enantioselective Fluorination of α-Branched Aldehydes with a New Primary Amine Catalyst" ○Moriakwa, H.; Abe, Y.; *Shibatomi, K.; Iwasa S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Organocatalytic Enantoselective Fluorination of α-Chloroaldehydes" ○Okimi, T.; Abe, Y.; Narayama, A.; Shibatomi, K.; Iwasa S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Synthesis of 4,4,4-Trifluorocrotonaldehyde and its use in Catalytic Asymmetric Synthesis" ○Kawasaki, Y.; Narayama, A.; Abe, Y.; *Shibatomi, K.; Iwasa, S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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| A01 加納 太一 | ||
| Original papers |
"Synthesis of N-Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with N-Boc-Aminals and Their Oxidation to N-Boc-Ketimines" Kano, T.; Kobayashi, R.; *Maruoka, K. Org. Lett. 2016, 18 (2), pp.276-279. |
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"Brønsted Acid-catalysed Mannich Reaction Through Dual Activation of Aldehydes and N-Boc-Imines" Kano, T.; Aota, Y.; Asakawa, D.; *Maruoka, K. Chem. Commun. 2015, 51 (92), pp.16472-16474. |
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"Regioselectivity Switch in Chiral Amine-catalysed Asymmetric Addition of Aldehydes to Reactive Enals" Kano, T.; Maruyama, H.; Sakamoto, R.; *Maruoka, K. Chem. Commun. 2015, 51 (49), pp.10062-10065. |
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"Regio- and Stereoselective Conjugate Addition of Aldehydes to β-Tosyl Enones Catalyzed by Binaphthyl-Modified Chiral Amine" Kano, T.; Sugimoto, H.; Maruyama, H.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (29), pp.8462-8465. |
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"Versatile, In-Situ Generated N-Boc-Imines: Application to Phase-Transfer Catalyzed Asymmetric Mannich-Type Reaction" Kano, T.; Kobayashi, R.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (29), pp.8471-8474. |
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"Design and Synthesis of a Biphenyl-based Chiral Amino Sulfonamide with High Catalytic Performance in Mannich Reactions" Kano, T.; Maruyama, H.; Akiyama, K.; *Maruoka, K. Tetrahedron Lett. 2014, 55 (30), pp.4227-4229. |
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"Synthesis of 3-Mono-Substituted Binaphthyl-Based Secondary Amine Catalysts via Monobromination of an Axially Chiral Dicarboxylic Acid Derivative" Kano, T.; Takeda, M.; Sakamoto, R.; *Maruoka, K. J. Org. Chem. 2014, 79 (9), pp.4240-4244. |
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"Practical Approach for Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds: Application to One-Pot Synthesis of Chiral Allylamines" Kano, T.; Shirozu, F.; *Maruoka, K. Org. Lett. 2014, 16 (5), pp.1530-1532. |
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"Amine-catalyzed Asymmetric Cross-aldol Reactions Using Hetero-functionalized Acetaldehydes as Nucleophiles" Kano, T.; Sakamoto, R.; *Maruoka, K. Org. Lett. 2014, 16 (3), pp.944-947. |
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"Chiral Brønsted Acid-catalyzed Enantioselective Addition of Indoles to Ketimines" Kano, T.; Takechi, R.; Kobayashi, R.; *Maruoka, K. Org. Biomol. Chem. 2014, 12 (5), pp.724-727. |
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"Remote Chirality Control Based on the Organocatalytic Asymmetric Mannich Reaction of α-Thio Acetaldehydes" Kano, T.; Sakamoto, R.; *Maruoka, K. Chem. Commun. 2014, 50 (8), pp.942-944. |
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"Metal-free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine" Kano, T.; Shirozu, F.; *Maruoka, K. J. Am. Chem. Soc. 2013, 135 (48), pp.18036-18039. |
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"Organocatalytic Asymmetric Synthesis of Propargylamines with Two Adjacent Stereocenters Through Mannich-type Reactions of in situ Generated C-Alkynyl Imines with β-Keto Esters" Kano, T.; Yurino, T.; *Maruoka, K. Angew. Chem. Int. Ed. 2013, 52 (44), pp.11509-11512. |
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"Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-transfer Conditions" Kano, T.; Hayashi, Y.; *Maruoka, K. J. Am. Chem. Soc. 2013, 135 (19), pp.7134-7137. |
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"Unusual anti-Selective Asymmetric Conjugate Addition of Aldehydes to Nitroalkenes Catalyzed by a Biphenyl-based Chiral Secondary Amine" Kano, T.; Sugimoto, H.; Tokuda, O.; *Maruoka, K. Chem. Commun. 2013, 49 (63), pp.7028-7030. |
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"Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals" Kano, T.; Yurino, T.; Asakawa, D.; *Maruoka, K. Angew. Chem. Int. Ed. 2013, 52 (21), pp.5532-5534. |
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"One-pot Cross Double-Mannich Reaction of Acetaldehyde Catalyzed by a Binaphthyl-based Amino Sulfonamide" Kano, T.; Sakamoto, R.; Yamaguchi, Y.; Itoh, K.; *Maruoka, K. Chem. Commun. 2013, 49 (11), pp.1118-1120. |
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"Stereoselective Synthesis of Cyclic Amino Acids via Asymmetric Phase-transfer Catalytic Alkylation" Kano, T.; Kumano, T.; Sakamoto, R.; *Maruoka, K. Org. Biomol. Chem. 2013, 11 (2), pp.271-278. |
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"Powerful Amino Diol Catalyst for Effecting the Direct Asymmetric Conjugate Addition of Aldehydes to Acrylates" Kano, T.; Shirozu, F.; Akakura, M.; *Maruoka, K. J. Am. Chem. Soc. 2012, 134 (38), pp.16068-16073. |
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"Molecular Recognition of Ketomalonates by Asymmetric Aldol Reaction of Aldehydes with Secondary-Amine Organocatalysts" Kano, T.; Song, S.; *Maruoka, K. Chem. Commun. 2012, 48 (56), pp.7037-7039. |
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"Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (–)-Agelastatin A" Kano, T.; Sakamoto, R.; Akakura, M.; *Maruoka, K. J. Am. Chem. Soc. 2012, 134 (17), pp.7516-7520. |
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"Highly Diastereo- and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine Organocatalysts" Kano, T.; Song, S.; Kubota, Y.; *Maruoka, K. Angew. Chem. Int. Ed. 2012, 51 (5), pp.1191-1194. |
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| Books |
「Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 2」 North, M. "Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts" Kano, T.; Maruoka, K. The Royal Society of Chemistry 2016, pp135-163. |
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「有機化学要論 生命科学を理解するための基礎概念」 入江一浩; 津江広人 "有機化学における熱力学の基礎" 入江一浩; 津江広人; 高野俊幸; 加納太一; 松原誠二郎; 板東俊和; 藤田健一 学術図書出版 2016, pp55-72. |
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「Comprehensive Chirality, Volume 6」 Maruoka, K.; Editors-in-Chief: Carreira, E. M.; Yamamoto, H. "6.20 C–X Bond Formation: α-Halogenation of Carbonyl Compounds" Kano, T. Elsevier Science (Amsterdam) 2016, pp488-505. ISBN:0080951678 |
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| Reviews / Accounts |
"Unique Properties of Chiral Biaryl-based Secondary Amine Catalysts for Asymmetric Enamine Catalysis" Kano, T.; *Maruoka, K. Chem. Sci. 2013, 4 (3), pp.907-915. |
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| Conference / Symposium / Lecture |
招待講演 "Catalyst Control of Diastereoselectivity in Chiral Amine-Catalyzed Asymmetric Conjugate Additions of Aldehydes" Kano, T. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" Kano, T. 7th Spanish Portuguese Japanese Organic Chemistry Symposium, Seville (Spain) 2015-06-23～2015-06-26 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" Kano, T. Departmental Seminar at Charles University, Prague (Czech Republic) 2015-06-19～2015-06-19 |
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口頭発表／ポスター発表 "Chiral Amine-Catalyzed Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds" Kano, T.; Shirozu, F.; *Maruoka, K. Chirality 2014, Prague (Czech Republic) 2014-07-27～2014-07-30 |
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口頭発表／ポスター発表 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T.; Shirozu, F.; *Maruoka, K. 13th Tateshina Conference, Tateshina (Japan) 2013-11-08～2013-11-10 |
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口頭発表／ポスター発表 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T.; *Maruoka, K. 23rd International Symposium, Synthesis in Organic Chemistry, Oxford (UK) 2013-07-22～2013-07-25 |
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招待講演 "Asymmetric α-Functionalization of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. Departmental Seminar at Oxford University, Oxford (UK) 2013-07-19～2013-07-19 |
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招待講演 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T. 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals" ○Kano, T.; Yurino, T.; *Maruoka, K. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 仙台 (日本) 2013-04-19～2013-04-20 |
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招待講演 "Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction: Formal Synthesis of (–)-Agelastatin A" ○Kano, T. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2013-12-18 |
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口頭発表／ポスター発表 "Highly Diastereo- and Enantioselective Mannich Reaction of Synthetically Flexible Ketimines by Secondary-Amine Organocatalysts" ○Kano, T.; Song, S.; *Maruoka, K. EUCHEM Conference on Stereochemistry (The 47th Bürgenstock Conference), Zürich (Switzerland) 2012-04-29～2012-05-04 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. Departmental Seminar at ETH, Zürich (Switzerland) 2012-04-27～2012-04-27 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. TAIWAN−JAPAN Symposium of Frontier Research on Design and Applications of Fine Chemicals, 台北 (台湾) 2012-01-06～2012-01-08 |
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| Prize |
"文部科学大臣表彰若手科学者賞" 加納太一 2012-04 文部科学省 デザイン型アミン有機触媒による精密有機合成の研究 |
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| Media |
"Brønsted Acid-catalysed Mannich Reaction Through Dual Activation of Aldehydes and N-Boc-Imines" Kano, T.; Aota, Y.; Asakawa, D.; *Maruoka, K. Chemical Communications 2015-11-28 PDF Chemical Communications誌のInside Coverに選定 |
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"Chiral Brønsted Acid-catalyzed Enantioselective Addition of Indoles to Ketimines" Kano, T.; Takechi, R.; Kobayashi, R.; *Maruoka, K. Org. Biomol. Chem. 2014-02-07 PDF Organic & Biomolecular Chemistry誌のFront Coverに選定 |
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"Unusual anti-Selective Asymmetric Conjugate Addition of Aldehydes to Nitroalkenes Catalyzed by a Biphenyl-based Chiral Secondary Amine" Kano, T.; Sugimoto, H.; Tokuda, O.; *Maruoka, K. Chemical Communications 2013-07-11 PDF Chemical Communications誌のFront Coverに選定 |
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"Stereoselective Synthesis of Cyclic Amino Acids via Asymmetric Phase-transfer Catalytic Alkylation" Kano, T.; Kumano, T.; Sakamoto, R.; *Maruoka, K. Organic & Biomolecular Chemistry 2013-01-14 PDF Organic & Biomolecular Chemistry誌のFront Coverに選定 |
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| A01 諸熊 奎治 | ||
| Original papers |
"Positive Effect of Water in Asymmetric Direct Aldol Reactions with Primary-Amine Organocatalyst: Experimental and Computational Studies" Moteki, S. A.; Nakayama, K.; Li, H.-B.; Petrova, G.; Maeda, S.; *Morokuma, K.; Maruoka, K. Chem. Asian J. 2015, DOI:10.1002/asia.201500078 |
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"Revisiting the Passerini Reaction Mechanism: Existence of the Nitrilium, Organocatalysis of Its Formation And Solvent Effect" Ramozzi, R.; *Morokuma, K. J. Org. Chem. 2015, 80 pp.5652-5657. DOI:10.1021/acs.joc.5b00594 |
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"Biginelli Reaction Is a Urea-Catalyzed Organocatalytic Multicomponent Reaction " Puripat, M.; Ramozzi, R.; Hatanaka, M.; Parasuk, W.; Parasuk, V.; *Morokuma, K. J. Org. Chem. 2015, DOI:10.1021/acs.joc.5b00407 |
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| Reviews / Accounts |
"The ONOIM Method and its Applications" Chung, L. W.; Sameera, W. M. C.: Ramozzi, R.; Page, A. J.; Hatanaka, M.; Petrova, G. P.; Harris, T. V.; Li, X.; Ke, Z.; Liu, F. Li, H.-B.; Ding, L.; *Morokuma, K. Chem. Rev. 2015, 115 pp.5678-5796. DOI:10.1021/cr5004419 |
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| Conference / Symposium / Lecture |
招待講演 "GRRM法を用いた複雑分子系の機構" GRRM誕生十周年 GRRM14発表記念講演会「GRRMで拓く化学のニューフロンティア」, 東京 (日本) 2014-11-30～2014-11-30 |
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招待講演 "複雑分子系のシミュレーション - 生体分子の反応への応用とその周辺" *Morokuma, K 情報計算化学生物学会（CBI学会 ), 東京 (日本) 2014-07-29～2014-07-29 |
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招待講演 "Quantum chemical molecular dynamics (QM/MD) simulations of nucleation, growth and healing processes of fullerenes, carbon nanotubes and graphenes" Morokuma, K the 17th International Symposium on Small Particles and Inorganic Clusters (ISSPIC XVII), Fukuoka (Japan) 2014-09-07～2014-09-07 |
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招待講演 "Gas-Phase Photochemical and Homogenous Catalytic Reactions Explored Using the Automated Reaction Route Mapping (GRRM) Method" *Morokuma, K American Chemical Society Spring Meeting, Denver (USA) 2015-03-23～2015-03-23 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Argonne National Laboratory, (USA) 2015-03-17～2015-03-17 |
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招待講演 "Chemical Reactions of Complex Molecular Systems -- Discovery and Insights from Computational Studies" *Morokuma, K 12th Fukui Institute Symposium, Fukui Institute for Fundamental Chemistry, Kyoto University,Kyoto (Japan) 2015-01-23～2015-01-23 |
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招待講演 "Fascinating World of Theoretical Studies of Chemical Reaction--From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Hiroshima University、Hiroshima (Japan) 2014-12-03～2014-12-03 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K Advanced Molecular Transformations by Organocatalysts”, 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-21 |
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招待講演 "Chemical Theory of Complex Molecular Systems: Discovery and Insights from Computational Studies of Chemical Reactions" *Morokuma, K CRC-SU Joint International Symposium on Chemical Theory of Complex Systems”: Symposium “Interplay between Theory and Experiments; New Trends in Catalysis, Stockholm University, Stockholm (Sweden) 2014-10-31～2014-10-31 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K Japan-Russia Joint-Symposium on Chemical Theory for Complex Systems, St. Petersburg State University (Russia) 2014-09-19～2014-09-19 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K International Conference "Molecular Complexity in Modern Chemistry (MCMC-2014), Moscow (Russia) 2014-09-16～2014-09-16 |
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招待講演 "Multiscale Computational Approaches And Applications in Biochemistry And Biomaterials" *Morokuma, K Annual Conference of Canadian Chemical Society, Vancouver (Canada) 2014-06-04～2014-06-04 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Swiss Chemical Society Lecture, EPFL, Lausanne (Switzerland) 2014-05-23～2014-05-23 |
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招待講演 "Complex Chemical Reaction Pathways Explored by Automatic Search Strategy" *Morokuma, K Swiss Chemical Society Lecture, ETH, Zurich (Switzerland) 2014-05-22～2014-05-22 |
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招待講演 "Theoretical Studies of Complex Molecular Systems. Methods and Applications" *Morokuma, K Swiss Chemical Society Lecture, University of Basel, Basel (Switzerland) 2014-05-21～2014-05-21 |
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招待講演 "Chemical Theory of Complex Molecular Systems: Discovery and Insights from Computational Studies of Chemical Reactions" *Morokuma, K Swiss Chemical Society Lecture, University of Fribourg, Fribourg (Switzerland) 2014-05-20～2014-05-20 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Swiss Chemical Society Lecture, University of Basel, Basel (Switzerland) 2014-05-19～2014-05-19 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, Australian National University, Canberra (Australia) 2014-05-01～2014-05-01 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, University of Sydney, Sydney (Australia) 2014-04-29～2014-04-29 |
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招待講演 "Exploring potential energy surfaces with GRRM automatic search strategy, Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, University of New Castle, Canberra, ( Australia) 2014-04-28～2014-04-28 |
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| A01 山田 健一 | ||
| Original papers |
"Striking Difference between Succinimidomethyl and Phthalimidomethyl Radicals in Conjugate Addition to Alkylidenemalonate Initiated by Dimethylzinc." *Yamada, K.; Matsumoto, Y.; Fuji, S.; Konishi, T.; Yamaoka, Y.; Takasu, K. J. Org. Chem. 2016, 81 (9), pp.3809-3817. |
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"Oxa- and Azacycle-formation via Migrative Cyclization of Sulfonylalkynol and Sulfonylalkynamide with N-Heterocyclic Carbene." Wang, Y.; Oriez, R.; Kuwano, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. J. Org. Chem. 2016, 81 (6), pp.2652-2664. |
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"An Arylative Ring Expansion Cascade of Fused Cyclobutenes via Short-Lived Intermediates with Planar Chirality." Arichi, N.; Yamada, K.; Yamaoka, Y.; *Takasu, K. J. Am. Chem. Soc. 2015, 137 (30), pp.9579-9582. |
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"Asymmetric Total Synthesis of Tylophorine via a Formal [2+2] Cycloaddition Followed by Migrative Ring Opening of a Cyclobutane." *Yamaoka, Y.; Taniguchi, M.; Yamada, K.; *Takasu, K. Synthesis 2015, 47 (18), pp.2819-2825. |
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"Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric SN2′ Reaction." Kuroda, Y.; Harada, S.; Oonishi, A.; Yamaoka, Y.; *Yamada, K.; *Takasu, K. Angew. Chem. Int. Ed. 2015, 54 (28), pp.8263-8266. |
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"Cyclic Model for the Asymmetric Conjugate Addition of Organolithium with Enoate." Nishimura, K.; Fukuyama, N.; Yamashita, M.; Sumiyoshi, T.; Yamamoto, Y.; Yamada, K.; *Tomioka, K. Synthesis 2015, 47 (15), pp.2256-2264. |
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"A Short Synthesis of (+)-β-Lycorane by Asymmetric Conjugate Addition Cascade." Nishimura, K.; Fukuyama, N.; Yasuhara, T.; Yamashita, M.; Sumiyoshi, T.; Yamamoto, Y.; Yamada, K.; *Tomioka, K. Tetrahedron 2015, 71 (39), pp.7222-7226. |
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"The Development of a Brønsted Acid-promoted Arene-Ynamide Cyclization toward the Total Syntheses of Marinoquinolines A and C, and Aplidiopsamine A." *Yamaoka, Y., Yoshida, T.; Shinozaki, M.; Yamada, K.; *Takasu, K. J. Org. Chem. 2015, 80 (2), pp.957-964. |
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"Hydrostannylation-Cross-Coupling Strategy for Stereoselective Synthesis of Alkylidenemalonates and Related α,β-Unsaturated Esters." Fujiwara, S.; Romain, C.; Yamaoka, Y.; Takasu, K.; *Yamada, K. Eur. J. Org. Chem. 2015, (6), pp.1264-1272. |
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"Synthesis of Steroidal Derivatives Bearing a Small Ring Using a Catalytic [2+2] Cycloaddition and a Ring-Contraction Rearrangement." Arichi, N.; Hata, K.; Takemoto, Y.; Yamada, K.; Yamaoka, Y.; *Takasu, K. Tetrahedron 2015, 71 (2), pp.233-244. |
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"Contiguous Radical Pivaloyloxymethylation–Directed C(sp3)–H Iodination of N-Tosyl Cycloalkanecarbaldimine." Fujii, S.; Nakano, M.; Yamaoka, Y.; Takasu, K.; *Yamada, K.; Tomioka, K. Tetrahedron Lett. 2015, 56 (23), pp.3086-3089. |
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"N-Heterocyclic Carbene-Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols." Kang, B.; Sutou, T.; Wang, Y.; Kuwano, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. Adv. Synth. Catal. 2015, 357 (1), pp.131-147. |
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"Radical Aminomethylation of Imines." Fujii, S.; Konishi, T.; Matsumoto, Y.; Yamaoka, Y.; Takasu, K.; *Yamada, K. J. Org. Chem. 2014, 79 (17), pp.8128-8133. |
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| Reviews / Accounts |
"Exploration of Dimethylzinc-Mediated Radical Reactions." *Yamada, K.; Tomioka, K. Chem. Rec. 2015, 15 (5), pp.854-870. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Migrative Cyclization of Alkynylsulfones Using N-Heterocyclic Carbenes" *Yamada, K.; ○Wang, Y.; Miyakawa, Y.; Oriez, R.; Yamaoka, Y.; Takasu, K. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015) , Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Activation of the leaving group in the chiral phosphoric acid-catalyzed intramolecular asymmetric SN2’ reaction" ○*Yamada, K. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015) , Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "E/Z-selective synthesis of unsymmetric alkylidenemalonates and its applications" ○Fujiwara, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. The 9th SKO Symposium, Seoul (Korea) 2015-11-17～2015-11-18 |
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口頭発表／ポスター発表 "Organocatalytic Activation of the Leaving Group in the Asymmetric Substitution Reaction" ○Kuroda, Y.; Harada, S.; Oonishi, A.; Yamaoka, Y.; *Yamada, K.; *Takasu, K. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Total Synthesis and Structural Revision of Paesslerin A" Mogi, Y.; Yamada, K.; Yamaoka, Y.; ○*Takasu, K. Inaugural Symposium of the Phytochemical Society of Asia 2015 (ISPSA2015) TOKUSHIMA, Tokushima (Japan) 2015-08-30～2015-09-02 |
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口頭発表／ポスター発表 "Efficient Synthesis of Nitrogen-containing Medium Rings with Ynamides" ○*Yamaoka, Y.; Takeuchi, N.; Yamada, K.; *Takasu, K. The 25th ISHC Congress, Santa Barbara (USA) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "The asymmetric intramolecular SN2' reaction catalyzed by chiral phosphoric acid" ○*Yamada, K.; Kuroda, Y.; Harada, S.; Yamaoka, Y.; *Takasu, K. The 39th Naito Conference「The chemistry of organocatalysts」, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Total Synthesis of Paesslerin A" Mogi, Y.; Inanaga, K.; Ishii, T.; Tokuyama, H.; Ihara, M.; ○Yamaoka, Y.; Yamada, K.; *Takasu, K. The 39th Naito Conference「The chemistry of organocatalysts」, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "N-HETEROCYCLIC CARBENE–CATALYZED BENZOIN STRATEGY FOR DIVERGENT SYNTHESIS OF INOSITOL DERIVATIVES FROM ALDITOLS" ○Kang, B.; Sutou, T.; Yamaoka, Y.; Takasu, K.; Yamada, K.* 8th Singapore International Chemistry Conference (SICC-8) , University Town (Singapore) 2014-12-14～2014-12-17 |
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口頭発表／ポスター発表 "TOTAL SYNTHESIS OF PAESSLERIN A" ○Mogi, Y.; Inanaga, K.; Ishii, T.; Tokuyama, H.; Ihara, M.; Yamaoka, Y.; Yamada, K.; Takasu, K.* 8th Singapore International Chemistry Conference (SICC-8) , University Town (Singapore) 2014-12-14～2014-12-17 |
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口頭発表／ポスター発表 "Desymmetrization of σ-symmetric acid anhydride by a chiral phosphoric acid " Yamada, K.;* ○Oonishi, A.; Kuroda, Y.; Harada,S.; Yamaoka, Y.; Takasu, K.* The Ninth International Symposium on Integrated Synthesis（ISIS-9）, Hyogo (Japan) 2014-11-14～2014-11-15 |
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口頭発表／ポスター発表 "Efficient Synthesis of Medium Ring with Ynamides" ○Yamaoka, Y.;* Takeuchi, N.; Yamada, K.; Takasu, K. The Ninth International Symposium on Integrated Synthesis（ISIS-9）, Hyogo (Japan) 2014-12-14～2014-12-15 |
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口頭発表／ポスター発表 "Palladium-Catalyzed Arylating Ring Expansion of Fused-Cyclobutenes " ○Arichi, N.; Yamada, K.; Yamaoka, Y.; Takasu, K.* Conference on C–C Bond Cleavage (CCCC), Kyoto (Japan) 2014-10-24～2014-10-26 |
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依頼講演 "Development of synthetic methodologies utilizing N-heterocyclic carbenes" Yamada, K. Tampere University of Technology, Department of Chemistry and Bioengineering Seminar, Tampere (Finland) 2014-09-22～2014-09-22 |
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口頭発表／ポスター発表 "ENHANCED RATE AND SELECTIVITY BY CARBOXYLATE SALT AS A BASIC COCATALYST IN CHIRAL NHC-CATALYZED ASYMMETRIC ACYLATION OF SECONDARY ALCOHOLS" Yamada, K. Molecular Complexity in Modern Chemistry (MCMC-2014), Moscow (Russia) 2014-09-13～2014-09-19 |
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口頭発表／ポスター発表 "Synthesis of 2,3,4,5-tetra-substituted pyrroles via a base-promoted double Michael reaction of oxime-enoates" ○Kuroda, Y.; Imaizumi, K.; Yamada, K.; Yamaoka, Y.; Takasu, K.* 20th International Conference on Organic Synthesis , Budapest (Hungary) 2014-06-29～2014-07-04 |
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口頭発表／ポスター発表 "Synthesis of Steroid Derivatives Bearing a Small Ring for the Conformational Fixation of D-Ring Side Chain" ○Arichi, N.; Hata, K.; Yamada, K.; Yamaoka, Y.; Takasu, K.* 20th International Conference on Organic Synthesis , Budapest (Hungary) 2014-06-29～2014-07-04 |
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| A01 村井 健一 | ||
| Original papers |
"Oxidative Rearrangement via in Situ Generated N-Chloroamine: Synthesis of Fused
Tetrahydroisoquinolines" *Murai, K.; Matsuura, K.; Aoyama, H.;
Fujioka, H. Org. Lett. 2016, 18 (6), pp.1314-1317. DOI:10.1021/acs.orglett.6b00233 |
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"Organic synthesis based on the Beckmann
fragmentation: generation of an electrophilic salt intermediate and successive
C-C bond formation using Gilman reagents" *Fujioka, H.; Matsumoto, N.; Ohta, R.;
Yamakawa, M.; Shimizu, N.; Kimura, T.; Murai, K. Tetrahedron Lett. 2015, 56 (21), pp.2656-2658. DOI:10.1016/j.tetlet.2015.03.089 |
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"Enantioselective organocatalytic oxidation of ketamine" *Takizawa, S.; Kishi, K.; Abozeid, M.
A.; *Murai, K.; Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2016, 14 (2), pp.761-767. DOI:10.1039/C5OB02042E |
滝沢 忍 | |
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"Oxidative Rearrangement of Cyclobutanone Derived N,O-Ketals Leading to Pyrrolidone Derivatives" *Murai, K.; Endo, D.; Kawashita, N.; Takagi, T.; *Fujioka, H. Chem. Pharm. Bull. 2015, 63 (4), pp.245-247. DOI:10.1248/cpb.c14-00856 |
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"Enantioselective, Desymmetrizing, Bromolactonization Reactions of Symmetric Olefinic Dicarboxylic Acids" *Murai, K.; Nakajima, J.; Nakamura, A.;
Hyogo, N.; *Fujioka, H. Chem. Asian J. 2014, 9 (12), pp.3511-3517. DOI:10.1002/asia.201402865 |
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"Enantioselective iodolactonization of allenoic
acids" *Murai, K.; Shimizu, N.; *Fujioka, H. Chem. Commun. 2014, 50 (83), pp.12530-12533. DOI:10.1039/C4CC05414H |
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"C3-Symmetric chiral trisimidazoline-catalyzed Friedel-Crafts (FC)-type reaction" *Takizawa, S.u; Hirata, S.; *Murai, K.;
Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2014, 12 (31), pp.5827-5830. DOI:10.1039/C4OB00925H |
滝澤 忍 | |
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"Selective Formation of Trans/threo/cis and Cis/threo/cis Bis-tetrahydrofurans from the Same Diene Diols" *Fujioka, H.; Oki, T.; Hayashi,
T.; Yamakawa, M.; Kurachi, T.; Nakahara, K.; Maehata, R.;
Hamada, T.; Murai, K.; Kita, Y. Heterocycles 2014, 88 (2), pp.1323-1336. DOI:10.3987/COM-13-S(S)102 |
Kita, Y. | |
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"Reactivity of the ester group attached isoxazoline, benzisoxazole, and isoxazole: a facial preparation of 3-acyl-substituted these heterocycles" Murai, K.; Miyazaki, S.; *Fujioka, H. Tetrahedron Lett. 2012, 53 (29), pp.3746-3749. DOI:10.1016/j.tetlet.2012.05.006 |
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"Asymmetric total synthesis of (-)-stenine and 9a-epi-stenine" *Fujioka, H.; Nakahara, K.; Kotoku, N.; Ohba, Y.; Nagatomi, Y.; Wang, T.-L.; Sawama, Y.; Murai, K.; Hirano, K.; Oki, T.; Wakamatsu, S.; *Kita, Y. Chem. Eur. J. 2012, 18 (43), pp.13861-13870. DOI:10.1002/chem.201200376 |
北泰行 | |
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"Remarkable effect of CF3CH2OH for the halogen induced oxidative rearrangement reaction of aminals leading to 3,4-dihydroquinazolines" Murai, K.; Shimura, M.; Nagao, R.; Endo, D.; *Fujioka, H. Org. Biomol. Chem. 2013, 11 (16), pp.2648-2651. DOI:10.1039/c3ob40132d |
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"Kinetic Resolution of β-Substituted Olefinic Carboxylic Acids by Asymmetric Bromolactonization" Murai, K.; Matsushita, T.; Nakamura, A.; Hyogo, N.; Nakajima, J.; *Fujioka, H. Org. Lett. 2013, 15 (10), pp.2526-2529. DOI:10.1021/ol401007u |
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"Preparation of THP-Ester-Derived Pyridinium-Type Salts and their Reactions with Various Nucleophiles" *Fujioka, H.; Minamitsuji, Y.; Moriya, T.; Okamoto, K.; Kubo, O.; Matsushita, T.; Murai, K. Chem. Asian J. 2012, 7 (8), pp.1925-1933. |
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"Oxidative Rearrangement of Spiro Cyclobutane Cyclic Aminals: Efficient Construction of Bicyclic Amidines" Murai, K.; Komatsu, H.; Nagao, R.; *Fujioka, H. Org. Lett. 2012, 14 (3), pp.772-775. DOI:10.1021/ol203313n |
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"C3-Symmetric Trisimidazoline Catalysed Enantioselective Bromolactonization of Internal Alkenoic Acids" Murai, K.; Nakamura, A.; Matsushita, T.; Shimura, M.; *Fujioka H. Chem. Eur. J. 2012, 18 (27), pp.8448-8453. DOI:10.1002/chem.201200647 |
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| Reviews / Accounts |
"Recent Progress in Organocatalytic Asymmetric Halocyclization" Murai, K.; *Fujioka, H. Heterocycles 2013, 87 (4), pp.763-805. DOI:10.3987/REV-12-762 |
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| A01 松原 亮介 | ||
| Original papers |
"Synthesis of Furoxans (1,2,5-oxadiazole 2-oxides) from Styrenes and Nitrosonium Tetrafluoroborate in Non-Acidic Media and Mechanistic Study" *R. Matsubara, A. Ando, Y. Saeki, K. Eda, N. Asada, T. Tsutsumi, Y.-S. Shin, M. Hayashi J. Heterocyclic Chem. 2016, in press |
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"Fluorofuroxans: Synthesis and Application as Photo-induced Nitric Oxide Donors" A. Ando, *R. Matsubara, S. Takazawa, T. Shimada, M. Hayashi Asian J. Org. Chem. 2016, in press |
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"Concise Synthesis of Asymmetrically 4,5-Disubstituted 9,9-Dimethyl-9H-xanthenes" *R. Matsubara, M. Koide, Y.-S. Shin, T. Shimada, M. Hayashi Synthesis 2015, 47 pp.187-192. |
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"Revisiting the Saito Photochemical Reduction and the Development of a One-Pot Deoxygenation of Alcohols" *R. Matsubara, Y-S. Shin, T. Shimada, M. Hayashi Asian J. Org. Chem. 2014, 3 pp.1054-1057. |
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"Synthesis of Furoxans from Styrenes under Basic or Neutral Conditions" *Matsubara, R.; Saeki, Y.; Li, J.; Eda, K. Synthesis 2013, 45 (11), pp.1524-1528. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of furoxan derivatives and study on their nitric oxide-releasing ability" ○Akihiro Ando, *Ryosuke Matsubara, Saori Takazawa, Toshiyuki Shimada, Masahiko Hayashi Pacifichem (2015 International Chemical Congress of Pacific Basin Societies), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development of the organocatalyst for efficient generation of carbon-centered radical" ○Toshiyuki Shimada, *Ryosuke Matsubara, Masahiko Hayashi Pacifichem (2015 International Chemical Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-15 |
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口頭発表／ポスター発表 "Development of Carbazole-Based Photocatalyst for Alcohol Reduction" ○*R. Matsubara Tateshina Conference on Organic Chemistry, Tateshina (Japan) 2014-11-07～2014-11-09 |
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口頭発表／ポスター発表 "The Development of a Direct Deoxygenation of Alcohols" *Ryosuke Matsubara, ○Toshiyuki Shimada, Yong-Soon Shin, Masahiko Hayashi 第2回 国際会議(兼)第7回 有機触媒シンポジウム, 東京 (日本) 2014-11-21～2014-11-21 |
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口頭発表／ポスター発表 "Study toward Photocatalytic One-Step Reduction of Alcohol" ○*Matsubara, R.; Shin, Y.-S. 12th Tateshina Conference, Tateshina (Japan) 2012-11-09～2012-11-11 |
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招待講演 "Study toward Photocatalytic One-Step Reduction of Alcohol" ○*Matsubara, R. Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-19 |
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| Prize |
"井上リサーチアウォード" Ryosuke Matsubara 2014-02 井上科学振興財団 外部刺激に応答して一酸化窒素を放出するフロキサン化合物の創製 |
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"２０１２年度有機合成化学協会研究企画賞" *Matsubara, R. 2012-12 有機合成化学協会 光エネルギーを用いる有機分子触媒的アルコール還元反応への挑戦 |
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| A01 坂倉 彰 | ||
| Original papers |
"Enantioselective Bromocyclization of 2-Gernaylphenols Induced by Chiral Phosphite-Urea Bifunctional Catalysts" Sawamura, Y.; Ogura, Y.; H.; Nakatsuji, H.; *Sakakura, A.; *Ishihara, K. Chem. Commun. 2016, 52 (36), pp.6068-6071. DOI:10.1039/C6CC00229C |
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"Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Imines with Propioloylpyrazoles Induced by Chiral π−Cation Catalysts" Hori, M.; *Sakakura, A.; *Ishihara, K. J. Am. Chem. Soc. 2014, 136 (38), pp.13198-13201. DOI:10.1021/ja508441t |
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"Cooperative Activation with Chiral Nucleophilic Catalysts and N-Haloimides: Enantioselective Iodolactonization of 4-Arylmethyl-4-pentenoic Acids" Nakatsuji, H.; Sawamura, Y.; *Sakakura, A.: *Ishihara, K. Angew. Chem. Int. Ed. 2014, 53 (27), pp.6974-6977. DOI:10.1002/anie.201400946 |
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"Catalytic Enantioselective Inverse Electron Demand Hetero-Diels–Alder Reaction with Allylsilanes" Matsumura, Y.; Suzuki, T.; *Sakakura, A.; *Ishihara, K. Angew. Chem. Int. Ed. 2014, 53 (24), pp.6131-6134. DOI:10.1002/anie.201402934 |
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| Reviews / Accounts |
"Stereoselective Electrophilic Cyclization" *Sakakura, A.; *Ishihara, K Chem. Rec. 2015, DOI:10.1002/tcr.201500005 |
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| Conference / Symposium / Lecture |
招待講演 "Synthetic studies of manzacidins A-C based on diastereoselective hydroxymethylation of chiral nitro compounds" ○*Sakakura, A.; Miyoshi, N.; Kudoh, T. The 2015 International Chemical Congress of Pacific Basin Societies (PAC CHEM™, Pacifichem 2015), Honolulu, Hawaii (USA) 2015-12-15～2015-12-20 |
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招待講演 "A Short Entry to 3,5-Disubstituted Piperazinones Based on Aza-Michael Addition of α-Amino Esters to Nitroalkenes" ○*Sakakura, A.; Kudoh, T.; Isoyama, S.; Kagimoto, S. The 10th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-10), KaoHsiung (Taiwan) 2015-11-02～2015-11-05 |
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| A01 今田 泰嗣 | ||
| Original papers |
"Controlled Physical Gelation of Thermoresponsive Poly(2-propionamidoacrylic acid) Aqueous Solution" *Minagawa, K.; Shiizaki, G.; Arakawa, Y.; Imada, Y.; Tanaka, M. Adv. Mater. Res. 2015, 1110 pp.96-99. |
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"Biomimetic flavin-catalysed reactions for organic synthesis" Iida, H.; Imada, Y.; *Murahashi, S.-I. Org. Biomol. Chem. 2015, 15 (28), pp.7599-7613. DOI:10.1039/C5OB00854A |
飯田拡基 | |
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"Highly Fluorescent Flavins: Rational Molecular Design forQuenching Protection Based on Repulsive and Attractive Controlof Molecular Alignment" Suzuki, H.; Inoue, R.; Kawamorita, S.; Komiya, N.; Imada, Y.; *Naota, T Chem. Eur. J. 2015, 21 (25), pp.9171-9178. DOI:10.1002/chem.201406346 |
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"Flavin-Functionalized Gold Nanoparticles as an Efficient Catalyst for Aerobic Organic Transformations" Imada, Y.; Osaki, M.; Noguchi, M.; Maeda, T.; Fujiki, M.; Kawamorita, S.; Komiya, N.; *Naota, T ChemCatChem 2015, 7 (1), pp.99-106. DOI:0.1002/cctc.201402619 |
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"Ring-expanding Metathesis Oligomerization of Cyclic Nitrones" Imada, Y.; Okita, C.; Maeda, H.; Kishimoto, M.; Sugano, Y.; Kaneshiro, M.; Nishida, Y.; Kawamorita, S.; Komiya, N.; *Naota, T. Eur. J. Org. Chem. 2014, 2014 (26), pp.5670-5674. DOI:10.1002/ejoc.201402859 |
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"Oxidation of sulfides with hydrogen peroxide catalyzed by synthetic flavin adducts with dendritic bis(acylamino)pyridines" *Imada, Y.; Kitagawa, T.; Iwata, S.; Komiya, N.; *Naota, T. Tetrahedron 2014, 70 (2), pp.495-501. DOI:10.1016/j.tet.2013.11.024 |
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"Non-Covalently Dendronized Flavins as Organocatalysts for Aerobic Reduction of Olefins" Imada, Y.; Kugimiya, Y.; Iwata, S.; Komiya, N.; *Naota, T. Tetrahedron 2013, 69 (40), pp.8572-8578. DOI:10.1016/j.tet.2013.07.082 |
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"Aerobic Oxidation of Sulfides with Vitamin B2-derived Organocatalyst" *Imada, Y.; Tonomura, I.; Komiya, N.; *Naota, T. Synlett 2013, 24 (13), pp.1679-1682. DOI:10.1055/s-0033-1339276 |
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"Oxidation of Sulfides with Hydrogen Peroxide Catalyzed by Vitamin B2 Derivatives" *Imada, Y.; Takagishi M.; Komiya, N.; *Naota, T. Synth. Commun. 2013, 43 (22), pp.3064-3071. DOI:10.1080/00397911.2013.767912 |
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"Flavin-catalyzed aerobic oxidation of sulfides in aqueous media" *Imada, Y.; Kitagawa, T.; Wang, H.-K.; Komiya, N; *Naota, T. Tetrahedron Lett. 2013, 54 (7), pp.621-624. DOI:j.tetlet.2012.11.133 |
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| Reviews / Accounts |
"フラビン触媒を用いた酸素酸化システムの開発" *今田泰嗣 化学と工業 2014, 67 (6), pp.480-482. |
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| Conference / Symposium / Lecture |
招待講演 "Organocatalytic Oxidations Catalyzed by Non-covalently Dendronized Flavins" ○*Imada, Y. Advanved Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Flavin-catalyzed photoinduced thioacetalization of aldehydes" ○Arakawa, Y.; Mihara, T.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Visible light-induced α-oxyamination of aldehydes with flavin organocatalysts" ○Tagami, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Facile preparation of flavinium organocatalysts utilizing cation-exchange resins" ○Oonishi, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Nucleophilic addition to nitrones using flow microreactors" ○Arakawa, Y.; Ueta, S.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Flavin Catalyzed α-oxyamination of Aldehydes under Visible Light Irradiation" ○Tagami, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of Facile Method for Preparing Flavinium Organocatalysts" ○Oonishi, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Analysis of Interaction between Diphenhydramine and Human Serum Albumin" Tanaka, M.; ○*Minagawa, K.; Arakawa, Y.; Imada, Y. Asia-Pacific Conference on Engineering & Applied Sciences (APCEAS2015), Osaka (Japan) 2015-08-25～2015-08-27 |
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口頭発表／ポスター発表 "Design of Effective Chemistry Laboratory Class Based on Partnership among High School, University and Graduate School" *○Minagawa, K.; Yasuzawa, M.; Arakawa, Y.; Imada, Y.; Fujita, S. Asia-Pacific Conference on Engineering & Applied Sciences (APCEAS2015), Osaka (Japan) 2015-08-25～2015-08-27 |
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口頭発表／ポスター発表 "Novel preparation method of flavinium organocatalysts" ○Arakawa, Y.; Oonishi, T.; Kohda, T.; Minagawa, K.; *Imada, Y. The 39th Naito Conference on The Chemistry of Organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Flavin Catalysts Captured in Network Polymers" ○Sato, F.; Arakawa, Y.; Minagawa, K.; *Imada, Y. Advanced Molecular Transformations by Organocatalysts 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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| Patent |
"ジエポキシ化合物の製造方法" 発明者：北尾久平; 今田泰嗣; 荒川幸弘 出願者：株式会社ダイセル; 徳島大学 特願2015-079601 2015-04-08, 2016-05, (国内) |
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| Media |
"Flavin-Functionalized Gold Nanoparticles as an Efficient Catalyst for Aerobic Organic Transformations" Imada, Y.; Osaki, M.; Noguchi, M.; Maeda, T.; Fujiki, M.; Kawamorita, S.; Komiya, N.; Naota, T. ChemCatChem 2015-01-07 ChemCatChem誌、2015年、第7巻、第1号のカバーピクチャーに選出された |
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| A01 白川 誠司 | ||
| Original papers |
"Catalytic asymmetric synthesis of axially chiral 2-amino-1,1'-biaryl compounds by phase-transfer-catalyzed kinetic resolution and desymmetrization" Shirakawa, S.; Wu, X.; Liu, S.; *Maruoka, K. Tetrahedron 2015, in press DOI:doi:10.1016/j.tet.2015.10.074 |
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"Tetraalkylammonium Salts as Hydrogen-Bonding Catalysts " *Shirakawa, S.; Liu, S.; Kaneko, S.; Kumatabara, Y.; Fukuda, A.; Omagari, Y.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (52), pp.15767-15770. DOI:DOI: 10.1002/anie.201508659 |
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"
Phase-Transfer-Catalyzed Asymmetric Desymmetrizations
of Cyclopentanones " Shirakawa, S.; Tokuda, T.; Kan, S. B. J.; *Maruoka, K Org. Chem. Front. 2015, 2 (4), pp.336-339. DOI:10.1039/C4QO00339J |
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"
Phase-Transfer-Catalyzed Asymmetric SNAr Reaction
of α-Amino Acid Derivatives with Arene Chromium Complexes " Shirakawa, S.; Yamamoto, K.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (3), pp.838-840. DOI:10.1002/anie.201409065 |
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"
Effect of Brønsted acid co-catalyst in asymmetric
conjugate addition of 3-aryloxindoles to maleimide under base-free
phase-transfer conditions " Shirakawa, S.; Makino, H.; Yoshidome, T.; *Maruoka, K. Tetrahedron 2014, 70 (40), pp.7128-7132. DOI:10.1016/j.tet.2014.06.017 |
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"
Efficient Asymmetric Synthesis of Spiro-2(3H)-furanones via Phase-Transfer-Catalyzed Alkynylation " Wu, X.; Shirakawa, S.; *Maruoka, K.Org. Biomol. Chem. 2014, 12 (29), pp.5388-5392. DOI:10.1039/c4ob00969j |
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"
Catalytic Asymmetric Synthesis of
3,3’-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary
Center: Phase-Transfer-Catalyzed SNAr Reaction " Shirakawa, S.; Koga, K.; Tokuda, T.; Yamamoto, K.; *Maruoka, K. Angew. Chem. Int. Ed. 2014, 53 (24), pp.6220-6223. DOI:10.1002/anie.201403046 |
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"
A Base-Free Neutral Phase-Transfer Reaction System " Shirakawa, S.; Wang, L.; He, R.; Arimitsu, S.; *Maruoka, K.Chem. Asian J. 2014, 9 (6), pp.1586-1593. DOI:10.1002/asia.201402194 |
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"
Phase-Transfer-Catalyzed Asymmetric α-Arylation of
α-Amino Acid Derivatives " Shirakawa, S.; Yamamoto, K.; Tokuda, T.; *Maruoka, K. Asian J. Org. Chem. 2014, 3 (4), pp.433-436. DOI:10.1002/ajoc.201400004 |
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| Reviews / Accounts |
"A new generation of chiral phase-transfer catalysts" Kaneko, S.; Kumatabara, Y.; *Shirakawa, S. Org. Biomol. Chem. 2016, in press DOI:DOI: 10.1039/C5OB02446C |
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"Chiral quaternary phosphonium salts as phase-transfer catalysts for environmentally benign asymmetric transformations" Liu, S.; Kumatabara, Y.; *Shirakawa, S. Green Chem. 2016, 18 (2), pp.331-341. DOI:DOI: 10.1039/C5GC02692J |
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"
Organocatalyzed Asymmetric Synthesis of Axially,
Planar, and Helical Chiral Compounds " *Shirakawa, S.; Liu, S.; Kaneko, S. Chem. Asian J. 2016, 11 (3), pp.330-341. DOI:DOI: 10.1002/asai.201500951 |
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"塩基を必要としない中性相間移動反応系の発見と展開" *白川誠司 有機合成化学協会誌 2014, 72 (12), pp.1374-1383. DOI:http://dx.doi.org/10.5059/yukigoseikyokaishi.72.1374 |
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"
Asymmetric Phase-Transfer Reactions under Base-Free Neutral Conditions " Shirakawa, S.; *Maruoka, K.Tetrahedron Lett. 2014, 55 (29), pp.3833-3839. DOI:http://dx.doi.org/10.1016/j.tetlet.2014.05.014 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Phase-Transfer-Catalyzed Asymmetric SNAr Reactions" *○Shirakawa, S. The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Base-Free Neutral Phase-Transfer Reaction System" *○Shirakawa, S. Sino-Japan International Exchange and Cooperation Forum on Organic Chemistry, Guangdong (China) 2015-11-27～2015-11-27 |
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招待講演 "
Discovery and Evolution of Base-Free Neutral
Phase-Transfer Reaction System " ○*Shirakawa, S. 2nd International Symposium on Catalysis Toward Green Sustainable Chemistry (CAT-GSC-2), Tokyo (Japan) 2015-03-30～2015-03-30 |
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招待講演 "
Efficient Approach for the Design of Effective Chiral Quaternary Phosphonium Bromides in Asymmetric Reactions " ○*Shirakawa, S2nd International Symposium on Integrated Science for Molecular Chirality in Biology and Chemistry, Kumamoto (Japan) 2014-11-30～2014-12-01 |
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招待講演 "
Development of Chiral Bifunctional Quaternary Phosphonium Bromides for Asymmetric Phase-Transfer Reactions " ○*Shirakawa, SAdvanced Molecular Transformations by Organocatalysts 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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| Prize |
"
長瀬研究振興賞 " *白川誠司 2015-04 公益財団法人 長瀬科学技術振興財団環境調和型精密有機合成を指向したキラル中性塩触媒反応系の構築 |
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"有機合成化学協会 三井化学研究企画賞" *白川誠司 2015-02 有機合成化学協会 不斉ラジカル反応およびルイス酸触媒反応のためのキラルゲルマニウム触媒の創製 |
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| A01 田中 富士枝 | ||
| Original papers |
"Catalytic asymmetric hetero-Diels-Alder reactions of enones with isatins to access functionalized spirooxindole tetrahydropyrans: Scope, derivatization, and discovery of bioactives." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; *Tanaka, F. Org. Biomol. Chem. 2016, 14 pp.1777-1783. DOI:10.1039/c5ob02393a |
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"Direct synthesis of C-glycosides from unprotected 2-N-acyl-aldohexoses via aldol condensation-oxa-Michael reactions with unactivated ketones." Johnson, S.; *Tanaka, F. Org. Biomol. Chem. 2016, 14 pp.259-264. DOI:10.1039/c5ob02094h |
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"Reaction-based mechanistic investigations of asymmetric hetero-Diels-Alder reactions of enones with isatins catalyzed by amine-based three-component catalyst systems." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; *Tanaka, F. Asian J. Org. Chem. 2016, 5 pp.153-161. DOI:10.1002/ajoc.201500412 |
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"Aldol reactions of ketone donors with aryl trifluoromethyl ketone acceptors catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) for concise access to aryl- and trifluoromethyl-substituted tertiary alcohols." Zhang, D.; *Tanaka, F. Adv. Synth. Catal. 2015, 357 pp.3458-3462. DOI:10.1002/adsc.201500497 |
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"Aldol reactions of 1,2-diketones catalyzed by amines to afford furanose derivatives" Jithender, E.; Katsuyama, I.; Zhang, D.; Johnson, S.; *Tanaka, F. Tetrahedron Lett. 2015, 56 pp.735-738. DOI:10.1016/j.tetlet.2014.12.094 |
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"Reactions of pyruvates: organocatalytic synthesis of functionalized dihydropyrans in one pot and further transformations to functionalized carbocycles and heterocycles" Chouthaiwale, P. V.; *Tanaka, F. Chem. Commun. 2014, 50 pp.14881-14884. DOI:110.1002/c4cc06035k |
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"One-pot synthesis of polysubstituted 3-acylpyrroles by cooperative catalysis" Cui, H.-L.; *Tanaka, F. Org. Biomol. Chem. 2014, 12 pp.5822-5826. DOI:110.1002/c4ob01019a |
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"Synthesis of furanose spirooxindoles via 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed aldol reactions of a pyruvic aldehyde derivative" Zhang, D.; Johnson, S.; Cui, H.-L.; *Tanaka, F. Asian J. Org. Chem. 2014, 3 pp.391-394. DOI:10.1002/ajoc.201400016 |
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"Fluorogenic probes for aldol reactions: Tuning of fluorescence using π-conjugation systems" Katsuyama, I.; Chouthaiwale, P. V.; Akama, H.; Cui, H.-L.; *Tanaka, F. Tetrahedron Lett. 2014, 55 (1), pp.74-78. DOI:10.1016/j.tetlet.2013.10.122 |
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"Catalytic enantioselective formal hetero-Diels-Alder reactions of enones with isatins to give spirooxindole tetrahydropyranones" Cui, H.-L.; *Tanaka, F. Chem. Eur. J. 2013, 19 (20), pp.6213-6216. DOI:10.1002/chem.201300595 |
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"Substituent-dependent reactivity in aldehyde transformations: 4-(phenylethynyl)benzaldehydes versus simple benzaldehydes
" Katsuyama, I.; Chouthaiwale, P. V.; Cui, H.-L.; Ito, Y.; Sando, A.; Tokiwa, H.; *Tanaka, F. Tetrahedron 2013, 69 (20), pp.4098-4104. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of iminosugar C-glycosides via a Mannich reaction-aminocyclization route" ○Maram, L.; *Tanaka, F. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Catalytic enantioselective hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones to give trifluoromethyl-substituted tetrahydropyranones" ○Zhang, D.; *Tanaka, F. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Construction of aryl- and trifluoromethyl-substituted tertiary alcohols via aldol reactions catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)" ○Zhang, D.; *Tanaka, F. ISACS19: Challenges in Organic Chemistry, Irvine (USA) 2016-03-20～2016-03-23 |
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口頭発表／ポスター発表 "DBU-catalyzed regioselective aldol reactions to synthesize functionalized molecules with tetrasubstituted carbon centers" ○Zhang, D.; *Tanaka, F. The 38th Naito Conference The Chemistry of Organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "β-Proline-catalyzed reactions of pyruvates to synthesize functionalized molecules" ○Chouthaiwale, P. V.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Synthesis of spirooxindole furanose derivatives via DBU-catalyzed aldol reactions" ○Zhang, D.; Johnson, S.; Cui, H.; *Tanaka, F. The 14th Belgian Organic Synthesis Symposium, Louvain-la-Neuve (Belgium) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Asymmetric formal oxa-Diels Alder reaction catalyzed by amine-based catalysts affording functionalized spirooxindole tetrahydropyrans" ○Cui, H.-L.; *Tanaka, F. The 14th Belgian Organic Synthesis Symposium, Louvain-la-Neuve (Belgium) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Catalytic enantioselective formal hetero-Diels-Alder reactions of enoneswith isatins to give spirooxindole tetrahydropyranones" ○Cui, H.-L.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Amino acid-catalyzed reactions of pyruvates: One-pot aldol condensation-Michael addition-cyclization sequence" ○Chouthaiwale, P. V.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Amine-catalyzed asymmetric construction of quaternary carbon centers" ○Cui, H.-L.; *Tanaka, F. The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Amino acid-catalyzed reactions of pyruvates: One-pot aldol condensation-Michael addition-cyclization sequence" ○Chouthaiwale, P. V.; *Tanaka, F. The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Enamine-based catalysis: Synthesis of amino acids and sugars" ○*Tanaka, F. The Second Asian Chemical Biology Conference (ACBC2012), Okinawa (Japan) 2012-07-04～2012-07-06 |
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| Patent |
"4-Substituted pyridine-2,6-dicarboxylic acid derivatives and method of preparing same" 発明者：Chouthaiwale, P. V.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2015/004588 2015-09-09, Publication No. WO 2016038890 A1（特許出願中） 2016-03, (国外) |
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"Process for producing dihydro-2H-pyran derivatives" 発明者：Chouthaiwale, P. V.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2013/0784249 2013-10-10, Publication No. WO 2014/058078 A1 （特許出願中） 2014-04, (国外) |
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"Novel spirooxindole derivative and process for producing the same" 発明者：Cui, H.-L.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2013/077682 2013-10-04, Publication No. WO 2014/058035 A1; US Patent No. 9,309,261 2016-04-12, (国外) |
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| Media |
"Inside Cover: Reaction-based mechanistic investigations of asymmetric hetero-Diels-Alder reactions of enones with isatins catalyzed by amine-based three-component catalyst systems." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; Tanaka, F. Asian Journal of Organic Chemistry 2015-12-12 論文 Asian Journal of Organic Chemistry, 5, 153-161 (2016), doi: 10.1002/ajoc.201500412 についての Inside Cover. Asian Journal of Organic Chemistry, 5, 2 (2016), doi: 10.1002/ajoc.201500503. |
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| A01 吉田 雅紀 | ||
| Original papers |
"Organocatalytic asymmetric Michael addition of α-branched aldehydes to vinyl ketones: synthesis of 5-ketoaldehydes possessing a stereo-controlled all-carbon quaternary stereogenic center" *Yoshida, M.; Ukigai, H.; Shibatomi, K.; Hara, S. Tetrahedron Lett. 2015, DOI:10.1016/j.tetlet.2015.04.107 |
柴富一孝 |
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"第一級アミノ酸およびその塩を用いた触媒的不斉合成" *吉田雅紀 有機合成化学協会誌 2014, 72 (8), pp.876-889. DOI:10.5059/yukigoseikyokaishi.72.876 |
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"Asymmetric Michael Addition of β-Ketoesters to Enones Catalyzed by a Primary β-Amino Acid Lithium Salt" *Yoshida, M.; Kubara, A.; Nagasawa, Y.; Hara, S.; Yamanaka, M. Asian J. Org. Chem. 2014, 3 pp.523-529. DOI:10.1002/ajoc.201400024 |
山中正浩 | |
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"Asymmetric α-Allylation of α-Branched Aldehydes with Allyl Alcohols by Synergistic Catalysis Using an Achiral Pd Complex and a Chiral Primary Amino Acid" *Yoshida, M.; Masaki, E.; Terumine, T.; Hara, S. Synthesis 2014, 46 pp.1367-1373. DOI:10.1055/s-0033-1340901 |
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"Direct Asymmetric α-Allylation of α-Branched Aldehydes by Two Catalytic Systems with an Achiral Pd Complex and a Chiral Primary α-Amino Acid" *Yoshida, M.; Terumine, T.; Masaki, E.; Hara, S. J. Org. Chem. 2013, 78 (21), pp.10853-10859. DOI:10.1021/jo4018414 |
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"Mechanistic study of asymmetric Michael addition of malonates to enones catalyzed by a primary amino acid lithium salt" *Yoshida, M.; Nagasawa, Y.; Kubara, A.; Hara, S.; *Yamanaka, M. Tetrahedron 2013, 69 (47), pp.10003-10008. DOI:10.1016/j.tet.2013.09.066 |
山中正浩（立教大学） | |
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"Primary β-Amino Acid Salt-catalyzed Asymmetric Michael Addition of Benzoylacetates to Cyclic Enones and Its Application for the Synthesis of Enantioenriched 1,5-Diketones" *Yoshida, M.; Kubara, A.; Hara, S. Chem. Lett. 2013, 42 (2), pp.180-182. DOI:10.1246/cl.2013.180 |
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"Enantioselective synthesis of gabapentin analogues via organocatalyticasymmetric Michael addition of α-branched aldehydes to β-nitroacrylates" *Yoshida, M.; Masaki, E.; Ikehara, H.; Hara, S. Org. Biomol. Chem. 2012, 10 (27), pp.5289-5298. DOI:10.1039/c2ob25413a |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Mechanistic Study of Primary β-Amino Acid Salt-Catalyzed Asymmetric Michael Addition to Enones" ○*Yoshida, M.; Kubara, A.; Hara, S. 文部科学省科学研究費補助金「新学術領域研究（研究領域提案型）」（平成23～27年度）「有機分子触媒による未来型分子変換」第1回 国際会議（兼）第6回 有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Stereoselective Construction of a Quaternary Carbon Center by a Primary Amino Acid-Catalyzed Asymmetric α-Allylation of Aldehydes" ○*Yoshida, M.; Terumine, T.; Hara, S. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 仙台 (日本) 2013-04-19～2013-04-20 |
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招待講演 "Organocatalytic Tandem Reaction for the Asymmetric Synthesis of γ-Nitroaldehydes" ○*Yoshida, M.; Kitamikado, N.; Ikehara, H.; Hara, S. Cambodian Malaysian Chemical Conference (CMCC) 2012, Siem Reap (Cambodia) 2012-10-19～2012-10-21 |
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招待講演 "Enantioselective Synthesis of 4,4-Disubstituted Pyrrolidine-3-carboxylic Acids via Organocatalytic Michael Addition of α-Branched Aldehydes to β-Nitroacrylates" ○*Yoshida, M.; Masaki, E.; Ikehara, H.; Hara, S. 17th Malaysian Chemical Congress (17MCC), Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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| Prize |
"日本化学会北海道支部奨励賞" *吉田雅紀 2013-01 日本化学会北海道支部 第一級アミノ酸およびその塩を利用する不斉有機触媒反応の開発 |
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| A01 植田 光洋 | ||
| Original papers |
"
Intramolecular Carbolithiation of 3-Lithioxy-5-Alkenyllithiums
as a Platform for Cyclopentanols and Cyclopentanones
" *Ryu, I.; Yamamura, G.; Minakata, S.; Komatsu, M.; Kubo, H.; Ueda, M. Synlett 2015, 26 pp.2413-2417. |
南方 聖司（大阪大学） |
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"A Construction of 4,4-Spirocyclic γ-Lactams by Tandem Radical Cyclization with Carbon Monoxide" Ueda, M.; Uenoyama, Y.; Terasoma, N.; Doi, S.; Kobayashi, S.; *Ryu, I.; *Murphy, J. A. Beilstein J. Org. Chem. 2013, 9 pp.1340-1345. |
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"Transition-Metal-Free Suzuki-Miyaura Coupling Reaction of Arylpropargylic Bromides with Aryl- and Alkenylboronic Acids" *Ueda, M.; Nishimura, K.; *Ryu, I. Synlett 2013, 24 pp.1683-1686. |
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"A Transition-Metal-Free Cross-Coupling Reaction of Allylic Bromides with Aryl- and Vinylboronic Acids" *Ueda, M.; Nishimura, K.; Kashima, R.; *Ryu, I. Synlett 2012, 23 pp.1085-1089. DOI:10.1055/s-0031-1290656 |
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| Books |
「
化学
」 "注目の論文：不斉ラジカル反応の真の触媒登場" Ueda, M. 化学同人 2015, pp64-65. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Ammonium Chiral Borate Salt Catalyzed Friedel-Crafts Alkylation of Indoles with α,β-Disubstituted Acroleins" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. ISIS-9, Hyogo (Japan) 2014-11-14～2014-11-15 |
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口頭発表／ポスター発表 "Asymmetric Reaction Catalyzed by Ammonium Chiral Borate Salt" ◯Yagyu, Y.; *Uead, M.; Ryu, I. Advanced Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Development of new ion-pairing catalyst based on chiral borate anion" ◯*Ueda, M. The 39th Naito conference on the chemistry of organocatalysts,, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Cyclic Ketone Synthesis by Intramolecular Acylation of Organocobalt with Esters" ◯Ueno, T.; Suyama, Y.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "[2+2] Cycloaddition of aromatic allenes with C60" ◯*Ueda, M.; Sakaguchi, T.; Yoshida, S.; Yasuda, H.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "[2+2] Cycloaddition of coumarin derivatives with fullerene under photo-irradiated conditions" ◯Hayama, M.; *Ueda, M.; Yasuda, H.; Yoshida, S.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis of 1,4-Enynes by Catalyst-Free Coupling Reaction of Alkenylboronic Acids with Secondary Propargylic Acetates" ◯Nakakoji, D.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Friedel-Crafts Alkylation between Indoles and α,β-Disubstituted Acroleins Catalyzed by Chiral Borate Salt" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "The Reaction of Organoboronic Acids with Activated Alkyl Halides" ○*Ueda, M.; Nishimura, K.; Nakakoji, D.; Ryu, I. 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2015-09-26 |
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口頭発表／ポスター発表 "
Asymmetric Reaction Catalyzed
by Ammonium Chiral Borate Salt
" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. 第２回国際会議（兼）第７回有機触媒シンポジウム, 東京都 (日本) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "
Ammonium Chiral Borate Salt
Catalyzed Friedel-Crafts Alkylation of Indoles with α,β-Disubstituted Acroleins
" ◯Yagyu, Y.; *Ueda, M.; Ryu, Ilhyong The Ninth International Symposium on Integrated Synthesis, 淡路市 (日本) 2014-11-14～2015-11-15 |
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招待講演 "Radical Cyclization by Using Photo-Organocatalyst" ◯*Ueda, M. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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| Patent |
"
フラーレン誘導体およびフラーレン誘導体の製造方法
" 発明者：Yasuda, H.; Watanabe, K.; Ryu, I.; Ueda, M. 特願 2014-046930 2014-07-12, 2014-07, (国内) |
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| A01 御前 智則 | ||
| Original papers |
"Organocatalytic 1,4-addition reaction of
2-formyl(thio)esters to vinylketones: an efficient access to acyclic chiral building
blocks with a quaternary carbon stereocenter" Tatsumi, T.; *Misaki, T.; Sugimura, T. Chem. Eur. J. 2015, 21 pp.18971-18974. DOI:10.1002/chem.201504479 |
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"Highly enantioselective and diastereoselective
conjugate addition of 5H-oxazol-4-ones
to 2-chloroacrylonitrile catalyzed by chiral guanidines" *Misaki, T.; Choi, N.-R.; Morita, A.; Sugimura, T. Tetrahedron Lett. 2015, 56 pp.5063-5066. DOI:10.1016/j.tetlet.2015.07.063 |
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"Another role of copper in the Simmons–Smith reaction: copper-catalyzed nucleophilic Michael-type cyclopropanation of α,β-unsaturated ketones" Fujii, K.; Misaki, T.; *Sugimura, T. Chem. Lett. 2014, 43 (5), pp.634-636. DOI:10.1246/cl.131193 |
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"Substrate dependent ligand acceleration in enantioselective hydrogenation of (E)-2,3-diarylpropenoic acid on cinchonidine-modified Pd/C" Mameda, T.; Nakai, K.; Misaki. T.; Okamoto, Y.; *Sugimura, T. Catalysis Today 2015, 245 pp.129-133. DOI:10.1016/j.cattod.2014.03.075 |
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"Kinetic and stereochemical analyses of amine-additive effects on the hydrogenation of α-phenylcinnamic acid over cinchonidine-modified Pd/C" Nakai, K.; Misaki, T.; Okamoto, Y.; *Sugimura, T. Bull. Chem. Soc. Jpn 2015, 88 (2), pp.300-302. DOI:10.1246/bcsj.20140292 |
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"Induction period for the enantioselective hydrogenation of α,β-unsaturated acids over a cinchonidine-modified palladium catalyst" Mameda, T.; Misaki, T.; Okamoto, Y.; *Sugimura, T. React. Kinet., Mech. cat. 2015, 114 (1), pp.55-61. DOI:10.1007/s11144-014-0769-0 |
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"1,4-Addition reaction of 5H-oxazol-4-ones to vinyl ketones catalyzed by chiral guanidines" Morita, A.; *Misaki, T.; *Sugimura, T. Tetrahedron Lett. 2015, 56 pp.264-267. DOI:10.1016/j.tetlet.2014.11.079 |
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"1,6-Addition reaction of 5H-oxazol-4-ones to conjugated dienones catalyzed by chiral guanidines" Morita, A.; *Misaki, T.; *Sugimura, T. Chem. Lett. 2014, 43 pp.1826-1828. DOI:10.1246/cl.140713 |
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"Asymmetric Ti-crossed Claisen condensation: application to concise asymmetric total synthesis of alternaric acid" Nagase, R.; Oguni, Y.; Ureshino, S.; Mura, H.; *Misaki, T.; *Tanabe, Y Chem. Commun. 2013, 49 pp.7001-7003. DOI:10.1039/c3cc43180k |
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"1,4-Addition Reaction of 5H-Oxazol-4-ones to Allnic Esters and Ketones Catalyzed by Chiral Guanidines" Jin, N.; *Misaki, T.; *Sugimura, T. Chem. Lett. 2013, 42 (8), pp.894-896. DOI:10.1246/cl.130295 |
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"Anomalous Ligand Acceleration on Cinchona-Modified Pd/C During Asymmetric Hydrogenation of Properly Substituted Phenylcinnamic Acid" Ogawa, H.; Mameda, T.; Misaki, T.; Okamoto, Y.; *Sugimura, T. Chem. Lett. 2013, 42 (8), pp.813-815. DOI:10.1246/cl.130245 |
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"Stereochemical Study on Oxygen-Directed Olefin Oxidation and Subsequent Oxygen Cyclization; Difference between Peracid and Metal Oxide-Catalyzed Hydroperoxide in Oxidation" Inoue, A.; Misaki, T.; Fujita, M.; Okuyama, T.; *Sugimura, T. Tetrahedron: Asymmetry 2013, 24 (13-14), pp.833-837. |
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"Hydrogenation of 5-Alkylidene-2,4-Thiazolidiones on Pd/C Catalysts Under Mild Conditions: An Alternative Synthesis Route to Pioglitazone" *Sugimura, T.; Oie, K.; Misaki, T.; Okamoto, Y.; Tanaka, K.; Mori, H. Catal. Lett. 2013, 143 (5), pp.495-500. DOI:10.1007/s10562-013-0976-8 |
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"Mitsunobu Reaction with 4-(Diphenylphosphino)benzoic Acid: A Separation-Friendly Bifunctional Reagent that Serves as Both a Reductant and a Pronucleophile" Muramoto, N.; Yoshino, K.; Misaki, T.; *Sugimura, T. Synthesis 2013, 45 (7), pp.931-935. DOI:10.1055/s-0032-1318327 |
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"Chiral Guanidine-Catalyzed 1,4-Addition Reaction of 5H-Oxazol-4-ones to Alkynones" *Misaki, T.;Jin, N.; Kawano, K.; *Sugimura, T. Chem. Lett. 2012, 41 (12), pp.1675-1677. DOI:10.1246/cl.2012.1675 |
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"Efficient Simmons-Smith Cyclopropanation with Zn/Cu and CH2I2" Fujii, K.; Shiine, K.; Misaki, T.; *Sugimura, T. Applied Organometallic Chemistry 2013, 27 (2), pp.69-72. |
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"Preparation of Pd/C Designed for Chiral Modified Catalyst: Comparison with Pd/TiO2 in Enantioselective Hydrogenation of α-Phenylcinnamic Acid" Kubota, T.; Ogawa, H.; Okamoto, Y.; Misaki, T.; *Sugimura, T. Applied Catalysis A: General 2012, 437-438 (26 September), pp.18-23. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Development of C-C bond forming reaction involving
chiral quaternary carbon atom construction using bifunctional organocatalysts" ○*Misaki, T. 2015 International Chemical Congress of Pacific Basin Societies, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development and applycation of conjugate addition of
β-carbonylesters to vinyl ketones involving a chiral quaternary carbon atom
construction catalyzed by organocatalysts" ○Tatumi, T.; *Misaki, T.; Sugimura, T. The 39th Naito conference on the chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Development of Conjugate Additions to Vinylketones and Dienones Using Chiral Guanidine Catalyst Bearing a Hydroxy Group" ○Morita, A.; *Misaki, T.; *Sugimura, T. Advanced Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Asymmetric C-C Bond Forming Reactions of 5H-Oxazol-4-ones Catalyzed by Hydroxy Group Combined Guanidines" ○*Misaki, T. 第1回 国際会議（兼）第6回 有機触媒シンポジウム, Otsu (Japan) 2013-05-27～2013-05-28 |
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|
招待講演 "Catalytic Enantioselective C-C Bond Forming Reactions of 5H-Oxazol-4-ones Using New Chiral Guanidines" ○*Misaki, T. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| A01 草間 博之 | ||
| Original papers |
" Total Synthesis of (±)-Integrifolin " Shimomaki, K.; Kusama, H.; *Iwasawa, N.Chem. Eur. J. 2016, pp.in press. DOI:10.1002/chem.201601275 |
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" Total Synthesis of Englerin A Utilizing Intermolecular [3+2] Cycloaddition Reaction of Platinum-Containing Carbonyl Ylide "Kusama, H.; Tazawa, A.; Ishida, K.; *Iwasawa, N. Chem. Asian J. 2016, 11 (1), pp.64-67. DOI:10.1002/asia.201500935 |
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"Total Synthesis of Proposed Structure of Yuremamine and All Diastereomers Utilizing [3+2]-Cycloaddition of Platinum-Containing Azomethine Ylide" Oyama, T.; Uchida, M.; Kusama, H.; Iwasawa, N.* Chem. Asian J. 2015, 10 pp.1850-1853. DOI:10.1002/asia.201500491 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 " Generation and Cycloaddition Reaction of Quinolinium Ylides Using Photochemical Isomerization of Acylsilane to Siloxycarbene "○*Kusama, H.; Ishida, K.; Ichikawa, K.; Sato, J.; Adegawa, M.; Tadami, S.; Mizuno, T.; Iwasawa, N.; Abe, M. The 26th IUPAC Symposium on Photochemistry, Osaka (Japan) 2016-04-04～2016-04-08 |
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口頭発表／ポスター発表 " Intramolecular Formal C-H Insertion Reaction of Photochemically-Generated Siloxycarbenes Leading to Benzofused Heterocycles "Nakada, T.; Ishii, S.; Ishida, K.; Iwasawa, N.; ○*Kusama, H. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 " [3+2]-Cycloaddition Reaction of Quinolinium Ylides Derived from Photochemically-Generated Siloxycarbenes and Clarification of Substituent Effects by Lase Flash Photolysis "○*Kusama, H.; Ishida, K.; Ichikawa, K.; Sato, J.; Adegawa, M.; Tadami, S.; Mizuno, T.; Iwasawa, N.; Abe, M. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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| A01 矢内 光 | ||
| Original papers |
"Synthesis of 1,2,3,4-tetrasubstituted naphthalenes through cascade reaction triggered by silyl acetal activation" *Yanai, H.; Ishii, N.; Matsumoto, T. Chem. Commun. 2016, pp.accepted. DOI:10.1039/C6CC03510H |
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"Concise total synthesis of elliptoxanthone A by utilizing aromatic oxy-Cope
rearrangement for efficient C-isoprenylation of xanthone skeleton " Fujimoto, Y.: Yanai, H.; *Matsumoto, T. Synlett 2016, pp.accepted. |
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"A new approach to axially chiral biaryls via the atrop-diastereoselective
formation of medium-sized lactone bridge " Yuyama, D.; Sugiyama, N.; Maeda, T.; Dobashi, Y.; Yokojima, S.; Fujimoto, Y.; Yanai, H.; *Matsumoto, T. Synlett 2016, pp.accepted. |
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"Sequential Mukaiyama–Michael reaction induced by carbon acids" *Yanai, H.; Kobayashi, O.; Takada, K.; Isono, T.; Satoh, T.; *Matsumoto, T. Chem. Commun. 2016, 52 (16), pp.3280-3283. DOI:10.1039/C5CC10115H |
佐藤敏文 | |
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"An efficient isoprenylation of xanthones at the C1 position by utilizing anion-accelerated aromatic oxy-Cope rearrangement" Fujimoto, Y.; Watabe, Y.; Yanai, H.; Taguchi, T.; *Matsumoto, T. Synlett 2016, 27 (6), pp.848-853. DOI:10.1055/s-0035-1561326 |
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"Chemoselective two-directional reaction of bi-functionalized substrates: formal ketal-selective Mukaiyama aldol type reaction" *Yanai, H.; Sasaki, Y.; Yamamoto, Y.; *Matsumoto, T. Synlett 2015, 26 (17), pp.2457-2461. DOI:10.1055/s-0035-1560478 |
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"Chemistry of fluorinated carbon acids: synthesis, physicochemical properties, and catalysis" *Yanai, H. Chem. Pharm. Bull. 2015, 63 (9), pp.649-662. DOI:10.1248/cpb.c15-00487 |
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"A rapid entry to diverse γ-ylidenetetronate derivatives through regioselective bromination of tetronic acid derived γ-lactones and metal-catalyzed postfunctionalization" Chopin, N.; Yanai, H.; Iikawa, S.; Pilet, G.; *Bouillon, J.-P.; *Médebielle, M. Eur. J. Org. Chem. 2015, (28), pp.6259-6269. DOI:10.1002/ejoc.201500663 |
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"Synthesis of (Z)-fluoroallyl azides through aluminium-mediated defluorinative functionalization reaction" Sato, A.; *Yanai, H.; Suzuki, D.; Okada, M.; *Taguchi, T. Tetrahedron Lett. 2015, 56 (7), pp.925-929. DOI:10.1016/j.tetlet.2014.12.128 |
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"Gas-phase acidity of 1,1-bis(trifluoromethanesulfonyl)propane derivatives and related compounds. Experimental and theoretical studies" Zhang, M.; Sonoda, T.; Shiota, Y.; *Mishima, M.; Yanai, H.; Fujita, M.; Taguchi, T. J. Phys. Org. Chem. 2015, 28 (3), pp.181-186. DOI:10.1002/poc.3304 |
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"1,1-Bis(triflyl)alkadienes: easy-to-handle building blocks for strongly acidic carbon acids" *Yanai, H.; Egawa, S.; Yamada, K.; Ono, J.; Aoki, M.; Matsumoto, T.; Taguchi, T. Asian J. Org. Chem. 2014, 3 (4), pp.556-563. DOI:10.1002/ajoc.201402010 |
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"Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities" *Yanai, H.; Fujita, M.; Takahashi, A.; Zhang, M.; Mishima, M.; Kotani, A.; Matsumoto, T.; Taguchi, T. Molecules 2013, 18 (12), pp.15531-15540. DOI:10.3390/molecules181215531 |
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"Novel One-Pot Synthesis of Xanthones via Sequential Fluoride Ion-Promoted Fries-Type Rearrangement/Nucleophilic Aromatic Substitution" Fujimoto, Y.; Itakura, R.; Hoshi, H.; Yanai, H.; Ando, Y.; Suzuki, K.; *Matsumoto, T. Synlett 2013, 24 (19), pp.2575-2580. DOI:10.1055/s-0033-1339881 |
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"Organic Acid-Catalysis in Reactions of Lactones with Silicon Enolates
" *Yanai, H.; Ishii, N.; Matsumoto, T.; Taguchi, T. Asian J. Org. Chem. 2013, 2 (11), pp.989-996. DOI:10.1002/ajoc.201300157 |
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"2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: Structural Behaviour and Availability as Bis(triflyl)ethylating Reagents" *Yanai, H.; Takahashi, Y.; Fukaya, H.; Dobashi, Y.; Matsumoto, T. Chem. Commun. 2013, 49 (86), pp.10091-10093. DOI:10.1039/C3CC46171H |
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"Reductive Alkylation of Bis(triflyl)methane through Self-promoting Formation of Easily Isolable 1,1-Bis(triflyl)alkenes" *Yanai, H.; Egawa, S.; Taguchi, T. Tetrahedron Lett. 2013, 54 (17), pp.2160-2163. DOI:10.1016/j.tetlet.2013.02.039 |
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"Synthesis, Characterization, and Applications of Zwitterions Containing Carbanion Moiety" *Yanai, H.; Yoshino, T.; Fujita, M.; Fukaya, H.; Kotani, A.; Kusu, F.; Taguchi, T. Angew. Chem. Int. Ed. 2013, 52 (5), pp.1560-1563. DOI:10.1002/anie.201208809 |
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"Organic Acid Induced Olefination Reaction of Lactones" *Yanai, H.; Taguchi, T. Chem. Commun. 2012, 48 (71), pp.8967-8969. DOI:10.1039/C2CC33606E |
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"Four Component Reaction of Aldehydes, Isocyanides, Me3SiN3, and Aliphatic Alcohols Catalyzed by Indium Triflate" *Yanai, H.; Sakiyama, T.; Oguchi, T.; Taguchi, T. Tetrahedron Lett. 2012, 53 (25), pp.3161-3164. DOI:10.1016/j.tetlet.2012.04.046 |
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| Books |
「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "3-ベンジル-2-ブチル-2-(ジフルオロメチル)-2,3-ジヒドロベンゾ[d]オキサゾール" 矢内 光 三共出版 (東京) 2015, pp220-223. ISBN:978-4-7827-0727-2 |
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「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "1-{(tert-ブチルジフェニルシリル)オキシ}-4,4-ジフルオロヘキサ-5-エン-3-オール" 矢内 光 三共出版 (東京) 2015, pp191-193. ISBN:978-4-7827-0727-2 |
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「Green Synthetic Approaches for Biologically Relevant Heterocycles」 Brahmachari, G. "Green and Catalytic Methods for γ-Lactone Synthesis" Yanai, H. Elsevier (Amsterdam) 2014, pp257-289. ISBN:978-0-128-00070-0 |
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| Reviews / Accounts |
"Synthesis of superacidic carbon acid and its derivatives" *Yanai, H.; Taguchi. T. J. Fluorine Chem. 2015, 127 pp.108-119. DOI:10.1016/j.jfluchem.2014.11.006 |
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"ビス（トリフリル）メチル基をもつ強酸性炭素酸の合成と触媒としての応用" *矢内 光, 田口武夫 J. Synth. Org. Chem. Jpn 2014, 72 (2), pp.158-170. DOI:10.5059/yukigoseikyokaishi.72.158 |
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| Conference / Symposium / Lecture |
招待講演 "Chemistry of Superacidic Carbon Acids: Synthesis, Properties and Applications" *Yanai, H. Departmental Seminar at Instituto de Química Orgánica General, CSIC, Madrid (Spain) 2015-09-03～2015-09-03 |
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口頭発表／ポスター発表 "Development of Fluorinated Zwitterion Catalysts" *Yanai, H. 9th French-Japanese Seminar on Fluorine, Nice (France) 2015-08-30～2015-09-01 |
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口頭発表／ポスター発表 "Sequential Mukaiyama-Michael Reaction Induced by Fluorinated Carbon Acid" *Yanai, H.; Kobayashi, O.; Médebielle, M.; Matsumoto1, T. 21st International Symposium on Fluorine Chemistry 2015年8月23日, Como (Italy) 2015-08-23～2015-10-28 |
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口頭発表／ポスター発表 "Synthesis of Fluoroalkene Dipeptide Isosteres Directing to Structural Diversity of Side Chain" *○Yanai, H.; Ando, H.; Tsutsumi, Y.; Matsumoto, T.; Taguchi, T. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-14～2014-12-17 |
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口頭発表／ポスター発表 "Chemoselective Mukaiyama Aldol Type Reactions Catalyzed by Fluorinated Zwitterion" *○Yanai, H.; Sasaki, Y.; Ishii, N.; Matsumoto, T. 4th International Symposium on Organofluorine Compounds in Biomedical, Organic Materials and Agriculture Sciences “Bordeaux Fluorine Days”, Bordeaux (France) 2014-07-06～2014-07-10 |
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招待講演 "Highly Stabilized Carbanions by Fluorinated Substituents" *○Yanai. H. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-12-30 |
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招待講演 "Carbon Acid –Synthesis, Properties, and Catalysis–" ○*Yanai, H. Departmental Seminar at Université de Rouen, Rouen (France) 2013-11-29～2013-11-29 |
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招待講演 "Chemistry and Applications of Fluorinated Carbon Acids" ○*Yanai, H. Departmental Seminar at Université Claude Bernard Lyon 1, Lyon (France) 2013-11-07～2013-11-07 |
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口頭発表／ポスター発表 "Stereoelectronic Effects in 2-Ammonioethan-1-ides: Experimental and Theoretical Analyses" ○*Yanai, H.; Takahashi, Y.; Fukaya, H.; Dobashi, Y. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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口頭発表／ポスター発表 "Synthesis and Catalysis of Fluorinated Organic Brønsted Acids" ○*Yanai, H.; Yoshino, T.; Ishii, N.; Taguchi, T. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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招待講演 "Strong Organic Acids Containig Fluorine; Synthesis, Structure, and Catalysis" ○*Yanai, H.; Taguchi, T. 4th Japan-Korea-China Joint Seminar on Fluorine Chemistry, Nagoya (Japan) 2013-04-12～2013-04-12 |
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口頭発表／ポスター発表 "Synthesis of Multiple Carbon Acids And Their Catalyst Activity in Organic Reactions" ○*Yanai, H.; Taguchi, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-27 |
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| Prize |
"日本薬学会 奨励賞" *矢内 光 2015-03 日本薬学会 |
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" 三菱ガス化学 研究企画賞" *矢内 光 2013-12 有機合成化学協会 |
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| Media |
"Sequential Mukaiyama–Michael reaction induced
by carbon acids" Yanai, H.; Kobayashi, O.; Takada, K.; Isono, T.; Satoh, T.; Matsumoto, T. Chem. Commun. 2016-02-18 当該研究論文の内容が，掲載号（52巻19号）の表紙を飾った。 |
佐藤敏文 |
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"フッ素の特異性に着目した有機フッ素化合物の新しい合成手法の開発と利用" 矢内 光 薬事日報 2015-03-20 研究成果の紹介記事 |
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"＜論文紹介＞ 1,1-ビス（トリフリル）アルカジエンを合成ブロックとする簡便な強酸性炭素酸の合成法｜東京薬科大・矢内助教らの論文をChemistry Viewsが紹介" Yanai, H. ワイリー・サイエンスカフェ 2014-04-28 |
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"Building Strong Carbon Acids from 1,1-Bis(triflyl)alkadienes" Yanai, H.; Egawa, S.; Yamada, K.; Ono, J.; Aoki, M.; Matsumoto, T.; Taguchi, T. ChemistryViews 2014-04-27 有機分子触媒を設計する際の酸性官能基として，我々が提案している炭素酸構造の新規かつ簡便な構築法を見出した。また、得られた炭素酸が，触媒として十分な活性を持っていることを実証した。 |
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"Switching Catalysts for Choosing Products" Yanai, H.; Ishii, N.; Matsumoto, T.; Taguchi, T. ChemistryViews 2013-11-21 独自に開発した二種の有機分子触媒を駆使することで，同一の反応基質から，異なった生成物がそれぞれ選択的に得られることを見出した。 |
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| A01 坂田 健 | ||
| Original papers |
"Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage" Nakajima,K.; Nojima, S.; *Sakata,K.; *Nishibayashi, Y. ChemCatChem. 2016, 8 (6), pp.1028-1032. DOI:10.1002/cctc.201600037 |
西林仁昭 |
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"Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Cyanamides" Hashimoto, T.; Ishii, S.; Yano, R.; Miura, H.; Sakata, K.; *Takeuchi, R. Adv. Synth. Catal. 2015, 357 (18), pp.3901-3916. DOI:10.1002/adsc.201500637 |
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"Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis" Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2015, 54 (34), pp.9944-9947. DOI:10.1002/anie.201503704 |
金井求 | |
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"Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes" Nakajima, K; Takata, S.; *Sakata,K.; *Nishibayashi, Y. Angew. Chem. Int. Ed. 2015, 54 (26), pp.7597-7601. DOI:10.1002/anie.201502531 |
西林仁昭 | |
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"Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C-H Alkenylation/Annulation Sequence " Ikemoto, H.; Yoshino, T.; Sakata, K.; *Matsunaga, S.; *Kanai, M. J. Am. Chem. Soc. 2014, 136 (14), pp.5424-5431. DOI:10.1021/ja5008432 |
金井求 | |
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"Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms using Snap-Shot Structural Analysis" Azuma, T.; Kobayashi, Y.; Sakata, K.; Sasamori, T.; Tokitoh, N.; *Takemoto, Y. J. Org. Chem. 2014, 79 (4), pp.1805-1817. DOI: 10.1021/jo4028775 |
竹本佳司 | |
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"Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexes as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents" Yuki, M.; *Sakata, K.; Hirao, Y.; Nonoyama,N.; Nakajima, K.; *Nishibayashi, Y. J. Am. Chem. Soc. 2015, 137 (12), pp.4173-4182. DOI:10.1021/jacs.5b00584 |
西林仁昭 | |
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"Quantum Chemical Study of the Reaction of 3-(Trimethylsilyl)cyclohexa-1,4-dienes with B(C6F5)3" *Sakata, K.; Fujimoto, H. Organometallics 2015, 34 (1), pp.236-241. DOI:10.1021/om501095e |
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"Qauntum Chemical Study of B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group" *Sakata, K.; Fujimoto, H. J. Org. Chem. 2013, 78 (24), pp.12505-12512. DOI:10.1021/jo402195x |
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"Qauntum Chemical Study of Diels-Alder Reactions Catalyzed by Lewis Acid Activated Oxazaborolidines" *Sakata, K.; Fujimoto, H. J. Org. Chem. 2013, 78 (7), pp.3095-3103. DOI:10.1021/jo400066h |
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"Ruthenium-Triggered Ring-Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal-AllenylideneIntermediates" Miyake, Y.; Endo, S.; Moriyama, T.; *Sakata, K.; *Nishibayashi, Y. Angew. Chem. Int. Ed. 2013, 52 (6), pp.1758-1762. DOI:10.1002/anie.201207801 |
三宅由寛 | |
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"Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Nitriles" Onodera, G.; Shimizu, Y.; Kimura, J.; Kobayashi, J.; Ebihara, Y.; Kondo, K.; Sakata, K.; *Takeuchi, R. J. Am. Chem. Soc. 2012, 134 (25), pp.10515-10531. DOI:10.1021/ja3028394 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 " DFT Study of Cp*CoIII Catalyzed C-H Allylation with Allylic Alcohols " Sakata,K.; Suzuki,Y.; Sun,B.; Yoshino, T.; Matsunaga,S.; Kanai, M.18th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS), Sitges (Barcelona) (Spain) 2015-06-28～2016-07-02 |
金井求 |
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口頭発表／ポスター発表 "Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Nitriles" ◯*Takeuchi, R.; Onodera, G.; Hashimoto, T.; Shimizu, Y.; Kimura, J.; Kobayashi, J.; Ebihara, Y.; Kondo, K.; Sakata, K. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), 札幌 (日本) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group: A DFT Study" ○*Sakata, K. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), 札幌 (日本) 2014-07-13～2015-07-18 |
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口頭発表／ポスター発表 "Catalytic activity of Lewis acid activated Oxazaborolidines in Diels-Alder Reactions: A DFT study" *Sakata, K. 1st International Conference and 6th symposium on Organocatalysis, 大津 (日本) 2013-05-27～2013-05-28 |
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招待講演 "Quantum Chemical Study on Roles of Lewis Acids and Bases in Organic Reactions" Sakata, K. CBC seminar at Nanyang Technological University, Singapore (Singapore) 2012-10-03～2012-10-03 |
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招待講演 "Quantum chemical study of Diels-Alder reactions catalyzed by Lewis acid activated oxazaborolidines" Sakata, K. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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| 分類 | 内容 | 共同研究者 |
|---|---|---|
| A02 北 泰行 | ||
| Original papers |
"Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary" Dohi, T.; Ueda, S.; Hirai, A.; Kojima, Y.; Morimoto, K.; *Kita, Y. Heterocycles 2017, 95 |
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"Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls" Kamitanaka, T.; Morimoto, K.; Tsuboshima, K.; Koseki, D.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2016, 55 (50), pp.15535-15538. |
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"Site-selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for Synthesis of Poly-arylated Phenols " *Sawama, S.; Masuda, M.; Nakatani, R.; Yokoyama, H.; Monguchi, Y.; Dohi, T. ; Kita, Y.; *Sajiki, H. Adv. Synth. Catal. 2016, 358 (23), pp.3683-3687. |
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"Stabilized Pyrrolyl Iodonium Salts and Metal-Fee Oxidative Cross-Coupling" Morimoto, Ｋ.; Ohnishi, Y.; Koseki, D.; Nakamura, A.; Dohi,
T.; *Kita, Y. Org. Biomol. Chem. 2016, 14 (38), pp.8947-8951. |
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"Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles" Morimoto, K.; Nakamura, A.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2016, (25), pp.4294-4297. |
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"Glycosylation Reaction of Thio-Glycosides by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter" *Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; *Kita, Y. Chem. Pharm. Bull. 2016, 64 (7), pp.838-844. |
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"Organo-Iodine(III) Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction" Morimoto, K.; Sakamoto, K.; Ohshika, T.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2016, 55 (11), pp.3652-3656. |
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"New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals and Alkene Nucleophiles" Kamitanaka, T.; Takamuro, H.; Shimizu, K.; Aramaki, Y.; Dohi, T.; *Kita, Y. Heterocycles 2016, 93 (1), pp.295-309. |
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"Gold-Catalyzed Benzylic Azidation of Phthalans and Isochromans and Subsequent FeCl3-Catalyzed Nucleophilic Substitutions" Asai, S.; Yabe, Y.; Goto, R.; Nagata, S.; Monguchi, Y.; Kita, Y.; *Sajiki, H.; *Sawama, Y. Chem. Pharm. Bull. 2015, 63 (10), pp.757-761. |
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"Clean Synthesis of N-pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent" Morimoto, K.; Ogawa, R.; Koseki, D.; Takahashi, Y.; Dohi, T.; *Kita, Y. Chem. Pharm. Bull. 2015, 63 (10), pp.819-824. |
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"Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines" Dohi, T.; Toyoda, Y.; Nakae, T.; Koseki, D.;Kubo, H.; Kamitanaka, T.; *Kita, Y. Heterocycles 2015, 90 (1), pp.631-644. |
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"Phenyliodine Bis(trifluoroacetate) (PIFA) as An Excellent Promoter of 2-Deoxy-2-phthalimido-1-thio-glycosides in the Presence of Triflic Acid in Glycosylation Reaction" Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2015, (10), pp.2138-2142. |
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"A New Arylation of Silyl Enol Ethers by Quinone Monoacetal Substitution" Dohi, T.; Kamitanaka, T.; Takamuro, H.; Mishima, Y.; Washimi, N.; *Kita, Y. Tetrahedron Lett. 2015, 56 (23), pp.3046-3051. |
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"Selective Formation of trans/threo/cis and cis/threo/cis Bis-Tetrahydrofurans from the Same Diene Diols" Fujioka H., Oki T., Hayashi T., Yamakawa M., Kurachi T., Nakahara K., Maehata R., Hamada T., Murai K., Kita Y. Heterocycles 2014, 88 (2), pp.1323-1336. |
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"Iodoarene-Catalyzed Fluorination and Aminofluorination by an Ar-I/HF•pyridine/mCPBA System" Suzuki, S.; Kamo, T.; Fukushi, K.; Hiramatsu, T.; Tokunaga, E.; Dohi, T.; *Kita, Y.; *Shibata, N. Chem. Sci. 2014, 5 (7), pp.2754-2760. |
柴田哲男 | |
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"N1-Selective Oxidative C-N Coupling of Azoles with Pyrroles Using Hypervalent Iodine Reagent" Morimoto, K.; Ohnishi, Y.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. Asian J. Org. Chem. 2014, 3 (4), pp.382-386. |
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"Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocylic Hypervalent Iodine Compound" Dohi, T.; Mochizuki, E.; Yamashita, D.; Miyazaki, K.; *Kita, Y. Heterocycles 2014, 88 (1), pp.245-260. |
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"Organocatalytic C-H/C-H' Cross-Biaryl-Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons" Ito, M.; Kubo, H.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y. J. Am. Chem. Soc. 2013, 135 (38), pp.14078-14081. |
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"Single-Electron-Transfer (SET) Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts" Yamaoka, N.; Sumida, K.; Itani, I.; Ohnishi, Y.; Sekiguchi, S.; Dohi, T.; *Kita, Y. Chem. Eur. J. 2013, 19 (44), pp.15004-15011. |
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"Brønsted Acid-Controlled [3+2] Coupling of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Efficient Construction of Benzofurans" Hu, Y.; Kamitanaka, T.; Mishima, Y.; Dohi, T.; *Kita, Y. J. Org. Chem. 2013, 78 (11), pp.5530-5543. |
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"Metal-Free Oxidative para Cross-Coupling of Phenols" Morimoto, K.; Sakamoto, K.; Ohnishi, Y.; Miyamoto, T.; Ito, M.; Dohi, T.; *Kita, Y. Chem. Eur. J. 2013, 19 (27), pp.8276-8731. |
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"Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y J. Am. Chem. Soc. 2013, 135 (11), pp.4558-4566. |
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"Generation of 3-Borylbenzynes, Their Regioselective Diels–Alder Reactions and Theoretical Analysis" Takagi A.; Ikawa T.; Kurita Y.; Saito K.; Azechi K.; Egi M.; Itoh Y.; Tokiwa H.; Kita Y.; Akai S.
Tetrahedron 2013, 69 (21), pp.4338-4352. DOI:10.1016/j.tet.2013.03.016 |
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"Efficient Synthesis of Regioregular Oligothiophene Photovaltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal Catalyzed Synthetic Route" Dohi, T.; Yamaoka, N.; Nakamura, S.; Sumida, K.; Morimoto, K.; *Kita, Y.
Chem. Eur. J. 2013, 19 (6), pp.2067-2075. |
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"Oxidative Trimerization of Catechol to Hexahydroxytriphenylene (HHTP)" Morimoto, K.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2013, (9), pp.1659-1662. |
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"Development of Efficient Generation Method of Ortho-Naphthoquinone Methides Derived from 1,4-Epoxy-1,4-dihydronaphthalenes and Its Unique Annulation Using Allylsilanes" Sawama, Y.; Shishido, Y.; Yanase, T.; Kawamoto, K.; Goto, R.; Monguchi, Y.; Kita, Y. ; Sajiki, H. Angew. Chem. Int. Ed. 2013, 52 (5), pp.1515-1519. |
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"Lewis Acid-Catalyzed Ring-Opening Functionalizations of 1,4-Epoxy-1,4-dihydronaphthalenes" Sawama, Y.; Ogata, Y.; Kawamoto, K.;
Satake, H.; Shibata, K.; Monguchi, Y.;
Sajiki, H.; Kita, Y. Adv. Synth. Catal. 2013, 355 (2-3), pp.517-528. |
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"Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation Toward Functionalized Aryl Boronates" Ito, M.; Itani, I.; Toyoda, Y.; Morimoto, K.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2012, 51 (50), pp.12555-12558. |
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"Efficient Synthesis of Oxygenated Terphenyls and other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation–Rearomatization
" Dohi, T.; Kamitanaka, T.; Watanabe, S.; Hu, Y.; Washimi, N.; *Kita, Y.
Chem. Eur. J. 2012, 18 (43), pp.13164-13168. |
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"Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-N-oxyl Organocatalyst" Dohi, T.; Kamitanaka, T.; Mochizuki, E.; Ito, M.; *Kita, Y. Chem. Pharm. Bull. 2012, 60 (11), pp.1442-1447. |
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"Asymmetric Total Synthesis of (−)-Stenine and 9a-epi-Stenine" Fujioka, H.; Nakahara K.; Kotoku, N.; Ohba, H.; Nagatomi, Y.; Wang, T.-L.; Sawama, Y.; Murai, K.; Hirano, K.; Oki, T.; Wakamatsu, S.; *Kita, Y.
Chem. Eur. J. 2012, 18 (43), pp.13861-13870. |
村井健一 | |
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"Controlled Couplings of Quinone Monoacetals Using Reusable Polystyrene-Anchored Specific Proton Catalyst" Dohi, T.; Hu, Y.: Kamitanaka, T.; *Kita, Y. Tetrahedron 2012, 68 (40), pp.8424-8430. DOI:10.1016/j.tet.2012.07.089 |
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"Protecting-Group-Free Catalytic Asymmetric Total Synthesis of (–)-Rosmarinecine " Nemoto, H.; Tanimoto, K.; Kanao, Y.; Omura, S.; Kita, Y.; *Akai, S. Tetrahedron 2012, 68 (36 ), pp.7295-7301. DOI:10.1016/j.tet.2012.06.095 |
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"Hypervalent Iodine-Induced Oxidative Cross Coupling via Thiophene Cation Radical Intermediate" Dohi, T ; Ito, M.; Sekigushi, S.; Ishikado, Y.; *Kita, Y. Heterocycles 2012, 86 (1), pp.767-776. |
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"An Excellent Dual Recycling Strategy for the Hypervalent Iodine/Nitroxyl Radical Mediated Selective Oxidation of Alcohols to Aldehydes and Ketones" Dohi, T.; Fukushima, K.; Kamitanaka, T.; Morimoto, K.; Takenaga, N.; *Kita, Y. Green Chem. 2012, 14 (5), pp.1493-1501. |
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"μ-Oxo-Bridged Hypervalent Iodine(III) Compound as Extreme Oxidant for Aqueous Oxidations" Dohi, T,; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. Synthesis 2012, 44 (8), pp.1183-1189. |
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"Reaction of Acetals with Various Carbon Nucleophiles under Non-Acidic Conditions: C-C Bond Formation via a Pyridinium-Type Salt" Fujioka, H.; Yahata, K.; Hamada, T.; Kubo, O.; Okitsu, T.; Sawama, Y.; Ohnaka, T.; Maegawa, T.; *Kita, Y. Chem. Asian J. 2012, 7 (2), pp.367-373. |
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"Metal-Free C-H Cross-Coupling Toward Oxygenated Naphthalene-Benzene Linked Biaryls" Dohi, T.; Ito, M.; Itani, I.; Yamaoka, N.; Morimoto, K.; Fujioka, H.; *Kita, Y. Org. Lett. 2011, 13 (23), pp.6208-6211. |
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"Metal-Free Oxidative Coupling Reaction via Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagent" Morimoto, K.; Nakae, T.; Yamaoka, N.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2011, (31), pp.6326-6334. |
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"New Synthesis of Spirocycles by Utilizing in situ Forming Hypervalent Iodine Species" Dohi, T.; Nakae, T.; Ishikado, Y.; Kato, D.; *Kita, Y. Org. Biomol. Chem. 2011, 9 (20), pp.6899-6902. |
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"[3+2] Coupling of Quinone Monoacetals by Combined Acid-Hydrogen Bond Donor" Dohi, T.; Hu, Y.; Kamitanaka, T.; Washimi, N.; *Kita, Y. Org. Lett. 2011, 13 (18), pp.4814-4817. |
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"The Synthetic and Biological Studies of Discorhabdins and Related Compounds" Wada, Y.; Harayama, Y.; Kamimura, D.; Yoshida, M.; Shibata, T.; Fujiwara, K.; Morimoto, K.; Fujioka, H.; *Kita, Y. Org. Biomol. Chem. 2011, 9 (13), pp.4959-4976. |
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"ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines " Ikawa, T.; Nishiyama, T.; Shigeta, T.; Mohri, S.; Morita, S.; Takayanagi, S.; Terauchi, Y.; Morikawa, Y.; Takagi, A.; Ishikawa, Y.; Fujii, S.; Kita, Y.; Akai, S. Angew. Chem. Int. Ed. 2011, 50 (25), pp.5674-5677. |
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"Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls" Dohi, T.; Washimi, N.; Kamitanaka, T.; Fukushima, K.; *Kita, Y. Angew. Chem. Int. Ed. 2011, 50 (27), pp.6142-6146. |
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"One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant" Dohi, T.; Yamaoka, N.; Itani, I.; *Kita, Y. Aust. J. Chem. 2011, 64 (5), pp.529-535. |
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"Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes" Dohi, T.; Kato, D.; Hyodo, R.; Yamashita, D.; Shiro, M.; *Kita, Y. Angew. Chem. Int. Ed. 2011, 50 (16), pp.3784-3787. |
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"Efficient Phenolic Oxidations Using μ-Oxo-Bridged Phenyliodine Trifluoroacetate" Dohi, T.; Uchiyama, T.; Yamashita, D.; Washimi, N.; *Kita, Y. Tetrahedron Lett. 2011, 52 (17), pp.2212-2215. DOI:10.1016/j.tetlet.2010.12.037 |
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"Asymmetric Total Synthesis of Clavolonine" Nakahara, K.; Hirano, K.; Maehata, R.; *Kita, Y.; Fujioka, H. Org. Lett. 2011, 13 (8), pp.2015-2017. |
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"Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound" Takenaga, N.; Uchiyama, T.; Kato, D.; Fujioka, H.; Dohi, T.; *Kita, Y. Heterocycles 2011, 82 (2), pp.1327-1336. |
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"Phenyliodine Diacetate-Mediated Oxidative Cleavage of Cyclobutanols Leading to
gamma-Hydroxy Ketones
" Fujioka, H.; Komatsu, H.; Miyoshi, A.; Murai, K.; *Kita, Y. Tetrahedron Lett. 2011, 52 (9), pp.973-975. DOI:10.1016/j.tetlet.2010.12.032 |
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"Intramolecular Iodoetherification of Ene or Diene Ketals: Facile Synthesis of Spiroketals" Fujioka, H.; Nakahara, K.; Hirose, H.; Hirano, K.; Oki, T.; *Kita, Y. Chem. Commun. 2011, 47 (3), pp.1060-1062. |
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| Books |
「CSJ Current Review 22 有機分子触媒の化学 － モノづくりのパラダイムシフト
」 Terada, M. "超原子価ヨウ素触媒反応～メタルフリー酸化的カップリング反応への触媒設計～" Kita, Y.; Dohi, T. 化学同人 (京都) 2016, pp157-166. |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 7: Hypervalent Iodine " Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2015, pp103-157. ISBN:978-1-118-46629-2 |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 15: Oxidizing Agents" Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2014, pp277-301. ISBN:978-1-118-46629-2 |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 16: Reaction of Iodo Compounds" Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2014, pp303-327. ISBN:978-1-118-46629-2 |
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「触媒の設計・応制御 事例集」 "クロスカップリング反応におけるホモカップリング体生成の制御" Kita, Y.; Morimoto, K. 技術情報協会 (東京) 2016, pp413-418. |
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「Natural Products」 Ramawat, K. G.;
Merillon, J.-M. "Makaluvamines and Discorhabdins, and Marine Pyrrole-Imidazole Alkaloids" Fujioka H.; Kita Y. Springer-Verlag (Berlin, Heidelberg) 2016, pp251-284. ISBN:978-3-642-22143-9 |
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「Quinones: Occurrence, Medicinal Uses and Physiological Importance」 Price, E. R.; Johnson, S. C. "Quinone Monoacetal Compounds in Application to Controlled Reactions with Nucleophiles" Dohi, T.; Kita, Y. NOVA Science Publisher (New York) 2016, pp85-140. ISBN:978-1-62618-323-0 |
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「CSJ Current Review 11 未来を拓く元素戦略 - 持続可能な社会を実現する化学」 西原 寛、岩澤伸治、林 克郎、辻 勇人 "超原子価ヨウ素 - 希少金属に代わる酸化剤および触媒としての利用" Kita, Y.; T. Dohi 化学同人 (京都) 2016, pp68-76. ISBN:978-4-7598-1371-5 |
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「Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated Organic Synthesis」 Fuchs, P. L "Ethoxy(trimethylsilyl)acetylene" Kita, Y. John Wiley & Sons (Chichester, UK) 2011, pp289-293. |
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「Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated Organic Synthesis」 Fuchs, P. L "Bis(1-methoxy-2-methyl-1-propenyloxy)-dimethylsilane" Kita, Y. John Wiley & Sons (Chichester, UK) 2011, pp51-52. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "ラジカル還元" Kita, Y.; Fujioka, H. 化学同人 2016, pp148-149. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "ベンザインの反応" Kita, Y.; Akai, S. 化学同人 2016, pp98-99. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "脱水反応" Kita, Y.; Fujioka, H. 化学同人 2016, pp22-23. |
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「ヨウ素の化学と最新応用技術」 Yokoyama, M. "３配位ヨウ素化合物の反応" Kita, Y.; Dohi, T. シーエムシー出版 2016, pp105-115. ISBN:978-4781304359 |
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| Reviews / Accounts |
"超原子価ヨウ素反応剤の新展開－有機ヨウ素触媒酸化的ビアリールカップリング－" Morimoto, K.; Dohi, T.; Kita, Y. 月刊ファインケミカル 2016, (12), |
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"超原子価ヨウ素を用いる芳香環酸化的クロスカップリングの基本戦略" Dohi, T.; Morimoto, K.; *Kita, Y. SIS ニュースレター 2016, 17 pp.2-10. |
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"Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)" Dohi, T.; *Kita, Y. Top. Curr. Chem. 2016, 373 pp.1-23. |
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"Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents" Dohi, T.; *Kita, Y. Curr. Org. Chem. 2016, 20 (5), pp.580-615. |
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"Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagent" *Kita, Y.; Dohi, T. Chem. Rec. 2015, 15 (5), pp.886-906. |
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"超原子価ヨウ素反応剤の新展開－有機ヨウ素触媒酸化的ビアリールカップリング－" *Kita, Y.; Dohi, T. 月刊ファインケミカル 有機分子触媒の躍進 2014, 43 (6), pp.31-40. |
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"New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3 C-H Oxidations" Dohi, T.; *Kita, Y. ChemCatChem. 2014, 6 (1), pp.76-78. |
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"Iodide Catalyzed Meta-Free Oxidative Coupling Reactions" *Kita Y.; Dohi, T. Shokubai 2012, 54 (4), pp.245-250. |
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"Marine Pyrroloiminoquinone Alkaloids" *Kita Y.; Fujioka H. Top. Curr. Chem. 2012, 309 pp.131-162. |
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"Hypervalent Iodine Induced Metal-Free C-H Cross Coupling to Biaryls " *Kita, Y.; Dohi, T.; Morimoto, K. J. Synth. Org. Chem., Jpn 2011, 69 (11), pp.1241-1250. |
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"Metal-Free Cross-Coupling Using Iodines" *Kita, Y.; Dohi, T. Fain Kemikaru 2011, 40 (12), pp.49-55. |
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"Cross-Coupling Reactions without Use of Rare Metals. From Encounter with Hypervalent Iodine Reagent to Synthesis of Conductive Polymers" *Kita, Y.; Dohi, T.; Morimoto, K. Kagaku 2011, 66 (8), pp.12-18. |
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"～2010年ノーベル化学賞を受賞した～クロスカップリング反応とレアメタルを用いない反応への可能性" *Kita, Y. マテリアルステージ 2011, 64 pp.332. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Oxidative cross-coupling of phenols with aromatic compounds using hypervalent iodine reagent" ○Morimoto, Ｋ.; Sakamoto, K.; Takahashi,
T.; Dohi, T.; *Kita, Y.
19th The Society of Iodine Science Symposium, Chiba (Japan) 2016-09-16～2016-09-16 |
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招待講演 "Metal－Free Oxidative Aryl Coupling Reactions by Hypervalent Iodine Reagent" ○Kita, Y. 5th International Conference on Hypervalent Iodine Chemistry, Les Diablerets (Switzerland) 2016-07-06～2016-07-06 |
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口頭発表／ポスター発表 "Enviromentally-benign glycosylation reaction using thioglycosides with phenyliodine bis(trifluoroacetate) (PIFA)" Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. 5th International Conference on Hypervalent Iodine Chemistry, Les Diablerets (Switzerland) 2016-07-04～2016-07-04 |
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口頭発表／ポスター発表 "Organo-iodine(III) catalyzed oxidative phenol-arene and phenol-phenol cross-couplings" ○Morimoto, K.; Sakamoto, K.; Takahashi, Y.; Dohi, T. ; Kita Y. The French-Japanese Society of Medicinal and Fine Chemistry, Tokyo (Japan) 2016-05-16～2016-05-16 |
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口頭発表／ポスター発表 "Hypervalent iodine as an excellent promoter of thioglycosides in glycosylation reaction" Kajimoto, T.; ○Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-22～2016-04-22 |
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依頼講演 "Metal-Free Oxidative Biaryl Coupling Reactions by Hypervalent Iodine Reagent" Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Development of Regioselective Introduction of Nucleophiles Toward Quinone Monoacetals by Design of Specific Acid Catalyst" ○Kamitanaka, T.; Washimi, N.; Hu, Y.; Dohi, T.; Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Phenyliodine Bis(trifluoroacetate) (PIFA) as An Excellent Promoter of Thioglycosides in Glycosylation Reaction" Kajimoto, T.; ○Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Enviromentally-Benign Glycosylation Reaction Using Thioglycosides Prepared with An Odorless Thiol and Phenyliodine Bis(trifluoroacetate) (PIFA)" ○Kajimoto, T.; Morimoto, K.; Dohi, T.; Kita, Y Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "New Conceptual Diaryliodonium Salts for Metal-Free Arylation of Carboxylic Acids Giving Aryl Esters" ○Dohi, T.; Sumida, K.; Kato, A.; Samura, K.; Morimoto, K.; *Kita, Y. The 3rd International Symposium on Process Chemistry, Kyoto (Japan) 2015-07-14～2015-07-14 |
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口頭発表／ポスター発表 "Development of New Hypervalent Iodine Catalytic Method in Oxidative Coupling Reactions" ○Dohi, T.; *Kita, Y. 7th International Conference on Green and Sustainable Chemistry, Tokyo (Japan) 2015-07-07～2015-07-07 |
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依頼講演 "Metal-Free Oxidative Coupling Reactions by Hypervalent Iodine Reagent" ○*Kita, Y. 内藤コンファレンス, Sapporo (Japan) 2015-07-06～2015-07-06 |
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口頭発表／ポスター発表 "Hypervalent Iodine(III)-Catalyzed Oxidative Cross-Coupling Reaction of Phenols" ○Morimoto, K.; Sakamoto, K.; Dohi, T.; *Kita, Y. 内藤コンファレンス, Sapporo (Japan) 2015-07-06～2015-07-06 |
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依頼講演 "Recent Progress on Metal-Free Oxidative Coupling Reactions" ○*Kita, Y. 2nd International Conference of Advanced Molecular Transformations by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "A New Carbon-Carbon Bond Forming Strategy for Dearomatizing Spirocyclization by Utilizing Bis(iodoarene) Compounds" ○Nakae, T.; Toyoda, Y.; Miyazaki, K.; Dohi, T.; *Kita, Y. 2nd International Conference of Advanced Molecular Transformations by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-21 |
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口頭発表／ポスター発表 "Oxidative Cross Coupling Reaction of Aromatic Compounds Using Hypervalent Iodine(III) Reagent" Morimoto, K.; Ito, M.; Dohi, T.; ○*Kita, Y. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-15～2014-09-15 |
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口頭発表／ポスター発表 "Oxidative C-N Coupling of Azoles with Heteroaromatic Compounds" ○Morimoto, K.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-15～2014-09-15 |
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口頭発表／ポスター発表 "Oxidative Cross-Coupling of Phenols with Aromatic Compounds Using Hypervalent Iodine Reagent" Morimoto, K.; ○Sakamoto, K.; Sakai, S.;Takahashi, Y.; Dohi, T.; *Kita, Y.
17th The Society of Iodine Science Symposium, Chiba (Japan) 2014-09-19～2014-09-19 |
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招待講演 "Metal-Free Oxidative Coupling Reactions" ○*Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "Organocatalytic C-H/C-H Cross-Biaryl-Coupling of Sulfonanilides with Aromatic Compounds" ○Dohi, T.; Ito, M.; Morimoto, K.; *Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "N1-Selective Oxidative C-N Coupling of Azoles with Pyrroles" ○Morimoto, K.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "Efficient Oxidative Cross-Coupling Reaction of Various Phenols" ○Morimoto, K.; Sakamoto, K.; Dohi, T.; *Kita Y. 9th AFMC International Medicinal Chemistry Symposium, Taipei (Taiwan) 2013-10-15～2013-10-18 |
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口頭発表／ポスター発表 "Coupling Reaction of Alkoxyarenes Using Iodonium Salts as Oxidants" Yamaoka, N.; Sumida, K.; ○Nakamura S.; Dohi, T.; *Kita, Y. 16th The Society of Iodine Science Symposium, Chiba (Japan) 2013-09-18～2013-09-18 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Cross-Coupling Reaction of Aromatic Compounds Using Hypervalent Iodine Reagent" ○*Kita, Y.; Dohi, T.; Morimoto, K.; Ito, M. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-27～2013-06-28 |
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口頭発表／ポスター発表 "Controlled Coupling of p-Nucleophiles Toward Quinone Monoacetal, the All Carbon Electrophilic Molecule" ○Dohi, T.; Hu, Y.; Kamitanaka, T.; Washimi, N.; *Kita, Y. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-26～2013-06-27 |
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口頭発表／ポスター発表 "Oxidative Direct Synthesis of Hexahydroxytriphenylene (HHTP)" ○Morimoto, K.; Dohi, T.; *Kita, Y. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-26～2013-06-27 |
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招待講演 "Hypervalent Iodine Reagent as an Entrance to Metal-Free Oxidative Coupling Reactions" 〇*Kita, Y. 1st International Conference of Advanced Molecular Transformations by Organocatalysts, Ohtsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Metal-Free Coupling Reactions - Hypervalent Iodine-Mediated Synthesis of Biaryl and Heterobiaryl Compounds-" ○*Kita, Y. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "New Oxidative Spirocyclization Utilizing Oxygen-Bridged Hypervalent Iodine Species" ○Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Novel C-C Bond Formation via SET Oxidation with Iodonium Salts" ○Yamaoka, N.; Nakamura, S.; Sumida, K.; Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Brønsted Acid Catalyzed Controlled Coupling of Quinone Monoacetals with Carbon and Other Nucleophiles" ○Hu, Y.; Kamitanaka, T.; Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Coupling Reaction: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagent" ○Morimoto, K.; Yamaoka, N.; Nakae, T.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Efficient Spirocyclization Through Phenolic Oxidations Using Hypervalent Iodine(III) Reagents and Its Application to Natural Product" Morimoto, K.; ○Nakae, T.; Miyamoto, T.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Meta-Free Oxidative Cross-Coupling Reaction of Aromatic Compounds" ○*Kita, Y.; Dohi, T.; Morimoto, K.; Ito, M. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Hypervalent Iodine(III) Mediated Oxidative Cross Coupling Leading to Functionalized Biaryls" ○Ito, M.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "New Synthesis Utilizing Designer oxo-Bridged Hypervalent Iodine Species" ○Dohi, T.; *Kita, Y. ICCOS-2102, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Consise and Expeditious Strategy Toward Oxygenated Terphenyls via Phenol Oxidation-Rearomatization Process" Dohi, T.; ○Kamitanaka, T.; Watanabe, S.; Hu, Y.; Washimi, N.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Synthesis of Boron-Functionalized Diaryliodonium Salts and Selective Arylation" Ito, M.; ○Toyoda, Y.; Itani, I.; Dohi, T.; *Kita, Y. 15th The Society of Iodine Science Symposium, Chiba (Japan) 2012-09-11～2012-09-11 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Cross-Coupling Reaction of Unfunctionalized Heteroaromatic Compound Using Hypervalent Iodine Reagent" ○*Kita, Y.; Dohi, T.; Morimoto, K. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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口頭発表／ポスター発表 "Versatile and Highly Reactive oxo-Bridged Hypervalent Iodine Compound for Green Oxidation and Catalyst" ○Dohi, T.; Fukushima,, K.; Uchiyama, T.; *Kita, Y. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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口頭発表／ポスター発表 "The Synthetic and Biological Studies of Discorhabdin Analogues" Wada, Y.; ○Morimoto, K.; Fujioka, H.; *Kita, Y. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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招待講演 "Power of Iodine - Discovery and Application of Novel Coupling Reactions -" ○*Kita, Y 14th The Society of Iodine Science Symposium, Chiba (Japan) 2011-11-18～2011-11-18 |
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口頭発表／ポスター発表 "The Synthetic and Biological Studies of Discorhabdin Analogues" Wada, Y.; ○Morimoto, K.; Fujioka, H.; *Kita, Y. 8th AFMC International Medicinal Chemistry Symposium “Frontier of Medicinal Science”, Tokyo (Japan) 2011-11-29～2011-12-02 |
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口頭発表／ポスター発表 "Concise Asymmetric Synthesis of Lycopodium Alkaloid, Clavolonine" ○Nakahara, K.; Hirano, K.; Maehata, R.; *Kita, Y.; Fujioka, H. 8th AFMC International Medicinal Chemistry Symposium “Frontier of Medicinal Science”, Tokyo (Japan) 2011-11-29～2011-12-02 |
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口頭発表／ポスター発表 "Novel Arylating Ability of Diaryliodoium Salts" ○Yamaoka, N.; Itani, I.; Itoh, M.; Dohi, T.; *Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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口頭発表／ポスター発表 "Designer µ-Oxo-Bridged Hypervalent Iodine Reagents and Catalysts" ○Dohi, T.; Yamashita, D.; Uchiyama, T.; Fukushima, K.; Katoh, D.; *Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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口頭発表／ポスター発表 "Metal-Free Biaryl Synthesis Using Hypervalnet Iodine Reagents from Unfunctionalized Heteroaromatic Compounds" ○*Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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依頼講演 "Hypervalent Iodine Metal-Free Cross Coupling Reactions" ○*Kita, Y. First Germany - Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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依頼講演 "Hypervalent Iodine Mediated Phenolic Oxidations – A Road to Metal-free and Asymmetric Organocatalytic Reactions" ○*Kita, Y. 2nd Annual World Congress of Catalytic Asymmetric Synthesis-2011, 北京 (中国) 2011-08-08～2011-08-12 |
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| Patent |
"2,3,6,7,10,11-ヘキサヒドロキシトリフェニレン類の製造方法" 発明者：Morimoto, K.; Dohi, T.; Kita, Y. 出願者：和光純薬工業株式会社
立命館大学 特願2012-174481 2012-08-06, 特許第5882162号 2016-02-05, (国内) |
出願者： 特願 2012-08-06, 特許第5878842号 2016-02-05, (国内) |
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"2,3,6,7,10,11-ヘキサヒドロキシトリフェニレン類の製造方法" 発明者：Morimoto, K.; Dohi, T.; Kita, Y. 出願者：和光純薬工業株式会社
立命館大学 特願2012-174481 2012-08-06, 特許第5878842号 2016-02-05, (国内) |
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"有機色素ＭＫ－２の製造方法" 発明者：*Kita Y.; Dohi, T. 出願者：立命館大学 2012188699 2012-08-29, 2012-08, (国内) |
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| Prize |
"The International Society of Heterocyclic Chemistry (ISHC) シニアフェロー " Kita, Y. 2015-10 The International Society of Heterocyclic Chemistry (ISHC) 本学会および本分野に著しい貢献があった者として、シニアフェローに選出された。 |
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"Angewandte Chemie 審査員章" *Kita, Y. 2015-04 WILEY-VCH 2014 Angewandte Chemie における the top 5% of reviewers として表彰された。 |
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"Angewandte Chemie 審査員章" *Kita, Y. 2014-04 WILEY-VCH 2013 Angewandte Chemie において excellent quality の審査報告を行ったとし、Certificate を贈呈された。 |
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| Media |
"「Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species」（J. Am. Chem. Soc., 2013, 135 (11), 4558.）が、月刊化学の「最新のトピックス」で紹介される" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y. 化学 2014-10-18 |
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"「New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species」（Org. Biomol. Chem., 2011, 9, 6899.）が、同誌の The Top 10% Most Highly Cited Articles に選定" Dohi T., Nakae, T., Ishikado, Y., Kato, D., *Kita, Y. 2014-08-31 |
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"「Organocatalytic C-H/C-H' cross-biaryl-coupling: C-selective arylation of sulfonaniliedes with aromatic hydrocarbons 」（J. Am. Chem. Soc., 2013, 135 (38), 14078.）が、同誌の Most Read Articles: Rank 4 に選定、Synfacts 誌 2013, 9 (12), 1345 に掲載" Ito, M.; Kubo, H.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y.
Synfacts, 2013, 9 (12), 1345 2013-12-01 |
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"「μ-Oxo bridged hypervalent iodine compound as extreme oxidatant for aqueous oxidations」（Synthesis, 2013, 44 (8), 1183.）が、同誌の Most Accessed Articles: Rank 1 に選定" Dohi, T.; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. 2013-10-20 PDF |
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"「Oxidative trimerization of catechol to hexahydroxytriphenylene」（Eur. J. Org. Chem., 2013, (9), 1659.）が、Wiley の Hot Topics に選定 " Morimoto, K.; Dohi, T.; *Kita, Y. 2013-06-30 |
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"「Metal-free oxidative para cross-coupling of phenols」（Chem.-Eur. J., 2013, 19 (27), 8276.）が、同誌のハイライト「Frontispiece」で紹介
、Inside Cover、Hot Topics、Most Accessed Articles in May に選定" Morimoto, K.; Sakamoto, K.; Ohnishi, Y.; Miyamoto, T.; Ito, M.; Dohi, T.; *Kita, Y. 2013-06-30 PDF |
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"「Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species」（J. Am. Chem. Soc., 2013, 135 (11), 4558.）が、Synfacts 誌 2013, 9 (6), 550 に掲載" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y. Synfacts, 2013, 9 (6), 550. 2013-05-01 |
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"「Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst」（Tetrahedron, 2012, 68 (40), 8424.）が、Synfacts 誌 2012, 8 (11), 1273 に掲載" Dohi, T.; Hu, Y.: Kamitanaka, T.; *Kita, Y. Synfacts, 2012, 8 (11), 1273. 2012-11-01 |
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"「Speedy and clean hypervalent iodine/nitroxyl radical mediated oxidation of alcohols using recyclable adamantane reagent and highly active 2-azaadamantane N-oxyl organocatalyst」（Chem. Pharm. Bull., 2012, 60 (11), 1442.）が、同誌の Front Cover に選定" Dohi, T.; Kamitanaka, T.; Mochizuki, E.; Ito, M.; *Kita, Y. Chem. Pham. Bull. 2012, 60 (11) 2012-11-01 PDF |
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"「μ-Oxo bridged hypervalent iodine compound as extreme oxidant for aqueous oxidations」(Synthesis, 2012, 44 (8), 1183.）が、''Organic Chemistry Portal'' web site で紹介" Dohi, T.; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. 2012-06-30 |
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"「Metal-free C-H cross coupling toward oxygenated naphthalene-benzene linked biaryls」（Org. Lett., 2011, 13 (23), 6208.）が、ACS cross-journal organic chemistry virtual issue, “Cross-Coupling Reactions” のハイライトとして紹介" Dohi, T.; Ito, M.; Itani, I.; Yamaoka, N.; Morimoto, K.; Fujioka, H.; *Kita, Y. J. Org. Chem. 2012, 77(12), 5221. 2012-03-01 |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、雑誌「選択」、「日本の科学アラカルト その最前線― 日本で産出される数少ない資源利用価値が注目されるヨウ素」、に掲載" *Kita, Y. 選択, 2011, (11), pp 90-91. 2011-11-01 PDF |
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"「Coupling of quinone monoacetals promoted by sandwiched Brönsted acids – Synthesis of oxygenated biaryls」（Angew. Chem., Int. Ed., 2011, 50 (27), 6142.）が、同誌の「Hot Papers」に選定" Dohi, T.; Washimi, N.; Kamitanaka, T.; Fukushima, K.; *Kita, Y. 2011-06-30 |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、日本経済新聞17面「知が支える京都産業ー大学と連携、最先端追う」に掲載" *Kita, Y. 日本経済新聞17面 2011-05-04 PDF |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、サムワン春号「元素航海」に掲載" *Kita, Y. サムワン春号, 2011, 15, pp 8-9. 2011-04-01 PDF |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、エコノミスト「エコノミストリポートー危機が新産業を生み出すレアメタル代替材料最前線」に掲載" *Kita, Y. エコノミスト, 2011, (2), pp 38. 2011-02-01 PDF |
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| A02 竹本 佳司 | ||
| Original papers |
"Chiral Integrated Catalysts Composed of Bifunctional Thiourea and Arylboronic Acid: Asymmetric Aza-Michael Addition of α,β-Unsaturated Carboxylic Acids" Hayama, N.; Azuma, T.; Kobayashi, Y.; *Takemoto，Y. Chem. Pharm. Bull. 2016, 64 (7), |
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"Synthesis and application of tetrahydro-2H-fluorenes via a Pd(0)-catalyzed benzylic C(sp3)–H functionalization" Suetsugu, S.; Muto, N.; Horinouchi, M.; Tsukano, C.; *Takemoto, Y. Chem. Eur. J. 2016, |
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"Synthesis of CPZEN-45: Construction of the 1,4-Diazepin-2-one Core by the Cu-catalyzed Intramolecular Amidation of a Vinyl Iodide" Nakamura, H.; Yoshida, T.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2016, 18 (20), pp.2300-2303. DOI:10.1021/acs.orglett.6b00943 |
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"
Proton Transfer Mechanism of Organocatalyzed Isomerization of Alkynoates into Allenoates: Enantioselectivity and Reversibility. A DFT Study
" Xiao, H.; Kobayashi, Y.; Takemoto, Y.; *Morokuma, K. ACS Catal. 2016, 6 (5), pp.2988-2996. DOI:10.1021/acscatal.6b00038 |
Keiji Morokuma | |
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"Catalytic asymmetric synthesis of anti-α,β-diamino acid derivatives" Izumi, S.; Kobayashi, Y.; *Takemoto; Y. Org. Lett. 2016, 18 (4), pp.696-699. DOI:10.1021/acs.orglett.5b03666 |
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"Synthetic studies towards communesins: Diastereoselective oxidative rearrangement of aurantioclavine derivatives" Suetsugu, S.; Tsukano, C.; *Takemoto, Y. Eur. J. Org. Chem. 2016, (1), pp.108-115. DOI:10.1002/ejoc.201501194 |
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"Catalytic asymmetric formal synthesis of beraprost" Kobayashi, Y.; Kuramoto, R.; *Takemoto, Y. Beilstein J. Org. Chem. 2015, 11 (1), pp.2654-2660. DOI:10.3762/bjoc.11.285 |
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"Synthesis of α-acyloxyketone derivatives via the platinum-catalyzed migration of propargylic esters" Tsukano, C.; Yamamoto, S.; *Takemoto, Y. Chem. Pharm. Bull. 2015, 63 (9), pp.710-719. DOI:org/10.1248/cpb.c15-00417 |
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"Direct dehydroxylative coupling reaction of alcohols with organosilanes
through Si–X bond activation by halogen bonding" Saito, M.; Tsuji, N.; Kobayashi, Y.; *Takemoto, Y. Org. Lett. 2015, 17 (12), pp.3000-3003. DOI:10.1021/acs.orglett.5b01290 |
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"Total Synthesis of (–)-Caprazamycin A" Nakamura, H.; Tsukano, C.; Yasui, M.; Yokouchi, S.; Igarashi, M.; *Takemoto, Y. Angew. Chem. Int. Ed. 2015, 54 (10), pp.3136-3139. DOI:10.1002/anie.201411954 |
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"Direct Photoinduced Electron Transfer from Excited State of Rhodamine B for Carbon-Radical Generation" Yoshioka, E.; *Kohtani, S.; Jichu, T.; Fukazawa, T.; Nagai, T.; Takemoto, Y.; *Miyabe, H. Synlett 2015, 2 (26), pp.265-270. DOI:10.1055/s-0034-1379699 |
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"Electrophilic iodine(I) compounds induced semipinacol rearrangement via C–X bond cleavage" Tsuji, N.; Kobayashi, Y.; *Takemoto, Y. Chem. Commun. 2014, 89 (50), pp.13691-13694. DOI:10.1039/c4cc06014h |
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"Catalytic asymmetric synthesis of the pentacyclic core of (−)-nakadomarin A via oxazolidine as an iminium cation equivalent" Tsuji, N.; Stadler, M.; Naoya Kazumi; Inokuma, T.; Kobayashi, Y.; *Takemoto, Y. Org. Biomol. Chem. 2014, 40 (12), pp.7919-7922. DOI:10.1039/c4ob01678e |
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"Asymmetric Synthesis of Trisubstituted Oxazolidinones by the Thiourea-Catalyzed Aldol Reaction of 2‑Isocyanatomalonate Diester" Sakamoto, S.; Kazumi, N.; Kobayashi, Y.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2014, 18 (16), pp.4758-4761. DOI:10.1021/ol502198e |
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"Synthesis of 3,3-Disubstituted 2-Aminoindolenines by Palladium-Catalyzed Allylic Amidination with Isocyanide" Nanjo, T.; Tsukano, C.; *Takemoto, Y. Synlett 2014, 25 (10), pp.1473-1477. DOI:10.1055/s-0033-1341241 |
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"Synthesis of Pyrrolophenanthridine Alkaloids Based on C(sp3)-H and C(sp2)-H Functionalization Reactions" Tsukano, C.; Muto, N.; Enkhtaivan, I.; *Takemoto, Y. Chem. Asian J. 2014, 9 (9), pp.2628-2634. DOI:org/10.1002/asia.201402490 |
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"A Dual Arylboronic Acid–Aminothiourea Catalytic System for the Asymmetric Intramolecular Hetero-Michael Reaction of α,β-Unsaturated Carboxylic Acids" Azuma, T.; Murata, A.; Kobayashi, Y.; Inokuma, T.; *Takemoto, Y. Org. Lett. 2014, 16 (16), pp.4256-4259. DOI:10.1021/ol501954r |
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"Synthesis of 3,3-disubstituted indoline-2-thiones catalysed by an N-heterocyclic carbene" Ikota, H.; Ishida, T.; Tsukano, C.; *Takemoto, Y. Chem. Commun. 2014, 50 (64), pp.8871-8874. DOI:10.1039/C4CC04047C |
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"A diversity-oriented synthesis of caroverine derivatives via TEMPO-promoted aerobic oxidative CAN bond formation" Kobayashi, Y.; Suzuki, Y.; Ogata, T.; Kimachi, T.; *Takemoto, Y. Tetrahedron Lett. 2014, 55 (22), pp.3299-3301. DOI:10.1016/j.tetlet.2014.03.061 |
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"Synthesis of Functionalized Polycyclic Aromatic Compounds via a Formal [2 + 2]-Cycloaddition" Nagamoto, Y.; Yamaoka, Y.; Fujimura, S.; *Takemoto, Y.; Takasu, K., Org. Lett. 2014, 16 (3), pp.1008-1011. DOI:10.1021/ol403757e |
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"Palladium(0)-Catalyzed Carbon-Hydrogen Bond Functionalization for the Synthesis of Indoloquinazolinones" Tsukano, C.; Okuno, M.; Nishiguchi, H.; *Takemoto, Y. Adv. Synth. Catal. 2014, 356 (7), pp.1533-1538. DOI:10.1002/adsc.201400078 |
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"Oxidant-Resistant Hydrogen-Bond-Donating Organocatalyst for Enantioselective Nucleophilic Epoxidation of α,β-Unsaturated Amides" Kobayashi, Y.; Li, S.; *Takemoto, Y., Asian J. Org. Chem. 2014, 3 (4), pp.403-407. DOI:10.1002/ajoc.201400031 |
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"Synthetic Study of Matrine-Type Alkaloids: Stereoselective Construction of the AB Rings of the Quinolizidine Skeleton" Tsukano, C.; Oimura, A.; Enkhtaivan, I.; *Takemoto, Y. Synlett 2014, 25 (5), pp.653-656. DOI:10.1055/s-0033-1340179 |
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"Asymmetric Synthesis of (–)-Aurantioclavine via Palladium-Catalyzed Intramolecular Allylic Amination" Suetsugu, S.; Nishiguchi, H.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2014, 16 (2), pp.996-999. DOI:10.1021/ol4037314 |
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"Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms Using Snap-Shot Structural Analysis" Azuma, T.; Kobayashi, Y.; Sakata, K.; Sasamori, T.; Tokitoh, N.; *Takemoto, Y. J. Org. Chem. 2014, 79 (4), pp.1805-1817. DOI:10.1021/jo4028775 |
Ken Sakata | |
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"Studies on the Oxidative Cyclization of 3-Hydroxyalkyl-1,2,4-trialkoxynaphthalenes and Synthetic Application for the Biologically Active Natural Compound Rhinacanthone" Ogata, T.; Doe, M.; Matsubara, A.; Torii, E.; Nishiura,
C.; Nishiuchi, A.; Kobayashi, Y.; *Kimachi, T. Tetrahedron 2014, 70 (2), pp.502-509. DOI:10.1016/j.tet.2013.11.025 |
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"Dearomatizing Conjugate Addition to Quinolinyl Amidines for the Synthesis of Dehaloperophoramidine through Tandem Arylation and Allylation" Ishida, T.; Ikota, H.; Kurahashi, K.; Tsukano, C.; *Takemoto, Y. Angew. Chem. Int. Ed. 2013, 52 (39), pp.10204-10207. DOI:doi.org/10.1002/anie.201305581 |
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"Synthesis of Spirooxindole from Carbamoyl Chlorides via Cyclopropyl Methine C(sp3)-H Activation using Palladium Catalyst" Tsukano, C.; Okuno, M.; *Takemoto, Y. Chem. Lett. 2013, 42 (7), pp.753-755. DOI:doi.org/10.1246/cl.130228 |
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"A Powerful Hydrogen-Bond-Donating Organocatalyst for the Enantioselective Intramolecular Oxa-Michael Reaction of α,β-Unactivated Amides and Esters" Kobayashi, Y.; Taniguchi, Y.; Hayama, N.; Inokuma, T.; *Takemoto, Y. Angew. Chem. Int. Ed. 2013, 52 (42), pp.11114-11118. DOI:doi.org/10.1002/anie.201305492 |
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"Synthesis of 3-Acyl-2-arylindole via Palladium-catalyzed Isocyanide Insertion and Oxypalladation of Alkyne" Nanjo, T.; Yamamoto, S.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2013, 15 (14), pp.3754-3757. DOI:10.1021/ol4016699 |
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"Selective Synthesis of Polysubstituted Dihydroquinolines and α,β-Unsaturated Amidines by a Catalytic Reaction of Ynamides with Ketimines" Kuroda, Y.; Shindoh, N.; Takemoto, Y.; *Takasu, K. Synthesis 2013, 45 (16), pp.2328-2336. DOI:10.1055/s-0033-1339191 |
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"Cascade radical reaction of substrates with a carbon–carbon triple bond as a radical acceptor" Miyabe, H.; Asada, R.; *Takemoto, Y. Beilstein J. Org. Chem. 2013, 9 pp.1148-1155. DOI:10.3762/bjoc.9.128 |
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"Synthetic study of perophoramidine: construction of pentacyclic core structure via SmI2-mediated reductive cyclization" Ishida, T.; *Takemoto, Y. Tetrahedron 2013, 69 (23), pp.4517-4523. DOI:10.1016/j.tet.2013.04.039 |
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"Total Syntheses of Complanadines A and B" Zhao, L.; *Tsukano, C.; Kwon, E.; Takemoto, Y.; Hirama, M. Angew. Chem. Int. Ed. 2013, 52 (6), pp.1722-1725. DOI:10.1002/anie.201208297 |
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"Gold(I)-Catalyzed Polycyclizations of Polyenyne-Type Anilines Based on Hydroamination and Consecutive Hydroarylation Cascade" Hirano, K.; Inaba, Y.; Takasu, K.; Oishi, S.; Takemoto, Y.; Fujii, N.; *Ohno, H. J. Org. Chem. 2011, 76 (21), pp.9068-9080. DOI:10.1021/jo2018119 |
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"Regio- and Enantioselective Allylic Substitution with Less Active N- or O-Nucleophiles Catalyzed by Iridium-Complex of Bis(oxazolinyl)pyridine" Miyabe, H.; Moriyama, K.; *Takemoto, Y. Chem. Pharm. Bull. 2011, 59 (6), pp.714-720. DOI:10.1248/cpb.59.714 |
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"Polarity-Mismatched Addition of Electrophilic Carbon Radicals to an Electron Deficient Acceptor: Cascade Radical Addition-Cyclization-Trapping Reaction" Yoshioka, E.; Kohtani, S.; Sawai, K.; Tanaka, E.; *Miyabe, H. J. Org. Chem. 2012, 77 (19), pp.8588-8604. DOI:10.1021/jo3015227 |
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"Adsorptive and Kinetic Properties on Photocatalytic Hydrogenation of Aromatic Ketones upon UV Irradiated Polycrystalline Titanium Dioxide: Differences between Acetophenone and its Trifluoromethylated Derivative" *Kohtani, S.; Yoshioka, E.; Saito, K.; Kudo, A.; *Miyabe, H. J. Phy. Chem. C 2012, 116 (33), pp.17705-17713. DOI:10.1021/jp3056174 |
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"Insertion of Arynes into the Carbon-Oxygen Double Bond of Amides And Its Application into the Sequential Reactions" Yoshioka, E.; *Miyabe, H. Tetrahedron 2012, 68 (1), pp.179-189. DOI:10.1016/j.tet.2011.10.072 |
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"Cascade Radical Reaction Induced by Polarity-Mismatched Perfluoroalkylation" Yoshioka, E.; Wang, KX.; Kohtani, S.; *Miyabe, H. Synlett 2011, (14), pp.2085-2089. DOI:10.1055/s-0030-1261167 |
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"A Multicomponent Coupling Reaction Induced by Insertion of Arynes into C=O Bond of Formamide
" Yoshioka, E.; Kohtani, S.; *Miyabe,H. Angew. Chem. Int. Ed. 2011, 50 (29), pp.6638-6642. DOI:10.1002/anie.201102088 |
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"Expression and Function of PD-1 in Human gdT Cell That Recognize Phosphoantigens" Iwasaki, M.; *Tanaka, Y.; Kobayashi, H.; Murata-Hirai, K. Miyabe, H.; Sugie, T.; Toi, M.; Minato,N. Eur. J. Immunology 2011, 41 (2), pp.345-355. DOI:10.1002/eji.201040959 |
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"
Highly Efficient Synthesis of Quinoxalinone-N-oxide via Tandem Nitrosation/Aerobic Oxidative C–N Bond Formation" Kobayashi, Y.; Kuroda, M.; Toba, N.; Okada, M.; Tanaka, R.; *Kimachi, T. Org. Lett. 2011, 13 (23), pp.6280-6283. DOI:10.1021/ol202760c |
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"Asymmetric total synthesis of biologically active (–)-dehydroiso-β-lapachone and the determination of its absolute configuration" Kimachi, T.; Torii, E.; Kobayashi, Y.; Doe, M.; *Ju-ichi, M. Chem. Pharm. Bull. 2011, 59 (6), pp.753-756. DOI:10.1248/cpb.59.753 |
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"α-Dimethylaminomethylenation-induced Houben–Hoesch-type cyclization of cyanoacetanilides: A practical synthesis of 3-formyl-4-hydroxyquinolin-2(1H)-ones" Kobayashi, Y.; Nakatani, T.; Tanaka, R.; Okada, M.; Torii, E.; Harayama, T.; *Kimachi, T. Tetrahedron 2011, 67 (19), pp.3457-3463. DOI:10.1016/j.tet.2011.03.040 |
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"Regioselective ring-opening reaction of unsymmetrical 2,3-diaryl epoxides via catalytic hydrogenolysis with Pd(0)EnCatTM" Kimachi, T.; Nagata, H.; Kobayashi, Y.; Takahashi, K.; Torii, E.; *Ju-ichi, M. Synlett 2011, (3), pp.365-368. DOI:10.1055/s-0030-1259505 |
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"pH-sensitive DNA cleaving agents: in situ activation by ring contraction of benzo-fused cyclobutanols" Nagamoto, Y.; Hattori, A.; Kakeya, H.; *Takemoto, Y.; *Takasu, K. Chem. Commun. 2013, 49 (26), pp.2622-2624. DOI:10.1039/c3cc39246e |
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"Study of Ring-Opening Reaction of Spiro[5.2]octenes with Aqueous Hydrohalic Acid: Substituent Effect on the Regioselectivity" Nagamoto, Y.; *Takemoto, Y.; *Takasu, K., Synlett 2013, 24 (1), pp.120-124. DOI:10.1055/s-0032-1317745 |
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"N-Heterocyclic carbene catalyzed direct cross-aza-benzoin reaction: Efficient synthesis of α–amino-β-keto esters" Uno, T.; Kobayashi, Y.; *Takemoto, Y. Beilstein Journal of Organic Chemistry 2012, 8 pp.1499-1504. DOI:10.3762/bjoc.8.169 |
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"Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)–H Activation: Concise Synthesis of Indole Derivatives" Nanjo, T.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2012, 14 (16), pp.4270-4273. DOI:DOI: 10.1021/ol302035j |
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"Platinum catalyzed 7-endo cyclization of internal alkynyl amides and its application to synthesis of the caprazamycin core" Tsukano, T.; Yokouchi, S.; Girard, A.-L.; Kuribayashi, T.; Sakamoto, S.; Enomoto, T.; *Takemoto, Y. Org. Biomol. Chem. 2012, 10 (30), pp.6074-6086. DOI:10.1039/C2OB25111F |
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"Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates via Dynamic Kinetic Resolution" Inokuma,T.; Furukawa, M.; Suzuki, Y.; Kimachi, T.; Kobayashi, Y.; *Takemoto, Y. ChemCatChem. 2012, 4 (7), pp.983-985. DOI:10.1002/cctc.201200065 |
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"Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization-(2+2) cycloaddition" Inanaga, K.; Ogawa, Y.; Nagamoto, Y. Daigaku, A.; Tokuyama, H.; *Takemoto, Y.; Takasu, K. Beilstein Journal of Organic Chemistry 2012, 8 pp.658-661. DOI:10.3762/bjoc.8.73 |
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"Synthesis of Highly Oxidized Quinolizidine via Reduction of Acylpyridinium Cation, and Total Syntheses of Quinolizidines 207I and 1-epi-207I" Tsukano, C.; Oimura, A.; Enkhtaivan, I.; *Takemoto, Y. Org. Lett. 2012, 14 (7), pp.1902-1905. DOI:10.1021/ol300541u |
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"Lewis acid-mediated radical cyclization: Stereocontrol in cascade radical addition-cyclization-trapping reactions" Miyabe, H.; Asada, R.; *Takemoto, Y. Org. Biomol. Chem. 2012, 10 (17), pp.3519-3530. DOI:10.1039/c2ob25073j |
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"Room-Temperature, Acid-Catalyzed [2+2] Cycloadditions: Suppression of Side Reactions by using a Flow Microreactor System" Kurahashi, K.; *Takemoto, Y.; Takasu, K. ChemCatChem. 2012, 5 (2), pp.270-273. DOI:10.1002/cssc.201100373 |
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"Palladium-Catalyzed Amidation by Chemoselective C(sp3)-H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor" Tsukano, C.; Okuno, M.; *Takemoto, Y. Angew. Chem. Int. Ed. 2012, 51 (11), pp.2763-2766. DOI:10.1002/anie.201108889 |
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"Synthesis of 2-Iminoindolines via Samarium Diiodide Mediated Reductive Cyclization of Carbodiimides" Ishida, T.; Tsukano, C.; *Takemoto, Y. Chem. Lett. 2012, 1 (41), pp.44-46. DOI:10.1246/cl.2012.44 |
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"Catalyst-Controlled Torquoselectivity Switch in the 4π Ring-Opening Reaction of 2-Amino-2-azetines Giving β-Substituted α,β-Unsaturated Amidines" Shindoh, N.; Kitaura, K.; *Takemoto, Y.; *Takasu, K. J. Am. Chem. Soc. 2011, 22 (133), pp.8470-8473. DOI:10.1021/ja202576e |
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"Unprecedented Synthesis of N,N-Divinylamines by Tf2NH-Catalyzed Reaction of Ynamide with Ketimine" Shindoh, N.; *Takemoto, Y.; *Takasu, K. Heterocycles 2011, 2 (82), pp.1133-1136. |
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"Control of 6-Exo and 7-Endo Cyclization of Alkynylamides using Platinum and Bismuth Catalysts" Girard, A.-L.; Enomoto, T.; Yokouchi, S.; Tsukano, C.; *Takemoto, Y. Chem. Asian J. 2011, 6 (6), pp.1321-1324. DOI:10.1002/asia.201100209 |
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"Flexible Strategy for Syntheses of Spirooxindoles using Palladium-Catalyzed Carbosilylation and Sakurai-Type Cyclization" Hande, S. M.; Nakajima, M.; Kamisaki, H.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2011, 7 (13), pp.1828-1831. DOI:10.1021/ol2003447 |
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"Synthetic studies of salinosporamide A through intramolecular hydroamidation of alkynes" Kamisaki, H.; Kobayashi, Y.; Kimachi, T.; Yasui, Y.; *Takemoto, Y. J. Organomet. Chem. 2011, 1 (696), pp.42-45. DOI:10.1016/j.jorganochem.2010.06.021 |
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"Domino Pd-Catalyzed Heck Cyclization and Bi-Catalyzed Hydroamination: Formal Synthesis of Elacomine and Isoelacomine" Kamisaki, H.; Nanjo, T.; Tsukano, C.; *Takemoto, Y. Chem. Eur. J. 2011, 2 (17), pp.626-633. DOI:10.1002/chem.201002287 |
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"NHC-catalyzed Thioesterification of Aldehydes by External Redox Activation" Uno, T.; Inokuma, T.; *Takemoto, Y. Chem. Commun. 2012, 13 (48), pp.1901-1903. DOI:10.1039/c2cc17183j |
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"Formal (3+3) cycloaddition of silyl enol ethers catalyzed by trifric imide: Domino Michael addition-Claisen condensation accompanied with isomerization of silyl enol ethers" Azuma, T.; *Takemoto, Y.; *Takasu, K. Chem. Pharm. Bull. 2011, 9 (59), pp.1190-1193. DOI:10.1248/cpb.59.1190 |
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"Bifunctional Hydrogen-Bond Donors That Bear a Quinazoline or Benzothiadiazine Skeleton for Asymmetric Organocatalysis" Inokuma, T.; Furukawa, M.; Uno, T.; Suzuki, Y.; Yoshida, K.; Yano, Y.; Matsuzaki, K.; *Takemoto, Y. Chem. Eur. J. 2011, 37 (17), pp.10470-10477. DOI:10.1002/chem.201101338 |
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"Synthesis of Optically Active N-Aryl Amino Acid Derivatives through the Asymmetric Petasis Reaction Catalyzed by Novel Hydroxy-thiourea" Inokuma, T.; Suzuki, Y.; Sakaeda, T.; *Takemoto, Y. Chem. Asian J. 2011, 11 (6), pp.2902-2906. DOI:10.1002/asia.201100453 |
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"Organocatalytic Asymmetric Neber Reaction for the Synthesis of 2H-Azirine Carboxylic Esters" Sakamoto, S.; Inokuma, T.; *Takemoto, Y. Org. Lett. 2011, 24 (13), pp.6374-6377. DOI:10.1021/ol2026747 |
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| Books |
「
Topics in Heterocyclic Chemistry “Guanidines as Reagents and Catalysts”
」 Selig P. "Bifunctional Guanidines as Hydrogen-Bond Donating Catalysts" Kobayashi, Y.; *Takemoto, Y. Springer (Berlin) 2015, pp1-24. ISSN:1861-9282 |
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「Comprehensive Organic Synthesis, 2nd edition, Vol. 1, Additions to C-X π-Bonds Part 1」 Molander G. A.; Knochel P. "Carbonyl and Imine Activation" Miyabe, H.; Takemoto, Y. Elsevier (Oxford) 2014, pp751-769. ISBN:978-0-08-097743-0 |
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「遺伝子医学 MOOK 20，ナノバイオ技術と最新創薬応用研究」 橋田充, 佐治英郎 "多環性アルカロイドからの新規抗癌剤シード化合物創製" 塚野千尋, 竹本佳司 メディカル ドｳ (大阪) 2012, pp66-71. |
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「Hydrogenation」 Karamé, I. "Photocatalytic Hydrogenation on Semiconductor Particles" Kohtani, S.; Yoshioka, E.; Miyabe, H. INTECH (Croatia) 2012, pp291-308. |
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「Occurrence, Characteristics and Applications」 Fukui, C. Ono, M. "Progress in Iridium-Catalyzed Allylic Substitutions, Iridium" Miyabe,H. Nova Science Pub Inc (NY) 2012, pp113-138. |
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「Comprehensive Chirality. In Volume 4 (Synthetic Methods III - Catalytic Methods: C-C Bond Formation)」 Yamamoto, H. Carreira, E. "4.15 C-C Bond Formation (Radical)" Miyabe, H.; Naito, T. ELSEVIER Ltd (Amsterdam) 2013, pp303-314. |
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「Heterocycles in Natural Product Synthesis」 Majumdar, K. C.; Chattopadhyay, S. K., "Chapter 5: Pyran and Its Derivatives" Miyabe, H.; Miyata, O.; Naito, T. WILEY-VCH (Weinheim) 2011, pp153-186. |
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「Asymmetric Synthesis II: More Methods and Applications」 Christmann, C.; Bräse, S. "Bifunctional Thiourea Catalysts" Takemoto, Y.; Inokuma, T. Wiley-VCH (Weinheim) 2012, pp233-237. ISBN:978-3-527-32900-7 |
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「Comprehensive Chirality, Volumr 6, Synthetic Methods V - Organocatalysis」 Maruoka, K.; Editors-in-Chief: Carreira, E. M.; Yamamoto, H. "6.2. C-C Bond Formation: Michael Reaction" Takemoto, Y.; Stadler, M. Elsevier Science (Oxford) 2012, pp37-68. ISBN:978-0-08-095168-3 |
Maruoka, K. | |
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「Science of Synthesis, Asymmetric Organocatalysis 2,Brønsted Base and Acid Catalysts, and Additional Topics」 Maruoka, K "Bifunctional (Thio)urea and BINOL Catalysts" Inokuma, T.; Takemoto, Y. Thieme (Stuttgart) 2012, pp437-497. |
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| Reviews / Accounts |
"Synthetic Approaches to Spiro-oxindoles and Iminoindolines Based on Formation of C2–C3 Bond" Tsukano, C.; *Takemoto, Y. Heterocycles 2014, 10 (89), pp.2271-2302. DOI:10.3987/REV-14-805 |
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"Cascade radical reactions via carbon-carbon/heteroatom bond-forming process" *Miyabe, H.; Takemoto, Y. Universal Organic Chemistry 2014, 2 (1), DOI:10.7243/2053-7670-2-1 |
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"Development of innovative hydrogen-bond-donor catalysts based on heterocyclic scaffolds and their applications to asymmetric reactions" Kobayashi, Y.; Inokuma, T.; *Takemoto, Y., J. Synth. Org. Chem. Jpn 2013, 71 (5), pp.491-502. |
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"Inter- and Intramolecular Carbon-Carbon Bond-Forming Radical Reactions" Miyabe,H. Synlett 2012, 23 (12), pp.1709-1724. DOI:10.1055/s-0031-1290378 |
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"An efficient construction of nitrogen-containing heterocycles utilizing CN functional groups and its application to the synthesis of natural products" Kobayashi, Y. Yakugaku Zasshi 2011, 131, pp.1037-1046. |
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"Thiourea,N-[3,5-BIS(TRIFLUOROMETHYL)PHENYL] -N-[(1R,2R)-2- (DIMETHYLAMINO)CYCLOHEXYL]-" Takasu, K.; *Takemoto, Y. e-EROS 2012, |
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| Conference / Symposium / Lecture |
招待講演 "水素結合を活用したマルチタスク触媒の設計と不斉合成への展開" 竹本佳司 第73回パネル討論会「有機分子触媒の精密設計に基づく高度分子変換」, 岡山県岡山市 (日本) 2016-05-21～2016-05-21 |
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依頼講演 "二官能チオ尿素触媒で何がやれるのか？その可能性を紐解く" 竹本佳司 研究開発専門委員会「有機分子触媒による高度分子変換技術」第１回講習会, 大阪府大阪市 (日本) 2016-01-21～2016-01-21 |
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依頼講演 "
Asymmetric Reactions Using Bifunctional HB-Donor Catalysts
" *Takemoto, Y. Lecture, Seoul (Korea) 2014-11-04～2014-11-04 |
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依頼講演 "Asymmetric Reactions Using Bifunctional HB-Donor Catalysts" *Takemoto. Y. Lecture, Suwon (Korea) 2014-11-03～2014-11-03 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Budapest (Hungary) 2015-07-30～2015-07-30 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Vienna (Austria) 2015-07-30～2016-07-30 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Bologna (Italy) 2015-07-28～2015-07-28 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Parma (Italy) 2015-07-27～2015-07-27 |
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招待講演 "Hetero-Michael addition to α,β-unsaturated carboxylic acids" *Takemoto, Y. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. The chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Asymmetric hetero-Michael reaction of α,β-unsaturated carboxylic acid derivatives" *Takemoto, Y. The 13th Eurasia Conference in Chemical Sciences, Bangalore (India) 2014-12-14～2014-12-18 |
(Indian Institute of Science, , India) Dec. 14-18, 2014, | |
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招待講演 "Asymmetric hetero-Michael reaction of α,β-unsaturated carboxylic acid derivatives" *Takemoto, Y. Advanced Molecular Transformations by Organocatalysts: 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at University of Strasbourg (ECPM), Strasbourg (France) 2013-11-18～2013-11-18 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at University of Rouen (IRCOF), Rouen (France) 2013-10-16～2013-10-16 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at Caen University (ICMT), Caen (France) 2013-10-11～2013-10-11 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry
" *Takemoto, Y. Seminar at Aix-Marseille University (iSm2), Marseille (France) 2013-10-08～2013-10-08 |
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招待講演 "Asymmetric Catalysis with HB Donor and NHC Catalysts" Takemoto, Y. Advanced Molecular Transformations by Organocatalysts: 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Dynamic Kinetic Resolution of α-Branched Aldehydes via Oxidative NHC-Catalysis" Uno, T.; Kobayashi, Y.; Takemoto, Y. The 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "Direct Thioesterification of Aldehydes via Oxidative NHC-Catalysis: Expansion into Dynamic Kinetic Resolution" Uno, T.; Kobayashi, Y.; *Takemoto, Y. First Japan-USA Organocatalytic Symposium, Hawii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Synthesis of Aminourea-Substrate Complex Models and Mechanistic Study" Azuma, T.; Kobayashi, Y.; *Takemoto, Y. First Japan-USA Organocatalytic Symposium, Hawii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "An Efficient Synthesis of Quinoxalinone-Containing Pharmaceuticals via Aerobic Oxidative C-N Bond Formation" Kobayashi, Y.; Kimachi, T.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)-H Activation: Concise Synthesis of Indole Derivatives" Nanjo, T.; Tsukano, C.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "NHC-Catalyzed Thioesterification of Aldehydes by Redox Activation" Uno, T.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "An Efficient Synthesis of Quinoxalinone-containing Pharmaceuticals via Aerobic Oxidative C-N Bond Formation" Kobayashi, Y.; Kimachi, T.; *Takemoto, Y. The 6th Takeda Science Foundation Symposium on Pharmasciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "NHC-catalyzed Direct and Practical Thioesterification of Aldehydes by Redox Activation" Uno, T.; *Takemoto, Y. The 6th Takeda Science Foundation Symposium on Pharmasciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "Formal (3 + 3) Cycloaddition of Silyl Enol Ethers Catalyzed by Trifric Imide: Domino Michael Addition―Claisen Condensation" Azuma, T.; *Takemoto, Y.; Takasu, K. 8th AFMC International Medicinal Chemistry Symposium, Tokyo (Japan) 2011-11-29～2013-12-02 |
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口頭発表／ポスター発表 "Tf2NH-Catalyzed Domino Reaction of Ynamides with Imines: Synthesis of α,β-Unsaturated Amidines and Quinolines" Takasu, K.; Kuroda, Y.; Shindoh, N.; *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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口頭発表／ポスター発表 "N-Heterocyclic Carbene-Catalyzed Oxidative Thioesterification of Aldehydes" Uno, T. *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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口頭発表／ポスター発表 "Studies towards the Organocatalytic, Asymmetric Total Synthesis of Nakadomarin A" Stadler, M.; Tsuji, N.; Inokuma, T.; *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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依頼講演 "Asymmetric Synthesis with Organocatalysts" ○*Takemoto, Y. Bristol-Kyoto Organic Synthesis Workshop in Kyoto, Kyoto (Japan) 2012-11-16～2012-11-17 |
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招待講演 "Asymmetric organocatalysis with bifunctional thioureas and newly designed hydrogen-bond donors" *Takemoto, Y. International Conference Catalysis in Organic Synthesis, Moscow (Russia) 2012-09-15～2012-09-20 |
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招待講演 "Asymmetric Organocatalysis: Toward Multifunctional Hydrogen-bond Donor Catalysts" *Takemoto, Y. The 6th Takeda Science Foundation Symposium on PharmaSciences “How Fascinating the Synthetic Organic Chemistry is!”, Osaka (Japan) 2012-09-13～2012-09-14 |
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招待講演 "Asymmetric Catalysis with Newly Designed Bifunctional Hydrogen-Bond Donors" *Takemoto, Y. 1st Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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| Patent |
"α−ヘテロシクリル酢酸化合物の製造方法
" 発明者：*竹本佳司、小林祐輔、東巧、村田晃洋 出願者：住友化学株式会社、国立大学法人京都大学 特願2014-099842 2014-05-13, 2015-01, |
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"アルツハイマー病予防薬" 発明者：垣塚彰、笹岡紀男、兼森祥子、坂本めぐみ、竹本佳司、塚野千尋 出願者：国立大学法人京都大学 特願2011-190433 2011-09-01, 2013-06, (国内) |
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"イソオキサゾリジン化合物の製造方法" 発明者：*竹本佳司、小林祐輔、猪熊翼、谷口大和 出願者：住友化学株式会社、国立大学法人京都大学 特願2012-206320 2012-09-19, 2013-04, (国内) |
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| A02 川端 猛夫 | ||
| Original papers |
"Asymmetric Synthesis of Multisubstituted Dihydrobenzofurans by Intramolecular Conjugate Addition of Short-Lived C-O Axially Chiral Enolates" Tomohara, K.; Kasamatsu, K.; Yoshimura, T.; Furuta, T.; *Kawabata, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00272 |
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"Organocatalytic Site-Selective Acylation of Avermect in B2a, a Unique Endectocidal Drug" Yamada, T.; Suzuki, K.; Hirose, T.; Furuta, T.; Ueda, Y.; Kawabata, T.; Omura, S.; *Sunazuka, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00205 |
砂塚敏明 | |
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"A Concise Access to C2-Symmetric Chiral 4-Pyrrolidinopyridine Catalysts with Dual Functional Side Chains" Mishiro, K.; Takeuchi, H.; Furuta, T.; *Kawabta, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00292 |
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"Organocatalytic Site-Selective Acylation of 10-Deacetylbaccatin III" Yanagi, M.; Ninomiya, R.; Ueda, Y.; Furuta, T.; Yamada, T.; Sunazuka, T.; *Kawabata, T. Chem. Pharm. Bull 2016, DOI:DOI:10.1248/cpb.c16-00037 |
砂塚敏明 | |
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"Catalytic Discrimination Among Formyl Groups in Regio- and Stereoselective Intramolecular Cross-Aldol Reactions" Baba, T.; Yamamoto, J.; Hayashi, K.; Sato, M.; Yamanaka, M.; Kawabata, T.; *Furuta, T. Chem. Sci. 2016, DOI:DOI:10.1039/C5SC04594K |
山中正浩 | |
|
"Insights into the Molecular Recognition Process in Organocatalytic Chemoselective Monoacylation of 1,5-Pentanediol" Imayoshi, A.; *Yamanaka, M.; Sato, M.; Yoshida, K.; Furuta, T.; Ueda, Y.; *Kawabata, T. Adv. Synth. Catal. 2016, 358 pp.1337-1344. DOI:10.1002/adsc.201600010 |
山中正浩 | |
|
"Catalyst-Controlled Regiodivergent Vinylogous Aza-Morita-Baylis-Hillman Reactions" Hyakutake, R.; Gondo, N.; Ueda, Y.; Yoshimura, T.; Furuta, Hyakutake, R.; Gondo, N.; Ueda, Y.; Yoshimura, T.; Furuta, T.; *Kawabata, T. Tetrahedron Lett. 2016, 57 pp.1321-1324. DOI:10.1016/j.tetlet.2016.02.029 |
||
|
"Final-Stage Site-Selective Acylation for the Total Syntheses of Multifidosides A-C by Organocatalysis"
Yoshihiro
Ueda, Takumi
Furuta, and Takeo Kawabata* Angew. Chem. Int. Ed. 2015, DOI:10.1002/anie.201504729R1 |
||
|
"Total synthesis of ellagitannins via regioselective sequential functionalization of unprotected glucose" Takeuchi, H.; Mishiro, K.; Ueda, Y.; Fujimori, Y.; Furuta, T.; *Kawabata, T. Angew. Chem. Int. Ed. 2015, 54 (21), pp.6177-6180. DOI:10.1002/anie. 20150070 |
||
|
"Origin of High E-Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α’-Alkenediol: A Computational and Experimental Study" *Yamanaka, M.; Yoshida, U.; Sato, M.; Shigeta, T.; Yoshida, K.; Furuta, T.; *Kawabata, T. J. Org. Chem. 2015, 80 (6), pp.3075-3082. DOI:10.1021/jo502945 |
山中正浩 | |
|
"Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives" Nakanishi, K.; Sasamori, T.; Kuramochi, K.; Tokitoh, N.; Kawabata, T.; *Tsubaki, K. J. Org. Chem. 2014, 79 (6), pp.2625-2631. DOI:DOI 10.1021/jo5000085a |
||
|
"
Oligonaphthofurans: Fan-Shaped and Three-Dimensional π-Compounds"
Nakanishi,
K.; Fukatsu, D.; Takaishi, K.; Tsuji, T.; Uenaka, K.; Kuramochi, K.; Kawabata,
T.; *Tsubaki, K.
J. Am. Chem. Soc. 2014, 136 (19), pp.7101-7109. DOI:10.1021/ja502209w |
||
|
"Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical" Hamada, S.; Wada, Y.; Sasamori, T.; Tokitoh, N.; Furuta, T.; *Kawabata, T. Tetrahedron Lett. 2014, 55 (11), pp.1943-1945. DOI:10.1016/j.tetlet.2014.02.005 |
||
|
"A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen Bonding Network" *Mishiro, K.; *Furuta, T.; Sasamori, T.; Hayashi, K.; Tokitoh, N.; Futaki, S.; Kawabata, T. J. Am. Chem. Soc. 2013, 135 (37), pp.13644-13647. DOI:10.1021/ja407051k |
||
|
"
Asymmetric α-Arylation of Amino Acid Derivatives by Clayden
Rearrangement of Ester Enolates via Memory of Chirality
"
Tomohara, K.; Yoshimura, T.; Hyakutake, R.; Yang, P.;
*Kawabata, T.
J. Am. Chem. Soc. 2013, DOI:10.1021/ja406653n |
||
|
"
Synthesis of Axially Chiral Amino Acid Derivatives via
the Selective Monoesterification of 1,1'-Biaryl-2,2'-dicarboxylic acids
"
*Furuta, T.; Nikaido, M.; Yamamoto, J.; Kuribayashi,
T.; Kawabata, T.
Synthesis 2013, 45 (10), pp.1312-1318. DOI:10.1055/s-0032-1318506 |
||
|
"
Chemoselective Oxidation by Electronically Tuned
Nitroxyl Radical Catalysts
"
Hamada, S.; Furuta, T. Wada, Y.; *Kawabata, T.
Angew. Chem. Int. Ed. 2013, 52 (31), pp.8093-8097. DOI:10.1002/anie.201302261 |
||
|
"
Investigation of the Carboxylate Position during the
Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal
Carboxylate
"
Nishino, R.; *Furuta, T.; Kan, K.; Sato, M.; Yamanaka,
M.; Sasamori, T.; Tokitoh, N.; *Kawabata, T.
Angew. Chem. Int. Ed. 2013, 52 (25), pp.6445-6449. DOI:10.1002/anie.201300665 |
立教大学、山中正浩 | |
|
"
Asymmetric Induction via Short-Lived Chiral Enolates
with a Chiral C-O Axis
"
Yoshimura, T.; Tomohara, K.; *Kawabata, T.
J. Am. Chem. Soc. 2013, 135 (19), pp.7102-7105. DOI:10.1021/ja4018122 |
||
|
"
Asymmetric Intermolecular Conjugate Addition of Amino
Acid Derivatives via Memory of Chirality: Total Synthesis of Manzacidin A
"
Yoshimura, T.; Kinoshita, T.; Yoshioka, H.; *Kawabata,
T.
Org. Lett. 2013, 15 (4), pp.864-867. DOI:10.1021/ol303568f |
||
|
"
Asymmetric Intramolecular Conjugate Addition of α-Amino Acid Derivatives via Racemization-free
Equilibrium of Intermediary Chiral Enolates
"
Monguchi, D.; Yoshimura, T.; Irie, K.; Hayashi, K.;
Majumdar, S.; Sasamori, T.; Tokitoh, N.; *Kawabata, T.
Heterocycles 2012, 86 (2), pp.1483-1494. DOI:10.3987/COM-12-S(N)129 |
||
|
"
Nonenzymatic
Geometry-Selective Acylation of Tri- and Tetrasubstituted α,α'-Alkenediols
"
Yoshida, K.; Mishiro, K.; Ueda, Y.; Shigeta, T.;
Furuta, T.; *Kawabata, T. Adv. Synth. Catal. 2012, 354 (17), pp.3291-3298. DOI:10.1002/adsc.201200242 |
||
|
"
Asymmetric Desymmetrization of Meso-Diols by
C2-Symmetric Chiral 4-Pyrrolidinopyridines
"
Schedel, H.; Kan, K.; Ueda, Y.; Mishiro, K.; Yoshida,
K.; Furuta, T.; *Kawabata, T.
Beilstein. J. Org. Chem. 2012, 8 pp.1778-1787. DOI:10.3762/bjoc.8.203 |
||
|
"
Protonation-Assisted Conjugate Addition of Axially
Chiral Enolates: Asymmetric Synthesis of Multisubstituted β-Lactams from α-Amino Acids"
Takuwa, M.; Tomohara, K.; Uyama, M.; Hayashi, K.;
Yang, P.; Hyakutake, R.; Sasamori, T.; Tokitoh, N.; *Kawabata, T. Chem. Eur. J. 2012, 18 (48), pp.15330-15336. DOI:10.1002/ chem.201201339 |
||
|
"
Regioselective Diversification of a Cardiac Glycoside,
Lanatoside C, by Organocatalysis"
Ueda, Y.; Mishiro, K.; Yoshida, K.; Furuta, T.;
*Kawabata, T. J. Org. Chem. 2012, 77 (18), pp.7850-7857. DOI:10.1021/jo301007x |
||
|
"
Dipicolylamine as a Unique Structural Switching
Element for Helical Peptides"
Azuma, Y.; Imai, H.; Yoshimura, T.; Kawabata, T.;
Imanishi, M.; *Futaki, S. Org. Biomol. Chem. 2012, 10 (30), pp.6062-6068. DOI:10.1039/C2OB07118E |
||
|
"
Catalyst-Controlled Reversal of Chemoselectivity in
Acylation of 2-Aminopentane-1,5-Diol Derivatives"
Yoshida, K.; Shigeta, T.; Furuta, T.; *Kawabata, T Chem. Commun. 2012, 48 (55), pp.6981-6983. DOI:10.1039/C2CC32525J |
||
|
"
Asymmetric Aldol Reaction via Memory of Chirality"
Watanabe, H.; Yoshimura, T.; Kawakami, S.; Sasamori,
T.; Tokitoh, N.; *Kawabata, T. Chem. Commun. 2012, 48 (43), pp.5346-5348. DOI:10.1039/C2CC31447A |
||
|
"
Asymmetric Carbonyl Migration of α-Amino Acid Derivatives via Memory of Chirality " Teraoka, F.; Fuji, K.; Ozturk, O.; Yoshimura, T.; *Kawabata, T.Synlett 2011, 11 (4), pp.543-546. DOI:10.1055/s-0030-1259324 |
||
|
"
Organocatalytic Chemoselective Monoacylation of 1,n-Linear Diols " Yoshida, K.; Furuta, T.; Kawabata, T.Angew. Chem. Int. Ed. 2011, 50 (21), pp.4888-4892. DOI:10.1002/anie.201100700 |
||
| Books |
「Site-Selective Catalysis」 Kawabata, T. "Site-Selective Acylation of Carbohydrates and Polyol Compounds" Ueda, Y.; *Kawabata, T. Springer Interntional Publishing 2016 2016, |
|
|
「e-EROS Encyclopedia of Reagents for Organic Synthesis」 Rovis, T. "L-Trytophan N,N'-[[(2S,5S)-1-(4-pyridinyl)-2,5-pyrrolidinediyl]dicarbonyl]bis-3,3'-dioctyl Ester" Ueda, Y.; *Kawabata, T. John Wiley ＆ Sons, Ltd. 2016, |
||
|
「e-EROS Encyclopedia of Reagents for Organic Synthesis」 Rovis, T. "Lithium tert-Butyl (trimethylsilyl)amide" Yoshimura, T.; *Kawabata, T. John Wiley ＆ Sons, Ltd 2016, |
||
|
「RSC Green Chemistry, Sustainable Catalysis」 North, M. "Chiral Imidazole and Pyridines as Asymmetric Organocatalysis" Furuta, T.; *Kawabata, T. The Royal Society of Chemistry 2016, pp351-380. |
||
|
「月刊ファインケミカル」 寺田眞浩 "アシル化触媒" 川端猛夫 シーエムシー出版 2015, pp14-23. |
||
|
「
Chiral DMAP-Type Catalysts for Acyl-Transfer Reactions
」
List, B
"Chiral DMAP-Type Catalysts for Acyl-Transfer Reaction" Furuta, T.; Kawabata, T. George Thieme Verlag KG (Stuttgart, New York) 2012, pp497-546. |
||
|
「化学」 化学同人 "触媒的位置選択的官能基化 –次世代の分子変換法" 古田巧、川端猛夫 化学同人 (京都市) 2011, pp70-71. |
||
| Conference / Symposium / Lecture |
招待講演 "Enantio- and Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. 2015 International Chemical Congress of Pacific Basin Societies, Honolulu (USA) 2016-12-15～2016-12-20 |
|
|
招待講演 "Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, Sendai (Japan) 2016-09-06～2016-09-09 |
||
|
招待講演 "Enantio- and Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. The 39th Naito Conference: The chemstry of organocatalysts, Spporo (Japan) 2016-07-06～2016-07-09 |
||
|
基調講演 "Site- and Enantio-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. 7th Spanish-Portuguese-Japanese Organic Chemistry Symposium, Seville (Spain) 2016-06-23～2016-05-26 |
||
|
招待講演 "Site-Selective Catalysis" ○Kawabata, T. 1st Kyoto University - UC San Diego Joint Symposium, Kyoto (Japan) 2015-03-11～2015-03-12 |
||
|
招待講演 "Regio- and Enanatioselective Acylation by Organocatalysis" ○Kawabata, T. 8th Singapore International Chemistry Conference (SICC8)(Singapore), (Singapore) 2014-12-14～2014-12-17 |
||
|
招待講演 "Regio- and Enantioselective Functionalization by Organocatalysis" ○Kawabata, T. Advanced Molecular Transformation by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-22 |
||
|
口頭発表／ポスター発表 "Enrichment of the diastereomeric ratio of chiral heterocycles via racemization free-equilibrium of the intermediary chiral enolates" ○Yang, P.; Monguchi, D.; Takuwa, M.; Yoshimura, T.; Kawabata, T. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-31 |
||
|
招待講演 "Regio- and Enantioselective Acylation Catalysis" ○Kawabata . T. 24th Symposium on Optically Active Compounds, Tokyo (Japan) 2014-10-10～2014-10-10 |
||
|
招待講演 "Regioselective Molecular Transformation of Sugars and Peptides by Organocatalysis" ○Kawabata, T. 45th KMC Frontier Seminar, Tokyo (Japan) 2014-08-27～2014-08-27 |
||
|
口頭発表／ポスター発表 "Total Synthesis of Ellagitannins via Regioselective Acylation of Glucose" Takeuchi, H.;, ○Fujimori, Y.; Mishiro, K.; Furuta, T.; Kawabata, T. XXVIIth International Conference on Polyphenols & The 8th Tannin Conference(ICP2014), Nagoya (Japan) 2014-09-02～2014-09-06 |
||
|
口頭発表／ポスター発表 "
An Innovative Synthetic
Process for Natural Glycosides
"
○Hironori Takeuchi, Takumi
Furuta, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, Uji (Kyoto) 2014-03-10～2014-03-12 |
||
|
"
Development of Asymmetric
Conjugate Addition and Dieckmann Condensation via MOC Strategy
"
○Tomohiko Kinoshita, Tomoyuki
Yoshimura, Takumi Furuta, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Enantioselective β-lactam
synthesis via intramolecular conjugate addition of axially chiral enolates
overcoming competitive β-elimination
"
○Ryuichi Hyakutake, Masatoshi
Takuwa, Pan Yang, Tomoyuki Yoshimura, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, Uji (Japan) 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Asymmetric intramolecular
cross-aldol reaction catalyzed by axially chiral anilines
"
○Tomonori Baba, Junya Yamamoto,
Takumi Furuta, Takeo Kawabata
ICRIS'14:The Science and Technology of Smart Material, Uji (Japan) 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Regioselective deoxygenation
of hexopyranose derivatives
"
○Masanori Yanagi, Yoshihiro
Ueda, Takumi Furuta, Takeo Kawabata
13th International Conference on the Chemistry of Antibiotics and other bioactive compounds , Yamanashi (Japana) 2013-09-24～2013-09-27 |
||
|
口頭発表／ポスター発表 "
Total Synthesis of
Ellagitannins by Regioselective Functionalization of D-Glucose
"
○Hironori Takeuchi, Takumi
Furuta, Takeo Kawabata
13th International Conference on the Chemistry of Antibiotics and other bioactive compounds , Yamanashi (Japan) 2013-09-24～2013-09-27 |
||
|
口頭発表／ポスター発表 "
Asymmetric aldol reaction via
memory of chirality
"
○Toshihide Watanabe, ○Haruka Otsuki, Tomoyuki Yoshimura, Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
"
Asymmetryc Intramolecular
Conjugate Addition of Chiral Enolates wtih Chiral C-O axis
"
○Koji Kasamatsu, Keisuke
Tomohara, Tomoyuki Yoshimura, Takeo Kawabata The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
口頭発表／ポスター発表 "
Asymmetric α-Arylation of
Amino Acid Derivatives via Intramolecular Aryl Migration of C-N Axially Chiral
Enolates
"
○Keisuke Tomohra, ○Pan Yang, Ryuichi Hyakutake, Tomoyuki Yoshimura,
Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
口頭発表／ポスター発表 "
Asymmetric Intermolecular
Conjugate Addition of Amino Acid Derivatives via Memory of Chirality: Total
Synthesis of Manzacidin A
"
○Tomohiko Kinoshita, Hiroyasu
Yoshioka, Tomoyuki Yoshimura, Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
招待講演 "
Asymmetric Intramolecular
Alkylation via Short-Lived C-O Axially Chiral Enolates " ○Tomoyuki Yoshimura, Keisuke
Tomohara, Takeo Kawabata
The 10th International Symposium on Carbanione Chemistry (ISCC-10) , Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
招待講演 "
Regioselective
Functionalization by Organocatalysis
"
○*Takeo
Kawabata
1st International Conference & 6th Symposium on Organiocatalysis, Ohtsu (Japan) 2013-05-17～2013-05-18 |
||
|
口頭発表／ポスター発表 "
Regioselective deoxygenation
of glucose derivatives
"
○Masanori
Yanagi, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
1st International Conference & 6th Symposium on Organiocatalysis, Ohtsu (Japan) 2013-05-27～2013-05-28 |
||
|
招待講演 "
Total synthesis of natural
glycosides by regioselective organocatalysis
"
○*Takeo
Kawabata
First Japan-USA Organocatalytic Symposium, Honolulu (Hawaii) 2012-12-15～2013-12-18 |
||
|
招待講演 "
Regioselective
Functionalization by Organocatalysis
"
○*Takeo
Kawabata Brystol-Kyoto Organic Synthesis Workshop in Kyoto , Kyoto (Japan) 2012-12-17～2012-12-18 |
||
|
口頭発表／ポスター発表 "
Organocatalysis-based
Enantioselective and Regioselective Total Syntheses of Natural Glycosides,
Multifidoside A and B
"
○Yoshihiro
Ueda, Takumi Furuta, *Takeo Kawabata
The 6th Takeda Science Foundation Symposium on PharmaSciences ' How Fascinating the Synthetic Organic Chemistry Is!' , Osaka (Japan) 2012-09-13～2012-09-14 |
||
|
口頭発表／ポスター発表 "
Asymmetric Synthesis of Cyclic Ethers with Tetrasubstituted Carbon via Short-lived C-O Axially Chiral Enolates " ○Tomoyuki Yoshimura, Keisuke Tomohara, and *Takeo KawabataThe 6th Takeda Science Foundation Symposium on PharmaSciences ' How Fascinating the Synthetic Organic Chemistry Is!' , Osaka (Japan) 2012-09-13～2012-09-14 |
||
|
口頭発表／ポスター発表 "
Total Syntheses of
Multifidoside A and B via Enantioselective and Regioselective Organocatalytic
Protocol
"
○Yoshihiro
Ueda, Takumi Furuta, *Takeo Kawabata
The 7th Seoul-Kyoto-Osaka Joint Symposium on Pharmaceutical Sciences for Young Scientists, Kyoto (Japan) 2012-05-24～2012-05-24 |
||
|
口頭発表／ポスター発表 "
Development of a Nitroxyl
Radical Oxidation Catalyst based on Electronic Tuning
"
○Shohei
Hamada, Takumi Furuta, *Takeo Kawabata
The 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
"
Intramolecular conjugate
addition of axially chiral enolates possessing a β-alkoxy leaving group: Asymmetric synthesis of β-lactams from L-serine
derivatives
"
○Ryuichi
Hyakutake, Masatoshi Takuwa, Makoto Uyama, Tomoyuki Yoshimura, *Takeo Kawabata
he 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
口頭発表／ポスター発表 "
Organocatalytic seven-step
total synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, and *Takeo Kawabata The 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
受賞講演 "
A Principle for Asymmetric
Molecular Transformatio
"
○*Takeo
Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Intramolecular conjugate
addition of axially chiral enolates possessing a β-alkoxy leaving group: Asymmetric synthesis of β-lactams from L-serine
derivatives
"
○Ryuichi
Hyakutake, Masatoshi Takuwa, Makoto Uyama, Tomoyuki Yoshimura, *Takeo Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Total Synthesis of Manzacidin
A via Asymmetric Intermolecular Conjugate Addition Reaction Based on Memory of
Chirality
"
○Tomohiko Kinoshita, Hiroyasu Yoshioka, Tomoyuki Yoshimura, *Takeo Kawabata Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
A novel chiral structural
motif consisting of a cyclic hydrogen bonding network
"
○Kenji
Mishiro, Takumi Furuta, *Takeo Kawabata Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Catalytic and Regioselective
Total Synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
基調講演 "
Remote Asymmetric
Desymmetrization of Flexible Linear Diols by Organocatalysis
"
○*Takeo Kawabata BIT's 3rd Annual World Congress of Catalytic Asymmetric Synthesis -2012, Beijing (China) 2012-05-12～2012-05-14 |
||
|
口頭発表／ポスター発表 "
An Organocatalytic Regioselective
Approach toward Short Total Synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
||
|
口頭発表／ポスター発表 "
Development of a Nitroxyl
Radical Oxidation Catalyst by Electronic
Tuning
"
○Shohei
Hamada, Takumi Furuta, *Takeo Kawabata
International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
||
|
口頭発表／ポスター発表 "
symmetric desymmetrization of σ-symmetric linear diols
by chiral PPY catalysts
"
○Takashi Shigeta, Keisuke
Yoshida, Takumi Furuta, *Takeo Kawabata
8th AFMC International Medicinal Chemistry Symposium "Frontier of Medicinal Science", Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
Kinetic Resolution of
1,1'-Binaphthyl-8,8'-diamines by Catalytic Acylation with Chiral PPYs:
Mechanistic and Kinetic Aspects
"
Yasser Samir Abdel-khalek
Sokeirik, Valluru Krishna Reddy, Keisuke Yoshida, ○*Takeo Kawabata
8th AFMC International Medicinal Chemistry Symposium , Tokyo (Japan) 2012-11-29～2012-12-02 |
||
|
口頭発表／ポスター発表 "
Catalytic Profile of Biaryl
DMAP Derivatives with an Internal Carboxylate
"
○Reiko Nishino, Takumi
Furuta, *Takeo Kawabata 8th AFMC International Medicinal Chemistry Symposium , Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
Asymmetric Synthesis of β-Lactams with Contiguous Tetrasubstituted Chiral Carbon Centers via Memory of Chirality " ○Pan Yang, Masatoshi Takuwa, Keisuke Tomohara, Tomoyuki Yoshimura, *Takeo Kawabata8th AFMC International Medicinal Chemistry Symposium, Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
An Organocatalytic
Regioselective Approach toward Short Total Syntheses of Telimagrandin I and II "
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
First Germany-Japan Organocatalytic Symposium in Kyoto, Kyoto (Japan) 2011-10-14～2011-10-14 |
||
|
口頭発表／ポスター発表 "Asymmetric Desymmetrization of
σ-Symmetric Linear Diols by Organocatalytic Remote
Chiral Recognition
"
○Takashi
Shigeta, Keisuke Yoshida, Takumi Furuta, *Takeo Kawabata
First Germany-Japan Organocatalytic Symposium in Kyoto, Kyoto (Japan) 2011-10-14～2011-10-14 |
||
|
招待講演 "
Regioselective Functionalization by Organocatalysis " ○*Kawabata, TThe Seventh International Symposium on Integrated Synthesis (ISIS-7), Kobe (Japan) 2011-10-09～2011-10-10 |
||
| Patent |
"
β-Lactam
Compound and Method for Producing Same
" 発明者：
Kawaba Tatakeo; Yoshimura
Tomoyuki
出願者：Kyoto University WO2012157504 2013-08, 2013-08, (国外) |
|
|
"
Helicene
Derivative, Axially Asymmetric Amino Acid, Amine or Amonoalcohol Derivative or
Salt thereof, and Methods for Producing Same
" 発明者：
Furuta Takumi; Kawaba Takeo
出願者：Kyoto University 2012-08, 2013-08, (国外) |
||
|
"
アルドール反応触媒
" 発明者：
古田巧、馬場智明、川端猛夫
出願者：国立大学法人京都大学 特願２０１３−１２７９７０ 2013-06-18, 2013-08, (国内) |
||
|
"
β-ラクタム化合物およびその製造方法
" 発明者：
川端猛夫、吉村智之
出願者：国立大学法人京都大学 特願２０１１−１０７７７１ 2011-05-11, 2013-08, (国内) |
||
|
"
アミノ酸誘導体およびその製造方法
" 発明者：
川端猛夫、吉村智之
出願者：国立大学法人京都大学 特願２０１１−１６７３１０ 2011-07-29, 2013-08, (国内) |
||
|
"
酸化触媒
" 発明者：
川端猛夫、浜田翔平、古田巧
出願者：国立大学法人京都大学 特願２０１１−１６７４２５ 2011-07-29, 2013-08, (国内) |
||
| Prize |
"Nagase Foundation Award 2013" Regioselective Short-Step Total Synthesis of Natural Glycosides 2013-05 Nagase Science and Technology Foundation |
|
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"Molecular Chirality Award 2012" *Kawabata, T. 2012-05 Molecular Chirality Research Organization Creation of Memory of Chirality Concept and Application to Asymmetric Synthesis |
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| A02 根東 義則 | ||
| Original papers |
"Palladium-Catalyzed Highly Chemoselective Intramolecular C-H Aminocarbonylation of Phenethylamines to Six-Membered Benzolactams" Taneda, H.; Inamoto, K.; *Kondo, Y. Org. Lett. 2016, in press DOI:10.1021/acs.orglett.6b01171 |
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"Development of Madelung-Type Indole Synthesis Using Copper-Catalyzed Amidation/Comdensation Strategy" Abe, M.; Denneval, C.; Nozawa-Kumada, K.; *Kondo, Y. Heterocycles 2016, 92 (5), pp.900-909. DOI:10.3987/COM-16-13440 |
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|
"Copper-Catalyzed sp3 C-H Aminative Cyclization of 2-Alkyl-N-arylbenzamide: An Approach for the Synthesis of N-Arylisoindolinones" Nozawa-Kumada, Kanako; Kadokawa, Jun; Kameyama, Takehiro; *Kondo, Yoshinori Org. Lett. 2015, 17 (18), pp.4479-4481. DOI:10.1021/acs.orglett.5b02235 |
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|
"Exploringa DNA Sequence for the Three-Dimensional Structure Dtermination of a Silver(I)-Mediated C-C Base Pair in a DNA Duplex By 1H NMR Spectroscopy" Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Kondo, Yoshinori; Kojima, Chojiroo; Ono, Akira; *Tanaka, Yoshiyuki Nucleosides, Nucleotides & Nucleic Acids 2015, 34 (12), pp.877-900. DOI:10.1080/15257770.2015.1088160 |
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|
"Direct detection of the mercury-nitrogen bond in the thymine-HgII-thymidine base pair with 199Hg NMR spectroscopy" Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Sebara, Jakub; Yamanaka, Daichi; Otaki, Hiroyuki; Kikkawa, Shoko; Kondo, Yoshinori; Katahira, Ritsuko; Matthhias, Bickelhaupt; *Tanaka, Yoshiyuki Chem. Commun. 2015, 51 (40), pp.8488-8491. DOI:10.1039/C5CC02423D |
||
|
"Deprotonative C-H solylation of functionalizaed arenes
and heteroarenes using trimethyl -trialkylsilane with fluoride" Sasaki, M.; *Kondo, Y. Org. Lett. 2015, 17 (4), pp.848-851. DOI:10.1021/ol503671b |
||
|
"Use of tetramehylammonium fluoride (TMAF) and alkali
metal alkoxides as an activator for catalytic deprotonative functionalization
of heteroaromatic C(sp2)-H" *Inamoto, K.; Okawa, H.; Kikkawa, S.; *Kondo,
Y. Tetrahedron 2014, 70 (43), pp.7917-7922. DOI:10.1016/j.tet.2014.08.054 |
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|
"Direct condensation of functionalized sp3 carbons with
formamides for enamine synthesis using an in situ generated HMDS amide catalyst" Taneda, H.; Inamoto, K.; *Kondo,
Y. Chem. Commun. 2014, 50 (49), pp.6523-6525. DOI:10.1039/c4cc02228a |
||
|
"Desilylative carboxylation of aryltrimethylsilanes
using CO2 in the presence of catalytic phosphazenium salt" Yonemoto-Kobayashi, M.; Inamoto, K.; *Kondo,
Y. Chem. Lett. 2014, 43 (4), pp.477-479. DOI:10.1246/cl.131108 |
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|
"Facile deprotection of dithioacetals by using a novel
1,4-benzoquinone/cat. NaI system" *Inamoto, K.; Yamada, T.; Kato S.;
Kikkawa, S.; *Kondo, Y. Tetrahedron 2013, 69 (44), pp.9192-9199. DOI:10.1016/j.tet.2013.08.061 |
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|
"Ruthenium -catalyzed
Carbonylative C-H cyclization of 2-arylphenols: a novel synthetic route to
6H-dibenzo[b,d]pyran-6-ones" *Inamoto, K.; Kadokawa, J.; *Kondo, Y. Org. Lett. 2013, 15 (15), pp.3962-3965. DOI:10.1021/0l401734m |
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|
"Organocatalytic functionalization of heteroaromatic
N-oxides with C-nucleopjiles using in situ generated onium amide bases" Inamoto, K.; Araki, Y.; Kikkawa S.;
Yonemoto, M.; Tanaka, Y.; *Kondo, Y. Org. Biomol. Chem. 2013, 11 (27), pp.4438-4441. DOI:10.1039/c3ob40782a |
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|
"Raman spectroscopic detection of the T-HgII-T base pair and the ionic characteristics of mercury" Uchiyama, T.; Miura, T.; Takeuchi, H.; Dairaku, T.; Komuro, T.; Kawamura, T.; Kondo, Y.; Benda, L.; *Sychrovsky, V.; Bour, P.; *Okamoto, I.; Ono, A.; *Tanaka, Y. Nucleic Acids Research 2012, 40 (12), pp.5766-5774. |
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|
"Carboxylation of alkynylsilanes with carbon dioxide mediated by sesium fluoride in DMSO" Yonemoto-Kobayashi, M.; Inamoto, K.; Tanaka, Y.; *Kondo, Y. Org. Biomol. Chem. 2013, 11 (23), pp.3773-3775. |
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|
"Organocatalytic deprotonative functionalization of C(sp2)-H and C(sp3)-H bonds using in situ generated onium amide bases" *Inamoto, K.; Okawa, H.; Taneda, H.; Sato, N.; Hirono, Y.; Yonemoto, M. Kikkawa, S.; *Kondo, Y. Chem. Commun. 2012, 48 (78), pp.9771-9773. DOI:10.1039/c2cc35701a |
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|
"Palladium-catalyzed C-H cyclization in water: a milder route to 2-arylbenzothiazole" *Inamoto, K.; Nozawa, K.; *Kondo, Y. Synlett 2012, 23 (11), pp.1678-1682. DOI:10.1055/s-0031-1291164 |
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|
"Efficient use of a surfactant for copper-catalyzed coupling reaction of arylboronic acids with imidazoles in water" *Inamoto, K.; Nozawa, K.; Kadokawa, J.; *Kondo, Y. Tetrahedron 2012, 68 (38), pp.7794-7798. DOI:10.1015/j.tet.2012.07.042 |
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|
"Synthesis of 3-Carboxylated Indole trough a Tandem Process Involving Cyclization of 2-Ethynylanilines Followed by CO2 Fixation in the Absence of Transition Metal Catalysts" +Inamoto, K.; Asano, N.; Nakamura, Y.; Yonemoto, M.; *Kondo, Y. Org. Lett. 2012, 14 (10), pp.2622-2625. DOI:10.1021/ol300958c |
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|
"Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinoplinones" *Inamoto, K.; Kawasaki, J.; Hiroya, K.; Kondo, Y.; *Doi, T. Chem. Commun. 2012, 48 (36), pp.4332-4334. DOI:10. 1039/c2cc30600 |
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|
"Functionalizaztion of heteroaromatic N-oxides using organic superbase catalyst" Araki, Y.; Kobayashi, K.; Yonemoto, M.; *Kondo, Y. Org. Biomol. Chem. 2011, 9 (1), pp.78-80. |
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|
"Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols" *Inamoto, K.; Nozawa, K.; Yonemto, M.; *Kondo, Y. Chem. Commun. 2011, 47 (42), pp.11775-11777. |
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|
"A copper-based catalytic system for carboxylation of terminal alkynes: synthesis of alkyl 2-alkynoates" *Inamoto, K.; Asano, N.; Kobayashi, K.; Yonemoto, M.; *Kondo, Y. Org. Biomol. Chem. 2012, 10 (8), pp.1514-1516. |
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|
"Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding aby transition metal catalyst" *Inamoto, K.; Hasegawa, C.; hiroya, K.; Kondo, Y.; Osako, T.; Uozumi, Y.; *Doi, T. Chem. Commun. 2012, 48 (23), pp.2912-2914. |
||
| A02 渕辺 耕平 | ||
| Original papers |
"Regioselective Synthesis of α,α-Difluorocyclopentanone Derivatives: Domino Nickel-Catalyzed Difluorocyclopropanation/Ring Expansion Sequence of Silyl Dienol Ethers" Aono, T.; Sasagawa, H.; Fuchibe, K.; *Ichikawa, J. Org. Lett. 2015, 17 (23), pp.5736-5739. DOI:10.1021/acs.orglett.5b02726 |
|
|
"Pinpoint-Fluorinated Phenanthrene Synthesis based on C–F Bond Activation of Difluoroalkenes" Fuchibe, K.; Morikawa, T.; Ueda, R.; Okauchi, T.; *Ichikawa, J. J. Fluorine Chem. 2015, 179 (-), pp.106-115. DOI:10.1016/j.jfluchem.2015.06.008 |
||
|
"
Pinpoint-Fluorinated Phenacenes: New Synthesis and Solubility
Enhancement Strategies" Fuchibe,
K.; Morikawa, T.; Shigeno, K.; Fujita, T.; *Ichikawa, J.
Org. Lett. 2015, 17 (5), pp.1126-1129. DOI:10.1021/ol503759d |
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|
"Organocatalytic, Difluorocarbene-Based S-Difluoromethylation of Thiocarbonyl Compounds" Fuchibe, K.; Bando, M.; Takayama, R.; *Ichikawa, J. J. Fluorine Chem. 2015, 171 pp.133-138. DOI:10.1016/j.jfluchem.2014.08.013 |
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|
"Indium(III)-Catalyzed Cationic Cyclization of 1,1-Difluoroallenes:
Regioselective Synthesis of 1-Fluoronaphthalenes" Fuchibe, K.; Mayumi, Y.; Yokota, M.; Aihara, H.; *Ichikawa, J. Bull. Chem. Soc. Jpn 2014, 87 (9), pp.942-949. DOI:10.1246/bcsj.20140128 |
||
| Books |
「有機合成実験法ハンドブック」 中井武（編集代表） "19.2.8 バナジウム・ニオブ・タンタルの化合物" 渕辺耕平 丸善出版 (東京都) 2015, pp71-73. ISBN:978-4-621-08948-4 |
|
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「フッ素化学入門 2015」 （独）日本学術振興会・フッ素化学第１５５委員会 "II 有機フッ素化合物の合成反応（一部）" 渕辺耕平 他48名 三共出版 (東京都) 2015, pp199-207等. ISBN:978-4-7827-0727-2 |
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|
「Science of Synthesis Knowledge Updates 2014/2」 Brønsted Nielsen, M.; Krause, N.; Marek, I.; Shaumann, E.; Wirth, T. "1,1-Dihaloallenes (Update 2014)" Fuchibe, K.; Ichikawa, J. Thieme (Stuttgart) 2015, pp217-231. |
||
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Regioselective Synthesis of Fluorinated Cyclopentenonesvia Organocatalytic Generation of Difluorocarbene" ○Takayama, R.; Fuchibe, K.; *Ichikawa, J. INTERNATIONAL CONFERENCE ON FLUORINE CHEMISTRY 2014 TOKYO, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Organocatalytic Generation of Difluorocarbene: Synthesis of Difluoromethyl Thioimidates" ○Fuchibe, K.; Bando, M.; Takayama, R.; *Ichikawa, J. The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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|
口頭発表／ポスター発表 "Control of difluorocarbene generation by organocatalyst and its applications" ○Fuchibe, K.; Koseki,Y.; Aono, T.; Bando, M.; Takayama, R.; *Ichikawa, J. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Catalytic introduction of difluoromethyl and difluoromethylene groups with difluorocarbene and its complexes" ○Fuchibe, K.; Aono, T.; Hu, J.; Takayama, R.; Koseki, Y.; Bando, M.; *Ichikawa, J. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu (USA) 2015-12-15～2015-12-20 |
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|
招待講演 "1,1-Difluoroallenes as Synthetic Platforms: Indium-Catalyzed Domino Synthesis of Pinpoint-Fluorinated PAHs" *Fuchibe, K. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, Sendai (Japan) 2015-09-06～2016-09-09 |
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|
招待講演 "1,1-Difluoroallenes as Synthetic Platforms: Preparation and Domino Reactions" *Fuchibe, K. ICOMC 2014 Sendai Pre-Symposium, Sendai (Japan) 2014-07-11～2014-07-11 |
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| A02 荒井 孝義 | ||
| Original papers |
"Catalytic Asymmetric [3+2]-Cycloaddition for Stereodivergent Synthesis of Chiral Indolyl-pyrrolidines." *Arai, T.; Tokumitsu, C.; Miyazaki, T.; Kuwano, S.; Awata A. Org. Biomol. Chem. 2016, 14 pp.1831-1839. DOI:DOI: 10.1039/ c5ob02278a |
|
|
"Synthesis of Highly Functionalized Chiral Benzopyrano[3,4-c]pyrrolidines Bearing Five Contiguous Stereogenic Centers" Sato, T.; Miyazaki, T.; *Arai, T. J. Org. Chem. 2015, 80 pp.10346-10352. DOI:10.1021/acs.joc.5b01445 |
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|
"Catalytic Asymmetric Iodocyclization of N-Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8-Oxa-6-Azabicyclo[3.2.1]octanes." *Arai, T.; Watanabe, O.; Yabe, S.; Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 pp.12767-12771. DOI:10.1002/anie.201505748 |
Yamanaka, M. | |
|
"Recyclable poly-Zn3(OAc)4-3,3'-bis(aminoimino)binaphthoxide catalyst for asymmetric iodolactonization." *Arai, T.; Kojima, T.; Watanabe, O.; Itoh, T.; Kanoh, H. ChemCatChem. 2015, 7 pp.3234-3238. DOI:10.1002/cctc.201500842 |
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|
"Chiral Bis(imidazolidine)-derived NCN Pincer Rh Complex for Catalytic Asymmetric Mannich Reaction of Malononitrile with N-Boc Imines." *Arai, T.; Moribatake T.; Masu H. Chem. Eur. J. 2015, 21 pp.10671-10675. DOI:DOI: 10.1002/chem.201502097 |
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|
"PyBidine–NiCl2-Catalyzed Asymmetric Addition of Alcohols and Peroxides to Isatin-Derived Ketimines." *Arai, T.; Tsuchiya, K.; Matsumura E. Org. Lett. 2015, 17 pp.2416-2419. DOI:DOI: 10.1021/acs.orglett.5b00928 |
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|
"PyBidine-Cu(OTf)2-catalyzed
asymmetric [3+2] cycloaddition using
imino esters: Harmony of
Cu-Lewis acid and imidazolidine-NH
hydrogen-bonding in concerto
catalysis" *Arai, T.; Ogawa, H.; Awata, A.; Sato, M.; Watabe,
M.; *Yamanaka, M. 2015, 54 pp.1595-1599. DOI:10.1002/anie.201410782 |
Yamanaka, M. | |
|
"Design of a Chiral Secondary
Amine Ligand for Cu-catalyzed anti-Selective
Henry Reaction" *Arai, T.; Joko, A.
Sato, K. Synlett 2015, 26 pp.209-214. DOI:10.1055/s-0034-1379607 |
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|
"Imidazoline-aminophenol (IAP)-nickel complex: Structure and catalytic activity in 1,4-addition of 3-indolyl-3-oxindoles to nitroethylene" Awata, A.; Wasai, M.; Masu,
H.; Kado, S.; *Arai, T. 2014, pp.2470-2477. DOI:10.1002/chem.201304456 |
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|
"PyBidine/Copper Catalyst: Asymmetric exo′-Selective [3+2]
Cycloaddition using Imino Ester and Electrophilic Indole." Awata, A.; *Arai,
T. Angew. Chem. Int. Ed. 2014, 53 pp.10462-10465. DOI:10.1002/anie.201405223 |
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|
"Bis(imidazolidine)pyridine-NiCl2 Catalyst for Nitro-Mannich
Reaction of Isatin-Derived N-Boc Ketimines: Asymmetric Synthesis of
Chiral 3-Substituted 3-Amino-2-oxindoles" *Arai,
T.; Matsumura, E.; Masu, H. Org. Lett. 2014, 16 pp.2768-2771. DOI:10.1021/ol501085y |
||
|
"Trinuclear Zn3(OAc)4-3,3’-bis(aminoimino)binaphthoxide
Complex for Highly Efficient Catalytic Asymmetric Iodolactonization" *Arai,
T.; Sugiyama, N.; Masu, H.; Kado, S.; Yabe, S.; Yamanaka, M. Chem. Commun. 2014, 42 pp.8287-8290. DOI:10.1039/C4CC02415J |
Yamanaka, M. | |
|
"Switching Enantioface
Selection in the Asymmetric Nitro-Mannich Reaction Using Single Chiral
Bis(imidazolidine)pyridine-metal Catalysts" *Arai, T.;
Matsumura, E. Synlett 2014, 25 pp.1776-1780. DOI:10.1055/s-0034-1378204 |
||
|
"Diversity-Oriented Asymmetric
Catalysis (DOAC): Stereochemically Divergent Synthesis of Thiochromanes Using
an Imidazoline-Aminophenol-Nickel Catalyzed Michael/Henry Reaction" *Arai, T.; Yamamoto, Y Org. Lett. 2014, 16 pp.1700-1703. DOI:10.1021/ol500361w |
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|
"Chiral
Bis(oxazolidine)pyridine-Cu-Catalyzed Enantioselective Friedel-Crafts
Alkylation of Indole with Nitroalkenes" Sato, T.; *Arai, T. Synlett 2014, 25 pp.349-354. DOI:10.1055/s-0033-1340311 |
||
| Reviews / Accounts |
"高機能化する不斉ヨードラクトン化触媒(最新のトピックス)" 荒井孝義 化学 2015, 70 pp.66-67. |
|
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Development of chiral iodine-catalyst assisted with NH-hydrogen bonding" Arai, T. The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Diversity-oriented asymmetric catalysis (DOAC) for spirooxindoles" Arai, T. The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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|
招待講演 " Imidazoline-aminophenol(IAP)-metal Catalyzed Asymmetric Synthesis of Diversified Chiral Mixed 3,3’-bisindoles " Arai, T.The XXVI International Conference on Organometallic Chemistry （ICOMC2014）, 札幌 (日本) 2014-07-13～2014-07-18 |
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| Patent |
"光学活性なペルオキシド付加体およびその製造方法" 発明者：荒井孝義、土屋賢人 出願者：千葉大学 特願2015-089893号 2015-04-25, 2016-04, (国内) |
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"8-オキサ-6-アザビシクロ[3,2,1]オクタン誘導体およびその製造方法" 発明者：荒井孝義、渡辺旺嗣 出願者：千葉大学 2015-04-15, 特願2015-083791号 2016-04, (国内) |
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|
"アミノサリチルアルジミン配位子を金属に配位させた触媒およびこれを用いたヨード環化体の製造方法" 発明者：荒井孝義、渡辺旺嗣 出願者：千葉大学 特願2015-081322号 2015-04-12, 2016-04, (国内) |
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| A02 金井 求 | ||
| Original papers |
"An Expeditious Synthesis of Sialic Acid Derivatives by Copper(I)-Catalyzed Stereodivergent Propargylation of Unprotected Aldoses" X.-F. Wei, Y. Shimizu, *M. Kanai ACS. Cent. Sci. 2016, 2 pp.21-26. |
|
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"Chemo- and Regioselective Oxygenation of C(sp3)-H Bonds in Aliphatic Alcohols Using a Covalently Bound Directing Activator and Atmospheric Oxygen" Ozawa, J.; Tashiro, M.; Ni, J.; Oisaki, K.; *Kanai, M. Chem. Sci. 2016, 7 pp.1904-1909. |
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|
"Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols" Lin, L.; Yamamoto, K.; Mitsunuma, H.; Kanzaki, Y.; Matsunaga, S.;* Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.15418-15421. |
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|
"Supramolecular Ligands for Histone Tails by Employing a Multivalent Display of Trisulfonated Calix[4]arenes" Kimura, Y.; Saito, N.; Hanada, K.; Liu, J.; Okabe, T.; Kawashima, S. A.; Yamatsugu, K.; *Kanai, M. ChemBioChem 2015, 16 pp.2599-2604. |
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|
"Benzylic C(sp3)-H Perfluoroalkylation of 6-Membered Heteroaromatic Compounds" Yoichiro Kuninobu, Masahiro Nagase, *Motomu Kanai Angew. Chem. Int. Ed. 2015, 54 pp.10263-10266. |
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|
"A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate" Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, *Motomu Kanai Nature Chem. 2015, 7 pp.712-717. |
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|
"Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis" Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2015, 54 pp.9944-9947. |
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|
"Design and synthesis of biotin analogues reversibly binding with streptavidin" Yamamoto, T.; Aoki, K.; Sugiyama, A.; Doi, H.; Kodama, T.; Shimizu, Y.; *Kanai, M. Chem. Asian J. 2015, 10 pp.1071-1078. |
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|
"Organocatalytic Aerobic Oxdation to α-Fluoroalkyl Alcohols to Fluoroalkyl Ketones at Room Temperature" Kadoh, Y.; Tashiro, M.; Oisaki, K.; *Kanai, M. Adv. Synth. Catal. 2015, |
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|
"Chemoselective Boron-Catalyzed Nucleophilic Activation of Carboxylic Acids for Mannich-Type Reactions" Morita, Y.; Yamamoto, T.; Nagai, H.; Shimizu, Y.; *Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.7075-7078. |
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|
"Synthesis of chemically-tethered amyloid-β segment trimer possessing amyloidogenic properties" Shinoda, K.; Sohma, Y.; *Kanai, M. Bioorg. Med. Chem. Lett. 2015, 25 pp.2976-2979. |
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|
"Covalent modifier-type aggregation inhibitor of amyloid-β based on a cyclo-KLVFF motif" Kino, R.; Araya, T.; Arai, T.; Sohma, Y.; *Kanai, M. Bioorg. Med. Chem. Lett. 2015, 25 pp.2972-2975. |
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|
"Metal-free C(3)-H arylation of coumarins promoted by catalytic amounts of 5,10,15,20-tetrakis(4-diethylaminophenyl)porphyrin" Kojima, M.; Oisaki, K.; *Kanai, M. Chem. Commun. 2015, 51 pp.9718-9721. |
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|
"Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C-H Bond Activation" Wang, Z.; Kuninobu, Y.; *Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.6140-6143. |
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|
"Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates" Chikkade, P. K.; Kuninobu, Y.; *Kanai, M. Chem. Sci. 2015, 6 pp.3195-3200. |
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"A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles" Sun, B.; Yoshino, T.; Matsunaga, S.; *Kanai, M. Chem. Commun. 2015, 51 pp. 4649-4661. |
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"A Cyclic KLVFF-Derived Peptide Aggregation Inhibitor Induces the Formation of Less Toxic Off-Pathway Amyloid-beta Oligomers" Tadamasa Arai; Daisuke Sasaki; Takushi Araya; Takeshi Sato; Youhei Sohma; *Motomu Kanai ChemBioChem 2014, 15 pp.2577-2583. |
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"Copper-Mediated Direct C(sp3)-H and C(sp2)-H Acetoxylation" Wang, Z.; Kuninobu, Y.; *Kanai, M. Org. Lett. 2014, 16 pp.4790-4793. |
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"Chemoselective aerobic photo-oxidation of 9H-fluorenes for the synthesis of 9-fluorenones" Masahiro Kojima, Kounosuke Oisaki, *Motomu Kanai Tetrahedron Lett. 2014, 55 pp.4736-4738. |
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"Molybdenum-Mediated Desulfurization of Thiols and Disulfides" Zhen Wang, Yoichiro Kuninobu, *Motomu Kanai Synlett 2014, 25 pp.1869-1872. |
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"Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under Dinuclear Schiff Base Catalysis" Yingjie Xu, Keiichi Kaneko, Motomu Kanai, Masakatsu Shibasaki, and Shigeki Matsunaga J. Am. Chem. Soc. 2014, 136 pp.9190-9194. |
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"Rational Design and Identification of Non-Peptidic Aggregation Inhibitor of Amyloid-beta Based on a Pharmacophore Motif Obtained from cyclo[-Lys-Leu-Val-Phe-Phe-]" Tadamasa Arai, Takushi Araya, Daisuke Sasaki, Atsuhiko Taniguchi, Takeshi Sato, Youhei Sohma, *Motomu Kanai Angew. Chem. Int. Ed. 2014, 53 pp.8236-8239. |
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"Serine-Selective Aerobic Cleavage of Peptides and a Protein Using Water-Soluble Copper Organoradical Conjugate" Seki, Y.; Tanabe, K.; Sasaki, D.; Sohma, Y.; Oisaki, K.; *Kanai, M. Angew. Chem. Int. Ed. 2014, 53 pp.6501-6505. |
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"Chemoselective aerobic oxidation catalyzed by a metal/stable organoradical redox conjugate" Seki, Y.; Oisaki, K.; *Kanai, M. Tetrahedron Lett. 2014, 55 pp.3738-3746. |
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"Recent progress in copper-catalyzed difunctionalization of unactivated carbon-carbon multiple bonds" Shimizu, Y.; *Kanai, M. Tetrahedron Lett. 2014, 55 pp.3727-3737. |
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"Copper-Catalyzed Regio- and Stereoselective Intermolecular Three-Component Oxyarylation of Allenes" Itoh, T.; Shimizu, Y.; *Kanai, M. Org. Lett. 2014, 16 pp.2736-2739. |
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"Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt
Diiodide Complex as a Precursor for Cationic
(Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed
C-2 Selective C-H Amidation of Indoles" Sun, B.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Adv. Synth. Catal. 2014, |
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"Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed
Redox-Neutral Directed C–H Alkenylation/Annulation Sequence" Hideya Ikemoto, Tatsuhiko Yoshino, Ken Sakata, *Shigeki
Matsunaga, *Motomu Kanai J. Am. Chem. Soc. 2014, 136 pp.5424-5431. |
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"Palladium-Catalyzed Direct C–H Silylation and
Germanylation of Benzamides and Carboxamides" Kyalo Stephen Kanyiva, Yoichiro Kuninobu, Motomu Kanai Org. Lett. 2014, 16 pp.1968-1971. |
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"Asparagine-Selective Cleavage of Peptide Bonds through
Hypervalent Iodine-Mediated Hofmann Rearrangement in Neutral Aqueous Solution" Kana Tanabe, Atsuhiko Taniguchi, Takuya Matsumoto,
Kounosuke Oisaki, *Youhei Sohma, *Motomu Kanai Chem. Sci. 2014, 5 |
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"Copper-Catalyzed Benzylic C(sp3)-H Alkoxylation of
Heterocyclic Compounds" Takemura,
N.; Kuninobu, Y.; Kanai, M. Org. Biomol. Chem. 2014, 12 pp.2528-2532. |
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"Copper-Catalyzed Intramolecular C(sp3)–H
and C(sp2)–H Amidation by Oxidative Cyclization" Zhen Wang, Jizhi Ni, Yoichiro Kuninobu, Motomu Kanai Angew. Chem. Int. Ed. 2014, 53 pp.3496-3499. |
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"Synthesis
of Pyridine N-Oxide–BF2CF3 Complexes and Their
Fluorescence Properties" Tomoaki Nishida, Aiko Fukazawa, Eriko Yamaguchi,
Hiroya Oshima, Shigehiro Yamaguchi, *Motomu Kanai, *Yoichiro Kuninobu Chem. Asian J. 2014, 9 pp.1026-1030. |
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"Regioselective Trifluoromethylation of N-Heteroaromatic Compounds using Trifluoromethyldifluoroborane
Activator" Nishida, T.;
Ida, H.; Kuninobu, Y.; Kanai, M. Nature Communications 2014, 5 pp.3387-3392. DOI:10.1038/ncomms4387 |
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"Catalytic
enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds
via consecutive intramolecular amido-cupration of allenes and asymmetric
addition of carbonyl compounds" Prasanna Kumara
Chikkade, Yohei Shimizu, *Motomu Kanai Chem. Sci. 2014, 5 pp.1585-1590. |
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"Cobalt-Catalyzed C-4 Selective Alkylation of
Quinolines" Yamamoto, S.; Saga, Y.; Andou, T.; *Matsunaga, S.;
*Kanai, M. Adv. Synth. Catal. 2014, 356 pp.401-405. |
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"A
Catalytic C-C Bond-Formation with Minimal Use of Protecting Groups:
Construction of Functionalized Isotetronic Acid Derivatives" *Yohei Shimizu, Kouji Yasuda, *Motomu Kanai Heterocycles 2014, 88 pp.919-927. |
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"Attenuation of the Aggregation and Neurotoxicity of
Amyloid-β Peptides by Catalytic Photooxygenation" Taniguchi, A.; Sasaki, D.; Shiohara, A.; Iwatsubo, T.;
Tomita, T.; *Sohma, Y.; *Kanai, M. Angew. Chem. Int. Ed. 2014, 53 pp.1382-1385. |
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"Rh-Catalyzed Aldehyde–Aldehyde Cross-Aldol Reaction
under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through
Orthogonal Activation" Luqing Lin, Kumiko Yamamoto, *Shigeki Matsunaga, *Motomu
Kanai Chem. Asian J. 2013, 8 pp.2974-2983. |
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"Catalytic Anomeric Aminoalkynylation of Unprotected
Aldoses" Kimura, Y.;
Ito, S.; Shimizu, Y.; *Kanai, M. Org. Lett. 2013, 15 pp.4130-4133. |
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"Copper-Catalyzed
Intramolecular N–S Bond Formation by Oxidative Dehydrogenative Cyclization" Zhen
Wang, Yoichiro Kuninobu, Motomu
Kanai J. Org. Chem. 2013, 78 pp.7337-7342. |
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"Manganese-Catalyzed Aerobic Dehydrogenative
Cyclization toward Ring-Fused Indole Skeletons" *Oisaki, K.; Abe, J.; *Kanai, M. Org. Biomol. Chem. 2013, 11 pp.4569-4572. |
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"Cp*CoIII-Catalyzed
C2-Selective Addition of Indoles to Imines" Tatsuhiko
Yoshino, Hideya Ikemoto, *Shigeki Matsunaga and *Motomu Kanai Chem. Eur. J. 2013, 19 pp.9142-9146. |
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"In situ Catalytic
Generation of Allylcopper Species for Asymmetric Allylation: Toward 1H-Isochromene
Skeletons" Junya
Kawai, Prasanna Kumara Chikkade, Yohei Shimizu and *Motomu Kanai Angew. Chem. Int. Ed. 2013, 52 pp.7177-7180. |
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"“From Chiral Base Catalysts to Redox-Active Catalysts: Chasing the Identity of Metal Catalysts in Carbon–Carbon Bond-Forming Reactions”" *Motomu Kanai, Shigeki Matsunaga, Kounosuke Oisaki, Yohei Shimizu J. Synth. Org. Chem.Japan 2013, 71 pp.433-442. |
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"“Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with N-Fluorobenzenesulfonimide”" Keiichi Kaneko, Tatsuhiko Yoshino, *Shigeki Matsunaga, *Motomu Kanai Org. Lett. 2013, 15 |
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"“Catalytic Asymmetric Synthesis of Spirooxindoles via Addition of Isothiocyanato Oxindoles to Aldehydes Under Dinuclear Nickel Schiff Base Catalysis”" Shota Kato, *Motomu Kanai, *Shigeki Matsunaga Chem. Eur. J. 2013, |
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"“Iron-Catalyzed Oxidative C(3)¬–H Functionalization of Amines”" Noriaki Takasu, *Kounosuke Oisaki, and *Motomu Kanai Org. Lett. 2013, 15 pp.1918-1921. |
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"“Intracellular activation of acetyl-CoA by an artificial reaction promoter and its fluorescent detection”" Hirokazu Komatsu, Yutaka Shindo, Shigehiro A. Kawashima, Kenzo Yamatsugu, Kotaro Oka, *Motomu Kanai Chem. Commun. 2013, 49 pp.2876-2878. |
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"“Copper-Catalyzed C–H Alkoxylation of Azoles”" Noriaki Takemura, *Yoichiro Kuninobu, *Motomu Kanai Org. Lett. 2013, 15 pp.844-847. |
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"“Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines”" Takashi Andou, Yutaka Saga, Hirotomo Komai, *Shigeki Matsunaga, *Motomu Kanai Angew. Chem. Int. Ed. 2013, 52 pp.3213-3216. |
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"“A Cationic High-Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed C-H Bond Activation”" Yoshino, T. Ikemoto, H.; *Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2013, 52 pp.2207-2211. |
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"“Synthesis of a New Oseltamivir Derivative Through Late-Stage Catalytic C-H Functionalization” " Kenta Saito, *Motomu Kanai Heterocycles 2013, 86 pp.1565-1574. |
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"“Copper(I)-Catalyzed Enantioselective Incorporation of Ketones to Cyclic Hemiaminals for the Synthesis of Versatile Alkaloid Precursors”" Shi, S.-L.; Wei, X.-F.; Shimizu, Y.; *Kanai, M. J. Am. Chem. Soc. 2012, 134 pp.17019-17022. |
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"“Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols”" Luqing Lin, Kumiko Yamamoto, *Shigeki Matsunaga, *Motomu Kanai Angew. Chem. Int. Ed. 2012, 51 pp.10275-10279. |
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"“Catalytic aerobic production of imines en route to mild, green, and concise derivatizations of amines”" Toshiaki Sonobe, *Kounosuke Oisaki, *Motomu Kanai Chem. Sci. 2012, 3 pp.3249-3255. |
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"“Cu(I)-catalyzed α-alkylation of ketones with styrene derivatives”" Shohei Majima, *Yohei Shimizu, *Motomu Kanai Tetrahedron Lett. 2012, 53 pp.4381-4384. |
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"“Functional-Group-Tolerant Catalytic Migratory Oxidative Coupling of Nitrones”" Shogo Hashizume, *Kounosuke Oisaki and *Motomu Kanai Chem. Asian J. 2012, 7 pp.2600-2606. |
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"“Catalytic Asymmetric Synthesis of Spirooxindoles by a Mannich-Type Reaction of Isothiocyanato Oxindoles”" Shota Kato, Tatsuhiko Yoshino, Masakatsu Shibasaki, *Motomu Kanai and *Shigeki Matsunaga Angew. Chem. Int. Ed. 2012, 51 pp.7007-7010. |
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""Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes; Addition to Imines and Enones" " Komai, H.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Synthesis 2012, 44 pp.2185-2194. |
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""Mg-catalyzed Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to Imines" " Yudai Suzuki, *Motomu Kanai, *Shigeki Matsunaga Chem. Eur. J. 2012, 18 pp.7654-7657. |
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"“Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine through Double Michael Reaction of Bisoxindole”" Mitsunuma, H.; Shibasaki, M.; *Kanai, M.; *Matsunaga, S. Angew. Chem. Int. Ed. 2012, 51 pp.5217-5221. |
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"“Asymmetric Synthesis of Dihydropyranones from Ynones by Sequential Copper(I)-Catalyzed Direct Aldol and Silver(I)-Catalyzed Oxy-Michael Reactions” " Shi, S.-L.; *Kanai, M.; *Shibasaki, M. Angew. Chem. Int. Ed. 2012, 51 pp.3932-3935. |
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"“Cu(I)-Catalyzed Decarboxylative Aldol-Type And Mannich-Type Reactions For Asymmetric Construction Of Contiguous Trisubstituted and Quaternary Stereocenters”" Yin, L.; *Kanai, M.; *Shibasaki, M. Tetrahedron 2012, 68 pp.3497-3506. |
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| Books |
「未来を拓く元素戦略－持続可能な社会を実現する化学－」 日本化学会 "銅触媒の多様な活性化形式を活用する反応開発と医薬リード合成" 嵯峨裕、金井求 化学同人 (京都市) 2013, pp39-44. |
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「Organic Chemistry–Breakthroughs and Perspectives」 Kuiling Ding and Li-Xin Dai "Recent Topics in Cooperative Catalysis: Asymmetric Catalysis, Polymerization, Hydrogen Activation, and Water Splitting" ○Motomu Kanai Wiley-VCH (Germany) 2013, pp385-412. ISBN |
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| Conference / Symposium / Lecture |
"Catalysis medicine: artificial catalysis in cells as a new modal medicine" ○Motomu Kanai 2015 Queenstown Molecular Biology Meetings in Shanghai, Shanghai (China) 2015-03-19～2015-03-20 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry, Vanderbilt University, Nashville (USA) 2014-04-28～2014-04-28 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX (USA) 2014-04-25～2014-04-25 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry and Biochemistry, UCLA, LA (USA) 2014-04-24～2014-04-24 |
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招待講演 "Cu-Catalyzed Asymmetric C–C Bond-Formations" Kanai, M. 12th Symposium on Chemical Approaches to Chirality, Tokyo (Japan) 2013-11-27～2013-11-27 |
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招待講演 "Cu-Catalyzed Reactions: Asymmetric Catalysis,
Carbohydrate Derivatization, and C-H Functionalization" Kanai, M. The Second International Conference on the Frontier Research in Organic Synthesis and Materials, Hsinchu (Taiwan) 2013-09-21～2013-09-22 |
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口頭発表／ポスター発表 "“Direct Benzylic C-H Bond Functionalization of Azaarenes” " ○Komai, H.; Yoshino, T.; Matsunaga, S.; Kanai, M. Program for Young Researcher Symposium in Europe’ supported by Graduate School of Pharmaceutical Sciences, ケンブリッジ（ケンブリッジ大学） (イギリス) 2012-06-06～2012-06-14 |
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口頭発表／ポスター発表 "Development of a Catalytic C-C Bond-Forming Reaction to Unprotected Aldoses" ○Yasuaki Kimura, Soichi Itoh, Yohei Shimizu, Motomu Kanai 13th Belgian Organic Synthesis Symposium, レーベン (ベルギー) 2012-07-15～2012-07-20 |
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口頭発表／ポスター発表 "Development of Cobalt(III)-Catalyzed Directed C-H Bond Functionalization Reactions" ○T. Yoshino, H. Ikemoto, S. Matsunaga, M. Kanai 2nd Junior International Conference on Cutting-Edge Organic Chemistry in Asia, クアラルンプール (マレーシア) 2012-12-08～2012-12-10 |
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口頭発表／ポスター発表 ""Catalytic Migratory Oxidative Coupling of Nitrones"" ○S.Hashizume, K.Oisaki, M.Kanai Program for Young Researcher Symposium in Europe’ supported by Graduate School of Pharmaceutical Sciences, U-Tokyo, ケンブリッジ（ケンブリッジ大学） (イギリス) 2012-06-06～2012-06-14 |
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口頭発表／ポスター発表 ""Catalytic Aerobic Production of Imines en Route to Mild, Green and Concise Derivatizations of Amines"" ○Kounosuke Oisaki, Toshiaki Sonobe, Motomu Kanai Frontiers of Organometallic Chemistry (FOC-2012), サンクトペテルブルグ (ロシア) 2012-09-21～2012-09-22 |
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口頭発表／ポスター発表 ""Catalytic Aerobic Production of Imines en Route to Mild, Green and Concise Derivatizations of Amines"" ○Kounosuke Oisaki, Toshiaki Sonobe, Motomu Kanai Catalysis in Organic Synthesis (ICCOS-2012), モスクワ (ロシア) 2012-09-15～2013-09-20 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Peking University in 北京 (中華人民共和国) 2012-06-29～2012-06-29 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Lanzhou University in 蘭州 (中華人民共和国) 2013-06-28～2013-06-28 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Shanghai Institute of Materia Medica in 上海 (中華人民共和国) 2012-06-26～2012-06-26 |
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口頭発表／ポスター発表 " “Catalytic Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to Imines” " ○Suzuki Yudai, Matsunaga Shigeki, Kanai MotomuSymposium Molecular Chirality ASIA 2012, 福岡市 (日本) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 " “The construction of spiro(imidazoline-indorinone) frameworks aiming at development of new antineoplastic agents” " ○Shota Kato, Seiko Kitahara, Tatsuhiko Yoshino, Shigeki Matsunaga, Motomu KanaiSymposium Molecular Chirality ASIA 2012, 福岡市 (日本) 2012-05-17～2012-05-18 |
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招待講演 "”Asymmetric C–C Bond-Formations Promoted by Cu(I)-Conjugated Brønsted Base Catalysts”" ○Motomu Kanai 4th UK/Japan Conference in Asymmetric Synthesis, 仙台市 (Japan) 2013-04-19～2013-04-19 |
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招待講演 "“First-row Transition Metal-Catalyzed C–C Bond Formations”" ○Motomu Kanai The 7th International Forus on Chemistry of Functional Organic Chemicals (IFOC-7), 東京 (日本) 2012-11-18～2012-11-18 |
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招待講演 " “Cu(I)-Catalyzed C-C Bond-Formations: Asymmetric Catalysis, Carbohydrate Derivatization, and Redox Catalysis”" ○Motomu Kanai The 5th International Forum on Homogeneous Catalysis, 上海 (China) 2012-10-11～2012-10-11 |
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招待講演 " “Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling” " ○Motomu KanaiACP Lectureship Award in China, Shanghai Institute of Organic Chemistry (SIOC) in 上海 (中華人民共和国) 2012-06-25～2012-06-25 |
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| Media |
"Functional-Group-Tolerant Catalytic Migratory
Oxidative Coupling of Nitrones" Shogo
Hashizume, Kounosuke Oisaki, Motomu Kanai Chem. Asian J. 2012-10-10 PDF 水中でも実施可能な収束的触媒的酸化カップリング反応を見出した。 |
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"窒素原子隣接位から炭素骨格を伸ばす触媒反応" 園部敏亮、生長幸之助、金井求 薬事日報 2013-03-22 PDF 酸素を吸収して水を排出しながら炭素骨格構築を行う触媒反応を見出した。 |
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| A02 工藤 一秋 | ||
| Original papers |
"Solvolysis of formylphenyl esters by a bifunctional peptide catalyst" K. Akagawa, *K. Kudo Chem. Lett. 2016, 45 pp.300-302. DOI:10.1246/cl.151154 |
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"Asymmetric Epoxidation of Enones by Peptide-Based Catalyst: A Strategy Inverting Juliá–Colonna Stereoselectivity" K. Akagawa,T. Hirata, *K. Kudo Synlett 2016, pp.1217-1222. DOI:10.1055/s-0035-1560597 |
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"Kinetic Resolution of a Planar-Chiral [2.2]Paracyclophane Derivative by Helical-Peptide-Catalyzed Michael Addition of Nitromethane" K. Akagawa, N. Nishi, I. Yoshikawa, *K. Kudo Eur. J. Org. Chem. 2015, pp.5055-5059. DOI:10.1002/ejoc.201500594 |
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"Peptide-Catalyzed Desymmetrization of an Achiral Ferrocenyl Compound To Induce Planar Chirality" K. Akagawa, M. Akiyama, *K. Kudo Eur. J. Org. Chem. 2015, pp.3894-3898. DOI:10.1002/ejoc.201500428 |
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"Histidine-Containing Peptide Catalysts Developed by a Facile Library Screening Method" K. Akagawa, N. Sakai, *K. Kudo Angew. Chem. Int. Ed. 2015, 54 pp.1822-1826. DOI:10.1002/anie.201410268 |
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"Peptide-Catalyzed Kinetic Resolution of Planar-Chiral Metallocenes" M. Akiyama, K. Akagawa, H. Seino, *K. Kudo Chem. Commun. 2014, 50 pp.7893-7896. DOI:10.1039/C4CC03266G |
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"Peptide-catalyzed consecutive 1,6- and 1,4-additions of thiols to α,β,γ,δ-unsaturated aldehydes" K. Akagawa, N. Nishi, J. Sen, *K. Kudo Org. Biomol. Chem. 2014, DOI:10.1039/C4OB00565A |
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"Development of a Peptide-Based Primary Aminocatalyst with a Helical Structure" K. Akagawa, R. Suzuki, *K. Kudo Asian J. Org. Chem. 2014, 4 pp.514-522. DOI:10.1002/ajoc.201400028 |
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"Peptide-Catalyzed Diastereo- and Enantioselective Cyclopropanation of Aromatic α,β-Unsaturated Aldehydes" K. Akagawa, S. Takigawa, I. S. Nagamine, R. Umezawa, *K. Kudo Org. Lett. 2013, 15 pp.4964-4967. DOI:10.1021/ol402227y |
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"Peptide-Catalyzed Regio- and Enantioselective Reduction of α,β,γ,δ-Unsaturated Aldehydes" K. Akagawa, J. Sen, *K. Kudo Angew. Chem. Int. Ed. 2013, 52 pp.11585-11588. DOI:10.1002/anie.201305004 |
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"Transformation of Gold(I)-cyclo[-Met-Met-] Complex Supramolecular Fibers into Aligned Gold Nanoparticles" M. Furutani, *K. Kudo Chem. Lett. 2013, 42 (6), pp.601-603. DOI:10.1246/cl.130106 |
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"Asymmetric α-amination of aldehydes by recyclable resin-supported peptide catalyst" T. Tanaka, K. Akagawa, M. Mitsuda, *K.Kudo, Adv. Synth. Catal. 2013, 355 (2-3), pp.294-296. DOI:10.1002/adsc.201200611 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes" K. Akagawa, *K. Kudo Angew. Chem. Int. Ed. 2012, 51 pp.12786-12789. DOI:10.1002/anie.201206916 |
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"Asymmetric one-pot sequential Friedel-Crafts-type alkylation and α-oxyamination catalyzed by a peptide and an enzyme" K. Akagawa, R. Umezawa, *K. Kudo Beilstein J. Org. Chem. 2012, 8 pp.1333-1337. DOI:10.3762/bjoc.8.152 |
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"Effect of the Helical Tether of a Resin-Supported Peptide Catalyst for Friedel-Crafts-Type Alkylation in Water" K. Akagawa, R. Suzuki, *K. Kudo Adv. Synth. Catal. 2012, 354 pp.1280-1286. DOI:10.1002/adsc.201100950 |
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"Asymmetric induction by helical poly(amino acid)s in cyanosilylation of aldehydes" *K. Akagawa, *K. Kudo Tetrahedron Lett. 2012, 53 (45), pp.5981-5983. DOI:10.1016/j.tetlet.2012.07.034 |
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"Asymmetric Michael addition of boronic acids to a γ-hydroxy-α,β-unsaturated aldehyde catalyzed by resin-supported peptide." K. Akagawa, M. Sugiyama, *K. Kudo Org. Biomol. Chem. 2012, 10 (25), pp.4839-4843. DOI:10.1039/C2OB25431J |
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"Sequential oxidation/asymmetric aldol reaction of primary alcohols by resin-supported catalysts" K. Akagawa, S. Takigawa, E. Mano and *K. Kudo Tetrahedron Lett. 2011, 52 pp.770-773. |
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"Synthesis of Indenes by Intramolecular Morita-Baylis-Hillman Reaction in Aqueous Media Catalyzed by Resin-Supported Proline" K. Akagawa, S. Sakamoto and *K. Kudo Synlett 2011, pp.817-820. |
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"Peptide/Laccase Cocatalyzed Asymmetric α-Oxyamination of Aldehydes" K. Akagawa, *K. Kudo Org. Lett. 2011, 13 pp.3498-3501. |
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"Asymmetric Epoxidation of alpha,beta-Unsaturated Aldehydes in Aqueous Media Catalyzed by Resin-Supported Peptide-Containing Unnatural Amino Acids" K. Akagawa, *K. Kudo Adv. Synth. Catal. 2011, 353 pp.843-847. |
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| Books |
「化学はじめの一歩シリーズ 有機化学」 工藤一秋，渡辺正 化学同人 (京都) 2016, ISBN:978-4759816341 |
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「ナノエレクトロニクスにおける絶縁超薄膜技術」 "low-k薄膜絶縁材料開発" 工藤一秋 シーエムシー (東京) 2013, pp189-198. ISBN:978-4864690393 |
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「Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis」 Itsuno S. "Peptide-catalyzed asymmetric synthesis" K. Kudo, K. Akagawa Wiley 2011, pp91-123. ISBN:0470568208 |
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| Reviews / Accounts |
"選択的ペプチド触媒の今とこれから―人工ペプチドで酵素に迫る" 工藤一秋 化学 2014, 69 pp.64-65. |
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"樹脂固定化ペプチドによる高選択的反応の開発" 赤川賢吾，工藤一秋 化学と工業 2014, 67 pp.477-479. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Screening of peptide libraries for discovering efficient aminocatalysts" ○K. Akagawa, J. Satou, *K. Kudo International Chemical Congress of Pacific Basin Societies 2015, Honolulu (USA) 2016-05-06～2016-05-06 |
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依頼講演 "Development of selective peptide catalysts having secondary structures" ○*K. Kudo,K. Akagawa International Chemical Congress of Pacific Basin Societies 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Peptide-catalyzed regio- and enantioselective reduction" ○Kengo Akagawa, Jun Sen, *Kazuaki Kudo 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Polymer Electrolyte Membranes for Fuel Cells of Graft-type sulfonated Polybenzimidazoles" ○J.Park,M.Asano,Y.Maekawa,*K.Kudo PRiME 2012, Honolulu (USA) 2012-10-07～2012-10-12 |
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口頭発表／ポスター発表 "Synthesis and Properties of Alicyclic Polyimides Using Unsymmetrical Spiroalicyclic Dianhydride" ○*K.Kudo SAMPE TECH 2012, Charleston (USA) 2012-10-22～2012-10-25 |
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口頭発表／ポスター発表 "Construction of All-Carbon Quaternary Stereocenter by Asymmetric Michael Addition of Nitromethane to β,β-Disubstituted Aldehydes with Peptide Catalyst " ○Kengo Akagawa, *Kazuaki Kudo IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Asymmetric alpha-Amination of Aldehyde by Recyclable Resin-supported Peptide Catalyst" ○Tatsuyoshi Tanaka, Kengo Akagawa, Masaru Mitsuda, *Kazuaki Kudo IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Resin-bound peptides as asymmetric
aminocatalysts" ○*Kazuaki Kudo 1st Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "Effect of Helical Tether on the Catalytic Performance of Resin-Supported Peptides for Asymmetric Organic Transformations" Akagawa, K.; ○*Kudo, K 6th International Conference on Cutting-Edge Organic Chemistry in Asia(ICCEOCA-6), 香港 (香港) 2011-12-11～2011-12-15 |
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| Patent |
"耐熱性高分子電解質膜及びその製造方法" 発明者：工藤 一秋，高山 俊雄，朴 俊，浅野 雅春，前川 康成 出願者：国立大学法人 東京大学，独立行政法人日本原子力研究開発機構 2011-245110 2011-11-09, 2013-06, (国内) |
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| Media |
2015-08-26 "Resolution of a Planar-Chiral [2.2]Paracyclophane Derivative by Helical-Peptide-Catalyzed Michael Addition of Nitromethane"がEur. J. Org. Chem.誌23号(2015年)のcover pictureに採用 |
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2015-07-08 EurJOC誌掲載の面不斉[2.2]パラシクロファンの速度論的光学分割(Eur. J. Org. Chem., 5055-5059 (2015))が，”Non-Racemic Planar-Chiral Cyclophanes”というタイトルでChemViews Magazineで取り上げられた。 |
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"東大 ペプチド触媒開発" 工藤一秋 日経産業新聞 2014-07-10 |
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"Peptide-Catalyzed Regio- and Enantioselective Reduction of α,β,γ,δ-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 52, 11585–11588 (2013))が、Synfacts 誌 2014(1), 97 に掲載" K. Akagawa, J. Sen, K. Kudo Synfacts 2013-12-13 |
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"Peptide-Catalyzed Diastereo- and Enantioselective Cyclopropanation of Aromatic α,β-Unsaturated Aldehydes (Org. Lett. 15, 4964–4967 (2013))が、Synfacts 誌 2014(1), 99 に掲載" K. Akagawa, K. Kudo Synfacts 2013-12-13 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 51, 12786-12789 (2012))が、Synform 2013(3), A32で取り上げられた" K. Akagawa, K. Kudo Synform 2013-02-15 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 51, 12786-12789 (2012))が、Synfacts 誌 2013, 9(3), 340に掲載. " K. Akagawa, K. Kudo Synfacts 2013-02-15 |
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"Asymmetric induction by helical poly(amino acid) in cyanosilylation of aldehydes, (Tetrahedron Lett., 53, 5981-5983 (2012))が、Chirality, On the Other Handというタイトルで、ポリアミノ酸による不斉反応が天然分子のホモキラリティーの起源となっている可能性があると紹介された" K. Akagawa, K. Kudo ChemViews Magazine 2012-10-10 |
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"Asymmetric induction by helical poly(amino acid) in cyanosilylation of aldehydes, (Tetrahedron Lett., 53, 5981-5983 (2012))が、Synfacts 誌 2013, 9(2), 225に掲載" K. Akagawa, K. Kudo Synfacts 2013-01-18 |
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"Asymmetric Michael addition of boronic acids to a γ-hydroxy-α,β-unsaturated aldehyde catalyzed by resin-supported peptide.(Org. Biomol. Chem. 10 4839-4843 (2012))が、Synfacts 誌 2012, 8(9), 1に掲載" K. Akagawa, M. Sugiyama, K. Kudo Synfacts 2012-08-21 |
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"Peptide/Laccase Cocatalyzed Asymmetric α-Oxyamination of Aldehydes, (Org. Lett. 13, 3498-3501 (2011))が、Synfacts 誌 2011(9), 1027 に掲載" K. Akagawa, K. Kudo Synfacts 2011-08-19 |
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"Epoxidation of alpha,beta-Unsaturated Aldehydes in Aqueous Media Catalyzed by Resin-Supported Peptide-Containing Unnatural Amino Acids (Adv. Synth. Catal. 353, 843-847 (2011))が、Synfacts 誌 2011(7), 803 に掲載" K. Akagawa, K. Kudo Synfacts 2011-06-17 |
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| A02 西林 仁昭 | ||
| Original papers |
"Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage" Nakajima,K.; Nojima, S.; Sakata, K.; *Nishibayashi, Y. ChemCatChem. 2016, 8 (6), pp.1028-1032. DOI:10.1002/cctc.201600037 |
坂田健 |
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"Recent Progress in Transition Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions " Y. Nishibayashi Inorg. Chem. 2015, 54 pp.9234-9247. DOI:10.1021/acs.inorgchem.5b00881 |
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"Nitrogen Fixation Catalyzed by Ferrocene-Substituted Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes: Unique Behavior of Ferrocene Moiety as Redox Active Site" S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and *Y. Nishibayashi Chem. Sci. 2015, 6 pp.3940-3951. DOI:10.1039/C5SC00545K |
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"Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes" K. Nakajima, S. Takata, K. Sakata, and *Y. Nishibayashi Angew. Chem. Int. Ed. 2015, 54 pp.7597-7601. DOI:10.1002/anie.201502531 |
坂田 健 | |
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"Catalytic Reduction of Dinitrogen into Ammonia by Use of Molybdenum-Nitride Complexes Bearing Tridentate Triphosphine as Catalysts " K. Arashiba, E. Kinoshita, S. Kuriyama, A. Eizawa, K. Nakajima, H. Tanaka ,K. Yoshizawa, and *Y. Nishibayashi J. Am. Chem. Soc. 2015, 137 pp.5666-5669. DOI:10.1021/jacs.5b02579 |
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"Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions " R. Imayoshi, H. Tanaka, Y. Matsuo, M. Yuki, K. Nakajima, K. Yoshizawa, and *Y. Nishibayashi Chem. Eur. J. 2015, 21 pp.8905-8909. DOI:10.1002/chem.201501088 |
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"Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexex as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents " M. Yuki, K. Sakata, Y. Hirao, N. Nonoyama, K. Nakajima, and Y. Nishibayashi* J. Am. Chem. Soc. 2015, 137 pp.4173-4182. DOI:10.1021/jacs.5b00584 |
坂田 健 | |
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"Copper-Catalyzed Enantioselective Etherification of Propargylic Esters with Alcohols " K. Nakajima, M. Shibata, and Y. Nishibayashi* J. Am. Chem. Soc. 2015, 137 pp.2472-2475. DOI:10.1021/jacs.5b00004 |
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"Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands " E. Kinoshita, K. Arashiba, S. Kuriyama, A. Eizawa, K. Nakajima, and Y. Nishibayashi* Eur. J. Inorg. Chem. 2015, pp.1789-1794. DOI:DOI: 10.1002/ejic.201500017 |
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"Radical Addition to Corannulene Mediated by Visible Light-Photoredox Catalysts " K. Nakajima, Y. Ashida, S. Nojima, and Y. Nishibayashi* Chem. Lett. 2015, pp.545-547. DOI:10.1246/cl.150019 |
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"Cooperative Catalytic Reactions: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide Hybrid Catalysts" Y. Senda, K. Nakajima, and Y. Nishibayashi* Angew. Chem. Int. Ed. 2015, 54 pp.4060-4064. DOI:DOI: 10.1002/anie.201411601 |
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"Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand " K. Arashiba, K. Nakajima, and Y. Nishibayashi* Z. Anorg. Allg. Chem. 2015, 641 pp.100-104. DOI:10.1002/zaac.201400117 |
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"Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand " Y. Tanabe, S. Kuriyama, K. Arashiba, K. Nakajima, and *Y. Nishibayashi Organometallics 2014, 33 pp.5295-5600. |
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"Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine" T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, and *Y. Nishibayashi Angew. Chem. Int. Ed. 2014, 53 pp.11488-11492. |
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"Synthesis of Nitrogen Heterocycles via a-Aminoalkyl Radicals Generated from a-Silyl Secondary-Amines under Visible Light Irradiation " K. Nakajima, M. Kitagawa, Y. Ashida, *Y. Miyake, and *Y. Nishibayashi Chem. Commun. 2014, 50 pp.8900-8903. |
三宅由寛 | |
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"Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides " Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and *Y. Nishibayashi Org. Biomol. Chem. 2014, 12 pp.5594-5596. |
三宅由寛 | |
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"Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand " S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, N. Kamaru, K. Yoshizawa, and *Y. Nishibayashi J. Am. Chem. Soc. 2014, 136 pp.9719-9731. |
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"Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst" M. Shibata, K. Nakajima, and *Y. Nishibayashi Chem. Commun. 2014, 50 pp.7874-7877. |
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"Visible Light-Mediated Addition of a-Aminoalkyl Radicals to [60]Fullerene Using Photoredox Catalysts" Y. Miyake,* Y. Ashida, K. Nakajima, and *Y. Nishibayashi Chem. Eur. J. 2014, 20 pp.6120-6126. |
三宅由寛 | |
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"Unique Behavior of Dinitrogen-Bridged Dimolybdenum Complexes Bearing Pincer Ligand towards Catalytic Formation of Ammonia " H. Tanaka, K. Arashiba, S. Kuriyama, A. Sasada, K. Nakajima, K. Yoshizawa,* and *Y. Nishibayashi Nature Communications 2014, 5 pp.3737. |
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| Reviews / Accounts |
"Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes" Tanabe, Y.; *Nishibayashi, Y. Chemical Record 2016, |
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"有機分子触媒と遷移金属触媒とを協奏的に利用した分子変換反応" 三宅由寛、中島一成、西林仁昭* 有機分子触媒の最前線 (日本化学会 Current Review) 2016, |
三宅由寛 | |
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"常温常圧下での触媒的窒素固定法開発の最近の進展" 田邊資明、西林仁昭* 日本エネルギー学会誌 2016, |
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"遷移金属錯体を触媒として利用した触媒的アンモニア合成法の開発" 田邊資明、西林仁昭* ファインケミカル 2016, 45 pp.7-18. |
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"特集にあたって-ハーバー・ボッシュ法を超えるアンモニア合成法開発への挑戦-" 西林仁昭* ファインケミカル 2016, 45 pp.5-6. |
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"非白金分子触媒による触媒的水素酸化反応の開発" 結城雅弘、西林仁昭* ENEOS Technical Review 2016, 58 (1), pp.12-18. |
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"温和な反応条件下での触媒的窒素固定法に関する最近の進展" 荒芝和也、西林仁昭* 化学工業 2016, 67 (1), pp.1-5. |
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"白金触媒に匹敵するアノード分子触媒の開発" 結城雅弘、西林仁昭* エネルギーデバイス 2015, 2 (7), pp.92-96. |
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"常温常圧でのアンモニアの合成" 田邊資明、西林仁昭* アンモニアを用いた水素利用システム 2015, pp.87-101. |
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"Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions" Y. Nishibayashi* Comptes rendus Chimie 2015, 18 pp.776-784. DOI:10.1016/j.crci.2015.01.014 |
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"温和な反応条件下での遷移金属窒素錯体を分子触媒として用いた窒素分子からのアンモニア合成反応の開発" 西林仁昭* 触媒 2015, 57 pp.33-38. |
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"常温常圧下での触媒的アンモニア合成反応開発の現状と将来展望" 田邊資明、*西林仁昭 日本エネルギー学会誌 2014, pp.386-392. |
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"遷移金属窒素錯体を用いた触媒的窒素固定反応に関する最近の進展" *西林仁昭、荒芝和也、結城雅弘 有機合成化学協会誌 2014, 72 pp.529-537. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "
Theoretical Study on Cobalt-Catalyzed Transformation of Molecular
Dinitrogen into Silylamine " Tanaka, H.; Imayoshi, R.; Matsuo, Y.; Yuki, M.; Nakajima, K.; Yoshizawa, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Synthesis and Catalytic Activity of Dimolybdenum-Dinitrogen Complex Bearing PCP-Type Pincer Ligands " Eizawa, A.; Arashiba, K.; Kuriyama, S.; Nakajima, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with Dihydropyridines via Dual Carbon-Carbon Bond Cleavage " Nojima, S.; Nakajima, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Synthesis of Phosphabenzenes by Iron-Catalyzed
[2+2+2] Cycloaddition of Diynes with Phosphaalkyne " Nakajima, K.; Takata, S.; Sakata, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
坂田健 | |
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口頭発表／ポスター発表 "
Enantioselective Propargylic Alkylation of
Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide
Hybrid Catalysts " Nakajima, K.; Senda, Y.; *Nishibayashi, Y. The 39th Naito Conference on the Chemistry of Organocatalysts, 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions " *Nishibayashi, Y. 80. The 2015 International Chemical Congress of Pacific Basin Societies, ハワイ (アメリカ合衆国) 2015-12-15～2015-12-20 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions " *Nishibayashi, Y. 76. 第10回日中クラスタ−会議, 福州 (中国) 2015-10-23～2015-10-27 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions
" *Nishibayashi, Y. The 2nd International Conference on Organometallics and Catalysis, 奈良 (日本) 2014-10-27～2014-10-29 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions
" *Nishibayashi, Y. The JSPS Strasbourg Symposium, Strasbourg (France) 2014-10-15～2014-10-17 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Mild Reaction Conditions
" *Nishibayashi, Y. 41st International Conference on Coordination Chemistry, Singapore (Singapore) 2014-07-21～2014-07-25 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Mild Reaction Conditions
" *Nishibayashi, Y. The 26th International Conference on Organometallic Chemistry, 札幌 (日本) 2014-07-14～2014-07-14 |
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| Prize |
"有機合成化学協会企業冠賞受賞（日産化学・有機合成新反応⁄手法賞）" 西林仁昭 2016-02 有機合成化学協会 触媒的プロパルギル位置換反応の開発と不斉反応への展開 |
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| Media |
"フロントランナー 挑む 「常温常圧のアンモニア合成でエネルギー資源革命」" 西林仁昭 日経サイエンス 2015-12-25 食糧生産に不可欠で，水素エネルギー利用でも注目されるアンモニア 現在は高温高圧が必要だが，常温常圧で合成できるようになれば 世界レベルで省エネルギーが実現，新エネルギーの普及にも弾みがつく |
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"触媒分野の研究活性化" *西林仁昭 化学工業日報 2014-10-10 PDF 常温常圧でアンモニアを合成する触媒の機能を解明 |
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"Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst, M. Shibata, K. Nakajima, and Y. Nishibayashi, Chem. Commun., 50, 7874-7877 (2014).の内容が、Synfacts 誌 2014, 10に掲載. " *西林仁昭 Synfact 2014-11-11 |
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"
Photolytic N2 Splitting: A Road to Sustainable NH3 Production? " *西林仁昭 Angew. Chem.誌 ハイライト 2014-11-11The split up: Recent advances in photochemical dinitrogen splitting have been achieved. Demonstration of the reversibility of the N2 splitting and ammonia formation from a nitride has advanced the field of N2 fixation using a synthetic homogeneous system. |
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"触媒的アンモニア生成反応におけるピンサー型配位子を持つ窒素架橋２核モリブデン錯体の特異な挙動" *西林仁昭 Nature Communications誌 日本語サイト 注目の論文 2014-06-04 |
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"
アンモニア合成省エネ化 東大、モリブデン触媒利用 常温・常圧目指す エネルギー源の期待も
" 西林仁昭 日経産業新聞 2014-06-16 |
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"
触媒機構解明に成功 アンモニア常温常圧合成低コスト化に道
" 西林仁昭 日刊工業新聞 2014-04-30 |
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| A02 ユー ウージン | ||
| Original papers |
"Chelating Bis(1,2,3-triazole-5-ylidene) Rhodium Complexes: Versatile Catalysts for Hydrosilylation Reactions" Nguyen, T. V. Q.; Yoo, W.-J.; *Kobayashi, S. Adv. Synth. Catal. 2016, 358 (3), pp.452-458. |
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"Effective Formylation of Amines with Carbon Dioxide and Diphenylsilane Catalyzed by Chelating bis(tzNHC) Rhodium Complexes" Nguyen, T. V. Q.; Yoo, W.-J.; *Kobayashi, S. Angew. Chem. Int. Ed. 2015, 54 (32), pp.9209-9212. |
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"Visible Light-Mediated Ullmann-Type CN Coupling Reactions of Carbazole Derivatives and Aryl Iodides" Yoo, W.-J. ; Tsukamoto, T; * Kobayashi, S. Org. Lett. 2015, 17 (14), pp.3640-3642. |
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"Lithium tert-Butoxide-Mediated Carboxylation Reactions of Unprotected Indoles and Pyrroles with Carbon Dioxide" Yoo, W.-J.; Nguyen, T. V. Q.; Guiteras Capdevila, M.; *Kobayashi, S. Heterocycles 2015, 90 (2), pp.1196-1204. |
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"Visible-Light-Mediated Chan-Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives" Yoo, W.-J.; Tsukamoto, T.; *Kobayashi, S. Angew. Chem. Int. Ed. 2015, 54 (22), pp.6587-6590. |
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"Zinc(II) Hexachloroantimonate-Catalyzed Oxidative Allylation of Glycine Derivatives" Yoo, W.-J.; Tanoue, A.; *Kobayashi, S. Asian J. Org. Chem. 2014, 3 (10), pp.1066-1069. |
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"Synthesis of Isocoumarins through Three-Component Couplings of Arynes, Terminal Alkynes, and Carbon Dioxide Catalyzed by an NHC-Copper Complex" Yoo, W.-J.; Nguyen, T. V. Q.; *Kobayashi, S. Angew. Chem. Int. Ed. 2014, 53 (38), pp.10213-10217. |
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"Sulfuryl Chloride as an Efficient Initiator for Metal-Free Aerobic Cross-Dehydrogenative Coupling Reaction of Tertiary Amines" Tanoue, A.; Yoo, W.-J.; *Kobayashi, S. Org. Lett. 2014, 16 (9), pp.2346-2349. |
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"Efficient Visible Light-Mediated Cross-Dehydrogenative Coupling Reactions of Tertiary Amines Catalyzed by a Polymer-Immobilized Iridium-Based Photocatalyst" Yoo, W.-J.; *Kobayashi, S. Green Chem. 2014, 16 (5), pp.2438-2442. |
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| A02 矢島 知子 | ||
| Original papers |
"Photoinduced double perfluoroalkylation of methylacenes" Nogami, E.; Washimi, Y.; Yamazaki, Y.; Kubota, T.; *Yajima, T. Tetrahedron Lett. 2016, 57 pp.2624-2627. DOI:10.1016 |
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"Helical Inversion of Gel Fibrils by Elongation of Perfluoroalkyl Chains as Studied by Vibrational Circular Dichroism" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi Chirality 2016, DOI:10.1002/chir.22592 |
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"Chiroptical Studies on Supramolecular Chirality of Molecular Aggregates" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi Chirality 2015, 27 (10), pp.659-666. DOI:10.1002/chir.22482 |
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"Perfluorinated gelators for solidifying fluorous solvents: effects of chain length and molecular chirality" *Tomoko Yajima, Erika Tabuchi, Emiko Nogami, Akihiko Yamagishi, *Hisako Sato RSC Adv. 2015, 5 pp.80542-80547. DOI:10.1039/C5RA12656H |
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"Stereochemical Investigation of the Products of the Photoinduced Perfluoroalkylation−Dimerization of Anthracene" Nogami, E.; Yamazaki, T.; Kubota, T.; *Yajima, T. J. Org. Chem. 2015, 80 pp.9208-9218. DOI:10.1021/acs.joc.5b01655 |
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"Facile synthetic protocols for perfluoroalkyl-substituteddiazapentaphenes" Shigeyuki Yamada, Shota Iwama, Keita Kinoshita, *Takashi Yamazaki, Toshio Kubota, Tomoko Yajima Tetrahedron 2014, 70 pp.6749-6756. DOI:10.1016/j.tet.2014.07.069 |
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"An Intermediate State in Gelation as Revealed by Vibrational Circular Dichroism Spectroscopy" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi RSC Adv. 2014, 4 (4), pp.25867-25870. DOI:10.1039/C4RA02526A |
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"Terminal Effects on Gelation by Low Molecular Weight Chiral Gelators" *Hisako Sato, Emiko Nogami, Tomoko Yajima, Akihiko Yamagishi RSC Adv. 2014, 4 (4), pp.1659-1665. DOI:10.1039/C3RA44070B |
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| Books |
「有機合成実験法ハンドブック 第二版」 有機合成化学協会 "フッ素化合物の合成法" Yamazaki, T.; Yajima, T. 丸善出版 (東京) 2015, pp1071-1098. ISBN:978-621-08948-4 |
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「フッ素化学入門2015」 独）日本学術振興会・フッ素化学第１５５委員会 "(R)-1-シクロヘキシル-2,2,2-トリフルオロエチルアミン" 矢島知子 他４８名 三共出版 (東京) 2015, pp235-237等. ISBN:978-4-7827-0727-2 |
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| Reviews / Accounts |
"ペルフルオロアルキル基を有するキラルα－アミノ酸の合成と応用" Yajima, T. オレオサイエンス 2015, 16 (3), pp.145-150. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "VCD
Application for Perfulorinated Gel Formation Mechanism" ○Sato, H.*; Sasaki, M., Tabuchi, , E.; Nogami, N.; Yajima, T.; Yamagishi, A. CD2015, Sapporo (Japan) 2015-08-30～2015-09-03 |
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口頭発表／ポスター発表 "Photoinduced
Radical Perfuloalkylation with Bromo Perfuloalkane Using Organocatalyst" ○Yajima, T.*; Ikegami, M.; Nogami, E. 21st ISFC & ISoFt ’15, Como (Italy) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "Synthesis
and crystallographic study of perfluoroalkylated naphtho[2,1-b:6,5-b']
dithiophene" ○Nogami, E.; Yajima, T.* Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Photoinduced radical perfluoroalkylation with bromo perfluoroalkane using acenes as catalysts" ○*Yajima, T.,; Ikegami, M.; Nishii, C.; Nogami, E. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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| Patent |
"含フッ素芳香族化合物およびその製造方法" 発明者：Yajima, T.; Yamamoto, K. 出願者：旭硝子株式会社 特願2012-033156 2012-02-17, 特許第5874744号 2016-05, (国外) |
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"ケイ素含有含フッ素化合物" 発明者：矢島知子、笹原佳奈、神原將、野口剛 出願者：お茶の水女子大学、ダイキン工業株式会社 特願2016-008651 2016-01-20, 2016-04, |
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"光学活性含フッ素アミン化合物の製造方法並びに光学活性含フッ素アミン化合物" 発明者：矢島知子、杉浦奈奈、香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2012-161056 2012-07-20, 特許第5902575号 2016-03-18, (国内) |
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"含フッ素化合物の製造法" 発明者：矢島知子.; 池上真子; 香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2016-008109 2016-01-19, 2016-04, |
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"含フッ素化合物の製造法" 発明者：矢島知子.; 池上真子; 香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2015-179552 2015-09-11, 2016-04, (国内) |
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"エチレングリコール鎖とパーフルオロアルキレン鎖を主鎖骨格中に有するポリマー" 発明者：矢島知子、笹原佳奈、神原 將、辻本 伸幸 出願者：国立大学法人お茶の水女子大学、ダイキン工業株式会社 2015-03-10, 特願2015-047416 2015-05, (国内) |
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"光学活性含フッ素アミン化合物及びその製造方法" 発明者：矢島知子、佐野杏奈、香川巧 出願者：国立大学法人お茶の水女子大学、東ソー・エフテック株式会社 2015-01-28, 特願2015-014539 2015-05, (国内) |
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| A02 松谷 裕二 | ||
| Original papers |
"Synthesis of Substituted Pyrrolo[2,1-a]isoquinolines by Gold-catalyzed Domino Cyclization of Alkynyl Iminoesters." Sugimoto, K.; Hoshiba, Y.; Tsuge, K.; *Matsuya, Y. Synthesis 2016, in Press DOI:10.1055/s-0035-1561423 |
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"Construction of cis-Fused Hydrindane Skeleton with a Lactone Tether Utilizing Intramolecular Diels-Alder Reaction." Yin, S.; Takai, K.; Minato, D.; Sugimoto, K.; Ohtsu, H.; Tsuge, K.; *Matsuya, Y. Heterocycles 2016, in Press DOI:10.3987/COM-15-S(T)34 |
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"In vitro and in vivo Antiherpetic Effects of (1R,2R)-1-(5'-methylful-3'-yl)propane-1,2,3-triol." Sasaki, K.; Hayashi, K.; Matsuya, Y.; Sugimoto, K.; *Lee, J.-B.; Kurosaki, F.; Hayashi, T. J. Nat. Med. 2016, 70 (2), pp.217-224. DOI:10.1007/s11418-016-0964-6 |
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"Synthesis of Denosomin–Vitamin D3 Hybrids and Evaluation of their Anti-Alzheimer's Disease Activities." Sugimoto, K.; Yajima, H.; Hayashi, Y.; Minato, D.; Terasaki, S.; Tohda, C.; *Matsuya, Y. Org. Lett. 2015, 17 (23), pp.5910-5913. DOI:10.1021/acs.orglett.5b03138 |
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"Three-Component Domino Process for Pyrrolizine Skeleton via [3+2]-Cycloaddition–Enamine Cyclization Triggered by Gold Catalyst." Sugimoto, K.; Yamamoto, N.; Tominaga, D.; *Matsuya, Y. Org. Lett. 2015, 17 pp.1320-1323. DOI:10.1021/acs.orglett.5b00320 |
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"Synthesis and Evaluations of GLP-1 Secretion and Anti-Diabetic Effect in KKAy Mice of New Tricyclic Compounds." Minehira, D.; Takeda, D.; Miyawaki, S.; Kato, A.; Adachi, I.; Miyazaki, A.; Miyatake, R.; Umezaki, M.; Miura, K.; Kitahara, Y.; Sugimoto, K.; Matsuya, Y.; *Toyooka, N. Heterocycles 2015, 90 pp.372-404. DOI:10.3987/COM-14-S(K)29 |
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"Preparation of (2R,4S)/(2S,4S)-4-Hydroxypipecolinic Acid Derivatives from L-(–)-Malic Acid." Yin, S.; Taneda, H.; Li, B.; Zhou, D.; Minato, D.; Sugimoto, K.; *Matsuya, Y. Heterocycles 2015, 90 pp.928-938. DOI:10.3987/COM-14-S(K)52 |
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"Stereoselective Approach to Potential Scaffold of A-nor B-aromatic OSW-1 Analogues via [4+2] Cycloaddition of o-Quinodimethane." Li, B.; Masuda, S.; Minato, D.; Zhou, D.; Sugimoto, K.; Nemoto, H.; *Matsuya, Y. Tetrahedron 2014, 70 pp.3981-3987. DOI:10.1016/j.tet.2014.04.079 |
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"Synthesis of Long-chain Fatty Acid Derivatives as a Novel Anti-Alzheimer’s Agent." Zhang, H.-Y.; Yamakawa, Y.; Matsuya, Y.; *Toyooka, N.; Tohda, C.; Awale, S.; Li, F.; Kadota, S.; Tezuka, Y. Bioorg. Med. Chem. Lett. 2014, 24 pp.604-608. DOI:10.1016/j.bmcl.2013.12.008 |
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"Synthesis of 8-Amino-(dihydrofuran-fused perhydrophenanthrene) via Copper-Mediated Amination Reaction." Sugimoto, K.; Tamura, K.; Toyooka, N.; *Matsuya, Y. Heterocycles 2014, 88 pp.755-763. DOI:10.3987/COM-13-S(S)38 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthetic Studies toward (+)-CJ-12,950 for the Stereochemical Assignment and Structure Activity Relationship Studies." ○Oguma, Y.; Yamagishi, T.; Yamamoto, N.; Shinoda, S.; Sugimoto, K.; Toyooka, N.; Minato, D.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Three-component Domino Process for the Pyrrolizine Skeleton via [3+2]-Cycloaddition of Azomethine Ylide and Enamine Cyclization Triggered by a Gold Catalyst." ○Sugimoto, K.; Yamamoto, N.; Tominaga, D.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Novel NHC-catalyzed Synthesis of Silyl Dienol Ethers via 1,4-Brook Rearrangement." ○Amano, H.; Sugimoto, K.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthetic Studies toward (+)-CJ-12,950 for the Stereochemical Assignment." ○Oguma, Y.; Yamagishi, T.; Yamamoto, N.; Shinoda, S.; Sugimoto, K.; Minato, D.; *Matsuya, Y. The 3rd International Symposium on Process Chemistry, Kyoto (Japan) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "NHC-catalyzed Transformation of β-Silylated Enones to Silyl Dienol Ethers via Silyl Migration." ○Sugimoto, K.; Amano, H.; *Matsuya Y. The 39th Naito Conference, The chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Design, Synthesis, and Biological Evaluation of Promising Anti-Alzheimer’s Compounds Having Dihydropyrone Unit as a Key Component." Sugimoto, K.; Yajima, H.; Tohda, C.; ○*Matsuya Y. The XVI International Conference on Heterocycles in Bioorganic Chemistry, Metz (France) 2015-06-08～2015-06-11 |
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口頭発表／ポスター発表 "Domino process for concise synthesis of pyrrolizines via 3-component coupling reaction with gold catalysis." ○Sugimoto, K.; Yamamoto, N.; Tominaga, D.; Minato, D.; *Matsuya, Y. 15th Tetrahedron Symposium - Asian Edition, Singapore (Singapore) 2014-10-28～2014-10-31 |
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口頭発表／ポスター発表 "Synthesis and antitumor activity of simplified des-AB-type analogue of OSW-1." ○*Matsuya, Y.; Li, B.; Minato, D.; Sugimoto, K.; Zhou, D.; Nemoto, H. XXIII International Symposium on Medicinal Chemistry, Lisbon (Portugal) 2014-09-07～2014-09-11 |
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| Patent |
"Oral Therapeutic Agent Containing Diosgenins for Diseases Associated with Nerve Axon Dysfunction, Including Alzheimer's Disease." 発明者：Tohda, C.; Matsuya, Y.; Sugimoto, K. 出願者：Resilio Company Limited WO 2015-JP62094 2015-04-21, WO 2015163318 2015-10-29, (国外) |
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"神経変性疾患の治療薬" 発明者：東田千尋，松谷裕二，杉本健士． 出願者：レジリオ株式会社 特願2014-091718 2014-04-25, 2014-04, (国内) |
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| A02 三宅 由寛 | ||
| Original papers |
"Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids" Yamaji, A.; Tsurugi, H.; *Miyake, Y.; Mashima, K.; *Shinokubo, H. Chem. Eur. J. 2016, 22 pp.3956-3961. |
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"Diversity-Oriented Synthesis of Tetrathia[8]circulenes by Sequential C–H Borylation and Annulation" Kato, S.; Serizawa, Y.; Sakamaki, D.; Seki, S.; *Miyake, Y.; Shinokubo, H. Chem. Commun. 2015, 51 pp.16944-16947. |
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"A 3-Pyridyl-5,15-Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transtion Metals" Yamaji, A.; Shin, J.-Y.; Miyake, Y.; *Shinokubo, H. Angew. Chem. Int. Ed. 2014, 53 pp.13924-13927. | ||