研究業績
年度：全て
| 分類 | 内容 | 共同研究者 |
|---|---|---|
| A01 秋山 隆彦 | ||
| Original papers |
"Cluster Preface: BINOL Phosphates for Chemistry" *Akiyama, T. Synlett 2016, 27 (4), pp.542-545. DOI:DOI: 10.1055/s-0035-1561678  |
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"Chiral Phosphoric Acid Catalyzed Kinetic Resolution of Indolines Based on a Self-Redox Reaction" Saito. K.; *Akiyama, T. Angew. Chem. Int. Ed. 2016, 55 (9), pp.3148-3152. DOI:DOI: 10.1002/anie.201510692 |
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"Why Benzothiazoline Cannot Be as Effective as Hantzsch Ester as a Hydrogen Donor in Chiral Phosphoric Acid-Catalyzed Asymmetric Reductive Amination of Ketones" Kim, K.-H.; *Akiyama, T.; *Cheon, C.-H. Chem. Asian J. 2016, 11 (2), pp.274-279. DOI:DOI: 10.1002/asia.201501020 |
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"Transformation of Trifluorotoluenes Triggered by Titanium Chloride(IV) Catalyzed Hydrodefluorination Using Hydrosilanes" Yamada, T.; Saito, K.; *Akiyama, T. Adv. Synth. Catal. 2016, 358 (1), pp.62-66. DOI:DOI: 10.1002/adsc.201500920 |
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"Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Cyclic Secondary Amine Derivatives including Tetrahydroquinolines by Hydrogen Transfer to Imines" Saito, K; Miyashita, H.; *Akiyama, T. Chem. Commun. 2015, DOI:DOI: 10.1039/C5CC06436H |
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"Enantioselective Synthesis of Fused Heterocycles with Contiguous Stereogenic Centers by Chiral Phosphoric Acid Catalyzed Symmetry Breaking" Mori, K.; Miyake, A.; *Akiyama, T. Chem. Commun. 2015, DOI:DOI: 10.1039/C5CC05508C |
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"B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes – Metal-Free Reduction of Sulfides" Saito, K.; Kondo, K.; *Akiyama, T. Org. Lett. 2015, 17 (13), pp.3366-3369. DOI:DOI: 10.1021/acs.orglett.5b01651 |
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"Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of 2-Substituted 2,3-Dihydro-4-quinolones by a Protecting-Group-Free Approach" Saito, K.; Moriya, Y.; *Akiyama, T. Org. Lett. 2015, 17 (13), pp.3202-3205. DOI:DOI: 10.1021/acs.orglett.5b01654 |
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"Synthesis of 3-Aryl-1-trifluoromethyltetrahydroisoquinolines by Bronsted Acid Catalyzed C(sp3)-H Bond Functionalization" Mori, K.; Umehara, N.; *Akiyama, T. Adv. Synth. Catal. 2015, 357 (5), pp.901-906. DOI:10.1002/adsc.201400775 |
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"γ-Silylboronates in the Chiral Brønsted ACid-catalysed Allylboration of Aldehydes" *Pablo, B.; Rodriguez, E.; Saito, K.; Fustero, S.; *Akiyama, T. Chem. Commun. 2015, 51 (25), pp.5246-5249. DOI:10.1039/C4CC08598A |
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"Enantioselective Synthesis of Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy" Mori, K.; Kobayashi, M.; Itakura, T.; Akiyama, T. Adv. Synth. Catal. 2015, 357 (1), pp.35-40. DOI:10.1002/adsc.201400611 |
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"Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable, Hydrogen Donor" Saito, K.; Miyashita, H.; Akiyama, T. Org. Lett. 2014, 16 (20), pp.5312-5315. DOI:10.1021/ol502486f |
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"Chiral Phosphoric-Acid-Catalyzed Transfer Hydrogenation of Ethyl Ketimine Derivatives by Using Benzothiazoline" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Chem. Eur. J. 2014, 20 (25), pp.7616-7620. DOI:10.1002/chem.201402763 |
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"Phosphoric Acid Bridged Cobalt Bis(dicarbollide) Ion as a Highly Efficient Catalyst for the Organocatalytic Hydrogenation of Ketimines" *Akiyama, T.; Saito, K.; Janczak, S.: Lesnikowski, Z. Synlett 2014, 25 (6), pp.795-798. DOI:10.1055/s-0033-1340847 |
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"Stereoselective Construction of All Carbon Quaternary Center by Chiral Phosphoric Acid: Highly Enantioselective Friedel-Crafts Reaction of Indoles with beta,beta-Disubstituted Nitoroalkenes" Mori, K.; Wakazawa, M.; *Akiyama, T. Chem. Sci. 2014, 5 (5), pp.1799-1803. DOI:10.1039/C3SC53542H |
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"Double C(sp3)-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles" Mori, K.; Kurihara, K.; Yabe, S.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2014, 136 (10), pp.3744-3747. DOI:10.1021/ja412706d |
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"Expeditious Synthesis of 1-Aminoindane Derivatives Achieved by [1,4]-Hydride Shift Mediated C(sp3)-H Bond Functionalization" Mori, K.; Kurihara, K.; *Akiyama, T. Chem. Commun. 2014, 50 (28), pp.3729-3731. DOI:10.1039/C4CC00894D |
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"Enantioselective Fluorination of beta-Ketoesters Catalyzed by Chiral Sodium Phosphate: Remarkable Enhancement of Reactivity by Simultaneous Utilization of Metal Enolate and Metal Phosphate
" Mori, K.; Miyake, A.; *Akiyama, T. Chem. Lett. 2014, 43 (1), pp.137-139. DOI:org/10.1246/cl.130934 |
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"Chiral Copper(II) Phosphate Catalyzed Enantioselective Synthesis of Isochromene Derivatives by Sequential Intramolecular Cyclization and Asymmetric Transfer Hydrogenation of o-Alkynylacetophenones" Saito, K.; Kajiwara, Y.; *Akiyama, T. Angew. Chem. Int. Ed. 2013, 52 (50), pp.13284-13288. DOI:10.1002/anie.201308303 |
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"Enantioselective Transfer Hydrogenation of Difluoromethyl Ketimines Using Benzothiazoline as a Hydrogen Donor in Combination with Chiral Phosphoric Acid" Sakamoto, T.; Horiguchi, K.; Saito, K.; Mori, K.; *Akiyama, T. Asian J. Org. Chem. 2013, 2 (11), pp.943-946. DOI:10.1002/ajoc.201300174 |
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"Prediction of Suitable Catalyst by 1H NMR: Asymmetric Synthesis of Multisubstituted Biaryls by Chiral Phosphoric Acid Catalyzed Asymmetric Bromination" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. Chem. Sci. 2013, 4 (11), pp.4235-4239. DOI:10.1039/C3SC52142G |
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"Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines" Saito, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (32), pp.11740-11743. DOI:doi:10.1021/ja406004q |
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"Molecular iodine catalyzed transfer hydrogenation: reduction of aldimines, ketimines, and alpha-imino esters" Bachu, P.; Zhu C.; *Akiyama, T. Tetrahedron Lett. 2013, 54 (30), pp.3977-3981. DOI:org/10.1016/j.tetlet.2013.05.071 |
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"Hydrodefluorinations of Trifluorotoluenes by LiAlH4 and TiCl4" *Akiyama, T.; Atobe, K.; Shibata, M.; Mori, K. J. Fluorine Chem. 2013, 152 pp.81-83. DOI:org/10.1016/j.jfluchem.2013.03.001 |
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"Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (10), pp.3964-3970. DOI:DOI: 10.1021/ja311902f |
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"Kinetic Resolution in Chiral Bronsted Acid Catalyzed Aldol Reaction: Enantioselective Robinson-type Annulation Reaction" Yamanaka, M.; Hoshino, M.; Katoh, T.; Mori, K.; *Akiyama, T. Eur. J. Org. Chem. 2012, (24), pp.4508-4514. DOI:10.1002/ejoc.201200338 |
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"Phopshoric Acid Catalyzed Enantioselective Transfer Deruteration of Ketimines by Use of Benzothiazoline as a Deuterium Donor: Synthesis of Optically Active Deuterated Amines" Sakamoto, T.; Mori, K.; *Akiyama, T. Org. Lett. 2012, 14 (13), pp.3312-3315. DOI:10.1021/ol3012869 |
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"Enantioselective Organocatalytic Reductive Amination of Aliphatic Ketones by Benzothiazoline as Hydrogen Donor" Saito, K.; *Akiyama, T. Chem. Commun. 2012, 48 (38), pp.4573-4575. DOI:10.1039/C2CC31486J |
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"Concise Route to 3-Arylisoquinoline Skeleton by Lewis Acid Catalyzed C(sp3)-H Bond Functionalization and Its Application to Formal Synthesis of (+-)-Tetrahydropalmatine" Mori, K.; Kawasaki, T.; *Akiyama, T. Org. Lett. 2012, 14 (6), pp.1436-1439. DOI:10.1021/ol300180w |
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"Carboxyl-Tailed Benzothiazoline: A Readily Removable Hydrogen Donor for the Transfer Hydrogenation of Imines" Zhu, C.; *Akiyama, T. Tetrahedron Lett. 2012, 53 (4), pp.416-418. DOI:10.1016/j.tetlet.2011.11.061 |
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"Rapid Access to 3-Aryltetraline Skeleton via C(sp3)–H Bond Functionalization: Investigation on the Substituent Effect of Aromatic Ring Adjacent to C–H Bond in Hydride Shift/Cyclization Sequence" Mori, K.; Sueoka, S.; *Akiyama, T. Chem. Lett. 2011, 40 (12), pp.1386-1388. DOI:10.1246/cl.2011.1386 |
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"Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation: A Facile Synthetic Access to Highly Optically Active Trifluoromehylated Amines" Henseler, A.; Kato, M.; Mori, K.; *Akiyama, T. Angew. Chem. Int. Ed. 2011, 50 (35), pp.8180-8183. DOI:10.1002/anie.201103240 |
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"Brønsted Acid Catalyzed Reductive Amination with Benzothiazoline as a Highly Efficient Hydrogen Donor" Zhu, C.; *Akiyama, T. Synlett 2011, (9), pp.1251-1254. DOI:10.1055/s-0030-1260539 |
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"Selective Activation of Enantiotopic C(sp3)-Hydrogen by Means of a Chiral Phosphoric Acid: Asymmetric Synthesis of Chiral Tetrahydroquinoline Derivatives" Mori, K.; Ehara, K.; Kurihara, K.; *Akiyama, T. J. Am. Chem. Soc. 2011, 133 (16), pp.6166-6169. DOI:10.1021/ja2014955 |
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"Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of β-Amino-α,α−difluoro Carbonyl Compounds," Kashikura, W.; Mori, K.; *Akiyama, T. Org. Lett. 2011, 13 (7), pp.1860-1863. DOI:10.1021/ol200374m |
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"Expeditious Construction of a Carbobicyclic Skeleton via a sp3-C–H Functionalization: Hydride Shift from an Aliphatic Tertiary Position in an Internal Redox Process
" Mori, K.; Sueoka, S.; *Akiyama, T. J. Am. Chem. Soc. 2011, 133 (8), pp.2424-2426. DOI:10.1021/ja110520p |
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| Books |
「Comprehensive Organic Synthesis, 2nd Edition, Volume 2」 Molander, G. A.; Kochel, P. "The Bimolecular and Intramolecular Mannich and Related Reactions" Akiyama, T. Elsevier (Oxford) 2014, pp629-681. |
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「Comprehensive Enantioselecitve Organocatalysis Volume 2」 Dalko, P. I. "Chiral Phosphoric Acid Catalys in Asymmetric Synthesis" Mori, K.; Akiyama, T. Wiley-VCH (Weinheim) 2013, pp289-314. |
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「「CSJカレントレビュー」未来を拓く元素戦略 - 持続可能な社会を実現する化学」 日本化学会 "有機分子触媒" 秋山隆彦 化学同人 2013, pp45-50. |
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「Volume 6: Synthetic Methods V -Organocatalysis, Comprehensive Chirality」 Keiji Maruoka "C-C Bond Formation : Mannich Reaction" Akiyama, T. Elsevier 2013, pp69-96. |
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「Asymetric Synthesis II」 Mathias Christmann and Stephan Bräse "Asymmetric C-C Bond Formation Using Chiral Phoshoric Acid" Akiyama, T. Wiley-VCH (Weinheim) 2012, pp261-266. |
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「Handbook of Green Chemistry」 Chao-Jun Li "Synthesis without Metals" Akiyama, T Wiley-VCH (Weinheim) 2012, pp307-334. |
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「Asymmetric Organocatalysis, Science of Synthesis」 Keiji Maruoka "Phosphoric Acid Catalyzed Reactions of Imines" Akiyama, T.* Georg Thieme Verlag KG (Stuttgart) 2013, pp169-217. |
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| Reviews / Accounts |
"The Bimolecular and Intramolecular Mannich and Related Reactions" Akiyama, T. Comprehensive Organic Synthesis II 2014, 2 pp.629-681. |
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"Stronger Brønsted Acids: Recent Progress" *Akiyama, T.; Mori, K. Chem. Rev. 2015, 115 (17), pp.9277-9306. DOI:DOI: 10.1021/acs.chemrev.5b00041 |
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"Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation" Zhu, C.; Saito, K.; Yamanaka, M.; *Akiyama, T. Acc. Chem. Res. 2015, 48 (2), pp.388-398. DOI:10.1021/ar500414x |
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"キラルブレンステッド酸の開発と不斉合成反応への展開" 秋山隆彦 有機合成化学協会誌 2011, 69 (11), pp.913-925. DOI:org/10.5059/yukigoseikyokaishi.69.913 |
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| Conference / Symposium / Lecture |
招待講演 "Stereoselective Synthesis of Heterocycles Based on the Internal Redox Reaction"" ○Akiyama, T. DOMINOCAT 1 Symposium, Aachen (ドイツ) 2015-09-09～2015-07-11 |
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招待講演 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation Reactions" ○Akiyama, T. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, 仙台 (日本) 2015-09-06～2015-09-09 |
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招待講演 "Stereoselective Synthesis of CF3-containing Heterocycles based on the Internal Redox Reaction" ○Akiyama, T. 9th French-Japanese Seminar on Fluorine, Nice (フランス) 2015-08-31～2015-09-01 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Phosphoric Aicd" ○Akiyama, T. 21st International Symposium on Fluorine Chemistry, Como (イタリア) 2015-08-23～2015-08-28 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. IUPAC 2015, 45th World Chemistry Congress,, 釜山 (韓国) 2015-08-08～2015-08-14 |
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口頭発表／ポスター発表 "Asymmetric Synthesis of 2-Substituted Dihydroquinolones by The Aza-Michael Reaction of N-Unprotected Amines" ○Moriya, Y.; Saito, K.; *Akiyama, T. The 3rd International Symposium on Process Chemistry, 京都 (日本) 2015-07-13～2015-07-15 |
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招待講演 "Transfer hydrogenation reactions of ketimines by means of chiral phosphoric acid" ○Akiyama, T. The 39th Naito Conference on the Chemistry of Organocatalysts, 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. XIV ICSN Smposium, Gif-sur-Yvette (フランス) 2015-06-18～2015-06-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at National Chiao Tung University（國立交通大學）, 新竹 (台湾) 2015-06-08～2015-06-08 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at University of Alicante, Alicante (Spain) 2015-05-19～2015-05-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at University of Valencia, Valencia (Spain) 2015-05-14～2015-05-14 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Department Seminar at New York University, New York (USA) 2015-03-03～2015-03-03 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Department Seminar at Rutgers University, Piscataway (USA) 2015-03-02～2015-03-02 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at the University of Pennsylvania, Philadelphia (USA) 2015-02-27～2015-02-27 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Phosphoric Acid" ○Akiyama, T. Japan/Russian Conference on Fluorine Chemistry and Friends, Nagoya (Japan) 2014-12-09～2014-12-09 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Trifluoromethylated N-H Ketimine Using Benzothiazoline " ○Noda, H.; Akiyama, T.; Yamanaka, M. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Theoretical Study on the Mechanism of Stereoselectivity in Chiral Phosphorus Acid Catalyzed Asymmetric Hydrogenation of 1, 5-benzodiazepine Using benzothiazoline " ○Yamamoto, E.; Horiguchi, K.; Saito, K.; Akiyama, T.; Yamanaka, M. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Enantioselective Route to Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy" ○Itakura, T.; Kobayashi, M.; Mori, K.; Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2015-01-22～2015-01-22 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid-Catalyzed Hydrogen Transfer Reaction of Indoline to Imines " ○Miyashita, H.; Saito, K.; Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Friedel-Crafts Alkylation of Indoles by Means of Chiral Phosphoric Acid" ○Akiyama, T. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Oxidative Kinetic Resolution of Indolines Based on the Enantioselective Transfer Hydrogenation of Ketimines by Means of Phosphoric Acid" ○Akiyama, T. Vietnam Malaysian International Chemical Congress (VMICC)), Hanoi (Vietnam) 2014-11-07～2014-11-09 |
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招待講演 "Enantioselective Synthesis of Chiral Biaryl Skeleton base on the Bromination of Cs-Symmetric Biaryls by Means of Phosphoric Acid " ○Akiyama,T. 18th Malaysian International Chemical Congress (18MICC)), Kuala Lumpur (Malaysis) 2014-11-04～2014-11-05 |
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基調講演 "Chiral Phosphoric Acid Catalyzed Enantioselective Reactions" ○Akiyama, T. Chiral China 2014, Hefei (China) 2014-09-29～2014-09-30 |
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口頭発表／ポスター発表 "Oxidative Kinetic Resolution of Indolines Based on the Enantioselective Transfer Hydrogenation of Ketimines by Means of Chiral Phosphoric Acid" ○Akiyama, T.; Saito, K. 5th EuCheMS Chemistry Congress, Istanbul (Turkey) 2014-08-31～2014-09-04 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Asymmetrci Reactions" ○Akiyama, T. Gordon Research Conferences on Natural Products, Andover (USA) 2014-07-20～2014-07-25 |
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基調講演 "Enantioselective Synthesis of Fluorinated Compoudns by Means of Chiral Phosphoric Acid " ○Akiyama, T. Bordeaux Fluorine Days, Bordeaux (France) 2014-07-06～2014-07-11 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at Ecole Polytechnique, Paris (France) 2014-07-04～2014-07-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. Departmental Seminar at the University of Lyon, Lyon (France) 2014-07-03～2014-07-03 |
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基調講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" ○Akiyama, T. 20th International Conference on Phosphorus Chemistry, Dublin (Ireland) 2014-06-28～2014-07-02 |
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口頭発表／ポスター発表 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" Akiyama, T. Asymmetric Synthesis Conference (Zing Conference), Nerja (Spain) 2014-02-25～2014-02-28 |
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招待講演 "Development of Enantioselective Reactions Catalyzed by Chiral Phosphoric Acid" Akiyama, T. Indo-Japanese Conference on Process Chemistry R&D, Mumbai (India) 2014-01-30～2014-01-31 |
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招待講演 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" ○Akiyama, T.; Saito, K. International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), Beijing (China) 2013-12-01～2013-12-05 |
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招待講演 "Oxidative Kinetic Resolution of Indolines based on Transfer Hydrogenation to Ketimines by means of Chiral Phosphoric Acid" ○*Akiyama, T.; Saito, K. International Symposium on Organic Reactions 2013 (ISOR 2013), 台北 (台湾) 2013-11-19～2013-11-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of Texas at Austiin, Austin (USA) 2013-08-23～2013-08-23 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of California at Los Angeles, Los Angeles (USA) 2013-08-21～2013-08-21 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the University of California, Berkeley, Berkeley (USA) 2013-08-20～2013-08-20 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at ICSN (Institute de Chimie des Substances Naturelles), , Gif-sur-Yvette (France) 2013-07-26～2013-07-26 |
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口頭発表／ポスター発表 "Enantioselective Transfer Hydrogenation of CF3-substituted Ketimines by Means of Chiral Phosphoric Acid" *Akiyama, T. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" *Akiyama, T. Departmental Seminar at the Delft University of Technology, Delft (The Netherland) 2013-07-19～2013-07-17 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Use of Benzothiazoline as a Hydrogen Donor" Akiyama, T. Advance Molecular Transformations by Organocatalysts, First International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The University of Hong Kong, Hong Kong (Hong Kong) 2013-03-13～2013-03-13 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The Hong Kong University of Science and Technology, Kowloon (Hong Kong) 2013-03-12～2013-03-12 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Chung Hsing University, Taichiung (Taiwan) 2013-03-07～2013-03-07 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Chung Cheng University, ChiaYi (Taiwan) 2013-03-06～2013-03-06 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at National Tsing Hua University, HsinChu (Taiwan) 2013-03-05～2013-03-05 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama. T. Department Seminar at National Taiwan Normal University, Taipei (Taiwan) 2013-03-04～2013-03-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at University of Texas Southwestern Medical Center, Dallas (USA) 2013-01-22～2013-01-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at University of South Florida, Tampa (USA) 2013-01-18～2013-01-18 |
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招待講演 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Trifluorimethylated Ketimines" Akiyama, T. 21st Winter Fluorine Conference, St. Pete Beach (USA) 2013-01-13～2013-01-18 |
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招待講演 "Enantioselective Transfer Hydrogenation by Use of Benzothiazoline" Akiyama, T. Japan-US Organocatalytic Symposium in Hawaii (2012),, Honolulu (USA) 2012-12-16～2012-12-18 |
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依頼講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Japan-Singapore Bilateral Symposium on Synthetic Organic Chemistsry, Singapore (Singapore) 2012-10-30～2012-10-30 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Use of Benzothiazoline as a Novel Hydrogen Donor" Akiyama, T. Cambodian Malaysian Chemical Conference (CMCC) 2012, Siem Reap (Cambodia) 2012-09-19～2012-09-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis
" Akiyama, T. Department Seminar at Zhejiang Sci-Tech University, Hangzhou (China) 2012-09-22～2012-09-22 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Zhejiang University, Hangzhou (China) 2012-09-20～2012-09-20 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at East China University of Science and Technology, Shanghai (China) 2012-09-19～2012-09-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Shanghai Institute of Organic Chemistry, Shanghai (China) 2012-09-19～2012-09-19 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at East China Normal University, Shanghai (China) 2012-09-18～2012-09-18 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at McGill University, Montreal (Canada) 2012-08-08～2012-08-08 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimines" Akiyama, T. Gordon Research Conferences on Stereochemistry, Newport (USA) 2012-07-29～2012-08-03 |
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口頭発表／ポスター発表 "Addition Reaction of Niobium Fluorocarbenoid Species Generated from Trifluorotoluene " ○Ito, R.; Atobe, K.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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口頭発表／ポスター発表 "Low-valent Titanium-catalyzed Reduction of Trifluorotoluene Derivatives" ○Shibata, M.; Atobe, K.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Trifluoromethyl Imines: Facile Synthetic Access to Highly Optically Active Trifluoromethylated Amines" ○Sato, T.; Henseler, A.; Kato, M.; Mori, K.; *Akiyama, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-25 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds by Means of Chiral Bronsted Acid Catalyt" Akiyama, T. Valencia Fluorine Days: Symposium on Fluorine Chemistry, Valencia (Spain) 2012-05-20～2013-05-24 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions " Akiyama, T. Department Seminar at Institute of Chemical Research of Catalonia, Tarragona (Spain) 2012-05-18～2012-05-18 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Enantioselective S(sp3)-H Bond Activation " Akiyama, T. The 47th Burgenstock Conference, Brunnen (Switzerland) 2012-04-29～2012-05-04 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at The University of Sydney, Sydney (Australia) 2012-03-09～2012-03-09 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalysis" Akiyama, T. Department Seminar at Griffith University, Brisbane (Australia) 2012-03-08～2012-03-08 |
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招待講演 "Enantioselective Transfer Hydrogenation of Ketimines by Means of Benzothiazoline as Novel Hydrogen Donor " Akiyama, T. International Symposium on Catalysis and Fine Chemicals 2011 (C&FC2011), Nara (Japan) 2011-12-04～2011-12-08 |
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口頭発表／ポスター発表 "Efficient Approach to Optically Active Tetrasubstituted Biaryl Skeleton by Chiral Phosphoric Acid-Catalyzed Asymmetric Bromination " ○Ichikawa, Y.; Mori, K.; Kobayashi, M.; *Akiyama, T. 10th International Symposium on Organic Reactions (ISOR 10), Yokohama (Japan) 2011-11-23～2011-11-24 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid catalyzed Enantioselective Deuteride Reduction of Ketimines " ○Sakamoto, T.; Zhu, C.; Mori, K.; *Akiyama, T. Yokohama (Japan) 2011-11-23～2011-11-24 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. 10th International Symposium on Organic Reactions (ISOR 10), Yokohama (Japan) 2011-11-23～2011-11-24 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed C(sp3)-H Bond Functionalization: Asymmetric Synthesis of Tetrahydroquinoline Derivatives" ○Mori, K.; Ehara, K.; Kurihara, K.; *Akiyama, T. 1st International Symposium on Molecular Activation, Awaji (Japan) 2011-11-09～2013-11-10 |
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招待講演 "Chiral Phosphoric Acid Catalyzed C(sp3)-H Bond Activation" Akiyama, T. First German-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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招待講演 "Low-valent Niobium Mediated Activation of C-F/C-H Bonds" Akiyama, T. The 5th Asian Network of Metal Chemistry, The 14th Asian Chemical Congress, Bangkok (Thailand) 2011-09-05～2011-09-08 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid-Catalyzed Enantioselective C-H Bond Functionalization: Construction of Chiral Tetarhydroquinoline Skeleton" ○Kurihara, K.; Ehara, K.; Mori, K.; *Akiyama, T. The 2nd International Symposium on Process Chemistry, Kyoto (Japan) 2011-08-11～2011-08-12 |
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口頭発表／ポスター発表 "Efficient Approach to Optically Active Tetrasubstituted Biaryl Skeleton by Chiral Phosphoric Acid-Catalyzed Asymmetric Bromination" ○Kobayashi, M.; Ichikawa, Y.; Mori, K.; *Akiyama, T. The 2nd International Symposium on Process Chemistry, Kyoto (Japan) 2011-08-11～2011-08-12 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Aachen University, Aachen (Germany) 2011-08-03～2011-08-03 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Munster University, Munster (Germany) 2011-08-01～2011-08-01 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at the MaxPlanck Institute, Muelheim an der Ruhr (Germany) 2011-07-29～2011-07-29 |
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招待講演 "Recent Progress in the Chiral Phosphoric Acid Catalyzed Reactions" Akiyama, T. Department Seminar at Boston College, Chestnut Hill (USA) 2011-07-22～2011-07-22 |
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口頭発表／ポスター発表 "Chiral Bronsted Acid Catalyzed Asymmetric Reactions" Akiyama, T. Gordon Research Conferences on Organic Reactions & Processes, Smithfield (USA) 2011-07-17～2011-07-22 |
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招待講演 "Chiral Bronsted Acid Catalyzed Asymmetric Reactions" Akiyama, T. Department Seminar at North Dakota State University, Fargo (USA) 2011-07-15～2011-07-15 |
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口頭発表／ポスター発表 "Chiral Phosphoric Acid Catalyzed Enantioselective Reactions" Akiyama, T. TrostCon, Stanford (USA) 2011-06-25～2013-06-25 |
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| Prize |
"Arthur C. Cope Scholar Award" 2016-08 American Chemical Society |
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"Humboldt Research Award" Akiyama, T. 2016-03 Alexander von Humboldt Foundation |
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"名古屋シルバーメダル2012" 秋山隆彦 2012-11 公益財団法人万有生命科学振興国際交流財団 |
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| Media |
"Isochromenes Synthesis by Cyclization and Asymmetric Transfer Hydrogenation" Saito, K.; Kajiwara, Y.; Akiyama, T. Synfacts 2014-02-17 |
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"Phosphoric Acid Catalyzed Transfer Hydrogenation of Ethyl Ketimines" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Synfacts 2014-07-18 |
山中正浩 | |
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"Asymmetric Organocatalytic Synthesis of Tetrasubstituted Chiral Biaryl Compounds" Mori, K.; Ichikawa,Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Synfacts 2013-04-16 |
山中正浩 | |
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"Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimines" Henseler, A.; Kato, M.; Mori, K.; Akiyama, T. Synfacts 2011-09-20 |
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"2016 Cope and Cope Scholar Award Winners" Akiyama, T. Chemical & Engineering News 2016-01-11  PDF |
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| A01 浦口 大輔 | ||
| Original papers |
"Independence from the Sequence of Single-Electron Transfer of Photoredox
Process in Redox-Neutral Asymmetric Bond-Forming Reaction" Tomohito Kizu, Daisuke Uraguchi, and *Takashi Ooi J. Org. Chem. 2016, DOI:DOI: 10.1021/acs.joc.6b00445 |
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"Fenton reagent-catalyzed trifluoromethylation of enamines of 3-oxocarboxylates with CF3I" Yuhki Ohtsuka, Daisuke Uraguchi, Kyoko Yamamoto, Kenji Tokuhisa, *Tetsu Yamakawa J. Fluorine Chem. 2016, 181 pp.1-6. DOI:DOI: 10.1016/j.jfluchem.2015.10.013 |
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"Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines" Daisuke Uraguchi, Natsuko Kinoshita, Tomohito Kizu, and *Takashi Ooi J. Am. Chem. Soc. 2015, 137 pp.13768-13771. DOI:DOI: 10.1021/jacs.5b09329 |
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"Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes" Matthew A. Horwitz, Naoya Tanaka, Takuya Yokosaka, Daisuke Uraguchi, *Jeffrey S. Johnson and *Takashi Ooi Chem. Sci. 2015, 6 DOI:10.1039/C5SC02170G |
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"Highly E-Selective and Enantioselective Michael Addition to Electron-Deficient Internal Alkynes Under Chiral Iminophosphorane Catalysis" Daisuke Uraguchi, Kohei Yamada and *Takashi Ooi Angew. Chem. Int. Ed. 2015, 54 (34), pp.9954-9957. DOI:10.1002/anie.201503928 |
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"Vinylogy in Nitronates: Utilization of α-Aryl Conjugated Nitroolefins as a Nucleophile for Highly Stereoselective Aza-Henry Reaction" Keigo Oyaizu, Daisuke Uraguchi, *Takashi Ooi Chem. Commun. 2015, 51 (21), pp.4437-4439. DOI:10.1039/C4CC10261D |
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"Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines" Daisuke Uraguchi, Keigo Oyaizu, Haruhiro Noguchi, *Takashi Ooi Chem. Asian J. 2015, 10 (2), pp.334-337. DOI:10.1002/asia.201402943 |
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"Enantioselective Protonation of α-Hetero Carboxylic Acid-Derived Ketene Disilyl Acetals under Chiral Ionic Brønsted Acid Catalysis" Daisuke Uraguchi, Tomohito Kizu, Yuki Ohira, *Takashi Ooi Chem. Commun. 2014, 50 (88), pp.13489-13491. DOI:10.1039/C4CC06081D |
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"Enantioselective Formal α-Allylation of Nitroalkanes through Chiral Iminophosphorane-Catalyzed Michael Reaction/Julia-Kocienski Olefination Sequence" Daisuke Uraguchi, Shinji Nakamura, Hitoshi Sasaki, Yuki Konakade, and *Takashi Ooi Chem. Commun. 2014, 50 (26), pp.3491-3493. DOI:10.1039/C3CC49477B |
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"Practical Preparation of Chiral N-Sulfonyl Oxaziridines by Catalytic Asymmetric Payne Oxidation" Ryosuke Tsutsumi, Seonwoo Kim, Daisuke Uraguchi, *Takashi Ooi Synthesis 2014, 46 (7), pp.871-878. DOI:10.1055/s-0033-1340818 |
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"Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: application to the synthesis of N-sulfonyl oxaziridines" Daisuke Uraguchi, Ryosuke Tsutsumi, *Takashi Ooi Tetrahedron 2014, 70 (8), pp.1691-1701. DOI:10.1016/j.tet.2013.12.086 |
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"Catalytic Asymmetric Oxidation of N-Sulfonyl Imines with Hydrogen Peroxide–Trichloroacetonitrile System" Daisuke Uraguchi, Ryosuke Tsutsumi, and *Takashi Ooi J. Am. Chem. Soc. 2013, 135 DOI:10.1021/ja403491j |
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"Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis: Importance of Protonation Pathway" Uraguchi, Daisuke; Ueki, Yusuke; Sugiyama, Atsushi; *Ooi, Takashi Chem. Sci. 2013, 4 (3), pp.1308-1311. DOI:10.1039/C2SC22027J |
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"Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles" Daisuke Uraguchi, Ken Yoshioka, Yusuke Ueki, and *Takashi Ooi J. Am. Chem. Soc. 2012, 134 (47), pp.19370-19373. DOI:10.1021/ja310209g |
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"Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins" Uraguchi, Daisuke; Kinoshita, Natsuko; Nakashima, Daisuke; *Ooi, Takashi Chem. Sci. 2012, 3 (11), pp.3161-3164. DOI:10.1039/C2SC20698F |
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"Nitroolefins as a Nucleophilic Component for Highly Stereoselective Aza-Henry Reaction under the Catalysis of Chiral Ammonium Betaines" Uraguchi, Daisuke; Oyaizu, Keigo; *Ooi, Takashi Chem. Eur. J. 2012, 18 (27), pp.8306-8309. DOI:10.1002/chem.201201259 |
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"Ionic Nucleophilic Catalysis of
Chiral Ammonium Betaines for Highly Stereoselective Aldol Reaction from
Oxindole-Derived Vinylic Carbonates" Uraguchi,
D.; Koshimoto, K.; *Ooi, T. J. Am. Chem. Soc. 2012, 134 (16), pp.6972-6975. DOI:10.1021/ja3022939 |
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"Base-Catalyzed Direct
Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates" Corbett, M. T.; Uraguchi,
D.; *Ooi, T.; *Johnson, J. S. Angew. Chem. Int. Ed. 2012, 51 (19), pp.4685-4689. DOI:10.1002/anie.201200559 |
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"Highly Stereoselective Catalytic
Conjugate Addition of Acyl Anion Equivalent to Nitroolefins" Uraguchi, D.; Ueki, Y.;
*Ooi, T. Chem. Sci. 2012, 3 (3), pp.842-845. DOI:10.1039/C1SC00678A |
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"Enantioselective Aza-Michael
Addition to Conjugated Nitroenynes Catalyzed by Chiral Arylaminophosphonium
Barfates" Uraguchi,
D.; Kinoshita, N.; Kizu, T.; *Ooi, T. Synlett 2011, (9), pp.1265-1267. DOI:10.1055/s-0030-1260541 |
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"Precise Control of Spontaneous
Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide–Arylhydroxide(s)
in Solution" Uraguchi,
D.; Ueki, Y.; *Ooi, T. Angew. Chem. Int. Ed. 2011, 50 (16), pp.3681-3683. DOI:10.1002/anie.201007752 |
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| Books |
「CSJカレントレビュー「有機分子触媒の化学」」 寺田眞浩 "イオン対を中心とした不斉塩基触媒" 浦口大輔、大井貴史 日本化学会 2016, |
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「Topics in Current Chemistry: Site Selective Catalysis」 T. Kawabata "Site-Selective Conjugate Addition through Catalytic Generation of Ion-Pairing Intermediates" Daisuke Uraguchi, Takashi Ooi Springer 2016, |
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「Comprehensive Enantioselective Organocatalysis」 Peter I. Dalko "Axially Chiral C2-Symmetric Catalysts" Uraguchi, Daisuke; Kohsuke, Ohmatsu; Ooi, Takashi Wiley-VCH 2013, ISBN:3527332367 |
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「Stereoselective Synthesis of Drugs and Natural Products」 Vasyl Andrushko, Natalia Andrushko "Asymmetric Phase-Transfer Catalysis" Kohsuke, Ohmatsu; Uraguchi, Daisuke; Ooi, Takashi Wiley 2013, ISBN:1118032179 |
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「ELECTRONIC ENCYCLOPEDIA OF REAGENTS FOR ORGANIC SYNTHESIS (e-EROS)」 "1,4,6,9-Tetraaza-5λ5-phosphaspiro[4.4]non-5-ene, 3,8-bis(1-methylethyl)-2,2,7,7-tetrakis(4-methylphenyl)-, hydrochloride (1:1), (3R,5R,8R)-" Uraguchi, Daisuke; Ooi, Takashi Wiley 2012, ppRN01546-. |
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「COMPREHENSIVE CHIRALITY」 Hisashi Yamamoto, Erick M Carreira "C–C Bond Formation: Alkylation" Uraguchi, Daisuke; Ooi, Takashi Elsevier Science 2013, pp1-36. ISBN:0080951678 |
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「Science
of Synthesis: Asymmetric Organicatalysis 2」 Maruoka, K. "Hydrogen-Bonding Catalysts Other than Ureas and Thioureas" Uraguchi, D.; Ooi, T. Georg Thieme Verlag KG (Stuttgart) 2012, pp413-435. |
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| Reviews / Accounts |
"Lectureship Award MBLA 2014受賞講演ツアーを終えて" 浦口大輔 J. Synth. Org. Chem. Jpn 2015, 73 (6), pp.653-662. |
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| Conference / Symposium / Lecture |
依頼講演 "Asymmetric catalysis of P-spiro chiral tetraaminophosphonium salts" ○Daisuke Uraguchi Pacifichem 2015, Honolulu (USA) 2015-12-18～2015-12-18 |
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依頼講演 "Catalysis of P-Spiro Chiral Aminophosphonium Salts" ○Daisuke Uraguchi Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Stanford (USA) 2014-10-29～2014-10-29 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lectrure, Berkeley (USA) 2014-10-28～2014-10-28 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, PASADENA (USA) 2014-10-27～2014-10-27 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Cambridge (USA) 2014-10-24～2014-10-24 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Cambridge (USA) 2014-10-23～2014-10-23 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Rahway (USA) 2014-10-21～2014-10-21 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Princeton (USA) 2014-10-20～2014-10-20 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Zurich (Switzerland) 2014-10-17～2014-10-17 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Dusseldorf (Germany) 2014-10-15～2014-10-15 |
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受賞講演 "Molecular design and applications of chiral organic ion pair catalysts featuring anion-controlling ability" ○Daisuke Uraguchi MBLA Lecture, Munchen (Germany) 2014-10-13～2014-10-13 |
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口頭発表／ポスター発表 "Chiral tetraaminophosphonium salts mediated highly regio- and stereoselective 1,6- and 1,8-additions" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "E/Z-Selective Asymmetric Conjugate Addition to Electron-Deficient Internal Alkynes" ○Kohei Yamada, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Betaine-Type Electron-Transfer Catalyst: Design and Application" ○Masahiro Torii, Daisuke Uraguchi, *Takashi Ooi Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Regio-, Stereo-, and Enantioselective Conjugate Addition of Azlactones to Enynyl N-Acylpyrazoles ligands" ○Ryo Shibazaki, Daisuke Uraguchi, *Takashi Ooi The 13th International Kyoto Conference, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Betaine-Type Electron-Transfer Catalyst: Design and Application" ○Masahiro Torii, Daisuke Uraguchi, *Takashi Ooi The 13th International Kyoto Conference, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of Dialkyl Phosphite Mediated Formal Asymmetric Cross Pinacol-Type Reaction Under the Catalysis of Chiral Triaminoiminophosphorane" ○Naoya Tanaka, Matthew A. Horwitz, Daisuke Uraguchi, *Takashi Ooi, *Jeffrey S. Johnson The 16th Tetrahedron Symposium, Berlin (Germany) 2015-06-17～2015-06-19 |
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口頭発表／ポスター発表 "Synthesis of α-Hetero Carboxylic Acids via Protonation under Chiral Ionic Brønsted Acid Catalysis" ○Tomohito Kizu, Daisuke Uraguchi, *Takashi Ooi the 19th International Symposium on Homogeneous Catalysis (ISHC-XIX), Ottawa (Canada) 2014-07-06～2014-07-13 |
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口頭発表／ポスター発表 "Enantioselective Formal α-Allylation of Nitroalkanes through Chiral Iminophosphorane-Catalyzed Michel Reaction/Julia-Kocienski Olefination Sequence" ○Hitoshi Sasaki, Shinji Nakamura, Yuki Konakade, Daisuke Uraguchi, *Takashi Ooi IGER International Symposium on Chemical Science in Asia, Nagoya (Japan) 2014-05-26～2014-05-28 |
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口頭発表／ポスター発表 "Chiral Asymmetric Oxidation of N-Sulfonyl α-Imino Ester with Hydrogen Peroxide" ○Naoya Tanaka, Daisuke Uraguchi, *Takashi Ooi The 2nd International Symposium on Transformative Bio-Molecules 2014, Nagoya (Japan) 2014-05-12～2014-05-12 |
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口頭発表／ポスター発表 "Chiral Tetraaminophosphonium Salts Mediated Highly Vinylog of Michel Addiions" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi The 2nd International Symposium on Transformative Bio-Molecules 2014, Nagoya (Japan) 2014-05-12～2014-05-12 |
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口頭発表／ポスター発表 "Diastereoselectivity Ambivalence in 1,6-Selective Conjugate Additions under the Catalysis of Chiral Aminophosphonium Aryloxides" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 第3回 キャンパスアジアシンポジウム, Seoul (Korea) 2013-11-07～2013-11-08 |
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口頭発表／ポスター発表 "Diastereodivergent Catalysis of Chiral Aminophosphonium Aryloxides for Highly Regio- and Stereoselective 1,6-Addition to δ-Aryl Dienyl N-Acylpyrroles" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 第10回カルバニオン化学国際シンポジウム（ISCC-10）, Kyoto (Japan) 2013-09-23～2013-09-26 |
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口頭発表／ポスター発表 "Development of a Vinylog of Stereoselective Michael Addition to δ-Substituted Dienyl N-Acylpyrroles" ○Ken Yoshioka, Daisuke Uraguchi, *Takashi Ooi 有機分子触媒による未来型分子変換第1回 国際会議 (兼) 第6回有機触媒シンポジウム , Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Precise Structural Control of Spontaneous Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide-Arylhydroxide(s)" ○Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi Nagoya University Global COE International Symposium on on Elucidation and Design of Materials and Molecular Functions & 7th and 8th Yoshimasa Hirata Memorial Lecture, Nagoya (Japan) 2011-11-28～2011-11-30 |
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口頭発表／ポスター発表 "Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis" ○Atsushi Sugiyama, Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi Nagoya University Global COE International Symposium on on Elucidation and Design of Materials and Molecular Functions & 7th and 8th Yoshimasa Hirata Memorial Lecture, Nagoya (Japan) 2011-11-28～2011-11-30 |
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口頭発表／ポスター発表 "Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton" ○Natsuko Kinoshita, Daisuke Uraguchi, *Takashi Ooi International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
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口頭発表／ポスター発表 "Catalytic Enantioselective Oxidation of N-Sulfonyl Imines Using Hydrogen Peroxide" ○Ryosuke Tsutsumi, Daisuke Uraguchi, *Takashi Ooi IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Highly Regio-, Diastereo-, and Enantioselective Vinylogous Michael Reaction" ○Ken Yoshioka, Yusuke Ueki, Daisuke Uraguchi, *Takashi Ooi IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Late-Stage Activation Strategy for Asymmetric Oxidation with Hydrogen Peroxide: Application to the Synthesis of Chiral Oxaziridines" ○Ryosuke Tsutsumi, Daisuke Uraguchi, *Takashi Ooi 1st Japan-USA Organocatalytic Symposium in Hawaii (2012), (USA) 2012-12-16～2012-12-18 |
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招待講演 "Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins" ○Daisuke Uraguchi 1st Japan-USA Organocatalytic Symposium in Hawaii, (USA) 2012-12-16～2012-12-18 |
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| Prize |
"Lectureship Award MBLA 2013" Daisuke Uraguchi 2014-02 公益財団法人 万有生命科学振興国際交流財団 反応性イオン種の制御を志向したキラル有機イオン対触媒の創製と応用 |
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"Thieme Chemistry Journal Award 2014" Daisuke Uraguchi 2013-12 Thieme |
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"Banyu Chemist Award（BCA）" 浦口大輔 2012-10 公益財団法人 万有生命科学振興国際交流財団 反応性イオン種の制御を志向したキラル有機イオン対触媒の創製と応用 |
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"平成２３年度科学技術分野の文部科学大臣表彰若手科学者賞" 浦口大輔 2011-04 文部科学省 分子認識型キラル有機イオン対触媒の創製と応用の研究 |
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| Media |
"「Enantioselective Reductive Multicomponent Coupling Reactions between Isatins and Aldehydes」が、Chemical Science誌のBack Coverに選定" 2016-04-29 |
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""「Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines」が、Chem. Asian J.誌のInside Coverに選定" 2015-01-22" 2015-01-22 |
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"「Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: application to the synthesis of N-sulfonyl oxaziridines」が、Tetrahedron誌のCoverに選定" 2014-02-01 |
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"「Chiral Ionic Brønsted Acid-Achiral Brønsted Base
Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to
Nitroolefins」が、Chemical Science誌のBack Coverに選定" 2012-10-29 |
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| A01 山中 正浩 | ||
| Original papers |
"Dynamic Kinetic Resolution Approach for the Asymmetric Synthesis of Tetrahydrobenzodiazepines Using Transfer Hydrogenation by Chiral Phosphoric Acid" Horiguchi, K.; Yamamoto, E.; Saito, K.; Yamanaka, M.; *Akiyama, T. Chem. Eur. J. 2016, 22 (in press), DOI:10.1002/chem.201601611 |
T. Akiyama |
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"Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular crossaldol reactions" Baba, T.; Yamamoto, J.; Hayashi, K.; Sato, M.; Yamanaka, M.; Kawabata, T.; *Furuta, T. Chem. Sci. 2016, DOI:10.1039/C5SC04594K |
Kawabata, T. | |
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"Insights into the Molecular Recognition Process in Organocatalytic ChemoselectiveMonoacylation of 1,5-Pentanediol" Imayoshi, A.; *Yamanaka, M.; Sato, M.; Yoshida, K.; Furuta, T.; Ueda, Y.; *Kawabata, T. Adv. Synth. Catal. 2016, 358 (8), pp.1337-1344. DOI:10.1002/adsc.201600010 |
Kawabata, T. | |
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"Synthesis of (+)-trans-Dihydrolycoricidine by an Organocatalytic Enantioselective Friedel-Crafts Reaction" Kato, M.; Yasui, K.; Yamanaka, M.; *Nagasawa, K. Asian J. Org. Chem 2016, 5 (3), pp.380-388. DOI:10.1002/ajoc.201500469 |
Nagasawa, K. | |
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"Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Bronsted Acid Catalyst" *Momiyama, N.; Funayama, K.; Noda, H.; Yamanaka, M.; Akasaka, N.; Ishida, S.; Iwamoto, T.; *Terada, M. ACS. Catalysis 2016, 6 pp.949-956. DOI:10.1021/acscatal.5b02079 |
Terada, M. | |
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"Entropy-Driven 1,2-Type Friedel-Crafts Reaction of Phenols with N-tert-Butoxycarbonyl Aldimines" Kato, M.; Hirao, S.; Nakano, K.; Sato, M.; Yamanaka, M.; *Sohtome, Y.; *Nagasawa, K. Chem. Eur. J. 2015, 21 pp.18606-18612. DOI:10.1002/chem.201503280 |
Nagasawa, K. | |
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"Catalytic Asymmetric Iodocyclization of N-Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8-Oxa-6-Azabicyclo[3.2.1]octanes" *Arai, T.; Watanabe, O.; Yabe, S.; Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 pp.12767-12771. DOI:10.1002/anie.201505748 |
Arai, T. | |
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"Development of Guanidine-Bisurea Bifunctional Organocatalysts with a Chiral Pyrrolidine Moiety and Application to α-Hydroxylation of Tetralone-Derived β-Keto Esters" Odagi, M.; Takayama, K.; Sato, M.; Yamanaka, M.; *Nagasawa, K. Molecules 2015, 20 pp.12590-12598. DOI:10.3390/molecules200712590 |
Nagasawa, K. | |
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"PyBidine-Cu(OTf)2-catalyzed asymmetric [3+2] cycloaddition usingimino esters: Harmony of Cu-Lewis acid and imidazolidine-NHhydrogen-bonding in concerto catalysis" *Arai, T.; Ogawa, H.; Awata, A.; Sato, M.; Watabe, M.; *Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 (5), pp.1595-1599. DOI:10.1002/anie.201410782 |
Arai, T. | |
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"Origin of High E-Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α’-Alkenediol: A Computational and Experimental Study" *Yamanaka, M.; Yoshida, U.; Sato, M.; Shigeta, T.; Yoshida, K.; Furuta, T.; *Kawabata, T. J. Org. Chem. 2015, 80 (6), pp.3075-3082. DOI:10.1021/jo5029453 |
Kawabata, T. | |
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"Origin of stereocontorol in guanidine-bisurea bifunctional organocatalyst that promotes α-hydroxyaltion of tetralone-derived β-ketoesters: Asymmetric synthesis of β- or γ-substituted tetralone derivatives via organocatalytic oxidative kinetic resolution" Odagi, M.; Furukori, K.; Yamamoto, Y.; Sato, M.; Iida, K.; Yamanaka, M.;*Nagasawa, K. J. Am. Chem. Soc. 2015, 137 (5), pp.1909-1915. DOI:10.1021/ja511149y |
Nagasawa, K. | |
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"Secondary Stereocontrolling Interactions in Chiral Brønsted Acid Catalysis: Study of a Petasis-Ferrier-Type Rearrangement Catalyzed by Chiral Phosphoric Acids" Kanomata, K.; Toda, Y.; Shibata, Y.; Yamanaka, M.; Tsuzuki, S.; Gridnev, I. D.; *Terada, M. Chem. Sci. 2014, 5 (9), pp.3515-3523. DOI:10.1039/C4SC00611A |
Tsuzuki, S.; Terada, M. | |
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"DFT Studies of Mechanism and Origin of Stereoselectivity of Palladium-Catalyzed Cyclotrimerization Reactions Affording syn-Tris(norborneno)benzenes" *Yamanaka, M.; Morishima, M.; Shibata, Y.; Higashibayashi, S.; *Sakurai, H. Organometallics 2014, 33 (12), pp.3060-3068. DOI:10.1021/om500322b |
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"Chiral Phosphoric-Acid-Catalyzed Transfer Hydrogenation of Ethyl Ketimine Derivatives by Using Benzothiazoline" Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. Chem. Eur. J. 2014, 20 (25), pp.7616-7620. DOI:10.1002/chem.201402763 |
Akiyama, T. | |
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"Trinuclear Zn3(OAc)4-3,3’-bis(aminoimino)binaphthoxide Complex for Highly Efficient Catalytic Asymmetric Iodolactonization" *Arai, T.; Sugiyama, N.; Masu, H.; Kado, S.; Yabe, S.; Yamanaka, M. Chem. Commun. 2014, 42 pp.8287-8290. DOI:10.1039/C4CC02415J |
Arai, T. | |
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"Prediction of suitable catalyst by 1H NMR:
asymmetric synthesis of multisubstituted biaryls by chiral phosphoric acid
catalyzed asymmetric bromination" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.;
Yamanaka, M.; *Akiyama, T. Chem. Sci. 2013, 4 pp.4235-4239. DOI:10.1039/c3sc52142g |
Akiyama, T. | |
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"Asymmetric Michael Addition of β-Ketoesters to Enones Catalyzed by the Lithium Salt of a Primary β-Amino Acid" *Yoshida, M.; Kubara, A.; Nagasawa, Y.; Hara, S.; *Yamanaka, M. Asian J. Org. Chem 2014, 3 (4), pp.523-529. DOI:10.1002/ajoc.201400024 |
Yoshida, M. | |
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"Mechanistic study of asymmetric Michael addition of malonates to enones catalyzed by a primary amino acid lithium salt " *Yoshida, M.; Nagasawa, Y.; Kubara, A.; Hara, S.; *Yamanaka, M. Tetrahedron 2013, 69 (47), pp.10003-10008. DOI:10.1016/j.tet.2013.09.066 |
Yoshida, M. | |
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"Double C(sp3)-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles" Mori, K.; Kurihara, K.; Yabe, S.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2014, 136 (10), pp.3744-3747. DOI:10.1021/ja412706d |
Akiyama, T. | |
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"Chiral Phosphoric Acid-Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines" Saito, K.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 (32), pp.11740-11743. DOI:10.1021/ja406004q |
Akiyama, T. | |
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"Investigation of the Carboxylate Position during the Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal Carboxylate" Nishino, R.; Furuta, T.; Kan K.; Sato, M.; Yamanaka, M.; Sasamori, T.; Tokitoh, N.; *Kawabata, T. Angew. Chem. Int. Ed. 2013, 52 pp.6445-6449. DOI:10.1002/anie.201300665 |
Kawabata, T. | |
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"DFT Study of Mechanism and Origin of Enantioselectivity in Chiral BINOL-Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimine and α-Imino Ester Using Benzothiazoline" Shibata, Y.; *Yamanaka, M. J. Org. Chem. 2013, 78 pp.3731-3736. DOI:10.1021/jo4002195 |
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"Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence" Mori, K.; Ichikawa, Y.; Kobayashi, M.; Shibata, Y.; Yamanaka, M.; *Akiyama, T. J. Am. Chem. Soc. 2013, 135 pp. 3964-3970. DOI:10.1021/ja311902f |
Akiyama, T. | |
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"Theoretical Study on the Regioselectivity of Baeyer-Villiger Reaction of α-Me-, -F-, -CF3-Cyclohexanones" Itoh, Y.; Yamanaka, M.; *Mikami, K. J. Org. Chem. 2013, 78 pp.146-153. DOI:10.1021/jo302151r |
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"Chiral Zn(II)-Bisamidine Complex as a Lewis-Brønsted Combined Acid Catalyst: Application to Asymmetric Mukaiyama Aldol Reactions of α-Ketoesters" Gotoh, R.; *Yamanaka, M. Molecules 2013, 17 pp. 9010-9022. DOI:10.3390/molecules17089010 |
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"Kinetic Resolution in Chiral Brønsted Acid Catalyzed Aldol Reaction: Enantioselective Robinson-type Annulation Reaction" *Yamanaka, M.; Hoshino, M.; Katoh, T.; Mori, K.; *Akiyama, T. Eur. J. Org. Chem. 2012, 24 pp.4508-4514. DOI:10.1002/ejoc.201200338 |
Akiyama, T. | |
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"DFT Study of Chiral Phosphoric Acid Catalyzed Enantioselective Friedel-Crafts Reaction of Indole with Nitroalkene: Bifunctionality and Substituent Effect of Phosphoric Acid" Hirata, T.; *Yamanaka, M. Chem. Asian J. 2011, 6 (2), pp.510-516. |
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| Reviews / Accounts |
"Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation" Zhu, C.; Saito, K.; Yamanaka, M.; *Akiyama, T. Acc. Chem. Res. 2015, 48 (2), pp.388-398. DOI:10.1021/ar500414x |
Akiyama, T. |
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"Theoretical Studies on
Mechanisms and Origins of Stereocontrol in Chiral Phosphoric Acid Catalyzed
Asymmetric Reactions" *Yamanaka, M.; Shibata, Y J. Synth. Org. Chem. Jpn 2014, 72 pp.580-595. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Transition-State Stabilization through Multiple Hydrogen Bonds and Dispersion Interactions in Organocatalysis" ○*Yamanaka, M. 39th NAITO Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Theoretical study on chiral bis-phosphoric acid catalyzed asymmetric Diels-Alder reaction" ○Noda, H.; *Yamanaka, M. Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "DFT study of chiral phosphoric acid catalyzed 1, 4-reduction of α,β-unsaturated ketones" ○Yamamoto, E.; *Yamanaka, M. PACIFICHEM2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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依頼講演 "Transition-state stabilization through multiple attractive non-covalent interactions in organocatalysis: A computational study" ○*Yamanaka, M. PACIFICHEM2015, Honolulu (USA) 2015-12-15～2016-05-20 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Phosphoric Acid Catalyzed Asymmetric Transfer Hydrogenation of Trifluoromethylated N-H Ketimine Using Benzothiazoline" ○Noda, H.; Akiyama, T.; *Yamanaka, M. 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Akiyama | |
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口頭発表／ポスター発表 "Theoretical Study on the Mechanism of Stereoselectivity in Chiral Phosphorus Acid Catalyzed Asymmetric Hydrogenation of 1,5-Benzodiazepine Using Benzothiazoline" ○Yamamoto, E.; Horiguchi, K.; Saito, K.; Akiyama, T.; *Yamanaka, M 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Akiyama | |
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口頭発表／ポスター発表 "Theoretical Study of Asymmertic Desymmetrization of 4-Nosylamino-1,7-heptanediol via 4PPY-Catalyzed Enantioselective Acylation" ○Sato, M.; *Yamanaka, M.; Shigeta, T.; Huruta, T.; Kawabata, T. 2th International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
T. Kawabata | |
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口頭発表／ポスター発表 "Multifunctional Bisamidine
Ligand: Applications in Asymmetric Catalysis" ○*Yamanaka, M. 13th Tateshina Conference on Organic Chemistry, Tateshina (Japan) 2013-11-08～2013-11-10 |
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口頭発表／ポスター発表 "Theoretical
Study on Asymmetric Michael Addition of Malonate to Enone Catalyzed by Primary b-Amino Acid Lithium Salt" ○Nagasawa, Y.; *Yamanaka, M. 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "The
Origin of Enantioselectivity in Chiral Phosphoric Acid-Catalyzed Transfer
Hydrogenation of Imines" ○*Yamanaka, M. 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Theoretical Study on 4-Pyrrolidinopyridine Catalyzed Chemoselective Monoacylation of 1,5-pentanediol" ○Sato, M.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Theoretical Study on Asymmetric Synthesis of Tetrahydroquinoline Derivatives by Chiral Phosphoric Acid Catalyzed Intramolecular Redox Reaction" ○Nagasawa, Y.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Dinuclear Zn-Bisamidinate Catalyzed Asymmetric Hydrophosphonylation of α-Ketoesters" ○Kaizu, K.; *Yamanaka, M. UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 " Theoretical Study on 4-Pyrrolidinopyridine Catalyzed Chemoselective Monoacylation of Linear Diols " ○Sato, M.; *Yamanaka, M.First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Theoretical Study on Chiral Magnesium Phosphate-Catalyzed Phosphination of Imine" ○Shibata, Y.; *Yamanaka, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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招待講演 "Theoretical Studies on Chiral Phosphoric Acid-catalyzed Transfer Hydrogenation of Ketimine Using Benzothiazoline" ○*Yamanaka, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| A01 内丸 忠文 | ||
| Original papers |
"Photooxidation studies on indene-C-60 adducts " Yamane, S.; Mizukado, J.; Uchimaru, T.; Suzuki, Y.; Chen, L.; Suda, H. Solar Energy Materials and Solar Cells 2015, 143 pp.135-140. DOI:10.1016/j.solmat.2015.06.045 |
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"Kinetics of gas-phase reactions of cyc-CF2CF2CF2CHFCH2- and trans-cyc-CF2CF2CF2CHFCHF- with OH radicals between 253 and 328K" Zhang, N.; Chen, L.; Uchimaru, T.; Qing, F. Y.; Mizukado, J.; Quan, H. D.; Suda, H. Chem. Phys. Lett. 2015, 639 pp.199-204. DOI:10.1016/j.cplett.2015.09.020 |
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"Asymmetric Nitrocyclopropanation of alpha-Substituted alpha,beta-Enals Catalyzed by Diphenylprolinol Silyl Ether for the Construction of All-Carbon Quaternary Stereogenic Centers" Hayashi, Y.; Yamazaki, T.; Nakanishi, Y.; Ono, T.; Taniguchi, T,; Monde, K.; Uchimaru, T. Eur. J. Org. Chem. 2015, (26), pp.5747-5754. DOI:10.1002/ejoc.201500838 |
林雄二郎 | |
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"Two Reaction Mechanisms via Iminium Ion Intermediates: The Different Reactivities of Diphenylprolinol Silyl Ether and Trifluoromethyl-Substituted Diarylprolinol Silyl Ether" Gotoh, H.; Uchimaru, T.; Hayashi, Y. Chem. Eur. J. 2015, DOI:10.1002/chem.201500326 |
林雄二郎 | |
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"A Theoretical and Experimental Study of the Effects of Silyl Substituents in Enantioselective Reactions Catalyzed by Diphenylprolinol Silyl Ether" Hayashi, Y.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Gotoh, H.; Tsuzuki, S.; Uchimaru, T.; Seebach, D. Chem. Eur. J. 2014, 20 (51), pp.17077-17088. DOI:10.1002/chem.201403514 |
Hayashi, Y.; Tsuzuki, S. | |
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"ESR study of singlet oxygen generation and its behavior during the photo-oxidation of P3HT in solution " Chen, L.; Yamane, S.; Mizukado, J.; Suzuki, Y.; Kutsuna, S.; Uchimaru, T.; Suda, H. Chem. Phys. Lett. 2015, 624 pp.87-92. DOI:10.1016/j.cplett.2015.02.019 |
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"CCSD(T) Level Interaction Energy for Halogen Bond between Pyridine and Substituted Iodobenzenes: Origin and Additivity of Substituent Effects " Tsuzuki, S.; Uchimaru, T.; Wakisaka, A.; Ono, T.; Sonoda, T. Phys. Chem. Chem. Phys. 2013, (15-16), pp.6088-6096. DOI:10.1039/C3CP43693D |
都築誠二 | |
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"Equatorenes: Synthesis and Properties of Chiral Naphthalene, Phenanthrene,
Chrysene, and Pyrene Possessing Bis(1-adamantyl) Groups at the Peri-Position " Yamamoto, K.; Oyamada, N.; Sheng, X.; Kobayashi, Y.; Yamaguchi, M.; Maeda, H.; Nishihara, H,; Uchimaru, T.; Ensang, K. J. Am. Chem. Soc. 2013, 135 (44), pp.16526-16532. DOI:10.1021/ja407800e |
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"Organocatalytic 1,4-Addition Reaction of alpha,beta-gamma,delta-Diunsaturated Aldehydes versus 1,6-Addition Reaction" *Hayashi, Y.; Okamura, D.; Umrmiya, S.; *Uchimaru, T. ChemCatChem. 2012, 4 (7), pp.959-962. DOI:10.1002/cctc.201200161 |
林雄二郎 | |
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"Kinetics and mechanism of gas-phase reaction of CF3CF2CF2CF2CF2CF2CF2CF2H with OH radicals in an environmental reaction chamber at 253-328 K " *Chen, L.; Uchimaru, T.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A,; Okamoto, H. Chem. Phys. Lett. 2011, 501 (4-6), pp.263-266. DOI:10.1016/j.cplett.2010.12.009 |
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"Kinetics and mechanism of gas-phase reactions of n-C4F9OCH3, i-C4F9OCH3, n-C4F9OC(O)H, and i-C4F9OC(O)H with OH radicals in an environmental reaction chamber at 253-328 K " *Chen, L.; Uchimaru, T.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A. Chem. Phys. Lett. 2011, 514 (4-6), pp.207-213. DOI:10.1016/j.cplett.2011.08.049 |
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"Organocatalytic, Enantioselective Intramolecular [6 + 2] CycloadditionReaction for the Formation of Tricyclopentanoids and Insight on ItsMechanism from a Computational Study" *Hayashi, Y.; Gotoh, H.; Honma, M.; Sankar, K.; Kumar, I.; Ishikawa, H.; Konno, K.; Yui, H.; Tsuzuki, S.; *Uchimaru, T. J. Am. Chem. Soc. 2011, 133 (50), pp.20175-20185. DOI:10.1021/ja108516b |
林雄二郎 都築誠二 石川勇人 | |
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes" Tsuzuki, S; Uchimaru, T. 有機分子触媒による未来型分子変換第１回国際会議, 大津 (日本) 2013-05-27～2013-05-28 |
都築誠二 |
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口頭発表／ポスター発表 "Effects of the Silyl Substituent of Diphenylprolinol Silyl Ether in the OrganoCatalyst-Mediated Asymmetric Reactions: Computational and Experimental Investigations" Uchimaru, T.; Tsuzuki, S.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Goto, H.; Hayashi, Y. 5th JCS International Symposium on Theoretical Chemistry, 奈良 (日本) 2013-12-02～2013-12-06 |
林雄二郎 都築誠二 | |
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口頭発表／ポスター発表 "Effects of the Silyl Substituent of Diphenylprolinol Silyl Ether in the Organocatalyst-Mediated Asymmetric Reactions: Computational and Experimental Investigations" Uchimaru, T.; Tsuzuki, S.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Gotoh, H.; Hayashi, Y. 有機分子触媒による未来型分子変換第１回国際会議, 大津 (日本) 2013-05-27～2013-05-27 |
林雄二郎 都築誠二 | |
| A01 都築 誠二 | ||
| Original papers |
" Synthesis of Novel Ionic Liquids with Aromatic Trifluoroborate Anions "
K. Iwasaki, K. Yoshii, S. Tsuzuki, T. Tsuda, and S. *Kuwabata ECS Transactions 2014, 64 (4), pp.83-93. DOI:10.1149/06404.0083ecst |
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Lithium Redox in Imidazolium Ionic Liquids Composed
of Five-Membered Cyclic Amide "
*H. Matsumoto, S. Tsuzuki, K. Kubota ECS Transactions 2014, 64 (4), pp.223-230. DOI:10.1149/06201.0223ecst |
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Effects of Non-Equimolar Lithium Salt Glyme Solvate
Ionic Liquid on the Suppression of Interfacial Degradation for High-Voltage
Operation of Lithium- Secondary Batteries "
*S. Seki, N. Serizawa, K. Takei, Y. Umebayashi, Y.
Katayama, M. Takashi, K. Dokko, M. Watanabe, S. Tsuzuki RSC Advance 2016, 6 (39), pp.33043-33047. DOI:10.1039/c6ra04404b |
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Origin of attraction and directionality of hydrogen bond and halogen bond: Analysis by ab initio MO calculations "S. Tsuzuki AIP Conference Proceedings 2015, 1702 pp.090044. DOI:10.1063/1.4938852 |
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Li+ Local Structure in Hydrofluoroether Diluted Li-Glyme Solvate Ionic Liquid " S. Saito, H. Watanabe, K. Ueno, T. Mandai, S. Seki, S. Tsuzuki, Y. Kameda, K. Dokko, M. Watanabe, *Y. UmebayashiJ. Phys. Chem. B 2016, 120 (13), pp.3378-3387. DOI:10.1021/acs.jpcb.5b12354 |
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Construction of Chiral Polar Crystals from Achiral Molecules by Stacking Control of Hydrogen-bonded Layers Using Type II Halogen Bonds " *T. Sasaki, Y. Ida, I. Hisaki, S. Tsuzuki, N. Tohnai, G. Coquerel, H. Sato, *M. MiyataCrystal Growth & Design, in press. 2016, DOI:DOI: 10.1021/acs.cgd.5b01724 |
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Thermal and Electrochemical Stability of Tetraglyme-Magnesium Bis(trifluoromethanesulfonyl)amide Complex: Electric Field Effect of Divalent Cation on Solvate Stability " S. Terada, T.o Mandai, S. Suzuki, S. Tsuzuki, K. Watanabe, Y. Kamei, K. Ueno, *K. Dokko, M. WatanabeThe Journal of Physical Chemistry C 2016, 120 (3), pp.1353-1365. DOI:DOI: 10.1021/acs.jpcc.5b09779 |
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Synthesis, ion recognition ability, and metal-assisted aggregation behavior of dinuclear metallohosts having a bis(saloph) macrocylic ligand " *Shigehisa Akine, Fumihiko Utsuno, Shunjin Piao, Hideo Orita, Seiji Tsuzuki, *Tatsuya NabeshimaInorganic Chemitry 2016, 55 (2), pp.810-821. DOI:DOI: 10.1021/acs.inorgchem.5b02288 |
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Design, synthesis and optical properties of unsymmetrical subphthalocyanine trimer connected by phloroglucinol via axial positions " S. Mori, N. Ogawa, E. Tokunaga, S. Tsuzuki and *N. ShibataDalton Trans 2016, 45 (3), pp.908-912. DOI:DOI: 10.1039/C5DT04500B. |
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Photo-Fries rearrangement of phenyl salicylate studied by Two-dimensional Infrared spectroscopy " *Hideyuki Shinzawa, Yuki Matsumoto, Seiji Tsuzuki, Yukihiro Shimoi, Hiroyuki SudaVibrational Spectroscopy 2015, 81 pp.131-135. |
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Reinforcement of guest selectivity through the self-assembly of host molecules: selective recognition of lithium ions by dimerizable tricarboxylic acids " Shoichi Minodani, Masaki Owaki, Shuhei Sano, Seiji Tsuzuki and *Masamichi YamanakaChem. Commun. 2015, 51 (65), pp.12920-12923. DOI:DOI: 10.1039/c5cc05227k |
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Ester-Linked Alkyl Chain Effect on 2D Structures of Isobutenyl Compounds: Scanning Tunneling Microscopic Study " *Y. Kikkawa, M. Ishitsuka, K. Omori, A. Kashiwada, S. Tsuzuki, K. HirataniBull. Chem. Soc. Jpn 2015, 88 (6), pp.834-842. DOI:DOI: 10.1246/bcsj.20150018 |
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Simulation of metal-organic framework self-assembly "*M. Yoneya, S. Tsuzuki, M. Aoyagi Phys. Chem. Chem. Phys. 2015, 17 (14), pp.8649-8652. DOI:DOI: 10.1039/C5CP00379B |
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Li Solvation in Glyme-Li Salt Solvate Ionic Liquids "K. Ueno, R. Tatara, S. Tsuzuki, S. Saito, H. Doi, K. Yoshida, T. Mandai, M. Matsugami, Y. Umebayashi, K. Dokko, *M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (14), pp.8248-8257. DOI:DOI: 10.1039/C4CP05943C |
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Effect of Ionic Size on Solvate Stability of
Glyme-Based Solvate Ionic Liquids "
T. Mandai, K. Yoshida, S. Tsuzuki, R. Nozawa, H. Masu, K. Ueno, Dokko, *M. Watanabe J. Phys. Chem. B 2015, 119 (4), pp.1523-1534. DOI:DOI: 10.1021/jp508100s J |
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Pentaglyme-K Salts Binary Mixtures: Phase Behavior, Solvate Structures, and Physicochemical Properties "*T. Mandai, S. Tsuzuki, K. Ueno, K. Dokko, M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (4), pp.2838-2849. |
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ハロゲン結合の引力の原因と方向性 "*都築誠二、内丸忠文 J. Comput. Chem. Jpn 2014, 13 (6), pp.328-329. DOI:DOI: 10.2477/jccj/2014-0062 |
内丸忠文 | |
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Upper Limit of Nitrogen Content in Carbon Materials "S. Zhang, S. Tsuzuki, K. Ueno, K. Dokko and *M. Watanabe Angew. Chem. Int. Ed. 2015, 54 (4), pp.1302-1306. DOI:DOI: 10.1002/ange.201410234 |
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Structures of [Li(glyme)]+ complexes and their interactions with anions in equimolar mixtures of glymes and Li[TFSA]: analysis by molecular dynamics simulations "*S. Tsuzuki, W. Shinoda, M. Matsugami, Y. Umebayashi, K. Ueno, T. Mandai, S. Seki, K. Dokko and M. Watanabe Phys. Chem. Chem. Phys. 2015, 17 (1), pp.126-129. DOI:DOI: 10.1039/C4CP04718D |
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Bicomponent blend-directed amplification of the alkyl chain effect on the 2D structures "*Y. Kikkawa, M. Ishitsuka, A. Kashiwada, S. Tsuzuki and K. Hiratani Chem. Commun. 2014, (50), pp.13146-13149. DOI:DOI: 10.1039/C4CC04624B |
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Static, Transport, and Diffusive Properties of Alkyl-trimethylammonium Cation-based Room-temperature Ionic Liquids " *S. Seki, S. Tsuzuki, K. Hayamizu, N. Serizawa, S. Ono, K. Takei, H. Doi, Y. UmebayashiJ. Phys. Chem. B 2015, 118 (17), pp.4590-4599. DOI:DOI: 10.1021/jp500123q |
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Transport and Electrochemical Properties of Three Quaternary Ammonium Ionic Liquids and Lithium Salts Doping Effects Studied by NMR Spectroscopy "*K. Hayamizu, S. Tsuzuki, S. Seki J. Chem. Eng. Data 2014, 59 (6), pp.1944-1954. DOI:DOI: 10.1021/je500065k |
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Studies on the C/O-regioselectivity in Electrophilic Fluoromethylations of β-Ketoesters based on Thermodynamics by Ab initio Calculations "Y.-D. Yang, X. Wang, S. Tsuzuki, E. Tokunaga, *N. Shibata Bull. Korean Chem. Soc. 2014, 35 (6), pp.1851-1854. DOI:DOI: 10.5012/bkcs.2014.35.6.1851 |
N. Shibata | |
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Physicochemical properties of pentaglyme-sodium bis(trifluoromethanesulfonyl)amide solvate ionic liquid "S. Terada, T. Mandai, R. Nozawa, K. Yoshida, K. Ueno, S. Tsuzuki, K. Dokko, *M. Watanabe Phys. Chem. Chem. Phys. 2014, 16 (23), pp.11737-11746. DOI:DOI: 10.1039/c4cp00746h |
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"Cation and anion dependence of stable geometries and stabilization energies of alkali metal cation complexes with FSA-, FTA- and TFSA- anions: Relationship with physicochemical properties of molten salts"
*S. Tsuzuki, K. Kubota, H. Matsumoto J. Phys. Chem. B 2013, 117 (50), pp.16212-16218. DOI:DOI: 10.1021/jp409113z |
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Coordination-Directed Self-Assembly of M12L24 Nanocage: Effects of Kinetic Trapping on the Assembly Process "*M. Yoneya, S. Tsuzuki, T. Yamaguchi, S. Sato, M. Fujita ACS NANO 2014, 8 (2), pp.1290-1296. DOI:DOI: 10.1021/nn404595j |
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Interactions in ion pairs of protic ionic liquids: Comparison with aprotic ionic liquids "*S. Tsuzuki, W. Shinoda, M. S. Miran, H. Kinoshita, T. Yasuda, M. Watanabe J. Phys. Chem. B 2013, 117 (50), pp.16212-16218. DOI:DOI: 10.1021/jp409113z |
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Phase Diagrams and Solvate Structures of Binary Mixtures of Glymes and Na Salts " T. Mandai, R. Nozawa, S. Tsuzuki, K. Yoshida, K. Ueno, K. Dokko, *M. WatanabeJ. Phys. Chem. C, 2013, 117 (48), pp.15072-15085. DOI:DOI: 10.1021/jp407582m |
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Comparative Study on Physicochemical Properties of Protic Ionic Liquids Based on Allylammonium and Propylammonium Cations " T. Yasuda, H. Kinoshita, M. S. Miran, S. Tsuzuki, *M. WatanabeJ. Chem. Eng. Data 2013, 58 (10), pp.2724-2732. DOI:DOI: 10.1021/je301284x |
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Unusual Li+ Ion Solvation Structure in Bis(fluorosulfonyl)amide Based Ionic Liquid " K. Fujii, H. Hamano, H. Doi, X. Song, *S. Tsuzuki, K. Hayamizu, S. Seki, Y. Kameda, K. Dokko, M. Watanabe, *Y. Umebayashi J. Phys. Chem. C, 2013, 117 (38), pp.19314-19324. DOI:DOI: 10.1021/jp4053264 |
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" Origin of Attraction in Chalgogen-Nitrogen Interaction of 1,2,5-Chalcogenadiazole Dimers "*Tsuzuki, S.; N. Sato, N. J. Chem. Phys. B 2013, 117 pp.6849-6855. DOI:10.1021/jp403200j |
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" Intermolecular Interactions in Li+-glymes and Li+-glymes-TFSA- complexes: Relationship with Physicochemical Properties of [Li(glymes)][TFSA] Ionic Liquids "*Tsuzuki, S.; Shinoda, W.;. Seki, S.; Umebayashi, Y.; Yoshida, K.; Dokko, K.; Watanabe, M. ChemPhysChem 2013, 14 pp.1993-2001. DOI:10.1002/cphc.201200843 |
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" Linkage Control between Molecular and Supramolecular Chirality in 21-Helical Hydrogen-bonding Networks by Using Achiral Components "Sasaki, T.; Hisaki, I.; Miyano, T.; Tohnai, N.; Morimoto, K.; Sato, H.; Tsuzuki, S.; *Miyata, M. Nature Commun. 2013, (4), pp.1787. DOI:10.1038/ncomms2756 |
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" CCSD(T) Level Interaction Energy for Halogen Bond between Pyridine and Substituted Iodobenzenes: Origin and Additivity of Substituent Effects "*Tsuzuki, S.; Uchimaru, T.; Wakisaka, A.; Ono, T.; Sonoda, T. Phys. Chem. Chem. Phys. 2013, 15 (16), pp.6088-6096. DOI:10.1039/C3CP43693D |
Uchimaru, T. | |
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" Encapsulation-Induced Remarkable Stability of Hydrogen-Bonded Heterocapsule "Ichihara, K.; Kawai, H.; Togari, Y.; Kikuta, E.; Kitagawa, H.; *Tsuzuki, S.; Yoza, K.; Yamanaka, M.; *Kobayashi, K. Chem. Eur. J. 2013, 19 (11), pp.3685-3692. |
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" Crystal Structure of Quinine: The Effects of Vinyl and Methoxy Groups on Molecular Assemblies of Cinchona Alkaloids Cannot Be Ignored "*Hisaki, I.; Hiraishi, E.; Sasaki, T.; Orita, H.; Tsuzuki, S.; Tohnai, N.; Miyata, M. Chem. Asian J. 2013, 7 (11), pp.2607-2614. |
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" Multinuclear NMR Studies on Translational and Rotational Motion for Two Ionic Liquids Composed of BF4 Anion "*Hayamizu, K.; Tsuzuki, S.; Seki, S.; Umebayashi, Y. J. Chem. Phys. B 2012, 116 (36), pp.11284-11291. |
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" Halogen bond effect on bundling of hydrogen bonded 2-fold helical columns "Sasaki, T.; *Hisaki, I.; Tsuzuki, S.; Tohnai, N.; *Miyata, M. CrystEngComm 2013, 14 (18), pp.5749-5752. |
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" Physicochemical and Electrochemical Properties of 1-Ethyl-3-Methylimidazolium Tris(pentafluoroethyl)trifluorophosphate and 1-Ethyl-3-Methylimidazolium Tetracyanoborate "*Seki, S.; Serizawa, N.; Hayamizu, K.; Tsuzuki, S.; Umebayashi, Y.; Takei, K.; Miyashiro, H. J. Electrochem. Soc. 2012, 159 (7), pp.A967-A971. |
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" Comprehensive Refractive Index Property for Room-Temperature Ionic Liquids "*Seki, S.; *Tsuzuki, S.; Hayamizu, K.; Umebayashi, Y., Serizawa, N.; Takei, K.; Miyashiro, H. J. Chem. Eng. Data 2012, 57 (8), pp.2211-2216. |
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" Comparative Study of Imidazolium- and Pyrrolidinium- Based Ionic Liquids: Thermodynamic Properties "*Shimizu, Y.; Ohte, Y.; Yamamura, Y.; Tsuzuki, S.; Saito, K. J. Phys. Chem. B 2012, 116 (18), pp.5406-5413. |
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" Interactions between dehydrobenzo[12]annulene (DBA) and gas molecules: do the preorganized acetylenes work cooperatively? "*Hisaki, I.; Yasumiya, D.; Shigemitsu, H.; *Tsuzuki, S.; Tohnai, N.; *Miyata, M. Phys. Chem. Chem. Phys. 2012, 14 (40), pp.13918-13921. |
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" Preference of the monodentate contact in the CH/π interaction between an alkyl group and a single phenyl ring: Stable structure of the benzene-ethane cluster " *Fujii, A.; Hayashi, H,; *Tsuzuki, S.Chem. Phys. Lett. 2012, 537 (1), pp.11-15. |
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" Magnitude of CH/O Interactions between Carbohydrate and Water "*Tsuzuki, S.; Uchimaru, T.; Mikami, M. Theor. Chem. Acc. 2012, 131 (3), pp.1192. |
Uchimaru, T. | |
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" Magnitude and Origin of Attraction and Directionality of Halogen Bonds of C6F5X and C6H5X (X = I, Br, Cl and F) with Pyridine "*Tsuzuki, S.; Wakisaka, A.; Ono, T.; Sonoda, T. Chem. Eur. J. 2012, 18 (3), pp.951-960. |
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" Organocatalytic, Enantioselective Intramolecular [6+2] Cycloaddition Reaction for the Formation of Tricyclopentanoids and Insight on Its Mechanism from a Computational Study "*Hayashi, Y.; Gotoh, H.; Honma, M.; Sankar, K.; Kumar, I.; Ishikawa, H.; Konno, K.; Yui, H.; Tsuzuki, S.; *Uchimaru, T. J. Am. Chem. Soc. 2011, 133 (50), pp.20175-20185. |
Hayashi, Y.; Uchimaru, T. | |
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" Liquid structure of and Li+ ion solvation in bis(trifluoromethanesulfonyl)amide based ionic liquids composed of 1-ethyl-3-methylimidazolium and N-methyl-N-propylpyrrodilinium cations "*Umebayashi, Y.; Hamano, H.; Seki, S.; Fujii, K.; Hayamizu, K.; Tsuzuki, S.; kameda, Y.; Kohara, S.; Watanabe, M. J. Phys. Chem. B 2011, 115 (42), pp.12179-12191. |
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" Magnitude and Nature of Carbohydrate-Aromatic Interactions in Fucose-Phenol and Fucose-Indole Complexes: CCSD(T) level interaction energy calculations "*Tsuzuki, S.; Uchimaru, T.: Mikami, M J. Phys. Chem. A 2011, 115 (41), pp.11256-11256. |
Uchimaru, T. | |
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" Nuclear magnetic resonance studies on the rotational and translational motions of ionic liquids composed of 1-ethyl-3-methylimidazolium cation and bis(trifluoromethanesulfonyl)amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts "*Hayamizu, K.; Tsuzuki, S..; Seki, S.; Umebayashi Y. J. Chem. Phys. 2011, 135 (8), pp.084505. |
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" Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme-Lithium Salt Equimolar Complexes "Yoshida, K.; Nakamura, M.; Kazue, Y.; Tachikawa, N.; Tsuzuki, S.; Seki, S.; Dokko, K.; *Watanabe, M. J. Am. Chem. Soc. 2011, 133 (33), pp.13121-13129. |
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" Physicochemical Properties and Application of Ionic Liquids with N-P Bonds as Lithium Secondary Battery Electrolytes "*Serizawa, N.; Seki, S.; Tsuzuki, S.; Hayamizu, K.; Umebayashi, Y.; Takei, K.; Miyashiro, H. J. Electrochem. Soc. 2011, 158 (9), pp.A1023-A1030. |
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" Experimental and theoretical determination of the accurate CH/pi interaction energies in benzene-alkane clusters: correlation between interaction energy and polarizability "*Fujii, A.; Hayashi, H.; Park, J. W.; kazama, T.; Mikami, N.; *Tsuzuki, S. PHys. Chem. Chem. Phys. 2011, 13 (31), pp.14131-14141. |
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" Effects of conformational flexibility of alkyl chain of cations on diffusion of ions in ionic liquids "*Tsuzuki, S. Matsumoto, H.; Shinoda, W.; Mikami, M. Phys. Chem. Chem. Phys. 2011, 13 (13), pp.5987-5993. |
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" Temperature-dependent (11)B spin-lattice relaxation time for BF(4) and CF(3)BF(3) anions in room-temperature ionic liquids "*Hayamizu, K.; Tsuzuki, S.; Seki, S. Magnetic Resonance in Chemistry 2011, 49 (1), pp.6-8. |
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| Books |
「
Advances in Organic Crystal Chemistry: Comprehensive Reviews 2015 」 R. Tamura, M. Miyata"Analysis of intermolecular interactions by ab initio molecular orbital calculations: Importance for studying organic crystals" S. Tsuzuki et al. Springer 2016, pp187-200. |
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「
有機分子の分子間力： Ab initio 分子軌道法による分子間相互作用エネルギーの解析 」都築誠二 東京大学出版会 (東京) 2015, ISBN:978-4-13-062510-4 |
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| Reviews / Accounts |
"
イオン間相互作用がイオン液体の液体構造や輸送物性に与える影響：Ab initio 分子軌道法、分子動力学を用いた解析 " 都築誠二日本結晶学会誌、in press. 2016, |
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分子軌道法を使った分子間力の解析 " 都築誠二化学と教育 2015, 63 (8), pp.376-379. |
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"
Origin of attraction and directionality of hydrogen bond and halogen bond: Analysis by ab initio MO calculations " S. TsuzukiAIP Conference Proceedings 2015, 1702 pp.090044. DOI:doi: 10.1063/1.4938852 |
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グライム系リチウム溶媒和イオン液体の化学と応用 "都築誠二、渡邉正義 Electrochemistry 2014, 82 (12), pp.1079-1084. |
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計算化学によるイオン液体電解質の研究 "Tsuzuki, S. Electrochemistry 2013, 81 (12), pp.1001-1005. DOI:JOI:DN/JST.JSTAGE/electrochemistry/81.1001 |
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" ハロゲン結合の性質と作用機構 "*Tsuzuki, S. Fluorine 2013, 5 (1-2), pp.11-18. |
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Factors controlling the diffusion of ions in ionic liquids "*Tsuzuki, S. ChemPhysChem 2012, 13 (7), pp.1664-1670. |
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"
Analysis of weak intermolecular interactions by ab initio molecular orbital calculations " Tsuzuki, S.Journal of Synthetic Organic Chemistry Japan 2012, 70 (8), pp.831-841. DOI:10.5059/yukigoseikyokaishi.70.831 |
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"CH/π interactions" Tsuzuki, S. Annu. Rep. Prog. Chem., Sect. C: Phys. Chem., 2012, 108 pp.69-95. DOI:DOI: 10.1039/C2PC90003C |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "
Battery performances of lithium solvated ionic liquid
as electrolyte materials "
○関志朗、芹沢信幸、竹井勝仁、都築誠二、梅林
泰宏、獨古薫、渡邉正義 Joint EMLG/JMLG Annual Meeting 2015 in Rostock Molecular Liquids Meet Ionic Liquids From Fundamentals to Applications, Rostock (ドイツ) 2016-03-10～2016-03-10 |
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口頭発表／ポスター発表 "
Why Stable Glyme-Li Complex Exists in Solvate Ionic Liquid? " ○Seiji Tsuzuki, Wataru Shinoda, Kazuhide Ueno, Toshihiko Mandai, Shiro Seki, Soushi Saito, Hiroyuki Doi, Yasuhiro Umebayashi, Kaoru, Dokko, Masayoshi Watanabe34th international conference on solution chemistry, プラハ (チェコ) 2015-08-31～2016-09-03 |
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招待講演 "
Relationship between interionic interaction and transport properties of ionic liquids: Analysis by ab initio MO calculations and MD simulations " Seiji Tsuzuki7th International Symposium on “Molecular Thermodynamics and Molecular Simulation (MTMS15), 福岡 (日本) 2016-08-04～2016-08-06 |
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口頭発表／ポスター発表 "
Analysis of chalcogen-chalcogen and halogen-halogen interactions in crystals by ab initio molecular orbital calculations " ○Seiji Tsuzuki、Yoshiki Higuchi, Naoki Satothe 22nd International Conference on the Chemistry of the Organic Solid State (ICCOSS XXII), 新潟 (日本) 2015-07-06～2015-07-10 |
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口頭発表／ポスター発表 "
Origin of directionality of hydrogen bond and halogen bond: Effects of anisotropic charge distributions on atoms " Seiji TsuzukiICQC 2015 Satellite Symposium in Kobe, 神戸 (日本) 2015-06-09～2015-06-12 |
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招待講演 "
Origin of attraction and
directionality of hydrogen bond and halogen bond: Analysis by ab initio MO
calculations "
S. Tsuzuki Computational Chemistry Symposium in 11TH INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING (ICCMSE 2015), アテネ (ギリシア) 2015-03-20～2015-03-24 |
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口頭発表／ポスター発表 "
Chromatographic Behavior in Reversed-Phase Liquid Chromatography Using Water as the Mobile Phase Solvent "○島崎裕紀、都築誠二、望月祐志、宮部寛志 PITTCON Confelence & Expo 2015, New Orleans (アメリカ) 2015-03-06～2015-03-09 |
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口頭発表／ポスター発表 "
Stability of Glyme-Li Complex in Solvate Ionic Liquid "○都築誠二、篠田渉、上野和英、万代俊彦、関志朗、齊藤蒼思、土井寛之、梅林泰宏、獨古薫、渡邉正義 4th Asia-Pacific Conference on Ionic Liquids and Green Processes & the 6th Australasian Symposium on Ionic Liquids (APCIL-4/ASIL-6 2014), シドニー (オーストラリア) 2014-09-27～2014-09-30 |
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口頭発表／ポスター発表 "
Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes "○都築 誠二、内丸 忠文 Computational Science Workshop 2014, Tsukuba (Japan) 2014-08-19～2014-08-21 |
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口頭発表／ポスター発表 "
Static and Transport Properties of Ionic Liquids and Their Binary Mixtures "
○関志朗、芹沢信幸、竹井勝仁、早水紀久子、都築誠二、梅林 泰宏 EUCHEM2014, Molten Salts and Ionic Liquids XXV, Tallinn (エストニア) 2014-07-05～2014-07-09 |
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招待講演 "
Origin of attraction and directionality of intermolecular interactions between organic molecules "Seiji Tsuzuki Joint Congress of Asian Crystallization Technology Symposium-2014 and 11th International Workshop of Crystal Growth of Organic Materials, Nara (Japan) 2014-06-18～2014-06-20 |
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口頭発表／ポスター発表 "
Molecular simulation of boron isotope effect influenced by pressure enhancing dehydration of boron hydrates "○Ichikawa, H.; Musashi, M.; Mikami, M.; Tsuzuki, S.; Ooi, T. The 4th International Symposium on Innovative nuclear energy systems, Tokyo (Japan) 2013-11-06～2013-11-08 |
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"
Computational and Experimental Approach for Halogen Bonds of Pyridine with Organic Compounds in Gas-phase and Solution "Tsuzuki, S.; Wakisaka, A.; Ono, T.; ○Sonoda, T. Prague (Czech Republic) 2013-09-01～2013-09-06 |
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口頭発表／ポスター発表 "
Physicochemical Properties of Imidazolium-Based Ionic Liquid-Glyme Mixtures "○Takuya Shimomura, Daisuke Kodama, Takashi Makino, Mitsuhiro Kanakubo, Seiji Tsuzuki International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan, Sendai (Japan) 2013-09-28～2013-09-30 |
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Li+ ion speciation in Li-glymes ionic liquids toward rechargeable batteries "○Saito, S.; Doi, H.; Mandai, H.; Tsuzuki, S.; Shinoda, W.; Seki, S.; Dokko, K.; Watanabe, M.; Umebayashi, H. 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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Liquid and Li+ Local Structures in Li-glymes Complex Ionic Liquids Revealed by Raman and X-ray Scattering Techniques with the Aid of Theoretical Calculations "○Saito, S.; Doi, H.; Tsuzuki, S.; Shinoda, W.; Dokko, K.; Watanabe, M.; Umebayashi, H. 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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招待講演 "
First principle approach for studying intermolecular interactions "Tsuzuki, S. 6th APCTCC (Asian-Pacific Conference of Theoretical and Computational Chemistry), Gyeongju (Korea) 2013-07-10～2013-07-13 |
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Mixiing state of imidazolium-based ionic liquid-diglyme solutions studied by NMR and MD simulations "○T. Shimomura, D. Kodama, M. Kannakubo, S. Tsuzuki 33rd International Conference on Solution Chemistry Post-symposium on Ionic Liquids From Science to Green Chemical Applications, Tokyo (Japan) 2013-07-13～2013-07-13 |
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Origin of attraction and directionality of
nonbonding interactions of halogen atoms
" Tsuzuki, S. 7th Molecular Quantum Mechanics, Lugano (Switzerland) 2013-06-02～2013-06-07 |
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口頭発表／ポスター発表 " Tetrabutylammonium Salts as Templates for Stereoselective Norrish Type II Reactions of 2-Benzyloxyacylbenzenes "○Yamada, S.; Iwaokoa, A.; Tsuzuki, S. 1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Yamada, S. | |
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口頭発表／ポスター発表 " Origin and Additivity of Substituent Effects on Halogen Bond between Pyridine and Substituted Iodobenzenes "○Tsuzuki, S.; Uchimaru, T. 1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Uchimaru, T. | |
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口頭発表／ポスター発表 " Intermolecular interactions and liquid properties of protic ionic liquids: Comparison with aprotic ionic liquds "○Tsuzuki, S.; Shinoda, W.; Miran, M. S.; Kinoshita, H.; Yasuda, T.; Dokko, K.; Watanabe, M. 5tn International congress on ionic liquids (COIL-5), Algarve (Portugal) 2013-04-21～2013-04-25 |
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招待講演 " Factors controlling the diffusion of ions in ionic liquids " Tsuzuki, S.243rd ACS National Meeting, San Diego (United State) 2012-03-25～2012-03-29 |
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口頭発表／ポスター発表 " Importance of Low Coordinating Anion for Developing Lithium Secondary Batteries Using Ionic Liquids "○Matsumoto, H.; Terasawa, N.; Sakaebe, H.; Tsuzuki, S.; Hubert, V.; Kohyama, M.; Tatsumi, K. The first Electrochemical Energy Summit, Boston (United State) 2011-10-09～2011-10-14 |
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口頭発表／ポスター発表 " Effects of Conformational Flexibility on Diffusion of Ions in Ionic Liquids "○ Tsuzuki, S.; Matsumoto, H.; Shinoda, W.; Mikami, M. the 62nd Annual Meeting of theInternational Society of Electrochemistry, Nigata (Japan) 2011-09-11～2013-09-15 |
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口頭発表／ポスター発表 " NMR Relaxation Studies on 1-Alkyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide "○Kanakubo, M.; Harris, K. R.; Tsuzuki, S.; Umecky, T.; Makino, T.; Suzuki, A. 32nd International Conference on Solution Chemistry (ICSC2011), La Grande Motte (France) 2011-08-28～2013-09-02 |
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| Media |
" アキラル成分を用いた2回らせん水素結合ネットワークにおける分子キラリティーと超分子キラリティーの間のつながり制御 "Sasaki, T.; Hisaki, I.; Miyano, T.; Tonai, K.; Morimoto, K.; Sato, H.; Tsuzuki, S.; Miyata, M. Nature communications ホームページ、注目の論文 2013-05-27PDF キラル分子は、分子の絶対配置を反映して片方のキラリティーの超分子集合体を優先的に形成する。しかし、特定の条件下では、結合長の柔軟性と非共有結合相互作用の可逆性のために、キラリティーが逆の超分子集合体も得られる。このキラリティーの選択性やスイッチング現象の機構はまだよくわかっておらず、ほとんどの現象は偶然観察される。今回我々は、結晶学的研究に基づいて結晶状態でのキラリティーを制御した、キラルな水素結合2回らせん集合体の構造構築を実証する。得られた結晶構造を詳細に調べることで、キラリティーのスイッチング機構を明らかにし、これに基づきアキラルな要素を導入して超分子集合体のキラリティーの制御に成功した。この研究によって、結晶状態における分子キラリティーと超分子キラリティーのつながりが明確になった。 |
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" ２回らせんの右巻き・左巻きの選択機構を解明 左右変換可能なキラル材料の開発へ "Sasaki, T.; Hisaki, I.; Miyano, T.; Tonai, K.; Morimoto, K.; Sato, H.; Tsuzuki, S.; Miyata, M. 大阪大学ホームページ、最新研究成果リリース 2013-05-15PDF 大阪大学産業科学研究所の宮田幹二招へい教授、同大学院工学研究科の藤内謙光准教授・久木一朗助教・佐々木俊之氏(博士後期課程3年)、愛媛大学理学研究科の佐藤久子教授、産業技術総合研究所の都築誠二上級主任研究員らの研究グループは共同で、キラルなアミンとアキラルなカルボン酸から成る数多くの有機塩結晶の単結晶X線構造解析を通して、結晶中の水素結合2回らせんの右巻きと左巻きの選択機構を解明し、その制御に成功しました。このようならせんの左右の制御は医薬品の開発だけでなく、円偏光を利用した3Dディスプレイなどの光学デバイスへの応用が期待されます。 本研究成果は2013年4月30日(ロンドン時間)に英国Nature Publishing GroupのNature Communicationsのオンライン速報版で公開されました。 |
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| A01 寺田 眞浩 | ||
| Original papers |
"Brønsted Base-Catalyzed Three-Component Coupling Reaction of α-Ketoesters, Imines, and Diethyl Phosphite Utilizing [1,2]-Phospha-Brook Rearrangement
" Kondoh, A.; *Terada, M. Org. Biomol. Chem. 2016, 14 (20), pp.4704-4711. DOI:10.1039/C6OB00739B |
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"Novel Methodology for the Efficient Synthesis of 3-Aryloxindoles: [1,2]-Phospha-Brook Rearrangement–Palladium-Catalyzed Cross-Coupling Sequence
" Kondoh, A.; Takei, A.; *Terada, M. Synlett 2016, Accepted Manuscript. DOI:10.1055/s-0035-1561859 |
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"Enantioselective Intramolecular Cyclization of Alkynyl Esters Catalyzed by Chiral Brønsted Base
" Kondoh, A.; Tran, H. T. Q.; Kimura, K.; *Terada, M. Chem. Commun. 2016, 52 (33), pp.5726-5729. DOI:10.1039/C6CC01690A |
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"Construction of Vicinal Quaternary Stereogenic Centers by Enantioselective Direct Mannich-Type Reaction Using a Chiral Bis(guanidino)iminophosphorane Catalyst
" Takeda, T.; Kondoh, A.; *Terada, M. Angew. Chem. Int. Ed. 2016, 55 (15), pp.4734-4737. DOI:10.1002/anie.201601352 |
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"Study of Stereocontrolling Elements in Chiral Phosphoric Acid Catalyzed Addition Reaction of Vinylindoles with Azlactones
" Kanomata, K.; *Terada, M. Synlett 2016, 27 (4), pp.581-585. DOI:10.1055/s-0035-1561677 |
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"Perfluorinated Aryls in the Design of Chiral Brønsted Acid Catalysts: Catalysis of Enantioselective [4+2] Cycloadditions and Ene–Reactions of Imines with Alkenes by Chiral Mono-Phosphoric Acids with Perfluoroaryls
" Momiyama, N.;* Okamoto, H.; Kikuchi, J.; Korenaga, T.; *Terada, M.
ACS Catal. 2016, 6 (2), pp.1198-1204. DOI:10.1021/acscatal.5b02136 |
是永敏伸 | |
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"Hydrogen Bonds-Enabled Design of a C1-Symmetric Chiral Brønsted Acid Catalyst
" Momiyama, N.;* Funayama, K.; Noda, H.; Yamanaka, M.; Akasaka, N.; Ishida, S.; Iwamoto, T.; *Terada, M. ACS Catal. 2016, 6 (2), pp.949-956. DOI:10.1021/acscatal.5b02079 |
山中正浩 | |
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"Enantioselective Aza Michael-Type Addition to Alkenyl Benzimidazoles Catalyzed by Chiral Phosphoric Acid
" Wang, Y.-Y.; Kanomata, K.; Korenaga, T.; *Terada, M. Angew. Chem. Int. Ed. 2016, 55 (3), pp.927-931. DOI:10.1002/anie.201508231 |
是永敏伸 | |
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"Chiral Brønsted acid-catalyzed enantioselective Friedel–Crafts reaction of 2-methoxyfuran with aliphatic ketimines generated in situ
" Kondoh, A.; Ota, Y.; T. Komuro.; Egawa, F.; Kanomata, K.; *Terada, M. Chem. Sci. 2016, 7 (2), pp.1057-1062. DOI:10.1039/c5sc03175c |
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"Enantioselective Addition of a 2-Alkoxycarbonyl-1,3-dithiane to Imines Catalyzed by a Bis(guanidino)iminophosphorane Organosuperbase
" Kondoh, A.; Oishi, M.; Takeda, T.; *Terada, M. Angew. Chem. Int. Ed. 2015, 54 (52), pp.15836-15839. DOI:10.1002/anie.201508178 Highlighted at the front cover |
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"Design of a Brønsted Acid with Two Different Acidic Sites: Synthesis and Application of Aryl Phosphinic Acid-Phosphoric Acid as a Brønsted Acid Catalyst
" Momiyama, N.;* Narumi, T.; *Terada, M. Chem. Commun. 2015, 51 (95), pp.16976-16979. DOI:10.1039/C5CC06787A |
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"Ring Expansion of Epoxides under Brønsted Base Catalysis: Formal [3+2] Cycloaddition of β,γ-Epoxy Esters with Imines Providing 2,4,5-Trisubstituted 1,3-Oxazolidines
" Kondoh, A.; Odaira, K.; *Terada, M. Angew. Chem. Int. Ed. 2015, 54 (38), pp.11240-11244. DOI:10.1002/anie.201505893 |
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"Synthesis of Phenanthrene Derivatives by Intramolecular Cyclization Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Brønsted Base" Kondoh, A.; Aoki, T.; *Terada, M. Chem. Eur. J. 2015, 21 (36), pp.12577-12580. DOI:10.1002/chem.201501377 |
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"Synthetic Method for 2,2'-Disubstituted Fluorinated Binaphthyl Derivatives and Application as Chiral Source in Design of Chiral Mono-Phosphoric Acid Catalyst
" *Momiyama, N.; Okamoto, H.; Shimizu, M.; *Terada, M. Chirality 2015, 27 (8), pp.464-475. DOI:10.1002/chir.22429 |
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"Skeletal Rearrangement of O-Propargylic Formaldoximes by a Gold-Catalyzed Cyclization/Intermolecular Methylene Transfer Sequence " *Nakamura, I.; Gima, S.; Kudo, Y.; Terada, M. Angew. Chem. Int. Ed. 2015, 54 (24), pp. 7154-7157. DOI:10.1002/anie.201501856 |
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"Brønsted Base-catalyzed α-Oxygenation of Carbonyl Compounds Utilizing the [1,2]-Phospha-Brook Rearrangement " Kondoh, A.; *Terada, M. Org. Chem. Front. 2015, 2 (7), pp.801-805. DOI:10.1039/C5QO00108K |
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"Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by a Chiral Brønsted Acid " Yamanaka, T.; Kondoh, A.; *Terada, M. J. Am. Chem. Soc. 2015, 137 (3), pp.1048-1051. DOI:10.1021/ja512238n |
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"Synthesis of Intermediary P3 Phosphazenium Framework and Its Derivatization to Chiral Cationic Macrocycles Including Two P3 Phosphazenium Units with Hydrogen Bond Donor Sites" *Terada, M.; Goto, K.; Ikehara, T.; Kondoh, A. Heterocycles 2015, 90 (2), pp.1396-1404. DOI:10.3987/COM-14-S(K)98 |
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"Copper-Catalyzed Cascade Transformation of O-Propargylic Oximes with Sulfonyl Azides to α,β-Unsaturated N-Acylamidines" Zhang, D.; *Nakamura, I.; Terada, M. Org. Lett. 2014, 16 (19), pp.5184-5187. DOI:10.1021/ol502541w. |
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"Efficient Synthesis of N-Alkylated α,β-Unsaturated Ketonitrones via Cu-Catalyzed Rearrangement " *Nakamura, I.; Onuma, T.; Kanazawa, R.; Nishigai, Y.; Terada, M. Org. Lett. 2014, 16 (16 ), pp.4198-4200. DOI:10.1021/ol501889g |
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"Efficient synthesis of eight-membered nitrogen heterocycles from O-propargylic oximes by rhodium-catalyzed cascade reactions " *Nakamura, I.; Sato, Y.; Takeda, K.; Terada, M. Chem. Eur. J. 2014, 20 (33), pp.10214-10219. DOI:10.1002/chem.201403637 |
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"N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates " *Nakamura, I.; Jo, T.; Zhang, D.; Terada, M. Org. Chem. Front. 2014, 1 (8 ), pp.914-918. DOI:10.1039/C4QO00156G |
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"Intramolecular Cyclization of Alkynyl α-Ketoanilide Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Phosphazene Base " Kondoh, A.; Aoki, T.; *Terada, M. Org. Lett. 2014, 16 (13 ), pp.3528-3531. DOI:10.1021/ol501479t |
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"Synthesis of Bulky Aryl Group-Substituted Chiral Bis(guanidino)iminophosphoranes as Uncharged Chiral Organosuperbase Catalysts" Takeda, T.; *Terada, M. Aust. J. Chem. 2014, 67 (7 ), pp.1124-1128. DOI:10.1071/CH14195 |
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"Secondary Stereocontrolling Interactions in Chiral Brønsted Acid Catalysis: Study of a Petasis-Ferrier-Type Rearrangement Catalyzed by Chiral Phosphoric Acids" Kanomata, K.; Toda, Y.; Shibata, Y.; Yamanaka, M.; Tsuzuki, S.; Gridnev, I. D.; *Terada, M. Chem. Sci. 2014, 5 (9 ), pp.3515-3523.. DOI:10.1039/C4SC00611A |
山中正浩・都築誠二 | |
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"Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid" *Terada, M.; Komuro, T.; Toda, Y.; Korenaga, T. J. Am. Chem. Soc. 2014, 136 (19), pp.7044-7057. DOI:10.1021/ja5017206 |
是永敏伸 | |
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"Synthesis of 1,6-Dihydropyrimidines via Copper-catalyzed Multistep Cascade Reactions between O-Propargylic Aldoximes and Isocyanates" *Nakamura, I.; Onuma, T.; Zhang, D.; Terada, M. Tetrahedron Lett. 2014, 55 (6), pp.1178-1182. DOI:10.1016/j.tetlet.2013.12.105 |
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"Cu-Catalyzed Skeletal Rearrangement of O-Propargylic Electron-Rich Arylaldoximes into Amidodienes" *Nakamura, I.; Ishida, Y.; Terada, M. Org. Lett. 2014, 16 (9), pp.2562-2565. DOI:10.1021/ol5009608 |
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"Binaphthol-Derived Phosphoric Acid as an Efficient Chiral Organocatalyst for the Enantiomer-Selective Polymerization of rac-Lactide" Makiguchi, K.; Yamanaka, T.; Kakuchi, T.; *Terada, M.; *Satoh, T. Chem. Commun. 2014, 50 (22), pp.2883-2885. DOI:10.1039/C4CC00215F |
佐藤敏文 | |
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"Chiral Silver Phosphate Catalyzed Transformation of ortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence" *Terada, M.; Li, F.; Toda, Y. Angew. Chem. Int. Ed. 2014, 53 (1), pp.235-239. DOI:10.1002/anie.201307371 |
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"Design and Synthesis of Helically Chiral Spirocyclic P3 Phosphazenes and Characterization of Their Onium Salts" Terada, M.; Goto, K.; Oishi, M.; Takeda, T.; Kwon, E.; Kondoh, A. Synlett 2013, 24 (19), pp.2531-2534. DOI:10.1055/s-0033-1340058 |
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"Development of a Chiral Bis(guanidino)iminophosphorane as an Uncharged Organosuperbase for the Enantioselective Amination of Ketones" Takeda, T.; *Terada, M. J. Am. Chem. Soc. 2013, 135 (41), pp.15306-15309. DOI:10.1021/ja408296h |
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"Phosphazene-Catalyzed Intramolecular Cyclization of Nitrogen-Tethered Alkynyl Esters" Kondoh, A.; Ando, K.; *Terada, M. Chem. Commun. 2013, 49 (87), pp.10254-10256. DOI:10.1039/C3CC46100A |
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"Brønsted Base Catalyzed [2,3]-Wittig/Phospha-Brook Tandem Rearrangement Sequence" Kondoh, A.; *Terada, M. Org. Lett. 2013, 15 (17), pp.4568-4571. DOI:10.1021/ol402144q |
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"Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" *Terada, M.; Yamanaka, T.; Toda, Y. Chem. Eur. J. 2013, 19 (41), pp.13658-13662. DOI:10.1002/chem.201302486 |
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"Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reaction between O-Propargylic Oximes and Dipolarophiles " *Nakamura, I.; Kudo, Y.; Terada, M. Angew. Chem. Int. Ed. 2013, 52 (19), pp.7536-7539. DOI:10.1002/anie.201302751 |
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"Relay Catalysis by a Ruthenium Complex/Chiral Brønsted Acid Binary System for Ternary Reaction Sequence Involving Enantioselective Pictet−Spengler-Type Cyclization as the Key Step" Toda, Y.; *Terada, M. Synlett 2013, 24 (6), pp.752-756. DOI:10.1055/s-0032-1318302 |
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"Synthesis of Azepine Derivatives by Rhodium-Catalyzed Tandem 2,3-Rearrangement/Heterocyclization" *Nakamura, I.; Okamoto, M.; Sato, Y.; Terada, M. Angew. Chem. Int. Ed. 2012, 51 (43), pp.10816-10819. DOI:10.1002/ange.201207154 |
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"Copper-catalyzed skeletal rearrangement of O-propargylic aryloximes into four-membered cyclic nitrones - chirality transfer and mechanistic insight" *Nakamura, I.; Kudo, Y.; Araki, T.; Zhang, D.; Kwon, E.; Terada, M. Synthesis 2012, 44 (10), pp.1542-1550. DOI:10.1055/s-0031-1290819 |
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"Guanidine/Azole Binary System as an Efficient Catalyst for Morita-Baylis-Hillman Reaction" *Terada, M.; Fukuchi, S.; Amagai, K.; Nakano, M.; Ube, H. ChemCatChem. 2012, 4 (7), pp.963-967. DOI:10.1002/cctc.201200149 |
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"Synthesis of Unsymmetrically Substituted 2,2’-Dihydroxy-1,1’-biaryl Derivatives Using Organic-Base-Catalyzed Ferrier-Type Rearrangement as the Key Step" *Terada, M.; Dan, K. Chem. Commun. 2012, 48 (46), pp.5781-5783. DOI:10.1039/C2CC31594G |
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"Relay Catalysis via a Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" *Terada, M.; Toda, Y. Angew. Chem. Int. Ed. 2012, 51 (9), pp.2093-2097. DOI:10.1002/anie.201107805 |
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"Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Alkylaldoximes via N-O Bond Cleavage" *Nakamura, I.; Iwata, T.; Zhang, D.; Terada, M. Org. Lett. 2012, 14 (1), pp.206-209. DOI:10.1021/ol203001w |
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"Chiral Brønsted Acid-Catalyzed Stereoselective Addition of Azlactones to 3-Vinylindoles for Facile Access to Enantioenriched Tryptophan Derivatives " *Terada, M.; Moriya, K.; Kanomata, K.; Sorimachi, K. Angew. Chem. Int. Ed. 2011, 50 (52), pp.12586-12590. DOI:10.1002/anie.201105562 |
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"Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3’-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels-Alder Reaction of α,β-Unsaturated Aldehydes with Amidodienes" *Momiyama, N.; Konno, T.; Furiya, T.; Iwamoto, T.; *Terada, M. J. Am. Chem. Soc. 2011, 133 (48), pp.19294-19297. DOI:10.1021/ja2081444 |
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"Thermally-induced Skeletal Rearrangement of (Z)-O-Propargylic α,β-Unsaturated Aldoximes to Multisubstituted Pyridine Oxides" *Nakamura, I.; Zhang, D.; Terada, M. Tetrahedron Lett. 2011, 52 (48), pp.6470-6472. DOI:10.1016/j.tetlet.2011.09.107 |
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"Platinum-catalyzed Cycloisomerization of 1,4-Enynes via 1,2-Alkenyl Rearrangement" Sato, T.; Onuma, T.; *Nakamura, I.; Terada, M. Org. Lett. 2011, 13 (19), pp.4992-4995. DOI:10.1021/ol202104c |
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"Direct Enantioselective Amination of α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Amagai, K.; Ando, K.; Kwon, E.; Ube, H. Chem. Eur. J. 2011, 17 (33), pp.9037-9041. DOI:10.1002/chem.201101076 |
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"Regioselective Transformation of O-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement" *Nakamura, I.; Araki, T.; Zhang, D.; Kudo, Y.; Kwon, E.; Terada, M. Org. Lett. 2011, 13 (14), pp.3616-3619. DOI:10.1021/ol2012583 |
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"Chiral Brønsted Acid Catalysis for Enantioselective Hosomi-Sakurai Reaction of Imines with Allyltrimethylsilane" *Momiyama, N.; Nishimoto, H.; *Terada, M. Org. Lett. 2011, 13 (8), pp.2126-2129. DOI:10.1021/ol200595b |
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"Enantioselective Direct Vinylogous Michael Addition of Functionalized Furanones to Nitroalkenes Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Ando, K. Org. Lett. 2011, 13 (8), pp.2026-2029. DOI:10.1021/ol200415u |
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"Metal-Free Chiral Phosphoric Acid or Chiral Metal Phosphate as Active Catalyst in the Activation of N-Acyl Aldimines" *Terada, M.; Kanomata, K. Synlett 2011, (9), pp.1255-1258. DOI:10.1055/s-0030-1260545 |
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"Highly Stereoselective [4+2] Cycloaddition of Azlactones to β,γ-Unsaturated α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base" *Terada, M.; Nii, H. Chem. Eur. J. 2011, 17 (6), pp.1760-1763. DOI:10.1002/chem.201003015 |
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| Books |
「CSJカレントレビュー第13号：キラリティ（キラル化学）―その起源から最新のキラル材料研究まで」 高田十志和, 門出健次, 八島栄次 "第10章 キラル触媒最前線2（有機触媒～キラル触媒の新たな潮流～）" *寺田眞浩 化学同人 (京都) 2013, pp119-125. |
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「Asymmetric Synthesis II」 M. Christmann, S. Braese "Asymmetric C-C bond formation using chiral guanidine catalysts" 2013, pp273-278. |
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「Science of Synthesis, Asymmetric Organocatalysis 2, Brønsted Base and Acid Catalysts, and Additional Topics」 K. Maruoka "Phosphoric Acid Catalysis of Reactions not Involving Imines" M. Terada, N. Momiyama Georg Thieme Verlag KG (New York) 2012, pp219-278. |
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「Science of Synthesis, Stereoselective Synthesis 3 」 P. A. Evans "Ene Reactions" Terada、M. Thieme (New York) 2011, pp309-346. |
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「触媒調整ハンドブック」 岩本正和 "第４編 均一系触媒 有機触媒" 寺田眞浩 エヌ・ティー・エス (東京) 2011, pp397-409. ISBN:978-4-86043-377-2 |
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| Reviews / Accounts |
"Copper-Catalyzed Skeletal Rearrangements of O-Propargylic Oximes via Cleavage of a Carbon-Oxygen Bond" *Nakamura, I.; Terada, M. Chem. Record. 2015, 15 (2 ), pp.429-444. DOI:10.1002/tcr.201402088 |
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"キラルブレンステッド酸触媒並びに塩基触媒の設計開発" *寺田眞浩 化学と工業 2014, 67 (6), pp.474-476. |
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"有機分子触媒の躍進" *寺田眞浩 ファインケミカル 2014, 43 (6), pp.5-6. |
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"「モノづくり」に思うこと" *寺田眞浩 有機合成化学協会誌 2014, 72 (2), pp.117-117. DOI:10.5059/yukigoseikyokaishi.72.117 |
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"Heterocyclic Synthesis by π-Acidic Metal Catalyzed Reactions via N-O Bond Cleavage" *Nakamura, I.; Terada, M. Heterocycles 2014, 89 (4), pp.845-868. DOI:10.3987/REV-13-791 |
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"キラルBrønsted酸を用いた不斉触媒反応" 寺田眞浩 有機合成化学協会誌 2013, 71 (5), pp.480-490. DOI:10.5059/yukigoseikyokaishi.71.480 |
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"最新のトピックス：触媒の”ハイブリッド”―金属触媒と有機触媒の組み合わせによる触媒反応" 近藤梓, 寺田眞浩 化学 2012, 67 (6), pp.66-67. |
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"Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acid Catalysts" *Terada, M. Curr. Org. Chem. 2011, 15 (13), pp.2227-2256. |
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| Conference / Symposium / Lecture |
招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen (Germany) 2016-03-22～2016-03-22 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of Westfälishe Wilhelms-Universität Münster, Münster (Germany) 2016-03-21～2016-03-21 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of RWTH Aachen University, Aachen (Germany) 2016-03-18～2016-03-18 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Max‐Planck‐Institut für Kohlenforschung, Mulheim an der Ruhr (Germany) 2016-03-17～2016-03-17 |
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招待講演 "New Aspects of Enantioselective Catalysis by Chiral Phosphoric Acid" 〇*Terada, M. 5th UK-Japanese Symposium on Asymmetric Catalysis, Manchester (UK) 2016-03-14～2016-03-15 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of Université de Genève, Genève (Switzerland) 2016-03-11～2016-03-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases
" 〇*Terada, M. Department Seminal of École Polytechnique Fédérale de Lausanne, Lausanne (Switzerland) 2016-03-10～2016-03-10 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Department Seminal of ETH Zurich, Zurich (Switzerland) 2016-03-09～2016-03-09 |
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招待講演 "Enantioselective Transformation of Cationic Intermediates Mediated by Chiral Phosphoric Acid Catalyst
" 〇*Terada, M. Pacifichem 2015 (#122 Recent Trends in Organocatalysis), Honolulu (USA ) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Enantio-convergent Nucleophilic Substitution Reaction of Racemic Alkyne-Cobalt Complex Catalyzed by Chiral Brønsted Acid: Asymmetric Synthesis of Enantio-enriched Thioethers
" 〇*Terada, M.; Ota, Y.; Li, F.; Toda, Y.; Kondoh, A. IKCOC-13, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M.; Yamanaka, T.; Kondoh, A. The 10th International Conference on Cutting-Edge Organic Chemistry in Asia, Kaohsiung (Taiwan) 2015-11-02～2015-11-06 |
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招待講演 "New Aspect of Organosuperbase Catalyst" 〇*Terada, M. Perspectives on Synthetic Organic Chemistry , Singapore (Singapore) 2015-09-30～2015-09-30 |
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招待講演 "Chiral Brønsted Acid-Catalyzed Transformations for Multistep Sequence " 〇*Terada, M. First Symposium DOMINOCAT @RWTH Aachen, Institute of Organic Chemistry, Aachen (Germany) 2015-09-09～2015-09-11 |
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招待講演 "Development of Chiral Bis(guanidino)iminophosphorane as Uncharged Organosuperbase Catalyst for Enantioselective Transformations" 〇*Terada, M. IUPAC World Chemistry Congress 2015 Molecular Synthesis Symposia, Busan (Korea) 2015-08-09～2015-08-14 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. Golden Jubilee Chemistry Conference, Singapore (Singapore) 2015-08-06～2015-08-08 |
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招待講演 "Enantioselective Transformation of Cationic Intermediates Mediated by Chiral Phosphoric Acid Catalyst" 〇*Terada, M. The 39th Naito Conference “The Chemistry of Organocatalyst”, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. 2nd Organic Chemistry Frontiers International Symposium, Hangzhou (China) 2015-04-21～2015-04-21 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Michigan State University, Michigan (USA) 2014-12-12～2014-12-12 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of University of Michigan, Michigan (USA) 2014-12-11～2014-12-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Rutgers University, The State University of New Jersey, New Jersey (USA) 2014-12-09～2014-12-09 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Columbia University, New York (USA) 2014-12-08～2014-12-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Vanderbilt University, Tennessee (USA) 2014-12-15～2014-12-15 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Colorado State University, Colorado (USA) 2014-12-04～2014-12-04 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of University of California-Berkeley, California (USA) 2014-12-01～2014-12-01 |
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招待講演 "Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by Chiral Brønsted Acid" 〇*Terada, M. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Toyko (Japan) 2014-11-21～2014-11-21 |
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招待講演 "Development of Chiral Bis(guanidino)iminophosphoranes as Uncharged Organosuperbase Catalysts for Enantioselective Transformations" 〇*Terada, M. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-29 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Taiwan Normal University (國立台湾師大), Taipei (Taiwan) 2014-10-17～2014-10-17 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of Institute of Chemistry, Academia Sinica, Taipei (Taiwan) 2014-10-16～2014-10-16 |
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受賞講演 "Lectureship Award:Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Tsing Hua University (國立精華大), HsinChu, (Taiwan) 2014-10-15～2014-10-15 |
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受賞講演 "Lectureship Award:Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" 〇*Terada, M. Departmental Seminar of National Chung Cheng University (國立中正大學), ChiaYi (Taiwan) 2014-10-14～2014-10-14 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Chiral Brønsted Bases" 〇*Terada, M. Molecular Complexity in Modern Chemistry” MCMC2014, Moscow (Russia ) 2014-09-13～2014-09-19 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite de Rouen, Rouen (France ) 2014-09-12～2014-09-12 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite Pierre et Marie Curie-Paris 6 (UPMC), Paris (France) 2014-09-11～2014-09-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" 〇*Terada, M. Departmental Seminar of Universite Paris Sud, Orsay (France) 2014-09-10～2014-09-10 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Dalian University of Technology, Dalian (China) 2014-04-11～2014-04-11 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Dalian Institute of Chemical Physics CAS, Dalian (China) 2014-04-09～2014-04-09 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Zhejiang University, Hangzhou (China) 2014-04-08～2014-04-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Zhejiang University of Technology, Hangzhou (China) 2014-04-08～2014-04-08 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Nanjing University, Nanjing (China) 2014-04-04～2014-04-04 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Shanghai Jiao Tong University, Shanghai (China) 2014-04-03～2014-04-03 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Chiral Brønsted Bases" ○*Terada, M. 1st Organic Chemistry Frontiers Symposium, Shanghai (China) 2014-04-03～2014-04-03 |
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招待講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of East China Normal University, Shanghai (China) 2014-04-01～2014-04-01 |
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受賞講演 "Lectureship Award: Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of National University of Singapore, Singapore (Singapore) 2014-03-14～2014-03-14 |
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受賞講演 "Lectureship Award: Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Departmental Seminar of Nanyang Technological University, Singapore (Singapore) 2014-03-13～2014-03-13 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. C&FC (Catalysis & Fine Chemicals) 2013, Beijing (China) 2013-12-01～2013-12-05 |
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口頭発表／ポスター発表 "Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation" ○*Terada, M. ICCEOCA-8 and NICCEOCA-4, Osaka (Japan) 2013-11-25～2013-11-28 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Kwangwon National University, Chun Cheon (Korea) 2013-10-31～2013-10-31 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Seoul National University, Seoul (Korea) 2013-10-30～2013-10-30 |
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受賞講演 "Lectureship Award: Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar of Sungkyunkwan University, Suwon (Korea) 2013-10-29～2013-10-29 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. Beijing Symposium 2013 on “New Frontiers in Organic Chemistry: New Reagents, New Reactions”, Beijing (China) 2013-10-09～2013-10-12 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. 25th ISCD (International Symposium on Chirality), Shanghai (China) 2013-07-07～2013-07-10 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. 5th Gratama Workshop, Tokyo (Japan) 2013-05-29～2013-06-01 |
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招待講演 "Chiral Anion Catalysis in Enantioselective Transformation of Carbocation Intermediates" ○*Terada, M. Advanced Molecular Transformations by Organocatalysts, First International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. The 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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招待講演 "Chiral Anion Catalysis in Enantioselective Transformation of Carbocation Intermediates" ○*Terada, M. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-08-19～2013-08-20 |
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招待講演 "Chiral Anion Catalysis in Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" ○*Terada, M. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate" ○*Terada, M., T. Yamanaka, Y. Toda ICCEOCA-7, Singapore (Singapore) 2012-12-11～2012-12-15 |
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口頭発表／ポスター発表 "Relay Catalysis via Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" ○*Terada, M., Y. Toda IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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受賞講演 "Enantioselective Catalysis by Chiral Brønsted Acids and Bases" ○*Terada, M. Nagoya Medal of Organic Chemistry 2012, Nagoya (Japan) 2012-11-08～2012-11-08 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. Molecular Chirality ASIA2012, Fukuoka (Japan) 2012-03-17～2012-03-18 |
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招待講演 "Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acids" ○*Terada, M. 4th Novel Chiral Chemistries Japan 2012, Tokyo (Japan) 2012-03-15～2012-03-16 |
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招待講演 "Enantioselective Transformations via Activation of Electron-Rich Double Bonds Using Chiral Phosphoric Acids" ○*Terada, M. International Symposium of Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Shanghai Institute of Materia Medica, Shanghai (China) 2011-11-30～2011-11-30 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at East China Normal University, Shanghai (China) 2011-11-30～2011-11-30 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Shanghai Institute of Organic Chemistry, Shanghai (China) 2011-11-29～2011-11-29 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Science & Technology of China, Hefei (China) 2011-11-28～2012-11-28 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Sichuan University, Chengdu (China) 2011-11-25～2011-11-25 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of South Florida, Tampa (USA) 2011-11-14～2011-11-14 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations, M. Terada, , Nov. 9 (2011), , （招待講演）" ○*Terada, M. Departmental Seminar at University of Miami, Miami (USA) 2011-11-09～2011-11-09 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Vanderbilt University, Nashville (USA) 2011-11-08～2011-11-08 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Texas at Austin, Austin (USA) 2011-11-07～2011-11-07 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of New Mexico, Albuquerque (USA) 2011-11-04～2011-11-04 |
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招待講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at California Institute of Technology, Los Angeles (USA) 2011-11-03～2012-11-03 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong University, Hong Kong (China) 2011-10-21～2011-10-21 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Peking University, Shenzhen Graduate School, Shenzhen (China) 2011-10-19～2011-10-19 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong Baptist University, Hong Kong (China) 2011-10-18～2011-10-18 |
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受賞講演 "Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at Hong Kong University of Science & Technology, Hong Kong (China) 2011-10-17～2011-10-17 |
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招待講演 "Enantioselective Transformations via Activation of Electron-Rich Double Bonds Using Chiral Phosphoric Acids" ○*Terada, M. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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招待講演 "Chiral Phosphoric Acids as a Versatile Catalyst for Enantioselective Transformations" ○*Terada, M. Departmental Seminar at University of Cambridge, Cambridge (UK) 2011-04-19～2011-04-19 |
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招待講演 "Binaphthol-derived Phosphoric Acid as a Versatile Catalyst for Enantioselective Carbon-Carbon Bond Forming Reactions" ○*Terada, M. 3rd UK-Japan Symposium on Catalytic Asymmetric Synthesis, Oxfordく反対 (UK日本) 2011-04-15～2011-04-16 |
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| Patent |
"ビス－リン酸化合物及びそれを用いる不斉合成" 発明者：寺田眞浩、椴山儀恵、今野徹 出願者：国立大学法人東北大学、株式会社エーピーアイ コーポレーション共同出願 WO2011JP55296 20110308 2011-03-08, WO2011111677 (A1) 2011-09-15, (国外) |
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| Prize |
"Molecular Chirality Award 2015" *Terada, M. 2015-06 Molecular Chirality Research Organization Development of Chiral Organocatalysts and Its application to Catalytic Asymmetric Synthesis |
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"Asian Core Program Lectureship Award (Thailand)" *Terada, M. 2013-11 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation |
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"Asian Core Program Lectureship Award (Taiwan)" *Terada, M. 2013-11 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Development of Chiral Bis(guanidino)iminophosphorane as a Superb Class of Uncharged Organosuperbase for Catalytic Enantioselective Transformation |
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"Asian Core Program Lectureship Award (Singapore)" *Terada, M. 2012-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate |
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"Asian Core Program Lectureship Award (Korea)" *Terada, M. 2012-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of 1-Benzopyrylium Ion as a Reactive Intermediate |
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"Nagoya Silver Medal" 寺田眞浩 2012-11 万有生命科学振興国際交流財団 水素結合を戦略的相互作用とする有機分子触媒の創製 |
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"第一三共・創薬有機化学賞
" 寺田眞浩 2012-02 有機合成化学協会 水素結合を戦略的相互作用とする有機分子触媒の創製 |
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| Media |
"Angew. Chem. Int. Ed. 誌に掲載された「Enantioselective Addition of a 2-Alkoxycarbonyl-1,3-dithiane to Imines Catalyzed by a Bis(guanidino)iminophosphorane Organosuperbase」がFront Cover Pictureに採用された。" Kondoh, A.; Oishi, M.; Takeda, T.; Terada, M. Angew. Chem. Int. Ed. 2015-12-21 PDF |
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"ChemCatChem. 2012, 4, 963-967に掲載された「Guanidine/Azole Binary System as an Efficient Catalyst for Morita-Baylis-Hillman Reaction」が「A Binary Coupling」としてChemistry Viewsに紹介された。" M. Terada, S. Fukuchi, K. Amagai, M. Nakano, H. Ube Chemistry Views 2013-06-18 |
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"Relay Catalysis via a Rhodium Complex/Chiral Brønsted Acid Binary System Involving Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate" M. Terada, Y. Toda Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 538 2012-04-18 |
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"Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3’-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels-Alder Reaction of ,-Unsaturated Aldehydes with Amidodienes" N. Momiyama, T. Konno, T. Furiya, T. Iwamoto, M. Terada Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 209 2012-01-19 |
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"Chiral Brønsted Acid Catalyzed Stereoselective Addition of Azlactones to 3-Vinylindoles for Facile Access to Enantioenriched Tryptophan Derivatives" M. Terada, K. Moriya, K. Kanomata, K. Sorimachi Synfact ‘Highlights in Current Synthetic Organic Chemistry’2012, 99 2011-12-19 |
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"Enantioselective Direct Vinylogous Michael Addition of
Functionalized Furanones to Nitroalkenes Catalyzed by an Axially Chiral
Guanidine Base" M. Terada, K. Ando Synfact ‘Highlights in Current Synthetic Organic Chemistry’2011, 680 2011-05-19 |
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"Highly Stereoselective [4+2] Cycloaddition of Azlactones to ,-Unsaturated -Ketoesters Catalyzed by an Axially Chiral Guanidine Base" M. Terada, H. Nii Synfact ‘Highlights in Current Synthetic Organic Chemistry’2011, 330 2011-02-16 |
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| A01 吉田 雅紀 | ||
| Original papers |
"Organocatalytic asymmetric Michael addition of α-branched aldehydes to vinyl ketones: synthesis of 5-ketoaldehydes possessing a stereo-controlled all-carbon quaternary stereogenic center" *Yoshida, M.; Ukigai, H.; Shibatomi, K.; Hara, S. Tetrahedron Lett. 2015, DOI:10.1016/j.tetlet.2015.04.107 |
柴富一孝 |
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"第一級アミノ酸およびその塩を用いた触媒的不斉合成" *吉田雅紀 有機合成化学協会誌 2014, 72 (8), pp.876-889. DOI:10.5059/yukigoseikyokaishi.72.876 |
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"Asymmetric Michael Addition of β-Ketoesters to Enones Catalyzed by a Primary β-Amino Acid Lithium Salt" *Yoshida, M.; Kubara, A.; Nagasawa, Y.; Hara, S.; Yamanaka, M. Asian J. Org. Chem. 2014, 3 pp.523-529. DOI:10.1002/ajoc.201400024 |
山中正浩 | |
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"Asymmetric α-Allylation of α-Branched Aldehydes with Allyl Alcohols by Synergistic Catalysis Using an Achiral Pd Complex and a Chiral Primary Amino Acid" *Yoshida, M.; Masaki, E.; Terumine, T.; Hara, S. Synthesis 2014, 46 pp.1367-1373. DOI:10.1055/s-0033-1340901 |
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"Direct Asymmetric α-Allylation of α-Branched Aldehydes by Two Catalytic Systems with an Achiral Pd Complex and a Chiral Primary α-Amino Acid" *Yoshida, M.; Terumine, T.; Masaki, E.; Hara, S. J. Org. Chem. 2013, 78 (21), pp.10853-10859. DOI:10.1021/jo4018414 |
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"Mechanistic study of asymmetric Michael addition of malonates to enones catalyzed by a primary amino acid lithium salt" *Yoshida, M.; Nagasawa, Y.; Kubara, A.; Hara, S.; *Yamanaka, M. Tetrahedron 2013, 69 (47), pp.10003-10008. DOI:10.1016/j.tet.2013.09.066 |
山中正浩（立教大学） | |
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"Primary β-Amino Acid Salt-catalyzed Asymmetric Michael Addition of Benzoylacetates to Cyclic Enones and Its Application for the Synthesis of Enantioenriched 1,5-Diketones" *Yoshida, M.; Kubara, A.; Hara, S. Chem. Lett. 2013, 42 (2), pp.180-182. DOI:10.1246/cl.2013.180 |
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"Enantioselective synthesis of gabapentin analogues via organocatalyticasymmetric Michael addition of α-branched aldehydes to β-nitroacrylates" *Yoshida, M.; Masaki, E.; Ikehara, H.; Hara, S. Org. Biomol. Chem. 2012, 10 (27), pp.5289-5298. DOI:10.1039/c2ob25413a |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Mechanistic Study of Primary β-Amino Acid Salt-Catalyzed Asymmetric Michael Addition to Enones" ○*Yoshida, M.; Kubara, A.; Hara, S. 文部科学省科学研究費補助金「新学術領域研究（研究領域提案型）」（平成23～27年度）「有機分子触媒による未来型分子変換」第1回 国際会議（兼）第6回 有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Stereoselective Construction of a Quaternary Carbon Center by a Primary Amino Acid-Catalyzed Asymmetric α-Allylation of Aldehydes" ○*Yoshida, M.; Terumine, T.; Hara, S. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 仙台 (日本) 2013-04-19～2013-04-20 |
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招待講演 "Organocatalytic Tandem Reaction for the Asymmetric Synthesis of γ-Nitroaldehydes" ○*Yoshida, M.; Kitamikado, N.; Ikehara, H.; Hara, S. Cambodian Malaysian Chemical Conference (CMCC) 2012, Siem Reap (Cambodia) 2012-10-19～2012-10-21 |
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招待講演 "Enantioselective Synthesis of 4,4-Disubstituted Pyrrolidine-3-carboxylic Acids via Organocatalytic Michael Addition of α-Branched Aldehydes to β-Nitroacrylates" ○*Yoshida, M.; Masaki, E.; Ikehara, H.; Hara, S. 17th Malaysian Chemical Congress (17MCC), Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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| Prize |
"日本化学会北海道支部奨励賞" *吉田雅紀 2013-01 日本化学会北海道支部 第一級アミノ酸およびその塩を利用する不斉有機触媒反応の開発 |
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| A01 小笠原 正道 | ||
| Original papers |
"Concise Asymmetric Construction of C2-Symmetric 1,9-Diarylnonanoids Using Hypervalent Silicon Complex: Total Synthesis of (–)-Ericanone" *Kotani, S.; Kai, K.; Shimoda, Y.; Hu, H.; Gao, S.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Chem. Asian J. 2016, 11 pp.376-379. DOI:10.1002/asia.201501080 |
中島誠教授（熊本大学） |
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"Kinetic Resolution of Planar-Chiral Ferrocenylphosphine Derivatives by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis and Their Application in Asymmetric Catalysis" *Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. ACS Catal. 2016, 6 pp.1308-1315. DOI:10.1021/acscatal.5b02692 |
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"Ring-Closing Metathesis of (η5-Alkenylcyclopentadienyl)(alkenylphosphine)manganese(I) Dicarbonyl Complexes" Tseng, Y.-Y.; *Kamikawa, K.; Wu, Q.; Takahashi, T.; *Ogasawara, M. Adv. Synth. Catal. 2015, 357 pp.2255-2264. DOI:10.1002/adsc.201500343 |
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"Enantioselective Synthesis of Macrocyclic Heterobiaryl Derivatives of Molecular Asymmetry by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" Okayama, Y.; Tsuji, S.; Toyomori, Y.; *Mori, A.; Arae, S.; Wu, W.-Y.; Takahashi, T.; *Ogasawara, M. Angew. Chem. Int. Ed. 2015, 54 pp.4927-4931. DOI:10.1002/anie.201500459 |
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"Simultaneous Induction of Axial and Planar Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis" *Kamikawa, K.; Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. Chem. Eur. J. 2015, 21 pp.4954-4957. DOI:10.1002/chem.201500226 |
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"Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library" *Ogasawara, M.; Wada, S.; Isshiki, E.; Kamimura, T.; *Yanagisawa, A.; *Takahashi, T.; *Yoshida, K. Org. Lett. 2015, 17 pp.2286-2289. DOI:10.1021/acs.orglett.5b01044 |
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"Enantioselective Desymmetrization of 1,2,3-Trisubstituted Metallocenes by Molybdenum-Catalyzed Asymmetric Intraannular Ring-Closing Metathesis" Arae, S.; Nakajima, K.; *Takahashi, T.; *Ogasawara, M. Organometallics 2015, 34 pp.1197-1202. DOI:10.1021/om5011484 |
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"Catalytic Asymmetric Synthesis of Planar-Chiral Transition-Metal Complexes" Arae, S.; *Ogasawara, M. Tetrahedron Lett. 2015, 56 pp.1751-1761. DOI:10.1016/j.tetlet.2015.01.130 |
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"Phosphine-Olefin Ligands Based on a Planar-Chiral (π-Arene)chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis" *Ogasawara, M.; Tseng, Y.-Y.; Arae, S.; Morita, T.; Nakaya, T.; Wu, W.-Y.; *Takahashi, T.; *Kamikawa, K. J. Am. Chem. Soc. 2014, 136 pp.9377-9384. DOI:10.1021/ja503060e |
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"Phosphine Oxide-Catalyzed Enantioselective Intramolecular Aldol Reaction via Regioselective Enolization of Unsymmetrical Diketones with Tetrachlorosilane" *Kotani, S.; Aoki, S.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Org. Lett. 2014, 16 pp.4802-4805. DOI:10.1021/ol502269w |
中島誠教授（熊本大学） | |
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"Hybrid Sponge Comprised of Galactosylated Chitosan and Hyaluronic Acid Mediates the Co-culture of Hepatocytes and Endothelial Cells" Shang, Y.; Tamai, M.; Ishii R.; Nagaoka, N.; Yoshida, Y.; Ogasawara, M.; Yang, J.; *Tagawa, Y. J. Biosci. Bioeng. 2014, 117 pp.99-106. DOI:10.1016/j.jbiosc.2013.06.015 |
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"Helically Chiral Diene in Asymmetric Catalysis: C2-Symmetric (Z,Z)-2,3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as Highly Active Lewis-Base Organocatalyst" *Ogasawara, M.; Kotani, S.; Nakajima, H.; Furusho, H.; Miyasaka, M.; Shimoda, Y.; Wu, W.-Y.; Sugiura, M.; *Takahashi, T.; *Nakajima, M. Angew. Chem. Int. Ed. 2013, 52 pp.13798-13802. DOI:10.1002/anie.201308112 |
中島誠教授（熊本大学） | |
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"Asymmetric Aldol Reaction on Water using an Organocatalyst Tethered on a Thermoresponsive Block Copolymer" *Suzuki, N.; Inoue, T.; Asada, T.; Akebi, R. Kobayashi, G.; Rikukawa, M.; Masuyama, Y.; Ogasawara, M.; Takahashi, T.; Thang, S. Chem. Lett. 2013, 42 pp.1493-1495. DOI:10.1246/cl.130711 |
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"Inter- versus Intraannular Ring-Closing Metathesis on Polyallylferrocenes: Five-Fold RCM within a Single Molecule" *Ogasawara, M.; Wu, W.-Y.; Arae, S.; Nakajima, K.; *Takahashi, T. Organometallics 2013, 32 pp.6593-6598. DOI:10.1021/om400936b |
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"Enantioselective Morita-Baylis-Hillman Reaction Catalyzed by a Chiral Phosphine Oxide" *Kotani, S.; Ito, M.; Nozaki, H.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Tetrahedron Lett. 2013, 54 pp.6430-6433. DOI:10.1016/j.tetlet.2013.09.067 |
中島誠教授（熊本大学） | |
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"Synthesis and Characterization of Benzo[b]phosphaferrocene Derivatives" *Ogasawara, M.; Arae, S.; Watanabe, S.; Subbarayan, V.; Sato, H.; *Takahashi, T. Organometallics 2013, 32 pp.4997-5000. DOI:10.1021/om400496b |
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"Kinetic Resolution of Planar-Chiral 1,2-Disubstituted Ferrocenes by Molybdenum-CatalyzedAsymmetric Intraannular Ring-Closing Metathesis" *Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. Chem. Eur. J. 2013, 19 pp.4151-4154. DOI:10.1002/chem.201300116 |
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"Kinetic Resolution of Planar-Chiral (eta6-Arene)chromium Complees by Molybdenum-CatalyzedAsymmetric Ring-Closing Metathesis" *Ogasawara, M.; Wu, W.-Y.; Arae, S.; Watanabe, S.; Morita, T.; *Takahashi, T.; *Kamikawa, K. Angew. Chem. Int. Ed. 2012, 51 pp.2951-2955. DOI:10.1002/anie.201108292 |
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"Effects of Silyl Substituents on the Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Their SE2' Chirality Transfer Reactions" *Ogasawara, M.; Ge, Y.; Okada, A.; *Takahashi, T. Eur. J. Org. Chem. 2012, pp.1656-1663. DOI:10.1002/ejoc.201101634 |
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"Preparation of C2-Symmetric Allenes by Palladium-Catalyzed Double Nucleophilic Substitution on 3-Bromopenta-2,4-dienyl Acetate" *Ogasawara, M.; Suzuki, M.; *Takahashi, T. J. Org. Chem. 2012, 77 pp.5406-5410. DOI:10.1021/jo300511e |
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| Reviews / Accounts |
"メタセシス反応による面不斉遷移金属錯体の触媒的不斉合成" *小笠原正道 ファインケミカル 2016, 45 pp.15-23. |
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"
面不斉遷移金属錯体の触媒的不斉合成
" 荒江祥永、*小笠原正道 J. Synth. Org. Chem. Jpn 2012, 70 pp.593-605. |
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| Conference / Symposium / Lecture |
招待講演 "Catalytic Asymmetric Synthesis of Planar-Chiral Zirconocene Derivatives and Their Application in Carbometallation Reactions" *Ogasawara, M. Pure and Applied Chemistry International Conference 2016 (PACCON 2016), Bangkok (Thailand) 2016-02-09～2016-02-11 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Zirconocenes and Application in Asymmetric Catalysis" *Ogasawara, M. International Science & Nature Congress (ISNaC2015), Kuala Lumpur (Malaysia) 2015-09-21～2015-09-23 |
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招待講演 "Design, Synthesis, and Application of Atropisomeric Chiral Dienes in Asymmetric Catalysis" *Ogasawara, M. The 8th Singapore International Chemical Conference, Singapore (Singapore) 2014-12-14～2014-12-17 |
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招待講演 "Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library" *Ogasawara, M. Vietnam Malaysia International Chemical Conference, Hanoi (Vietnam) 2014-11-07～2014-11-09 |
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招待講演 "Development of Enantioselective Transformations on (η6-Arene)chromium Templates by Molybdenum-Catalyzed Asymmetric Metathesis Reactions" *Ogasawara, M. The 18th Malaysian International Chemical Congress, Kuala Lumpur (Malaysia) 2014-11-03～2014-11-05 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes and Their Application in Organic Transformations" *Ogasawara, M. The 8th Asian European Symposium on Metal-Mediated Efficient Organic Synthesis, Cesme/Izmir (Turkey) 2014-09-07～2014-09-10 |
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招待講演 "Development of Catalytic Enantioselective Transformations Utilizing (η6-Arene)chromium Templates and Chiral Molybdenum-Alkylidene Catalysts" *Ogasawara, M. 41st International Conference on Coordination Chemistry, Singapore (Singapore) 2014-07-21～2014-07-25 |
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依頼講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Lecture at Dept. of Chemistry, The Univ. of Chicago, Chicago (USA) 2014-03-21～2014-03-21 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral (η6-Arene)chromium Complexes" ○*Ogasawara, M. The 247th ACS National Meeting, Dallas (USA) 2014-03-16～2014-03-20 |
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依頼講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Lecture at Dept. of Chemistry, Tsinghua Univ., Beijing (China) 2013-12-06～2013-12-06 |
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招待講演 "Atropisomeric Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of C2-Symmetric (Z,Z)-1,2-Bis[1-(diphenylphosphino)ethylidene]cycloalkane Derivatives" ○*Ogasawara, M. International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), Beijing (China) 2013-12-01～2013-12-05 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. Invited Lecture at Charles University in Prague, Prague (Czech Republic) 2013-11-04～2013-11-04 |
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基調講演 "Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Application to Synthesis of Allenic Natural Products" ○*Ogasawara, M. The 48th Advances in Organic, Bioorganic and Pharmaceutical Chemistry (Liblice 2013), Špindlerův Mlýn (Czech Republic) 2013-11-01～2013-11-03 |
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口頭発表／ポスター発表 " Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes by Asymmetric RCM " ○*Ogasawara, M.International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis" *Ogasawara, M.; ○Wu, W.-Y.; Nakaya, T.; Morita, T.; Arae, S.; Tseng, Y.-Y.; *Takahashi, T.; *Kamikawa, K. International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Catalytic Induction of Planar Chirality in Functional Metallocenes by Mo-Catalyzed Asymmetric Ring-Closing Metathesis" *Ogasawara, M.; ○Arae, S.; Watanabe, S.; Oana, A.; Nakajima, K.; *Takahashi, T. International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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口頭発表／ポスター発表 "Concomitant Catalytic Induction of Planar- and Axial-Chirality in [h6-(N-Indolyl)arene]chromium Complexes by Mo-Catalyzed Asymmetric Ring-Closing Metathesis" *Kamikawa, K.; ○Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. The 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2014-04-11 |
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口頭発表／ポスター発表 "Catalytic Enantioselective Synthesis of Planar-Chiral Metallocenylphosphines by Mo-Catalyzed Asymmetric Ring-Closing Metathesis and Their Application as Chiral Ligands" *Ogasawara, M.; ○Arae, S.; Watanabe, S.; Nakajima, K.; *Takahashi, T. 25th International Conference on Organometallic Chemistry, Lisbon (Portugal) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Kinetic Resolution of Planar-Chiral (π-Arene)chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" ○*Ogasawara, M.; Wu, W.-Y.; Arae, S.; Watanabe, S.; Morita, T.; *Takahashi, T.; *Kamikawa, K. 25th International Conference on Organometallic Chemistry, Lisbon (Portugal) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Helically Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of 1,4-Bis(phosphino)-1,3-butadiene Derivatives Having C2-C3-Fused Cyclic System
" ○*Ogasawara, M.; Nakajima, H.; Nakajima, K.; *Takahashi, T. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Synchronous Induction of Planar- and Axial-Chirality in [η6-(N-indolyl)arene]chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis" *Kamikawa, K.; ○Arae, S.; Wu, W.-Y.; Nakamura, C.; *Takahashi, T.; *Ogasawara, M. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Greg Fu’s Planar-Chiral Fc*-DMAPs" *Ogasawara, M.; ○Wada, S.; Isshiki, E.; *Yanagisawa, A.; *Takahashi, T.; *Yoshida, K. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Helically Chiral Dienes in Asymmetric Catalysis: Design, Synthesis, and Application of 1,4-Bis(phosphino)-1,3-butadiene Derivatives Having C2-C3-Fused Cyclic System" ○*Ogasawara, M. The 17th Malaysian Chemical Congress, Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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招待講演 "Design and Synthesis of Phosphine-Olefin Ligands Having Planar-Chiral (π-Arene)chromium Framework and Application in Asymmetric Catalysis" ○*Ogasawara, M. Cambodian Malaysian Chemical Conference, Siem Reap (Cambodia) 2012-10-19～2012-10-21 |
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招待講演 "Herically Chiral Dienes in Asymmetric Catalysis: C2-Symmetric (Z, Z)-1,2-Bis(1-diphenylphosphinylethylidene)cyclohexanes as Highly Acitve Lewis-Base Organocatalysts" ○*Ogasawara, M. The 1st Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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招待講演 "Pd-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Their Application in Organic Transformations
" ○*Ogasawara, M. Invited Lecture at National Taiwan University (the Chemistry Research Promotion Center, Taiwan), Taipei (Taiwan) 2012-12-28～2012-12-28 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes
" ○*Ogasawara, M. Invited Lecture at National Tsing Hua University (the Chemistry Research Promotion Center, Taiwan), Hsinchu (Taiwan) 2012-12-26～2012-12-26 |
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招待講演 " Pd-Catalyzed Asymmetric Synthesis of Axially Chiral Allenes and Their Application in Organic Transformations
" ○*Ogasawara, M. Invited Lecture at National Taiwan Normal University (the Chemistry Research Promotion Center, Taiwan), Taipei (Taiwan) 2012-12-24～2012-12-24 |
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招待講演 "Catalytic Asymmetric Synthesis of Planar-Chiral Ferrocenes and Their Applications in Optically Active Metallocene-Polymers" ○*Ogasawara, M. The 3rd Molecular Materials Meeting, Singapore (Singapore) 2013-01-14～2013-01-16 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes" ○*Ogasawara, M. The 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2013-04-11 |
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招待講演 "Catalytic Enantioselective Synthesis of Planar-Chiral (π-Arene)chromium Complexes" ○*Ogasawara, M. The 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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| A01 是永 敏伸 | ||
| Original papers |
"Synthesis of highly refractive and highly fluorescent rigid cyanuryl polyimines with polycyclic aromatic hydrocarbon pendants" Kotaki,T.; Nishimura, N.; Ozawa, M.; Fujimori, A.; Muraoka, H.; Ogawa, S.; Korenaga, T.; Suzuki, E.; Oishi, Y.; *Shibasaki, Y. Polymer Chemistry 2016, 7 pp.1297-1308. |
T. Kotaki, N. Nishimura, M. Ozawa, A. Fujimori, H. Muraoka, S. Ogawa, T. Korenaga, E. Suzuki, Y. Oishi, and Y. Shibasaki |
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"Enantioselective acyl transfer catalysis by a combination of common catalytic motifs and electrostatic interactions" *Mandai, H.; Fujii, K.; Yasuhara, H.; Abe, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Nat. Commun. 2016, 7 pp.11297. |
菅誠治 | |
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"Perfluorinated Aryls in the Design of Chiral Bronsted Acid Catalysts: Catalysis of Enantioselective [4 + 2] Cycloadditions and Ene Reactions of Imines with Alkenes by Chiral Mono-Phosphoric Acids with Perfluoroaryls" *Momiyama, N.; Okamoto, H.; Kikuchi, J.; Korenaga, T.; *Terada, M. ACS Catal. 2016, 6 (2), pp.1198-1204. DOI:10.1021/acscatal.5b02136 |
寺田 眞浩 | |
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"EnantioselectiveAza Michael-Type Addition to AlkenylBenzimidazoles Catalyzed by aChiral PhosphoricAcid" Wang,Y.Y.; Kanomata, K.; Korenaga, T.;*Terada, M. Angew. Chem. Int. Ed. 2016, 55 (3), pp.927-931. DOI:10.1002/anie.201508231 |
寺田 眞浩 | |
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"Development and Application of a Multielectron-Accepting Organic Oxidant for the Catalytic Transition-Metal-Free Oxidative Homocoupling of Grignard Reagents in Air" *Korenaga, T.; Nitatori, K.; Muraoka, H.; Ogawa, S.; Shimada, K. Org. Lett. 2015, 17 (21), pp.5500-5503. DOI:10.1021/acs.orglett.5b02887 |
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"Enantioselective Steglich Rearrangement of Oxindole Derivatives by Easily Accessible Chiral N,N-4-(Dimethylamino)pyridine Derivatives" *Mandai, H., Fujiwara, T.; Noda, K.; Fujii, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Org. Lett. 2015, 17 (18), pp.4436-4439. DOI:10.1021/acs.orglett.5b02089 |
菅 誠治 | |
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"Highly Electron-poor Buchwald-type Ligand: Application for Pd-catalysed Direct Arylation of Thiophene Derivatives and Theoretical Consideration of the Secondary Pd0-arene Interaction" *Korenaga, T.; Sasaki, R.; Shimada, K. Dalton Trans. 2015, 44 pp.19642-19650. DOI:10.1039/C5DT01991E |
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"Ligand Effect on Direct Arylation by CMD Process" *Korenaga, T.; Suzuki, N.; Sueda, M.; Shimada, K. J. Organomet. Chem. 2015, 780 pp.63-69. |
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"Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid" *Terada, M.; Komuro, T.; Toda, Y.; Korenaga, T. J. Am. Chem. Soc. 2014, 136 (19), pp.7044-7057. |
寺田眞浩 | |
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"Low-Temperature Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds" *Korenaga, T.; Ko, A.; Shimada, K. J. Org. Chem. 2013, 78 (19), pp.9975-9980. |
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"The Shielding Effect of Fluoroaromatic Rings in NMR" *Korenaga,T.; Kobayashi, F.; Nomura, K.; Sakai, T.; Shimada, K. J. Fluorine Chem. 2013, 156 pp.1-4. |
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"Biogenous Iron Oxide-immobilized Palladium Catalyst for the Solvent-free Suzuki-Miyaura Coupling Reaction" Mandai, K.; Korenaga, T.; Ema, T.; Sakai, T.; Furutani, M.; Hashimoto, H.; *Takada, J. Tetrahedron Lett. 2012, 53 (3), pp.329-332. |
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| Books |
「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "[(S)-6,6'-ジメトキシ-1,1'-ビフェニル-2,2'-ジイル]- ビス[1,1-ビス(3,4,5-トリフルオロフェニル)ホスフィン]" 是永敏伸 三共出版 (東京) 2015, pp348-351. ISBN:978-4-7827-0727-2 |
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「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "ペンタフルオロフェニルベンゼン" 是永敏伸 三共出版 (東京) 2015, pp326-329. ISBN:978-4-7827-0727-2 |
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「触媒の設計･反応制御 事例集」 "電子不足な不斉ジホスフィン配位子を用いた触媒反応の高効率化" *是永敏伸 科学技術情報社 2013, pp703-711. |
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| Reviews / Accounts |
"金属錯体触媒を超高活性化する新型リン配位子の開発" *是永敏伸 化学工業 2013, 63 (5), pp.329-336. |
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"遷移金属をルイス酸として用いるFrustrated Lewis Pairs " *是永敏伸 Oraganometallic News 2012, (2), pp.68. |
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"高度に電子不足な含フッ素アリールホスフィン配位子を用いた高効率的金属錯体触媒反応" *是永敏伸 有機合成化学協会誌 2013, 71 (1), pp.55-65. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Oxidative homocoupling reaction of aryl Grignard reagents using perfluorocyclopentene derivatives" ○*Korenaga, T.; Nitatori, K.; Shimada, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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依頼講演 "Highly active transition metal catalysts bearing electron-poor phosphine ligand" ○*Korenaga, T. The 95th CSJ Annual Meeting，Asian International Symposium -Organic Chemistry/Green Chemistry-, Narashino (Japan) 2015-03-26～2015-03-26 |
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口頭発表／ポスター発表 "High Efficiency Rh-Catalyzed Asymmetric 1,4- or 1,2-Additions of Arylboronic acids using Highly Electron-Poor Chiral Diphosphine Ligands" ○*Korenaga, T.; Ko, A.; Shimada, K. XXVI International Conference on Organometallic Chemistry, Sappro (Japan) 2014-07-13～2014-07-18 |
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依頼講演 "Highly Electron-Poor Phosphine Ligands Bearing Fluoro-Functional Groups for Rh or Pd Catalysts" ○*Korenaga, T. ICOMC2014 Pre-Symposium in Sendai, Sendai (Japan) 2014-07-11～2014-07-11 |
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口頭発表／ポスター発表 "RHODIUM CATALYZED-ASYMMETRIC ADDITION OF ARYLBORONIC ACID USING HIGHLY ELECTRON-POOR CHIRAL DIPHOSPHINE BEARING FLUORO-FUNCTIONAL GROUPS" ○*Korenaga, T.; Ko, A.; Osaki, K.; Maenishi, R.; Sakai, T. The 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2013-07-27 |
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| Patent |
"含フッ素有機化合物及びこれとグリニャール試薬によるビアリール化合物の製造方法" 発明者：是永敏伸、似鳥馨 出願者：国立大学法人岩手大学 特願2015-119781 2015-06-12, 2015-08, (国内) |
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| Media |
"レアメタル代替新触媒" 是永 敏伸 岩手日報 2015-11-29 PDF 研究成果の紹介記事 |
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| A01 鳴海 哲夫 | ||
| Original papers |
"A minimally cytotoxic CD4 mimic as an HIV entry inhibitor" Mizuguchi, T.; Harada, S.; Miura, T.; Ohashi, N.; Narumi, T.; Mori, H.; Irahara, Y.; Yamada, Y.; Nomura, W.; Matsushita, S.; Yoshimura, K.; Tamamura, H. Bioorganic & Medicinal Chemistry Letters 2016, 26 (2), pp.397-400. DOI:10.1016/j.bmcl.2015.11.103 |
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"Utilization of the Heavy Atom Effect for the Development of a Photosensitive 8-Azacoumarin-Type Photolabile Protecting Group" Takano, H; *Narumi, T.; Nomura, W.; Furta, T.; *Tamamura, H. Org. Lett. 2015, 17 (21), pp.5372-5375. DOI:10.1021/acs.orglett.5b02720 |
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"Remote Stereoinduction in the Organocuprate-Mediated Allylic Alkylation of Allylic gem-Dichlorides: Highly Diastereoselective Synthesis of (Z)-Chloroalkene Dipeptide Isosteres" Kobayakawa, T.; *Narumi, T.; *Tamamura, H. Org. Lett. 2015, 17 (10), pp.2302-2305. DOI:10.1021/acs.orglett.5b00611 |
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"Imidazolium Salt-Catalyzed Friedel–Crafts-Type Conjugate Addition of Indoles: Analysis of Indole/Imidazolium Complex by High Level ab Initio Calculations" Narumi, T.; Tsuzuki, S.; *Tamamura, H. Asian J. Org. Chem 2014, 3 (4), pp.497-503. |
都誠二 | |
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"Development of the 8-aza-3-bromo-7-hydroxycoumarin-4-ylmethyl group as a new entry of photolabile protecting groups" Takano, H.; *Narumi, T.; Takano, H.; Ohashi, N.; Suzuki, A.; Furuta, T.; *Tamamura, H. Tetrahedron 2014, In Press |
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"Isostere-Based Design of 8-Azacoumarin-Type Photolabile Protecting Groups: A Hydrophilicity-Increasing Strategy for Coumarin-4-ylmethyls" Narumi, T.; Takano, H.; Ohashi, N.; Suzuki, A.; Furuta, T.; *Tamamura, H. Org. Lett. 2014, 16 (4), pp.1184-1187. |
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"A CD4 Mimic as an HIV Entry Inhibitors: Pharmacokinetic" Hashimoto, C.; Narumi, T.; Otsuki, H.; Hirota, Y.; Arai, H.; Yoshimura, K.; Harada, S.; Ohashi, N.; Nomura, W.; Miura, T.; Igarashi, T.; Matsushita S.; *Tamamura, H. Bioorg. Med. Chem. 2013, 21 (24), pp.7884-7889. |
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"Generation of a Replication-competent Simian-human Immunodeficiency Virus, the Neutralisation Sensitivity of Which can be Enhanced in the Presence of a Small Molecule CD4 Mimic" Otsuki, H.; Hishiki, T.; Miura, T.; Hashimoto, C.; Narumi, T.; Tamamura, H.; Yoshimura, K.; Matsushita, S.; *Igarashi, T. J. Gen. Virol. 2013, 94 (12), pp.2710-2716. |
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"Peptide-based Ligand Screening and Functional Analysis of Protein Kinase C" Ohashi, N.; Nomura, W.; Narumi, T.; *Tamamura, H. Biopolymers: Peptide Science 2013, 100 (6), pp.613-620. |
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" Low Molecular Weight CXCR4 Ligands with Variable Spcers " Narumi, T.; Aikawa, H.; Tanaka, T.; Hashimoto, C.; Ohashi, N., Nomura, W.; Kobayakawa, T.; Takano, H.; Hirota, Y.; Murakami, T.; Yamamoto, N.; *Tamamura, H.ChemMedChem 2013, 8 (1), pp.118-124. DOI:10.1002/cmdc.201200390 |
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"CD4 Mimics as HIV Entry Inhibitors: Lead Optimization Studies of the Aromatic Substituents" Narumi, T.; Arai, H.; Yoshimura, K.; Harada, S.; Hirota, Y.; Ohashi, N.; Hashimoto, C.; Nomura, W.; Matsushita, S.; *Tamamura, H. Bioorg. Med. Chem. 2013, 21 (9), pp.2518-2526. DOI:10.1016/j.bmc.2013.02.041 |
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"Conjugation of Cell-penetrating Peptides Leads to Identification of Anti-HIV Peptides from Matrix Proteins" Narumi, T.; Komoriya, M.; Hashimoto, C.; Wu, H.; Nomura, W.; Suzuki, S.; Tanaka, T.; Chiba, J.; Yamamoto, N.; Murakami, T.; *Tamamura, H. Bioorg. Med. Chem. 2013, 20 (4), pp.1468-1474. DOI:10.1016/j.bmc.2011.12.055 |
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"Synthetic C34 Trimer of HIV-1 gp41 Shows Significant Increase of Inhibition Potency" Nomura, W.; Hashimoto, C.; Ohya, A.; Miyauchi, K.; Urano, E.; Tanaka, T.; Narumi, T., Nakahara, T.; Komano, J. A.; Yamamoto, N.; *Tamamura, H. ChemMedChem 2012, 7 (2), pp.205-208. DOI:10.1002/cmdc.201100542 |
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"Evaluation of a Synthetic C34 Trimer of HIV-1 gp41 as AIDS Vaccines." Hashimoto, C.; Nomura, W.; Ohya, A.; Urano, E.; Miyauchi, K.; Narumi, T.; Aikawa, H.; Komano J. A.; Yamamoto, N.; *Tamamura, H. Bioorg. Med. Chem. 2012, 20 (15), pp.3287-3291. DOI:10.1016/j.bmc.2012.03.050 |
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"Pharmacophore-Based Small Molecule CXCR4 Ligands. " Narumi, T.; Tanaka, T.; Hashimoto, C.; Nomura, W.; Aikawa, H.; Sohma, A.; Itotani, K.; Kawamata, M.; Murakami, T.; Yamamoto, N.; *Tamamura, H. Bioorg. Med. Chem. Lett. 2012, 22 (12), pp.4169-4172. DOI:10.1016/j.bmcl.2012.04.032 |
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"Stereoselective Formation of Trisubstituted (Z)-Chloroalkenes Adjacent to a Tertiary Carbon Stereogenic Center by Organocuprate-Mediated Reduction/Alkylation" Narumi, T.; Kobayakawa, T.; Aikawa, H.; Seike, S.; *Tamamura, H. Org. Lett. 2012, 14 (17), pp.4490-4493. DOI:10.1021/ol301988d |
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| Books |
「Peptide Newsletter Japan」 林 良雄; 中馬 吉郎 "焦らず、たゆまず、楽しんで" 鳴海哲夫 日本ペプチド学会 2015, pp3-6. |
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「最新ペプチド合成技術とその創薬研究への応用」 木曽良明 "α-ケト酸とヒドロキシアミンの化学選択的なライゲーション反応によるペプチド合成" 鳴海哲夫, Jeffrey W. Bode 株式会社 メディカル ドゥ (大阪) 2012, pp68-75. ISSN:1349-2527 |
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| A01 山田 眞二 | ||
| Original papers |
"
A pyridinium cation–pi
interaction sensor for the fluorescent detection of alkyl halides
"
Chen, W.; Elfeky, S. A.;
Nonne, Y.; Male, L.; Ahmed, K.; Amiable, C.; Axe, P.; Yamada, S.; James, T. D.; Bull, S. D.; *Fossey,
J. S.
Chem. Commun. 2011, 47 pp.253-255. |
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"
2,4-dihydroxy-2,5-dimethyl-3(2H)-thiophenone
as low-molecular-weight yellow pigment in soy sauce
"
Satoh, M.; Nomi, Y.; Yamada, S.; Takenaka, M.; Ono, H.; *Murata,
M.
Biosci. Biotechnol. Biochem. 2011, 75 pp.1240-1244. |
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|
"
Regiospecific [2+2]
photocyclodimerization of trans-4-styrylpyridines templated by
cucurbit[8]uril
"
*Nakamura, A.; Irie, H.; Hara, S.; Sugawara, M.; Yamada, S.
Photochem. Photobiol. Sci. 2011, 10 pp.1496-1500. |
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"
Water-assisted assembly of (E)-arylvinylpyridine
hydrochlorides: effective substrates for solid-state [2+2] photodimerization
"
*Yamada,
S.; Nojiri, Y.
Chem. Commun. 2011, 47 pp.9143-9145. |
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"
Nitrogen cation-pi interactions
in asymmetric organocatalytic synthesis
"
*Yamada,
S.; Fossey, J. S.
Org. Biomol. Chem. 2011, 9 pp.7275-7281. |
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"[2+2] Photodimerization of ( E )-styrylthiazoles through cation-π-controlled preorientation" *Yamada, S.; Yamagami, K.; Oaku, S. Tetrahedron Lett. 2016, 57 pp.2451-2454. DOI:10.1016/j.tetlet.2016.04.085 |
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"Porous organic hydrate crystals: structure anddynamic behaviour of water clusters" *Yamada, S.; Sako, N.; Yamada, K.; Deguchi, K.; Shimizu, T. CrystEngComm 2015, 17 pp.5629-5633. DOI:10.1039/c4ce02517b |
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"Vapochromism associated with the changes in themolecular arrangement of organic crystals" *Yamada, S.; Katsuki, A.; Nojiri, Y.; Tokugawa, Y. CrystEngComm 2015, 17 pp.1416-1420. DOI:10.1039/c4ce01314 |
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"A Molecular Seesaw Balance: Evaluation of Solvent andCounteranion Effects on Pyridinium−π Interactions" *Yamada, S; Yamamoto, N; Takamori, E. Org. Lett. 2015, 17 pp.4862-4865. DOI:10.1021/acs.orglett.5b02420 |
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"Isolation, identification, and formation conditions of a novel Maillardyellowish pigment, pyrrolothiazolate" Noda, K.; Yamada, S.; *Murata, M. Biosci. Biotechnol. Biochem. 2015, 79 pp.1350-1355. DOI:10.1080/09168451.2015.1018127 |
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"Tetrabutylammonium-assisted diastereoselective [6π]-photocyclization of acrylanilides" *Yamada, S.; Okuda, M.; Yamamoto, N. Tetrahedron Lett. 2015, 56 pp.2098-2101. |
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"[2+2] photodimerization of 1-aryl-4-pyridylbutadienes through cation-pi interactions" *Yamada, S.; Azuma, Y.; Aya, K. Tetrahedron Lett. 2014, 55 pp.2801-2804. |
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"Tetraalkylammonium-Templated Stereoselective Norrish-Yang Cyclization" *Yamada, S.; Iwaoka, A.; Fujita, Y.; Tsuzuki, S. Org. Lett. 2013, 15 (23), pp.5994-5997. DOI:10.1021/ol4028732 |
Tsuzuki, S. | |
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"
Cascade reactions in crystals through cation-pi-controlled
reorientation on exposure to HCl gas
"
*Yamada, S.; Tokugawa, Y. Nojiri, Y.; Takamori, E.
Chem. Commun. 2012, 48 pp.1763-1765. DOI:10.1039/c2cc17019a |
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"
[2
+ 2] Photodimerization of bispyridylethylenes by a controlled shift of the
protonation equilibrium"
*Yamada, S.; Kusafuka, M.; Sugawara, M. Tetrahedron Lett. 2013, 54 pp.3997-4000. DOI:10.1016/j.tetlet.2013.05.075 |
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"
A dual-synthon in pyridinium chloride: formation of ladder-like and columnar motifs through hydrogen bonds and cation–pi interactions
" *Yamada, S.; Sako, N.; Okuda, M.; Hozumi, A. CrystEngComm 2013, 15 (1), pp.199-205. DOI:10.1039/C2CE26547H |
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"[4 + 4] Photodimerization of Azaanthracenes in Both Solution and Solid Phase Controlled by Cation-π Interactions" *Yamada, S.; Kawamura, C. Org. Lett. 2012, 14 (6), pp.1572-1575. DOI:10.1021/ol3003089 |
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"Contribution of Cation-pi Interactions in Iminium Catalysis" Mori, Y.; *Yamada, S. Molecules 2012, 17 pp.2161-2168. DOI:10.3390/molecules17022161 |
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| Reviews / Accounts |
"ピリジン誘導体と気体の反応による分子配列変化：カチオン−π相互作用による制御" 山田眞二 日本結晶学会誌 2013, 55 pp.63-68. |
|
| Conference / Symposium / Lecture |
依頼講演 "
カチオンーπ相互作用に基づく有機触媒設計：イオン液体の有機触媒としての利用
"
○*山田眞二 第５回有機触媒シンポジウム, 東京 (日本) 2012-10-27～2012-10-28 |
|
|
口頭発表／ポスター発表 "
テトラアルキルアンモニウム塩をテンプレートとするNorrish-Yang環化反応 " ○藤田結香、*山田眞二、都築誠二第６回有機触媒シンポジウム, 札幌 (日本) 2014-06-20～2014-06-21 |
都築誠二 | |
|
"
テトラアルキルアンモニウム塩を用いる芳香族ケトン類の立体選択的Norrish-Yang 反応
"
〇大島 有貴・*山田 眞二・都築 誠二
日本化学会第９５春期年会, 船橋 (日本) 2015-03-26～2015-03-29 |
都築誠二 | |
|
口頭発表／ポスター発表 "
テトラアルキルアンモニウム塩を触媒とする立体選択的Norrish-Yang反応
"
○大島有貴・藤田結香・*山田眞二・都築誠二
第８回有機触媒シンポジウム, 沖縄 (日本) 2016-05-10～2016-05-11 |
都築誠二 | |
|
口頭発表／ポスター発表 "Synthesis of Molecular Seesaw Balance and Its Application to a Molecular Switch" ○Yamamoto, N.; *Yamada, S CMES International Symposium on Supramolecular Chemistry and Functional Materials 2016 (CEMSupra) 2016, 東京 (日本) 2016-01-13～2016-01-14 |
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口頭発表／ポスター発表 "Cation-π Interactions between Pyridinium and Benzene Rings:A Powerful Tool for Arrangement of Organic Molecules" ○*Yamada, S. The 22nd International Conference on the Chemistry of Organic Solid State (ICCOSS XXII), 新潟 (日本) 2015-07-12～2015-07-17 |
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|
招待講演 "Diastereoselective Photocyclization Reactions throughTetraalkylammonium-π Interactions " ○*Yamada, S. Advanced Molecular Transformationsby Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, 東京 (日本) 2014-11-21～2014-11-22 |
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|
招待講演 "Tetraalkylammonium-Templated Stereoselective Norrish-Yang Cyclization of 2-Benzyloxyacylbenzenes" ○*Yamada, S.; Iwaoka, A.; Fujita, Y.; Tsuzuki, S. International Sympsium on Organic Reaction-11 (ISOR-11), Taipei (Taiwan) 2013-11-19～2013-11-22 |
Tsuzuki, S. | |
|
口頭発表／ポスター発表 "
[2+2] Photodimerization of Bispyridylethylene through Cation-π Interaction "○*Yamada, S.; Kusafuka, M.; Sugawara, M. 7th Asian Photochemistry Conference 2012, Osaka (Japan) 2012-11-12～2012-11-15 |
||
|
口頭発表／ポスター発表 "
アンモニウム塩との相互作用による２-アルコキシ芳香族ケトン類の立体選択的 Norrish Type II 反応"
○*山田眞二・岩岡梓・都築誠二 日本化学会第93春季年会, 草津 (日本) 2013-03-24～2013-03-24 |
都築誠二 | |
|
口頭発表／ポスター発表 "
Tetrabutylammonium Salts as Templates for
Stereoselective Norrish Type II Reactions of 2-Benzyloxyacylbenzenes
"
*○Yamada, S.;
Iwaokoa, A.; Tsuzuki, S.
1st international conference & 6th symposium on organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
Tsuzuki, S. | |
| Media |
"
Making an Azaanthracene Sandwich? Use Cation-pi! "Yamada, S.; Kawamura, C. 10.1055/s-0031-1291133 2012-06-01PDF （Synfacts誌, 2012, 8(6),0615 に掲載） アザアントラセンの光二量化では、異性体混合物を与え、固相反応では二量体を与えない。しかし、酸を触媒として用いることで、溶液中では選択的にanti-HT二量体を与えた。さらに塩酸塩の固相光反応によって定量的にanti-HT体を与えた。ピリジニウムとベンゼンとのカチオン−π相互作用が立体選択的[4+4]光二量化を可能にした。 |
|
| A01 波多野 学 | ||
| Original papers |
"Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds" Hatano, M.; Hayashi, K.; Sakamoto, T.; Makino, Y.; *Ishihara, K. Synlett 2016, 27 (7), pp.1061-1067. DOI:10.1055/s-0035-1561362 |
|
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"Enantioselective Cyanosilylation of Ketones with Lithium(I) Dicyanotrimethylsilicate(IV) Catalyzed by a Chiral Lithium(I) Phosphoryl Phenoxide" Hatano, M.; Yamakawa, K.; Kawai, T.; Horibe, T.; *Ishihara, K. Angew. Chem. Int. Ed. 2016, 55 (12), pp.4021-4025. DOI:10.1002/anie.201510682 |
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"Remote Tris(pentafluorophenyl)borane-Assisted Chiral Phosphoric Acid Catalysts for the Enantioselective Diels–Alder Reaction" Hatano, M.; Ishihara, H.; Goto, Y.; *Ishihara, K. Synlett 2016, 27 (4), pp.564-570. DOI:10.1055/s-0035-1560369 |
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|
"Boron Tribromide-Assisted Chiral Phosphoric Acid Catalyst for a Highly Enantioselective Diels–Alder Reaction of 1,2-Dihydropyridines" Hatano, M.; Goto, Y.; Izumiseki, A.; Akakura, M.; *Ishihara, K. J. Am. Chem. Soc. 2015, 137 (42), pp.13472-13475. DOI:10.1021/jacs.5b08693 |
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"C- and N-Selective Grignard Addition Reactions of α-Aldimino Esters in the Presence or Absence of Zinc(II) Chloride: Synthetic Applications to Optically Active Azacycles" Hatano, M.; Yamashita, K.; *Ishihara, K. Org. Lett. 2015, 17 pp.2412-2415. DOI:10.1021/acs.orglett.5b00927 |
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"C-Selective and Diastereoselective Alkyl Addition to beta,gamma-Alkynyl-alpha-imino Esters with Zinc(II)ate Complexes" Hatano, M.; Yamashita, K.; Mizuno, M.; Ito, O.; *Ishihara, K. Angew. Chem. Int. Ed. 2015, 54 (9), pp.2707-2711. DOI:10.1002/anie.201408916 |
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"Chiral Supramolecular Magnesium(II) Binaphtholate Catalysts for the Enantioselective Direct Mannich-Type Reaction and Hetero-Diels–Alder Reaction" Hatano, M.; Horibe, T.; Yamashita, K.; *Ishihara. K. Asain J. Org. Chem. 2013, 2 (11), pp.952-956. DOI:10.1002/ajoc.201300190 |
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"Synthesis of Optically Pure 3,3′-Diaryl Binaphthyl Disulfonic Acids via Stepwise N–S Bond Cleavage" Hatano, M.; Ozaki, T.; Nishikawa, K.; *Ishihara, K. J. Org. Chem. 2013, 78 pp.10405-10413. DOI:10.1021/jo401848z |
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"Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones" Hatano, M.; Horibe, T.; *Ishihara, K. Angew. Chem. Int. Ed. 2013, 52 (17), pp.4549-4553. DOI:10.1002/anie.201300938 |
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"Lanthanum(III) Catalysts for Highly Efficient and Chemoselective Transesterification" Hatano, M.; *Ishihara, K. Chem. Commun. 2013, 49 (20), pp.1983-1997. DOI:10.1039/C2CC38204K |
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"In Situ Generated "Lanthanum(III) Nitrate Alkoxide" as a Highly Active and Nearly Neutral Transesterification Catalyst" Hatano, M.; Kamiya, S.; *Ishihara, K. Chem. Commun. 2012, 48 (76), pp.9465-9467. DOI:10.1039/C2CC34987F |
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"Enantioselective Direct Aminalization with Primary Carboxamides Catalyzed by Chiral Ammonium 1,1’-Binaphthyl-2,2’-disulfonates" Hatano, M.; Ozaki, T.; Sugiura, Y.; *Ishihara, K. Chem. Commun. 2012, 48 (41), pp.4986-4988. DOI:10.1039/C2CC31530K |
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"Conformationally Flexible Chiral Supramolecular Catalysts for Enantioselective Diels-Alder Reactions with Anomalous Endo/Exo Selectivities" Hatano, M.; *Ishihara, K. Chem. Commun. 2012, 48 (36), pp.4273-4283. DOI:10.1039/C2CC00046F |
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| Books |
「RSC Green Chemistry No. 38, Sustainable Catalysis: With Non-endangered Metals, Part 1」 North, M. "Chapter 2. Alkali metal (Li, Na, K)-based Catalysts " Hatano, M.; Ishihara, K The Royal Society of Chemistry 2016, pp15-48. |
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「超分子材料の設計と応用展開」 監修：原田 明 "テーラーメード型超分子触媒" 波多野学、石原一彰 シーエムシー出版 2014, pp162-175. ISBN:978-4-7813-0973-6 |
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「Science of Synthesis Knowledge Updates 2013/1」 Fuertner, A. (Vol. 9), Ishihara, K. (Vol. 7), Li, J. J. (Vol. 16), Moloney, M. G. (Vol. 5) "7.7 Product Class 7: Calcium Compounds" Hatano, M. Georg Thieme Verlag KG 2013, pp113-156. |
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| Reviews / Accounts |
"リン酸の酸・塩基協奏機能を活用したホウ素Lewis酸-キラルリン酸複合高活性触媒の開発" 波多野 学; *石原 一彰 月刊ファインケミカル 2016, 45 (2), pp.24-32. |
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"高機能触媒の超分子設計" 波多野学; 石原一彰 化学工業 2015, 66 (5), pp.381-388. |
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"アルキルZ試薬：亜鉛(II)アート錯体を用いるケトン及びイミノエステルへの高効率Grignard付加反応の開発" 波多野学; 石原一彰 和光純薬時報 2015, 83 (2), pp.2-5. |
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"キラルビナフチルジスルホン酸を鍵とする分子触媒設計の新機軸" 波多野学, 西川圭祐, *石原 一彰 TCIメール 2014, 160 pp.2-23. |
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"Chiral 1,1′-Binaphthyl-2,2′-Disulfonic Acid (BINSA) and Its Derivatives for Asymmetric Catalysis" Hatano, M.; *Ishihara, K. Asian J. Org. Chem. 2014, 3 (4), pp.352-365. DOI:10.1002/ajoc.201300256 |
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"テーラーメイド型超分子触媒の設計" Hatano, M.; *Ishihara, K. ケミカルエンジニヤリング 2012, 9 (57), pp.656-661. |
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"Design of Tailor-Made Conformationally Flexible Chiral Supramolecular Catalysts Beyond Enzymes (酵素を凌駕するテーラーメイド型配座柔軟性キラル超分子触媒の精密設計)" *Hatano, M. J. Synth. Org. Chem. Jpn 2012, 12 (70), pp.1242-1254. |
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"「飛翔する若手研究者」キラルジスルホン酸を鍵とする酸・塩基触媒化学" 波多野 学 化学と工業 2012, 65 (10), pp.782-783. |
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| Conference / Symposium / Lecture |
招待講演 "Synthesis of 3,3'-diaryl-1,1'-binaphthalene-2,2'-disulfonic acids and design of chiral 3,3'-Ar2-BINSA salt catalysts" ○*Ishihara, K.; Hatano, M.; Nishikawa, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Boron tribromide-assisted chiral phosphoric acid catalysts for highly enantioselective Diels–Alder reaction of 1,2-dihydropyridines (Paper #: 1544)" ○Hatano, M.; Goto, Y.; *Ishihara, K. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development of Chiral 3,3’-Diaryl-1,1’-Binaphthyl-2,2’-Disulfonic Acids (BINSA) as Chiral Brønsted Acid Catalysts" ○Hatano, M.; Nishikawa, K.; *Ishihara, K. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones" Hatano, M.; Horibe. T.; *Ishihara, K Gordon Research Conferences (GRC) 2013; Heterocyclic Compounds, Newport (USA) 2013-06-16～2013-06-21 |
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招待講演 "Design of Chiral Tailor-Made Supramolecular Catalysts for Higher-Ordered Stereoselective Diels-Alder Reaction" ○*Hatano, M. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Conformationally Flexible Chiral Supramolecular Catalysts for Enantioselective Diels-Alder Reactions with Anomalous Endo/Exo Selectivities" ○Hatano, M.; *Ishihara, K. Gordon Research Conferences (GRC) 2012; Heterocyclic Compounds, Newport (USA) 2012-06-24～2012-06-29 |
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| Prize |
"Thieme Chemistry Journal Award 2015" *Hatano, M. 2015-01 Thieme Chemistry (The editorial boards of Synlett, Synthesis, and Synfacts) |
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"平成25年度科学技術分野の文部科学大臣表彰若手科学者賞" 波多野学 2013-04 文部科学省 酸塩基協奏型高次機能触媒を用いる精密有機合成法の研究 |
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| Media |
"Enantioselective Cyanosilylation of Ketones with Extremely Reactive Lithium(I) Dicyanotrimethylsilicate(IV) Catalyzed by Chiral Lithium(I) Phosphoryl Phenoxide" Hatano, M.; Yamakawa, K.; Kawai, T.; Horibe, T.; Ishihara, K. Angew. Chem. Int. Ed. 2016-02-05 PDF ■Cover pictureに採用 http://onlinelibrary.wiley.com/doi/10.1002/anie.201601600/epdf ■名古屋大学記者発表(2016年2月5日(金) 名古屋大学広報プラザ2階)「ケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 〜構造多様性四置換不斉炭素の構築とキラル合成素子ライブラリーの拡充〜」http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20160208_engg.pdf ■「日本の研究.com」に研究成果掲載(2016年2月8日(月))「ケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 〜構造多様性四置換不斉炭素の構築とキラル合成素子ライブラリーの拡充〜」https://research-er.jp/articles/view/43198 ■化学工業日報 2016年2月9日(火)、第5面「キラル化合物 ケトン由来 効率合成 名大、新不斉触媒を開発」■中日新聞朝刊 2016年3月4日(金)、第6面「有機化合物の合成に新手法 名大グループが開発」■AlphaGalileoにハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (22 February 2016) http://www.alphagalileo.org/ViewItem.aspx?ItemId=161259&CultureCode=en ■ResearchSEAにハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (Article Released Mon-22nd-February-2016) http://www.researchsea.com/index.php ■EurekAlert! にハイライト ‘Breakthrough Improves Method for Synthesizing Cyanohydrins as Pharmaceutical Precursors’ (Article Released Mon-22nd-February-2016) http://www.eurekalert.org/pub_releases/2016-02/nu-bim022216.php ■ワイリー・サイエンスカフェに論文紹介 (2016年3月1日)「名古屋大・石原 一彰教授らがケトン由来の光学活性α-シアノヒドリンの触媒的不斉合成法を開発 (ACIE)」http://www.wiley.co.jp/blog/pse/ ■名大・学術研究・産学官連携推進本部NU Research論文ハイライトに掲載(2016年3月18日)http://www.aip.nagoya-u.ac.jp/public/nu_research_ja/highlights/detail/0003356.html ■Synfacts 2016, 12(4), 0395に論文紹介(Synfacts Contributors: Mark Lautens and Kosuke Yamamoto) |
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""C-Selective and Diastereoselective Alkyl Addition to beta,gamma-Alkynyl-alpha-imino Esters with Zinc(II)ate Complexes"" Hatano, M.; Yamashita, K.; Mizuno, M.; Ito, O.; *Ishihara, K. Angew. Chem. Int. Ed. 2015, 54, ASAP 2015-01-23 PDF ■日刊工業新聞（2015年1月23日（金）23面） 「人工アミノ酸産出多彩 名大が新合成法 光学活性物質ほぼ100% 副作用軽減、創薬開発に応用」(ウェブ版 http://www.nikkan.co.jp/news/nkx1020150123eaaj.html) ■中日新聞（2015年1月23日（金）3面） 「安価に高純度アミノ酸 名大開発、新薬の原料に」 ■化学工業日報（2015年1月30日（金）9面） 「α-第四級2置換アミノ酸 名大が高純度合成技術 アルキル化の新規錯体開発 安価で調整容易 医薬原料や機能材向け」 |
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"Supramolecular Catalysts from Simple Components" Hatano, M.; Horibe, T.; Yamashita, K.; *Ishihara. K. ChemistryViews 2013-11-18 Since Jean-Marie Lehn received the Novel Prize for supramolecular chemistry in 1987, chiral supramolecular catalysts have been attractive in organic synthesis. However, their practical use has been limited, as a precise synthesis of a sole designed species is difficult because of undesired aggregation of the catalysts. |
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""In Situ Generated "Lanthanum(III) Nitrate Alkoxide" as a Highly Active and Nearly Neutral Transesterification Catalyst"" Hatano, M.; Kamiya, S.; Ishihara, K. Chem. Commun. 2012, 48(76), 9465-9467. DOI: 10.1039/C2CC34987F 2012-08-08 PDF ・日刊工業新聞21面に記事掲載(2012年8月28日)「名大、ランタン触媒でエステル合成－医薬品製造の効率化へ」 |
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""Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid–Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones"" Hatano, M.; Horibe, T.; Ishihara, K.* Angew. Chem. Int. Ed. 2013-04-08 PDF Front Coverに選定 (Angew. Chem. Int. Ed. 2013, 52, 4549-4553.) ■中日新聞 2013年3月7日朝刊第29面「混ぜるだけで不斉触媒、有機物×金属「黄金比」発見、名大グループ、アルツハイマー薬に道」 ■朝日新聞 2013年3月7日朝刊第30面「薬合成「触媒」の自由設計法、名大院研究室が開発」 ■日刊工業新聞 2013年3月7日第19面「光学活性リン化合物、安価な合成技術開発」 ■日刊工業新聞 2013年3月7日(Web版)「名大、光学活性リン化合物を安価に合成する技術開発」 ■化学工業日報 2013年3月7日第4面「名大 超分子錯体で不斉触媒 ２物質混ぜるだけ 高収率・選択性を確認」 ■化学工業日報 2013年3月7日(Web版)「名古屋大学 超分子錯体で不斉触媒 ２物質混ぜるだけ」 ■名古屋大学ーJST共同発表：プレスリリース http://www.jst.go.jp/pr/announce/20130307/ ■日経プレスリリース http://release.nikkei.co.jp/detail.cfm?relID=332308&lindID=5 ■名古屋大学研究教育成果情報(PDF資料) http://www.nagoya-u.ac.jp/research/pdf/activities/20130307_engg.pdf?20130307 |
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| A01 加納 太一 | ||
| Original papers |
"Synthesis of N-Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with N-Boc-Aminals and Their Oxidation to N-Boc-Ketimines" Kano, T.; Kobayashi, R.; *Maruoka, K. Org. Lett. 2016, 18 (2), pp.276-279. |
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"Brønsted Acid-catalysed Mannich Reaction Through Dual Activation of Aldehydes and N-Boc-Imines" Kano, T.; Aota, Y.; Asakawa, D.; *Maruoka, K. Chem. Commun. 2015, 51 (92), pp.16472-16474. |
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"Regioselectivity Switch in Chiral Amine-catalysed Asymmetric Addition of Aldehydes to Reactive Enals" Kano, T.; Maruyama, H.; Sakamoto, R.; *Maruoka, K. Chem. Commun. 2015, 51 (49), pp.10062-10065. |
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"Regio- and Stereoselective Conjugate Addition of Aldehydes to β-Tosyl Enones Catalyzed by Binaphthyl-Modified Chiral Amine" Kano, T.; Sugimoto, H.; Maruyama, H.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (29), pp.8462-8465. |
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"Versatile, In-Situ Generated N-Boc-Imines: Application to Phase-Transfer Catalyzed Asymmetric Mannich-Type Reaction" Kano, T.; Kobayashi, R.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (29), pp.8471-8474. |
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"Design and Synthesis of a Biphenyl-based Chiral Amino Sulfonamide with High Catalytic Performance in Mannich Reactions" Kano, T.; Maruyama, H.; Akiyama, K.; *Maruoka, K. Tetrahedron Lett. 2014, 55 (30), pp.4227-4229. |
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"Synthesis of 3-Mono-Substituted Binaphthyl-Based Secondary Amine Catalysts via Monobromination of an Axially Chiral Dicarboxylic Acid Derivative" Kano, T.; Takeda, M.; Sakamoto, R.; *Maruoka, K. J. Org. Chem. 2014, 79 (9), pp.4240-4244. |
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"Practical Approach for Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds: Application to One-Pot Synthesis of Chiral Allylamines" Kano, T.; Shirozu, F.; *Maruoka, K. Org. Lett. 2014, 16 (5), pp.1530-1532. |
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"Amine-catalyzed Asymmetric Cross-aldol Reactions Using Hetero-functionalized Acetaldehydes as Nucleophiles" Kano, T.; Sakamoto, R.; *Maruoka, K. Org. Lett. 2014, 16 (3), pp.944-947. |
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"Chiral Brønsted Acid-catalyzed Enantioselective Addition of Indoles to Ketimines" Kano, T.; Takechi, R.; Kobayashi, R.; *Maruoka, K. Org. Biomol. Chem. 2014, 12 (5), pp.724-727. |
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"Remote Chirality Control Based on the Organocatalytic Asymmetric Mannich Reaction of α-Thio Acetaldehydes" Kano, T.; Sakamoto, R.; *Maruoka, K. Chem. Commun. 2014, 50 (8), pp.942-944. |
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"Metal-free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine" Kano, T.; Shirozu, F.; *Maruoka, K. J. Am. Chem. Soc. 2013, 135 (48), pp.18036-18039. |
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"Organocatalytic Asymmetric Synthesis of Propargylamines with Two Adjacent Stereocenters Through Mannich-type Reactions of in situ Generated C-Alkynyl Imines with β-Keto Esters" Kano, T.; Yurino, T.; *Maruoka, K. Angew. Chem. Int. Ed. 2013, 52 (44), pp.11509-11512. |
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"Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-transfer Conditions" Kano, T.; Hayashi, Y.; *Maruoka, K. J. Am. Chem. Soc. 2013, 135 (19), pp.7134-7137. |
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"Unusual anti-Selective Asymmetric Conjugate Addition of Aldehydes to Nitroalkenes Catalyzed by a Biphenyl-based Chiral Secondary Amine" Kano, T.; Sugimoto, H.; Tokuda, O.; *Maruoka, K. Chem. Commun. 2013, 49 (63), pp.7028-7030. |
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"Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals" Kano, T.; Yurino, T.; Asakawa, D.; *Maruoka, K. Angew. Chem. Int. Ed. 2013, 52 (21), pp.5532-5534. |
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"One-pot Cross Double-Mannich Reaction of Acetaldehyde Catalyzed by a Binaphthyl-based Amino Sulfonamide" Kano, T.; Sakamoto, R.; Yamaguchi, Y.; Itoh, K.; *Maruoka, K. Chem. Commun. 2013, 49 (11), pp.1118-1120. |
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"Stereoselective Synthesis of Cyclic Amino Acids via Asymmetric Phase-transfer Catalytic Alkylation" Kano, T.; Kumano, T.; Sakamoto, R.; *Maruoka, K. Org. Biomol. Chem. 2013, 11 (2), pp.271-278. |
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"Powerful Amino Diol Catalyst for Effecting the Direct Asymmetric Conjugate Addition of Aldehydes to Acrylates" Kano, T.; Shirozu, F.; Akakura, M.; *Maruoka, K. J. Am. Chem. Soc. 2012, 134 (38), pp.16068-16073. |
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"Molecular Recognition of Ketomalonates by Asymmetric Aldol Reaction of Aldehydes with Secondary-Amine Organocatalysts" Kano, T.; Song, S.; *Maruoka, K. Chem. Commun. 2012, 48 (56), pp.7037-7039. |
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"Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (–)-Agelastatin A" Kano, T.; Sakamoto, R.; Akakura, M.; *Maruoka, K. J. Am. Chem. Soc. 2012, 134 (17), pp.7516-7520. |
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"Highly Diastereo- and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine Organocatalysts" Kano, T.; Song, S.; Kubota, Y.; *Maruoka, K. Angew. Chem. Int. Ed. 2012, 51 (5), pp.1191-1194. |
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| Books |
「Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 2」 North, M. "Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts" Kano, T.; Maruoka, K. The Royal Society of Chemistry 2016, pp135-163. |
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「有機化学要論 生命科学を理解するための基礎概念」 入江一浩; 津江広人 "有機化学における熱力学の基礎" 入江一浩; 津江広人; 高野俊幸; 加納太一; 松原誠二郎; 板東俊和; 藤田健一 学術図書出版 2016, pp55-72. |
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「Comprehensive Chirality, Volume 6」 Maruoka, K.; Editors-in-Chief: Carreira, E. M.; Yamamoto, H. "6.20 C–X Bond Formation: α-Halogenation of Carbonyl Compounds" Kano, T. Elsevier Science (Amsterdam) 2016, pp488-505. ISBN:0080951678 |
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| Reviews / Accounts |
"Unique Properties of Chiral Biaryl-based Secondary Amine Catalysts for Asymmetric Enamine Catalysis" Kano, T.; *Maruoka, K. Chem. Sci. 2013, 4 (3), pp.907-915. |
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| Conference / Symposium / Lecture |
招待講演 "Catalyst Control of Diastereoselectivity in Chiral Amine-Catalyzed Asymmetric Conjugate Additions of Aldehydes" Kano, T. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" Kano, T. 7th Spanish Portuguese Japanese Organic Chemistry Symposium, Seville (Spain) 2015-06-23～2015-06-26 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" Kano, T. Departmental Seminar at Charles University, Prague (Czech Republic) 2015-06-19～2015-06-19 |
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口頭発表／ポスター発表 "Chiral Amine-Catalyzed Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds" Kano, T.; Shirozu, F.; *Maruoka, K. Chirality 2014, Prague (Czech Republic) 2014-07-27～2014-07-30 |
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口頭発表／ポスター発表 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T.; Shirozu, F.; *Maruoka, K. 13th Tateshina Conference, Tateshina (Japan) 2013-11-08～2013-11-10 |
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口頭発表／ポスター発表 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T.; *Maruoka, K. 23rd International Symposium, Synthesis in Organic Chemistry, Oxford (UK) 2013-07-22～2013-07-25 |
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招待講演 "Asymmetric α-Functionalization of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. Departmental Seminar at Oxford University, Oxford (UK) 2013-07-19～2013-07-19 |
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招待講演 "Enantioselective Carbon-Heteroatom Bond Formation by Binaphthyl-based Amine Catalysts" ○Kano, T. 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc-Imines from N-Boc-Aminals" ○Kano, T.; Yurino, T.; *Maruoka, K. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 仙台 (日本) 2013-04-19～2013-04-20 |
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招待講演 "Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction: Formal Synthesis of (–)-Agelastatin A" ○Kano, T. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2013-12-18 |
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口頭発表／ポスター発表 "Highly Diastereo- and Enantioselective Mannich Reaction of Synthetically Flexible Ketimines by Secondary-Amine Organocatalysts" ○Kano, T.; Song, S.; *Maruoka, K. EUCHEM Conference on Stereochemistry (The 47th Bürgenstock Conference), Zürich (Switzerland) 2012-04-29～2012-05-04 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. Departmental Seminar at ETH, Zürich (Switzerland) 2012-04-27～2012-04-27 |
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招待講演 "Asymmetric α-Functionalizations of Aldehydes Catalyzed by Biaryl-based Secondary Amines" ○Kano, T. TAIWAN−JAPAN Symposium of Frontier Research on Design and Applications of Fine Chemicals, 台北 (台湾) 2012-01-06～2012-01-08 |
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| Prize |
"文部科学大臣表彰若手科学者賞" 加納太一 2012-04 文部科学省 デザイン型アミン有機触媒による精密有機合成の研究 |
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| Media |
"Brønsted Acid-catalysed Mannich Reaction Through Dual Activation of Aldehydes and N-Boc-Imines" Kano, T.; Aota, Y.; Asakawa, D.; *Maruoka, K. Chemical Communications 2015-11-28 PDF Chemical Communications誌のInside Coverに選定 |
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"Chiral Brønsted Acid-catalyzed Enantioselective Addition of Indoles to Ketimines" Kano, T.; Takechi, R.; Kobayashi, R.; *Maruoka, K. Org. Biomol. Chem. 2014-02-07 PDF Organic & Biomolecular Chemistry誌のFront Coverに選定 |
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"Unusual anti-Selective Asymmetric Conjugate Addition of Aldehydes to Nitroalkenes Catalyzed by a Biphenyl-based Chiral Secondary Amine" Kano, T.; Sugimoto, H.; Tokuda, O.; *Maruoka, K. Chemical Communications 2013-07-11 PDF Chemical Communications誌のFront Coverに選定 |
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"Stereoselective Synthesis of Cyclic Amino Acids via Asymmetric Phase-transfer Catalytic Alkylation" Kano, T.; Kumano, T.; Sakamoto, R.; *Maruoka, K. Organic & Biomolecular Chemistry 2013-01-14 PDF Organic & Biomolecular Chemistry誌のFront Coverに選定 |
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| A01 村井 健一 | ||
| Original papers |
"Oxidative Rearrangement via in Situ Generated N-Chloroamine: Synthesis of Fused
Tetrahydroisoquinolines" *Murai, K.; Matsuura, K.; Aoyama, H.;
Fujioka, H. Org. Lett. 2016, 18 (6), pp.1314-1317. DOI:10.1021/acs.orglett.6b00233 |
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"Organic synthesis based on the Beckmann
fragmentation: generation of an electrophilic salt intermediate and successive
C-C bond formation using Gilman reagents" *Fujioka, H.; Matsumoto, N.; Ohta, R.;
Yamakawa, M.; Shimizu, N.; Kimura, T.; Murai, K. Tetrahedron Lett. 2015, 56 (21), pp.2656-2658. DOI:10.1016/j.tetlet.2015.03.089 |
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"Enantioselective organocatalytic oxidation of ketamine" *Takizawa, S.; Kishi, K.; Abozeid, M.
A.; *Murai, K.; Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2016, 14 (2), pp.761-767. DOI:10.1039/C5OB02042E |
滝沢 忍 | |
|
"Oxidative Rearrangement of Cyclobutanone Derived N,O-Ketals Leading to Pyrrolidone Derivatives" *Murai, K.; Endo, D.; Kawashita, N.; Takagi, T.; *Fujioka, H. Chem. Pharm. Bull. 2015, 63 (4), pp.245-247. DOI:10.1248/cpb.c14-00856 |
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"Enantioselective, Desymmetrizing, Bromolactonization Reactions of Symmetric Olefinic Dicarboxylic Acids" *Murai, K.; Nakajima, J.; Nakamura, A.;
Hyogo, N.; *Fujioka, H. Chem. Asian J. 2014, 9 (12), pp.3511-3517. DOI:10.1002/asia.201402865 |
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"Enantioselective iodolactonization of allenoic
acids" *Murai, K.; Shimizu, N.; *Fujioka, H. Chem. Commun. 2014, 50 (83), pp.12530-12533. DOI:10.1039/C4CC05414H |
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"C3-Symmetric chiral trisimidazoline-catalyzed Friedel-Crafts (FC)-type reaction" *Takizawa, S.u; Hirata, S.; *Murai, K.;
Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2014, 12 (31), pp.5827-5830. DOI:10.1039/C4OB00925H |
滝澤 忍 | |
|
"Selective Formation of Trans/threo/cis and Cis/threo/cis Bis-tetrahydrofurans from the Same Diene Diols" *Fujioka, H.; Oki, T.; Hayashi,
T.; Yamakawa, M.; Kurachi, T.; Nakahara, K.; Maehata, R.;
Hamada, T.; Murai, K.; Kita, Y. Heterocycles 2014, 88 (2), pp.1323-1336. DOI:10.3987/COM-13-S(S)102 |
Kita, Y. | |
|
"Reactivity of the ester group attached isoxazoline, benzisoxazole, and isoxazole: a facial preparation of 3-acyl-substituted these heterocycles" Murai, K.; Miyazaki, S.; *Fujioka, H. Tetrahedron Lett. 2012, 53 (29), pp.3746-3749. DOI:10.1016/j.tetlet.2012.05.006 |
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"Asymmetric total synthesis of (-)-stenine and 9a-epi-stenine" *Fujioka, H.; Nakahara, K.; Kotoku, N.; Ohba, Y.; Nagatomi, Y.; Wang, T.-L.; Sawama, Y.; Murai, K.; Hirano, K.; Oki, T.; Wakamatsu, S.; *Kita, Y. Chem. Eur. J. 2012, 18 (43), pp.13861-13870. DOI:10.1002/chem.201200376 |
北泰行 | |
|
"Remarkable effect of CF3CH2OH for the halogen induced oxidative rearrangement reaction of aminals leading to 3,4-dihydroquinazolines" Murai, K.; Shimura, M.; Nagao, R.; Endo, D.; *Fujioka, H. Org. Biomol. Chem. 2013, 11 (16), pp.2648-2651. DOI:10.1039/c3ob40132d |
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"Kinetic Resolution of β-Substituted Olefinic Carboxylic Acids by Asymmetric Bromolactonization" Murai, K.; Matsushita, T.; Nakamura, A.; Hyogo, N.; Nakajima, J.; *Fujioka, H. Org. Lett. 2013, 15 (10), pp.2526-2529. DOI:10.1021/ol401007u |
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"Preparation of THP-Ester-Derived Pyridinium-Type Salts and their Reactions with Various Nucleophiles" *Fujioka, H.; Minamitsuji, Y.; Moriya, T.; Okamoto, K.; Kubo, O.; Matsushita, T.; Murai, K. Chem. Asian J. 2012, 7 (8), pp.1925-1933. |
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"Oxidative Rearrangement of Spiro Cyclobutane Cyclic Aminals: Efficient Construction of Bicyclic Amidines" Murai, K.; Komatsu, H.; Nagao, R.; *Fujioka, H. Org. Lett. 2012, 14 (3), pp.772-775. DOI:10.1021/ol203313n |
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"C3-Symmetric Trisimidazoline Catalysed Enantioselective Bromolactonization of Internal Alkenoic Acids" Murai, K.; Nakamura, A.; Matsushita, T.; Shimura, M.; *Fujioka H. Chem. Eur. J. 2012, 18 (27), pp.8448-8453. DOI:10.1002/chem.201200647 |
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| Reviews / Accounts |
"Recent Progress in Organocatalytic Asymmetric Halocyclization" Murai, K.; *Fujioka, H. Heterocycles 2013, 87 (4), pp.763-805. DOI:10.3987/REV-12-762 |
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| A01 今田 泰嗣 | ||
| Original papers |
"Controlled Physical Gelation of Thermoresponsive Poly(2-propionamidoacrylic acid) Aqueous Solution" *Minagawa, K.; Shiizaki, G.; Arakawa, Y.; Imada, Y.; Tanaka, M. Adv. Mater. Res. 2015, 1110 pp.96-99. |
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"Biomimetic flavin-catalysed reactions for organic synthesis" Iida, H.; Imada, Y.; *Murahashi, S.-I. Org. Biomol. Chem. 2015, 15 (28), pp.7599-7613. DOI:10.1039/C5OB00854A |
飯田拡基 | |
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"Highly Fluorescent Flavins: Rational Molecular Design forQuenching Protection Based on Repulsive and Attractive Controlof Molecular Alignment" Suzuki, H.; Inoue, R.; Kawamorita, S.; Komiya, N.; Imada, Y.; *Naota, T Chem. Eur. J. 2015, 21 (25), pp.9171-9178. DOI:10.1002/chem.201406346 |
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"Flavin-Functionalized Gold Nanoparticles as an Efficient Catalyst for Aerobic Organic Transformations" Imada, Y.; Osaki, M.; Noguchi, M.; Maeda, T.; Fujiki, M.; Kawamorita, S.; Komiya, N.; *Naota, T ChemCatChem 2015, 7 (1), pp.99-106. DOI:0.1002/cctc.201402619 |
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"Ring-expanding Metathesis Oligomerization of Cyclic Nitrones" Imada, Y.; Okita, C.; Maeda, H.; Kishimoto, M.; Sugano, Y.; Kaneshiro, M.; Nishida, Y.; Kawamorita, S.; Komiya, N.; *Naota, T. Eur. J. Org. Chem. 2014, 2014 (26), pp.5670-5674. DOI:10.1002/ejoc.201402859 |
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"Oxidation of sulfides with hydrogen peroxide catalyzed by synthetic flavin adducts with dendritic bis(acylamino)pyridines" *Imada, Y.; Kitagawa, T.; Iwata, S.; Komiya, N.; *Naota, T. Tetrahedron 2014, 70 (2), pp.495-501. DOI:10.1016/j.tet.2013.11.024 |
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"Non-Covalently Dendronized Flavins as Organocatalysts for Aerobic Reduction of Olefins" Imada, Y.; Kugimiya, Y.; Iwata, S.; Komiya, N.; *Naota, T. Tetrahedron 2013, 69 (40), pp.8572-8578. DOI:10.1016/j.tet.2013.07.082 |
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"Aerobic Oxidation of Sulfides with Vitamin B2-derived Organocatalyst" *Imada, Y.; Tonomura, I.; Komiya, N.; *Naota, T. Synlett 2013, 24 (13), pp.1679-1682. DOI:10.1055/s-0033-1339276 |
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"Oxidation of Sulfides with Hydrogen Peroxide Catalyzed by Vitamin B2 Derivatives" *Imada, Y.; Takagishi M.; Komiya, N.; *Naota, T. Synth. Commun. 2013, 43 (22), pp.3064-3071. DOI:10.1080/00397911.2013.767912 |
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"Flavin-catalyzed aerobic oxidation of sulfides in aqueous media" *Imada, Y.; Kitagawa, T.; Wang, H.-K.; Komiya, N; *Naota, T. Tetrahedron Lett. 2013, 54 (7), pp.621-624. DOI:j.tetlet.2012.11.133 |
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| Reviews / Accounts |
"フラビン触媒を用いた酸素酸化システムの開発" *今田泰嗣 化学と工業 2014, 67 (6), pp.480-482. |
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| Conference / Symposium / Lecture |
招待講演 "Organocatalytic Oxidations Catalyzed by Non-covalently Dendronized Flavins" ○*Imada, Y. Advanved Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Flavin-catalyzed photoinduced thioacetalization of aldehydes" ○Arakawa, Y.; Mihara, T.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Visible light-induced α-oxyamination of aldehydes with flavin organocatalysts" ○Tagami, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Facile preparation of flavinium organocatalysts utilizing cation-exchange resins" ○Oonishi, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Nucleophilic addition to nitrones using flow microreactors" ○Arakawa, Y.; Ueta, S.; Minagawa, K.; *Imada, Y. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Flavin Catalyzed α-oxyamination of Aldehydes under Visible Light Irradiation" ○Tagami, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of Facile Method for Preparing Flavinium Organocatalysts" ○Oonishi, T.; Arakawa, Y.; Minagawa, K.; *Imada, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Analysis of Interaction between Diphenhydramine and Human Serum Albumin" Tanaka, M.; ○*Minagawa, K.; Arakawa, Y.; Imada, Y. Asia-Pacific Conference on Engineering & Applied Sciences (APCEAS2015), Osaka (Japan) 2015-08-25～2015-08-27 |
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口頭発表／ポスター発表 "Design of Effective Chemistry Laboratory Class Based on Partnership among High School, University and Graduate School" *○Minagawa, K.; Yasuzawa, M.; Arakawa, Y.; Imada, Y.; Fujita, S. Asia-Pacific Conference on Engineering & Applied Sciences (APCEAS2015), Osaka (Japan) 2015-08-25～2015-08-27 |
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口頭発表／ポスター発表 "Novel preparation method of flavinium organocatalysts" ○Arakawa, Y.; Oonishi, T.; Kohda, T.; Minagawa, K.; *Imada, Y. The 39th Naito Conference on The Chemistry of Organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Flavin Catalysts Captured in Network Polymers" ○Sato, F.; Arakawa, Y.; Minagawa, K.; *Imada, Y. Advanced Molecular Transformations by Organocatalysts 1st International Conference & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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| Patent |
"ジエポキシ化合物の製造方法" 発明者：北尾久平; 今田泰嗣; 荒川幸弘 出願者：株式会社ダイセル; 徳島大学 特願2015-079601 2015-04-08, 2016-05, (国内) |
|
| Media |
"Flavin-Functionalized Gold Nanoparticles as an Efficient Catalyst for Aerobic Organic Transformations" Imada, Y.; Osaki, M.; Noguchi, M.; Maeda, T.; Fujiki, M.; Kawamorita, S.; Komiya, N.; Naota, T. ChemCatChem 2015-01-07 ChemCatChem誌、2015年、第7巻、第1号のカバーピクチャーに選出された |
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| A01 松原 亮介 | ||
| Original papers |
"Synthesis of Furoxans (1,2,5-oxadiazole 2-oxides) from Styrenes and Nitrosonium Tetrafluoroborate in Non-Acidic Media and Mechanistic Study" *R. Matsubara, A. Ando, Y. Saeki, K. Eda, N. Asada, T. Tsutsumi, Y.-S. Shin, M. Hayashi J. Heterocyclic Chem. 2016, in press |
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"Fluorofuroxans: Synthesis and Application as Photo-induced Nitric Oxide Donors" A. Ando, *R. Matsubara, S. Takazawa, T. Shimada, M. Hayashi Asian J. Org. Chem. 2016, in press |
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|
"Concise Synthesis of Asymmetrically 4,5-Disubstituted 9,9-Dimethyl-9H-xanthenes" *R. Matsubara, M. Koide, Y.-S. Shin, T. Shimada, M. Hayashi Synthesis 2015, 47 pp.187-192. |
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"Revisiting the Saito Photochemical Reduction and the Development of a One-Pot Deoxygenation of Alcohols" *R. Matsubara, Y-S. Shin, T. Shimada, M. Hayashi Asian J. Org. Chem. 2014, 3 pp.1054-1057. |
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"Synthesis of Furoxans from Styrenes under Basic or Neutral Conditions" *Matsubara, R.; Saeki, Y.; Li, J.; Eda, K. Synthesis 2013, 45 (11), pp.1524-1528. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of furoxan derivatives and study on their nitric oxide-releasing ability" ○Akihiro Ando, *Ryosuke Matsubara, Saori Takazawa, Toshiyuki Shimada, Masahiko Hayashi Pacifichem (2015 International Chemical Congress of Pacific Basin Societies), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development of the organocatalyst for efficient generation of carbon-centered radical" ○Toshiyuki Shimada, *Ryosuke Matsubara, Masahiko Hayashi Pacifichem (2015 International Chemical Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-15 |
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口頭発表／ポスター発表 "Development of Carbazole-Based Photocatalyst for Alcohol Reduction" ○*R. Matsubara Tateshina Conference on Organic Chemistry, Tateshina (Japan) 2014-11-07～2014-11-09 |
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口頭発表／ポスター発表 "The Development of a Direct Deoxygenation of Alcohols" *Ryosuke Matsubara, ○Toshiyuki Shimada, Yong-Soon Shin, Masahiko Hayashi 第2回 国際会議(兼)第7回 有機触媒シンポジウム, 東京 (日本) 2014-11-21～2014-11-21 |
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口頭発表／ポスター発表 "Study toward Photocatalytic One-Step Reduction of Alcohol" ○*Matsubara, R.; Shin, Y.-S. 12th Tateshina Conference, Tateshina (Japan) 2012-11-09～2012-11-11 |
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招待講演 "Study toward Photocatalytic One-Step Reduction of Alcohol" ○*Matsubara, R. Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-19 |
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| Prize |
"井上リサーチアウォード" Ryosuke Matsubara 2014-02 井上科学振興財団 外部刺激に応答して一酸化窒素を放出するフロキサン化合物の創製 |
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"２０１２年度有機合成化学協会研究企画賞" *Matsubara, R. 2012-12 有機合成化学協会 光エネルギーを用いる有機分子触媒的アルコール還元反応への挑戦 |
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| A01 植田 光洋 | ||
| Original papers |
"
Intramolecular Carbolithiation of 3-Lithioxy-5-Alkenyllithiums
as a Platform for Cyclopentanols and Cyclopentanones
" *Ryu, I.; Yamamura, G.; Minakata, S.; Komatsu, M.; Kubo, H.; Ueda, M. Synlett 2015, 26 pp.2413-2417. |
南方 聖司（大阪大学） |
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"A Construction of 4,4-Spirocyclic γ-Lactams by Tandem Radical Cyclization with Carbon Monoxide" Ueda, M.; Uenoyama, Y.; Terasoma, N.; Doi, S.; Kobayashi, S.; *Ryu, I.; *Murphy, J. A. Beilstein J. Org. Chem. 2013, 9 pp.1340-1345. |
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"Transition-Metal-Free Suzuki-Miyaura Coupling Reaction of Arylpropargylic Bromides with Aryl- and Alkenylboronic Acids" *Ueda, M.; Nishimura, K.; *Ryu, I. Synlett 2013, 24 pp.1683-1686. |
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"A Transition-Metal-Free Cross-Coupling Reaction of Allylic Bromides with Aryl- and Vinylboronic Acids" *Ueda, M.; Nishimura, K.; Kashima, R.; *Ryu, I. Synlett 2012, 23 pp.1085-1089. DOI:10.1055/s-0031-1290656 |
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| Books |
「
化学
」 "注目の論文：不斉ラジカル反応の真の触媒登場" Ueda, M. 化学同人 2015, pp64-65. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Ammonium Chiral Borate Salt Catalyzed Friedel-Crafts Alkylation of Indoles with α,β-Disubstituted Acroleins" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. ISIS-9, Hyogo (Japan) 2014-11-14～2014-11-15 |
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口頭発表／ポスター発表 "Asymmetric Reaction Catalyzed by Ammonium Chiral Borate Salt" ◯Yagyu, Y.; *Uead, M.; Ryu, I. Advanced Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Development of new ion-pairing catalyst based on chiral borate anion" ◯*Ueda, M. The 39th Naito conference on the chemistry of organocatalysts,, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Cyclic Ketone Synthesis by Intramolecular Acylation of Organocobalt with Esters" ◯Ueno, T.; Suyama, Y.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "[2+2] Cycloaddition of aromatic allenes with C60" ◯*Ueda, M.; Sakaguchi, T.; Yoshida, S.; Yasuda, H.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "[2+2] Cycloaddition of coumarin derivatives with fullerene under photo-irradiated conditions" ◯Hayama, M.; *Ueda, M.; Yasuda, H.; Yoshida, S.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis of 1,4-Enynes by Catalyst-Free Coupling Reaction of Alkenylboronic Acids with Secondary Propargylic Acetates" ◯Nakakoji, D.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Friedel-Crafts Alkylation between Indoles and α,β-Disubstituted Acroleins Catalyzed by Chiral Borate Salt" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. Pacifichem 2015, Honolulu (Hawaii) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "The Reaction of Organoboronic Acids with Activated Alkyl Halides" ○*Ueda, M.; Nishimura, K.; Nakakoji, D.; Ryu, I. 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2015-09-26 |
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口頭発表／ポスター発表 "
Asymmetric Reaction Catalyzed
by Ammonium Chiral Borate Salt
" ◯Yagyu, Y.; *Ueda, M.; Ryu, I. 第２回国際会議（兼）第７回有機触媒シンポジウム, 東京都 (日本) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "
Ammonium Chiral Borate Salt
Catalyzed Friedel-Crafts Alkylation of Indoles with α,β-Disubstituted Acroleins
" ◯Yagyu, Y.; *Ueda, M.; Ryu, Ilhyong The Ninth International Symposium on Integrated Synthesis, 淡路市 (日本) 2014-11-14～2015-11-15 |
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招待講演 "Radical Cyclization by Using Photo-Organocatalyst" ◯*Ueda, M. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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| Patent |
"
フラーレン誘導体およびフラーレン誘導体の製造方法
" 発明者：Yasuda, H.; Watanabe, K.; Ryu, I.; Ueda, M. 特願 2014-046930 2014-07-12, 2014-07, (国内) |
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| A01 御前 智則 | ||
| Original papers |
"Organocatalytic 1,4-addition reaction of
2-formyl(thio)esters to vinylketones: an efficient access to acyclic chiral building
blocks with a quaternary carbon stereocenter" Tatsumi, T.; *Misaki, T.; Sugimura, T. Chem. Eur. J. 2015, 21 pp.18971-18974. DOI:10.1002/chem.201504479 |
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"Highly enantioselective and diastereoselective
conjugate addition of 5H-oxazol-4-ones
to 2-chloroacrylonitrile catalyzed by chiral guanidines" *Misaki, T.; Choi, N.-R.; Morita, A.; Sugimura, T. Tetrahedron Lett. 2015, 56 pp.5063-5066. DOI:10.1016/j.tetlet.2015.07.063 |
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|
"Another role of copper in the Simmons–Smith reaction: copper-catalyzed nucleophilic Michael-type cyclopropanation of α,β-unsaturated ketones" Fujii, K.; Misaki, T.; *Sugimura, T. Chem. Lett. 2014, 43 (5), pp.634-636. DOI:10.1246/cl.131193 |
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"Substrate dependent ligand acceleration in enantioselective hydrogenation of (E)-2,3-diarylpropenoic acid on cinchonidine-modified Pd/C" Mameda, T.; Nakai, K.; Misaki. T.; Okamoto, Y.; *Sugimura, T. Catalysis Today 2015, 245 pp.129-133. DOI:10.1016/j.cattod.2014.03.075 |
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"Kinetic and stereochemical analyses of amine-additive effects on the hydrogenation of α-phenylcinnamic acid over cinchonidine-modified Pd/C" Nakai, K.; Misaki, T.; Okamoto, Y.; *Sugimura, T. Bull. Chem. Soc. Jpn 2015, 88 (2), pp.300-302. DOI:10.1246/bcsj.20140292 |
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"Induction period for the enantioselective hydrogenation of α,β-unsaturated acids over a cinchonidine-modified palladium catalyst" Mameda, T.; Misaki, T.; Okamoto, Y.; *Sugimura, T. React. Kinet., Mech. cat. 2015, 114 (1), pp.55-61. DOI:10.1007/s11144-014-0769-0 |
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"1,4-Addition reaction of 5H-oxazol-4-ones to vinyl ketones catalyzed by chiral guanidines" Morita, A.; *Misaki, T.; *Sugimura, T. Tetrahedron Lett. 2015, 56 pp.264-267. DOI:10.1016/j.tetlet.2014.11.079 |
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"1,6-Addition reaction of 5H-oxazol-4-ones to conjugated dienones catalyzed by chiral guanidines" Morita, A.; *Misaki, T.; *Sugimura, T. Chem. Lett. 2014, 43 pp.1826-1828. DOI:10.1246/cl.140713 |
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"Asymmetric Ti-crossed Claisen condensation: application to concise asymmetric total synthesis of alternaric acid" Nagase, R.; Oguni, Y.; Ureshino, S.; Mura, H.; *Misaki, T.; *Tanabe, Y Chem. Commun. 2013, 49 pp.7001-7003. DOI:10.1039/c3cc43180k |
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"1,4-Addition Reaction of 5H-Oxazol-4-ones to Allnic Esters and Ketones Catalyzed by Chiral Guanidines" Jin, N.; *Misaki, T.; *Sugimura, T. Chem. Lett. 2013, 42 (8), pp.894-896. DOI:10.1246/cl.130295 |
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"Anomalous Ligand Acceleration on Cinchona-Modified Pd/C During Asymmetric Hydrogenation of Properly Substituted Phenylcinnamic Acid" Ogawa, H.; Mameda, T.; Misaki, T.; Okamoto, Y.; *Sugimura, T. Chem. Lett. 2013, 42 (8), pp.813-815. DOI:10.1246/cl.130245 |
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"Stereochemical Study on Oxygen-Directed Olefin Oxidation and Subsequent Oxygen Cyclization; Difference between Peracid and Metal Oxide-Catalyzed Hydroperoxide in Oxidation" Inoue, A.; Misaki, T.; Fujita, M.; Okuyama, T.; *Sugimura, T. Tetrahedron: Asymmetry 2013, 24 (13-14), pp.833-837. |
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"Hydrogenation of 5-Alkylidene-2,4-Thiazolidiones on Pd/C Catalysts Under Mild Conditions: An Alternative Synthesis Route to Pioglitazone" *Sugimura, T.; Oie, K.; Misaki, T.; Okamoto, Y.; Tanaka, K.; Mori, H. Catal. Lett. 2013, 143 (5), pp.495-500. DOI:10.1007/s10562-013-0976-8 |
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"Mitsunobu Reaction with 4-(Diphenylphosphino)benzoic Acid: A Separation-Friendly Bifunctional Reagent that Serves as Both a Reductant and a Pronucleophile" Muramoto, N.; Yoshino, K.; Misaki, T.; *Sugimura, T. Synthesis 2013, 45 (7), pp.931-935. DOI:10.1055/s-0032-1318327 |
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"Chiral Guanidine-Catalyzed 1,4-Addition Reaction of 5H-Oxazol-4-ones to Alkynones" *Misaki, T.;Jin, N.; Kawano, K.; *Sugimura, T. Chem. Lett. 2012, 41 (12), pp.1675-1677. DOI:10.1246/cl.2012.1675 |
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"Efficient Simmons-Smith Cyclopropanation with Zn/Cu and CH2I2" Fujii, K.; Shiine, K.; Misaki, T.; *Sugimura, T. Applied Organometallic Chemistry 2013, 27 (2), pp.69-72. |
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"Preparation of Pd/C Designed for Chiral Modified Catalyst: Comparison with Pd/TiO2 in Enantioselective Hydrogenation of α-Phenylcinnamic Acid" Kubota, T.; Ogawa, H.; Okamoto, Y.; Misaki, T.; *Sugimura, T. Applied Catalysis A: General 2012, 437-438 (26 September), pp.18-23. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Development of C-C bond forming reaction involving
chiral quaternary carbon atom construction using bifunctional organocatalysts" ○*Misaki, T. 2015 International Chemical Congress of Pacific Basin Societies, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development and applycation of conjugate addition of
β-carbonylesters to vinyl ketones involving a chiral quaternary carbon atom
construction catalyzed by organocatalysts" ○Tatumi, T.; *Misaki, T.; Sugimura, T. The 39th Naito conference on the chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Development of Conjugate Additions to Vinylketones and Dienones Using Chiral Guanidine Catalyst Bearing a Hydroxy Group" ○Morita, A.; *Misaki, T.; *Sugimura, T. Advanced Molecular Transformations by Organocatalysts 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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招待講演 "Asymmetric C-C Bond Forming Reactions of 5H-Oxazol-4-ones Catalyzed by Hydroxy Group Combined Guanidines" ○*Misaki, T. 第1回 国際会議（兼）第6回 有機触媒シンポジウム, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Catalytic Enantioselective C-C Bond Forming Reactions of 5H-Oxazol-4-ones Using New Chiral Guanidines" ○*Misaki, T. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| A01 矢内 光 | ||
| Original papers |
"Synthesis of 1,2,3,4-tetrasubstituted naphthalenes through cascade reaction triggered by silyl acetal activation" *Yanai, H.; Ishii, N.; Matsumoto, T. Chem. Commun. 2016, pp.accepted. DOI:10.1039/C6CC03510H |
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"Concise total synthesis of elliptoxanthone A by utilizing aromatic oxy-Cope
rearrangement for efficient C-isoprenylation of xanthone skeleton " Fujimoto, Y.: Yanai, H.; *Matsumoto, T. Synlett 2016, pp.accepted. |
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"A new approach to axially chiral biaryls via the atrop-diastereoselective
formation of medium-sized lactone bridge " Yuyama, D.; Sugiyama, N.; Maeda, T.; Dobashi, Y.; Yokojima, S.; Fujimoto, Y.; Yanai, H.; *Matsumoto, T. Synlett 2016, pp.accepted. |
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"Sequential Mukaiyama–Michael reaction induced by carbon acids" *Yanai, H.; Kobayashi, O.; Takada, K.; Isono, T.; Satoh, T.; *Matsumoto, T. Chem. Commun. 2016, 52 (16), pp.3280-3283. DOI:10.1039/C5CC10115H |
佐藤敏文 | |
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"An efficient isoprenylation of xanthones at the C1 position by utilizing anion-accelerated aromatic oxy-Cope rearrangement" Fujimoto, Y.; Watabe, Y.; Yanai, H.; Taguchi, T.; *Matsumoto, T. Synlett 2016, 27 (6), pp.848-853. DOI:10.1055/s-0035-1561326 |
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"Chemoselective two-directional reaction of bi-functionalized substrates: formal ketal-selective Mukaiyama aldol type reaction" *Yanai, H.; Sasaki, Y.; Yamamoto, Y.; *Matsumoto, T. Synlett 2015, 26 (17), pp.2457-2461. DOI:10.1055/s-0035-1560478 |
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"Chemistry of fluorinated carbon acids: synthesis, physicochemical properties, and catalysis" *Yanai, H. Chem. Pharm. Bull. 2015, 63 (9), pp.649-662. DOI:10.1248/cpb.c15-00487 |
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"A rapid entry to diverse γ-ylidenetetronate derivatives through regioselective bromination of tetronic acid derived γ-lactones and metal-catalyzed postfunctionalization" Chopin, N.; Yanai, H.; Iikawa, S.; Pilet, G.; *Bouillon, J.-P.; *Médebielle, M. Eur. J. Org. Chem. 2015, (28), pp.6259-6269. DOI:10.1002/ejoc.201500663 |
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"Synthesis of (Z)-fluoroallyl azides through aluminium-mediated defluorinative functionalization reaction" Sato, A.; *Yanai, H.; Suzuki, D.; Okada, M.; *Taguchi, T. Tetrahedron Lett. 2015, 56 (7), pp.925-929. DOI:10.1016/j.tetlet.2014.12.128 |
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"Gas-phase acidity of 1,1-bis(trifluoromethanesulfonyl)propane derivatives and related compounds. Experimental and theoretical studies" Zhang, M.; Sonoda, T.; Shiota, Y.; *Mishima, M.; Yanai, H.; Fujita, M.; Taguchi, T. J. Phys. Org. Chem. 2015, 28 (3), pp.181-186. DOI:10.1002/poc.3304 |
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"1,1-Bis(triflyl)alkadienes: easy-to-handle building blocks for strongly acidic carbon acids" *Yanai, H.; Egawa, S.; Yamada, K.; Ono, J.; Aoki, M.; Matsumoto, T.; Taguchi, T. Asian J. Org. Chem. 2014, 3 (4), pp.556-563. DOI:10.1002/ajoc.201402010 |
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"Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities" *Yanai, H.; Fujita, M.; Takahashi, A.; Zhang, M.; Mishima, M.; Kotani, A.; Matsumoto, T.; Taguchi, T. Molecules 2013, 18 (12), pp.15531-15540. DOI:10.3390/molecules181215531 |
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"Novel One-Pot Synthesis of Xanthones via Sequential Fluoride Ion-Promoted Fries-Type Rearrangement/Nucleophilic Aromatic Substitution" Fujimoto, Y.; Itakura, R.; Hoshi, H.; Yanai, H.; Ando, Y.; Suzuki, K.; *Matsumoto, T. Synlett 2013, 24 (19), pp.2575-2580. DOI:10.1055/s-0033-1339881 |
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"Organic Acid-Catalysis in Reactions of Lactones with Silicon Enolates
" *Yanai, H.; Ishii, N.; Matsumoto, T.; Taguchi, T. Asian J. Org. Chem. 2013, 2 (11), pp.989-996. DOI:10.1002/ajoc.201300157 |
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"2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: Structural Behaviour and Availability as Bis(triflyl)ethylating Reagents" *Yanai, H.; Takahashi, Y.; Fukaya, H.; Dobashi, Y.; Matsumoto, T. Chem. Commun. 2013, 49 (86), pp.10091-10093. DOI:10.1039/C3CC46171H |
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"Reductive Alkylation of Bis(triflyl)methane through Self-promoting Formation of Easily Isolable 1,1-Bis(triflyl)alkenes" *Yanai, H.; Egawa, S.; Taguchi, T. Tetrahedron Lett. 2013, 54 (17), pp.2160-2163. DOI:10.1016/j.tetlet.2013.02.039 |
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"Synthesis, Characterization, and Applications of Zwitterions Containing Carbanion Moiety" *Yanai, H.; Yoshino, T.; Fujita, M.; Fukaya, H.; Kotani, A.; Kusu, F.; Taguchi, T. Angew. Chem. Int. Ed. 2013, 52 (5), pp.1560-1563. DOI:10.1002/anie.201208809 |
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"Organic Acid Induced Olefination Reaction of Lactones" *Yanai, H.; Taguchi, T. Chem. Commun. 2012, 48 (71), pp.8967-8969. DOI:10.1039/C2CC33606E |
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"Four Component Reaction of Aldehydes, Isocyanides, Me3SiN3, and Aliphatic Alcohols Catalyzed by Indium Triflate" *Yanai, H.; Sakiyama, T.; Oguchi, T.; Taguchi, T. Tetrahedron Lett. 2012, 53 (25), pp.3161-3164. DOI:10.1016/j.tetlet.2012.04.046 |
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| Books |
「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "3-ベンジル-2-ブチル-2-(ジフルオロメチル)-2,3-ジヒドロベンゾ[d]オキサゾール" 矢内 光 三共出版 (東京) 2015, pp220-223. ISBN:978-4-7827-0727-2 |
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「フッ素化学入門2015」 独立行政法人 日本学術振興会・フッ素化学第155委員会 "1-{(tert-ブチルジフェニルシリル)オキシ}-4,4-ジフルオロヘキサ-5-エン-3-オール" 矢内 光 三共出版 (東京) 2015, pp191-193. ISBN:978-4-7827-0727-2 |
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「Green Synthetic Approaches for Biologically Relevant Heterocycles」 Brahmachari, G. "Green and Catalytic Methods for γ-Lactone Synthesis" Yanai, H. Elsevier (Amsterdam) 2014, pp257-289. ISBN:978-0-128-00070-0 |
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| Reviews / Accounts |
"Synthesis of superacidic carbon acid and its derivatives" *Yanai, H.; Taguchi. T. J. Fluorine Chem. 2015, 127 pp.108-119. DOI:10.1016/j.jfluchem.2014.11.006 |
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"ビス（トリフリル）メチル基をもつ強酸性炭素酸の合成と触媒としての応用" *矢内 光, 田口武夫 J. Synth. Org. Chem. Jpn 2014, 72 (2), pp.158-170. DOI:10.5059/yukigoseikyokaishi.72.158 |
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| Conference / Symposium / Lecture |
招待講演 "Chemistry of Superacidic Carbon Acids: Synthesis, Properties and Applications" *Yanai, H. Departmental Seminar at Instituto de Química Orgánica General, CSIC, Madrid (Spain) 2015-09-03～2015-09-03 |
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口頭発表／ポスター発表 "Development of Fluorinated Zwitterion Catalysts" *Yanai, H. 9th French-Japanese Seminar on Fluorine, Nice (France) 2015-08-30～2015-09-01 |
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口頭発表／ポスター発表 "Sequential Mukaiyama-Michael Reaction Induced by Fluorinated Carbon Acid" *Yanai, H.; Kobayashi, O.; Médebielle, M.; Matsumoto1, T. 21st International Symposium on Fluorine Chemistry 2015年8月23日, Como (Italy) 2015-08-23～2015-10-28 |
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口頭発表／ポスター発表 "Synthesis of Fluoroalkene Dipeptide Isosteres Directing to Structural Diversity of Side Chain" *○Yanai, H.; Ando, H.; Tsutsumi, Y.; Matsumoto, T.; Taguchi, T. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-14～2014-12-17 |
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口頭発表／ポスター発表 "Chemoselective Mukaiyama Aldol Type Reactions Catalyzed by Fluorinated Zwitterion" *○Yanai, H.; Sasaki, Y.; Ishii, N.; Matsumoto, T. 4th International Symposium on Organofluorine Compounds in Biomedical, Organic Materials and Agriculture Sciences “Bordeaux Fluorine Days”, Bordeaux (France) 2014-07-06～2014-07-10 |
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招待講演 "Highly Stabilized Carbanions by Fluorinated Substituents" *○Yanai. H. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-12-30 |
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招待講演 "Carbon Acid –Synthesis, Properties, and Catalysis–" ○*Yanai, H. Departmental Seminar at Université de Rouen, Rouen (France) 2013-11-29～2013-11-29 |
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招待講演 "Chemistry and Applications of Fluorinated Carbon Acids" ○*Yanai, H. Departmental Seminar at Université Claude Bernard Lyon 1, Lyon (France) 2013-11-07～2013-11-07 |
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口頭発表／ポスター発表 "Stereoelectronic Effects in 2-Ammonioethan-1-ides: Experimental and Theoretical Analyses" ○*Yanai, H.; Takahashi, Y.; Fukaya, H.; Dobashi, Y. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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口頭発表／ポスター発表 "Synthesis and Catalysis of Fluorinated Organic Brønsted Acids" ○*Yanai, H.; Yoshino, T.; Ishii, N.; Taguchi, T. 17th European Symposium on Fluorine Chemistry, Paris (France) 2013-07-21～2013-07-25 |
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招待講演 "Strong Organic Acids Containig Fluorine; Synthesis, Structure, and Catalysis" ○*Yanai, H.; Taguchi, T. 4th Japan-Korea-China Joint Seminar on Fluorine Chemistry, Nagoya (Japan) 2013-04-12～2013-04-12 |
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口頭発表／ポスター発表 "Synthesis of Multiple Carbon Acids And Their Catalyst Activity in Organic Reactions" ○*Yanai, H.; Taguchi, T. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-27 |
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| Prize |
"日本薬学会 奨励賞" *矢内 光 2015-03 日本薬学会 |
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" 三菱ガス化学 研究企画賞" *矢内 光 2013-12 有機合成化学協会 |
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| Media |
"Sequential Mukaiyama–Michael reaction induced
by carbon acids" Yanai, H.; Kobayashi, O.; Takada, K.; Isono, T.; Satoh, T.; Matsumoto, T. Chem. Commun. 2016-02-18 当該研究論文の内容が，掲載号（52巻19号）の表紙を飾った。 |
佐藤敏文 |
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"フッ素の特異性に着目した有機フッ素化合物の新しい合成手法の開発と利用" 矢内 光 薬事日報 2015-03-20 研究成果の紹介記事 |
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"＜論文紹介＞ 1,1-ビス（トリフリル）アルカジエンを合成ブロックとする簡便な強酸性炭素酸の合成法｜東京薬科大・矢内助教らの論文をChemistry Viewsが紹介" Yanai, H. ワイリー・サイエンスカフェ 2014-04-28 |
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"Building Strong Carbon Acids from 1,1-Bis(triflyl)alkadienes" Yanai, H.; Egawa, S.; Yamada, K.; Ono, J.; Aoki, M.; Matsumoto, T.; Taguchi, T. ChemistryViews 2014-04-27 有機分子触媒を設計する際の酸性官能基として，我々が提案している炭素酸構造の新規かつ簡便な構築法を見出した。また、得られた炭素酸が，触媒として十分な活性を持っていることを実証した。 |
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"Switching Catalysts for Choosing Products" Yanai, H.; Ishii, N.; Matsumoto, T.; Taguchi, T. ChemistryViews 2013-11-21 独自に開発した二種の有機分子触媒を駆使することで，同一の反応基質から，異なった生成物がそれぞれ選択的に得られることを見出した。 |
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| A01 坂田 健 | ||
| Original papers |
"Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage" Nakajima,K.; Nojima, S.; *Sakata,K.; *Nishibayashi, Y. ChemCatChem. 2016, 8 (6), pp.1028-1032. DOI:10.1002/cctc.201600037 |
西林仁昭 |
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"Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Cyanamides" Hashimoto, T.; Ishii, S.; Yano, R.; Miura, H.; Sakata, K.; *Takeuchi, R. Adv. Synth. Catal. 2015, 357 (18), pp.3901-3916. DOI:10.1002/adsc.201500637 |
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"Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis" Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2015, 54 (34), pp.9944-9947. DOI:10.1002/anie.201503704 |
金井求 | |
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"Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes" Nakajima, K; Takata, S.; *Sakata,K.; *Nishibayashi, Y. Angew. Chem. Int. Ed. 2015, 54 (26), pp.7597-7601. DOI:10.1002/anie.201502531 |
西林仁昭 | |
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"Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C-H Alkenylation/Annulation Sequence " Ikemoto, H.; Yoshino, T.; Sakata, K.; *Matsunaga, S.; *Kanai, M. J. Am. Chem. Soc. 2014, 136 (14), pp.5424-5431. DOI:10.1021/ja5008432 |
金井求 | |
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"Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms using Snap-Shot Structural Analysis" Azuma, T.; Kobayashi, Y.; Sakata, K.; Sasamori, T.; Tokitoh, N.; *Takemoto, Y. J. Org. Chem. 2014, 79 (4), pp.1805-1817. DOI: 10.1021/jo4028775 |
竹本佳司 | |
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"Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexes as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents" Yuki, M.; *Sakata, K.; Hirao, Y.; Nonoyama,N.; Nakajima, K.; *Nishibayashi, Y. J. Am. Chem. Soc. 2015, 137 (12), pp.4173-4182. DOI:10.1021/jacs.5b00584 |
西林仁昭 | |
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"Quantum Chemical Study of the Reaction of 3-(Trimethylsilyl)cyclohexa-1,4-dienes with B(C6F5)3" *Sakata, K.; Fujimoto, H. Organometallics 2015, 34 (1), pp.236-241. DOI:10.1021/om501095e |
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"Qauntum Chemical Study of B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group" *Sakata, K.; Fujimoto, H. J. Org. Chem. 2013, 78 (24), pp.12505-12512. DOI:10.1021/jo402195x |
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"Qauntum Chemical Study of Diels-Alder Reactions Catalyzed by Lewis Acid Activated Oxazaborolidines" *Sakata, K.; Fujimoto, H. J. Org. Chem. 2013, 78 (7), pp.3095-3103. DOI:10.1021/jo400066h |
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"Ruthenium-Triggered Ring-Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal-AllenylideneIntermediates" Miyake, Y.; Endo, S.; Moriyama, T.; *Sakata, K.; *Nishibayashi, Y. Angew. Chem. Int. Ed. 2013, 52 (6), pp.1758-1762. DOI:10.1002/anie.201207801 |
三宅由寛 | |
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"Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Nitriles" Onodera, G.; Shimizu, Y.; Kimura, J.; Kobayashi, J.; Ebihara, Y.; Kondo, K.; Sakata, K.; *Takeuchi, R. J. Am. Chem. Soc. 2012, 134 (25), pp.10515-10531. DOI:10.1021/ja3028394 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 " DFT Study of Cp*CoIII Catalyzed C-H Allylation with Allylic Alcohols " Sakata,K.; Suzuki,Y.; Sun,B.; Yoshino, T.; Matsunaga,S.; Kanai, M.18th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS), Sitges (Barcelona) (Spain) 2015-06-28～2016-07-02 |
金井求 |
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口頭発表／ポスター発表 "Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Nitriles" ◯*Takeuchi, R.; Onodera, G.; Hashimoto, T.; Shimizu, Y.; Kimura, J.; Kobayashi, J.; Ebihara, Y.; Kondo, K.; Sakata, K. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), 札幌 (日本) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group: A DFT Study" ○*Sakata, K. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), 札幌 (日本) 2014-07-13～2015-07-18 |
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口頭発表／ポスター発表 "Catalytic activity of Lewis acid activated Oxazaborolidines in Diels-Alder Reactions: A DFT study" *Sakata, K. 1st International Conference and 6th symposium on Organocatalysis, 大津 (日本) 2013-05-27～2013-05-28 |
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招待講演 "Quantum Chemical Study on Roles of Lewis Acids and Bases in Organic Reactions" Sakata, K. CBC seminar at Nanyang Technological University, Singapore (Singapore) 2012-10-03～2012-10-03 |
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招待講演 "Quantum chemical study of Diels-Alder reactions catalyzed by Lewis acid activated oxazaborolidines" Sakata, K. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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| A01 田中 富士枝 | ||
| Original papers |
"Catalytic asymmetric hetero-Diels-Alder reactions of enones with isatins to access functionalized spirooxindole tetrahydropyrans: Scope, derivatization, and discovery of bioactives." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; *Tanaka, F. Org. Biomol. Chem. 2016, 14 pp.1777-1783. DOI:10.1039/c5ob02393a |
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"Direct synthesis of C-glycosides from unprotected 2-N-acyl-aldohexoses via aldol condensation-oxa-Michael reactions with unactivated ketones." Johnson, S.; *Tanaka, F. Org. Biomol. Chem. 2016, 14 pp.259-264. DOI:10.1039/c5ob02094h |
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"Reaction-based mechanistic investigations of asymmetric hetero-Diels-Alder reactions of enones with isatins catalyzed by amine-based three-component catalyst systems." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; *Tanaka, F. Asian J. Org. Chem. 2016, 5 pp.153-161. DOI:10.1002/ajoc.201500412 |
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"Aldol reactions of ketone donors with aryl trifluoromethyl ketone acceptors catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) for concise access to aryl- and trifluoromethyl-substituted tertiary alcohols." Zhang, D.; *Tanaka, F. Adv. Synth. Catal. 2015, 357 pp.3458-3462. DOI:10.1002/adsc.201500497 |
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"Aldol reactions of 1,2-diketones catalyzed by amines to afford furanose derivatives" Jithender, E.; Katsuyama, I.; Zhang, D.; Johnson, S.; *Tanaka, F. Tetrahedron Lett. 2015, 56 pp.735-738. DOI:10.1016/j.tetlet.2014.12.094 |
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"Reactions of pyruvates: organocatalytic synthesis of functionalized dihydropyrans in one pot and further transformations to functionalized carbocycles and heterocycles" Chouthaiwale, P. V.; *Tanaka, F. Chem. Commun. 2014, 50 pp.14881-14884. DOI:110.1002/c4cc06035k |
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"One-pot synthesis of polysubstituted 3-acylpyrroles by cooperative catalysis" Cui, H.-L.; *Tanaka, F. Org. Biomol. Chem. 2014, 12 pp.5822-5826. DOI:110.1002/c4ob01019a |
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"Synthesis of furanose spirooxindoles via 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed aldol reactions of a pyruvic aldehyde derivative" Zhang, D.; Johnson, S.; Cui, H.-L.; *Tanaka, F. Asian J. Org. Chem. 2014, 3 pp.391-394. DOI:10.1002/ajoc.201400016 |
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"Fluorogenic probes for aldol reactions: Tuning of fluorescence using π-conjugation systems" Katsuyama, I.; Chouthaiwale, P. V.; Akama, H.; Cui, H.-L.; *Tanaka, F. Tetrahedron Lett. 2014, 55 (1), pp.74-78. DOI:10.1016/j.tetlet.2013.10.122 |
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"Catalytic enantioselective formal hetero-Diels-Alder reactions of enones with isatins to give spirooxindole tetrahydropyranones" Cui, H.-L.; *Tanaka, F. Chem. Eur. J. 2013, 19 (20), pp.6213-6216. DOI:10.1002/chem.201300595 |
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"Substituent-dependent reactivity in aldehyde transformations: 4-(phenylethynyl)benzaldehydes versus simple benzaldehydes
" Katsuyama, I.; Chouthaiwale, P. V.; Cui, H.-L.; Ito, Y.; Sando, A.; Tokiwa, H.; *Tanaka, F. Tetrahedron 2013, 69 (20), pp.4098-4104. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of iminosugar C-glycosides via a Mannich reaction-aminocyclization route" ○Maram, L.; *Tanaka, F. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Catalytic enantioselective hetero-Diels-Alder reactions of enones with aryl trifluoromethyl ketones to give trifluoromethyl-substituted tetrahydropyranones" ○Zhang, D.; *Tanaka, F. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Construction of aryl- and trifluoromethyl-substituted tertiary alcohols via aldol reactions catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)" ○Zhang, D.; *Tanaka, F. ISACS19: Challenges in Organic Chemistry, Irvine (USA) 2016-03-20～2016-03-23 |
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口頭発表／ポスター発表 "DBU-catalyzed regioselective aldol reactions to synthesize functionalized molecules with tetrasubstituted carbon centers" ○Zhang, D.; *Tanaka, F. The 38th Naito Conference The Chemistry of Organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "β-Proline-catalyzed reactions of pyruvates to synthesize functionalized molecules" ○Chouthaiwale, P. V.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Synthesis of spirooxindole furanose derivatives via DBU-catalyzed aldol reactions" ○Zhang, D.; Johnson, S.; Cui, H.; *Tanaka, F. The 14th Belgian Organic Synthesis Symposium, Louvain-la-Neuve (Belgium) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Asymmetric formal oxa-Diels Alder reaction catalyzed by amine-based catalysts affording functionalized spirooxindole tetrahydropyrans" ○Cui, H.-L.; *Tanaka, F. The 14th Belgian Organic Synthesis Symposium, Louvain-la-Neuve (Belgium) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Catalytic enantioselective formal hetero-Diels-Alder reactions of enoneswith isatins to give spirooxindole tetrahydropyranones" ○Cui, H.-L.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Amino acid-catalyzed reactions of pyruvates: One-pot aldol condensation-Michael addition-cyclization sequence" ○Chouthaiwale, P. V.; *Tanaka, F. Advanced Molecular Transformations by Organocatalysts 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Amine-catalyzed asymmetric construction of quaternary carbon centers" ○Cui, H.-L.; *Tanaka, F. The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Amino acid-catalyzed reactions of pyruvates: One-pot aldol condensation-Michael addition-cyclization sequence" ○Chouthaiwale, P. V.; *Tanaka, F. The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Enamine-based catalysis: Synthesis of amino acids and sugars" ○*Tanaka, F. The Second Asian Chemical Biology Conference (ACBC2012), Okinawa (Japan) 2012-07-04～2012-07-06 |
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| Patent |
"4-Substituted pyridine-2,6-dicarboxylic acid derivatives and method of preparing same" 発明者：Chouthaiwale, P. V.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2015/004588 2015-09-09, Publication No. WO 2016038890 A1（特許出願中） 2016-03, (国外) |
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"Process for producing dihydro-2H-pyran derivatives" 発明者：Chouthaiwale, P. V.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2013/0784249 2013-10-10, Publication No. WO 2014/058078 A1 （特許出願中） 2014-04, (国外) |
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"Novel spirooxindole derivative and process for producing the same" 発明者：Cui, H.-L.; Tanaka, F. 出願者：Okinawa Institute of Science and Technology School Corporation PCT/JP2013/077682 2013-10-04, Publication No. WO 2014/058035 A1; US Patent No. 9,309,261 2016-04-12, (国外) |
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| Media |
"Inside Cover: Reaction-based mechanistic investigations of asymmetric hetero-Diels-Alder reactions of enones with isatins catalyzed by amine-based three-component catalyst systems." Cui, H.-L.; Chouthaiwale, P. V.; Yin, F.; Tanaka, F. Asian Journal of Organic Chemistry 2015-12-12 論文 Asian Journal of Organic Chemistry, 5, 153-161 (2016), doi: 10.1002/ajoc.201500412 についての Inside Cover. Asian Journal of Organic Chemistry, 5, 2 (2016), doi: 10.1002/ajoc.201500503. |
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| A01 飯田拡基 | ||
| Original papers |
"Allosteric Regulation of Unidirectional Spring-Like Motion of Double-Stranded Helicates" Y. Suzuki, T. Nakamura, H. Iida, N. Ousaka, E. Yashima* J. Am. Chem. Soc. 2016, 138 (14), pp.4852-4859. DOI:10.1021/jacs.6b00787 |
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"Helical Poly(phenylacetylene)s Bearing Chiral and Achiral Imidazolidinone-Based Pendants that Catalyze Asymmetric Reaction due to Catalytically Active Achiral Pendants Assisted by Macromolecular Helicity" Takata, L. M. S.; *Iida, H.; Shimomura, K.; Hayashi, K.; dos Santos, A. A.; *Yashima, E. Macromol. Rapid Commun. 2015, 36 (23), pp.2047-2054. DOI:10.1002/marc.201500456 |
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"Enantioseparation on Riboflavin Derivatives Chemically Bonded to Silica Gel as Chiral Stationary Phases for HPLC" Kumano, D.; Iwahana, S.; Iida, H.; Shen, C.; Crassous, J.; *Yashima, E. Chirality 2015, 27 (8), pp.507-517. DOI:10.1002/chir.22452 |
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"Chirality- and Sequence-Selective Successive Self-Sorting via Specific Homo- and Complementary-Duplex Formations" Makiguchi, W.; Tanabe, J.; Yamada, H.; Iida, H.; Taura, D.; Ousaka, N.; *Yashima, E. Nature Commun. 2015, pp.6:7236. DOI:10.1038/ncomms8236 |
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"Homo-Double Helix Formation of an Optically Active Conjugated Polymer Bearing Carboxy Groups and Amplification of the Helicity upon Complexation with Achiral and Chiral Amines" Makiguchi, W.; Kobayashi, S.; Furukawa, K.; Iida, H.; Furusho, Y.; *Yashima, E. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 pp.990-999. DOI:10.1002/pola.27527 |
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"Flavin-Catalyzed Aerobic Oxidation of Sulfides and Thiols with Formic Acid/Triethylamine" *Murahashi, S.-I.; Zhang, D.; Iida, H.; Miyawaki, T.; Uenaka, M.; Murano, K.; Meguro, K. Chem. Commun. 2014, 50 (71), pp.10295-10298. |
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"Synthesis and Chiral Recognition Ability of Helical Polyacetylenes Bearing Helicene Pendants" Anger, E.; Iida, H.; Yamaguchi, T.; Hayashi, K.; Kumano, D.; *Crassous, J.; Vanthuyne, N.; Roussel, C.; *Yashima, E. Polym. Chem. 2014, 5 (17), pp.4909-4914. |
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"Absolute Stereochemistry of a 4 a-Hydroxyriboflavin Analogue of the Key Intermediate of the FAD-Monooxygenase Cycle" Iwahana, S.; Iida, H.; *Yashima, E.; Pescitelli, G.; *Di Bari, L.; Petrovic, A. G.; *Berova, N. Chem. Eur. J. 2014, 20 (15), pp.4386-4395. DOI:10.1002/chem.201304393 |
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"Riboflavin-Based Fluorogenic Sensor for Chemo- and Enantioselective Detection of Amine Vapors" Iida, H.; Miki, M.; Iwahana, S.; *Yashima, E. Chem. Eur. J. 2014, 20 (15), pp.4257-4262. DOI:10.1002/chem.201400234 |
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| Reviews / Accounts |
"Biomimetic flavin-catalysed reactions for organic synthesis" Iida, H.; Imada, Y.; *Murahashi, S.-I. Org. Biomol. Chem. 2015, 13 pp.7599-7613. DOI:10.1039/C5OB00854A |
Imada, Y. |
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of a Novel Optically Active Polymer Containing a π-Conjugated Riboflavin-Dimer Unit as the Main-Chain and Its Application to Organic Vapor Sensing" ○Nakajima, Y.; Iwahana, S.; Iida, H.; Yashima, E.* Molecular Chirality Asia 2014 (MCA2014), Beijing (China) 2014-10-29～2014-10-31 |
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口頭発表／ポスター発表 "Synthesis and Application of a Novel Optically Active Polymer Containing a π-Conjugated Dimeric Riboflavin Derivative as the Main-Chain" ○Nakajima, Y.; Iwahana, S.; Iida, H.; Yashima, E.* 2014 International Symposium on Integrated Molecular/Materials Science and Engineering (IMSE2014), Nanjing (China) 2014-11-01～2014-11-03 |
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口頭発表／ポスター発表 "Optical Detection of an Organic Vapor with a Dimeric Rboflavin-Containing Redox Active Polymer" Nakajima, Y.; Iwahana, S.; ○Iida, H.; Yashima, E.* IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering, Yokohama (Japan) 2015-10-18～2016-10-22 |
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口頭発表／ポスター発表 "Synthesis of Helical Poly(phenylacetylene)s Bearing Imidazolidinone Pendants and Their Application to Asymmetric Catalysis" ○Shimomura, K.; Takata, L. M. S.; Iida, H.; Hayashi, K.; dos Santos, A. A.; Yashima, E.* The 8th International Forum on Chemistry of Functional Organic Chemicals, Tokyo (Japan) 2015-11-15～2016-11-16 |
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口頭発表／ポスター発表 "Poly(phenylacetylene)s Bearing Chiral and Achiral Imidazolidinone Pendants and Their Application to Asymmetric Organocatalysis" ○Shimomura, K.; Takata, L. M. S.; Iida, H.; Hayashi, K.; dos Santos, A. A.; Yashima, E.* Pacifichem2015, Honolulu (USA) 2015-12-15～2016-12-20 |
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| A01 草間 博之 | ||
| Original papers |
" Total Synthesis of (±)-Integrifolin " Shimomaki, K.; Kusama, H.; *Iwasawa, N.Chem. Eur. J. 2016, pp.in press. DOI:10.1002/chem.201601275 |
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" Total Synthesis of Englerin A Utilizing Intermolecular [3+2] Cycloaddition Reaction of Platinum-Containing Carbonyl Ylide "Kusama, H.; Tazawa, A.; Ishida, K.; *Iwasawa, N. Chem. Asian J. 2016, 11 (1), pp.64-67. DOI:10.1002/asia.201500935 |
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"Total Synthesis of Proposed Structure of Yuremamine and All Diastereomers Utilizing [3+2]-Cycloaddition of Platinum-Containing Azomethine Ylide" Oyama, T.; Uchida, M.; Kusama, H.; Iwasawa, N.* Chem. Asian J. 2015, 10 pp.1850-1853. DOI:10.1002/asia.201500491 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 " Generation and Cycloaddition Reaction of Quinolinium Ylides Using Photochemical Isomerization of Acylsilane to Siloxycarbene "○*Kusama, H.; Ishida, K.; Ichikawa, K.; Sato, J.; Adegawa, M.; Tadami, S.; Mizuno, T.; Iwasawa, N.; Abe, M. The 26th IUPAC Symposium on Photochemistry, Osaka (Japan) 2016-04-04～2016-04-08 |
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口頭発表／ポスター発表 " Intramolecular Formal C-H Insertion Reaction of Photochemically-Generated Siloxycarbenes Leading to Benzofused Heterocycles "Nakada, T.; Ishii, S.; Ishida, K.; Iwasawa, N.; ○*Kusama, H. The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 " [3+2]-Cycloaddition Reaction of Quinolinium Ylides Derived from Photochemically-Generated Siloxycarbenes and Clarification of Substituent Effects by Lase Flash Photolysis "○*Kusama, H.; Ishida, K.; Ichikawa, K.; Sato, J.; Adegawa, M.; Tadami, S.; Mizuno, T.; Iwasawa, N.; Abe, M. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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| A01 小西 玄一 | ||
| Original papers |
"Highly twisted N,N-dialkylamines as a design strategy to tune simple aromatic hydrocarbons as steric environment-sensitive fluorophores" Sasaki, S.; Suzuki, S.; Sameera, W. M. C.; *Morokuma, K.; *Konishi, G. J. Am. Chem. Soc. 2016, 138 (26), pp.8194-8206. DOI:10.1021/jacs.6b03749 |
諸熊奎治（A01班) |
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"Amphiphilic gels of solvatochromic fluorescent poly(2-oxazoline)s containing D–π–A pyrenes" Chen, C.-H.; Niko, Y.; *Konishi, G. RSC Adv. 2016, 6 (49), pp.42962-42970. DOI:10.1039/C6RA06251B |
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"Recent advances in Twisted Intramolecular Charge Transfer (TICT) fluorescence and related phenomena in materials chemistry" Sasaki, S.; *Drummen, G. P. C.; Konishi, G J. Mater. Chem. C 2016, 4 (14), pp.2731-2742. DOI:DOI: 10.1039/C5TC03933A |
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"Bright and photostable push-pull pyrene dye visualizes lipid order variation between plasma and intracellular membranes" Niko, Y.; Didier, P.; Mely, I.; Konishi, G.; *Klymchenko, A. S. Sci. Rep. 2016, 6 pp.18870. DOI:DOI: 10.1038/srep18870 |
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"1-, 3-, 6-, and 8-Tetrasubstituted Asymmetric Pyrene Derivatives with Electron-Donors and -Acceptors: High Photostability and Regioisomer-Specific Photophysical Properties" Niko, Y.; Sasaki, S.; Narushima, K.; Sharma, D. K.; Vacha, M.; *Konishi, G. J. Org. Chem. 2015, 80 (21), pp.10794-10805. DOI:DOI: 10.1021/acs.joc.5b01987 |
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"The effect of regioisomerism on the solid-state fluorescence of bis(piperidyl)anthracenes: structurally simple but bright AIE luminogens" Sasaki, S.; Igawa, K.; *Konishi, G. J. Mater. Chem. C 2015, 3 (23), pp.5940-5950. DOI:10.1039/C5TC00946D |
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"Directional Control of π-Conjugation Enabled by Distortion of the Donor Plane in Diarylaminoanthracenes: A Photophysical Study" Sasaki, S.; Hattori, K.; Igawa, K.; *Konishi, G. J. Phys. Chem. A 2015, 119(20) pp.4898-4906 . DOI:10.1021/acs.jpca.5b03238 |
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"Novel pyrene-based two-photon active fluorescent dye efficiently excited and emitting in the ‘tissue optical window (650–1100 nm)’" Niko, Y.; Sugihara, H.; Moritomo, H.; Suzuki, Y.; Kawamata, J.; *Konishi, G. J. Mater. Chem. B 2015, 3 (2), pp.184-190. DOI:10.1039/C4TB01404A |
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"Disassembly-driven fluorescence turn-on of cross-linked micelles by reductive stimuli in living cells" Niko, Y.; Arntz, Y.; Mely, Y.; Konishi, G.; *Klymchenko, A. S. Chem. Eur. J. 2014, 20 (50), pp.16473-16477. DOI:10.1002/chem.201405040 |
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"Design of donor-acceptor geometry for tuning of excited state polarization: fluorescence solvatochromism of push-pull biphenyls with various torsional restrictions on their aryl-aryl bonds" Sasaki, S.; Niko, Y.; Klymchenko, A. S.; *Konishi, G. Tetrahedron 2014, 70 (41), pp.7551-7559. DOI:10.1016/j.tet.2014.08.002 |
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"Pyrene-based D-π-A dyes that exhibit solvatochromism and high fluorescence brightness in apolar solvents and water" Niko, Y.; Cho, Y.; Kawauchi, S.; *Konishi, G. RSC Adv. 2014, 4 (69), pp.36480-36484. DOI:10.1039/C4RA06282E |
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"Aggregation-induced emission active D-π-A binaphthyl luminophore with dual-mode fluorescence" Sasaki, S.; Niko, Y.; Igawa, K.; *Konishi G. RSC Adv. 2014, 4 (63), pp.33474-33477. DOI:10.1039/C4RA05871B |
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"Design of Weak-Donor Alkyl–Functionalized Push–Pull Pyrene Dyes Exhibiting Enhanced Fluorescence Quantum Yields and Unique On–Off Switching Properties" Niko, Y.; Sasaki, S.; Kawauchi, S.; Tokumaru, K.; *Konishi, G Chem. Asian J. 2014, 9 (7), pp.1797-1807. DOI:10.1002/asia.201402088 |
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| A01 坂倉 彰 | ||
| Original papers |
"Enantioselective Bromocyclization of 2-Gernaylphenols Induced by Chiral Phosphite-Urea Bifunctional Catalysts" Sawamura, Y.; Ogura, Y.; H.; Nakatsuji, H.; *Sakakura, A.; *Ishihara, K. Chem. Commun. 2016, 52 (36), pp.6068-6071. DOI:10.1039/C6CC00229C |
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"Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Imines with Propioloylpyrazoles Induced by Chiral π−Cation Catalysts" Hori, M.; *Sakakura, A.; *Ishihara, K. J. Am. Chem. Soc. 2014, 136 (38), pp.13198-13201. DOI:10.1021/ja508441t |
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"Cooperative Activation with Chiral Nucleophilic Catalysts and N-Haloimides: Enantioselective Iodolactonization of 4-Arylmethyl-4-pentenoic Acids" Nakatsuji, H.; Sawamura, Y.; *Sakakura, A.: *Ishihara, K. Angew. Chem. Int. Ed. 2014, 53 (27), pp.6974-6977. DOI:10.1002/anie.201400946 |
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"Catalytic Enantioselective Inverse Electron Demand Hetero-Diels–Alder Reaction with Allylsilanes" Matsumura, Y.; Suzuki, T.; *Sakakura, A.; *Ishihara, K. Angew. Chem. Int. Ed. 2014, 53 (24), pp.6131-6134. DOI:10.1002/anie.201402934 |
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| Reviews / Accounts |
"Stereoselective Electrophilic Cyclization" *Sakakura, A.; *Ishihara, K Chem. Rec. 2015, DOI:10.1002/tcr.201500005 |
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| Conference / Symposium / Lecture |
招待講演 "Synthetic studies of manzacidins A-C based on diastereoselective hydroxymethylation of chiral nitro compounds" ○*Sakakura, A.; Miyoshi, N.; Kudoh, T. The 2015 International Chemical Congress of Pacific Basin Societies (PAC CHEM™, Pacifichem 2015), Honolulu, Hawaii (USA) 2015-12-15～2015-12-20 |
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招待講演 "A Short Entry to 3,5-Disubstituted Piperazinones Based on Aza-Michael Addition of α-Amino Esters to Nitroalkenes" ○*Sakakura, A.; Kudoh, T.; Isoyama, S.; Kagimoto, S. The 10th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-10), KaoHsiung (Taiwan) 2015-11-02～2015-11-05 |
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| A01 柴富 一孝 | ||
| Original papers |
"Highly stereoselective cyclopropanation of diazo Weinreb amides catalyzed by chiral Ru(II)–Amm–Pheox complexes" Chanthamath, S.; Mandour, H. S. A.; Tong, T. M. T.; Shibatomi, K.; *Iwasa, S. Chem. Commun. 2016, Advance Article DOI:10.1039/C6CC02498J |
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"Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters" *Shibatomi, K.; Kotozaki, M.; Sasaki, N.; Fujisawa, I.; Iwasa, S. Chem. Eur. J. 2015, 21 (40), pp.14095-14098. DOI:10.1002/chem.201502042 |
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"Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C-F bond cleavage" *Shibatomi, K.; Kitahara, K.; Okimi, T.; Abe, Y.; Iwasa, S. Chem. Sci. 2016, 7 (2), pp.1388-1392. DOI:10.1039/C5SC03486H |
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"Ru(II)–Pheox-Catalyzed Asymmetric Intramolecular Cyclopropanation of Electron-Deficient Olefins" Nakagawa, Y.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2015, 17 (11), pp.2792-2795. DOI:10.1021/acs.orglett.5b01201 |
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"Organocatalytic asymmetric Michael addition of α-branched aldehydes to vinyl ketones: synthesis of 5-ketoaldehydes possessing a stereo-controlled all-carbon quaternary stereogenic center" *Yoshida, M.; Ukigai, H.; Shibatomi, K.; Hara, S. Tetrahedron Lett. 2015, 56 (25), pp.3890-3893. DOI:10.1016/j.tetlet.2015.04.107 |
吉田雅紀 准教授 | |
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"Highly Regio- and Stereoselective Synthesis of Alkylidenecyclopropanes via Ru(II)-Pheox Catalyzed Asymmetric Inter- and Intramolecular Cyclopropanation of Allenes" Chanthamath, S.; Chua, H. W.; Kimura, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2014, 16 (12), pp.3408-3411. DOI:10.1021/ol5014944 |
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"Highly Stereoselective Synthesis of Cyclopropylphosphonates Catalyzed by Chiral Ru(Ⅱ)-Pheox Complex" Chanthamath, S.; Ozaki, S.; Shibatomi, K.; *Iwasa, S. Org. Lett. 2014, 16 (11), pp.3012-3015. DOI:10.1021/ol501135p |
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"Highly Enantioselective Synthesis of Halogenated Compounds Utilizing Lewis Acid or Organocatalyst" *Shibatomi, K 有機合成化学協会誌 2014, 72 (3), pp.232-245. DOI:10.5059/yukigoseikyokaishi.72.232 |
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*Shibatomi, K.; Okimi, T.; Abe, Y.; Narayama, A.; Nakamura, N.; Iwasa, S. Beilstein J. Org. Chem. 2014, 10 pp.323-331. DOI:10.3762/bjoc.10.30 |
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"Organocatalytic Enantioselective Diels–Alder Reaction of 4,4,4-Trifluorocrotonaldehyde" *Shibatomi, K.; Kawasaki, Y.; Iwasa, S. J. Fluorine Chem. 2015, 179 pp.77-82. DOI:10.1016/j.jfluchem.2015.05.011 |
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| Reviews / Accounts |
"Catalytic Enantioselective Constructions of Trifluoromethylated Chiral Stereogenic Centers via the Conjugate Addition to CF3-Alkenes: Overview of Current Progress" *Shibatomi, K. Curr. Org. Chem. 2015, 19 (16), pp.1619-1637. |
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| Conference / Symposium / Lecture |
招待講演 "Asymmetric Synthesis of Halogenated Compounds Directed Toward Drug Development" ○*Shibatomi, K. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Williamson ether synthesis at a tertiary stereogenic carbon: a new synthetic route to anti-diabetic drugs" ○Sasaki, N.; Kotozaki, M.; *Shibatomi, K.; Iwasa, S. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Highly enantioselective fluorination of branched aldehydes and its
application for the synthesis of fluorinated biologically active
molecules" ○Kitaharam K.; Okimi, T.; Abe, Y.; *Shibatomi, K.; Iwasa, S. The 3rd International Conference of Global Network for Innovative Technology (IGNITE 2016), Penang (Malaysia) 2016-01-27～2016-01-29 |
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口頭発表／ポスター発表 "Organocatalytic enantioselective fluorination of α,α-disubstituted aldehydes" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Narayama, A.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Favorskii Rearrangement of α-Chloro-β-keto Esters" ○Sasaki, N.; Kotozaki, M.; *Shibatomi, K.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly enantioselective fluorination of α-branched aldehydes with a newly developed chiral primary amine catalyst" ○Kitahara, K.; Okimi, T.; *Shibatomi, K.; Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly Stereoselective Cyclopropanations of Weinreb Amide Derivatives Using Novel Ru(Ⅱ)-Pheox Catalysts" ○H. S. A. Mandour; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Ru(Ⅱ)-Pheox catalyzed carbene transfer reactions of diethyldiazomethylphosphonate" ○Ozaki, S.; Chanthamath, S.; Shibatomi K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly enantioselective synthesis of cyclopropane ring fused γ-lactones via intramolecular carbene transfer reactions" ○Nakagawa. Y.; Chanthamath, S.; Nakayama, N.; Goto, H.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Highly Enantioselective C−H Insertion Reaction of N-Alkyldiazoacetamides by using Ru(Ⅱ)-Pheox Complex" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The International Chemical Congress of Pacific Basin Society 2015 (Pacifichem 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Ru(II)-Pheox Catalyzed Stereoselective Cyclopropanation of Allylsilanes" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Ru(II)-Pheox Catalyzed Enantioselective Si-H Insertion Reaction of Diazoacetates" ○Nakagawa, Y.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Development of New Chiral Primary Amine Catalyst and Its Application to
the Enantioselective Halogenation of α-Branched Aldehydes" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Abe, Y.; Iwasa, S. The 13th International Kyoto Conference On New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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依頼講演 "Organocatalytic Enantioselective Fluorination of α,α-Disubstituted Aldehydes" ○*Shibatomi, K. 21st International Symposium on Fluorine Chemistry, Como (Italy) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "Computational Chemical Analysis for Ru(Ⅱ)-Pheox Catalyzed Enantioselective Intramolecular Cyclopropanation" ○Nakagawa, Y.; Chanthamath, S.; Nakayama, N.; Goto, H.; Shibatomi, K.; *Iwasa, S. 250th ACS National Meeting, Boston (USA) 2015-08-16～2015-08-20 |
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口頭発表／ポスター発表 "Asymmetric synthesis of α-heteroatom-substituted β-keto esters via SN2 substitution of tertiary chlorides" ○*Shibatomi, K.; Kotozaki, M.; Sasaki, N.; Iwasa, S 250th ACS National Meeting, Boston (USA) 2015-08-16～2015-08-20 |
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口頭発表／ポスター発表 "Development of New Chiral Primary Amine Catalyst and Its Use for Enantioselective Fluorination of α-Branched Aldehydes" ○*K. Shibatomi The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Copper(II)-Catalyzed Enantioselective Chlorination of β-Keto Esters and
Subsequent SN2 Displacement of Chiral Tertiary Chlorides Using Oxygen
Nucleophiles" ○Kotozaki, M.; Narayama, A.; Shibatomi, K.; *Iwasa, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Ru(Ⅱ)-Pheox Catalyzed Asymmetric Cyclopropanation of Diethyl Diazomethylphosphonate with Various Alkenes" ○Chanthamath, S.; Ozaki, S.; Shibatomi, K.; *Iwasa, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014), Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Highly Stereoselective Synthesis of trans- and cis-Cinnamic Weinreb Amides via 1,2-Hydride Migration" ○Ozaki, S.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Computational Chemical Analysis for Catalytic Asymmetric Spiral Cyclization and their Application" ○Nakagawa, Y.; Chanthamath, S.; Nakayama, T.; Goto, T.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "A Synthesis of Novel Three Member Ring System via Carbene Transfer Reactions" ○Mandour, H. S. A.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "A Synthesis of Novel Ru(Ⅱ) Complex and its Application for Synthesis of Bioactive Molecules via Carbene Transfer Reactions" ○Chanthamath, S.; Mandour, H. S. A.; Shibatomi, K; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Highly Enantioselective Synthesis of beta-Lactam Derivatives via Catalytic Asymmetric C-H Insertion" ○Doan, T. T. T.; Chanthamath, S.; Shibatomi, K.; *Iwasa, S. International Conference of Global Network for Innovative Technology (IGNITE2014), Penang (Malaysia) 2014-12-15～2014-12-16 |
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口頭発表／ポスター発表 "Primary Amine-Catayzed Enantioselective Fluorination of α-Branched
Aldehydes and Subsequent Stereospecific C-F Bond Cleavage at Tertiary
Carbon" ○*Shibatomi, K.; Kitahara, K.; Okimi, T.; Iwasa, S. 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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依頼講演 "Enantioselective synthesis of chiral fluorinated molecules" ○*Shibatomi, K. The 5th China-Japan-Korea Joint Seminar on Fluorine Chemistry, Shanghai (China) 2014-10-19～2014-10-21 |
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口頭発表／ポスター発表 "Enantioselective Fluorination of α-Branched Aldehydes with a New Primary Amine Catalyst" ○Moriakwa, H.; Abe, Y.; *Shibatomi, K.; Iwasa S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Organocatalytic Enantoselective Fluorination of α-Chloroaldehydes" ○Okimi, T.; Abe, Y.; Narayama, A.; Shibatomi, K.; Iwasa S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Synthesis of 4,4,4-Trifluorocrotonaldehyde and its use in Catalytic Asymmetric Synthesis" ○Kawasaki, Y.; Narayama, A.; Abe, Y.; *Shibatomi, K.; Iwasa, S. International Conference on Fluorine Chemistry 2014, Yokohama (Japan) 2014-05-28～2014-05-30 |
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| A01 白川 誠司 | ||
| Original papers |
"Catalytic asymmetric synthesis of axially chiral 2-amino-1,1'-biaryl compounds by phase-transfer-catalyzed kinetic resolution and desymmetrization" Shirakawa, S.; Wu, X.; Liu, S.; *Maruoka, K. Tetrahedron 2015, in press DOI:doi:10.1016/j.tet.2015.10.074 |
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"Tetraalkylammonium Salts as Hydrogen-Bonding Catalysts " *Shirakawa, S.; Liu, S.; Kaneko, S.; Kumatabara, Y.; Fukuda, A.; Omagari, Y.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (52), pp.15767-15770. DOI:DOI: 10.1002/anie.201508659 |
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"
Phase-Transfer-Catalyzed Asymmetric Desymmetrizations
of Cyclopentanones " Shirakawa, S.; Tokuda, T.; Kan, S. B. J.; *Maruoka, K Org. Chem. Front. 2015, 2 (4), pp.336-339. DOI:10.1039/C4QO00339J |
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"
Phase-Transfer-Catalyzed Asymmetric SNAr Reaction
of α-Amino Acid Derivatives with Arene Chromium Complexes " Shirakawa, S.; Yamamoto, K.; *Maruoka, K. Angew. Chem. Int. Ed. 2015, 54 (3), pp.838-840. DOI:10.1002/anie.201409065 |
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|
"
Effect of Brønsted acid co-catalyst in asymmetric
conjugate addition of 3-aryloxindoles to maleimide under base-free
phase-transfer conditions " Shirakawa, S.; Makino, H.; Yoshidome, T.; *Maruoka, K. Tetrahedron 2014, 70 (40), pp.7128-7132. DOI:10.1016/j.tet.2014.06.017 |
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"
Efficient Asymmetric Synthesis of Spiro-2(3H)-furanones via Phase-Transfer-Catalyzed Alkynylation " Wu, X.; Shirakawa, S.; *Maruoka, K.Org. Biomol. Chem. 2014, 12 (29), pp.5388-5392. DOI:10.1039/c4ob00969j |
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|
"
Catalytic Asymmetric Synthesis of
3,3’-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary
Center: Phase-Transfer-Catalyzed SNAr Reaction " Shirakawa, S.; Koga, K.; Tokuda, T.; Yamamoto, K.; *Maruoka, K. Angew. Chem. Int. Ed. 2014, 53 (24), pp.6220-6223. DOI:10.1002/anie.201403046 |
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"
A Base-Free Neutral Phase-Transfer Reaction System " Shirakawa, S.; Wang, L.; He, R.; Arimitsu, S.; *Maruoka, K.Chem. Asian J. 2014, 9 (6), pp.1586-1593. DOI:10.1002/asia.201402194 |
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"
Phase-Transfer-Catalyzed Asymmetric α-Arylation of
α-Amino Acid Derivatives " Shirakawa, S.; Yamamoto, K.; Tokuda, T.; *Maruoka, K. Asian J. Org. Chem. 2014, 3 (4), pp.433-436. DOI:10.1002/ajoc.201400004 |
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| Reviews / Accounts |
"A new generation of chiral phase-transfer catalysts" Kaneko, S.; Kumatabara, Y.; *Shirakawa, S. Org. Biomol. Chem. 2016, in press DOI:DOI: 10.1039/C5OB02446C |
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"Chiral quaternary phosphonium salts as phase-transfer catalysts for environmentally benign asymmetric transformations" Liu, S.; Kumatabara, Y.; *Shirakawa, S. Green Chem. 2016, 18 (2), pp.331-341. DOI:DOI: 10.1039/C5GC02692J |
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"
Organocatalyzed Asymmetric Synthesis of Axially,
Planar, and Helical Chiral Compounds " *Shirakawa, S.; Liu, S.; Kaneko, S. Chem. Asian J. 2016, 11 (3), pp.330-341. DOI:DOI: 10.1002/asai.201500951 |
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"塩基を必要としない中性相間移動反応系の発見と展開" *白川誠司 有機合成化学協会誌 2014, 72 (12), pp.1374-1383. DOI:http://dx.doi.org/10.5059/yukigoseikyokaishi.72.1374 |
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"
Asymmetric Phase-Transfer Reactions under Base-Free Neutral Conditions " Shirakawa, S.; *Maruoka, K.Tetrahedron Lett. 2014, 55 (29), pp.3833-3839. DOI:http://dx.doi.org/10.1016/j.tetlet.2014.05.014 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Phase-Transfer-Catalyzed Asymmetric SNAr Reactions" *○Shirakawa, S. The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Base-Free Neutral Phase-Transfer Reaction System" *○Shirakawa, S. Sino-Japan International Exchange and Cooperation Forum on Organic Chemistry, Guangdong (China) 2015-11-27～2015-11-27 |
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|
招待講演 "
Discovery and Evolution of Base-Free Neutral
Phase-Transfer Reaction System " ○*Shirakawa, S. 2nd International Symposium on Catalysis Toward Green Sustainable Chemistry (CAT-GSC-2), Tokyo (Japan) 2015-03-30～2015-03-30 |
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招待講演 "
Efficient Approach for the Design of Effective Chiral Quaternary Phosphonium Bromides in Asymmetric Reactions " ○*Shirakawa, S2nd International Symposium on Integrated Science for Molecular Chirality in Biology and Chemistry, Kumamoto (Japan) 2014-11-30～2014-12-01 |
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招待講演 "
Development of Chiral Bifunctional Quaternary Phosphonium Bromides for Asymmetric Phase-Transfer Reactions " ○*Shirakawa, SAdvanced Molecular Transformations by Organocatalysts 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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| Prize |
"
長瀬研究振興賞 " *白川誠司 2015-04 公益財団法人 長瀬科学技術振興財団環境調和型精密有機合成を指向したキラル中性塩触媒反応系の構築 |
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"有機合成化学協会 三井化学研究企画賞" *白川誠司 2015-02 有機合成化学協会 不斉ラジカル反応およびルイス酸触媒反応のためのキラルゲルマニウム触媒の創製 |
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| A01 中村 修一 | ||
| Original papers |
"Catalytic Enantioselective Reaction of α-Aminoacetonitriles Using Chiral Bis(imidazoline)-Pd Catalysts " Masaru Kondo, Tomoki Nishi, Tsubasa Hatanaka, Yasuhiro Funahashi, *Shuichi Nakamura Angew. Chem. Int. Ed. 2015, 54 (28), pp.8198-8202. DOI:10.1002/anie.201503098 |
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"Organocatalytic Enantioselective Peroxidation of Ketimines Derived from Isatins" *Shuichi Nakamura, Shun Takahashi Org. Lett. 2015, 17 (11), pp.2590-2593. DOI:10.1021/acs.orglett.5b00805 |
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"Catalytic enantioselective reaction of a-phenylthioacetonitriles using chiral bis(imidazoline)-Pd catalysts" Masaru Kondo, Natsumi Kobayashi, Tsubasa Hatanaka, Yasuhiro Funahashi, *Shuichi Nakamura Chem. Eur. J. 2015, 21 (25), pp.9066-9070. DOI:10.1002/chem.201501351 |
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"Direct Enantioselective Vinylogous Mannich Reaction of Ketimines with g-Butenolide by Using Cinchona Alkaloid Amide/Zinc(II) Catalysts" *Shuichi Nakamura, Ryota Yamaji, Masashi Hayashi Chem. Eur. J. 2015, 21 (27), pp.9615-9618. DOI:10.1002/chem.201500599 |
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"Direct Enantioselective Three-Component Synthesis of Optically Active Propargylamines in Water " Mutsuyo Ohara, Yoshichika Hara, Tohru Ohnuki, Shuichi Nakamura* Chem. Eur. J. 2014, 20 (9), pp.8848-8851. DOI:10.1002/chem.201402384 |
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"Organocatalytic Enantioselective Decarboxylative Reaction of Malonic Acid Half Thioesters with Cyclic N-Sulfonyl Ketimines Using N-Heteroarenesulfonyl Cinchona Alkaloid Amides" Shuichi Nakamura*, Masahide Sano, Ayaka Toda, Daisuke Nakane, Hideki Masuda Chem. Eur. J. 2015, 21 (10), pp.3929-3932. DOI:10.1002/chem.201406270 |
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"Organocatalytic Enantioselective Addition of Thiols to Ketimines Derived from Isatins" Shuichi Nakamura,* Shun Takahashi, Daisuke Nakane, Hideki Masuda Org. Lett. 2015, 17 (1), pp.106-109. DOI:10.1021/ol503309s |
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"Desymmetrization of meso-Aziridines with TMSNCS Using Metal Salts of Novel Chiral ImidazolinePhosphoric Acid Catalysts" Shuichi Nakamura,* Mutsuyo Ohara, Madoka Koyari, Masashi Hayashi, Kengo Hyodo, Nadaf Rashid Nabisaheb, and Yasuhiro Funahashi Org. Lett. 2014, 16 (17), pp.4452-4455. DOI:10.1021/ol501990t |
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"Direct Asymmetric Mannich-Type Reaction of a-Isocyanoacetates with Ketimines using Cinchona Alkaloid Amide/Copper(II) Catalysts" Masashi Hayashi, Masaru Iwanaga, Noriyuki Shiomi, Daisuke Nakane, Hideki Masuda, Shuichi Nakamura* Angew. Chem. Int. Ed. 2014, 53 (32), pp.8411-8415. DOI:10.1002/anie.201404629 |
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| Reviews / Accounts |
"Enantioselective Reaction Using Palladium Pincer Complexes with C2-Symmetric Chiral Bis(imidazoline)s" Shuichi Nakamura J. Synth. Org. Chem. Jpn 2016, 73 (12), pp.1062-1071. DOI:http://doi.org/10.5059/yukigoseikyokaishi.73.1062 |
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"イミノホスホランを利用する不斉有機分子触媒 －部位別の開発が新たな道を拓く" 中村修一 月間「化学」 2014, 69 (4), pp.66-67. |
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"Catalytic enantioselective decarboxylative reactions using organocatalysts " Shuichi Nakamura Org. Biomol. Chem. 2014, 12 (3), pp.394-405. DOI:10.1039/C3OB42161A |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Enantioselective Reaction of a-Heteroacetonitriles Using Palladium Pincer Complexes with Chiral Bis(imidazoline)s" ○Masaru Kondo, Natsumi Kobayashi, Tomoki Nishi, *Shuichi Nakamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM),, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Desymmetrization of meso-Aziridines Catalyzed by Cinchona Alkaloid amides-Metal Complexes " ○Noriyuki Shiomi, Masashi Hayashi, *Shuichi Nakamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM),, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "N-Heteroarenesulfonylated cinchona alkaloid amide catalysts: Asymmetric reaction of some nucleophiles with ketimines" ○*Shuichi Nakamura, Masahide Sano, Shun Takahashi, Ayako Toda, Noriyuki Hara, Ryota Tamura The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICCHEM), , Hawaii (USA) 2015-12-15～2015-12-20 |
N-Heteroarenesulfonylated cinchona alkaloid amide catalysts: Asymmetric reaction of some nucleophiles with ketimines | |
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口頭発表／ポスター発表 "Asymmetric Mannich-type Reaction of α-Phenylthioacetonitriles to Imines Using Chiral Bis(imidazoline)–Palladium Catalysts " ○Natsumi Kobayashi, Masaru Kondo, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry,, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Organocatalytic Enantioselective Aza-Friedel-Crafts Reaction of Cyclic Ketimines with Pyrroles " ○Nazumi Matsuda, Mutsuyo Ohara, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Enantioselective Decarboxylative Mannich-type Reaction Using N-Heteroarenesulfonyl Cinchona Alkaloid amide Catalyst " ◯Ayaka Toda, Masahide Sano, *Shuichi Nakamura The 13th International Kyoto Conference on New Aspects of Organic Chemistry,, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Synthesis of Optically Active Sultams Using N-Heteroarenesulfonyl Cinchona Alkaloid Amide Catalyst " Ayaka Toda, Masahide Sano, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Enantioselective Three-component Synthesis of propargylamines accompanied by the dehydration in water " ○Yoshichika Hara, Mutsuyo Ohara, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Efficient Synthesis of Chiral Diaminonitriles Using Chiral Bis(imidazoline)-Pd Catalysts" ○Masaru Kondo, Tomoki Nishi, *Shuichi Nakamura The 3rd International Symposium on Process Chemistry ISPC 2015 , 京都 (日本) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Cinchona Alkaloid Picolinamide Catalysts: Asymmetric Reactions of Aziridines or Ketimines " ◯Noriyuki Shiomi, Shuichi Nakamura 内藤コンファレンス 有機分子触媒の化学 , 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "Enantioselective Nucleophilic Addition to Ketimines Using N-Heteroarenesulfonylated Cinchona Alkaloid Amide Catalysts " Shuichi Nakamura 第５回日英触媒的不斉合成コンフェレンス (5th UK-Japan Conference on Asymmetric Catalysis) , マンチェスター (イギリス) 2016-03-14～2016-03-15 |
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口頭発表／ポスター発表 "Development of Chiral Imidazoline-Phosphoric Acid Catalyst and Application to
Desymmetrization of meso-Aziridine with TMSNCS " ○Mutsuyo Ohara, Madoka Koyari, Masashi Hayashi, Kengo Hyodo, Nadaf Rashid
Nabisaheb, Shuichi Nakamura Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Enantioselective Addition of Thiols to Ketimines Derived from Isatins Using
N-Heteroarenesulfonylated Organocatalysts" ○Shun Takahashi, Shuichi Nakamura* Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Organocatalytic Decarboxylative Reaction with Cyclic Ketimines Using
N-Heteroarenesulfonyl Cinchona Alkaloid Amides " ○Ayaka Toda, Masahide Sano, Shuichi Nakamura* Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 " Cinchona Alkaloid amides/Copper(II) Ctalyzed Asymmetric Mannich-Type Reaction of
α-Isocyanoacetates with Ketimines " ◯Noriyuki Shiomi, Masashi Hayashi, Masaru Iwanaga, Shuichi Nakamura Nagoya (Japan) 2014-05-26～2014-05-28 |
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口頭発表／ポスター発表 "Catalytic Asymmetric Synthesis of Chiral a-Aminonitrile Using Palladium Pincer
Complexes with C2-Symmetric Chiral Bis(imidazoline)s" ◯Masaru Kondo, Kengo Hyodo, Shuichi Nakamura* Nagoya (Japan) 2014-05-26～2015-05-28 |
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招待講演 "Enantioselective reaction using chiral organocatalysts having heteroaryl groups" Shuichi Nakamura 8th Singapore International Chemistry Conference (シンガポール) 2014-12-14～2014-12-17 |
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招待講演 "Enantioselective reaction using chiral organocatalysts having heteroaryl groups" Shuichi Nakamura 青島 (中国) 2014-09-20～2014-09-24 |
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| Patent |
"光学活性なα－チオ－β－アミノニトリル類の製造方法" 発明者：中村修一・近藤 健・小林奈津美 出願者：名古屋工業大学長 特願2015-40258 2015-03-02, 2015-04, |
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"光学活性なα，β－ジアミノニトリル類の製造方法" 発明者：中村修一・近藤 健・西 友暉 出願者：名古屋工業大学長 特願2015-40217 2015-03-02, 2015-04, (国内) |
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| A01 諸熊 奎治 | ||
| Original papers |
"Positive Effect of Water in Asymmetric Direct Aldol Reactions with Primary-Amine Organocatalyst: Experimental and Computational Studies" Moteki, S. A.; Nakayama, K.; Li, H.-B.; Petrova, G.; Maeda, S.; *Morokuma, K.; Maruoka, K. Chem. Asian J. 2015, DOI:10.1002/asia.201500078 |
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"Revisiting the Passerini Reaction Mechanism: Existence of the Nitrilium, Organocatalysis of Its Formation And Solvent Effect" Ramozzi, R.; *Morokuma, K. J. Org. Chem. 2015, 80 pp.5652-5657. DOI:10.1021/acs.joc.5b00594 |
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"Biginelli Reaction Is a Urea-Catalyzed Organocatalytic Multicomponent Reaction " Puripat, M.; Ramozzi, R.; Hatanaka, M.; Parasuk, W.; Parasuk, V.; *Morokuma, K. J. Org. Chem. 2015, DOI:10.1021/acs.joc.5b00407 |
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| Reviews / Accounts |
"The ONOIM Method and its Applications" Chung, L. W.; Sameera, W. M. C.: Ramozzi, R.; Page, A. J.; Hatanaka, M.; Petrova, G. P.; Harris, T. V.; Li, X.; Ke, Z.; Liu, F. Li, H.-B.; Ding, L.; *Morokuma, K. Chem. Rev. 2015, 115 pp.5678-5796. DOI:10.1021/cr5004419 |
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| Conference / Symposium / Lecture |
招待講演 "GRRM法を用いた複雑分子系の機構" GRRM誕生十周年 GRRM14発表記念講演会「GRRMで拓く化学のニューフロンティア」, 東京 (日本) 2014-11-30～2014-11-30 |
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招待講演 "複雑分子系のシミュレーション - 生体分子の反応への応用とその周辺" *Morokuma, K 情報計算化学生物学会（CBI学会 ), 東京 (日本) 2014-07-29～2014-07-29 |
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招待講演 "Quantum chemical molecular dynamics (QM/MD) simulations of nucleation, growth and healing processes of fullerenes, carbon nanotubes and graphenes" Morokuma, K the 17th International Symposium on Small Particles and Inorganic Clusters (ISSPIC XVII), Fukuoka (Japan) 2014-09-07～2014-09-07 |
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招待講演 "Gas-Phase Photochemical and Homogenous Catalytic Reactions Explored Using the Automated Reaction Route Mapping (GRRM) Method" *Morokuma, K American Chemical Society Spring Meeting, Denver (USA) 2015-03-23～2015-03-23 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Argonne National Laboratory, (USA) 2015-03-17～2015-03-17 |
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招待講演 "Chemical Reactions of Complex Molecular Systems -- Discovery and Insights from Computational Studies" *Morokuma, K 12th Fukui Institute Symposium, Fukui Institute for Fundamental Chemistry, Kyoto University,Kyoto (Japan) 2015-01-23～2015-01-23 |
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招待講演 "Fascinating World of Theoretical Studies of Chemical Reaction--From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Hiroshima University、Hiroshima (Japan) 2014-12-03～2014-12-03 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K Advanced Molecular Transformations by Organocatalysts”, 2nd International Conference and 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-21 |
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招待講演 "Chemical Theory of Complex Molecular Systems: Discovery and Insights from Computational Studies of Chemical Reactions" *Morokuma, K CRC-SU Joint International Symposium on Chemical Theory of Complex Systems”: Symposium “Interplay between Theory and Experiments; New Trends in Catalysis, Stockholm University, Stockholm (Sweden) 2014-10-31～2014-10-31 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K Japan-Russia Joint-Symposium on Chemical Theory for Complex Systems, St. Petersburg State University (Russia) 2014-09-19～2014-09-19 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K International Conference "Molecular Complexity in Modern Chemistry (MCMC-2014), Moscow (Russia) 2014-09-16～2014-09-16 |
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招待講演 "Multiscale Computational Approaches And Applications in Biochemistry And Biomaterials" *Morokuma, K Annual Conference of Canadian Chemical Society, Vancouver (Canada) 2014-06-04～2014-06-04 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Swiss Chemical Society Lecture, EPFL, Lausanne (Switzerland) 2014-05-23～2014-05-23 |
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招待講演 "Complex Chemical Reaction Pathways Explored by Automatic Search Strategy" *Morokuma, K Swiss Chemical Society Lecture, ETH, Zurich (Switzerland) 2014-05-22～2014-05-22 |
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招待講演 "Theoretical Studies of Complex Molecular Systems. Methods and Applications" *Morokuma, K Swiss Chemical Society Lecture, University of Basel, Basel (Switzerland) 2014-05-21～2014-05-21 |
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招待講演 "Chemical Theory of Complex Molecular Systems: Discovery and Insights from Computational Studies of Chemical Reactions" *Morokuma, K Swiss Chemical Society Lecture, University of Fribourg, Fribourg (Switzerland) 2014-05-20～2014-05-20 |
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招待講演 "Exciting World of Theoretical Studies of Chemical Reactions − From Gas Phase Reactions to Catalysts, and Enzymatic Reactions" *Morokuma, K Swiss Chemical Society Lecture, University of Basel, Basel (Switzerland) 2014-05-19～2014-05-19 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, Australian National University, Canberra (Australia) 2014-05-01～2014-05-01 |
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招待講演 "Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, University of Sydney, Sydney (Australia) 2014-04-29～2014-04-29 |
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招待講演 "Exploring potential energy surfaces with GRRM automatic search strategy, Theory and Computation Provide Insights and Discovery on Chemical Reactions of Complex Molecular Systems" *Morokuma, K the 2014 AATACC Seminar, University of New Castle, Canberra, ( Australia) 2014-04-28～2014-04-28 |
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| A01 山田 健一 | ||
| Original papers |
"Striking Difference between Succinimidomethyl and Phthalimidomethyl Radicals in Conjugate Addition to Alkylidenemalonate Initiated by Dimethylzinc." *Yamada, K.; Matsumoto, Y.; Fuji, S.; Konishi, T.; Yamaoka, Y.; Takasu, K. J. Org. Chem. 2016, 81 (9), pp.3809-3817. |
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"Oxa- and Azacycle-formation via Migrative Cyclization of Sulfonylalkynol and Sulfonylalkynamide with N-Heterocyclic Carbene." Wang, Y.; Oriez, R.; Kuwano, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. J. Org. Chem. 2016, 81 (6), pp.2652-2664. |
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"An Arylative Ring Expansion Cascade of Fused Cyclobutenes via Short-Lived Intermediates with Planar Chirality." Arichi, N.; Yamada, K.; Yamaoka, Y.; *Takasu, K. J. Am. Chem. Soc. 2015, 137 (30), pp.9579-9582. |
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"Asymmetric Total Synthesis of Tylophorine via a Formal [2+2] Cycloaddition Followed by Migrative Ring Opening of a Cyclobutane." *Yamaoka, Y.; Taniguchi, M.; Yamada, K.; *Takasu, K. Synthesis 2015, 47 (18), pp.2819-2825. |
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"Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric SN2′ Reaction." Kuroda, Y.; Harada, S.; Oonishi, A.; Yamaoka, Y.; *Yamada, K.; *Takasu, K. Angew. Chem. Int. Ed. 2015, 54 (28), pp.8263-8266. |
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"Cyclic Model for the Asymmetric Conjugate Addition of Organolithium with Enoate." Nishimura, K.; Fukuyama, N.; Yamashita, M.; Sumiyoshi, T.; Yamamoto, Y.; Yamada, K.; *Tomioka, K. Synthesis 2015, 47 (15), pp.2256-2264. |
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"A Short Synthesis of (+)-β-Lycorane by Asymmetric Conjugate Addition Cascade." Nishimura, K.; Fukuyama, N.; Yasuhara, T.; Yamashita, M.; Sumiyoshi, T.; Yamamoto, Y.; Yamada, K.; *Tomioka, K. Tetrahedron 2015, 71 (39), pp.7222-7226. |
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"The Development of a Brønsted Acid-promoted Arene-Ynamide Cyclization toward the Total Syntheses of Marinoquinolines A and C, and Aplidiopsamine A." *Yamaoka, Y., Yoshida, T.; Shinozaki, M.; Yamada, K.; *Takasu, K. J. Org. Chem. 2015, 80 (2), pp.957-964. |
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"Hydrostannylation-Cross-Coupling Strategy for Stereoselective Synthesis of Alkylidenemalonates and Related α,β-Unsaturated Esters." Fujiwara, S.; Romain, C.; Yamaoka, Y.; Takasu, K.; *Yamada, K. Eur. J. Org. Chem. 2015, (6), pp.1264-1272. |
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"Synthesis of Steroidal Derivatives Bearing a Small Ring Using a Catalytic [2+2] Cycloaddition and a Ring-Contraction Rearrangement." Arichi, N.; Hata, K.; Takemoto, Y.; Yamada, K.; Yamaoka, Y.; *Takasu, K. Tetrahedron 2015, 71 (2), pp.233-244. |
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"Contiguous Radical Pivaloyloxymethylation–Directed C(sp3)–H Iodination of N-Tosyl Cycloalkanecarbaldimine." Fujii, S.; Nakano, M.; Yamaoka, Y.; Takasu, K.; *Yamada, K.; Tomioka, K. Tetrahedron Lett. 2015, 56 (23), pp.3086-3089. |
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"N-Heterocyclic Carbene-Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols." Kang, B.; Sutou, T.; Wang, Y.; Kuwano, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. Adv. Synth. Catal. 2015, 357 (1), pp.131-147. |
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"Radical Aminomethylation of Imines." Fujii, S.; Konishi, T.; Matsumoto, Y.; Yamaoka, Y.; Takasu, K.; *Yamada, K. J. Org. Chem. 2014, 79 (17), pp.8128-8133. |
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| Reviews / Accounts |
"Exploration of Dimethylzinc-Mediated Radical Reactions." *Yamada, K.; Tomioka, K. Chem. Rec. 2015, 15 (5), pp.854-870. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Migrative Cyclization of Alkynylsulfones Using N-Heterocyclic Carbenes" *Yamada, K.; ○Wang, Y.; Miyakawa, Y.; Oriez, R.; Yamaoka, Y.; Takasu, K. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015) , Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Activation of the leaving group in the chiral phosphoric acid-catalyzed intramolecular asymmetric SN2’ reaction" ○*Yamada, K. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015) , Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "E/Z-selective synthesis of unsymmetric alkylidenemalonates and its applications" ○Fujiwara, S.; Yamaoka, Y.; Takasu, K.; *Yamada, K. The 9th SKO Symposium, Seoul (Korea) 2015-11-17～2015-11-18 |
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口頭発表／ポスター発表 "Organocatalytic Activation of the Leaving Group in the Asymmetric Substitution Reaction" ○Kuroda, Y.; Harada, S.; Oonishi, A.; Yamaoka, Y.; *Yamada, K.; *Takasu, K. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Total Synthesis and Structural Revision of Paesslerin A" Mogi, Y.; Yamada, K.; Yamaoka, Y.; ○*Takasu, K. Inaugural Symposium of the Phytochemical Society of Asia 2015 (ISPSA2015) TOKUSHIMA, Tokushima (Japan) 2015-08-30～2015-09-02 |
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口頭発表／ポスター発表 "Efficient Synthesis of Nitrogen-containing Medium Rings with Ynamides" ○*Yamaoka, Y.; Takeuchi, N.; Yamada, K.; *Takasu, K. The 25th ISHC Congress, Santa Barbara (USA) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "The asymmetric intramolecular SN2' reaction catalyzed by chiral phosphoric acid" ○*Yamada, K.; Kuroda, Y.; Harada, S.; Yamaoka, Y.; *Takasu, K. The 39th Naito Conference「The chemistry of organocatalysts」, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Total Synthesis of Paesslerin A" Mogi, Y.; Inanaga, K.; Ishii, T.; Tokuyama, H.; Ihara, M.; ○Yamaoka, Y.; Yamada, K.; *Takasu, K. The 39th Naito Conference「The chemistry of organocatalysts」, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "N-HETEROCYCLIC CARBENE–CATALYZED BENZOIN STRATEGY FOR DIVERGENT SYNTHESIS OF INOSITOL DERIVATIVES FROM ALDITOLS" ○Kang, B.; Sutou, T.; Yamaoka, Y.; Takasu, K.; Yamada, K.* 8th Singapore International Chemistry Conference (SICC-8) , University Town (Singapore) 2014-12-14～2014-12-17 |
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口頭発表／ポスター発表 "TOTAL SYNTHESIS OF PAESSLERIN A" ○Mogi, Y.; Inanaga, K.; Ishii, T.; Tokuyama, H.; Ihara, M.; Yamaoka, Y.; Yamada, K.; Takasu, K.* 8th Singapore International Chemistry Conference (SICC-8) , University Town (Singapore) 2014-12-14～2014-12-17 |
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口頭発表／ポスター発表 "Desymmetrization of σ-symmetric acid anhydride by a chiral phosphoric acid " Yamada, K.;* ○Oonishi, A.; Kuroda, Y.; Harada,S.; Yamaoka, Y.; Takasu, K.* The Ninth International Symposium on Integrated Synthesis（ISIS-9）, Hyogo (Japan) 2014-11-14～2014-11-15 |
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口頭発表／ポスター発表 "Efficient Synthesis of Medium Ring with Ynamides" ○Yamaoka, Y.;* Takeuchi, N.; Yamada, K.; Takasu, K. The Ninth International Symposium on Integrated Synthesis（ISIS-9）, Hyogo (Japan) 2014-12-14～2014-12-15 |
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口頭発表／ポスター発表 "Palladium-Catalyzed Arylating Ring Expansion of Fused-Cyclobutenes " ○Arichi, N.; Yamada, K.; Yamaoka, Y.; Takasu, K.* Conference on C–C Bond Cleavage (CCCC), Kyoto (Japan) 2014-10-24～2014-10-26 |
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依頼講演 "Development of synthetic methodologies utilizing N-heterocyclic carbenes" Yamada, K. Tampere University of Technology, Department of Chemistry and Bioengineering Seminar, Tampere (Finland) 2014-09-22～2014-09-22 |
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口頭発表／ポスター発表 "ENHANCED RATE AND SELECTIVITY BY CARBOXYLATE SALT AS A BASIC COCATALYST IN CHIRAL NHC-CATALYZED ASYMMETRIC ACYLATION OF SECONDARY ALCOHOLS" Yamada, K. Molecular Complexity in Modern Chemistry (MCMC-2014), Moscow (Russia) 2014-09-13～2014-09-19 |
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口頭発表／ポスター発表 "Synthesis of 2,3,4,5-tetra-substituted pyrroles via a base-promoted double Michael reaction of oxime-enoates" ○Kuroda, Y.; Imaizumi, K.; Yamada, K.; Yamaoka, Y.; Takasu, K.* 20th International Conference on Organic Synthesis , Budapest (Hungary) 2014-06-29～2014-07-04 |
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口頭発表／ポスター発表 "Synthesis of Steroid Derivatives Bearing a Small Ring for the Conformational Fixation of D-Ring Side Chain" ○Arichi, N.; Hata, K.; Yamada, K.; Yamaoka, Y.; Takasu, K.* 20th International Conference on Organic Synthesis , Budapest (Hungary) 2014-06-29～2014-07-04 |
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| A01 テスト 太郎 | ||
| Original papers |
"a'lert" a'lert 2015, |
a'lert |
| Books |
「a'lert」 a'lert 2015, |
a'lert |
| Reviews / Accounts |
"a'lert" a'lert 2015, |
a'lert |
| Conference / Symposium / Lecture |
依頼講演 会議名 member, 2015-08-19～2015-08-19 |
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招待講演 会議名 member, 2015-08-19～2015-08-19 |
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受賞講演 会議名 member, 2015-08-19～2015-08-19 |
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基調講演 会議名 member, 2015-08-19～2015-08-19 |
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口頭発表／ポスター発表 会議名 member, 2015-08-19～2015-08-19 |
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依頼講演 会議名, 2015-08-19～2015-08-19 |
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招待講演 会議名, 2015-08-19～2015-08-19 |
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受賞講演 会議名, 2015-08-19～2015-08-19 |
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基調講演 会議名, 2015-08-19～2015-08-19 |
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口頭発表／ポスター発表 会議名, 2015-08-19～2015-08-19 |
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"a'lert" a'lert a'lert, a'lert 2015-08-08～2015-08-08 |
a'lert | |
| Patent |
"a'lert" 発明者：a'lert 出願者：a'lert 2015-08, a'lert 2015-08, |
a'lert |
| Media |
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| 分類 | 内容 | 共同研究者 |
|---|---|---|
| A02 川端 猛夫 | ||
| Original papers |
"Asymmetric Synthesis of Multisubstituted Dihydrobenzofurans by Intramolecular Conjugate Addition of Short-Lived C-O Axially Chiral Enolates" Tomohara, K.; Kasamatsu, K.; Yoshimura, T.; Furuta, T.; *Kawabata, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00272 |
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"Organocatalytic Site-Selective Acylation of Avermect in B2a, a Unique Endectocidal Drug" Yamada, T.; Suzuki, K.; Hirose, T.; Furuta, T.; Ueda, Y.; Kawabata, T.; Omura, S.; *Sunazuka, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00205 |
砂塚敏明 | |
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"A Concise Access to C2-Symmetric Chiral 4-Pyrrolidinopyridine Catalysts with Dual Functional Side Chains" Mishiro, K.; Takeuchi, H.; Furuta, T.; *Kawabta, T. Chem. Pharm. Bull. 2016, DOI:DOI:10.1248/cpb.c16-00292 |
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"Organocatalytic Site-Selective Acylation of 10-Deacetylbaccatin III" Yanagi, M.; Ninomiya, R.; Ueda, Y.; Furuta, T.; Yamada, T.; Sunazuka, T.; *Kawabata, T. Chem. Pharm. Bull 2016, DOI:DOI:10.1248/cpb.c16-00037 |
砂塚敏明 | |
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"Catalytic Discrimination Among Formyl Groups in Regio- and Stereoselective Intramolecular Cross-Aldol Reactions" Baba, T.; Yamamoto, J.; Hayashi, K.; Sato, M.; Yamanaka, M.; Kawabata, T.; *Furuta, T. Chem. Sci. 2016, DOI:DOI:10.1039/C5SC04594K |
山中正浩 | |
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"Insights into the Molecular Recognition Process in Organocatalytic Chemoselective Monoacylation of 1,5-Pentanediol" Imayoshi, A.; *Yamanaka, M.; Sato, M.; Yoshida, K.; Furuta, T.; Ueda, Y.; *Kawabata, T. Adv. Synth. Catal. 2016, 358 pp.1337-1344. DOI:10.1002/adsc.201600010 |
山中正浩 | |
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"Catalyst-Controlled Regiodivergent Vinylogous Aza-Morita-Baylis-Hillman Reactions" Hyakutake, R.; Gondo, N.; Ueda, Y.; Yoshimura, T.; Furuta, Hyakutake, R.; Gondo, N.; Ueda, Y.; Yoshimura, T.; Furuta, T.; *Kawabata, T. Tetrahedron Lett. 2016, 57 pp.1321-1324. DOI:10.1016/j.tetlet.2016.02.029 |
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"Final-Stage Site-Selective Acylation for the Total Syntheses of Multifidosides A-C by Organocatalysis"
Yoshihiro
Ueda, Takumi
Furuta, and Takeo Kawabata* Angew. Chem. Int. Ed. 2015, DOI:10.1002/anie.201504729R1 |
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"Total synthesis of ellagitannins via regioselective sequential functionalization of unprotected glucose" Takeuchi, H.; Mishiro, K.; Ueda, Y.; Fujimori, Y.; Furuta, T.; *Kawabata, T. Angew. Chem. Int. Ed. 2015, 54 (21), pp.6177-6180. DOI:10.1002/anie. 20150070 |
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"Origin of High E-Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α’-Alkenediol: A Computational and Experimental Study" *Yamanaka, M.; Yoshida, U.; Sato, M.; Shigeta, T.; Yoshida, K.; Furuta, T.; *Kawabata, T. J. Org. Chem. 2015, 80 (6), pp.3075-3082. DOI:10.1021/jo502945 |
山中正浩 | |
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"Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives" Nakanishi, K.; Sasamori, T.; Kuramochi, K.; Tokitoh, N.; Kawabata, T.; *Tsubaki, K. J. Org. Chem. 2014, 79 (6), pp.2625-2631. DOI:DOI 10.1021/jo5000085a |
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"
Oligonaphthofurans: Fan-Shaped and Three-Dimensional π-Compounds"
Nakanishi,
K.; Fukatsu, D.; Takaishi, K.; Tsuji, T.; Uenaka, K.; Kuramochi, K.; Kawabata,
T.; *Tsubaki, K.
J. Am. Chem. Soc. 2014, 136 (19), pp.7101-7109. DOI:10.1021/ja502209w |
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"Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical" Hamada, S.; Wada, Y.; Sasamori, T.; Tokitoh, N.; Furuta, T.; *Kawabata, T. Tetrahedron Lett. 2014, 55 (11), pp.1943-1945. DOI:10.1016/j.tetlet.2014.02.005 |
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"A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen Bonding Network" *Mishiro, K.; *Furuta, T.; Sasamori, T.; Hayashi, K.; Tokitoh, N.; Futaki, S.; Kawabata, T. J. Am. Chem. Soc. 2013, 135 (37), pp.13644-13647. DOI:10.1021/ja407051k |
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"
Asymmetric α-Arylation of Amino Acid Derivatives by Clayden
Rearrangement of Ester Enolates via Memory of Chirality
"
Tomohara, K.; Yoshimura, T.; Hyakutake, R.; Yang, P.;
*Kawabata, T.
J. Am. Chem. Soc. 2013, DOI:10.1021/ja406653n |
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"
Synthesis of Axially Chiral Amino Acid Derivatives via
the Selective Monoesterification of 1,1'-Biaryl-2,2'-dicarboxylic acids
"
*Furuta, T.; Nikaido, M.; Yamamoto, J.; Kuribayashi,
T.; Kawabata, T.
Synthesis 2013, 45 (10), pp.1312-1318. DOI:10.1055/s-0032-1318506 |
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"
Chemoselective Oxidation by Electronically Tuned
Nitroxyl Radical Catalysts
"
Hamada, S.; Furuta, T. Wada, Y.; *Kawabata, T.
Angew. Chem. Int. Ed. 2013, 52 (31), pp.8093-8097. DOI:10.1002/anie.201302261 |
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"
Investigation of the Carboxylate Position during the
Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal
Carboxylate
"
Nishino, R.; *Furuta, T.; Kan, K.; Sato, M.; Yamanaka,
M.; Sasamori, T.; Tokitoh, N.; *Kawabata, T.
Angew. Chem. Int. Ed. 2013, 52 (25), pp.6445-6449. DOI:10.1002/anie.201300665 |
立教大学、山中正浩 | |
|
"
Asymmetric Induction via Short-Lived Chiral Enolates
with a Chiral C-O Axis
"
Yoshimura, T.; Tomohara, K.; *Kawabata, T.
J. Am. Chem. Soc. 2013, 135 (19), pp.7102-7105. DOI:10.1021/ja4018122 |
||
|
"
Asymmetric Intermolecular Conjugate Addition of Amino
Acid Derivatives via Memory of Chirality: Total Synthesis of Manzacidin A
"
Yoshimura, T.; Kinoshita, T.; Yoshioka, H.; *Kawabata,
T.
Org. Lett. 2013, 15 (4), pp.864-867. DOI:10.1021/ol303568f |
||
|
"
Asymmetric Intramolecular Conjugate Addition of α-Amino Acid Derivatives via Racemization-free
Equilibrium of Intermediary Chiral Enolates
"
Monguchi, D.; Yoshimura, T.; Irie, K.; Hayashi, K.;
Majumdar, S.; Sasamori, T.; Tokitoh, N.; *Kawabata, T.
Heterocycles 2012, 86 (2), pp.1483-1494. DOI:10.3987/COM-12-S(N)129 |
||
|
"
Nonenzymatic
Geometry-Selective Acylation of Tri- and Tetrasubstituted α,α'-Alkenediols
"
Yoshida, K.; Mishiro, K.; Ueda, Y.; Shigeta, T.;
Furuta, T.; *Kawabata, T. Adv. Synth. Catal. 2012, 354 (17), pp.3291-3298. DOI:10.1002/adsc.201200242 |
||
|
"
Asymmetric Desymmetrization of Meso-Diols by
C2-Symmetric Chiral 4-Pyrrolidinopyridines
"
Schedel, H.; Kan, K.; Ueda, Y.; Mishiro, K.; Yoshida,
K.; Furuta, T.; *Kawabata, T.
Beilstein. J. Org. Chem. 2012, 8 pp.1778-1787. DOI:10.3762/bjoc.8.203 |
||
|
"
Protonation-Assisted Conjugate Addition of Axially
Chiral Enolates: Asymmetric Synthesis of Multisubstituted β-Lactams from α-Amino Acids"
Takuwa, M.; Tomohara, K.; Uyama, M.; Hayashi, K.;
Yang, P.; Hyakutake, R.; Sasamori, T.; Tokitoh, N.; *Kawabata, T. Chem. Eur. J. 2012, 18 (48), pp.15330-15336. DOI:10.1002/ chem.201201339 |
||
|
"
Regioselective Diversification of a Cardiac Glycoside,
Lanatoside C, by Organocatalysis"
Ueda, Y.; Mishiro, K.; Yoshida, K.; Furuta, T.;
*Kawabata, T. J. Org. Chem. 2012, 77 (18), pp.7850-7857. DOI:10.1021/jo301007x |
||
|
"
Dipicolylamine as a Unique Structural Switching
Element for Helical Peptides"
Azuma, Y.; Imai, H.; Yoshimura, T.; Kawabata, T.;
Imanishi, M.; *Futaki, S. Org. Biomol. Chem. 2012, 10 (30), pp.6062-6068. DOI:10.1039/C2OB07118E |
||
|
"
Catalyst-Controlled Reversal of Chemoselectivity in
Acylation of 2-Aminopentane-1,5-Diol Derivatives"
Yoshida, K.; Shigeta, T.; Furuta, T.; *Kawabata, T Chem. Commun. 2012, 48 (55), pp.6981-6983. DOI:10.1039/C2CC32525J |
||
|
"
Asymmetric Aldol Reaction via Memory of Chirality"
Watanabe, H.; Yoshimura, T.; Kawakami, S.; Sasamori,
T.; Tokitoh, N.; *Kawabata, T. Chem. Commun. 2012, 48 (43), pp.5346-5348. DOI:10.1039/C2CC31447A |
||
|
"
Asymmetric Carbonyl Migration of α-Amino Acid Derivatives via Memory of Chirality " Teraoka, F.; Fuji, K.; Ozturk, O.; Yoshimura, T.; *Kawabata, T.Synlett 2011, 11 (4), pp.543-546. DOI:10.1055/s-0030-1259324 |
||
|
"
Organocatalytic Chemoselective Monoacylation of 1,n-Linear Diols " Yoshida, K.; Furuta, T.; Kawabata, T.Angew. Chem. Int. Ed. 2011, 50 (21), pp.4888-4892. DOI:10.1002/anie.201100700 |
||
| Books |
「Site-Selective Catalysis」 Kawabata, T. "Site-Selective Acylation of Carbohydrates and Polyol Compounds" Ueda, Y.; *Kawabata, T. Springer Interntional Publishing 2016 2016, |
|
|
「e-EROS Encyclopedia of Reagents for Organic Synthesis」 Rovis, T. "L-Trytophan N,N'-[[(2S,5S)-1-(4-pyridinyl)-2,5-pyrrolidinediyl]dicarbonyl]bis-3,3'-dioctyl Ester" Ueda, Y.; *Kawabata, T. John Wiley ＆ Sons, Ltd. 2016, |
||
|
「e-EROS Encyclopedia of Reagents for Organic Synthesis」 Rovis, T. "Lithium tert-Butyl (trimethylsilyl)amide" Yoshimura, T.; *Kawabata, T. John Wiley ＆ Sons, Ltd 2016, |
||
|
「RSC Green Chemistry, Sustainable Catalysis」 North, M. "Chiral Imidazole and Pyridines as Asymmetric Organocatalysis" Furuta, T.; *Kawabata, T. The Royal Society of Chemistry 2016, pp351-380. |
||
|
「月刊ファインケミカル」 寺田眞浩 "アシル化触媒" 川端猛夫 シーエムシー出版 2015, pp14-23. |
||
|
「
Chiral DMAP-Type Catalysts for Acyl-Transfer Reactions
」
List, B
"Chiral DMAP-Type Catalysts for Acyl-Transfer Reaction" Furuta, T.; Kawabata, T. George Thieme Verlag KG (Stuttgart, New York) 2012, pp497-546. |
||
|
「化学」 化学同人 "触媒的位置選択的官能基化 –次世代の分子変換法" 古田巧、川端猛夫 化学同人 (京都市) 2011, pp70-71. |
||
| Conference / Symposium / Lecture |
招待講演 "Enantio- and Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. 2015 International Chemical Congress of Pacific Basin Societies, Honolulu (USA) 2016-12-15～2016-12-20 |
|
|
招待講演 "Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, Sendai (Japan) 2016-09-06～2016-09-09 |
||
|
招待講演 "Enantio- and Site-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. The 39th Naito Conference: The chemstry of organocatalysts, Spporo (Japan) 2016-07-06～2016-07-09 |
||
|
基調講演 "Site- and Enantio-Selective Molecular Transformation by Organocatalysis" *Kawabata, T. 7th Spanish-Portuguese-Japanese Organic Chemistry Symposium, Seville (Spain) 2016-06-23～2016-05-26 |
||
|
招待講演 "Site-Selective Catalysis" ○Kawabata, T. 1st Kyoto University - UC San Diego Joint Symposium, Kyoto (Japan) 2015-03-11～2015-03-12 |
||
|
招待講演 "Regio- and Enanatioselective Acylation by Organocatalysis" ○Kawabata, T. 8th Singapore International Chemistry Conference (SICC8)(Singapore), (Singapore) 2014-12-14～2014-12-17 |
||
|
招待講演 "Regio- and Enantioselective Functionalization by Organocatalysis" ○Kawabata, T. Advanced Molecular Transformation by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-22 |
||
|
口頭発表／ポスター発表 "Enrichment of the diastereomeric ratio of chiral heterocycles via racemization free-equilibrium of the intermediary chiral enolates" ○Yang, P.; Monguchi, D.; Takuwa, M.; Yoshimura, T.; Kawabata, T. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-31 |
||
|
招待講演 "Regio- and Enantioselective Acylation Catalysis" ○Kawabata . T. 24th Symposium on Optically Active Compounds, Tokyo (Japan) 2014-10-10～2014-10-10 |
||
|
招待講演 "Regioselective Molecular Transformation of Sugars and Peptides by Organocatalysis" ○Kawabata, T. 45th KMC Frontier Seminar, Tokyo (Japan) 2014-08-27～2014-08-27 |
||
|
口頭発表／ポスター発表 "Total Synthesis of Ellagitannins via Regioselective Acylation of Glucose" Takeuchi, H.;, ○Fujimori, Y.; Mishiro, K.; Furuta, T.; Kawabata, T. XXVIIth International Conference on Polyphenols & The 8th Tannin Conference(ICP2014), Nagoya (Japan) 2014-09-02～2014-09-06 |
||
|
口頭発表／ポスター発表 "
An Innovative Synthetic
Process for Natural Glycosides
"
○Hironori Takeuchi, Takumi
Furuta, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, Uji (Kyoto) 2014-03-10～2014-03-12 |
||
|
"
Development of Asymmetric
Conjugate Addition and Dieckmann Condensation via MOC Strategy
"
○Tomohiko Kinoshita, Tomoyuki
Yoshimura, Takumi Furuta, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Enantioselective β-lactam
synthesis via intramolecular conjugate addition of axially chiral enolates
overcoming competitive β-elimination
"
○Ryuichi Hyakutake, Masatoshi
Takuwa, Pan Yang, Tomoyuki Yoshimura, Takeo Kawabata
ICRIS'14: The Science and Technology of Smart Material, Uji (Japan) 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Asymmetric intramolecular
cross-aldol reaction catalyzed by axially chiral anilines
"
○Tomonori Baba, Junya Yamamoto,
Takumi Furuta, Takeo Kawabata
ICRIS'14:The Science and Technology of Smart Material, Uji (Japan) 2014-03-10～2014-03-12 |
||
|
口頭発表／ポスター発表 "
Regioselective deoxygenation
of hexopyranose derivatives
"
○Masanori Yanagi, Yoshihiro
Ueda, Takumi Furuta, Takeo Kawabata
13th International Conference on the Chemistry of Antibiotics and other bioactive compounds , Yamanashi (Japana) 2013-09-24～2013-09-27 |
||
|
口頭発表／ポスター発表 "
Total Synthesis of
Ellagitannins by Regioselective Functionalization of D-Glucose
"
○Hironori Takeuchi, Takumi
Furuta, Takeo Kawabata
13th International Conference on the Chemistry of Antibiotics and other bioactive compounds , Yamanashi (Japan) 2013-09-24～2013-09-27 |
||
|
口頭発表／ポスター発表 "
Asymmetric aldol reaction via
memory of chirality
"
○Toshihide Watanabe, ○Haruka Otsuki, Tomoyuki Yoshimura, Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
"
Asymmetryc Intramolecular
Conjugate Addition of Chiral Enolates wtih Chiral C-O axis
"
○Koji Kasamatsu, Keisuke
Tomohara, Tomoyuki Yoshimura, Takeo Kawabata The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
口頭発表／ポスター発表 "
Asymmetric α-Arylation of
Amino Acid Derivatives via Intramolecular Aryl Migration of C-N Axially Chiral
Enolates
"
○Keisuke Tomohra, ○Pan Yang, Ryuichi Hyakutake, Tomoyuki Yoshimura,
Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
口頭発表／ポスター発表 "
Asymmetric Intermolecular
Conjugate Addition of Amino Acid Derivatives via Memory of Chirality: Total
Synthesis of Manzacidin A
"
○Tomohiko Kinoshita, Hiroyasu
Yoshioka, Tomoyuki Yoshimura, Takeo Kawabata
The 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
招待講演 "
Asymmetric Intramolecular
Alkylation via Short-Lived C-O Axially Chiral Enolates " ○Tomoyuki Yoshimura, Keisuke
Tomohara, Takeo Kawabata
The 10th International Symposium on Carbanione Chemistry (ISCC-10) , Kyoto (Japan) 2013-09-23～2013-09-26 |
||
|
招待講演 "
Regioselective
Functionalization by Organocatalysis
"
○*Takeo
Kawabata
1st International Conference & 6th Symposium on Organiocatalysis, Ohtsu (Japan) 2013-05-17～2013-05-18 |
||
|
口頭発表／ポスター発表 "
Regioselective deoxygenation
of glucose derivatives
"
○Masanori
Yanagi, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
1st International Conference & 6th Symposium on Organiocatalysis, Ohtsu (Japan) 2013-05-27～2013-05-28 |
||
|
招待講演 "
Total synthesis of natural
glycosides by regioselective organocatalysis
"
○*Takeo
Kawabata
First Japan-USA Organocatalytic Symposium, Honolulu (Hawaii) 2012-12-15～2013-12-18 |
||
|
招待講演 "
Regioselective
Functionalization by Organocatalysis
"
○*Takeo
Kawabata Brystol-Kyoto Organic Synthesis Workshop in Kyoto , Kyoto (Japan) 2012-12-17～2012-12-18 |
||
|
口頭発表／ポスター発表 "
Organocatalysis-based
Enantioselective and Regioselective Total Syntheses of Natural Glycosides,
Multifidoside A and B
"
○Yoshihiro
Ueda, Takumi Furuta, *Takeo Kawabata
The 6th Takeda Science Foundation Symposium on PharmaSciences ' How Fascinating the Synthetic Organic Chemistry Is!' , Osaka (Japan) 2012-09-13～2012-09-14 |
||
|
口頭発表／ポスター発表 "
Asymmetric Synthesis of Cyclic Ethers with Tetrasubstituted Carbon via Short-lived C-O Axially Chiral Enolates " ○Tomoyuki Yoshimura, Keisuke Tomohara, and *Takeo KawabataThe 6th Takeda Science Foundation Symposium on PharmaSciences ' How Fascinating the Synthetic Organic Chemistry Is!' , Osaka (Japan) 2012-09-13～2012-09-14 |
||
|
口頭発表／ポスター発表 "
Total Syntheses of
Multifidoside A and B via Enantioselective and Regioselective Organocatalytic
Protocol
"
○Yoshihiro
Ueda, Takumi Furuta, *Takeo Kawabata
The 7th Seoul-Kyoto-Osaka Joint Symposium on Pharmaceutical Sciences for Young Scientists, Kyoto (Japan) 2012-05-24～2012-05-24 |
||
|
口頭発表／ポスター発表 "
Development of a Nitroxyl
Radical Oxidation Catalyst based on Electronic Tuning
"
○Shohei
Hamada, Takumi Furuta, *Takeo Kawabata
The 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
"
Intramolecular conjugate
addition of axially chiral enolates possessing a β-alkoxy leaving group: Asymmetric synthesis of β-lactams from L-serine
derivatives
"
○Ryuichi
Hyakutake, Masatoshi Takuwa, Makoto Uyama, Tomoyuki Yoshimura, *Takeo Kawabata
he 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
口頭発表／ポスター発表 "
Organocatalytic seven-step
total synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, and *Takeo Kawabata The 10th International Conference on Heteroatom chemistry, Uji (Japan) 2012-05-20～2012-05-25 |
||
|
受賞講演 "
A Principle for Asymmetric
Molecular Transformatio
"
○*Takeo
Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Intramolecular conjugate
addition of axially chiral enolates possessing a β-alkoxy leaving group: Asymmetric synthesis of β-lactams from L-serine
derivatives
"
○Ryuichi
Hyakutake, Masatoshi Takuwa, Makoto Uyama, Tomoyuki Yoshimura, *Takeo Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Total Synthesis of Manzacidin
A via Asymmetric Intermolecular Conjugate Addition Reaction Based on Memory of
Chirality
"
○Tomohiko Kinoshita, Hiroyasu Yoshioka, Tomoyuki Yoshimura, *Takeo Kawabata Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
A novel chiral structural
motif consisting of a cyclic hydrogen bonding network
"
○Kenji
Mishiro, Takumi Furuta, *Takeo Kawabata Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
口頭発表／ポスター発表 "
Catalytic and Regioselective
Total Synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
Symposium on Molecular Chirality ASIA 2012 -Chiral Science and Technology: From ASIA to the World, Hakata (Japan) 2012-05-17～2012-05-18 |
||
|
基調講演 "
Remote Asymmetric
Desymmetrization of Flexible Linear Diols by Organocatalysis
"
○*Takeo Kawabata BIT's 3rd Annual World Congress of Catalytic Asymmetric Synthesis -2012, Beijing (China) 2012-05-12～2012-05-14 |
||
|
口頭発表／ポスター発表 "
An Organocatalytic Regioselective
Approach toward Short Total Synthesis of Tellimagrandin I and II
"
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
||
|
口頭発表／ポスター発表 "
Development of a Nitroxyl
Radical Oxidation Catalyst by Electronic
Tuning
"
○Shohei
Hamada, Takumi Furuta, *Takeo Kawabata
International Symposium on Catalysis and Fine Chemicals 2011, Nara (Japan) 2011-12-04～2011-12-08 |
||
|
口頭発表／ポスター発表 "
symmetric desymmetrization of σ-symmetric linear diols
by chiral PPY catalysts
"
○Takashi Shigeta, Keisuke
Yoshida, Takumi Furuta, *Takeo Kawabata
8th AFMC International Medicinal Chemistry Symposium "Frontier of Medicinal Science", Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
Kinetic Resolution of
1,1'-Binaphthyl-8,8'-diamines by Catalytic Acylation with Chiral PPYs:
Mechanistic and Kinetic Aspects
"
Yasser Samir Abdel-khalek
Sokeirik, Valluru Krishna Reddy, Keisuke Yoshida, ○*Takeo Kawabata
8th AFMC International Medicinal Chemistry Symposium , Tokyo (Japan) 2012-11-29～2012-12-02 |
||
|
口頭発表／ポスター発表 "
Catalytic Profile of Biaryl
DMAP Derivatives with an Internal Carboxylate
"
○Reiko Nishino, Takumi
Furuta, *Takeo Kawabata 8th AFMC International Medicinal Chemistry Symposium , Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
Asymmetric Synthesis of β-Lactams with Contiguous Tetrasubstituted Chiral Carbon Centers via Memory of Chirality " ○Pan Yang, Masatoshi Takuwa, Keisuke Tomohara, Tomoyuki Yoshimura, *Takeo Kawabata8th AFMC International Medicinal Chemistry Symposium, Tokyo (Japan) 2011-11-29～2011-12-02 |
||
|
口頭発表／ポスター発表 "
An Organocatalytic
Regioselective Approach toward Short Total Syntheses of Telimagrandin I and II "
○Hironori
Takeuchi, Kenji Mishiro, Yoshihiro Ueda, Takumi Furuta, *Takeo Kawabata
First Germany-Japan Organocatalytic Symposium in Kyoto, Kyoto (Japan) 2011-10-14～2011-10-14 |
||
|
口頭発表／ポスター発表 "Asymmetric Desymmetrization of
σ-Symmetric Linear Diols by Organocatalytic Remote
Chiral Recognition
"
○Takashi
Shigeta, Keisuke Yoshida, Takumi Furuta, *Takeo Kawabata
First Germany-Japan Organocatalytic Symposium in Kyoto, Kyoto (Japan) 2011-10-14～2011-10-14 |
||
|
招待講演 "
Regioselective Functionalization by Organocatalysis " ○*Kawabata, TThe Seventh International Symposium on Integrated Synthesis (ISIS-7), Kobe (Japan) 2011-10-09～2011-10-10 |
||
| Patent |
"
β-Lactam
Compound and Method for Producing Same
" 発明者：
Kawaba Tatakeo; Yoshimura
Tomoyuki
出願者：Kyoto University WO2012157504 2013-08, 2013-08, (国外) |
|
|
"
Helicene
Derivative, Axially Asymmetric Amino Acid, Amine or Amonoalcohol Derivative or
Salt thereof, and Methods for Producing Same
" 発明者：
Furuta Takumi; Kawaba Takeo
出願者：Kyoto University 2012-08, 2013-08, (国外) |
||
|
"
アルドール反応触媒
" 発明者：
古田巧、馬場智明、川端猛夫
出願者：国立大学法人京都大学 特願２０１３−１２７９７０ 2013-06-18, 2013-08, (国内) |
||
|
"
β-ラクタム化合物およびその製造方法
" 発明者：
川端猛夫、吉村智之
出願者：国立大学法人京都大学 特願２０１１−１０７７７１ 2011-05-11, 2013-08, (国内) |
||
|
"
アミノ酸誘導体およびその製造方法
" 発明者：
川端猛夫、吉村智之
出願者：国立大学法人京都大学 特願２０１１−１６７３１０ 2011-07-29, 2013-08, (国内) |
||
|
"
酸化触媒
" 発明者：
川端猛夫、浜田翔平、古田巧
出願者：国立大学法人京都大学 特願２０１１−１６７４２５ 2011-07-29, 2013-08, (国内) |
||
| Prize |
"Nagase Foundation Award 2013" Regioselective Short-Step Total Synthesis of Natural Glycosides 2013-05 Nagase Science and Technology Foundation |
|
|
"Molecular Chirality Award 2012" *Kawabata, T. 2012-05 Molecular Chirality Research Organization Creation of Memory of Chirality Concept and Application to Asymmetric Synthesis |
||
| A02 北 泰行 | ||
| Original papers |
"Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary" Dohi, T.; Ueda, S.; Hirai, A.; Kojima, Y.; Morimoto, K.; *Kita, Y. Heterocycles 2017, 95 |
|
|
"Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls" Kamitanaka, T.; Morimoto, K.; Tsuboshima, K.; Koseki, D.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2016, 55 (50), pp.15535-15538. |
||
|
"Site-selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for Synthesis of Poly-arylated Phenols " *Sawama, S.; Masuda, M.; Nakatani, R.; Yokoyama, H.; Monguchi, Y.; Dohi, T. ; Kita, Y.; *Sajiki, H. Adv. Synth. Catal. 2016, 358 (23), pp.3683-3687. |
||
|
"Stabilized Pyrrolyl Iodonium Salts and Metal-Fee Oxidative Cross-Coupling" Morimoto, Ｋ.; Ohnishi, Y.; Koseki, D.; Nakamura, A.; Dohi,
T.; *Kita, Y. Org. Biomol. Chem. 2016, 14 (38), pp.8947-8951. |
||
|
"Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles" Morimoto, K.; Nakamura, A.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2016, (25), pp.4294-4297. |
||
|
"Glycosylation Reaction of Thio-Glycosides by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter" *Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; *Kita, Y. Chem. Pharm. Bull. 2016, 64 (7), pp.838-844. |
||
|
"Organo-Iodine(III) Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction" Morimoto, K.; Sakamoto, K.; Ohshika, T.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2016, 55 (11), pp.3652-3656. |
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"New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals and Alkene Nucleophiles" Kamitanaka, T.; Takamuro, H.; Shimizu, K.; Aramaki, Y.; Dohi, T.; *Kita, Y. Heterocycles 2016, 93 (1), pp.295-309. |
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"Gold-Catalyzed Benzylic Azidation of Phthalans and Isochromans and Subsequent FeCl3-Catalyzed Nucleophilic Substitutions" Asai, S.; Yabe, Y.; Goto, R.; Nagata, S.; Monguchi, Y.; Kita, Y.; *Sajiki, H.; *Sawama, Y. Chem. Pharm. Bull. 2015, 63 (10), pp.757-761. |
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"Clean Synthesis of N-pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent" Morimoto, K.; Ogawa, R.; Koseki, D.; Takahashi, Y.; Dohi, T.; *Kita, Y. Chem. Pharm. Bull. 2015, 63 (10), pp.819-824. |
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"Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines" Dohi, T.; Toyoda, Y.; Nakae, T.; Koseki, D.;Kubo, H.; Kamitanaka, T.; *Kita, Y. Heterocycles 2015, 90 (1), pp.631-644. |
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"Phenyliodine Bis(trifluoroacetate) (PIFA) as An Excellent Promoter of 2-Deoxy-2-phthalimido-1-thio-glycosides in the Presence of Triflic Acid in Glycosylation Reaction" Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2015, (10), pp.2138-2142. |
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"A New Arylation of Silyl Enol Ethers by Quinone Monoacetal Substitution" Dohi, T.; Kamitanaka, T.; Takamuro, H.; Mishima, Y.; Washimi, N.; *Kita, Y. Tetrahedron Lett. 2015, 56 (23), pp.3046-3051. |
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"Selective Formation of trans/threo/cis and cis/threo/cis Bis-Tetrahydrofurans from the Same Diene Diols" Fujioka H., Oki T., Hayashi T., Yamakawa M., Kurachi T., Nakahara K., Maehata R., Hamada T., Murai K., Kita Y. Heterocycles 2014, 88 (2), pp.1323-1336. |
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"Iodoarene-Catalyzed Fluorination and Aminofluorination by an Ar-I/HF•pyridine/mCPBA System" Suzuki, S.; Kamo, T.; Fukushi, K.; Hiramatsu, T.; Tokunaga, E.; Dohi, T.; *Kita, Y.; *Shibata, N. Chem. Sci. 2014, 5 (7), pp.2754-2760. |
柴田哲男 | |
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"N1-Selective Oxidative C-N Coupling of Azoles with Pyrroles Using Hypervalent Iodine Reagent" Morimoto, K.; Ohnishi, Y.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. Asian J. Org. Chem. 2014, 3 (4), pp.382-386. |
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"Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocylic Hypervalent Iodine Compound" Dohi, T.; Mochizuki, E.; Yamashita, D.; Miyazaki, K.; *Kita, Y. Heterocycles 2014, 88 (1), pp.245-260. |
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"Organocatalytic C-H/C-H' Cross-Biaryl-Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons" Ito, M.; Kubo, H.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y. J. Am. Chem. Soc. 2013, 135 (38), pp.14078-14081. |
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"Single-Electron-Transfer (SET) Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts" Yamaoka, N.; Sumida, K.; Itani, I.; Ohnishi, Y.; Sekiguchi, S.; Dohi, T.; *Kita, Y. Chem. Eur. J. 2013, 19 (44), pp.15004-15011. |
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"Brønsted Acid-Controlled [3+2] Coupling of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Efficient Construction of Benzofurans" Hu, Y.; Kamitanaka, T.; Mishima, Y.; Dohi, T.; *Kita, Y. J. Org. Chem. 2013, 78 (11), pp.5530-5543. |
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"Metal-Free Oxidative para Cross-Coupling of Phenols" Morimoto, K.; Sakamoto, K.; Ohnishi, Y.; Miyamoto, T.; Ito, M.; Dohi, T.; *Kita, Y. Chem. Eur. J. 2013, 19 (27), pp.8276-8731. |
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"Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y J. Am. Chem. Soc. 2013, 135 (11), pp.4558-4566. |
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"Generation of 3-Borylbenzynes, Their Regioselective Diels–Alder Reactions and Theoretical Analysis" Takagi A.; Ikawa T.; Kurita Y.; Saito K.; Azechi K.; Egi M.; Itoh Y.; Tokiwa H.; Kita Y.; Akai S.
Tetrahedron 2013, 69 (21), pp.4338-4352. DOI:10.1016/j.tet.2013.03.016 |
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"Efficient Synthesis of Regioregular Oligothiophene Photovaltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal Catalyzed Synthetic Route" Dohi, T.; Yamaoka, N.; Nakamura, S.; Sumida, K.; Morimoto, K.; *Kita, Y.
Chem. Eur. J. 2013, 19 (6), pp.2067-2075. |
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"Oxidative Trimerization of Catechol to Hexahydroxytriphenylene (HHTP)" Morimoto, K.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2013, (9), pp.1659-1662. |
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"Development of Efficient Generation Method of Ortho-Naphthoquinone Methides Derived from 1,4-Epoxy-1,4-dihydronaphthalenes and Its Unique Annulation Using Allylsilanes" Sawama, Y.; Shishido, Y.; Yanase, T.; Kawamoto, K.; Goto, R.; Monguchi, Y.; Kita, Y. ; Sajiki, H. Angew. Chem. Int. Ed. 2013, 52 (5), pp.1515-1519. |
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"Lewis Acid-Catalyzed Ring-Opening Functionalizations of 1,4-Epoxy-1,4-dihydronaphthalenes" Sawama, Y.; Ogata, Y.; Kawamoto, K.;
Satake, H.; Shibata, K.; Monguchi, Y.;
Sajiki, H.; Kita, Y. Adv. Synth. Catal. 2013, 355 (2-3), pp.517-528. |
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"Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation Toward Functionalized Aryl Boronates" Ito, M.; Itani, I.; Toyoda, Y.; Morimoto, K.; Dohi, T.; *Kita, Y. Angew. Chem. Int. Ed. 2012, 51 (50), pp.12555-12558. |
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"Efficient Synthesis of Oxygenated Terphenyls and other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation–Rearomatization
" Dohi, T.; Kamitanaka, T.; Watanabe, S.; Hu, Y.; Washimi, N.; *Kita, Y.
Chem. Eur. J. 2012, 18 (43), pp.13164-13168. |
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"Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-N-oxyl Organocatalyst" Dohi, T.; Kamitanaka, T.; Mochizuki, E.; Ito, M.; *Kita, Y. Chem. Pharm. Bull. 2012, 60 (11), pp.1442-1447. |
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"Asymmetric Total Synthesis of (−)-Stenine and 9a-epi-Stenine" Fujioka, H.; Nakahara K.; Kotoku, N.; Ohba, H.; Nagatomi, Y.; Wang, T.-L.; Sawama, Y.; Murai, K.; Hirano, K.; Oki, T.; Wakamatsu, S.; *Kita, Y.
Chem. Eur. J. 2012, 18 (43), pp.13861-13870. |
村井健一 | |
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"Controlled Couplings of Quinone Monoacetals Using Reusable Polystyrene-Anchored Specific Proton Catalyst" Dohi, T.; Hu, Y.: Kamitanaka, T.; *Kita, Y. Tetrahedron 2012, 68 (40), pp.8424-8430. DOI:10.1016/j.tet.2012.07.089 |
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"Protecting-Group-Free Catalytic Asymmetric Total Synthesis of (–)-Rosmarinecine " Nemoto, H.; Tanimoto, K.; Kanao, Y.; Omura, S.; Kita, Y.; *Akai, S. Tetrahedron 2012, 68 (36 ), pp.7295-7301. DOI:10.1016/j.tet.2012.06.095 |
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"Hypervalent Iodine-Induced Oxidative Cross Coupling via Thiophene Cation Radical Intermediate" Dohi, T ; Ito, M.; Sekigushi, S.; Ishikado, Y.; *Kita, Y. Heterocycles 2012, 86 (1), pp.767-776. |
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"An Excellent Dual Recycling Strategy for the Hypervalent Iodine/Nitroxyl Radical Mediated Selective Oxidation of Alcohols to Aldehydes and Ketones" Dohi, T.; Fukushima, K.; Kamitanaka, T.; Morimoto, K.; Takenaga, N.; *Kita, Y. Green Chem. 2012, 14 (5), pp.1493-1501. |
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"μ-Oxo-Bridged Hypervalent Iodine(III) Compound as Extreme Oxidant for Aqueous Oxidations" Dohi, T,; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. Synthesis 2012, 44 (8), pp.1183-1189. |
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"Reaction of Acetals with Various Carbon Nucleophiles under Non-Acidic Conditions: C-C Bond Formation via a Pyridinium-Type Salt" Fujioka, H.; Yahata, K.; Hamada, T.; Kubo, O.; Okitsu, T.; Sawama, Y.; Ohnaka, T.; Maegawa, T.; *Kita, Y. Chem. Asian J. 2012, 7 (2), pp.367-373. |
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"Metal-Free C-H Cross-Coupling Toward Oxygenated Naphthalene-Benzene Linked Biaryls" Dohi, T.; Ito, M.; Itani, I.; Yamaoka, N.; Morimoto, K.; Fujioka, H.; *Kita, Y. Org. Lett. 2011, 13 (23), pp.6208-6211. |
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"Metal-Free Oxidative Coupling Reaction via Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagent" Morimoto, K.; Nakae, T.; Yamaoka, N.; Dohi, T.; *Kita, Y. Eur. J. Org. Chem. 2011, (31), pp.6326-6334. |
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"New Synthesis of Spirocycles by Utilizing in situ Forming Hypervalent Iodine Species" Dohi, T.; Nakae, T.; Ishikado, Y.; Kato, D.; *Kita, Y. Org. Biomol. Chem. 2011, 9 (20), pp.6899-6902. |
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"[3+2] Coupling of Quinone Monoacetals by Combined Acid-Hydrogen Bond Donor" Dohi, T.; Hu, Y.; Kamitanaka, T.; Washimi, N.; *Kita, Y. Org. Lett. 2011, 13 (18), pp.4814-4817. |
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"The Synthetic and Biological Studies of Discorhabdins and Related Compounds" Wada, Y.; Harayama, Y.; Kamimura, D.; Yoshida, M.; Shibata, T.; Fujiwara, K.; Morimoto, K.; Fujioka, H.; *Kita, Y. Org. Biomol. Chem. 2011, 9 (13), pp.4959-4976. |
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"ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines " Ikawa, T.; Nishiyama, T.; Shigeta, T.; Mohri, S.; Morita, S.; Takayanagi, S.; Terauchi, Y.; Morikawa, Y.; Takagi, A.; Ishikawa, Y.; Fujii, S.; Kita, Y.; Akai, S. Angew. Chem. Int. Ed. 2011, 50 (25), pp.5674-5677. |
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"Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls" Dohi, T.; Washimi, N.; Kamitanaka, T.; Fukushima, K.; *Kita, Y. Angew. Chem. Int. Ed. 2011, 50 (27), pp.6142-6146. |
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"One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant" Dohi, T.; Yamaoka, N.; Itani, I.; *Kita, Y. Aust. J. Chem. 2011, 64 (5), pp.529-535. |
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"Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes" Dohi, T.; Kato, D.; Hyodo, R.; Yamashita, D.; Shiro, M.; *Kita, Y. Angew. Chem. Int. Ed. 2011, 50 (16), pp.3784-3787. |
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"Efficient Phenolic Oxidations Using μ-Oxo-Bridged Phenyliodine Trifluoroacetate" Dohi, T.; Uchiyama, T.; Yamashita, D.; Washimi, N.; *Kita, Y. Tetrahedron Lett. 2011, 52 (17), pp.2212-2215. DOI:10.1016/j.tetlet.2010.12.037 |
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"Asymmetric Total Synthesis of Clavolonine" Nakahara, K.; Hirano, K.; Maehata, R.; *Kita, Y.; Fujioka, H. Org. Lett. 2011, 13 (8), pp.2015-2017. |
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"Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound" Takenaga, N.; Uchiyama, T.; Kato, D.; Fujioka, H.; Dohi, T.; *Kita, Y. Heterocycles 2011, 82 (2), pp.1327-1336. |
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"Phenyliodine Diacetate-Mediated Oxidative Cleavage of Cyclobutanols Leading to
gamma-Hydroxy Ketones
" Fujioka, H.; Komatsu, H.; Miyoshi, A.; Murai, K.; *Kita, Y. Tetrahedron Lett. 2011, 52 (9), pp.973-975. DOI:10.1016/j.tetlet.2010.12.032 |
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"Intramolecular Iodoetherification of Ene or Diene Ketals: Facile Synthesis of Spiroketals" Fujioka, H.; Nakahara, K.; Hirose, H.; Hirano, K.; Oki, T.; *Kita, Y. Chem. Commun. 2011, 47 (3), pp.1060-1062. |
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| Books |
「CSJ Current Review 22 有機分子触媒の化学 － モノづくりのパラダイムシフト
」 Terada, M. "超原子価ヨウ素触媒反応～メタルフリー酸化的カップリング反応への触媒設計～" Kita, Y.; Dohi, T. 化学同人 (京都) 2016, pp157-166. |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 7: Hypervalent Iodine " Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2015, pp103-157. ISBN:978-1-118-46629-2 |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 15: Oxidizing Agents" Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2014, pp277-301. ISBN:978-1-118-46629-2 |
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「Iodine Chemistry and Application」 Kaiho, T. "Chapter 16: Reaction of Iodo Compounds" Dohi, T.; Kita, Y. Wiley-Blackwell (Hoboken) 2014, pp303-327. ISBN:978-1-118-46629-2 |
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「触媒の設計・応制御 事例集」 "クロスカップリング反応におけるホモカップリング体生成の制御" Kita, Y.; Morimoto, K. 技術情報協会 (東京) 2016, pp413-418. |
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「Natural Products」 Ramawat, K. G.;
Merillon, J.-M. "Makaluvamines and Discorhabdins, and Marine Pyrrole-Imidazole Alkaloids" Fujioka H.; Kita Y. Springer-Verlag (Berlin, Heidelberg) 2016, pp251-284. ISBN:978-3-642-22143-9 |
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「Quinones: Occurrence, Medicinal Uses and Physiological Importance」 Price, E. R.; Johnson, S. C. "Quinone Monoacetal Compounds in Application to Controlled Reactions with Nucleophiles" Dohi, T.; Kita, Y. NOVA Science Publisher (New York) 2016, pp85-140. ISBN:978-1-62618-323-0 |
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「CSJ Current Review 11 未来を拓く元素戦略 - 持続可能な社会を実現する化学」 西原 寛、岩澤伸治、林 克郎、辻 勇人 "超原子価ヨウ素 - 希少金属に代わる酸化剤および触媒としての利用" Kita, Y.; T. Dohi 化学同人 (京都) 2016, pp68-76. ISBN:978-4-7598-1371-5 |
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「Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated Organic Synthesis」 Fuchs, P. L "Ethoxy(trimethylsilyl)acetylene" Kita, Y. John Wiley & Sons (Chichester, UK) 2011, pp289-293. |
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「Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated Organic Synthesis」 Fuchs, P. L "Bis(1-methoxy-2-methyl-1-propenyloxy)-dimethylsilane" Kita, Y. John Wiley & Sons (Chichester, UK) 2011, pp51-52. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "ラジカル還元" Kita, Y.; Fujioka, H. 化学同人 2016, pp148-149. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "ベンザインの反応" Kita, Y.; Akai, S. 化学同人 2016, pp98-99. |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "脱水反応" Kita, Y.; Fujioka, H. 化学同人 2016, pp22-23. |
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「ヨウ素の化学と最新応用技術」 Yokoyama, M. "３配位ヨウ素化合物の反応" Kita, Y.; Dohi, T. シーエムシー出版 2016, pp105-115. ISBN:978-4781304359 |
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| Reviews / Accounts |
"超原子価ヨウ素反応剤の新展開－有機ヨウ素触媒酸化的ビアリールカップリング－" Morimoto, K.; Dohi, T.; Kita, Y. 月刊ファインケミカル 2016, (12), |
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"超原子価ヨウ素を用いる芳香環酸化的クロスカップリングの基本戦略" Dohi, T.; Morimoto, K.; *Kita, Y. SIS ニュースレター 2016, 17 pp.2-10. |
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"Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)" Dohi, T.; *Kita, Y. Top. Curr. Chem. 2016, 373 pp.1-23. |
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"Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents" Dohi, T.; *Kita, Y. Curr. Org. Chem. 2016, 20 (5), pp.580-615. |
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"Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagent" *Kita, Y.; Dohi, T. Chem. Rec. 2015, 15 (5), pp.886-906. |
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"超原子価ヨウ素反応剤の新展開－有機ヨウ素触媒酸化的ビアリールカップリング－" *Kita, Y.; Dohi, T. 月刊ファインケミカル 有機分子触媒の躍進 2014, 43 (6), pp.31-40. |
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"New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3 C-H Oxidations" Dohi, T.; *Kita, Y. ChemCatChem. 2014, 6 (1), pp.76-78. |
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"Iodide Catalyzed Meta-Free Oxidative Coupling Reactions" *Kita Y.; Dohi, T. Shokubai 2012, 54 (4), pp.245-250. |
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"Marine Pyrroloiminoquinone Alkaloids" *Kita Y.; Fujioka H. Top. Curr. Chem. 2012, 309 pp.131-162. |
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"Hypervalent Iodine Induced Metal-Free C-H Cross Coupling to Biaryls " *Kita, Y.; Dohi, T.; Morimoto, K. J. Synth. Org. Chem., Jpn 2011, 69 (11), pp.1241-1250. |
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"Metal-Free Cross-Coupling Using Iodines" *Kita, Y.; Dohi, T. Fain Kemikaru 2011, 40 (12), pp.49-55. |
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"Cross-Coupling Reactions without Use of Rare Metals. From Encounter with Hypervalent Iodine Reagent to Synthesis of Conductive Polymers" *Kita, Y.; Dohi, T.; Morimoto, K. Kagaku 2011, 66 (8), pp.12-18. |
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"～2010年ノーベル化学賞を受賞した～クロスカップリング反応とレアメタルを用いない反応への可能性" *Kita, Y. マテリアルステージ 2011, 64 pp.332. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Oxidative cross-coupling of phenols with aromatic compounds using hypervalent iodine reagent" ○Morimoto, Ｋ.; Sakamoto, K.; Takahashi,
T.; Dohi, T.; *Kita, Y.
19th The Society of Iodine Science Symposium, Chiba (Japan) 2016-09-16～2016-09-16 |
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招待講演 "Metal－Free Oxidative Aryl Coupling Reactions by Hypervalent Iodine Reagent" ○Kita, Y. 5th International Conference on Hypervalent Iodine Chemistry, Les Diablerets (Switzerland) 2016-07-06～2016-07-06 |
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口頭発表／ポスター発表 "Enviromentally-benign glycosylation reaction using thioglycosides with phenyliodine bis(trifluoroacetate) (PIFA)" Kajimoto, T.; Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. 5th International Conference on Hypervalent Iodine Chemistry, Les Diablerets (Switzerland) 2016-07-04～2016-07-04 |
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口頭発表／ポスター発表 "Organo-iodine(III) catalyzed oxidative phenol-arene and phenol-phenol cross-couplings" ○Morimoto, K.; Sakamoto, K.; Takahashi, Y.; Dohi, T. ; Kita Y. The French-Japanese Society of Medicinal and Fine Chemistry, Tokyo (Japan) 2016-05-16～2016-05-16 |
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口頭発表／ポスター発表 "Hypervalent iodine as an excellent promoter of thioglycosides in glycosylation reaction" Kajimoto, T.; ○Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-22～2016-04-22 |
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依頼講演 "Metal-Free Oxidative Biaryl Coupling Reactions by Hypervalent Iodine Reagent" Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Development of Regioselective Introduction of Nucleophiles Toward Quinone Monoacetals by Design of Specific Acid Catalyst" ○Kamitanaka, T.; Washimi, N.; Hu, Y.; Dohi, T.; Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Phenyliodine Bis(trifluoroacetate) (PIFA) as An Excellent Promoter of Thioglycosides in Glycosylation Reaction" Kajimoto, T.; ○Morimoto, K.; Ogawa, R.; Dohi, T.; Kita, Y. Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Enviromentally-Benign Glycosylation Reaction Using Thioglycosides Prepared with An Odorless Thiol and Phenyliodine Bis(trifluoroacetate) (PIFA)" ○Kajimoto, T.; Morimoto, K.; Dohi, T.; Kita, Y Pacifichem 2015, Hawaii (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "New Conceptual Diaryliodonium Salts for Metal-Free Arylation of Carboxylic Acids Giving Aryl Esters" ○Dohi, T.; Sumida, K.; Kato, A.; Samura, K.; Morimoto, K.; *Kita, Y. The 3rd International Symposium on Process Chemistry, Kyoto (Japan) 2015-07-14～2015-07-14 |
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口頭発表／ポスター発表 "Development of New Hypervalent Iodine Catalytic Method in Oxidative Coupling Reactions" ○Dohi, T.; *Kita, Y. 7th International Conference on Green and Sustainable Chemistry, Tokyo (Japan) 2015-07-07～2015-07-07 |
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依頼講演 "Metal-Free Oxidative Coupling Reactions by Hypervalent Iodine Reagent" ○*Kita, Y. 内藤コンファレンス, Sapporo (Japan) 2015-07-06～2015-07-06 |
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口頭発表／ポスター発表 "Hypervalent Iodine(III)-Catalyzed Oxidative Cross-Coupling Reaction of Phenols" ○Morimoto, K.; Sakamoto, K.; Dohi, T.; *Kita, Y. 内藤コンファレンス, Sapporo (Japan) 2015-07-06～2015-07-06 |
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依頼講演 "Recent Progress on Metal-Free Oxidative Coupling Reactions" ○*Kita, Y. 2nd International Conference of Advanced Molecular Transformations by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "A New Carbon-Carbon Bond Forming Strategy for Dearomatizing Spirocyclization by Utilizing Bis(iodoarene) Compounds" ○Nakae, T.; Toyoda, Y.; Miyazaki, K.; Dohi, T.; *Kita, Y. 2nd International Conference of Advanced Molecular Transformations by Organocatalysts, Tokyo (Japan) 2014-11-21～2014-11-21 |
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口頭発表／ポスター発表 "Oxidative Cross Coupling Reaction of Aromatic Compounds Using Hypervalent Iodine(III) Reagent" Morimoto, K.; Ito, M.; Dohi, T.; ○*Kita, Y. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-15～2014-09-15 |
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口頭発表／ポスター発表 "Oxidative C-N Coupling of Azoles with Heteroaromatic Compounds" ○Morimoto, K.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-15～2014-09-15 |
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口頭発表／ポスター発表 "Oxidative Cross-Coupling of Phenols with Aromatic Compounds Using Hypervalent Iodine Reagent" Morimoto, K.; ○Sakamoto, K.; Sakai, S.;Takahashi, Y.; Dohi, T.; *Kita, Y.
17th The Society of Iodine Science Symposium, Chiba (Japan) 2014-09-19～2014-09-19 |
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招待講演 "Metal-Free Oxidative Coupling Reactions" ○*Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "Organocatalytic C-H/C-H Cross-Biaryl-Coupling of Sulfonanilides with Aromatic Compounds" ○Dohi, T.; Ito, M.; Morimoto, K.; *Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "N1-Selective Oxidative C-N Coupling of Azoles with Pyrroles" ○Morimoto, K.; Nakamura, A.; Sakamoto, K.; Dohi, T.; *Kita, Y. 4th International Conference on Hypervalent Iodine Chemsitry, Narita (Japan) 2014-07-03～2014-07-03 |
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口頭発表／ポスター発表 "Efficient Oxidative Cross-Coupling Reaction of Various Phenols" ○Morimoto, K.; Sakamoto, K.; Dohi, T.; *Kita Y. 9th AFMC International Medicinal Chemistry Symposium, Taipei (Taiwan) 2013-10-15～2013-10-18 |
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口頭発表／ポスター発表 "Coupling Reaction of Alkoxyarenes Using Iodonium Salts as Oxidants" Yamaoka, N.; Sumida, K.; ○Nakamura S.; Dohi, T.; *Kita, Y. 16th The Society of Iodine Science Symposium, Chiba (Japan) 2013-09-18～2013-09-18 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Cross-Coupling Reaction of Aromatic Compounds Using Hypervalent Iodine Reagent" ○*Kita, Y.; Dohi, T.; Morimoto, K.; Ito, M. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-27～2013-06-28 |
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口頭発表／ポスター発表 "Controlled Coupling of p-Nucleophiles Toward Quinone Monoacetal, the All Carbon Electrophilic Molecule" ○Dohi, T.; Hu, Y.; Kamitanaka, T.; Washimi, N.; *Kita, Y. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-26～2013-06-27 |
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口頭発表／ポスター発表 "Oxidative Direct Synthesis of Hexahydroxytriphenylene (HHTP)" ○Morimoto, K.; Dohi, T.; *Kita, Y. 14th Tetrahedron Symposium, Vienna (Austria) 2013-06-26～2013-06-27 |
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招待講演 "Hypervalent Iodine Reagent as an Entrance to Metal-Free Oxidative Coupling Reactions" 〇*Kita, Y. 1st International Conference of Advanced Molecular Transformations by Organocatalysts, Ohtsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Metal-Free Coupling Reactions - Hypervalent Iodine-Mediated Synthesis of Biaryl and Heterobiaryl Compounds-" ○*Kita, Y. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "New Oxidative Spirocyclization Utilizing Oxygen-Bridged Hypervalent Iodine Species" ○Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Novel C-C Bond Formation via SET Oxidation with Iodonium Salts" ○Yamaoka, N.; Nakamura, S.; Sumida, K.; Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Brønsted Acid Catalyzed Controlled Coupling of Quinone Monoacetals with Carbon and Other Nucleophiles" ○Hu, Y.; Kamitanaka, T.; Dohi, T.; *Kita, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Coupling Reaction: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagent" ○Morimoto, K.; Yamaoka, N.; Nakae, T.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Efficient Spirocyclization Through Phenolic Oxidations Using Hypervalent Iodine(III) Reagents and Its Application to Natural Product" Morimoto, K.; ○Nakae, T.; Miyamoto, T.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Meta-Free Oxidative Cross-Coupling Reaction of Aromatic Compounds" ○*Kita, Y.; Dohi, T.; Morimoto, K.; Ito, M. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Hypervalent Iodine(III) Mediated Oxidative Cross Coupling Leading to Functionalized Biaryls" ○Ito, M.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "New Synthesis Utilizing Designer oxo-Bridged Hypervalent Iodine Species" ○Dohi, T.; *Kita, Y. ICCOS-2102, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Consise and Expeditious Strategy Toward Oxygenated Terphenyls via Phenol Oxidation-Rearomatization Process" Dohi, T.; ○Kamitanaka, T.; Watanabe, S.; Hu, Y.; Washimi, N.; *Kita, Y. ICCOS-2012, Moscow (Russia) 2012-09-15～2012-09-20 |
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口頭発表／ポスター発表 "Synthesis of Boron-Functionalized Diaryliodonium Salts and Selective Arylation" Ito, M.; ○Toyoda, Y.; Itani, I.; Dohi, T.; *Kita, Y. 15th The Society of Iodine Science Symposium, Chiba (Japan) 2012-09-11～2012-09-11 |
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口頭発表／ポスター発表 "Metal-Free Oxidative Cross-Coupling Reaction of Unfunctionalized Heteroaromatic Compound Using Hypervalent Iodine Reagent" ○*Kita, Y.; Dohi, T.; Morimoto, K. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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口頭発表／ポスター発表 "Versatile and Highly Reactive oxo-Bridged Hypervalent Iodine Compound for Green Oxidation and Catalyst" ○Dohi, T.; Fukushima,, K.; Uchiyama, T.; *Kita, Y. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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口頭発表／ポスター発表 "The Synthetic and Biological Studies of Discorhabdin Analogues" Wada, Y.; ○Morimoto, K.; Fujioka, H.; *Kita, Y. IUPAC ICOS-19, Melbourne (Australia) 2011-06-30～2012-07-05 |
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招待講演 "Power of Iodine - Discovery and Application of Novel Coupling Reactions -" ○*Kita, Y 14th The Society of Iodine Science Symposium, Chiba (Japan) 2011-11-18～2011-11-18 |
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口頭発表／ポスター発表 "The Synthetic and Biological Studies of Discorhabdin Analogues" Wada, Y.; ○Morimoto, K.; Fujioka, H.; *Kita, Y. 8th AFMC International Medicinal Chemistry Symposium “Frontier of Medicinal Science”, Tokyo (Japan) 2011-11-29～2011-12-02 |
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口頭発表／ポスター発表 "Concise Asymmetric Synthesis of Lycopodium Alkaloid, Clavolonine" ○Nakahara, K.; Hirano, K.; Maehata, R.; *Kita, Y.; Fujioka, H. 8th AFMC International Medicinal Chemistry Symposium “Frontier of Medicinal Science”, Tokyo (Japan) 2011-11-29～2011-12-02 |
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口頭発表／ポスター発表 "Novel Arylating Ability of Diaryliodoium Salts" ○Yamaoka, N.; Itani, I.; Itoh, M.; Dohi, T.; *Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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口頭発表／ポスター発表 "Designer µ-Oxo-Bridged Hypervalent Iodine Reagents and Catalysts" ○Dohi, T.; Yamashita, D.; Uchiyama, T.; Fukushima, K.; Katoh, D.; *Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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口頭発表／ポスター発表 "Metal-Free Biaryl Synthesis Using Hypervalnet Iodine Reagents from Unfunctionalized Heteroaromatic Compounds" ○*Kita, Y. 23rd International Congress of Heterocyclic Chemistry, Glasgow (England) 2011-07-31～2011-08-04 |
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依頼講演 "Hypervalent Iodine Metal-Free Cross Coupling Reactions" ○*Kita, Y. First Germany - Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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依頼講演 "Hypervalent Iodine Mediated Phenolic Oxidations – A Road to Metal-free and Asymmetric Organocatalytic Reactions" ○*Kita, Y. 2nd Annual World Congress of Catalytic Asymmetric Synthesis-2011, 北京 (中国) 2011-08-08～2011-08-12 |
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| Patent |
"2,3,6,7,10,11-ヘキサヒドロキシトリフェニレン類の製造方法" 発明者：Morimoto, K.; Dohi, T.; Kita, Y. 出願者：和光純薬工業株式会社
立命館大学 特願2012-174481 2012-08-06, 特許第5882162号 2016-02-05, (国内) |
出願者： 特願 2012-08-06, 特許第5878842号 2016-02-05, (国内) |
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"2,3,6,7,10,11-ヘキサヒドロキシトリフェニレン類の製造方法" 発明者：Morimoto, K.; Dohi, T.; Kita, Y. 出願者：和光純薬工業株式会社
立命館大学 特願2012-174481 2012-08-06, 特許第5878842号 2016-02-05, (国内) |
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"有機色素ＭＫ－２の製造方法" 発明者：*Kita Y.; Dohi, T. 出願者：立命館大学 2012188699 2012-08-29, 2012-08, (国内) |
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| Prize |
"The International Society of Heterocyclic Chemistry (ISHC) シニアフェロー " Kita, Y. 2015-10 The International Society of Heterocyclic Chemistry (ISHC) 本学会および本分野に著しい貢献があった者として、シニアフェローに選出された。 |
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"Angewandte Chemie 審査員章" *Kita, Y. 2015-04 WILEY-VCH 2014 Angewandte Chemie における the top 5% of reviewers として表彰された。 |
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"Angewandte Chemie 審査員章" *Kita, Y. 2014-04 WILEY-VCH 2013 Angewandte Chemie において excellent quality の審査報告を行ったとし、Certificate を贈呈された。 |
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| Media |
"「Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species」（J. Am. Chem. Soc., 2013, 135 (11), 4558.）が、月刊化学の「最新のトピックス」で紹介される" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y. 化学 2014-10-18 |
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"「New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species」（Org. Biomol. Chem., 2011, 9, 6899.）が、同誌の The Top 10% Most Highly Cited Articles に選定" Dohi T., Nakae, T., Ishikado, Y., Kato, D., *Kita, Y. 2014-08-31 |
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"「Organocatalytic C-H/C-H' cross-biaryl-coupling: C-selective arylation of sulfonaniliedes with aromatic hydrocarbons 」（J. Am. Chem. Soc., 2013, 135 (38), 14078.）が、同誌の Most Read Articles: Rank 4 に選定、Synfacts 誌 2013, 9 (12), 1345 に掲載" Ito, M.; Kubo, H.; Itani, I.; Morimoto, K.; Dohi, T.; *Kita, Y.
Synfacts, 2013, 9 (12), 1345 2013-12-01 |
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"「μ-Oxo bridged hypervalent iodine compound as extreme oxidatant for aqueous oxidations」（Synthesis, 2013, 44 (8), 1183.）が、同誌の Most Accessed Articles: Rank 1 に選定" Dohi, T.; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. 2013-10-20 PDF |
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"「Oxidative trimerization of catechol to hexahydroxytriphenylene」（Eur. J. Org. Chem., 2013, (9), 1659.）が、Wiley の Hot Topics に選定 " Morimoto, K.; Dohi, T.; *Kita, Y. 2013-06-30 |
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"「Metal-free oxidative para cross-coupling of phenols」（Chem.-Eur. J., 2013, 19 (27), 8276.）が、同誌のハイライト「Frontispiece」で紹介
、Inside Cover、Hot Topics、Most Accessed Articles in May に選定" Morimoto, K.; Sakamoto, K.; Ohnishi, Y.; Miyamoto, T.; Ito, M.; Dohi, T.; *Kita, Y. 2013-06-30 PDF |
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"「Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species」（J. Am. Chem. Soc., 2013, 135 (11), 4558.）が、Synfacts 誌 2013, 9 (6), 550 に掲載" Dohi, T.; Takenaga, N.; Nakae, T.; Toyoda, Y.; Yamasaki, M.; Shiro, M.; Fujioka, H.; Maruyama, A.; *Kita, Y. Synfacts, 2013, 9 (6), 550. 2013-05-01 |
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"「Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst」（Tetrahedron, 2012, 68 (40), 8424.）が、Synfacts 誌 2012, 8 (11), 1273 に掲載" Dohi, T.; Hu, Y.: Kamitanaka, T.; *Kita, Y. Synfacts, 2012, 8 (11), 1273. 2012-11-01 |
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"「Speedy and clean hypervalent iodine/nitroxyl radical mediated oxidation of alcohols using recyclable adamantane reagent and highly active 2-azaadamantane N-oxyl organocatalyst」（Chem. Pharm. Bull., 2012, 60 (11), 1442.）が、同誌の Front Cover に選定" Dohi, T.; Kamitanaka, T.; Mochizuki, E.; Ito, M.; *Kita, Y. Chem. Pham. Bull. 2012, 60 (11) 2012-11-01 PDF |
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"「μ-Oxo bridged hypervalent iodine compound as extreme oxidant for aqueous oxidations」(Synthesis, 2012, 44 (8), 1183.）が、''Organic Chemistry Portal'' web site で紹介" Dohi, T.; Nakae, T.; Takenaga, N.; Uchiyama, T.; Fukushima, K.; Fujioka, H.; *Kita, Y. 2012-06-30 |
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"「Metal-free C-H cross coupling toward oxygenated naphthalene-benzene linked biaryls」（Org. Lett., 2011, 13 (23), 6208.）が、ACS cross-journal organic chemistry virtual issue, “Cross-Coupling Reactions” のハイライトとして紹介" Dohi, T.; Ito, M.; Itani, I.; Yamaoka, N.; Morimoto, K.; Fujioka, H.; *Kita, Y. J. Org. Chem. 2012, 77(12), 5221. 2012-03-01 |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、雑誌「選択」、「日本の科学アラカルト その最前線― 日本で産出される数少ない資源利用価値が注目されるヨウ素」、に掲載" *Kita, Y. 選択, 2011, (11), pp 90-91. 2011-11-01 PDF |
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"「Coupling of quinone monoacetals promoted by sandwiched Brönsted acids – Synthesis of oxygenated biaryls」（Angew. Chem., Int. Ed., 2011, 50 (27), 6142.）が、同誌の「Hot Papers」に選定" Dohi, T.; Washimi, N.; Kamitanaka, T.; Fukushima, K.; *Kita, Y. 2011-06-30 |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、日本経済新聞17面「知が支える京都産業ー大学と連携、最先端追う」に掲載" *Kita, Y. 日本経済新聞17面 2011-05-04 PDF |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、サムワン春号「元素航海」に掲載" *Kita, Y. サムワン春号, 2011, 15, pp 8-9. 2011-04-01 PDF |
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"超原子価ヨウ素反応剤を用いるメタルフリークロスカップリングに関わる当研究室の成果が、エコノミスト「エコノミストリポートー危機が新産業を生み出すレアメタル代替材料最前線」に掲載" *Kita, Y. エコノミスト, 2011, (2), pp 38. 2011-02-01 PDF |
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| A02 根東 義則 | ||
| Original papers |
"Palladium-Catalyzed Highly Chemoselective Intramolecular C-H Aminocarbonylation of Phenethylamines to Six-Membered Benzolactams" Taneda, H.; Inamoto, K.; *Kondo, Y. Org. Lett. 2016, in press DOI:10.1021/acs.orglett.6b01171 |
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"Development of Madelung-Type Indole Synthesis Using Copper-Catalyzed Amidation/Comdensation Strategy" Abe, M.; Denneval, C.; Nozawa-Kumada, K.; *Kondo, Y. Heterocycles 2016, 92 (5), pp.900-909. DOI:10.3987/COM-16-13440 |
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"Copper-Catalyzed sp3 C-H Aminative Cyclization of 2-Alkyl-N-arylbenzamide: An Approach for the Synthesis of N-Arylisoindolinones" Nozawa-Kumada, Kanako; Kadokawa, Jun; Kameyama, Takehiro; *Kondo, Yoshinori Org. Lett. 2015, 17 (18), pp.4479-4481. DOI:10.1021/acs.orglett.5b02235 |
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"Exploringa DNA Sequence for the Three-Dimensional Structure Dtermination of a Silver(I)-Mediated C-C Base Pair in a DNA Duplex By 1H NMR Spectroscopy" Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Kondo, Yoshinori; Kojima, Chojiroo; Ono, Akira; *Tanaka, Yoshiyuki Nucleosides, Nucleotides & Nucleic Acids 2015, 34 (12), pp.877-900. DOI:10.1080/15257770.2015.1088160 |
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"Direct detection of the mercury-nitrogen bond in the thymine-HgII-thymidine base pair with 199Hg NMR spectroscopy" Dairaku, Takenori; Furuita, Kyoko; Sato, Hajime; Sebara, Jakub; Yamanaka, Daichi; Otaki, Hiroyuki; Kikkawa, Shoko; Kondo, Yoshinori; Katahira, Ritsuko; Matthhias, Bickelhaupt; *Tanaka, Yoshiyuki Chem. Commun. 2015, 51 (40), pp.8488-8491. DOI:10.1039/C5CC02423D |
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"Deprotonative C-H solylation of functionalizaed arenes
and heteroarenes using trimethyl -trialkylsilane with fluoride" Sasaki, M.; *Kondo, Y. Org. Lett. 2015, 17 (4), pp.848-851. DOI:10.1021/ol503671b |
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"Use of tetramehylammonium fluoride (TMAF) and alkali
metal alkoxides as an activator for catalytic deprotonative functionalization
of heteroaromatic C(sp2)-H" *Inamoto, K.; Okawa, H.; Kikkawa, S.; *Kondo,
Y. Tetrahedron 2014, 70 (43), pp.7917-7922. DOI:10.1016/j.tet.2014.08.054 |
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"Direct condensation of functionalized sp3 carbons with
formamides for enamine synthesis using an in situ generated HMDS amide catalyst" Taneda, H.; Inamoto, K.; *Kondo,
Y. Chem. Commun. 2014, 50 (49), pp.6523-6525. DOI:10.1039/c4cc02228a |
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"Desilylative carboxylation of aryltrimethylsilanes
using CO2 in the presence of catalytic phosphazenium salt" Yonemoto-Kobayashi, M.; Inamoto, K.; *Kondo,
Y. Chem. Lett. 2014, 43 (4), pp.477-479. DOI:10.1246/cl.131108 |
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"Facile deprotection of dithioacetals by using a novel
1,4-benzoquinone/cat. NaI system" *Inamoto, K.; Yamada, T.; Kato S.;
Kikkawa, S.; *Kondo, Y. Tetrahedron 2013, 69 (44), pp.9192-9199. DOI:10.1016/j.tet.2013.08.061 |
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"Ruthenium -catalyzed
Carbonylative C-H cyclization of 2-arylphenols: a novel synthetic route to
6H-dibenzo[b,d]pyran-6-ones" *Inamoto, K.; Kadokawa, J.; *Kondo, Y. Org. Lett. 2013, 15 (15), pp.3962-3965. DOI:10.1021/0l401734m |
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"Organocatalytic functionalization of heteroaromatic
N-oxides with C-nucleopjiles using in situ generated onium amide bases" Inamoto, K.; Araki, Y.; Kikkawa S.;
Yonemoto, M.; Tanaka, Y.; *Kondo, Y. Org. Biomol. Chem. 2013, 11 (27), pp.4438-4441. DOI:10.1039/c3ob40782a |
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"Raman spectroscopic detection of the T-HgII-T base pair and the ionic characteristics of mercury" Uchiyama, T.; Miura, T.; Takeuchi, H.; Dairaku, T.; Komuro, T.; Kawamura, T.; Kondo, Y.; Benda, L.; *Sychrovsky, V.; Bour, P.; *Okamoto, I.; Ono, A.; *Tanaka, Y. Nucleic Acids Research 2012, 40 (12), pp.5766-5774. |
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"Carboxylation of alkynylsilanes with carbon dioxide mediated by sesium fluoride in DMSO" Yonemoto-Kobayashi, M.; Inamoto, K.; Tanaka, Y.; *Kondo, Y. Org. Biomol. Chem. 2013, 11 (23), pp.3773-3775. |
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"Organocatalytic deprotonative functionalization of C(sp2)-H and C(sp3)-H bonds using in situ generated onium amide bases" *Inamoto, K.; Okawa, H.; Taneda, H.; Sato, N.; Hirono, Y.; Yonemoto, M. Kikkawa, S.; *Kondo, Y. Chem. Commun. 2012, 48 (78), pp.9771-9773. DOI:10.1039/c2cc35701a |
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"Palladium-catalyzed C-H cyclization in water: a milder route to 2-arylbenzothiazole" *Inamoto, K.; Nozawa, K.; *Kondo, Y. Synlett 2012, 23 (11), pp.1678-1682. DOI:10.1055/s-0031-1291164 |
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"Efficient use of a surfactant for copper-catalyzed coupling reaction of arylboronic acids with imidazoles in water" *Inamoto, K.; Nozawa, K.; Kadokawa, J.; *Kondo, Y. Tetrahedron 2012, 68 (38), pp.7794-7798. DOI:10.1015/j.tet.2012.07.042 |
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"Synthesis of 3-Carboxylated Indole trough a Tandem Process Involving Cyclization of 2-Ethynylanilines Followed by CO2 Fixation in the Absence of Transition Metal Catalysts" +Inamoto, K.; Asano, N.; Nakamura, Y.; Yonemoto, M.; *Kondo, Y. Org. Lett. 2012, 14 (10), pp.2622-2625. DOI:10.1021/ol300958c |
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"Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinoplinones" *Inamoto, K.; Kawasaki, J.; Hiroya, K.; Kondo, Y.; *Doi, T. Chem. Commun. 2012, 48 (36), pp.4332-4334. DOI:10. 1039/c2cc30600 |
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"Functionalizaztion of heteroaromatic N-oxides using organic superbase catalyst" Araki, Y.; Kobayashi, K.; Yonemoto, M.; *Kondo, Y. Org. Biomol. Chem. 2011, 9 (1), pp.78-80. |
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"Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols" *Inamoto, K.; Nozawa, K.; Yonemto, M.; *Kondo, Y. Chem. Commun. 2011, 47 (42), pp.11775-11777. |
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"A copper-based catalytic system for carboxylation of terminal alkynes: synthesis of alkyl 2-alkynoates" *Inamoto, K.; Asano, N.; Kobayashi, K.; Yonemoto, M.; *Kondo, Y. Org. Biomol. Chem. 2012, 10 (8), pp.1514-1516. |
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"Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding aby transition metal catalyst" *Inamoto, K.; Hasegawa, C.; hiroya, K.; Kondo, Y.; Osako, T.; Uozumi, Y.; *Doi, T. Chem. Commun. 2012, 48 (23), pp.2912-2914. |
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| A02 竹本 佳司 | ||
| Original papers |
"Chiral Integrated Catalysts Composed of Bifunctional Thiourea and Arylboronic Acid: Asymmetric Aza-Michael Addition of α,β-Unsaturated Carboxylic Acids" Hayama, N.; Azuma, T.; Kobayashi, Y.; *Takemoto，Y. Chem. Pharm. Bull. 2016, 64 (7), |
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"Synthesis and application of tetrahydro-2H-fluorenes via a Pd(0)-catalyzed benzylic C(sp3)–H functionalization" Suetsugu, S.; Muto, N.; Horinouchi, M.; Tsukano, C.; *Takemoto, Y. Chem. Eur. J. 2016, |
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"Synthesis of CPZEN-45: Construction of the 1,4-Diazepin-2-one Core by the Cu-catalyzed Intramolecular Amidation of a Vinyl Iodide" Nakamura, H.; Yoshida, T.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2016, 18 (20), pp.2300-2303. DOI:10.1021/acs.orglett.6b00943 |
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"
Proton Transfer Mechanism of Organocatalyzed Isomerization of Alkynoates into Allenoates: Enantioselectivity and Reversibility. A DFT Study
" Xiao, H.; Kobayashi, Y.; Takemoto, Y.; *Morokuma, K. ACS Catal. 2016, 6 (5), pp.2988-2996. DOI:10.1021/acscatal.6b00038 |
Keiji Morokuma | |
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"Catalytic asymmetric synthesis of anti-α,β-diamino acid derivatives" Izumi, S.; Kobayashi, Y.; *Takemoto; Y. Org. Lett. 2016, 18 (4), pp.696-699. DOI:10.1021/acs.orglett.5b03666 |
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"Synthetic studies towards communesins: Diastereoselective oxidative rearrangement of aurantioclavine derivatives" Suetsugu, S.; Tsukano, C.; *Takemoto, Y. Eur. J. Org. Chem. 2016, (1), pp.108-115. DOI:10.1002/ejoc.201501194 |
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"Catalytic asymmetric formal synthesis of beraprost" Kobayashi, Y.; Kuramoto, R.; *Takemoto, Y. Beilstein J. Org. Chem. 2015, 11 (1), pp.2654-2660. DOI:10.3762/bjoc.11.285 |
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"Synthesis of α-acyloxyketone derivatives via the platinum-catalyzed migration of propargylic esters" Tsukano, C.; Yamamoto, S.; *Takemoto, Y. Chem. Pharm. Bull. 2015, 63 (9), pp.710-719. DOI:org/10.1248/cpb.c15-00417 |
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"Direct dehydroxylative coupling reaction of alcohols with organosilanes
through Si–X bond activation by halogen bonding" Saito, M.; Tsuji, N.; Kobayashi, Y.; *Takemoto, Y. Org. Lett. 2015, 17 (12), pp.3000-3003. DOI:10.1021/acs.orglett.5b01290 |
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"Total Synthesis of (–)-Caprazamycin A" Nakamura, H.; Tsukano, C.; Yasui, M.; Yokouchi, S.; Igarashi, M.; *Takemoto, Y. Angew. Chem. Int. Ed. 2015, 54 (10), pp.3136-3139. DOI:10.1002/anie.201411954 |
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"Direct Photoinduced Electron Transfer from Excited State of Rhodamine B for Carbon-Radical Generation" Yoshioka, E.; *Kohtani, S.; Jichu, T.; Fukazawa, T.; Nagai, T.; Takemoto, Y.; *Miyabe, H. Synlett 2015, 2 (26), pp.265-270. DOI:10.1055/s-0034-1379699 |
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"Electrophilic iodine(I) compounds induced semipinacol rearrangement via C–X bond cleavage" Tsuji, N.; Kobayashi, Y.; *Takemoto, Y. Chem. Commun. 2014, 89 (50), pp.13691-13694. DOI:10.1039/c4cc06014h |
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"Catalytic asymmetric synthesis of the pentacyclic core of (−)-nakadomarin A via oxazolidine as an iminium cation equivalent" Tsuji, N.; Stadler, M.; Naoya Kazumi; Inokuma, T.; Kobayashi, Y.; *Takemoto, Y. Org. Biomol. Chem. 2014, 40 (12), pp.7919-7922. DOI:10.1039/c4ob01678e |
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"Asymmetric Synthesis of Trisubstituted Oxazolidinones by the Thiourea-Catalyzed Aldol Reaction of 2‑Isocyanatomalonate Diester" Sakamoto, S.; Kazumi, N.; Kobayashi, Y.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2014, 18 (16), pp.4758-4761. DOI:10.1021/ol502198e |
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"Synthesis of 3,3-Disubstituted 2-Aminoindolenines by Palladium-Catalyzed Allylic Amidination with Isocyanide" Nanjo, T.; Tsukano, C.; *Takemoto, Y. Synlett 2014, 25 (10), pp.1473-1477. DOI:10.1055/s-0033-1341241 |
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"Synthesis of Pyrrolophenanthridine Alkaloids Based on C(sp3)-H and C(sp2)-H Functionalization Reactions" Tsukano, C.; Muto, N.; Enkhtaivan, I.; *Takemoto, Y. Chem. Asian J. 2014, 9 (9), pp.2628-2634. DOI:org/10.1002/asia.201402490 |
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"A Dual Arylboronic Acid–Aminothiourea Catalytic System for the Asymmetric Intramolecular Hetero-Michael Reaction of α,β-Unsaturated Carboxylic Acids" Azuma, T.; Murata, A.; Kobayashi, Y.; Inokuma, T.; *Takemoto, Y. Org. Lett. 2014, 16 (16), pp.4256-4259. DOI:10.1021/ol501954r |
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"Synthesis of 3,3-disubstituted indoline-2-thiones catalysed by an N-heterocyclic carbene" Ikota, H.; Ishida, T.; Tsukano, C.; *Takemoto, Y. Chem. Commun. 2014, 50 (64), pp.8871-8874. DOI:10.1039/C4CC04047C |
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"A diversity-oriented synthesis of caroverine derivatives via TEMPO-promoted aerobic oxidative CAN bond formation" Kobayashi, Y.; Suzuki, Y.; Ogata, T.; Kimachi, T.; *Takemoto, Y. Tetrahedron Lett. 2014, 55 (22), pp.3299-3301. DOI:10.1016/j.tetlet.2014.03.061 |
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"Synthesis of Functionalized Polycyclic Aromatic Compounds via a Formal [2 + 2]-Cycloaddition" Nagamoto, Y.; Yamaoka, Y.; Fujimura, S.; *Takemoto, Y.; Takasu, K., Org. Lett. 2014, 16 (3), pp.1008-1011. DOI:10.1021/ol403757e |
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"Palladium(0)-Catalyzed Carbon-Hydrogen Bond Functionalization for the Synthesis of Indoloquinazolinones" Tsukano, C.; Okuno, M.; Nishiguchi, H.; *Takemoto, Y. Adv. Synth. Catal. 2014, 356 (7), pp.1533-1538. DOI:10.1002/adsc.201400078 |
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"Oxidant-Resistant Hydrogen-Bond-Donating Organocatalyst for Enantioselective Nucleophilic Epoxidation of α,β-Unsaturated Amides" Kobayashi, Y.; Li, S.; *Takemoto, Y., Asian J. Org. Chem. 2014, 3 (4), pp.403-407. DOI:10.1002/ajoc.201400031 |
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"Synthetic Study of Matrine-Type Alkaloids: Stereoselective Construction of the AB Rings of the Quinolizidine Skeleton" Tsukano, C.; Oimura, A.; Enkhtaivan, I.; *Takemoto, Y. Synlett 2014, 25 (5), pp.653-656. DOI:10.1055/s-0033-1340179 |
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"Asymmetric Synthesis of (–)-Aurantioclavine via Palladium-Catalyzed Intramolecular Allylic Amination" Suetsugu, S.; Nishiguchi, H.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2014, 16 (2), pp.996-999. DOI:10.1021/ol4037314 |
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"Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms Using Snap-Shot Structural Analysis" Azuma, T.; Kobayashi, Y.; Sakata, K.; Sasamori, T.; Tokitoh, N.; *Takemoto, Y. J. Org. Chem. 2014, 79 (4), pp.1805-1817. DOI:10.1021/jo4028775 |
Ken Sakata | |
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"Studies on the Oxidative Cyclization of 3-Hydroxyalkyl-1,2,4-trialkoxynaphthalenes and Synthetic Application for the Biologically Active Natural Compound Rhinacanthone" Ogata, T.; Doe, M.; Matsubara, A.; Torii, E.; Nishiura,
C.; Nishiuchi, A.; Kobayashi, Y.; *Kimachi, T. Tetrahedron 2014, 70 (2), pp.502-509. DOI:10.1016/j.tet.2013.11.025 |
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"Dearomatizing Conjugate Addition to Quinolinyl Amidines for the Synthesis of Dehaloperophoramidine through Tandem Arylation and Allylation" Ishida, T.; Ikota, H.; Kurahashi, K.; Tsukano, C.; *Takemoto, Y. Angew. Chem. Int. Ed. 2013, 52 (39), pp.10204-10207. DOI:doi.org/10.1002/anie.201305581 |
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"Synthesis of Spirooxindole from Carbamoyl Chlorides via Cyclopropyl Methine C(sp3)-H Activation using Palladium Catalyst" Tsukano, C.; Okuno, M.; *Takemoto, Y. Chem. Lett. 2013, 42 (7), pp.753-755. DOI:doi.org/10.1246/cl.130228 |
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"A Powerful Hydrogen-Bond-Donating Organocatalyst for the Enantioselective Intramolecular Oxa-Michael Reaction of α,β-Unactivated Amides and Esters" Kobayashi, Y.; Taniguchi, Y.; Hayama, N.; Inokuma, T.; *Takemoto, Y. Angew. Chem. Int. Ed. 2013, 52 (42), pp.11114-11118. DOI:doi.org/10.1002/anie.201305492 |
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"Synthesis of 3-Acyl-2-arylindole via Palladium-catalyzed Isocyanide Insertion and Oxypalladation of Alkyne" Nanjo, T.; Yamamoto, S.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2013, 15 (14), pp.3754-3757. DOI:10.1021/ol4016699 |
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"Selective Synthesis of Polysubstituted Dihydroquinolines and α,β-Unsaturated Amidines by a Catalytic Reaction of Ynamides with Ketimines" Kuroda, Y.; Shindoh, N.; Takemoto, Y.; *Takasu, K. Synthesis 2013, 45 (16), pp.2328-2336. DOI:10.1055/s-0033-1339191 |
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"Cascade radical reaction of substrates with a carbon–carbon triple bond as a radical acceptor" Miyabe, H.; Asada, R.; *Takemoto, Y. Beilstein J. Org. Chem. 2013, 9 pp.1148-1155. DOI:10.3762/bjoc.9.128 |
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"Synthetic study of perophoramidine: construction of pentacyclic core structure via SmI2-mediated reductive cyclization" Ishida, T.; *Takemoto, Y. Tetrahedron 2013, 69 (23), pp.4517-4523. DOI:10.1016/j.tet.2013.04.039 |
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"Total Syntheses of Complanadines A and B" Zhao, L.; *Tsukano, C.; Kwon, E.; Takemoto, Y.; Hirama, M. Angew. Chem. Int. Ed. 2013, 52 (6), pp.1722-1725. DOI:10.1002/anie.201208297 |
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"Gold(I)-Catalyzed Polycyclizations of Polyenyne-Type Anilines Based on Hydroamination and Consecutive Hydroarylation Cascade" Hirano, K.; Inaba, Y.; Takasu, K.; Oishi, S.; Takemoto, Y.; Fujii, N.; *Ohno, H. J. Org. Chem. 2011, 76 (21), pp.9068-9080. DOI:10.1021/jo2018119 |
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"Regio- and Enantioselective Allylic Substitution with Less Active N- or O-Nucleophiles Catalyzed by Iridium-Complex of Bis(oxazolinyl)pyridine" Miyabe, H.; Moriyama, K.; *Takemoto, Y. Chem. Pharm. Bull. 2011, 59 (6), pp.714-720. DOI:10.1248/cpb.59.714 |
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"Polarity-Mismatched Addition of Electrophilic Carbon Radicals to an Electron Deficient Acceptor: Cascade Radical Addition-Cyclization-Trapping Reaction" Yoshioka, E.; Kohtani, S.; Sawai, K.; Tanaka, E.; *Miyabe, H. J. Org. Chem. 2012, 77 (19), pp.8588-8604. DOI:10.1021/jo3015227 |
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"Adsorptive and Kinetic Properties on Photocatalytic Hydrogenation of Aromatic Ketones upon UV Irradiated Polycrystalline Titanium Dioxide: Differences between Acetophenone and its Trifluoromethylated Derivative" *Kohtani, S.; Yoshioka, E.; Saito, K.; Kudo, A.; *Miyabe, H. J. Phy. Chem. C 2012, 116 (33), pp.17705-17713. DOI:10.1021/jp3056174 |
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"Insertion of Arynes into the Carbon-Oxygen Double Bond of Amides And Its Application into the Sequential Reactions" Yoshioka, E.; *Miyabe, H. Tetrahedron 2012, 68 (1), pp.179-189. DOI:10.1016/j.tet.2011.10.072 |
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"Cascade Radical Reaction Induced by Polarity-Mismatched Perfluoroalkylation" Yoshioka, E.; Wang, KX.; Kohtani, S.; *Miyabe, H. Synlett 2011, (14), pp.2085-2089. DOI:10.1055/s-0030-1261167 |
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"A Multicomponent Coupling Reaction Induced by Insertion of Arynes into C=O Bond of Formamide
" Yoshioka, E.; Kohtani, S.; *Miyabe,H. Angew. Chem. Int. Ed. 2011, 50 (29), pp.6638-6642. DOI:10.1002/anie.201102088 |
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"Expression and Function of PD-1 in Human gdT Cell That Recognize Phosphoantigens" Iwasaki, M.; *Tanaka, Y.; Kobayashi, H.; Murata-Hirai, K. Miyabe, H.; Sugie, T.; Toi, M.; Minato,N. Eur. J. Immunology 2011, 41 (2), pp.345-355. DOI:10.1002/eji.201040959 |
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"
Highly Efficient Synthesis of Quinoxalinone-N-oxide via Tandem Nitrosation/Aerobic Oxidative C–N Bond Formation" Kobayashi, Y.; Kuroda, M.; Toba, N.; Okada, M.; Tanaka, R.; *Kimachi, T. Org. Lett. 2011, 13 (23), pp.6280-6283. DOI:10.1021/ol202760c |
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"Asymmetric total synthesis of biologically active (–)-dehydroiso-β-lapachone and the determination of its absolute configuration" Kimachi, T.; Torii, E.; Kobayashi, Y.; Doe, M.; *Ju-ichi, M. Chem. Pharm. Bull. 2011, 59 (6), pp.753-756. DOI:10.1248/cpb.59.753 |
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"α-Dimethylaminomethylenation-induced Houben–Hoesch-type cyclization of cyanoacetanilides: A practical synthesis of 3-formyl-4-hydroxyquinolin-2(1H)-ones" Kobayashi, Y.; Nakatani, T.; Tanaka, R.; Okada, M.; Torii, E.; Harayama, T.; *Kimachi, T. Tetrahedron 2011, 67 (19), pp.3457-3463. DOI:10.1016/j.tet.2011.03.040 |
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"Regioselective ring-opening reaction of unsymmetrical 2,3-diaryl epoxides via catalytic hydrogenolysis with Pd(0)EnCatTM" Kimachi, T.; Nagata, H.; Kobayashi, Y.; Takahashi, K.; Torii, E.; *Ju-ichi, M. Synlett 2011, (3), pp.365-368. DOI:10.1055/s-0030-1259505 |
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"pH-sensitive DNA cleaving agents: in situ activation by ring contraction of benzo-fused cyclobutanols" Nagamoto, Y.; Hattori, A.; Kakeya, H.; *Takemoto, Y.; *Takasu, K. Chem. Commun. 2013, 49 (26), pp.2622-2624. DOI:10.1039/c3cc39246e |
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"Study of Ring-Opening Reaction of Spiro[5.2]octenes with Aqueous Hydrohalic Acid: Substituent Effect on the Regioselectivity" Nagamoto, Y.; *Takemoto, Y.; *Takasu, K., Synlett 2013, 24 (1), pp.120-124. DOI:10.1055/s-0032-1317745 |
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"N-Heterocyclic carbene catalyzed direct cross-aza-benzoin reaction: Efficient synthesis of α–amino-β-keto esters" Uno, T.; Kobayashi, Y.; *Takemoto, Y. Beilstein Journal of Organic Chemistry 2012, 8 pp.1499-1504. DOI:10.3762/bjoc.8.169 |
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"Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)–H Activation: Concise Synthesis of Indole Derivatives" Nanjo, T.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2012, 14 (16), pp.4270-4273. DOI:DOI: 10.1021/ol302035j |
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"Platinum catalyzed 7-endo cyclization of internal alkynyl amides and its application to synthesis of the caprazamycin core" Tsukano, T.; Yokouchi, S.; Girard, A.-L.; Kuribayashi, T.; Sakamoto, S.; Enomoto, T.; *Takemoto, Y. Org. Biomol. Chem. 2012, 10 (30), pp.6074-6086. DOI:10.1039/C2OB25111F |
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"Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates via Dynamic Kinetic Resolution" Inokuma,T.; Furukawa, M.; Suzuki, Y.; Kimachi, T.; Kobayashi, Y.; *Takemoto, Y. ChemCatChem. 2012, 4 (7), pp.983-985. DOI:10.1002/cctc.201200065 |
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"Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization-(2+2) cycloaddition" Inanaga, K.; Ogawa, Y.; Nagamoto, Y. Daigaku, A.; Tokuyama, H.; *Takemoto, Y.; Takasu, K. Beilstein Journal of Organic Chemistry 2012, 8 pp.658-661. DOI:10.3762/bjoc.8.73 |
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"Synthesis of Highly Oxidized Quinolizidine via Reduction of Acylpyridinium Cation, and Total Syntheses of Quinolizidines 207I and 1-epi-207I" Tsukano, C.; Oimura, A.; Enkhtaivan, I.; *Takemoto, Y. Org. Lett. 2012, 14 (7), pp.1902-1905. DOI:10.1021/ol300541u |
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"Lewis acid-mediated radical cyclization: Stereocontrol in cascade radical addition-cyclization-trapping reactions" Miyabe, H.; Asada, R.; *Takemoto, Y. Org. Biomol. Chem. 2012, 10 (17), pp.3519-3530. DOI:10.1039/c2ob25073j |
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"Room-Temperature, Acid-Catalyzed [2+2] Cycloadditions: Suppression of Side Reactions by using a Flow Microreactor System" Kurahashi, K.; *Takemoto, Y.; Takasu, K. ChemCatChem. 2012, 5 (2), pp.270-273. DOI:10.1002/cssc.201100373 |
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"Palladium-Catalyzed Amidation by Chemoselective C(sp3)-H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor" Tsukano, C.; Okuno, M.; *Takemoto, Y. Angew. Chem. Int. Ed. 2012, 51 (11), pp.2763-2766. DOI:10.1002/anie.201108889 |
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"Synthesis of 2-Iminoindolines via Samarium Diiodide Mediated Reductive Cyclization of Carbodiimides" Ishida, T.; Tsukano, C.; *Takemoto, Y. Chem. Lett. 2012, 1 (41), pp.44-46. DOI:10.1246/cl.2012.44 |
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"Catalyst-Controlled Torquoselectivity Switch in the 4π Ring-Opening Reaction of 2-Amino-2-azetines Giving β-Substituted α,β-Unsaturated Amidines" Shindoh, N.; Kitaura, K.; *Takemoto, Y.; *Takasu, K. J. Am. Chem. Soc. 2011, 22 (133), pp.8470-8473. DOI:10.1021/ja202576e |
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"Unprecedented Synthesis of N,N-Divinylamines by Tf2NH-Catalyzed Reaction of Ynamide with Ketimine" Shindoh, N.; *Takemoto, Y.; *Takasu, K. Heterocycles 2011, 2 (82), pp.1133-1136. |
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"Control of 6-Exo and 7-Endo Cyclization of Alkynylamides using Platinum and Bismuth Catalysts" Girard, A.-L.; Enomoto, T.; Yokouchi, S.; Tsukano, C.; *Takemoto, Y. Chem. Asian J. 2011, 6 (6), pp.1321-1324. DOI:10.1002/asia.201100209 |
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"Flexible Strategy for Syntheses of Spirooxindoles using Palladium-Catalyzed Carbosilylation and Sakurai-Type Cyclization" Hande, S. M.; Nakajima, M.; Kamisaki, H.; Tsukano, C.; *Takemoto, Y. Org. Lett. 2011, 7 (13), pp.1828-1831. DOI:10.1021/ol2003447 |
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"Synthetic studies of salinosporamide A through intramolecular hydroamidation of alkynes" Kamisaki, H.; Kobayashi, Y.; Kimachi, T.; Yasui, Y.; *Takemoto, Y. J. Organomet. Chem. 2011, 1 (696), pp.42-45. DOI:10.1016/j.jorganochem.2010.06.021 |
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"Domino Pd-Catalyzed Heck Cyclization and Bi-Catalyzed Hydroamination: Formal Synthesis of Elacomine and Isoelacomine" Kamisaki, H.; Nanjo, T.; Tsukano, C.; *Takemoto, Y. Chem. Eur. J. 2011, 2 (17), pp.626-633. DOI:10.1002/chem.201002287 |
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"NHC-catalyzed Thioesterification of Aldehydes by External Redox Activation" Uno, T.; Inokuma, T.; *Takemoto, Y. Chem. Commun. 2012, 13 (48), pp.1901-1903. DOI:10.1039/c2cc17183j |
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"Formal (3+3) cycloaddition of silyl enol ethers catalyzed by trifric imide: Domino Michael addition-Claisen condensation accompanied with isomerization of silyl enol ethers" Azuma, T.; *Takemoto, Y.; *Takasu, K. Chem. Pharm. Bull. 2011, 9 (59), pp.1190-1193. DOI:10.1248/cpb.59.1190 |
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"Bifunctional Hydrogen-Bond Donors That Bear a Quinazoline or Benzothiadiazine Skeleton for Asymmetric Organocatalysis" Inokuma, T.; Furukawa, M.; Uno, T.; Suzuki, Y.; Yoshida, K.; Yano, Y.; Matsuzaki, K.; *Takemoto, Y. Chem. Eur. J. 2011, 37 (17), pp.10470-10477. DOI:10.1002/chem.201101338 |
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"Synthesis of Optically Active N-Aryl Amino Acid Derivatives through the Asymmetric Petasis Reaction Catalyzed by Novel Hydroxy-thiourea" Inokuma, T.; Suzuki, Y.; Sakaeda, T.; *Takemoto, Y. Chem. Asian J. 2011, 11 (6), pp.2902-2906. DOI:10.1002/asia.201100453 |
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"Organocatalytic Asymmetric Neber Reaction for the Synthesis of 2H-Azirine Carboxylic Esters" Sakamoto, S.; Inokuma, T.; *Takemoto, Y. Org. Lett. 2011, 24 (13), pp.6374-6377. DOI:10.1021/ol2026747 |
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| Books |
「
Topics in Heterocyclic Chemistry “Guanidines as Reagents and Catalysts”
」 Selig P. "Bifunctional Guanidines as Hydrogen-Bond Donating Catalysts" Kobayashi, Y.; *Takemoto, Y. Springer (Berlin) 2015, pp1-24. ISSN:1861-9282 |
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「Comprehensive Organic Synthesis, 2nd edition, Vol. 1, Additions to C-X π-Bonds Part 1」 Molander G. A.; Knochel P. "Carbonyl and Imine Activation" Miyabe, H.; Takemoto, Y. Elsevier (Oxford) 2014, pp751-769. ISBN:978-0-08-097743-0 |
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「遺伝子医学 MOOK 20，ナノバイオ技術と最新創薬応用研究」 橋田充, 佐治英郎 "多環性アルカロイドからの新規抗癌剤シード化合物創製" 塚野千尋, 竹本佳司 メディカル ドｳ (大阪) 2012, pp66-71. |
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「Hydrogenation」 Karamé, I. "Photocatalytic Hydrogenation on Semiconductor Particles" Kohtani, S.; Yoshioka, E.; Miyabe, H. INTECH (Croatia) 2012, pp291-308. |
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「Occurrence, Characteristics and Applications」 Fukui, C. Ono, M. "Progress in Iridium-Catalyzed Allylic Substitutions, Iridium" Miyabe,H. Nova Science Pub Inc (NY) 2012, pp113-138. |
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「Comprehensive Chirality. In Volume 4 (Synthetic Methods III - Catalytic Methods: C-C Bond Formation)」 Yamamoto, H. Carreira, E. "4.15 C-C Bond Formation (Radical)" Miyabe, H.; Naito, T. ELSEVIER Ltd (Amsterdam) 2013, pp303-314. |
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「Heterocycles in Natural Product Synthesis」 Majumdar, K. C.; Chattopadhyay, S. K., "Chapter 5: Pyran and Its Derivatives" Miyabe, H.; Miyata, O.; Naito, T. WILEY-VCH (Weinheim) 2011, pp153-186. |
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「Asymmetric Synthesis II: More Methods and Applications」 Christmann, C.; Bräse, S. "Bifunctional Thiourea Catalysts" Takemoto, Y.; Inokuma, T. Wiley-VCH (Weinheim) 2012, pp233-237. ISBN:978-3-527-32900-7 |
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「Comprehensive Chirality, Volumr 6, Synthetic Methods V - Organocatalysis」 Maruoka, K.; Editors-in-Chief: Carreira, E. M.; Yamamoto, H. "6.2. C-C Bond Formation: Michael Reaction" Takemoto, Y.; Stadler, M. Elsevier Science (Oxford) 2012, pp37-68. ISBN:978-0-08-095168-3 |
Maruoka, K. | |
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「Science of Synthesis, Asymmetric Organocatalysis 2,Brønsted Base and Acid Catalysts, and Additional Topics」 Maruoka, K "Bifunctional (Thio)urea and BINOL Catalysts" Inokuma, T.; Takemoto, Y. Thieme (Stuttgart) 2012, pp437-497. |
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| Reviews / Accounts |
"Synthetic Approaches to Spiro-oxindoles and Iminoindolines Based on Formation of C2–C3 Bond" Tsukano, C.; *Takemoto, Y. Heterocycles 2014, 10 (89), pp.2271-2302. DOI:10.3987/REV-14-805 |
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"Cascade radical reactions via carbon-carbon/heteroatom bond-forming process" *Miyabe, H.; Takemoto, Y. Universal Organic Chemistry 2014, 2 (1), DOI:10.7243/2053-7670-2-1 |
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"Development of innovative hydrogen-bond-donor catalysts based on heterocyclic scaffolds and their applications to asymmetric reactions" Kobayashi, Y.; Inokuma, T.; *Takemoto, Y., J. Synth. Org. Chem. Jpn 2013, 71 (5), pp.491-502. |
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"Inter- and Intramolecular Carbon-Carbon Bond-Forming Radical Reactions" Miyabe,H. Synlett 2012, 23 (12), pp.1709-1724. DOI:10.1055/s-0031-1290378 |
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"An efficient construction of nitrogen-containing heterocycles utilizing CN functional groups and its application to the synthesis of natural products" Kobayashi, Y. Yakugaku Zasshi 2011, 131, pp.1037-1046. |
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"Thiourea,N-[3,5-BIS(TRIFLUOROMETHYL)PHENYL] -N-[(1R,2R)-2- (DIMETHYLAMINO)CYCLOHEXYL]-" Takasu, K.; *Takemoto, Y. e-EROS 2012, |
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| Conference / Symposium / Lecture |
招待講演 "水素結合を活用したマルチタスク触媒の設計と不斉合成への展開" 竹本佳司 第73回パネル討論会「有機分子触媒の精密設計に基づく高度分子変換」, 岡山県岡山市 (日本) 2016-05-21～2016-05-21 |
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依頼講演 "二官能チオ尿素触媒で何がやれるのか？その可能性を紐解く" 竹本佳司 研究開発専門委員会「有機分子触媒による高度分子変換技術」第１回講習会, 大阪府大阪市 (日本) 2016-01-21～2016-01-21 |
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依頼講演 "
Asymmetric Reactions Using Bifunctional HB-Donor Catalysts
" *Takemoto, Y. Lecture, Seoul (Korea) 2014-11-04～2014-11-04 |
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依頼講演 "Asymmetric Reactions Using Bifunctional HB-Donor Catalysts" *Takemoto. Y. Lecture, Suwon (Korea) 2014-11-03～2014-11-03 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Budapest (Hungary) 2015-07-30～2015-07-30 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Vienna (Austria) 2015-07-30～2016-07-30 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Bologna (Italy) 2015-07-28～2015-07-28 |
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依頼講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. Lecture, Parma (Italy) 2015-07-27～2015-07-27 |
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招待講演 "Hetero-Michael addition to α,β-unsaturated carboxylic acids" *Takemoto, Y. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids" *Takemoto, Y. The chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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招待講演 "Asymmetric hetero-Michael reaction of α,β-unsaturated carboxylic acid derivatives" *Takemoto, Y. The 13th Eurasia Conference in Chemical Sciences, Bangalore (India) 2014-12-14～2014-12-18 |
(Indian Institute of Science, , India) Dec. 14-18, 2014, | |
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招待講演 "Asymmetric hetero-Michael reaction of α,β-unsaturated carboxylic acid derivatives" *Takemoto, Y. Advanced Molecular Transformations by Organocatalysts: 2nd International Conference, Tokyo (Japan) 2014-11-21～2014-11-22 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at University of Strasbourg (ECPM), Strasbourg (France) 2013-11-18～2013-11-18 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at University of Rouen (IRCOF), Rouen (France) 2013-10-16～2013-10-16 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry" *Takemoto, Y. Seminar at Caen University (ICMT), Caen (France) 2013-10-11～2013-10-11 |
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依頼講演 "Hydrogen-Bond Donor Catalysts for Process Chemistry
" *Takemoto, Y. Seminar at Aix-Marseille University (iSm2), Marseille (France) 2013-10-08～2013-10-08 |
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招待講演 "Asymmetric Catalysis with HB Donor and NHC Catalysts" Takemoto, Y. Advanced Molecular Transformations by Organocatalysts: 1st International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Dynamic Kinetic Resolution of α-Branched Aldehydes via Oxidative NHC-Catalysis" Uno, T.; Kobayashi, Y.; Takemoto, Y. The 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "Direct Thioesterification of Aldehydes via Oxidative NHC-Catalysis: Expansion into Dynamic Kinetic Resolution" Uno, T.; Kobayashi, Y.; *Takemoto, Y. First Japan-USA Organocatalytic Symposium, Hawii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Synthesis of Aminourea-Substrate Complex Models and Mechanistic Study" Azuma, T.; Kobayashi, Y.; *Takemoto, Y. First Japan-USA Organocatalytic Symposium, Hawii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "An Efficient Synthesis of Quinoxalinone-Containing Pharmaceuticals via Aerobic Oxidative C-N Bond Formation" Kobayashi, Y.; Kimachi, T.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)-H Activation: Concise Synthesis of Indole Derivatives" Nanjo, T.; Tsukano, C.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "NHC-Catalyzed Thioesterification of Aldehydes by Redox Activation" Uno, T.; *Takemoto, Y. IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "An Efficient Synthesis of Quinoxalinone-containing Pharmaceuticals via Aerobic Oxidative C-N Bond Formation" Kobayashi, Y.; Kimachi, T.; *Takemoto, Y. The 6th Takeda Science Foundation Symposium on Pharmasciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "NHC-catalyzed Direct and Practical Thioesterification of Aldehydes by Redox Activation" Uno, T.; *Takemoto, Y. The 6th Takeda Science Foundation Symposium on Pharmasciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "Formal (3 + 3) Cycloaddition of Silyl Enol Ethers Catalyzed by Trifric Imide: Domino Michael Addition―Claisen Condensation" Azuma, T.; *Takemoto, Y.; Takasu, K. 8th AFMC International Medicinal Chemistry Symposium, Tokyo (Japan) 2011-11-29～2013-12-02 |
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口頭発表／ポスター発表 "Tf2NH-Catalyzed Domino Reaction of Ynamides with Imines: Synthesis of α,β-Unsaturated Amidines and Quinolines" Takasu, K.; Kuroda, Y.; Shindoh, N.; *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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口頭発表／ポスター発表 "N-Heterocyclic Carbene-Catalyzed Oxidative Thioesterification of Aldehydes" Uno, T. *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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口頭発表／ポスター発表 "Studies towards the Organocatalytic, Asymmetric Total Synthesis of Nakadomarin A" Stadler, M.; Tsuji, N.; Inokuma, T.; *Takemoto, Y. First Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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依頼講演 "Asymmetric Synthesis with Organocatalysts" ○*Takemoto, Y. Bristol-Kyoto Organic Synthesis Workshop in Kyoto, Kyoto (Japan) 2012-11-16～2012-11-17 |
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招待講演 "Asymmetric organocatalysis with bifunctional thioureas and newly designed hydrogen-bond donors" *Takemoto, Y. International Conference Catalysis in Organic Synthesis, Moscow (Russia) 2012-09-15～2012-09-20 |
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招待講演 "Asymmetric Organocatalysis: Toward Multifunctional Hydrogen-bond Donor Catalysts" *Takemoto, Y. The 6th Takeda Science Foundation Symposium on PharmaSciences “How Fascinating the Synthetic Organic Chemistry is!”, Osaka (Japan) 2012-09-13～2012-09-14 |
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招待講演 "Asymmetric Catalysis with Newly Designed Bifunctional Hydrogen-Bond Donors" *Takemoto, Y. 1st Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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| Patent |
"α−ヘテロシクリル酢酸化合物の製造方法
" 発明者：*竹本佳司、小林祐輔、東巧、村田晃洋 出願者：住友化学株式会社、国立大学法人京都大学 特願2014-099842 2014-05-13, 2015-01, |
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"アルツハイマー病予防薬" 発明者：垣塚彰、笹岡紀男、兼森祥子、坂本めぐみ、竹本佳司、塚野千尋 出願者：国立大学法人京都大学 特願2011-190433 2011-09-01, 2013-06, (国内) |
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"イソオキサゾリジン化合物の製造方法" 発明者：*竹本佳司、小林祐輔、猪熊翼、谷口大和 出願者：住友化学株式会社、国立大学法人京都大学 特願2012-206320 2012-09-19, 2013-04, (国内) |
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| A02 金井 求 | ||
| Original papers |
"An Expeditious Synthesis of Sialic Acid Derivatives by Copper(I)-Catalyzed Stereodivergent Propargylation of Unprotected Aldoses" X.-F. Wei, Y. Shimizu, *M. Kanai ACS. Cent. Sci. 2016, 2 pp.21-26. |
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"Chemo- and Regioselective Oxygenation of C(sp3)-H Bonds in Aliphatic Alcohols Using a Covalently Bound Directing Activator and Atmospheric Oxygen" Ozawa, J.; Tashiro, M.; Ni, J.; Oisaki, K.; *Kanai, M. Chem. Sci. 2016, 7 pp.1904-1909. |
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"Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols" Lin, L.; Yamamoto, K.; Mitsunuma, H.; Kanzaki, Y.; Matsunaga, S.;* Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.15418-15421. |
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"Supramolecular Ligands for Histone Tails by Employing a Multivalent Display of Trisulfonated Calix[4]arenes" Kimura, Y.; Saito, N.; Hanada, K.; Liu, J.; Okabe, T.; Kawashima, S. A.; Yamatsugu, K.; *Kanai, M. ChemBioChem 2015, 16 pp.2599-2604. |
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"Benzylic C(sp3)-H Perfluoroalkylation of 6-Membered Heteroaromatic Compounds" Yoichiro Kuninobu, Masahiro Nagase, *Motomu Kanai Angew. Chem. Int. Ed. 2015, 54 pp.10263-10266. |
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"A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate" Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, *Motomu Kanai Nature Chem. 2015, 7 pp.712-717. |
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"Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis" Suzuki, Y.; Sun, B.; Sakata, K.; Yoshino, T.; Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2015, 54 pp.9944-9947. |
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"Design and synthesis of biotin analogues reversibly binding with streptavidin" Yamamoto, T.; Aoki, K.; Sugiyama, A.; Doi, H.; Kodama, T.; Shimizu, Y.; *Kanai, M. Chem. Asian J. 2015, 10 pp.1071-1078. |
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"Organocatalytic Aerobic Oxdation to α-Fluoroalkyl Alcohols to Fluoroalkyl Ketones at Room Temperature" Kadoh, Y.; Tashiro, M.; Oisaki, K.; *Kanai, M. Adv. Synth. Catal. 2015, |
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"Chemoselective Boron-Catalyzed Nucleophilic Activation of Carboxylic Acids for Mannich-Type Reactions" Morita, Y.; Yamamoto, T.; Nagai, H.; Shimizu, Y.; *Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.7075-7078. |
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"Synthesis of chemically-tethered amyloid-β segment trimer possessing amyloidogenic properties" Shinoda, K.; Sohma, Y.; *Kanai, M. Bioorg. Med. Chem. Lett. 2015, 25 pp.2976-2979. |
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"Covalent modifier-type aggregation inhibitor of amyloid-β based on a cyclo-KLVFF motif" Kino, R.; Araya, T.; Arai, T.; Sohma, Y.; *Kanai, M. Bioorg. Med. Chem. Lett. 2015, 25 pp.2972-2975. |
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"Metal-free C(3)-H arylation of coumarins promoted by catalytic amounts of 5,10,15,20-tetrakis(4-diethylaminophenyl)porphyrin" Kojima, M.; Oisaki, K.; *Kanai, M. Chem. Commun. 2015, 51 pp.9718-9721. |
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"Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C-H Bond Activation" Wang, Z.; Kuninobu, Y.; *Kanai, M. J. Am. Chem. Soc. 2015, 137 pp.6140-6143. |
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"Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates" Chikkade, P. K.; Kuninobu, Y.; *Kanai, M. Chem. Sci. 2015, 6 pp.3195-3200. |
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"A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles" Sun, B.; Yoshino, T.; Matsunaga, S.; *Kanai, M. Chem. Commun. 2015, 51 pp. 4649-4661. |
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"A Cyclic KLVFF-Derived Peptide Aggregation Inhibitor Induces the Formation of Less Toxic Off-Pathway Amyloid-beta Oligomers" Tadamasa Arai; Daisuke Sasaki; Takushi Araya; Takeshi Sato; Youhei Sohma; *Motomu Kanai ChemBioChem 2014, 15 pp.2577-2583. |
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"Copper-Mediated Direct C(sp3)-H and C(sp2)-H Acetoxylation" Wang, Z.; Kuninobu, Y.; *Kanai, M. Org. Lett. 2014, 16 pp.4790-4793. |
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"Chemoselective aerobic photo-oxidation of 9H-fluorenes for the synthesis of 9-fluorenones" Masahiro Kojima, Kounosuke Oisaki, *Motomu Kanai Tetrahedron Lett. 2014, 55 pp.4736-4738. |
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"Molybdenum-Mediated Desulfurization of Thiols and Disulfides" Zhen Wang, Yoichiro Kuninobu, *Motomu Kanai Synlett 2014, 25 pp.1869-1872. |
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"Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under Dinuclear Schiff Base Catalysis" Yingjie Xu, Keiichi Kaneko, Motomu Kanai, Masakatsu Shibasaki, and Shigeki Matsunaga J. Am. Chem. Soc. 2014, 136 pp.9190-9194. |
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"Rational Design and Identification of Non-Peptidic Aggregation Inhibitor of Amyloid-beta Based on a Pharmacophore Motif Obtained from cyclo[-Lys-Leu-Val-Phe-Phe-]" Tadamasa Arai, Takushi Araya, Daisuke Sasaki, Atsuhiko Taniguchi, Takeshi Sato, Youhei Sohma, *Motomu Kanai Angew. Chem. Int. Ed. 2014, 53 pp.8236-8239. |
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"Serine-Selective Aerobic Cleavage of Peptides and a Protein Using Water-Soluble Copper Organoradical Conjugate" Seki, Y.; Tanabe, K.; Sasaki, D.; Sohma, Y.; Oisaki, K.; *Kanai, M. Angew. Chem. Int. Ed. 2014, 53 pp.6501-6505. |
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"Chemoselective aerobic oxidation catalyzed by a metal/stable organoradical redox conjugate" Seki, Y.; Oisaki, K.; *Kanai, M. Tetrahedron Lett. 2014, 55 pp.3738-3746. |
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"Recent progress in copper-catalyzed difunctionalization of unactivated carbon-carbon multiple bonds" Shimizu, Y.; *Kanai, M. Tetrahedron Lett. 2014, 55 pp.3727-3737. |
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"Copper-Catalyzed Regio- and Stereoselective Intermolecular Three-Component Oxyarylation of Allenes" Itoh, T.; Shimizu, Y.; *Kanai, M. Org. Lett. 2014, 16 pp.2736-2739. |
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"Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt
Diiodide Complex as a Precursor for Cationic
(Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed
C-2 Selective C-H Amidation of Indoles" Sun, B.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Adv. Synth. Catal. 2014, |
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"Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed
Redox-Neutral Directed C–H Alkenylation/Annulation Sequence" Hideya Ikemoto, Tatsuhiko Yoshino, Ken Sakata, *Shigeki
Matsunaga, *Motomu Kanai J. Am. Chem. Soc. 2014, 136 pp.5424-5431. |
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"Palladium-Catalyzed Direct C–H Silylation and
Germanylation of Benzamides and Carboxamides" Kyalo Stephen Kanyiva, Yoichiro Kuninobu, Motomu Kanai Org. Lett. 2014, 16 pp.1968-1971. |
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"Asparagine-Selective Cleavage of Peptide Bonds through
Hypervalent Iodine-Mediated Hofmann Rearrangement in Neutral Aqueous Solution" Kana Tanabe, Atsuhiko Taniguchi, Takuya Matsumoto,
Kounosuke Oisaki, *Youhei Sohma, *Motomu Kanai Chem. Sci. 2014, 5 |
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"Copper-Catalyzed Benzylic C(sp3)-H Alkoxylation of
Heterocyclic Compounds" Takemura,
N.; Kuninobu, Y.; Kanai, M. Org. Biomol. Chem. 2014, 12 pp.2528-2532. |
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"Copper-Catalyzed Intramolecular C(sp3)–H
and C(sp2)–H Amidation by Oxidative Cyclization" Zhen Wang, Jizhi Ni, Yoichiro Kuninobu, Motomu Kanai Angew. Chem. Int. Ed. 2014, 53 pp.3496-3499. |
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"Synthesis
of Pyridine N-Oxide–BF2CF3 Complexes and Their
Fluorescence Properties" Tomoaki Nishida, Aiko Fukazawa, Eriko Yamaguchi,
Hiroya Oshima, Shigehiro Yamaguchi, *Motomu Kanai, *Yoichiro Kuninobu Chem. Asian J. 2014, 9 pp.1026-1030. |
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"Regioselective Trifluoromethylation of N-Heteroaromatic Compounds using Trifluoromethyldifluoroborane
Activator" Nishida, T.;
Ida, H.; Kuninobu, Y.; Kanai, M. Nature Communications 2014, 5 pp.3387-3392. DOI:10.1038/ncomms4387 |
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"Catalytic
enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds
via consecutive intramolecular amido-cupration of allenes and asymmetric
addition of carbonyl compounds" Prasanna Kumara
Chikkade, Yohei Shimizu, *Motomu Kanai Chem. Sci. 2014, 5 pp.1585-1590. |
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"Cobalt-Catalyzed C-4 Selective Alkylation of
Quinolines" Yamamoto, S.; Saga, Y.; Andou, T.; *Matsunaga, S.;
*Kanai, M. Adv. Synth. Catal. 2014, 356 pp.401-405. |
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"A
Catalytic C-C Bond-Formation with Minimal Use of Protecting Groups:
Construction of Functionalized Isotetronic Acid Derivatives" *Yohei Shimizu, Kouji Yasuda, *Motomu Kanai Heterocycles 2014, 88 pp.919-927. |
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"Attenuation of the Aggregation and Neurotoxicity of
Amyloid-β Peptides by Catalytic Photooxygenation" Taniguchi, A.; Sasaki, D.; Shiohara, A.; Iwatsubo, T.;
Tomita, T.; *Sohma, Y.; *Kanai, M. Angew. Chem. Int. Ed. 2014, 53 pp.1382-1385. |
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"Rh-Catalyzed Aldehyde–Aldehyde Cross-Aldol Reaction
under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through
Orthogonal Activation" Luqing Lin, Kumiko Yamamoto, *Shigeki Matsunaga, *Motomu
Kanai Chem. Asian J. 2013, 8 pp.2974-2983. |
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"Catalytic Anomeric Aminoalkynylation of Unprotected
Aldoses" Kimura, Y.;
Ito, S.; Shimizu, Y.; *Kanai, M. Org. Lett. 2013, 15 pp.4130-4133. |
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"Copper-Catalyzed
Intramolecular N–S Bond Formation by Oxidative Dehydrogenative Cyclization" Zhen
Wang, Yoichiro Kuninobu, Motomu
Kanai J. Org. Chem. 2013, 78 pp.7337-7342. |
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"Manganese-Catalyzed Aerobic Dehydrogenative
Cyclization toward Ring-Fused Indole Skeletons" *Oisaki, K.; Abe, J.; *Kanai, M. Org. Biomol. Chem. 2013, 11 pp.4569-4572. |
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"Cp*CoIII-Catalyzed
C2-Selective Addition of Indoles to Imines" Tatsuhiko
Yoshino, Hideya Ikemoto, *Shigeki Matsunaga and *Motomu Kanai Chem. Eur. J. 2013, 19 pp.9142-9146. |
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"In situ Catalytic
Generation of Allylcopper Species for Asymmetric Allylation: Toward 1H-Isochromene
Skeletons" Junya
Kawai, Prasanna Kumara Chikkade, Yohei Shimizu and *Motomu Kanai Angew. Chem. Int. Ed. 2013, 52 pp.7177-7180. |
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"“From Chiral Base Catalysts to Redox-Active Catalysts: Chasing the Identity of Metal Catalysts in Carbon–Carbon Bond-Forming Reactions”" *Motomu Kanai, Shigeki Matsunaga, Kounosuke Oisaki, Yohei Shimizu J. Synth. Org. Chem.Japan 2013, 71 pp.433-442. |
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"“Sultam Synthesis via Cu-Catalyzed Intermolecular Carboamination of Alkenes with N-Fluorobenzenesulfonimide”" Keiichi Kaneko, Tatsuhiko Yoshino, *Shigeki Matsunaga, *Motomu Kanai Org. Lett. 2013, 15 |
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"“Catalytic Asymmetric Synthesis of Spirooxindoles via Addition of Isothiocyanato Oxindoles to Aldehydes Under Dinuclear Nickel Schiff Base Catalysis”" Shota Kato, *Motomu Kanai, *Shigeki Matsunaga Chem. Eur. J. 2013, |
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"“Iron-Catalyzed Oxidative C(3)¬–H Functionalization of Amines”" Noriaki Takasu, *Kounosuke Oisaki, and *Motomu Kanai Org. Lett. 2013, 15 pp.1918-1921. |
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"“Intracellular activation of acetyl-CoA by an artificial reaction promoter and its fluorescent detection”" Hirokazu Komatsu, Yutaka Shindo, Shigehiro A. Kawashima, Kenzo Yamatsugu, Kotaro Oka, *Motomu Kanai Chem. Commun. 2013, 49 pp.2876-2878. |
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"“Copper-Catalyzed C–H Alkoxylation of Azoles”" Noriaki Takemura, *Yoichiro Kuninobu, *Motomu Kanai Org. Lett. 2013, 15 pp.844-847. |
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"“Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines”" Takashi Andou, Yutaka Saga, Hirotomo Komai, *Shigeki Matsunaga, *Motomu Kanai Angew. Chem. Int. Ed. 2013, 52 pp.3213-3216. |
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"“A Cationic High-Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed C-H Bond Activation”" Yoshino, T. Ikemoto, H.; *Matsunaga, S.; *Kanai, M. Angew. Chem. Int. Ed. 2013, 52 pp.2207-2211. |
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"“Synthesis of a New Oseltamivir Derivative Through Late-Stage Catalytic C-H Functionalization” " Kenta Saito, *Motomu Kanai Heterocycles 2013, 86 pp.1565-1574. |
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"“Copper(I)-Catalyzed Enantioselective Incorporation of Ketones to Cyclic Hemiaminals for the Synthesis of Versatile Alkaloid Precursors”" Shi, S.-L.; Wei, X.-F.; Shimizu, Y.; *Kanai, M. J. Am. Chem. Soc. 2012, 134 pp.17019-17022. |
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"“Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols”" Luqing Lin, Kumiko Yamamoto, *Shigeki Matsunaga, *Motomu Kanai Angew. Chem. Int. Ed. 2012, 51 pp.10275-10279. |
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"“Catalytic aerobic production of imines en route to mild, green, and concise derivatizations of amines”" Toshiaki Sonobe, *Kounosuke Oisaki, *Motomu Kanai Chem. Sci. 2012, 3 pp.3249-3255. |
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"“Cu(I)-catalyzed α-alkylation of ketones with styrene derivatives”" Shohei Majima, *Yohei Shimizu, *Motomu Kanai Tetrahedron Lett. 2012, 53 pp.4381-4384. |
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"“Functional-Group-Tolerant Catalytic Migratory Oxidative Coupling of Nitrones”" Shogo Hashizume, *Kounosuke Oisaki and *Motomu Kanai Chem. Asian J. 2012, 7 pp.2600-2606. |
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"“Catalytic Asymmetric Synthesis of Spirooxindoles by a Mannich-Type Reaction of Isothiocyanato Oxindoles”" Shota Kato, Tatsuhiko Yoshino, Masakatsu Shibasaki, *Motomu Kanai and *Shigeki Matsunaga Angew. Chem. Int. Ed. 2012, 51 pp.7007-7010. |
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""Lewis Acid Catalyzed Benzylic C-H Bond Functionalization of Azaarenes; Addition to Imines and Enones" " Komai, H.; Yoshino, T.; *Matsunaga, S.; *Kanai, M. Synthesis 2012, 44 pp.2185-2194. |
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""Mg-catalyzed Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to Imines" " Yudai Suzuki, *Motomu Kanai, *Shigeki Matsunaga Chem. Eur. J. 2012, 18 pp.7654-7657. |
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"“Catalytic Asymmetric Total Synthesis of Chimonanthine, Folicanthine, and Calycanthine through Double Michael Reaction of Bisoxindole”" Mitsunuma, H.; Shibasaki, M.; *Kanai, M.; *Matsunaga, S. Angew. Chem. Int. Ed. 2012, 51 pp.5217-5221. |
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"“Asymmetric Synthesis of Dihydropyranones from Ynones by Sequential Copper(I)-Catalyzed Direct Aldol and Silver(I)-Catalyzed Oxy-Michael Reactions” " Shi, S.-L.; *Kanai, M.; *Shibasaki, M. Angew. Chem. Int. Ed. 2012, 51 pp.3932-3935. |
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"“Cu(I)-Catalyzed Decarboxylative Aldol-Type And Mannich-Type Reactions For Asymmetric Construction Of Contiguous Trisubstituted and Quaternary Stereocenters”" Yin, L.; *Kanai, M.; *Shibasaki, M. Tetrahedron 2012, 68 pp.3497-3506. |
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| Books |
「未来を拓く元素戦略－持続可能な社会を実現する化学－」 日本化学会 "銅触媒の多様な活性化形式を活用する反応開発と医薬リード合成" 嵯峨裕、金井求 化学同人 (京都市) 2013, pp39-44. |
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「Organic Chemistry–Breakthroughs and Perspectives」 Kuiling Ding and Li-Xin Dai "Recent Topics in Cooperative Catalysis: Asymmetric Catalysis, Polymerization, Hydrogen Activation, and Water Splitting" ○Motomu Kanai Wiley-VCH (Germany) 2013, pp385-412. ISBN |
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| Conference / Symposium / Lecture |
"Catalysis medicine: artificial catalysis in cells as a new modal medicine" ○Motomu Kanai 2015 Queenstown Molecular Biology Meetings in Shanghai, Shanghai (China) 2015-03-19～2015-03-20 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry, Vanderbilt University, Nashville (USA) 2014-04-28～2014-04-28 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX (USA) 2014-04-25～2014-04-25 |
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招待講演 "Merging Organic Synthesis and Life Science by
Catalysis" Kanai, M. Dept. of Chemistry and Biochemistry, UCLA, LA (USA) 2014-04-24～2014-04-24 |
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招待講演 "Cu-Catalyzed Asymmetric C–C Bond-Formations" Kanai, M. 12th Symposium on Chemical Approaches to Chirality, Tokyo (Japan) 2013-11-27～2013-11-27 |
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招待講演 "Cu-Catalyzed Reactions: Asymmetric Catalysis,
Carbohydrate Derivatization, and C-H Functionalization" Kanai, M. The Second International Conference on the Frontier Research in Organic Synthesis and Materials, Hsinchu (Taiwan) 2013-09-21～2013-09-22 |
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口頭発表／ポスター発表 "“Direct Benzylic C-H Bond Functionalization of Azaarenes” " ○Komai, H.; Yoshino, T.; Matsunaga, S.; Kanai, M. Program for Young Researcher Symposium in Europe’ supported by Graduate School of Pharmaceutical Sciences, ケンブリッジ（ケンブリッジ大学） (イギリス) 2012-06-06～2012-06-14 |
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口頭発表／ポスター発表 "Development of a Catalytic C-C Bond-Forming Reaction to Unprotected Aldoses" ○Yasuaki Kimura, Soichi Itoh, Yohei Shimizu, Motomu Kanai 13th Belgian Organic Synthesis Symposium, レーベン (ベルギー) 2012-07-15～2012-07-20 |
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口頭発表／ポスター発表 "Development of Cobalt(III)-Catalyzed Directed C-H Bond Functionalization Reactions" ○T. Yoshino, H. Ikemoto, S. Matsunaga, M. Kanai 2nd Junior International Conference on Cutting-Edge Organic Chemistry in Asia, クアラルンプール (マレーシア) 2012-12-08～2012-12-10 |
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口頭発表／ポスター発表 ""Catalytic Migratory Oxidative Coupling of Nitrones"" ○S.Hashizume, K.Oisaki, M.Kanai Program for Young Researcher Symposium in Europe’ supported by Graduate School of Pharmaceutical Sciences, U-Tokyo, ケンブリッジ（ケンブリッジ大学） (イギリス) 2012-06-06～2012-06-14 |
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口頭発表／ポスター発表 ""Catalytic Aerobic Production of Imines en Route to Mild, Green and Concise Derivatizations of Amines"" ○Kounosuke Oisaki, Toshiaki Sonobe, Motomu Kanai Frontiers of Organometallic Chemistry (FOC-2012), サンクトペテルブルグ (ロシア) 2012-09-21～2012-09-22 |
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口頭発表／ポスター発表 ""Catalytic Aerobic Production of Imines en Route to Mild, Green and Concise Derivatizations of Amines"" ○Kounosuke Oisaki, Toshiaki Sonobe, Motomu Kanai Catalysis in Organic Synthesis (ICCOS-2012), モスクワ (ロシア) 2012-09-15～2013-09-20 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Peking University in 北京 (中華人民共和国) 2012-06-29～2012-06-29 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Lanzhou University in 蘭州 (中華人民共和国) 2013-06-28～2013-06-28 |
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招待講演 "“Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling”" ○Motomu Kanai ACP Lectureship Award in China, Shanghai Institute of Materia Medica in 上海 (中華人民共和国) 2012-06-26～2012-06-26 |
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口頭発表／ポスター発表 " “Catalytic Enantioselective Benzylic C-H Bond Functionalization of Isoindolinones: Addition to Imines” " ○Suzuki Yudai, Matsunaga Shigeki, Kanai MotomuSymposium Molecular Chirality ASIA 2012, 福岡市 (日本) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 " “The construction of spiro(imidazoline-indorinone) frameworks aiming at development of new antineoplastic agents” " ○Shota Kato, Seiko Kitahara, Tatsuhiko Yoshino, Shigeki Matsunaga, Motomu KanaiSymposium Molecular Chirality ASIA 2012, 福岡市 (日本) 2012-05-17～2012-05-18 |
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招待講演 "”Asymmetric C–C Bond-Formations Promoted by Cu(I)-Conjugated Brønsted Base Catalysts”" ○Motomu Kanai 4th UK/Japan Conference in Asymmetric Synthesis, 仙台市 (Japan) 2013-04-19～2013-04-19 |
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招待講演 "“First-row Transition Metal-Catalyzed C–C Bond Formations”" ○Motomu Kanai The 7th International Forus on Chemistry of Functional Organic Chemicals (IFOC-7), 東京 (日本) 2012-11-18～2012-11-18 |
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招待講演 " “Cu(I)-Catalyzed C-C Bond-Formations: Asymmetric Catalysis, Carbohydrate Derivatization, and Redox Catalysis”" ○Motomu Kanai The 5th International Forum on Homogeneous Catalysis, 上海 (China) 2012-10-11～2012-10-11 |
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招待講演 " “Cu(I)-Catalyzed C-C Bond-Formation: Asymmetric Catalysis and Oxidative C(sp3)-H Coupling” " ○Motomu KanaiACP Lectureship Award in China, Shanghai Institute of Organic Chemistry (SIOC) in 上海 (中華人民共和国) 2012-06-25～2012-06-25 |
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| Media |
"Functional-Group-Tolerant Catalytic Migratory
Oxidative Coupling of Nitrones" Shogo
Hashizume, Kounosuke Oisaki, Motomu Kanai Chem. Asian J. 2012-10-10 PDF 水中でも実施可能な収束的触媒的酸化カップリング反応を見出した。 |
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"窒素原子隣接位から炭素骨格を伸ばす触媒反応" 園部敏亮、生長幸之助、金井求 薬事日報 2013-03-22 PDF 酸素を吸収して水を排出しながら炭素骨格構築を行う触媒反応を見出した。 |
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| A02 三宅 由寛 | ||
| Original papers |
"Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids" Yamaji, A.; Tsurugi, H.; *Miyake, Y.; Mashima, K.; *Shinokubo, H. Chem. Eur. J. 2016, 22 pp.3956-3961. |
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"Diversity-Oriented Synthesis of Tetrathia[8]circulenes by Sequential C–H Borylation and Annulation" Kato, S.; Serizawa, Y.; Sakamaki, D.; Seki, S.; *Miyake, Y.; Shinokubo, H. Chem. Commun. 2015, 51 pp.16944-16947. |
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"A 3-Pyridyl-5,15-Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transtion Metals" Yamaji, A.; Shin, J.-Y.; Miyake, Y.; *Shinokubo, H. Angew. Chem. Int. Ed. 2014, 53 pp.13924-13927. |
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"Synthesis of Nitrogen Heterocycles via α-Aminoalkyl Radicals Generated from α-Silyl Secondary-Amines under Visible Light Irradiation" Nakajima, K.; Kitagawa, M.; Ashida, Y.; *Miyake, Y.; *Nishibayashi, Y. Chem. Commun. 2014, 50 pp.8900-8903. |
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"Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides" Miyake, Y.; Ota, S.; Shibata, M.; Nakajima, K.; *Nishibayashi, Y. Org. Biomol. Chem. 2014, 12 pp.5594-5596. |
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"Visible-Light-Mediated Addition of α-Aminoalkyl Radicals to [60]Fullerene by Using Photoredox Catalysts" *Miyake, Y.; Ashida, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Eur. J. 2014, 20 pp.6120-6126. |
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"Preparation and Reactivity of Molybdenum-Dinitrogen Complexes Bearing Arsenic-Containing ANA-type Pincer Ligand" Tanabe, Y.; Kuriyama, S.; Arashiba, K.; Miyake, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Commun. 2013, 49 pp.9290-9292. |
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"Design and Preparation of Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands" Miyazaki, T.; Tanabe, Y.; Yuki, M.; Miyake, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Eur. J. 2013, 19 pp.11874-11877. |
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"Visible Light-Mediated Oxidative Decarboxylation of Arylacetic Acids into Benzyl Radicals: Addition to Electron-Deficient Alkenes by Using Photoredox Catalysts" *Miyake, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Commun. 2013, 49 pp.7854-7856. |
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"Copper-Catalyzed Nucleophilic Trifluoromethylation of Propargylic Halides" Miyake, Y.; Ota, S.; Shibata, M.; Nakajima, K.; *Nishibayashi, Y. Chem. Commun. 2013, 49 pp.7809-7811. |
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"Synthesis, Structure, and Reactivity of Group VI Metal Complexes Bearing Group IV Metallocenyldiphosphine Moieties and Pentamethylcyclopentadienyl Ligand " Miyazaki, T.; Tanabe, Y.; Yuki, Y.; Miyake,Y.; *Nishibayashi, Y. Organometallics 2013, 32 (6), pp.2007-2013. |
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"Ruthenium–Triggered Ring-Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal–Allenylidene Intermediates" Miyake, Y.; Endo, S.; Moriyama, T.; Sakata, K.; *Nishibayashi, Y. Angew. Chem. Int. Ed. 2013, 52 (6), pp.1758-1762. |
坂田 健 | |
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"Iron-Catalyzed Transformation of Molecular Dinitrogen into Silylamine Under Ambient Conditions" Yuki, M.; Tanaka, H.; Sasaki, K.; Miyake, Y.; *Yoshizawa, K.; *Nishibayashi, Y. Nature Commun. 2012, 3 pp.1254. |
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"Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands" Kinoshita, E.; Arashiba, K.; Kuriyama, S.; Miyake, Y.; Shimazaki, R.; Nakanishi, H.; *Nishibayashi, Y. Organometallics 2012, 31 (23), pp.8437-8443. |
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"Direct sp3 C-H Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysts" Miyake, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Eur. J. 2012, 18 (51), pp.16473-16477. |
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"Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: Simple Approach to Allylic Trifluoromethylation" Miyake, Y.; Ota, S.; *Nishibayashi, Y. Chem. Eur. J. 2012, 18 (42), pp.13255-13258. |
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"Enantioselective Alkylation of β-Keto Phosphonates by Direct Use of Diaryl Methanols as Electrophiles" Shibata, M.; Ikeda, M.; Motoyama, K.; Miyake, M.; *Nishibayashi, Y. Chem. Commun. 2012, 48 (76), pp.9528-9530. |
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"Visible-Light-Mediated Addition of α-Aminoalkyl Radicals Generated from α-Silylamines to α,β-Unsaturated Carbonyl Compounds" Miyake, Y.; Ashida, Y.; Nakajima, K.; *Nishibayashi, Y. Chem. Commun. 2012, 48 (55), pp.6966-6968. |
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"Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes" Ikeda, M.; Miyake, Y.; *Nishibayashi, Y. Organometallics 2012, 31 (9), pp.3810-3813. |
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"Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines " Yuki, M.; Miyake, Y.; *Nishibayashi, Y. Organometallics 2012, 31 (8), pp.2953-2956. |
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"Ruthenium- and Copper-Catalyzed Enantioseletive Propargylic Alkylation of Propargylic Alcohols with β-Keto Phosphonates" Motoyama, K.; Ikeda, M.; Miyake, Y.; *Nishibayashi, Y. Organometallics 2012, 31 (8), pp.3426-3430. |
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"Synthesis and Reactivity of Hybrid Phophido- and Hydrosulfido-Bridged Diruthenium Complex: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands" Miyake, Y.; Moriyama, T.; Tanabe, Y.; Endo, S.; Nishibayashi, Y. Organometallics 2012, 31 (8), pp.3292-3299. |
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"Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-Type Pincer Ligands" Arashiba, K.; Sasaki, K.; Kuriyama, S.; Miyake, Y.; Nakanishi, H.; *Nishibayashi, Y. Organometallics 2012, 31 (5), pp.2035-2041. |
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"Visible Light Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts" Miyake, Y.; Nakajima, K.; *Nishibayashi, Y. J. Am. Chem. Soc. 2012, 134 (7), pp.3338-3341. |
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"Cooperative Catalytic Reactions Using Distinct Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation" Ikeda, M.; Miyake, Y.; *Nishibayashi, Y. Chem. Eur. J. 2012, 18 (11), pp.3321-3328. DOI:DOI: 10.1002/chem.201103892 |
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| Conference / Symposium / Lecture |
招待講演 "Visible-Light-Mediated Transformations of Nitrogen-Containing Compounds Based on Control of Single Electron Transfer Process" ○*Miyake, Y. The 7th Pacific Symposium on Radical Chemistry, (シンガポール) 2015-07-15～2015-07-18 |
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口頭発表／ポスター発表 "Diversity-Oriented Synthesis of Tetrathia[8]circulenes by C–H Borylation and Annulation" Kato, S,; Serizawa, Y.; Sakamaki, D.; Seki, S.; ○*Miyake, Y.; Shinokubo, H. The 13th International Kyoto Conference on New Aspect of Organic Chemistry, 京都 (日本) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Synthesis and Reactivity of Molybdenum Dinitrogen Complxes Bearing Ferrocenyl Diphosphine and Cyclopentadienyl Moieties" ○Miyazaki, T.; Tanabe, Y.; Yuki, M.; Miyake, Y.; *Nishibayashi, Y. The 25th International Conference on Organometallic Chemistry, リスボン (ポルトガル) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Synthesis and Reactivity of Coordinatively Unsaturated Diruthenium Complex Bridged by Hybrid Phosphido and Sulfido Ligands" ○Tanabe, Y.; Miyake, Y.; Moriyama, T.; Endo, S.; *Nishibayashi, Y. The 25th International Conference on Organometallic Chemistry, リスボン (ポルトガル) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Remarkable Effect of Substituents at Dinitrogen-Bridged Dimolybdenum Complexes on Catalytic Formation of Ammonia From Dinitrogen" ○Kuriyama, S.; Arashiba, K.; Miyake, Y.; *Nishibayashi, Y. The 25th International Conference on Organometallic Chemistry, リスボン (ポルトガル) 2012-09-02～2012-09-07 |
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口頭発表／ポスター発表 "Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts" ○Nakajima, K.; Ashida, Y.; Miyake, Y.; *Nishibayashi, Y. The 25th International Conference on Organometallic Chemistry, リスボン (ポルトガル) 2012-09-02～2012-09-07 |
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| Prize |
"有機合成化学奨励賞" 三宅 由寛 2014-12 有機合成化学協会 光誘起電子移動の精密制御に基づく含窒素化合物の効率的変換反応の開発 |
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| A02 工藤 一秋 | ||
| Original papers |
"Solvolysis of formylphenyl esters by a bifunctional peptide catalyst" K. Akagawa, *K. Kudo Chem. Lett. 2016, 45 pp.300-302. DOI:10.1246/cl.151154 |
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"Asymmetric Epoxidation of Enones by Peptide-Based Catalyst: A Strategy Inverting Juliá–Colonna Stereoselectivity" K. Akagawa,T. Hirata, *K. Kudo Synlett 2016, pp.1217-1222. DOI:10.1055/s-0035-1560597 |
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"Kinetic Resolution of a Planar-Chiral [2.2]Paracyclophane Derivative by Helical-Peptide-Catalyzed Michael Addition of Nitromethane" K. Akagawa, N. Nishi, I. Yoshikawa, *K. Kudo Eur. J. Org. Chem. 2015, pp.5055-5059. DOI:10.1002/ejoc.201500594 |
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"Peptide-Catalyzed Desymmetrization of an Achiral Ferrocenyl Compound To Induce Planar Chirality" K. Akagawa, M. Akiyama, *K. Kudo Eur. J. Org. Chem. 2015, pp.3894-3898. DOI:10.1002/ejoc.201500428 |
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"Histidine-Containing Peptide Catalysts Developed by a Facile Library Screening Method" K. Akagawa, N. Sakai, *K. Kudo Angew. Chem. Int. Ed. 2015, 54 pp.1822-1826. DOI:10.1002/anie.201410268 |
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"Peptide-Catalyzed Kinetic Resolution of Planar-Chiral Metallocenes" M. Akiyama, K. Akagawa, H. Seino, *K. Kudo Chem. Commun. 2014, 50 pp.7893-7896. DOI:10.1039/C4CC03266G |
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"Peptide-catalyzed consecutive 1,6- and 1,4-additions of thiols to α,β,γ,δ-unsaturated aldehydes" K. Akagawa, N. Nishi, J. Sen, *K. Kudo Org. Biomol. Chem. 2014, DOI:10.1039/C4OB00565A |
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"Development of a Peptide-Based Primary Aminocatalyst with a Helical Structure" K. Akagawa, R. Suzuki, *K. Kudo Asian J. Org. Chem. 2014, 4 pp.514-522. DOI:10.1002/ajoc.201400028 |
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"Peptide-Catalyzed Diastereo- and Enantioselective Cyclopropanation of Aromatic α,β-Unsaturated Aldehydes" K. Akagawa, S. Takigawa, I. S. Nagamine, R. Umezawa, *K. Kudo Org. Lett. 2013, 15 pp.4964-4967. DOI:10.1021/ol402227y |
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"Peptide-Catalyzed Regio- and Enantioselective Reduction of α,β,γ,δ-Unsaturated Aldehydes" K. Akagawa, J. Sen, *K. Kudo Angew. Chem. Int. Ed. 2013, 52 pp.11585-11588. DOI:10.1002/anie.201305004 |
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"Transformation of Gold(I)-cyclo[-Met-Met-] Complex Supramolecular Fibers into Aligned Gold Nanoparticles" M. Furutani, *K. Kudo Chem. Lett. 2013, 42 (6), pp.601-603. DOI:10.1246/cl.130106 |
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"Asymmetric α-amination of aldehydes by recyclable resin-supported peptide catalyst" T. Tanaka, K. Akagawa, M. Mitsuda, *K.Kudo, Adv. Synth. Catal. 2013, 355 (2-3), pp.294-296. DOI:10.1002/adsc.201200611 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes" K. Akagawa, *K. Kudo Angew. Chem. Int. Ed. 2012, 51 pp.12786-12789. DOI:10.1002/anie.201206916 |
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"Asymmetric one-pot sequential Friedel-Crafts-type alkylation and α-oxyamination catalyzed by a peptide and an enzyme" K. Akagawa, R. Umezawa, *K. Kudo Beilstein J. Org. Chem. 2012, 8 pp.1333-1337. DOI:10.3762/bjoc.8.152 |
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"Effect of the Helical Tether of a Resin-Supported Peptide Catalyst for Friedel-Crafts-Type Alkylation in Water" K. Akagawa, R. Suzuki, *K. Kudo Adv. Synth. Catal. 2012, 354 pp.1280-1286. DOI:10.1002/adsc.201100950 |
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"Asymmetric induction by helical poly(amino acid)s in cyanosilylation of aldehydes" *K. Akagawa, *K. Kudo Tetrahedron Lett. 2012, 53 (45), pp.5981-5983. DOI:10.1016/j.tetlet.2012.07.034 |
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"Asymmetric Michael addition of boronic acids to a γ-hydroxy-α,β-unsaturated aldehyde catalyzed by resin-supported peptide." K. Akagawa, M. Sugiyama, *K. Kudo Org. Biomol. Chem. 2012, 10 (25), pp.4839-4843. DOI:10.1039/C2OB25431J |
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"Sequential oxidation/asymmetric aldol reaction of primary alcohols by resin-supported catalysts" K. Akagawa, S. Takigawa, E. Mano and *K. Kudo Tetrahedron Lett. 2011, 52 pp.770-773. |
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"Synthesis of Indenes by Intramolecular Morita-Baylis-Hillman Reaction in Aqueous Media Catalyzed by Resin-Supported Proline" K. Akagawa, S. Sakamoto and *K. Kudo Synlett 2011, pp.817-820. |
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"Peptide/Laccase Cocatalyzed Asymmetric α-Oxyamination of Aldehydes" K. Akagawa, *K. Kudo Org. Lett. 2011, 13 pp.3498-3501. |
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"Asymmetric Epoxidation of alpha,beta-Unsaturated Aldehydes in Aqueous Media Catalyzed by Resin-Supported Peptide-Containing Unnatural Amino Acids" K. Akagawa, *K. Kudo Adv. Synth. Catal. 2011, 353 pp.843-847. |
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| Books |
「化学はじめの一歩シリーズ 有機化学」 工藤一秋，渡辺正 化学同人 (京都) 2016, ISBN:978-4759816341 |
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「ナノエレクトロニクスにおける絶縁超薄膜技術」 "low-k薄膜絶縁材料開発" 工藤一秋 シーエムシー (東京) 2013, pp189-198. ISBN:978-4864690393 |
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「Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis」 Itsuno S. "Peptide-catalyzed asymmetric synthesis" K. Kudo, K. Akagawa Wiley 2011, pp91-123. ISBN:0470568208 |
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| Reviews / Accounts |
"選択的ペプチド触媒の今とこれから―人工ペプチドで酵素に迫る" 工藤一秋 化学 2014, 69 pp.64-65. |
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"樹脂固定化ペプチドによる高選択的反応の開発" 赤川賢吾，工藤一秋 化学と工業 2014, 67 pp.477-479. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Screening of peptide libraries for discovering efficient aminocatalysts" ○K. Akagawa, J. Satou, *K. Kudo International Chemical Congress of Pacific Basin Societies 2015, Honolulu (USA) 2016-05-06～2016-05-06 |
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依頼講演 "Development of selective peptide catalysts having secondary structures" ○*K. Kudo,K. Akagawa International Chemical Congress of Pacific Basin Societies 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Peptide-catalyzed regio- and enantioselective reduction" ○Kengo Akagawa, Jun Sen, *Kazuaki Kudo 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Polymer Electrolyte Membranes for Fuel Cells of Graft-type sulfonated Polybenzimidazoles" ○J.Park,M.Asano,Y.Maekawa,*K.Kudo PRiME 2012, Honolulu (USA) 2012-10-07～2012-10-12 |
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口頭発表／ポスター発表 "Synthesis and Properties of Alicyclic Polyimides Using Unsymmetrical Spiroalicyclic Dianhydride" ○*K.Kudo SAMPE TECH 2012, Charleston (USA) 2012-10-22～2012-10-25 |
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口頭発表／ポスター発表 "Construction of All-Carbon Quaternary Stereocenter by Asymmetric Michael Addition of Nitromethane to β,β-Disubstituted Aldehydes with Peptide Catalyst " ○Kengo Akagawa, *Kazuaki Kudo IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Asymmetric alpha-Amination of Aldehyde by Recyclable Resin-supported Peptide Catalyst" ○Tatsuyoshi Tanaka, Kengo Akagawa, Masaru Mitsuda, *Kazuaki Kudo IKCOC-12, Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Resin-bound peptides as asymmetric
aminocatalysts" ○*Kazuaki Kudo 1st Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "Effect of Helical Tether on the Catalytic Performance of Resin-Supported Peptides for Asymmetric Organic Transformations" Akagawa, K.; ○*Kudo, K 6th International Conference on Cutting-Edge Organic Chemistry in Asia(ICCEOCA-6), 香港 (香港) 2011-12-11～2011-12-15 |
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| Patent |
"耐熱性高分子電解質膜及びその製造方法" 発明者：工藤 一秋，高山 俊雄，朴 俊，浅野 雅春，前川 康成 出願者：国立大学法人 東京大学，独立行政法人日本原子力研究開発機構 2011-245110 2011-11-09, 2013-06, (国内) |
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| Media |
2015-08-26 "Resolution of a Planar-Chiral [2.2]Paracyclophane Derivative by Helical-Peptide-Catalyzed Michael Addition of Nitromethane"がEur. J. Org. Chem.誌23号(2015年)のcover pictureに採用 |
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2015-07-08 EurJOC誌掲載の面不斉[2.2]パラシクロファンの速度論的光学分割(Eur. J. Org. Chem., 5055-5059 (2015))が，”Non-Racemic Planar-Chiral Cyclophanes”というタイトルでChemViews Magazineで取り上げられた。 |
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"東大 ペプチド触媒開発" 工藤一秋 日経産業新聞 2014-07-10 |
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"Peptide-Catalyzed Regio- and Enantioselective Reduction of α,β,γ,δ-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 52, 11585–11588 (2013))が、Synfacts 誌 2014(1), 97 に掲載" K. Akagawa, J. Sen, K. Kudo Synfacts 2013-12-13 |
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"Peptide-Catalyzed Diastereo- and Enantioselective Cyclopropanation of Aromatic α,β-Unsaturated Aldehydes (Org. Lett. 15, 4964–4967 (2013))が、Synfacts 誌 2014(1), 99 に掲載" K. Akagawa, K. Kudo Synfacts 2013-12-13 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 51, 12786-12789 (2012))が、Synform 2013(3), A32で取り上げられた" K. Akagawa, K. Kudo Synform 2013-02-15 |
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"Construction of an All-Carbon Quaternary Stereocenter by the Peptide-Catalyzed Asymmetric Michael Addition of Nitromethane to β-Disubstituted α,β-Unsaturated Aldehydes (Angew. Chem. Int. Ed., 51, 12786-12789 (2012))が、Synfacts 誌 2013, 9(3), 340に掲載. " K. Akagawa, K. Kudo Synfacts 2013-02-15 |
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"Asymmetric induction by helical poly(amino acid) in cyanosilylation of aldehydes, (Tetrahedron Lett., 53, 5981-5983 (2012))が、Chirality, On the Other Handというタイトルで、ポリアミノ酸による不斉反応が天然分子のホモキラリティーの起源となっている可能性があると紹介された" K. Akagawa, K. Kudo ChemViews Magazine 2012-10-10 |
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"Asymmetric induction by helical poly(amino acid) in cyanosilylation of aldehydes, (Tetrahedron Lett., 53, 5981-5983 (2012))が、Synfacts 誌 2013, 9(2), 225に掲載" K. Akagawa, K. Kudo Synfacts 2013-01-18 |
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"Asymmetric Michael addition of boronic acids to a γ-hydroxy-α,β-unsaturated aldehyde catalyzed by resin-supported peptide.(Org. Biomol. Chem. 10 4839-4843 (2012))が、Synfacts 誌 2012, 8(9), 1に掲載" K. Akagawa, M. Sugiyama, K. Kudo Synfacts 2012-08-21 |
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"Peptide/Laccase Cocatalyzed Asymmetric α-Oxyamination of Aldehydes, (Org. Lett. 13, 3498-3501 (2011))が、Synfacts 誌 2011(9), 1027 に掲載" K. Akagawa, K. Kudo Synfacts 2011-08-19 |
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"Epoxidation of alpha,beta-Unsaturated Aldehydes in Aqueous Media Catalyzed by Resin-Supported Peptide-Containing Unnatural Amino Acids (Adv. Synth. Catal. 353, 843-847 (2011))が、Synfacts 誌 2011(7), 803 に掲載" K. Akagawa, K. Kudo Synfacts 2011-06-17 |
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| A02 矢倉 隆之 | ||
| Original papers |
"Application of a stereoselective
rhodium(II)-catalyzed oxonium ylide formation−[2,3]-sigmatropic rearrangement
of an a-diazo-b-keto ester to the synthesis of 2-epi-cinatrin
C1 dimethyl ester." *Yakura, T.; Ozono, A.; Matsui,
K.; Yamashita, M.; Fujiwara, T. Synlett 2013, 24 (1), pp.65-68. |
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| Conference / Symposium / Lecture |
招待講演 "Development
of novel catalysts for oxidation based on hypervalent iodine chemistry." *Yakura, T. First Japan–USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-08 |
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口頭発表／ポスター発表 "Development
of fluorination-cyclization of tryptamines and their analogs." ○Fujiwara, T.; Seki, T.;
Yasuda, H.; Takeuchi, Y.; *Yakura, T. The 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-27 |
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| A02 柴田 哲男 | ||
| Original papers |
"Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon-Assisted C-F Bond Cleavage" Nishimine, T.; Fukushi, K.; Shibata, N.; Taira, H.; Tokunaga, E.; Yamano, A.; Shiro, M.; *Shibata, N. Angew. Chem. Int. Ed. 2014, 126 (2), pp.527-530. DOI:10.1002/ange.201308071 |
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"Studies on the C/O–regioselectivity in Electrophilic Fluoromethylations of β-Ketoesters based on Thermodynamics by Ab initio Calculations" Yang, Y. D.; Wang, X.; Tsuzuki, S.; Tokunaga, E.; Shibata, N. Bulletin of the Korean Chemical Society 2014, |
独立行政政人 産業技術総合研究所 ナノシステム研究部門 ソフトマターモデリンググループ 都築誠二 | |
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"S-((Phenylsulfonyl)difluoromethyl)thiophenium Salts: Carbon-Selective Electrophilic Difluoromethylation of β-Ketoesters, β-Diketones, and Dicyanoalkylidenes" Wang, X.; Liu, G.; Xu, X. H.; Shibata, N.; Tokunaga, E.; *Shibata N. Angew. Chem. Int. Ed. 2014, 53 (7), pp.1827-1831. DOI:10.1002/anie.201309875 |
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"Thalidomide Increases Human Hepatic Cytochrome P450 3A Enzymes by Direct Activation of the Pregnane X Receptor" Murayama, N.; Beuningen, R.; Suemizu, H.; Guguen-Guillouzo, C.; Shibata, N.; Yajima, K.; Utoh, M.; Shimizu, M.; Chesné, C.; Nakamura, M.; Guengerich, F. P.; Houtman, R.; Yamazaki, H. Chemical Research in Toxicology 2014, 27 (2), pp.304-308. DOI:10.1021/tx4004374 |
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"A phthalocyanine–subphthalocyanine heterodinuclear dimer: comparison of spectroscopic " Shibata, N.; Mori, S.; Hayashi, M.; Umeda, M.; Tokunaga, E.; Shiro, M.; Sato, H.; Hoshi, T.; Kobayashi, N. Chem. Commun. 2014, 50 (23), pp.3040-3043. DOI:10.1039/C3CC49831j |
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"Diastereoselective Additive Trifluoromethylation/Halogenation of Isoxazole Triflones: Synthesis of All-carbon Functionalized Trifluoromethyl Isoxazoline Triflones" Kawai,H.; Sugita, Y.; Tokunaga, E.; Sato, H.; Shiro, M.; *Shibata, N. ChemistryOpen. 2014, 3 (1), pp.14-18. DOI:10.1002/open.201300044 |
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"Bis(pentafluorosulfanyl)phenyl Azide as an Expeditious Tool for Click Chemistry toward Antitumor " Yang, Y. D.; Tokunaga, E.; Akiyama, H.; Saito, N.; *Shibata, N. ChemMedChem 2014, DOI:10.1002/cmdc.201400059 |
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"Iodoarene-catalyzed fluorination and aminofluorination by Ar-I/HF·pyridine/mCPBA system" Suzuki, S.; Kamo, T.; Fukushi, K.; Hiramatsu, T.; Tokunaga, E.; Dohi, T.; Kita, Y.; *Shibata, N. Chem. Sci. 2014, DOI:10.1039/C3SC53107D |
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"Asymmetric Synthesis of Efavirenz via Organocatalyzed Enantioselective Trifluoromethylation" Okusu, S.; Kawai, H.; Yasuda, Y.; Sugita, Y.; Kitayama, T.; Tokunaga, E.; *Shibata, N. Asian Journal of Organic Chemistry 2014, 3 (4), pp.449-452. DOI:10.1002/ajoc.201402016 |
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"Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters" Yang, Y. D.; Azuma, A.; Tokunaga, E.; Yamasaki, M.; Shiro, M.; *Shibata, N. J. Am. Chem. Soc. 2013, 135 (24), pp.8782-8785. DOI:10.1021/ja402455f |
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"Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via a S-(trifluoromethyl)diphenylsulfonium salts/copper system" Okusu, S.; Sugita, Y.; Tokunaga, E.; *Shibata, N. Beilstein J. Org. Chem. 2013, 9 pp.2189-2193. DOI:10.3762/bjoc.9.257 |
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"Transition-metal-free oxidative trifluoromethylation ofunsymmetrical biaryls with trifluoromethanesulfinate" Yang, D.; Iwamoto, K.; Tokunaga, E.; *Shibata, N. Chem. Commun. 2013, 49 pp.5510-5512. DOI:10.1039/c3cc41667 |
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"Enantioselective Synthesis of 5-Trifluoromethyl-2-isoxazolines and Their N-Oxides by [Hydroxy(tosyloxy)iodo]benzene-Mediated Oxidative N–O Coupling" Kawai, H.; Okusu, S.; Tokunaga, E.; *Shibata, N. Eur. J. Org. Chem. 2013, 29 pp.6506-6509. DOI:10.1002/ejoc.201301096 |
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"Efficient direct ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by trifluoromethanesulfonic acid (TfOH) in Solkane365mfc" Xu, X. H.; Azuma, A.; Taniguchi, M.; Tokunaga, E.; *Shibata, N. RSC Adv. 2013, 3 pp.3848-3852. DOI:10.1039/C3RA00132F |
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"Enantioselective monofluoromethylation of aldehydes with 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide catalyzed by a bifunctional cinchona alkaloid-derived thiourea–titanium complex" Ma, H.; Matsuzaki, K.; Yang, Y. D.; Tokunaga, E.; Nakane, D.; Ozawa, T.; Masuda, H.; *Shibata, N. Chem. Commun. 2013, 49 pp.11206-11208. DOI:10.1039/C3CC46544F |
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"A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform" Kawai, H.; Yuan, Z.; Tokunaga, E.; *Shibata, N. Org. Biomol. Chem. 2013, 11 pp.1446-1450. DOI:10.1039/C3OB27368G |
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"Remote Anionic Fries Rearrangement of Sulfonates: Regioselective Synthesis of Indole Triflones" Xu, X. H.; Taniguchi, M.; Azuma, A.; Liu, G. K.; Tokunaga, E.; *Shibata, N. Org. Lett. 2013, 15 (3), pp.686-689. DOI:10.1021/ol3035559 |
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"Selective O-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents" Liu, G.; Wang, X.; Xu, X. H.; Lu, X.; Tokunaga, E.; Tsuzuki, S.; *Shibata, N. Org. Lett. 2013, 15 (5), pp.1044-1047. DOI:10.1021/ol4000313 |
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"Highly Enantioselective Monofluoromethylation of C2-Arylindoles Using FBSM under Chiral Phase-Transfer Catalysis" Matsuzaki, K.; Furukawa, T.; Tokunaga, E.; Matsumoto, T.; Shiro, M.; *Shibata, N. Org. Lett. 2013, 15 (13), pp.3282-3285. DOI:10.1021/ol4013102 |
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"Cinchona alkaloid/TMAF combination: Enantioselective trifluoromethylation of aryl aldehydes" Kawai, H.; Mizuta, S.; Tokunaga, E.; *Shibata, N. Journal of Fluorine Chemistry 2013, 152 pp.46-50. |
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"Efficient Access to Trifluoromethyl Diarylpyrrolines and their N-Oxides through Enantioselective Conjugate Addition of Nitromethane to β,β-Disubstituted Enones" Kawai, H.; Yuan, Z.; Kitayama, T.; Tokunaga, E.; *Shibata, N. Angew. Chem. Int. Ed. 2013, 125 (21), pp.5685-5689. DOI:10.1002/ange.201301123 |
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"Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β,β-Disubstituted Enones" Kawai, H.; Okusu, S.; Yuan, Z.; Tokunaga, E.; Yamano, A.; Shiro, M.; *Shibata, N. Angew. Chem. Int. Ed. 2013, 125 (8), pp.2277-2281. DOI:10.1002/ange.201209355 |
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"Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O→Cvinyl and N→Cvinyl Trifluoromethanesulfonyl Migration Reactions" Xu, X. H.; Taniguchi, M.; Wang, X.; Tokunaga, E.; Ozawa, T.; Masuda, H.; *Shibata, N. Angew. Chem. Int. Ed. 2013, 52 (48), pp.12455-12746. DOI:10.1002/anie.201308947 |
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"Chiral N-Fluorodibenzenesulfonimide Analogues for EnantioselectiveElectrophilic Fluorination and Oxidative Fluorination" Zhu, C.L.; Maeno, M.; Zhang, F. G.; Shigehiro, T.; Kagawa, T.; Kawada, K.; *Shibata, N.; *Ma, J. A.; *Cahard, D. Eur. J. Org. Chem. 2013, 29 pp.6501-6505. DOI:10.1002/ejoc.201300956 |
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"Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles and b-Keto Esters
" Yang, Y. D.; Azuma, A.; Tokunaga, E.; Yamasaki, M.; Shiro, M.; *Shibata, N. J. Am. Chem. Soc. 2013, 135 (24), pp.8782-8785. DOI:10.1021/ja402455f |
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"Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate" Yang, Y. D.; Iwamoto, K.; Tokunaga, E.; *Shibata, N. Chem. Commun. 2013, 49 pp.5510-5512. DOI:10.1039/C3CC41667D |
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"Cinchona alkaloid/TMAF combination: Enantioselective trifluoromethylation of aryl aldehydes" Kawai, H.; Mizuta, S.; Tokunaga, E.; *Shibata, N. Journal of Fluorine Chemistry 2013, (152), pp.46-50. |
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"Selective o-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents" Liu, G.; Wang, X.; Xu, X.-H.; Lu, X.; Tokunaga, E; Tsuzuki, S.; *Shibata, N. Org. Lett. 2013, 15 (5), pp.1044-1047. DOI:10.1021/ol4000313 |
独立行政法人 産業技術総合研究所 ナノシステム研究部門 ソフトマターモデリンググループ 都築誠二 | |
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"Remote Anionic Fries Rearrangement of Sulfonates: Regioselective Synthesis of Indole Triflones" Xu, X.-H.; Taniguchi, M.; Azuma, A.; Liu, G.K.; Tokunaga, E.; *Shibata, N. Org. Lett. 2013, 15 (3), pp.686-689. DOI:10.1021/ol3035559 |
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"Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β,β-Disubstituted Enones" Kawai, H.; Okusu, S.; Yuan, Z.; Tokunaga, E.; Yamano, A.; Motoo, S.; *Shibata, N. Angew. Chem. Int. Ed. 2013, 52 (8), pp.2221-2225. DOI:10.1002/anie.201209355 |
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"Efficient direct ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by trifluoromethanesulfonic acid (TfOH) in Solkane365mfc" Xu, X.-H.; Azuma, A.; Taniguchi, M.; Tokunaga, E.; *Shibata, N. The Royal Society of Chemistry Advances 2013, 3 pp.3848-3852. DOI:10.1039/C3RA00132F |
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"A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform" Kawai, H.; Yuan, Z.; Tokunaga, E.; *Shibata, N. Org. Biomol. Chem. 2013, 11 (9), pp.1446-1450. DOI:10.1039/C3OB27368G |
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"N-2-Iodobenzylcinchoninium bromide is effective for catalytic enantioselective trifluoromethylation of azomethine imines in Solkane® 365mfc" Okusu, S.; Kawai, H.; Xu, X.-H.; Tokunaga, E.; *Shibata, N. Journal of Fluorine Chemistry 2012, 143 pp.216-219. |
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"3,5-Bis(pentafluorosulfanyl)phenylboronic acid: A new organocatalyst for Conia-ene carbocyclization of 1,3-dicarbonyl compounds having terminal alkynes" Yang, Y.-D.; Lu, X.; Tokunaga, E.; *Shibata, N. Journal of Fluorine Chemistry 2013, 143 pp.204-209. |
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"C-F Bond Activation of Unactivated Aliphatic Fluorides: Synthesis of Fluoromethyl-3,5-diaryl-2 oxazolidinones by Desymmetrization od 2-Aryl-1,3-difluoropropan-2-ols" *Haufe, G.; Suzuki, S.; Yasui, H.; Terada, C.; Kitayama, T.; Shiro, M.; *Shibata, N. Angew. Chem. Int. Ed. 2012, 51 (49), pp.12275-12279. DOI:10.1002/anie.201207304 |
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"Decarboxylative Allylation of Trifluoroethyl Sulfones and Approach to Difluoromethyl Compounds" *Shibata, N.; Fukushi, K.; Furukawa, T.; Suzuki, S.; Tokunaga, E.; Cahard, D. Org. Lett. 2013, 14 (20), pp.5366-5369. DOI:10.1021/ol302589w |
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"Regioselective Synthesis of Pyrazole Triflones Based on Triflyl Alkyne Cycloadditions" Kawai, H.; Yuan, Z.; Tokunaga, E.; *Shibata, N. Org. Lett. 2012, 14 (20), pp.5330-5333. DOI:10.1021/ol3025154 |
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"Efficient Difluoromethylation of sp3 Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases" Liu, G.-K.; Wang, X.; Lu, X.; Xu, X.-H.; Tokunaga, E.; *Shibata, N. ChemistryOpen. 2012, 1 (5), pp.227-231. DOI:10.1002/open.201200033 |
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"Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters" Yang, Y.-D.; Lu, X.; Liu, G.-K.; Tokunaga, E.; *Tsuzuki, S.; *Shibata, N. ChemistryOpen. 2013, 1 (5), pp.221-226. DOI:10.1002/open.201200032 |
独立行政法人 産業技術総合研究所 ナノシステム研究部門 ソフトマターモデリンググループ 都築誠二 | |
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"Efficient synthesis of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts for electrophilic bromodifluoromethylating reagents" Liu, G.-K.; Mori, S.; Wang, X.; Noritake, S.; Tokunaga, E.; *Shibata, N. New Journal of Chemistry 2012, 36 (9), pp.1769-1773. DOI:10.1039/c2nj40255f |
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| Conference / Symposium / Lecture |
招待講演 "Thalidomide and its Chirality" ○*Shibata, N. Pharmacy – a journey from Edo times to modern pharmaceuticals and health economics 19. , Erlangen-Nürnberg University (Germany) 2014-05-23～2014-05-24 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. University of Rouen Lecture, Rouen (France) 2014-03-03～2014-03-03 |
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招待講演 "Kinetic Resolution of Allylic Fluorides by Enantioselective Allylic Trifluoromethylation based on " ○*Shibata, N. ZING Conference(Asymmetric Synthesis Conference), Parador de Nerja (Spain) 2014-02-25～2014-02-28 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. IBM research center Lecture, IBM research center (USA) 2014-02-18～2014-02-18 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. SynQuest Laboratories. Inc. Lecture, SynQuest (USA) 2014-02-15～2014-02-15 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. University of Florida Lecture, Florida (USA) 2014-02-14～2014-02-14 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. Changwon National University Lecture, Changwon (Korea) 2013-12-20～2013-12-20 |
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招待講演 "A new reagent for electrophilic trifluoromethylthiolation" ○*Shibata, N. 14th Tetrahedron Symposium Asian Edition, Ritz Carlton Seoul (Korea) 2013-10-21～2013-10-24 |
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招待講演 "Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Trifluoromethylthiolation" ○*Shibata, N. 9th AFMC International Medicinal Chemistry Symposium(AIMECS13) , Taipei (Taiwan) 2013-10-15～2013-10-18 |
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招待講演 "A Sterically Demanding Organo-superbase Avoids Decomposition of a Naked Trifluoromethyl Carbanion Directly Generated from Fluoroform" ○*Shibata, N. 10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds" ○*Shibata, N. Changzhou University Lecture, Changzhou University (Chaina) 2013-09-16～2013-09-16 |
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招待講演 "Enantioselective Synthesis of Organofluorine Compounds" ○*Shibata, N. International Workshop on Organofluorine Chemistry 2013, Nanjing University of Science & Technology (Chaina) 2013-09-12～2013-09-14 |
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招待講演 "First Synthesis of Benzene-fused Hetero-dimers of Phthalocyanine and Subphthalocyanine for Potential Applications in OPV" ○*Shibata, N. Solvay Fluor GmbH, Lecture, Solvay ( Germany) 2013-08-01～2013-08-09 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β,β,-Disubstituted Enones" ○*Shibata, N. 17th European Symposium on Fluorine Chemistry(17ESFC) , Paris Descartes University (France) 2013-07-21～2013-07-25 |
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招待講演 "Enantioselective Synthesis of Epoxides having a Tetrasubstituted Trifluoromethylated Carbon Center by Methylhydrazine-induced Non-metallic Aerobic Epoxidation of β,β-Disubstituted Enones" ○*Shibata, N. 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, 大津市 (日本) 2013-05-27～2013-05-28 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. Zhejiang University Lecture, Zhejiang (China) 2013-05-21～2013-05-21 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. Zhejiang University of Industry Lecture, Zhejiang (China) 2013-05-20～2013-05-20 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. Lanzhou University Lecture, Lanzhou (China) 2013-05-18～2013-05-18 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. Lanzhou Institute of Chemical Physics Lecture, Lanzhou (China) 2013-05-17～2013-05-17 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. Northwest Normal University Lecture, Lanzhou (China) 2013-05-17～2013-05-17 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. East China University Of Science And Technology Lecture, Shanghai (China) 2013-05-15～2013-05-15 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. EAST CHINA NORMAL UNIVERSITY Lecture, Shanghai (China) 2013-05-14～2013-05-14 |
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招待講演 "Enantioselective Synthesis of Biologically Active Molecules having a CF3 Quaternary Carbon " ○*Shibata, N. 中国科学院上海有机化学研究所講演会, Shanghai (China) 2013-05-13～2013-05-13 |
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招待講演 "First Synthesis of Benzene-fused Hetero-dimers of Phthalocyanine and Subphthalocyanine" ○*Shibata, N. 4th Japan-Korea-China Joint Seminar on Fluorine Chemistry, Nagoya (Japan) 2013-04-10～2013-04-12 |
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招待講演 "Trifluoroethoxy-Coated Subphthalocyanines: Synthesis, Characterization, Reactivity and Solubility" ○*Shibata, N. 245th ACS National Meeting & Exposition, New Orleans, LA (USA) 2013-04-07～2013-04-11 |
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招待講演 "ENANTIOSELECTIVE SYNTHESIS OF FLUORO-ORGANICCOMPOUNDS" ○*Shibata, N. Université de Versailles Seminer, Versailles (France) 2013-02-12～2013-02-12 |
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招待講演 "Recent Progress of Fluoromethylation Reactions" ○*Shibata, N. Barcelona University Seminer, Barcelona (Spain) 2012-05-25～2012-05-25 |
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招待講演 "Enantiocontrolled Synthesis of Organofluorine Compounds" ○*Shibata, N. BIT’s 3nd Annual World Congress of Catalytic Asymmetric Synthesis (WCCAS-2012), Beijing (China) 2012-05-12～2012-05-14 |
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招待講演 "Recent Progress of Fluoromethylation Reactions" ○*Shibata, N. 3rd International Symposium on Organofluorine Compounds in Biomedical, Materials and Agricultural Sciences, Valencia (Spain) 2012-05-20～2012-05-24 |
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招待講演 "Development of Shelf-stable Electrophilic Trifluoromethylating Reagents" ○*Shibata, N. 8th Japanese-French Joint Seminar on Fluorine Chemistry, Kyoto (Japan) 2012-07-19～2012-07-21 |
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招待講演 "ENANTIOSELECTIVE SYNTHESIS OF FLUORO-ORGANIC COMPOUNDS" ○*Shibata, N. 20th International Symposium on Fluorine Chemistry, Kyoto (Japan) 2012-07-22～2012-07-27 |
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招待講演 "Trifluoroethoxy-Coated Subphthalocyanines:Synthesis, Characterization, Reactivity and Solubility" ○*Shibata, N. 17th Malaysian Chemical Congress (17MCC), Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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招待講演 "Enantioselective 5-Endo-dig Carbocyclization with Internal Alkynes using a Combinatorial Box-Ph/Zn(II)/Yb(OTf)3/HFIP System" ○*Shibata, N. Cambodian Malaysian Chemical Conference (CMCC), Siem Reap (Cambodia) 2012-10-19～2012-10-21 |
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招待講演 "Enantioselective Synthesis of Partially Saturated Fluorinated HeterocyclesEnantioselective Synthesis of Partially Saturated Fluorinated Heterocycles" ○*Shibata, N. Fluorine Chemistry to Environment and Health Aspects , Changwon (South Korea) 2012-11-14～2012-11-16 |
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招待講演 "Enantioselective Synthesis of Partially Saturated Fluorinated Heterocycles " ○*Shibata, N. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| Prize |
"Angewandte Chemie - International Edition 審査員章" Shibata, N. 2014-04 WILEY-VCH 2013Angewandte Chemie-International Editionにおいてexcellent qualityの審査報告を17回行ったとしてCertificateを贈呈された。 |
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"文部学大臣表彰・学技術賞" Shibata N. 2014-04 文部学省 |
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| Media |
"フタロシアニン 溶解性高め多機能化－新化合物と合成法開発 電材用途など照準" Shibata. N. 化学工業日報5面 2014-05-07 PDF |
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"Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones via Anionic O→Cvinyl/N→Cvinyl Trifluoromethanesulfonyl Migration Reactions" Xu, X.-H.; Taniguchi, M.; Wang, X.; Tokunaga, E.; Ozawa, T.; Masuda, H.; Shibata, N. Angew. Chem. Int. Ed., 52(48), 12628-12631, 2013 2013-10-15 カバーとして紹介された。 |
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"Kinetic Resolution of Allylic Fluorides by Enantioselective Allylic Trifluoromethylation based on Silicon-assisted C-F Bond Cleavage" Nishimine, T.; Fukushi, K.; Shibata, N.; Taira, H.; Tokunaga, E.; Yamano, A.; Shiro, M.; Shibata, N. Angew. Chem. Int. Ed., 53(2), 517-520, 2014. (Cover) 2013-11-07カバーとして紹介された。 |
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"Diastereoselective Additive Trifluoromethylation/Halogenation of Isoxazole Triflones: Synthesis of All-carbon Functionalized Trifluoromethyl Isoxazoline Triflones" Kawai, H.; Sugita, Y., Tokunaga, E.; Sato, H.; Shiro, M.; Shibata, N. ChemistryOpen, 3(1), 2, 2014 2014-02-27 PDF Profileのページ\\研究室\\が掲載された。 |
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"
Diastereoselective Additive Trifluoromethylation/Halogenation of Isoxazole Triflones: Synthesis of All-carbon Functionalized Trifluoromethyl Isoxazoline Triflones " Kawai, H.; Sugita, Y., Tokunaga, E.; Sato, H.; Shiro, M.; Shibata, N. ChemistryOpen, 3(1), Cover-1, 2014 2014-02-27 PDF カバーとして紹介された。 |
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"名古工大、フッ素化合物から一度の応で種々の有用物質得られる合成法を開発" Shibata, N. 日刊工業新聞，20 2014-02-17 PDF |
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"名古工大、フッ素化合物「トリフロン」の簡便合成法を\\医薬品\\用期待" Shibata, N. 日刊工業新聞，17 \ 2014-01-20 PDF |
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"ビニルトリフロン類の新しい合成法-名古工大の研究グループ開発-反応時間短縮，医薬品開発に応用期待" Shibata, N. 科学新聞，4 面 2013-12-06 PDF |
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"フッ素化学の錬金術：フッ素樹脂副産物フルオロホルムの医薬品原料・液晶材料への活用" Shibata, N.; Sugita, Y.; Kawai, H. 月刊ファインケミカル42 11 5 頁 2013-11-01 PDF |
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"医・農薬向けフッ素化合物 安く安全・簡単製造 名古工大が試薬開発" Shibata, N. 日刊工業新聞，19 面 2013-08-20 PDF |
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"有機物と酸素で実現 不斉酸化反応 名古工大 医薬品製造低コスト化" Shibata, N. 日刊工業新聞，15 面 2013-07-29 PDF |
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"進む「フッ素科学」小さく自己主張強い元素" Shibata, N. 中部経済新聞，4面 2013-05-20 PDF |
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"名古工大、フッ素樹脂副産物フルオロホルム－医薬・液晶向け活用" Shibata, N. 日刊工業新聞，14 面 2013-03-04 PDF |
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"
名古屋工大、フッ素を含む農薬・動物医薬原料―有機触媒で効率合成
" Shibata, N. 日刊工業新聞 2012-07-24 PDF |
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| A02 滝澤 忍 | ||
| Original papers |
"Enantioselective organocatalytic oxidation of ketimine" *Takizawa, S.; Kishi, K.; Abozeid, M. A.; *Murai, K.; Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2016, 14 (2), pp.761-767. DOI:10.1039/C5OB02042E |
Murai, K. |
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"Phosphine-catalyzed β,γ-umpolung domino reaction of allenic esters: Facile synthesis of tetrahydrobenzofuranones bearing a chiral tetrasubstituted carbon stereogenic center" Takizawa, S.; Kishi, K.; Yoshida, Y. Mader, S.; Arteaga, F. A.; Lee, S.; Hoshino, M.; Rueping, M.; Fujita, M.; *Sasai, H. Angew. Chem. Int. Ed. 2015, 54 (51), pp.15511-15515. DOI:10.1002/anie.201508022 |
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"An enantioselective organocatalyzed aza-Morita−Baylis−Hillman reaction of isatin-derived ketimines with acrolein" Yoshida, Y.; Sako, M.; Kishi, K.; Sasai, H.; Hatakeyama, S.; *Takizawa, S. Org. Biomol. Chem. 2015, 13 (34), pp.9022-9028. DOI:10.1039/C5OB00874C |
Hatakeyama, S. | |
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"Pd(II)-catalyzed diastereoselective and enantioselective domino cyclization/cycloaddition reactions of alkenyl oximes for polycyclic heterocycles with four chiral stereogenic centers" Abozeid, M. A.; *Takizawa, S.; Sasai, H. Tetrahedron Lett. 2015, 56 (29), pp.4316-4319. DOI:10.1016/j.tetlet.2015.05.070 |
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"Enantioselective and aerobic oxidative coupling of 2-naphthol derivatives using chiral dinuclear vanadium(V) complex in water" Sako, M.; *Takizawa, S.; Yoshida, Y.; *Sasai, H. Tetrahedron: Asymmetry 2015, 26 (12-13), pp.613-616. DOI:10.1016/j.tetasy.2015.05.002 |
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"Structural Features and Asymmetric Environment of i-Pr-SPRIX Ligand" Takenaka, K.; Lin, X.; Takizawa, S.; *Sasai, H. Chirality 2015, 27 (8), pp.532-537. DOI:10.1002/chir.22467 |
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"Pd-catalyzed enantioselective intramolecular
α-arylation of α-substituted cyclic ketones: Facile synthesis of functionalized
chiral spirobicycles
" Fan, L.; *Takizawa, S.; Takeuchi, Y.; Takenaka, K.; *Sasai, H. Org. Biomol. Chem. 2015, 13 (17), pp.4837-4840. DOI:10.1039/C5OB00382B |
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"Facile Regio- and Stereoselective Metal-Free Synthesis of All-Carbon Tetrasubstituted Alkenes Bearing a C(sp3)–F Unit via Dehydroxyfluorination of Morita–Baylis–Hillman (MBH) Adducts" *Takizawa, S.; Arteaga F. A.; Kishi, K.; Hirata, S.; *Sasai, H. Org. Lett. 2014, 16 (16), pp.4162-4165. DOI:10.1021/ol501855m |
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"C3-Symmetric Chiral
Trisimidazoline-Catalyzed Friedel-Crafts (FC)-Type Reaction" *Takizawa, S.; Hirata, S.; *Murai, K.; Fujioka, H.; Sasai, H. Org. Biomol. Chem. 2014, 12 (31), pp.5827-5830. DOI:10.1039/C4OB00925H |
Murai, K. | |
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"Enantioselective Organocatalyzed Formal [4+2]
Cycloaddition of Ketimines with Allenoates: Easy Access to a Tetrahydropyridine
Framework with a Chiral Tetrasubstituted Carbon Stereogenic Center" Takizawa, S.; Arteaga,
F. A.; Yoshida, Y.; Suzuki, M.; *Sasai, H. Asian J. Org. Chem. 2014, 3 (4), pp.412-415. DOI:10.1002/ajoc.201300244 |
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"Enantioselective oxidative-coupling of polycyclic phenols" Takizawa, S.; Kodera, J.; Yoshida, Y.; Sako, M.; Breukers, S.; Enders, D.; *Sasai, H. Tetrahedron 2014, 70 (9), pp.1786-1793. DOI:10.1016/j.tet.2014.01.017 |
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"P-Chirogenic
organocatalysts: Application to the aza-Morita-Baylis-Hillman (aza-MBH)
reaction of ketimines" Takizawa, S.; Rémond, E.; Arteaga,
F. A.; Yoshida, Y.; Sridharan, V.; Bayardon, J.; *Jugé, S.; *Sasai, H. Chem. Commun. 2013, 49 (75), pp.8392-8394. DOI:10.1039/C3CC44549F |
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"Organocatalyzed formal
[2+2] cycloaddition of ketimines with allenoates: Facile access to azetidines
with a chiral tetrasubstituted carbon stereogenic center" Takizawa, S.; Arteaga,
F. A.; Yoshida, Y.; Suzuki, M.; *Sasai, H. Org. Lett. 2013, 15 (16), pp.4142-4145. DOI:10.1021/ol401817q |
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"Pd(II)-SDP-catalyzed enantioselective 5-exo-dig cyclization
of γ-alkynoic acids: Application to the synthesis of functionalized dihydofuran-2(3H)-ones containing a
chiral quaternary carbon center" Sridharan, V.; Fan, L.; Takizawa, S.; Suzuki, T.; *Sasai,
H. Org. Biomol. Chem. 2013, 11 (35), pp.5936-5943. DOI:10.1039/C3OB41103F |
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"Chiral
bifunctional organocatalysts bearing a 1,3-propanediamine unit for the aza-MBH reaction" Hirata, S.; Tanaka, K.; Matsui, K.; Arteaga, F. A.; Yoshida, Y.; *Takizawa,
S.; *Sasai, H. Tetrahedron: Asymmetry 2013, 24 (19), pp.1189-1192. DOI:10.1016/j.tetasy.2013.08.005 |
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"DFT
study on 5-endo-trig-type cyclization of 3-alkenoic acids using Pd-SPRIX catalyst:
Importance of the rigid spiro framework for both selectivity and reactivity" Gabr, R. K.; Hatakeyama, T.; Takenaka, K.; Takizawa, S.; Okada, Y.; Nakamura, M.; *Sasai, H.
Chem. Eur. J. 2013, 19 (29), pp.9518-9525. DOI:10.1002/chem.201203189 |
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"Vanadium-catalyzed enantioselective Friedel Crafts-type reactions" Takizawa, S.; Arteaga, F. A.; Yoshida, Y.; Kodera, J.; Nagata, Y.; *Sasai, H.
Dalton Trans 2013, 42 (33), pp.11787-11790. DOI:10.1039/C2DT32202A |
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"o-(Hydroxyalkyl)phenyl P-chirogenic phosphines as functional chiral Lewis bases" Rémond, E.; Bayardon, J.; Takizawa, S.; Rousselin, Y.; *Sasai, H.; *Jugé, S. Org. Lett. 2013, 15 (8), pp.1870-1873. DOI:10.1021/ol400515e |
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"Facile synthesis of
α-methylidene-γ-butyrolactones: Intramolecular Rauhut-Currier reaction promoted
by chiral acid-base organocatalysts" Takizawa, S.; Nguyen, T. M.-N.; Grossmann, A.; Suzuki, M.; Enders, D.; *Sasai, H. Tetrahedron 2013, 69 (3), pp.1202-1209. DOI:10.1016/j.tet.2012.11.046 |
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"Design and Synthesis of Spiro Bis(1,2,3-triazolium) Salts as Chiral Ionic Liquids" Yoshida, Y.; *Takizawa, S.; Sasai, H. Tetrahedron: Asymmetry 2012, 23 (11-12), pp.843-851. DOI:10.1016/j.tetasy.2012.06.007 |
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"Enantioselective Synthesis of α-Alkylidene-γ-Butyrolactones: Intramolecular Rauhut–Currier Reaction Promoted by Acid/Base Organocatalysts" Takizawa, S.; Nguyen, T. M-N.; Grossmann, A.; Enders, D.; *Sasai, H. Angew. Chem. Int. Ed. 2012, 51 (22), pp.5423-5426. DOI:10.1002/anie.201201542 |
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| Books |
「Sustainable Catalysis: With Non-endangered Metals, Part 1」 North, M. "Vanadium and niobium catalyzed enantioselective reactions" Sasai, H.; Takizawa, S. RSC 2015, pp216-249. ISBN:978-1-78262-057-0 |
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「Domino Reactions」 L. F. Tietze "Metal-Catalyzed Enantio- and Diastereoselective C-C Bond-Forming Reaction in Domino Processes" Takizawa, S.; Sasai, H. Wiley-VCH (Germany) 2014, pp419-462. |
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「Comprehensive Chirality」 Yamamoto, H.; Carreira, E. "(aza) Morita–Baylis–Hillman Reaction" Sasai, H.; Takizawa, S. ELSEVIER Ltd (UK) 2013, pp234-263. |
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| Reviews / Accounts |
"Vanadium in Asymmetric Synthesis: Emerging Concepts in Catalyst Design and Applications" Takizawa, S.; *Gröger, H.; *Sasai, H. Chem. Eur. J. 2015, 21 (25), pp.8992-8997. DOI:10.1002/chem.201406444 |
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"Enantioselective Acid-Base Organocatalyzed Domino Reactions
Based on aza-Morita-Baylis-Hillman Process" Takizawa, S.; *Sasai, H. J. Synth. Org. Chem. Jpn 2014, 72 (7), pp.781-796. DOI:10.5059/yukigoseikyokaishi.72.781 |
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| Conference / Symposium / Lecture |
招待講演 "Enantioselective organocatalyzed formal [n+2] cycloaddition using allenoates" ○Takizawa, S.; *Sasai, H.
PACIFICHEM 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Organocatalyzed syntheis of heterocycles bearing a chiral tetrasubstituted carbon center" ○Takizawa, S.; Kishi, K.; *Sasai, H. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Pd(II)-SPRIX Catalyzed Enantioselective Fujiwara-Moritani Annulation of Alkenylindoles" ○Abozeid, M. A.; Takizawa, S.; *Sasai, H. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Facile Synthesis of α-Methylidene-γ-Lactams via Amidation and Rauhut-Currier Reaction Sequence" ○Kishi, K.; Takizawa, S.; Arteaga, F. A.; *Sasai, H. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Vanadium (V)-catalyzed enantioselective synthesis of oxa[9]helicene" ○Sako, M.; Takizawa, S.; Takeuchi, Y.; Tsujihara, T.; Ichinose, K.; Kodera, J.; Yoneyam, S.; Kawano, T.; *Sasai, H. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Vanadium complex catalyzed enantioselective synthesis of oxa[9]helicenes" ○Takizawa, S.; Sako, M.; *Sasai, H. 251st ACS National Meeting, San Diego (USA) 2016-03-13～2016-03-17 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed [3+2] Annulation via Umpolung Domino Reaction of Allenoates" ○Kishi, K.; Takizawa, S.; Yoshida, Y.; Mader, S.; Rueping, M.; *Sasai, H. Aachen-Osaka Joint Symposium “Biotechnology and Chemistry for Green Growth”, Osaka (Japan) 2016-03-09～2016-03-10 |
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"Synthetic Studies on Heterohelicene Derivatives Using Vanadium-catalyzed Oxidative Reaction" ○Sako, M.; Ichinose, K.; Takizawa, S.; *Sasai, H. Osaka (Japan) 2016-03-09～2016-03-10 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Synthesis of Tetrahydrobenzofuranones Bearing a Tetrasubstituted Stereogenic Center" ○Kishi, K.; Takizawa, S.; Yoshida, Y.; Mader, S.; Rueping, M.; *Sasai, H. The 8th Takeda Science Foundation Symposium on PharmaSciences, Osaka (Japan) 2016-01-21～2016-01-22 |
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口頭発表／ポスター発表 "Spiro Chiral Ligand-Pd(II) Complex Catalyzed Enantioselective Construction of Heterocycles" ○Abozeid, M. A.; *Takizawa, S.; Sasai, H. The 8th Takeda Science Foundation Symposium on PharmaSciences, Osaka (Japan) 2016-01-21～2016-01-22 |
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口頭発表／ポスター発表 "Organocatalyzed Synthesis Of Heterocycles Bearing a Chiral Tetrasubstituted Carbon Center" Takizawa, S.; ○Kishi, K.; *Sasai, H. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Spiro Chiral Ligand-Pd(II) Complex Catalyzed Enantioselective Construction of Heterocycles" ○Abozeid, M. A.; *Takizawa, S.; Sasai, H. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Vanadium(V)-Catalyzed Enantioselective C–C Bond Forming Reactions" ○Sako, M.; Takizawa, S.; Yoshida, Y.; *Sasai, H. Aachen-Osaka Joint Symposium “Biological and Chemical Methods for Selective Catalysis”, Aachen (Germany) 2015-09-01～2015-09-02 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Oxa[9]helicenes Using Chiral Vanadium Catalysts" ○Takizawa, S.; Sako, M.; Takeuchi, Y.; Tsujihara, T.; Kodera, J.; Kawano, T.; *Sasai, H. 15th International Conference on Chiroptical Spectroscopy, Hokkaido (Japan) 2015-08-30～2015-09-03 |
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口頭発表／ポスター発表 "Enantioselective and Aerobic Oxidative Coupling of 2-Naphthol Derivatives Using Chiral Dinuclear Vanadium Complex in Water" ○Sako, M.; *Takizawa, S.; Yoshida, Y.; Sasai, H. The 3rd International Symposium on Process Chemistry, Kyoto (Japan) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Enantioselective organocatalyzed formal cycloaddition reactions based on the aza-Morita-Baylis-Hillman process" ○Takizawa, S.; *Sasai, H. The 39th Naito Conference, Hokkaido (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Vanadium Complex Catalyzed Enantioselective Synthesis of Oxa[9]helicene" ○Takizawa, S.; Sako, M.; Takeuchi, Y.; Tsujihara, T.; Yoshida, Y.; Kodera, J.; Kawano, T.; *Sasai, H. 18th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS18), Barcelona (Spain) 2015-06-28～2015-07-02 |
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口頭発表／ポスター発表 "Carbon Nanotubes(CNTs)-Supported Vanadium(V) Catalyst" ○Sako, M.; Takizawa, S.; Tsujihara, T.; Yoshida, Y.; Kodera, J.; Kawano, T.; *Sasai, H. The 18th SANKEN and The 13th SANKEN Nanotechnology Symposium, Osaka (Japan) 2014-12-10～2014-12-11 |
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口頭発表／ポスター発表 "Enantio- and Diastereoselective Rauhut-Currier Reaction: Facile Synthesis of α-Methylidene-γ-Butyrolactones and γ-Butyrolactams" ○Takizawa, S.; Kishi, K.; Nguyen, T. M.-N.; Arteaga, F. A.; Suzuki, M.; *Sasai, H. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2] Cycloaddition Using Allenoates " ○Takizawa, S.; Arteaga, F. A.; Yoshida, Y.; Suzuki, M.; Kishi, K.; Nguyen, T. M.-N.; *Sasai, H Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-31 |
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口頭発表／ポスター発表 "Enantioselective C–C Bond Forming Reactions Catalyzed by Vanadium(V) Complex" Takizawa, S.; Yoshida, Y.; Sako, M.; Kodera, J.; ○Sakai, T.; *Sasai, H. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-31 |
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口頭発表／ポスター発表 "Enantioselective Palladium(II) Catalyzed Cyclization-Cycloaddition Cascade Reactions of Alkenyl Oximes" ○Abozeid, M. A.; Takizawa, S.; *Sasai, H. Molecular Chirality Asia 2014, Beijing (China) 2014-10-29～2014-10-31 |
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口頭発表／ポスター発表 "Enantioselective C–C Bonf Forming Reactions Catalyzed by Vanadium(V) Complex" ○Sako, M.; Takizawa, S.; Tsujihara, T.; Yoshida, Y.; Kodera, J.; Kawano, T.; *Sasai, H. ETH Zürich-Osaka Univ. Joint Symposium, Osaka (Japan) 2014-10-09～2014-10-10 |
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口頭発表／ポスター発表 "Enantioselective C–C Bond Forming Reactions Catalyzed by Vanadium(V) Complex" ○Sako, M.; Takizawa, S.; Yoshida, Y.; Kodera, J.; *Sasai, H. Aachen-Osaka Joint Symposium, Aachen (Germany) 2014-09-03～2014-09-05 |
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口頭発表／ポスター発表 "Organocatalyzed Enantioselective Reactions of Ketimines with Allenoates" Takizawa, S.; Arteaga, F. A.; Yoshida, Y.; Suzuki, M.; ○*Sasai, H. Aachen-Osaka Joint Symposium, Aachen (Germany) 2014-09-03～2014-09-05 |
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口頭発表／ポスター発表 "Enantioselective Palladium(II) Catalyzed Cyclization-Cycloaddition Cascade Reactions of Alkenyl Oximes" ○Abozeid, M. A.; Takizawa, S.; *Sasai, H. 248th ACS National Meeting & Exposition, San Francisco (USA) 2014-08-10～2014-08-14 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Domino Process Based on aza-Morita-Baylis-Hillman-type (aza-MBH) Reaction" ○Hirata, S.; Takizawa, S.; Inoue, N.; Arteaga, F. A.; Yoshida, Y.; Suzuki, M.; *Sasai, H. 248th ACS National Meeting & Exposition, San Francisco (USA) 2014-08-10～2014-08-14 |
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口頭発表／ポスター発表 "Enantioselective C-C Bond Forming Reactions Catalyzed by Vanadium(V) complex" ○Sako, M.; Takizawa, S.; Yoshida, Y.; Kodera, J.; Doi, T.; *Sasai, H. ICOMC-2014 Post-Symposium, Osaka (Japan) 2014-07-19～2014-07-19 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Chiral Spiro Compounds and Their Applications to Organocatalysis" ○Takeuchi, Y.; Fan, L.; Takizawa, S.; *Sasai, H. The XXVI International Conference on Organometallic Chemistry, Sapporo ( Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2] Cycloaddition Using Allenoates" Takizawa, S.; Arteaga, F. A.; ○Yoshida, Y.; Suzuki, M.; Nguyen, T. M.-N.; *Sasai, H. 15th Tetrahedron Symposium, London (UK) 2014-06-24～2014-06-27 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of α-Methylidene-γ-Butyrolactones and γ-Butyrolactams: Intramolecular Rauhut-Currier Reaction Promoted by Bifunctional Organocatalysts" Takizawa, S.; Nguyen, T. M.-N.; Kishi, K.; ○Arteaga, F. A.; Suzuki, M.; *Sasai, H. 15th Tetrahedron Symposium, London (UK) 2014-06-24～2014-06-27 |
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口頭発表／ポスター発表 "Development of Chiral Catalyst Based on Functionalization of 1,2,3-Triazoles" ○Yoshida, Y.; Takizawa, S.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2] Cycloaddition Using Ketimines and Allenoates" ○Arteaga, F. A.; Takizawa, S.; Yoshida, Y.; Suzuki, M.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Dual Activation in Homo-Couplings Catalyzed by a Chiral Dinuclear Vanadium(V) Complex" Takizawa, S.; Tsujihara, T.; Kodera, J.; ○Sako, M.; Akita, M.; Doi, T.; Hatanaka, M.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Chiral Trisimidazole-Catalyzed Friedel-Crafts (FC)-type Reaction" ○Hirata, S.; *Takizawa, S.; *Murai, K.; *Fujioka, H.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
Murai, K. | |
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口頭発表／ポスター発表 "Catalytic Enantioselective Synthesis of Spiro Compounds and Their Applications to Asymmetric Catalysis" ○Fan, L.; Takeuchi, Y.; Takizawa, S.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Enantioselective Palladium(II) Catalyzed Cyclization-Cycloaddition Cascade Reactions of Alkenyl Oximes" ○Abozeid, M. A.; Takizawa, S.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Facile Synthesis of Tetrasubstituted Olefins Bearing Four Different Functional Units" ○Kishi, K.; Takizawa, S.; Arteaga, F. A.; *Sasai, H. The 17th SANKEN International Symposium, Osaka (Japan) 2014-01-21～2014-01-22 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of Alfa-Methylidene-Ganma-Butyrolactones: Intramolecular Rauhut-Currier Reaction Promoted by Acid/Base Organocatalysts" ○Nguyen, T. M.-N.; Grossmann, A.; Takizawa, S.; Suzuki, M.; Enders, D.; *Sasai, H. First Osaka University-EPFL International Symposium, Osaka (Japan) 2013-12-02～2013-12-04 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2] Cycloaddition of Ketimines" ○Arteaga, F. A.; Takizawa, S.; Yoshida, Y.; Suzuki, M.; *Sasai, H. First Osaka University-EPFL International Symposium, Osaka (Japan) 2013-12-02～2013-12-04 |
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口頭発表／ポスター発表 "Recent Progress in Pd-SPRIX Catalyzed Enantioselective Reactions" Takenaka, K.; ○Dhage, Y. D.; Mohanta, S. C.; Takizawa, S.; *Sasai, H. The 8th International Symposium on Integrated Synthesis (ISIS-8), Nara (Japan) 2013-11-29～2013-12-01 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2]
Cycloaddition of Ketimines with Allenoates" ○Arteaga, F. A.; Takizawa, S.; Yoshida, Y.; Suzuki, M.; *Sasai, H. The 8th International Symposium on Integrated Synthesis (ISIS-8), Nara (Japan) 2013-11-29～2013-12-01 |
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口頭発表／ポスター発表 "Recent Progress in Pd-SPRIX Catalyses" Takenaka, K.; Mohanta, S. C.; Dhage, Y. D.; Takizawa, S.; ○*Sasai, H. The 8th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-8) and The 4th New Phase International Conference on S Cutting-Edge Organic Chemistry in Asia (NICCEOCA-4), Osaka (Japan) 2013-11-25～2013-11-28 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Cycloadditions Based
on the aza-Morita-Baylis-Hillman-type (aza-MBH) and Rauhut-Currier (RC) Process" ○Takizawa, S.; *Sasai, H. The 8th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-8) and The 4th New Phase International Conference on S Cutting-Edge Organic Chemistry in Asia (NICCEOCA-4), Osaka (Japan) 2013-11-25～2013-11-28 |
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口頭発表／ポスター発表 "Acid-Base Organocatalyzed Enantioselective Synthesis
of Highly Functionalized Heterocyclic Compounds" ○Takizawa, S.; Nguyen,
T. M.-N.; Inoue,
N.; Hirata, S.; *Sasai, H. 10th International Symposium on Carbanion Chemistry, Kyoto (Japan) 2013-09-23～2013-09-26 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Formal [n+2]
Cycloaddition of Ketimines" ○Arteaga, F. A.; Takizawa, S.; Yoshida, Y.; Suzuki, M.; *Sasai, H. 10th International Symposium on Carbanion Chemistry, Kyoto (Japan) 2013-09-23～2013-09-26 |
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口頭発表／ポスター発表 "Dual Activation in Homo- and Hetero-Couplings Promoted
by A Chiral Dinuclear Vanadium(V) Catalyst" ○Takizawa, S.; Tsujihara, T.; Kodera,
J.; Arteaga, F. A.; Yoshida, Y.; Nagata,
Y.; *Sasai, H. 15th Asian Chemical Congress, Sentosoa (Singapore) 2013-08-19～2013-08-23 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed Aza-Morita-Baylis-Hillman
(aza-MBH) Reraction of Ketimines" Takizawa, S.; Remond, E.; ○Arteaga, F. A.; Yoshida, Y.; Sridharan, V.; Bayardon, J.; *Jugé, S.; *Sasai, H. 15th Asian Chemical Congress, Sentosoa (Singapore) 2013-08-19～2013-08-23 |
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口頭発表／ポスター発表 "Enantioselective Organocatalyzed aza-MBH Domino
Reactions of Ketimine" Takizawa, S.; Arteaga, F. A.; ○Yoshida, Y.; *Sasai, H. The 16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis, Sapporo (Japan) 2013-08-04～2013-08-09 |
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口頭発表／ポスター発表 "Dual Activation in Homo- and Hetero-Couplings Promoted
by a Chiral Dinuclear Vanadium(V) Catalys" ○Takizawa, S.; Kodera, J.; Arteaga, F. A.; Yoshida, Y.; Nagata, Y.; *Sasai, H. Sapporo (Japan) 2013-08-04～2013-08-09 |
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口頭発表／ポスター発表 "Catalytic Enantioselective Synthesis of Chiral
Spiro[4.4]nonane Derivatives and Their Applications to Asymmetric Catalysis" ○Fan, L.; Takizawa, S.; *Sasai, H. 25th International Symposium on Chirality, Shanghai (China) 2013-07-07～2013-07-10 |
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口頭発表／ポスター発表 "Novel Catalytic Reaction Promoted by Pd-SPRIX Complex" Takenaka, K.; Mohanta, S. C.; Dhage, Y. D.; Takizawa, S.; ○*Sasai, H. First Osaka University-EPFL International Symposium, Osaka (Japan) 2013-12-02～2013-12-04 |
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口頭発表／ポスター発表 "Organocatalyzed Enantioselective Aza-MBH Reaction of
Ketimines" Takizawa,
S.; Rémond, E.; ○Arteaga, F. A.; Bayardon, J.; Yoshida, Y.; Jugé, S.; *Sasai, H. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Recent Progress of Enantioselective Catalysis
Promoted by Pd-SPRIX" ○Takenaka,
K.; Mohanta, S. C.; Akita, M.; Takizawa, S.; *Sasai, H. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Enantioselective C-C Bond Forming Reactions Using
Multi-Functional Organocatalysts " ○Takizawa,
S.; Matsui, K.; Inoue, N.; Nguyen, T.
M.-N.; *Sasai,
H. The 12th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Recent Application of Spiro Bis(isoxazoline) Ligand
(SPRIX) for Asymmetric Catalysis" ○Mohanta,
S. C.; Tsujihara, T.; Akita, M.; Takenaka, K.; Takizawa, S.; *Sasai, H. The 6th Takeda Science Foundation Symposium on PharmaSciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "Enantioselective Synthesis of a-Alkylidene-g-Butyrolactones:
Intramolecular Rauhut-Currier Reaction Promoted by Acid/Base Organocatalysts" ○Nguyen,
T. M.-N.; Takizawa, S.; Grossmann, A.;
Enders, D.; *Sasai, H. The 6th Takeda Science Foundation Symposium on PharmaSciences, Osaka (Japan) 2012-09-13～2012-09-14 |
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口頭発表／ポスター発表 "Enantioselective Carboxylation via a p-Allyl Pd
Intermediate Promoted by Pd-SPRIX Catalyst" ○Takenaka,
K.; Akita, M.; Mohanta, S. C.; Takizawa, S.; Sasai, H. International Conference on Functional Organic Materials and Related Devices, Hsinchu (Taiwan) 2012-06-16～2012-06-17 |
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口頭発表／ポスター発表 "Enantioselective Coupling of Phenanthrols Using
Vanadium Catalysts" ○Kodera,
J.; Takizawa, S.; *Sasai,
H. International Conference on Functional Organic Materials and Related Devices, Hsinchu (Taiwan) 2012-06-16～2012-06-17 |
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口頭発表／ポスター発表 "Development
of BINOL-Derived Organocatalysts with Dual Activation Mechanism and Their
Applications to Enantioselective Friedel-Crafts Type Reaction" ○Nagata, Y.; Takizawa, S.; *Sasai, H. 3rd International Symposium on Organic Synthesis and Drug Development (ISOSDD2012), Changzhou (China) 2012-05-20～2012-05-23 |
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"Enantioselective Intramolecular Rauhut-Currier Reaction" ○Nguyen, T. M.-N.; Grossmann, A.; Takizawa, S.; Enders, D.; *Sasai, H. 3rd International Symposium on Organic Synthesis and Drug Development (ISOSDD2012), Changzhou (China) 2012-05-20～2012-05-23 |
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口頭発表／ポスター発表 "Enantioselective
Synthesis of Multifunctional Heterocyclic Compounds via Acid-Base
Organocatalysis" ○Takizawa, S.; Nguyen, T. M.-N.; Inoue, N.; Hirata, S.;
*Sasai, H. 7th International Symposium on Acid-Base Catalysis, Tokyo (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "Dual
Activation in Homo- and Hetero-couplings Promoted by a Chiral Dinuclear
Vanadium(V) Catalyst" ○Takizawa, S.; Tsujihara, T.; Kodera, J.; Arteaga-Arteaga,
F.; Yoshida, Y.; Nagata, Y.; *Sasai, H. The 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Enantioselective
Cyclization of 4-Alkenoic Acids via an Oxidative Allylic C–H Esterification" ○Akita,
M.; Tanigaki, Y.; Takenaka, K.; Takizawa, S.; *Sasai, H. 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2013-04-11 |
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口頭発表／ポスター発表 "Umpolung
Reactivity of Pd Enolate: Cyclative Diacetoxylation of Alkynyl
Cyclohexadienones Catalyzed by Pd-SPRIX" ○Takenaka,
K.; Mohanta, S. C.; Takizawa, S.; *Sasai, H. 245th ACS National Meeting, New Orleans (USA) 2013-04-07～2013-04-11 |
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口頭発表／ポスター発表 "Organocatalyzed Enantioselective Aza-MBH Reaction of
Ketimines" Takizawa,
S.; Rémond, E.; ○Arteaga. A. F.; Bayardon, J.; Yoshida, Y.; Vellaisamy,
S.; Jugé, S.; *Sasai,
H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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"Enantioselective Synthesis of Alfa-Methylidene-Gamma-Butyrolactones:
Intramolecular Rauhut-Currier Reaction Promoted by Acid/Base Organocatalysts" ○Nguyen, T. M.-N.; Takizawa, S.; Grossmann, A.;
Suzuki, M.; Enders, D.; *Sasai, H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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口頭発表／ポスター発表 "Development
of New Efficient Synthesis Method of Spiro Bis(1,2,3-triazole)s and Their
Applications" ○Yoshida,
Y.; Takizawa, S.; *Sasai,
H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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口頭発表／ポスター発表 "Design
and Synthesis of Organocatalysts Bearing Spiro Backbone" ○Fan,
L.; Takizawa, S.; *Sasai,
H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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口頭発表／ポスター発表 "Study
on Asymmetric Environment of SPRIX Ligand" ○Lin,
X.; Takenaka, K.; Takizawa, S.; *Sasai, H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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口頭発表／ポスター発表 "Enantioselective
Cyclization of 4-Alkenoic Acids via an Oxidative Allylic C-H Esterification" ○Akita,
M.; Tanigaki, Y.; Takenaka, K.; Takizawa, S.; *Sasai, H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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口頭発表／ポスター発表 "Recent
Progress of Enantioselective Catalysis Promoted by Pd-SPRIX" ○Mohanta,
S. C.; Dhage, Y. D.; Takenaka, K.; Takizawa, S.; *Sasai, H. The 16th SANKEN International and The 11th SANKEN Nanotechnology Symposium, Osaka (Japan) 2013-01-22～2013-01-23 |
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招待講演 "Enantioselective C-C
Bond Forming Reactions Using Multi-Functional Organocatalysts: aza-Morita-Baylis-Hillman (aza-MBH) Reaction of Ketimines" ○*Takizawa, S.
第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, Japan (Otsu) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Development
of New Efficient Synthesis Method of Spiro Bis(1,2,3-triazole)s and Their
Applications" ○Yoshida,
Y.; Takizawa, S.; *Sasai,
H. Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Osaka (Japan) 2013-03-11～2013-03-13 |
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口頭発表／ポスター発表 "Enantioselective
Pd(II)/Pd(IV) Catalysis Using SPRIX Ligand: Efficient Synthesis of Chiral
Tetrahydrofuran Derivatives" ○Takenaka,
K.; Dhage, Y. D.; Takizawa, S.; *Sasai, H Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Osaka (Japan) 2013-03-11～2013-03-13 |
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招待講演 "Enantioselective
Organocatalyzed Aza-Morita-Baylis-Hillman (Aza-MBH) Reaction of Ketimines" ○Takizawa,
S.; Arteaga, A. F.; Yoshida, Y.; Vellaisamy, S.; Rémond, E.; Bayardon, J.; Jugé,
S.; *Sasai,
H. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Study
on Asymmetric Environment of SPRIX Ligand" ○Lin,
X.; Takenaka, K.; Takizawa, S.; *Sasai, H Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Aachen (Germany) 2012-12-03～2012-12-05 |
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口頭発表／ポスター発表 "Design
and Synthesis of Organocatalysts Bearing Spiro Backbone
" ○Fan,
L.; Takizawa, S.; *Sasai,
H. Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Aachen (Germany) 2012-12-03～2012-12-05 |
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口頭発表／ポスター発表 "Enantioselective
Organocatalyzed Aza-Morita-Baylis-Hillman (Aza-MBH) Reaction of Ketimines" ○Takizawa, S.; Arteaga, A. F.; Yoshida, Y.; Vellaisamy, S.; Rémond, E.; Bayardon, J.; Jugé, S.; *Sasai, H. Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Aachen (Germany) 2012-12-03～2012-12-05 |
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口頭発表／ポスター発表 "Umpolung Reactivity of Pd Enolate
" Takenaka,
K.; Mohanta, S. C.; Takizawa, S.; ○*Sasai, H. Aachen-Osaka Symposium “Biological and Chemical Methods for Selective Catalysis”, Aachen (Germany) 2012-12-03～2012-12-05 |
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招待講演 "Umpolung
Reactivity of Pd Enolate: Cyclative Diacetoxylation of Alkynyl
Cyclohexadienones Catalyzed by Pd-SPRIX" Takenaka,
K.; Mohanta, S. C.; Takizawa, S.; ○*Sasai, H. The 6th Kansai-CMDS Meeting on OMCOS 2012, Gangwon-do (Korea) 2012-09-21～2012-09-23 |
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招待講演 "Enantioselective C-C Bond-forming Reactions Catalyzed
by Vanadium(V) Complexes" ○*Sasai,
H.; Takizawa, S.; Kodera, J. 8th International Vanadium Symposium Chemistry, Biological Chemistry, & Toxicology (V8), Washington DC (USA) 2012-08-15～2012-08-18 |
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口頭発表／ポスター発表 "Several
Catalytic Enantioselective Reactions Promoted by Vanadium Complexes" ○Takizawa,
S.; *Sasai,
H. Osaka-Bielefeld Symposium on Chiral Synthetic Chemistry, Bielefeld (Germany) 2012-07-11～2012-07-11 |
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| Prize |
"Molecular Chirality Asia 2016 Poster Award" Sako, M.; Takizawa, S.; Takeuchi, Y.; Tsujihara, T.; Ichinose, K.; Kodera, J.; Yoneyam, S.; Kawano, T.; *Sasai, H. 2016-04 Molecular Chirality Asia 2016 |
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"優秀ポスター賞" Kishi, K.; Takizawa, S.; Yoshida, Y.; *Sasai, H. 2016-01 「有機分子触媒による未来型分子変換」第6回公開シンポジウム エナンチオ選択的非対称化を基盤とする二連続不斉炭素を有する複素環化合物の合成 |
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"大阪大学総長奨励賞（研究部門）" *Takizawa, S. 2015-05 国立大学法人大阪大学 大学の研究活動への貢献 |
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"大阪大学総長表彰" Takizawa, S. 2014-10 国立大学法人大阪大学 学会発表・受賞による大学発展寄与に関する表彰 |
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"第34回有機合成若手セミナー優秀研究発表賞(ポスター賞)" Kishi, K.; Arteaga、F. A.; Hirata, S.; Takizawa, S.; *Sasai, H. 2014-08 日本薬学会近畿支部・有機合成化学協会関西支部 四置換オレフィンの簡便かつメタルフリーな立体選択的合成法の開発 |
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"Elsevier Best Poster Prize" Takizawa, S.; Nguyen, T.M.N.; Kishi, K.; Arteaga,
F.A.; Suzuki, M.; *Sasai, H.
2014-06 15th Tetrahedron Symposium Enantioselective synthesis of α-methylidene-γ-butyrolactones and γ-butyrolactams: intramolecular Rauhut-Currier reaction promoted by bifunctional organocatalysts |
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"シンポジウム モレキュラー・キラリティー 2014 ポスター賞" Takizawa, S.; Yoshida, Y.; Kodera, J.; Sako, M.; Doi, T.; *Sasai, H. 2014-06 シンポジウム モレキュラー・キラリティー 2014 実行委員会 Development of Efficient and Enantioselective Syntheses of Helicene and Helicene-like Molecules |
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"The 17th SANKEN International Symposium 2014 Poster
Award" Lin, X.; Takenaka, K.; Takizawa,
S.; *Sasai, H. 2014-01 The 17th SANKEN International Symposium 2014 Development of New SPRIX Ligands Having an Effective Asymmetric Environment |
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"25th International Symposium on Chirality(ISCD-25) Bio Tools Poster Award" Fan, L.; Takizawa, S.; *Sasai, H. 2013-07 上海有機化学研究所 Catalytic Enantioselective Synthesis of Chiral Spiro[4.4]nonane Derivatives and Their Applications to Asymmetric Catalysis |
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"平成25年度有機合成化学北陸セミナー優秀発表賞（ポスター賞）" Arteaga, F. A.; Takizawa, S.; Rémond, E.; Yoshida, Y.; Bayardon, J.; Sridharan, V.; *Sylvain, J.; *Sasai, H. 2013-10 有機合成化学協会関西支部 P-キラル有機分子触媒を用いる光学活性4置換炭素の合成と応用 |
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| Media |
"Phosphine-catalyzed β,γ-umpolung domino reaction of allenic esters:
Facile synthesis of tetrahydrobenzofuranones bearing a chiral
tetrasubstituted carbon stereogenic center" Takizawa, S.; Kishi, K.; Yoshida, Y. Mader, S.; Arteaga, F. A.; Lee, S.; Hoshino, M.; Rueping, M.; Fujita, M.; *Sasai, H. Synfact 2016-01-19 Angew. Chem. Int. Ed. 2015, 54, 15511.に掲載された論文が紹介された。 |
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"Enantioselective synthesis of α-alkylidene-γ-butyrolactones via
an intramolecular Rauhut-Currier reaction promoted by acid-base organocatalysts" Takizawa, S.; Nguyen, T. M.-N.; Grossmann, A.; Enders, D.; *Sasai, H. Synfact 2012-06-19 Angew. Chem. Int. Ed. 2012, 51, 5423に掲載された論文が紹介された。 |
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"Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions" Takizawa, S.; Arteaga, F. A.; Yoshida, Y.; Kodera, J.; Nagata, Y.; *Sasai, H. Dalton Trans 2013-09-07 Dalton Trans, 2013, 42, 11787.に掲載された論文がInside front coverに選定 |
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"P-Chirogenic Organocatalysts in the Enantioselective Aza-MBH Reaction" Takizawa, S.; Rémond, E.; Arteaga, F. A.; Yoshida, Y.; Sridharan, V.; Bayardon, J.; Jugé, S.; Sasai, H. Synfacts 2013-11-18 Chem. Commun. 2013, 49, 8392.に掲載された論文が紹介された。 |
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| A02 雨夜 徹 | ||
| Original papers |
"Bowl-to-bowl Inversion Accelerated by Introduction of Bulky 1,1,4,4-Tetramethylbutane-1,4-diyl Group to Sumanene" *Amaya, T.; Katoh, S.; *Hirao, T. Synlett 2016, accepted |
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"Quinonediimines as a redox-active organocatalyst
for oxidative coupling of aryl- and alkenylmagnesium compounds under molecular
oxygen" *Amaya, T.; Suzuki, R.; *Hirao, T. Chem. Commun. 2016, DOI:10.1039/c6cc03053j |
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"Self-doped polyaniline derived from poly(2-methoxyaniline-5-phosphonic acid) and didodecyldimethylammonium salt" *Amaya, T.; Sugihara, R.; Hata, D.; *Hirao, T. RSC Adv. 2016, 6 (27), pp.22447-22452. DOI:10.1039/c5ra18468a |
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"Polyaniline-induced C-H Arylation of Arenes with Arenediazonium Salts" *Amaya, T.; Hata, D.; Moriuchi, T.; *Hirao, T. Chem. Eur. J. 2015, 21 (46), pp.16427-16433. DOI:10.1002/chem.201501969 |
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"Selective Intermolecular Oxidative Cross-Coupling of Enolates" *Amaya, T.; Maegawa, Y.; Masuda, T.; Osafune, Y.; *Hirao, T. J. Am. Chem. Soc. 2015, 137 (32), pp.10072-10075. DOI:10.1021/jacs.5b05058 |
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" Convex and Concave Encapsulation of Multiple Potassium Ions by Sumanenyl Anions " Spisak, S. N.; Wei, Z.; O’Neil, N. J.; Rogachev, A. Yu.; Amaya, T.; *Hirao, T.; *Petrukhina, M. A.J. Am. Chem. Soc. 2015, 137 (31), pp.9768-9771. DOI:10.1021/jacs.5b06662 |
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"Regioselective Functionalization of Sumanene" *Amaya, T.; Ito, T.; Katoh, S.; *Hirao, T. Tetrahedron 2015, 71 (35), pp.5906-5909. DOI:10.1016/j.tet.2015.05.086 |
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"Construction of a Hemifullerene Skeleton: A Regioselective Intramolecular Oxidative Cyclization" *Amaya, T.; Ito, T.; *Hirao, T. Angew. Chem. Int. Ed. 2015, 54 (18), pp.5483-5487. DOI:dx.doi.org/10.1002/anie.201500548 |
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"Investigation of thresholds in laser-inducedcarbonization of sumanene derivatives through insitu observation utilizing a Raman spectroscope" Inada, Y.; Amaya, T.; *Hirao, T. RSC Adv. 2015, 5 (24), pp.18523-18530. DOI:10.1039/c5ra00747j |
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"Hydrogen Peroxide Generation Using Polyaniline/Transition Metal Nanohybrid Electrodes" Isaji, T.; Abe, M.; Amaya, T.; *Hirao, T. J. Inorg. Organomet. Polym. 2015, DOI:10.1007/s10904-015-0172-y |
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"Laser-induced Carbonization of Sumanene Derivatives: Exposure-time Dependence of Time-resolved Microwave Conductivity" Inada, Y.; Amaya, T.; Saeki, A.; Seki, S.; *Hirao, T. Bull. Chem. Soc. Jpn 2015, 88 (2), pp.330-332. DOI:10.1246/bcsj.20140318 |
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"Investigation of the Dynamic Behavior of Bisumanenyl" Shrestha, B. B.; Karanjit, S.; *Higashibayashi, S.; Amaya, T.; *Hirao, T.; Sakurai, T. Asian J. Org. Chem. 2015, 4 (1), pp.62-68. DOI:10.1002/ajoc.201402226 |
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"Synthesis of Polyaniline and Transition Metal Nanoparticles Hybrids" Amaya, T.; Isaji, Y.; Abe, M.; *Hirao, T. J. Inorg. Organomet. Polym. 2015, 25 (1), pp.145-152. DOI:10.1007/s10904-014-0123-z |
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"Deprotonation-Induced Efficient Delocalization of Polaron in Self-Doped Poly(anilinephosphonic acid)" *Amaya, T.; Abe, Y.; *Hirao, T. Macromolecules 2014, 47 (22), pp.8115-8118. DOI:10.1021/ma5016209 |
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"Conductivity of poly(2-methoxyaniline-5-phosphonic acid)/amine complex and its charge dissipation property in electron beam lithography" *Amaya, T.; Abe, Y.; Yamamoto, H.; *Kozawa, T.; *Hirao, T. Synth. Met. 2014, 198 pp.88-92. DOI:10.1016/j.synthmet.2014.09.027 |
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"Characterization of self-doped conducting polyanilines bearing phosphonic acid and phosphonic acid monoester" Abe, Y.; *Amaya, T.; Inada, Y.; *Hirao, T Synth. Met. 2014, 197 pp.240-245. DOI:10.1016/j.synthmet.2014.09.020 |
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"Bowl Inversion of Surface Adsorbed Sumanene" Jafaar, R.; Pignedoli, C.; Bussi, G.; Ait-Mansour, K.; Groening, O.; Amaya, T.; Hirao, T.; *Fasel, R.; *Ruffieux, P. J. Am. Chem. Soc. 2014, 136 (39), pp.13666-13671. DOI:10.1021/ja504126z |
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"Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes" Amaya, T.; Takahashi, Y.; Moriuchi, T.; *Hirao, T. J. Am. Chem. Soc. 2014, 136 (36), pp.12794-12798. DOI:10.1021/ja5072459 |
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"Preparation of Polyaniline/Pt Nanoparticles via Ligand Exchange from Starch/Pt Nanoparticles" Isaji, T.; Amaya, T.; Inada, Y.; Abe, M.; *Hirao, T. Bull. Chem. Soc. Jpn 2014, 87 (10), pp.1130-1132. DOI:10.1246/bcsj.20140106 |
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"Practical Synthesis of Poly(2-methoxyaniline-5-phosphonic acid), a Self-doped Conducting Polyaniline Bearing Phosphonic Acid" Abe, Y.; *Amaya, T.; *Hirao, T. Bull. Chem. Soc. Jpn 2014, 87 (9), pp.1026-1028. DOI:10.1246/bcsj.20140153 |
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"Synthesis of self-doped conducting polyaniline bearing phosphonic acid monoester" *Amaya, T.; Abe, Y.; Inada, Y.; *Hirao, T. Synth. Met. 2014, 195 pp.137-140. DOI:10.1016/j.synthmet.2014.05.021 |
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"Synthesis of self-doped conducting polyaniline bearing phosphonic acid" *Amaya, T.; Abe, Y.; Inada, Y.; *Hirao, T. Tetrahedron Lett. 2014, 55 (29), pp.3976-3968. DOI:10.1016/j.tetlet.2014.04.115 |
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"Sumanenemonoone
Imines Bridged by Redox-Active π-Conjugated Unit: Synthesis, Stepwise
Coordination to Palladium(II), and Laser-Induced Formation of
Nitrogen-Doped Graphitic Carbon" Amaya, T.; Inada, Y.; Shimizu, Y.; Saeki, A.; Tsuji, R.; Seki, S.; *Hirao, T. Chem. Asian J. 2014, 9 (9), pp.2568-2575. DOI:10.1002/asia.201402242 |
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"Synthesis and
Characterization of Bisumanenylidene" Amaya, T.; Ito, T.; *Hirao, T. Eur. J. Org. Chem. 2014, (17), pp.3531-3535. DOI:10.1002/ejoc.201402168 |
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"Vanadium(V)-Induced Diastereoselective Oxidative
Homocoupling of Boron Enolates" Amaya, T.; Masuda, T.; Maegawa, Y.; *Hirao, T. Chem. Commun. 2014, 50 (18), pp.2279-2281. DOI:10.1039/c3cc49624d |
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"Synthesis of Heterodinuclear Hemisalen Complexes on
a Hexaarylbenzene Scaffold and their Application for the Cross-Pinacol Coupling
Reaction" Miyasaka, A.; Amaya, T.; *Hirao, T. Chem. Eur. J. 2014, 20 (6), pp.1615-1621. DOI:dx.doi.org/10.1002/chem.201303946 |
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"Quinonediimine-Induced Oxidative Coupling of Organomagnesium
Reagents" *Amaya, T.; Suzuki, R.; *Hirao, T. Chem. Eur. J. 2014, 20 (3), pp.653-656. DOI:dx.doi.org/10.1002/chem.201301993 |
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"Nitrogen-doped Graphitic Carbon Synthesized
by Laser Annealing of Sumanenemonoone Imine as a Bowl-shaped p-Conjugated Molecule" Inada, Y.; Amaya, T.; Shimizu, Y.; Saeki, A.; Otsuka, T.; Tsuji, R.; Seki, S.; *Hirao, T. Chem. Asian J. 2013, 8 (11), pp.2569-2574. DOI:dx.doi.org/10.1002/asia.201300500 |
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"Synthesis and Characterization of Bisumanenyl" Amaya, T.; Kobayashi, K.; *Hirao, T. Asian J. Org. Chem. 2013, 2 (8), pp.642-645. DOI:dx.doi.org/10.1002/ajoc.201300091. |
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"Design and synthesis of dinuclear hemisalen complex on hexaarylbenzene scaffold" Miyasaka, A.; Amaya, T.; *Hirao, T. Tetrahedron Lett. 2012, 53 (42), pp.5589-5592. DOI:10.1016/j.tetlet.2012.07.127 |
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"Discussion Addendum for: dl-Selective Pinacol-Type Coupling Using Zinc, Chlorosilane, and Catalytic Amounts of Cp2VCl2; dl-1,2-Dicyclohexylethanediol (1,2-Ethanediol,1,2-dicyclohexyl-)" Amaya, T.; *Hirao. T. Org. Synth. 2012, 89 pp.73-75. |
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"Theoretical Investigation for the Stability of the Concave-Bound Cyclopentadienyl Iron Complex of Sumanene" *Okumura, M.; Nakanishi, Y.; Kinoshita, K.; Yamada, S.; Kitagawa, Y.; Kawakami, T.; Yamanaka, S.; Amaya, T.; Hirao, T. Int. J. Quant. Chem. 2012, 113 (4), pp.437-442. DOI:10.1002/qua.24057 |
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"Bowl-to-bowl inversion of sumanene derivatives" Amaya, T.; *Hirao, T. Pure Appl. Chem. 2012, 84 (4), pp.1089-1100. DOI:10.1351/PAC-CON-11-09-09 |
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"Aerobic dehydrogenative imination in complete aqueous media catalyzed by poly(aniline sulfonic acid)/gold nanoparticles" Amaya, T.; Ito, T.; *Hirao, T. Tetrahedron Lett. 2013, 54 (19), pp.2409-2411. DOI:10.1016/j.tetlet.2013.02.098 |
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"Selective Cross-Dehydrogenative Coupling of N-Phenyltetrahydroisoquinolines in Aqueous Media Using Poly(Aniline Sulfonic Acid)/Gold Nanoparticles" Amaya, T.; Ito, T.; *Hirao, T. Heterocycles 2012, 86 (2), pp.927-932. DOI:10.3987/COM-12-S(N)71 |
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"Gold nanoparticles catalyst with redox-active poly(aniline sulfonic acid): application in aerobic dehydrogenative oxidation of cyclic amines in aqueous solution" Amaya, T.; Ito, T.; Inada, Y.; Saio, D.; *Hirao, T. Tetrahedron Lett. 2012, 53 (45), pp.6144-6147. DOI:10.1016/j.tetlet.2012.09.002 |
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| Books |
「Advances in Organometallic Chemistry and Catalysis」 Pombeiro, A. J. L. Amaya, T.; Hirao, T. Wiley (Hoboken, USA) 2014, pp473-483. |
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| Reviews / Accounts |
"最新の”炭”で白金に挑む！－酸素還元反応触媒用含窒素カーボンの最近の動向" 稲田雄飛、雨夜 徹 化学 2015, 70 (8), pp.68-69. |
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"Chemistry of Sumanene" Amaya, T.; *Hirao, T. Chem. Rec. 2015, 15 (1), pp.310-321. DOI:10.1002/tcr.201402078 |
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| Conference / Symposium / Lecture |
招待講演 "Catalytic
Systems Consisting of Polyanilines and Metal Nanoparticles" ○*Amaya, T. The first Asian conference for “MONODUKURI” Strategy by Synthetic Organic Chemistry, Itoman, Okinawa (Japan) 2013-07-17～2013-07-19 |
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招待講演 "Quinonediimine-Induced Oxidative Coupling of
Organomagnesium" ○Amaya, T. Japan-USA Organocatalytic Symposium in Hawaii (2012), Honolulu (USA) 2012-12-15～2012-12-18 |
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| Patent |
"自己ドーピング機能を持つポリアニリンの製造方法およびその方法により製造されたポリアニリンを含む帯電防止剤" 発明者：平尾俊一、雨夜 徹、阿部 靖 出願者：国立大学法人大阪大学、大八化学工業株式会社 特願2013-84037 2013-04-12, 2014-04, |
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| Prize |
"平成２７年度有機合成化学奨励賞" 雨夜 徹 2016-02 公益社団法人有機合成化学協会 有機合成化学の発展への寄与 |
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"大阪大学総長奨励賞（研究部門）" 雨夜 徹 2015-07 大阪大学 大阪大学の研究活動への貢献 |
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"有機電子移動化学奨励賞" 雨夜 徹 2015-06 有機電子移動化学研究会 有機電子移動化学の発展への寄与 |
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" 大阪大学総長奨励賞（研究部門） " 雨夜 徹 2013-08 大阪大学大阪大学の研究活動への貢献 |
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| Media |
"Polyaniline-induced C-H Arylation of Arenes with Arenediazonium Salts" *Amaya, T.; Hata, D.; Moriuchi, T.; *Hirao, T. Chem. Eur. J. 2015-10-06 PDF Hot Paperに選出されるとともに、Inside Back Coverに採択された。 |
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"Gold Nanoparticles Catalyzed Dehydrogenative Oxidation of Amines" Amaya, T.; Ito, T.; Hirao, T. SYNFACTS 2013-06-17 Tetrahedron Lett. 2013, 54, 2409.に掲載された論文が紹介された。 |
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| A02 菅 誠治 | ||
| Original papers |
"Kinetic Resolution of Secondary Carbinols by a Chiral N,N-4-Dimethylaminopyridine Derivative Containing a 1,1́-Binaphthyl Unit: Hydrogen Bonding Affects Catalytic Activity and Enantioselectivity" Fujii, K.; Mitsudo, K.; *Mandai, H.; *Suga, S. Bull. Chem. Soc. Jpn 2016, in press DOI:dx.doi.org/doi:10.1246/bcsj.20160135 |
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"Enantioselective Acyl Transfer Catalysis by a Combination of Common Catalytic Motifs and Electrostatic Interactions" *Mandai, H.; Fujii, K.; Yasuhara, H.; Abe, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Nat. Commun. 2016, 7 pp.11297. DOI:10.1038/ncomms11297 |
Toshinobu Korenaga | |
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"Facile Synthesis of 1,4-Bis(diaryl)-1,3-butadiynes Bearing Two Amino Moieties by Electrochemical Reaction-Site Switching, and Their Solvatochromic Fluorescence" Kamimoto, N.; Nakamura, N.; Tsutsumi, A.; Mandai, H.; *Mitsudo, K.; Wakamiya, A.; Murata, Y.; Hasegawa, J.; *Suga, S. Asian J. Org. Chem. 2016, 5 (3), pp.373-379. DOI:10.1002/ajoc.201500502 |
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"Bacteriogenic iron oxide as an effective catalyst for Baeyer-Villiger oxidation with molecular oxygen and benzaldehyde" Mandai, K.; Hanata, M.; Mitsudo, K.; Mandai, H.; *Suga, S.; Hashimoto, H.; Takada, J. Tetrahedron 2015, 71 (50), pp.9403-9407. DOI:10.1016/j.tet.2015.10.057 |
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"Synthesis and Properties of Ethene-Bridged Terthiophenes" Mitsudo*, K.; Sato, H.; Yamasaki, A.; Kamimoto, N.; Goto, J.; Mandai, H.; *Suga, S. Org. Lett. 2015, 17 (19), pp.4858-4861. DOI:10.1021/acs.orglett.5b02417 |
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"Enantioselective Steglich Rearrangement of Oxindole Derivatives by Easily Accessible Chiral N,N-4-(Dimethylamino)pyridine Derivatives" *Mandai, H.; Fujiwara, T.; Noda, K.; Fujii, K.; Mitsudo, K.; Korenaga, T.; *Suga, S. Org. Lett. 2015, 17 (18), pp.4436-4439. DOI:10.1021/acs.orglett.5b02089 |
Toshinobu Korenaga | |
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"Low temperature in situ Raman spectroscopy of an electro-generated arylbis(arylthio)sulfonium ion" *Matsumoto, Ｋ.; Miyamoto, Y.; Shimada, K.; Morisawa, Y.; Zipse, H.; Suga, S.; Yoshida, J.; Kashimura, S.; *Wakabayashi, T. Chem. Commun. 2015, 51 (66), pp.13106-13109. DOI:10.1039/c5cc03585f |
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"Palladium-Catalyzed Domino C-H/N-H Functionalization: An Efficient Approach to Nitrogen-Bridged Heteroacenes" Kamimoto, N.; Schollmeyer, D.; Mitsudo, K.; Suga, S.; *Waldvogel, S. R. Chem. Eur. J. 2015, 21 (22), pp.8257-8261. DOI:10.1002/chem.201500897 |
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"
Synthetic (+)-terrein suppresses interleukin-6/soluble interleukin-6 receptor induced-secretion of vascular endothelial growth factor in human gingival fibroblasts "*Mandai, H.; Omori, K.; Yamamoto, D.; Tsumura, T.; Murota, K.; Yamamoto, S.; Mitsudo, K.; Ibaragi, S.; Sasaki, A.; Maeda, H.; Takashiba, S.; *Suga, S. Bioorg. Med. Chem. 2014, 22 (19), pp.5338-5344. DOI:10.1016/j.bmc.2014.07.047 |
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"An Efficient Petasis Boronic-Mannich Reaction of Chiral Lactol Derivatives Prepared from D-Araboascorbic Acid" *Mandai, H.; Yamada, H.; Shimowaki, K.; Mitsudo, K.; *Suga, S. Synthesis 2014, 46 (19), pp.2672-2681. DOI:10.1055/s-0034-1378900 |
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"Remarkable Enhancement of the Rate of the Intramolecular Morita-Baylis-Hillman Reaction by the Combination of a Nucleophilic Catalyst and 1,3-Diphenyl-2-thiourea" *Mandai, H.; Shimowaki, K.; Mitsudo, K.; *Suga, S. Asian J. Org. Chem. 2014, 3 (4), pp.437-441. DOI:10.1002/ajoc.201402001 |
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"Addition of N-Acyliminium Ion Pools to Alkenes Having a Nucleophilic Moiety: Integration of Intermolecular and Intramolecular Reactions" Ashikari, Y.; Kiuchi, Y.; Takeuchi, T.; Ueoka, K.; Suga, S.; *Yoshida, J. Chem. Lett. 2014, 43 (2), pp.210-212. DOI:10.1246/cl.130947 |
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"Recyclable Palladium Catalyst in PEG/CH3CN Biphasic System for Electro-oxidative Wacker-type Reaction." *Mitsudo, K.; Fukunaga, S.; Fujita, T.; Mandai, H.; Suga, S.; *Tanaka, H. Electrochemistry 2013, 81 (5), pp.347-349. DOI:10.5796/electrochemistry.81.347 |
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"Electro-reductive Halogen–Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile." *Mitsudo, K.; Okada, T.; Shimohara, S.; Mandai, H.; *Suga, S. Electrochemistry 2013, 81 (5), pp.362-364. DOI:10.5796/electrochemistry.81.362 |
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"Electrogenerated Acid (EGA) Catalyzed Addition of Diaryldisulfides toCarbon-Carbon Multiple Bonds" Matsumoto, K.; Shimazaki, H.; Sanada, T.; Shimada, K.; Hagiwara, S.; Suga, S.; Kashimura, S.; *Yoshida, J. Chem. Lett. 2013, 42 (8), pp.843-845. DOI:doi.org/10.1246/cl.130255 |
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"Kinetic Resolution of Secondary Alcohols by Chiral DMAP Derivatives Prepared by the Ugi Multicomponent Reaction " *Mandai, H.; Irie, S.; Akehi, M.; Yuri, K.; Yoden, M.; Mitsudo, K.; *Suga, S. Heterocycles 2013, 87 (2), pp.329-340. |
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"Synthesis of Hexa(furan-2-yl)benzenes and Their π-Extended Derivatives " *Mitsudo, K.; Harada, J.; Tanaka, Y.; Mandai, H.; Nishioka, Tanaka, H.; Wakamiya, A.; Murata, Y.; *Suga, S. J. Org. Chem. 2013, 78 (6), pp.2763-2768. |
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"Addition of ArSSAr to Alkenes. Implication of a Cationic Chain Mechanism Initiated by Electrogenerated ArS(ArSSAr)+ " *Matsumoto, K.; Sanada, T.; Shimazaki, H.; Shimada, K.; Hagiwara, S.; Fujie, S.; Ashikari, Y.; *Suga, S.; Kashimura, S.; *Yoshida, J. Asian J. Org. Chem. 2013, 2 (4), pp.325-329. |
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"Site-Selective Sequential Coupling Reactions Controlled by “Electrochemical Reaction Site Switching”: a Straightforward Approach to 1,4-Bis(diaryl)buta-1,3-diynes. " *Mitsudo, K.; Kamimoto, N.; Murakami, H.; Mandai, H.; Wakamiya, A.; Murata, Y.; *Suga, S. Org. Biomol. Chem. 2012, 10 (48), pp.9562-9569. |
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"Electro-reductive cyclization of aryl halides promoted by fluorene derivatives" *Mitsudo, K.; Nakagawa, Y.; Mizukawa, J.; Tanaka, H.; Akaba, R.; Okada, T.; *Suga, S. Electrochim. Acta. 2012, 82 pp.444-449. |
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"Studies on the Petasis Reaction of 2-Pyridinecarbaldehyde Derivatives and its Products" Mandai, H.; Murota, K.; *Suga, S. Heterocycles 2012, 85 (7), pp.1655-1669. |
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"Kinetic Resolution of Secondary Alcohols by the Combination of a Chiral Bronsted Acid, DABCO, and Acetyl Chloride" *Mandai, H.; Murota, K.; Mitsudo, K.; *Suga, S. Org. Lett. 2012, 14 (13), pp.3486-3489. |
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"Synthesis of Nitrogen-Bridged Terthiophenes by Tandem Buchwald-Hartwig Coupling and Their Properties" *Mitsudo, K.; Shimohara, S.; Mizoguchi, J.; Mandai, H.; *Suga, S. Org. Lett. 2012, 14 (11), pp.2702-2705. |
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"Electrophilic substitution reactions using an electrogenerated ArSS(ArSSAr)+ cation pool as an ArS+ equivalent" Matsumoto, K.; Koizumi, Y.; Ashikari, Y.; Suga, S.; Kashimura, S.; *Yoshida, J. Tetrahedron Lett. 2012, 53 (15), pp.1916-1919. |
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| Books |
「Organic Electrochemistry, 5th Ed.」 Hammerich, O; Speiser, B. "Organoelemental Compounds" Yoshida, J.; Nokami, T.; Suga, S. CRC Press (New York) 2016, pp1357-1392. ISBN:978-1-4200-8401-6 |
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| Reviews / Accounts |
"電気化学的な酸化プロセスを含むカップリング反応の開発と拡張π電子系化合物合成への応用 " *Mitsudo, K.; Tanaka, H.; Suga, S. J. Synth. Org. Chem. Jpn 2015, 73 (2), pp.173-180. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Stereoselective Synthesis of Piperidine Derivatives Using the Indirect Cation Pool Method" 〇Yamamoto, J.; Akagi, T.; Haisa, M.; Mitsudo, K.; *Suga, S. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Catalytic activity of electrochemically generated organo-dications" 〇*Suga, S.; Fujiwara, I.; Kurihara, Y.; Onishi, Y.; Mitsudo, K. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Iridium-catalyzed dehydrogenative cyclization leading to dithienosilole derivatives and their electrochemical properties" 〇Isobuchi, R.; *Mitsudo, K.; *Suga, S. Pcifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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"Enantioselective Steglich rearrangement of oxindole derivatives and kinetic resolution of secondary alcohols by chiral nucleophilic catalyst containing a 1,1'-binaphthyl unit" 〇Fujii, K.; *Mandai, H.; Korenaga, T.; *Suga, S. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Enantioselective desymmetrization of meso 1,2-diols by chiral nucleophilic catalyst containing a 1,1'-binaphthyl unit" 〇*Mandai, H.; Yasuhara, H.; Fujii, K.; *Suga, S. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Various applications of bacteriogenic iron oxide in a tube reactor and other systems for organic synthesis" 〇Mandai, K; Fukuda, T.; Miyazaki, Y.; Hanata, N.; Mandai, H.; Hashimoto, H.; Ema, T.; Takada, J.; *Suga, S. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis of Ethene-Bridged Terthiophenes by Double Sonogashira Coupling of Dibromoterthiophene and Sequential Double Cyclization" 〇*Mitsudo, K.; Kamimoto, N.; Sato, H.; Yamazaki, A.; Goto, J.; *Suga, S. The13th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Palladium-Catalyzed Domino C–H/N–H Functionalization For the Synthesis of Novel Nitrogen-Bridged Thienoacenes" 〇Kamimoto, N.; Schllmeyer, D.; Mitsudo, K.; Suga, S.; *Waldvogel, S. The13th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2015-11-09～2015-11-13 |
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招待講演 "Electrochemically Generated Carbocations for Stereoselective Synthesis and Catalytic Reactions
" *Suga, S. 7th Spanish-Portuguese-Japanese Organic Chemistry Symposium, Seville (Spain) 2015-06-23～2015-06-26 |
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招待講演 "Electrochemically Generated Carbocations for Stereoselective Synthesis and Catalytic Reactions" *Suga, S. Gesellschaft Deutscher Chemiker , Mainz (Germany) 2014-07-04～2014-07-04 |
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口頭発表／ポスター発表 "Development of Redox-Switchable Organocatalysts" *Suga, S.; Takasuka, Y.;Onishi, Y.; Okamura, Y.; Fujiwara, I.; Kurihara, Y.; Kawakami, M.; Mitsudo, K. ECS 225th Annual Meeting, Orlando (USA) 2014-05-11～2014-05-15 |
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口頭発表／ポスター発表 "Synthesis and Properties of New Classes of Dithienopyrrole Derivatives" *Suga, S.; Mizoguchi, J.; Shimohara, S.; Mitsudo, K. The 4th German-Japanese Symposium on Electrosynthesis, Kyoto (Japan) 2013-12-02～2013-12-03 |
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口頭発表／ポスター発表 "Synthesis of π-Extended Dehydrobenzoannulenes Bearing Thiophenes and Their Physical Properties" Kamimoto, N.; Mitsudo, K.; *Suga, S. The Ninth International Symposium on Integrated Synthesis, Awaji-Shima (Japan) 2014-11-14～2014-11-15 |
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口頭発表／ポスター発表 "Integrated Synthesis of Bis(diaryl)butadiynes Bearing Two Amino Moieties by Sequential Coupling Reactions and Their Solvatochromic Fluorescence" *Mitsudo, K.; Kamimoto, N.; Nakamura, N.; Tsutsumi, A.; *Suga, S. The Ninth International Symposium on Integrated Synthesis, Awaji-Shima (Japan) 2014-11-14～2015-11-15 |
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口頭発表／ポスター発表 "Site-Selective Sequential Coupling Reactions Controlled by “Electrochemical Reaction Site Switching”: a Straightforward Approach to 1,4-Bis(diaryl)-1,3-butadiynes" Kamimoto, N.; Nakamura, N.; Mitsudo, K.; *Suga, S. The Eighth International Symposium on Integrated Synthesis (ISIS-8), Nara (Japan) 2013-11-29～2013-12-01 |
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口頭発表\ポスター発表 "Kinetic Resolution of Secondary Alcohols Using New Axially Chiral Diamine Catalysts" Akehi, M.; *Mandai, H.; *Suga, S. 1st International Symposium on Advanced Molecular Transformation by Organocatalysts, Ohtsu (Japan) 2013-06-27～2013-06-28 |
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招待講演 "Electroorganic Synthesis Using a Small Amount of Electricity" *Suga, S. Post-ISOR-11 Symposium, Taipei (Taiwan) 2013-11-23～2013-11-23 |
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招待講演 "Synthesis and Properties of Alkylene-linked Bis(dithienopyrrole)s and Bis(dibenzothienopyrrole)s" *Suga, S. Taipei (Taiwan) 2013-11-19～2013-11-22 |
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口頭発表／ポスター発表 "Synthesis of Nitrogen-Bridged Terthiophenes by Tandem Buchwald–Hartwig Coupling and Their Properties" *Mitsudo, K.; Shimohara, S.; ○*Suga, S. The 11th International Symposium on Functional Pi-electron systems, Arcachon (France) 2013-06-02～2013-06-07 |
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口頭発表／ポスター発表 "Site-Selective Sequential Coupling Reactions Controlled by ʺElectrochemical Reaction Site Switching (e-RSS)ʺ: a Straightforward Approach to 1,4-Bis(diaryl)-1,3-butadiynes" ○Kamimoto, N.; *Mitsudo, K.; *Suga, S. The 11th International Symposium on Functional Pi-electron systems., Arcachon (France) 2013-06-02～2013-06-07 |
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口頭発表／ポスター発表 "Reactions Using Electrochemically Generated Organo-dications" ○Onishi, Y.; Kawakami, M.; Takasuka, Y.; Okamura, Y.; Mitsudo, K.; *Suga, S. The Twelfth International Kyoto Conference on New Aspect of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Site-Selective Sequential Coupling Reactions Controlled by“Electrochemical Reaction Site Switching (e-RSS)”: a Straightforward Approach to 1,4-Bis(diaryl)butadiynes " ○Kamimoto, N.; *Mitsudo, K.; *Suga, S. The Twelfth International Kyoto Conference on New Aspect of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Synthesis and Properties of Nitrogen-Bridged Terthiophenes " *Mitsudo, K.; Shimohara, S.; ○*Suga, S. PRiME(Pacific Rim Meeting on Electrochemical and Solid-State Science) 2012, Honolulu (USA) 2012-10-07～2012-10-12 |
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招待講演 "Reactions Using Electrochemically Generated Organo-dications" ○*Suga, S. German-Japanese Meeting on Electrosynthesis, Mainz (Germany) 2013-08-17～2013-08-18 |
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招待講演 "Organic Reactions Mediated by Electrochemically Generated Species" ○*Suga, S. French-Japanese Kinki-Divio Symposium, Dijon (France) 2012-07-24～2012-07-24 |
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口頭発表／ポスター発表 "Reactions Using Electrochemically Generated Organo-dications" ○*Suga, S.; Takasuka, Y.; Kawakami, M.; Onishi, Y.; Okamura, Y.; Mitsudo, K. 6th Spanish-Portuguese-Japanese Organic Chemistry Symposium, Lisbon (Portugal) 2012-07-18～2012-07-19 |
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| Patent |
"軸不斉を有するピリジン誘導体又はその塩、及びそれからなる不斉触媒" 発明者：萬代大樹, 菅 誠治 出願者：国立大学法人 岡山大学 森田 潔 2015-07, 特願2014-169974 2014-08-23, (国内) |
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| Prize |
"6th Spanish-Portugese-Japanese Organic Chemistry Symposium Poster Award" ○*Suga, S.; Takasuka, Y.; Kawakami, M.; Onishi, Y.; Okamura, Y.; Mitsudo, K. Reactions Using Electrochemically Generated Organo-dications 2012-07 Symposium CommitteeReactions Using Electrochemically Generated Organo-dications |
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"長瀬研究振興賞" 菅 誠治 2012-04 長瀬科学技術振興財団 レドックス応答型有機分子触媒反応系の開発 |
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| Media |
"高活性有機分子触媒開発 触媒使用量が数十分の一に" 萬代大樹、藤居一輝、菅 誠治 科学新聞 2016-05-13 PDF エナンチオ選択的なアシル化反応を促進する極めて活性の高い有機分子触媒の開発に成功した |
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"独自の有機分子触媒開発" 萬代大樹、藤居一輝、菅 誠治 山陽新聞 2016-05-07 PDF 有機化合物の化学反応を効率的に短時間で行う独自の有機分子触媒を開発した。従来の触媒に比べ使用量を最大60分の1に抑えられ、医薬品、農薬といった化学薬品の応用研究への進展が期待される。 |
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| A02 徳永 信 | ||
| Original papers |
"Catalytic Asymmetric Hydrolysis: Asymmetric Hydrolytic Protonation of Enolesters Catalyzed by Phase Transfer Catalysts" Yamamoto, E.; Nagai, A. Hamasaki, A.; Tokunaga, M. Chem. Eur. J. 2011, 17 pp.7178-7182. DOI: 10.1002 |
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"
Hydrolytic Enantioselective Protonation of Cyclic Dienyl Esters and a -diketone with Chiral Phase-transfer Catalysts" Yamamoto, E.; Gokuden, D.; Nagai, A.; Kamachi, T.; Yoshizawa, K.; Hamasaki, A.; Ishida, T.; Tokunaga, M. Org. Lett. 2012, 14 pp.6178-6181. DOI:10.1021/ol3027363 |
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| Books |
「現代化学 2015年 10月号」 "日本酒の香りをナノテクロジーで制御 －担持貴金属ナノ粒子による老香の選択的除去－" 徳永 信、村山美乃、磯谷敦子 東京化学同人 2016, pp23-26. |
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「触媒技術の動向と展望 2016年版」 触媒学会 "担持パラジウムおよび金触媒によるC—H官能基化反応" 石田玉青、徳永 信 触媒学会 2016, pp37-45. |
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「基幹教育シリーズ 化学 有機物質化学」 "３章、６章" 徳永 信・石田玉青・伊藤芳雄・内田竜也・大石 徹・川東利男・末永正彦 共著 学術図書出版 2013年9月20日 2014, ISBN:978-4-7806-0357-6 |
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「化学便覧 応用化学編 第7版」 日本化学 " II基盤的化学技術 6.触媒・吸着技術 「6-2-2錯触調製」、「6-3-2重合・斉」、「6-6-3有機金属、配位子、有機触」" 丸善出版 2014, ISBN:978-4-621-08759-6 |
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「In: Carreira E.M. and Yamamoto H. (eds.)
Comprehensive Chirality, Volume 5 」 "Addition Reaction/Kinetic Resolution" Tokunaga, M.; Hamasaki, A. Elsevier (Amsterdam) 2012, pp421-435. |
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| Reviews / Accounts |
"キラル四級アンモニウム塩を触媒とする不斉塩基加水分解反応の開発" 山本 英治，徳永 信 月刊「ファインケミカル」 2014, 43 (6), pp.24-30. |
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"不斉四級アンモニウム塩を触媒に用いるエステル類の不斉加水分解反応" 山本 英治，永井 あやの，中村 亮太，武久 克磨，蒲池 高志，吉澤 一成，濱崎 昭行，石田 玉青，徳永 信 九州大学中央分析センター報告 2014, 31 pp.13-21. |
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"
研究室紹介 ‐北から南から‐
" 徳永信、石田玉青、濱崎昭行
Organometallic News 2012, pp.64-65. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthesis of novel chiral quaternary
phosphonium salts with hydrogen-bond donor and their application to asymmetric
reactions" Yuki Hidani, Akiyuki Hamasaki, Tamao Ishida, Makoto
Tokunaga PACIFICHEM2015, Honolulu (USA) 2015-12-19～2015-12-19 |
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口頭発表／ポスター発表 "Asymmetric hydrolysis of 2-arylpropanic acid esters
catalyzed by chiral phase-transfer catalyst" Akiko Murakami, Katsuma Takehisa, Akiyuki Hamasaki,
Tamao Ishida, Takashi Kamachi, Kazunari Yoshizawa, Makoto Tokunaga PACIFICHEM2015, Honolulu (USA) 2016-12-19～2016-12-19 |
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口頭発表／ポスター発表 "Synthesis of novel quaternary ammonium salts derived
from quinine and their application to asymmetric hydrolysis of amino acid
esters" Yuho Furutachi, Yuki Hidani, Tamao ISHIDA, Akiyuki
Hamasaki, Makoto Tokunaga PACIFICHEM2015, Honolulu (USA) 2015-12-19～2015-12-19 |
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"Asymmetric hydrolysis of
a-chiralesters using
chiral quanternary ammonium catalysts" ○K, Takehisa, R. Nakamura, E. Yamamoto, A. Hamasaki, T.
Ishida, T. Kamachi, K. Yoshizawa, M. Tokunaga ICOMC 2014 Pre-symposium in Kyoto“Synthetic Approaches to New Chemical Functions”, Kyoto (Japan) 2014-07-11～2014-07-12 |
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"Asymmetric base hydrolysis with chiral
phase-transfer catalysts" ○Katsuma Takehisa, Ryota Nakamura, Eiji Yamamoto, Akiyuki Hamasaki, Tamao Ishida, Makoto Tokunaga* The 21st Joint Seminar of KB-CSJ and BB-KCS, Busan (Korea) 2013-06-12～2013-06-13 |
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口頭発表／ポスター発表 "Asymmetric Hydrolytic Protonation of Alkenyl Esters and Hydrolysis of Axially Chiral Compounds with Chiral Phase-Transfer Catalysts" Nagai A, Yamamoto E, Hamasaki A, Ishida T, Kamachi T, Yoshizawa K, Tokunaga M. First Japan – USA Organocatalytic Symposium, Hawaii (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "Dynamic Kinetic Resolution of N-protected amino acid esters by base hydrolysis with Chiral Phase-Transfer Catalysts
" Nakamura R, Yamamoto E, Hamasaki A, Ishida T, Tokunaga M. First Japan – USA Organocatalytic Symposium, Hawaii (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "Phase-Transfer Catalytic Base-Hydrolysis of Esters" E. Yamamoto, R. Nakamura, A. Nagai, T. Kamachi, K. Yoshizawa, A. Hamasaki, T. Ishida, M. Tokunaga Symposium on Molecular Chirality ASIA 2012 (MS ASIA 2012), 福岡 (日本) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 "ydrolytic Enantioselective Protonation Catalyzed by Chiral Quaternary Ammonium Salts" E. Yamamoto, D. Gokuden, A. Nagai, R. Nakamura, A. Hamasaki, T. Ishida, M. Tokunaga The 4 th Pusan National Univ. Global COE Kyushu Univ. Joint Symposium on Molecular Science and Technology, 釜山 (韓国) 2011-12-20～2011-12-21 |
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口頭発表／ポスター発表 "Asymmetric Hydrolysis of Esters Catalyzed by Phase Transfer Catalysts" E. Yamamoto, A. Nagai, R. Nakamura, A. Hamasaki, T. Ishida, M. Tokunaga International Symposium on Catalysis and Fine Chemicals, 奈良 (日本) 2011-12-04～2011-12-08 |
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口頭発表／ポスター発表 "Asymmetric Hydrolytic Protonation of Dienyl Esters and Diketones for the Catalytic Enantioselective Synthesis of -Tertiary Chiral Cyclic Enones" Eiji Yamamoto, Daichi Gokuden, Ayano Nagai, Akiyuki Hamasaki, Tamao Ishida, Makoto Tokunaga The 2011 Global COE International Symposium on Future Molecular Systems, 福岡 (日本) 2011-11-25～2011-11-25 |
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招待講演 "Asymmetric Base Hydrolysis of Esters Catalyzed by Chiral Phase-transfer Catalysts Derived from Cinchona Alkaloids" Makoto Tokunaga First Japan – USA Organocatalytic Symposium,, Hawaii (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "Asymmetric Hydrolysis of Esters with Chiral Phase-transfer Catalysts" Eiji Yamamoto, Ayano Nagai, Ryota Nakamura, Katsuma Takehisa, Akiyuki Hamasaki, Tamao Ishida, Takashi Kamachi, Kazunari Yoshizawa, and Makoto Tokunaga The 2 nd International Conference on MEXT Project of Integrated Research on Chemical Synthesis, “Molecular Functions in Complex Systems, 名古屋 (日本) 2012-12-10～2012-12-11 |
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招待講演 "Asymmetric Base Hydrolysis of Esters Catalyzed by Chiral Quaternary Ammonium Salts (Keynote)" E. Yamamoto, D. Gokuden, A. Nagai, R. Nakamura, K. Takehisa, A. Hamasaki, T. Ishida, T. Kamachi, K. Yoshizawa, M. Tokunaga 17 th Malaysian Chemical Congress 2012 (17MCC), Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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招待講演 "Alcoholysis and Hydrolysis of Alkenyl Esters and Ethers with Homogeneous Catalysis" E. Yamamoto, H. Ito, A. Hamasaki, T. Ishida and M. Tokunaga The 6th International Conference on Cutting-Edge Organic Chemistry in Asia ( ICCEOCA-6) and The 2nd New Phase International Conference on Cutting-Edge Organic Chemistry in Asia, 香港 (中国) 2011-12-11～2011-12-15 |
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| Patent |
"
エステルの不斉加水分解方法 " 発明者：徳永 信、濱崎昭行、山本英治、佐久間毅、大村直也、永井あやの、中村亮太、九州大学特願2011-006529 2011-06-16, 特開2012-148983 2012-08-09, (国内) |
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| Prize |
"優秀発表賞(第５２回化学関連支部合同九州大会)" 古舘 裕歩 2015-06 有機合成化学協会、九州山口支部 |
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"優秀発表賞シンコナアルカロイド由来相間移動触媒を用いたアミノ酸エステル類の不斉加水分解反応 |
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"ポスター賞" 山本英治 2012-05 MCRO Phase-Transfer Catalytic Base-Hydrolysis of Esters |
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"九州大学Ｇ－ＣＯＥ「未来分子システム科学」院生プロジェクト優秀研究賞" 山本英治 2012-02 九州大学Ｇ－ＣＯＥ キラル相間移動触媒を用いたエステル類の動的速度論分割に関する研究 |
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"有機合成化学協会九州山口支部ポスター賞（万有シンポジウム）" 山本 英治・永井 あやの・濱崎 昭行・徳永 信 2011-05 有機合成化学協会九州山口支部 相間移動触媒を用いたエステル類の不斉加水分解 |
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| Media |
"日本酒、日がたつと香りが変化" 徳永 信 日本経済新聞 2015-04-12 |
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"日本酒の劣化臭だけ除去 九大成功、海外輸出加速に期待" 徳永 信 西日本新聞 2015-03-30 |
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| A02 田中 正一 | ||
| Original papers |
"Handedness preferences of heterochiral helical peptides containing homochiral peptide segments" *Y. Demizu, H. Yamashita, T. Misawa, M. Doi, M. Oba, M. Tanaka, M. Kurihara Eur. J. Org. Chem. 2016, pp.840-846. DOI:10.1002/ejoc.201501146 |
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"A Helix-Stabilized Cell-Penetrating Peptide as An Intracellular-Delivery Tool" H. Yamashita, M. Oba, T. Misawa, M. Tanaka, T. Hattori, M. Naito, *M. Kurihara, and *Y. Demizu ChemBioChem. 2016, 17 pp.137-140. DOI:10.1002/cbic.201500468 |
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"A Cell-Penetrating Peptide with a Guanidinylethyl Amine Structure Directed to Gene Delivery" *M. Oba, T. Kato, K. Furukawa, and M. Tanaka Sci. Rep. 2016, DOI:10.1038/srep19913 |
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"alpha-Helical structures of oligopeptides with alternating L-Leu-Aib segment" *Y. Demizu, K. Okitsu, H. Yamashita, M. Doi, T. Misawa, M. Oba, M. Tanaka, *M. Kurihara Eur. J. Org. Chem. 2016, pp.in press. DOI:10.1002/ejoc.201600327 |
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"Plasmid DNA delivery by arginine-rich cell-penetrating peptides containing unnatural amino acids" T. Kato, H. Yamashita, T. Misawa, K. Nishida, M. Kurihara, M. Tanaka, *Y. Demizu, *M. Oba Bioorg. & Med. Chem. 2016, pp.in press. |
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"Cyclic alpha,alpha-Disubstituted alpha-Amino Acids with Menthone in Their Side Chains through an Acetal Moiety and Helical Structures of Their Peptides" K. Furukawa, *M. Oba, G. O. Opiyo, M. Doi, *M. Tanaka Eur. J. Org. Chem. 2016, pp.in press. |
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"Conformational studies on peptides having dipropylglycine (Dpg) or 1-aminocycloheptanecarboxylic acid (Ac7c) within the sequence of L-leucine (Leu) residues"
*M. Oba, H. Nonaka, M. Doi, *M. Tanaka Biopolymers (Pept.Sci.) 2016, 106 pp.210-218. DOI:10.1002/bip.22810 |
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"Helical structures of L-Leu-based peptides having chiral six-membered ring amino acids" Umeno, T.; Ueda, A.; Oba, M.; Doi, M.; Hirata, T.; Suemune, H.; *Tanaka, M. Tetrahedron 2016, pp.in press. DOI:10.1016/j.tet.2016.04.040 |
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"Synthesis of chiral five-membered carbocyclic ring amino acids with an acetal moiety and helical conformations of its homo-chiral homopeptide" Koba, Y.; Hirata, Y.; Ueda, A.; Oba, M.; Doi, M.; Demizu, Y.; Kurihara, M.; *Tanaka, M. Biopolymers (Pept. Sci.) 2016, pp.in press. DOI:10.1002/bip.22769 |
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"Peptide foldamers composed of six-membered ring alpha,alpha-disubstituted alpha-amino acids with two changeable chiral acetal moieties " Tanda, K.; Eto, R.; Kato, K.; Oba, M.; Ueda, A.; Suemune, H.; Doi, M.; Demizu, Y.; Kurihara, M.; *Tanaka, M. Tetrahedron 2015, 71 pp.3909-3914. DOI:10.1016/j.tet.2015.04.031 |
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"Amino equatorial effect of a six-membered ring
amino acid on its peptide 310- and alpha-helices" Hirata, T.; Ueda, A.; Oba, M.; Doi, M.; Demizu, Y.;
Kurihara, M.; Nagano, M.; Suemune, H.; *Tanaka, M. Tetrahedron 2015, 71 pp.2409-2420. |
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"Conformational studies on
peptides having chiral five-membered ring amino acid with two azido or triazole functional groups
within the sequence of Aib residues" Oba, M.; Kawabe, N.; Takasaki,
H.; Demizu, Y.; Doi, M.; Kurihara, M.; Suemune, H.; *Tanaka, M. Tetrahedron 2014, 70 pp.8900-8907. |
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"Helical
peptide-foldamers having a chiral five-membered ring amino acid with two azido
functional groups" Oba, M.; Takazaki, H.; Kawabe, N.; Doi, M.; Demizu, Y.; Kurihara, M.; Kawakubo, H.; Nagano, M.; Suemune, H.; *Tanaka, M. J. Org. Chem. 2014, 79 (19), pp.9125-9140. DOI:10.1021/jo501493x |
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"Oligopeptides with Equal
Amounts of L- and D‑Amino Acids May Prefer a
Helix Screw Sense" Demizu, Y.; Yamashita, H.; Yamazaki, N.; Sato, Y.; Doi, M.; Tanaka, M.; Kurihara M. J. Org. Chem. 2013, 78 (23), pp.12106-12113. DOI:DOI: 10.1021/jo402133e |
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"
Helical Oligomers with a Changeable Chiral Acetal
Moiety"
Oba, M.; Ishikawa, N.; Demizu, Y.; Kurihara, M.; Suemune, H.; *Tanaka M. Eur. J. Org. Chem. 2013, pp.7679-7682. DOI:10.1002/ejoc.201301450 |
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" One-Handed Helical-Screw Direction of Homopeptide-Foldamer Exclusively Induced by Cyclic a-Amino Acid Side-Chain Chiral Centers " Demizu, Y; Doi, M; Kurihara, M; Maruyama, T; Suemune, H; *Tanaka, MChem. Eur. J. 2012, 18 (8), pp.2430-2439. DOI:10.1002/chem.201102902 |
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"Intracellular internalization mechanism of protein transfection reagents" *Oba, M; Tanaka M Biol. Pharm. Bull. 2012, 35 (7), pp.1064-1068. |
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"Conformations of helical Aib peptides containing a pair of L-amino acid and D-amino acid" *Demizu, Y; Yabuki, Y; Doi, M; Sato, Y; Tanaka, M; *Kurihara, M J. Pept. Sci. 2012, 18 (7), pp.466-475. DOI:10.1002/psc.2418 |
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" Twisted structure of a cyclic hexapeptide containing a combination of alternating L-Leu-D-Leu-Aib sgments " Demizu, Y; Nagoya, S; Doi, M; Sato, Y; Tanaka, M; Kurihara, MJ. Org. Chem. 2012, 77 (20), pp.9361-9365 . DOI:10.1021/jo301509c |
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"Synthesis of both enantiomers of cyclic methionine analogue: (R)- and (S)-3-aminotetrahydrothiophene-3-carboxylic acids" Oba, M; Shimabukuro, A; Ono, M; Doi, M; *Tanaka, M Tetrahedron: Asymmetry 2013, 24 (8), pp.464-467. DOI:10.1016/j.tetasy.2013.03.010 |
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"Helical Structures of Bicyclic α-Amino Acid Homo-chiral Oligomers with the Chiral Centers at the Side-chain Fused-ring Junctions" Anan, K.; Demizu, Y.; Oba, M.; Kurihara, M.; Doi, M.; Suemune, H.; *Tanaka, M. Helv. Chim. Acta 2012, 95 (10), pp.1694-1713 . |
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| Books |
「遺伝子医学MOOK21 「最新ペプチド合成技術とその創薬研究への応用」 」 木曽良明 "α，α-ジ置換アミノ酸の設計・合成とそのペプチドの二次構造解析・機能化" 大庭 誠, 田中正一 株式会社 メディカル ドゥ (大阪) 2012, pp205-210. |
|
| Conference / Symposium / Lecture |
招待講演 " Design of Helical Peptides as Chiral Organocatalysts " *Tanaka, M.Japan-USA Organocatalytic Symposium in Hawaii , Honolulu (USA) 2012-12-16～2012-12-18 |
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| A02 中島 誠 | ||
| Original papers |
"Stereoselective Synthesis of Highly Functionalized 2,3-Dihydro-4-pyranones Using Phosphine Oxide as Catalyst" *Kotani, S.; Miyazaki, S.; Kai, K.; Kawahara, K.; Shimoda, Y.; Sugiura, M.; Nakajima, M. Chem. Pharm. Bull. 2016, 64 pp.189-192. DOI:10.1248/cpb.c15-00806 |
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"Asymmetric Direct 1,2-Addition of Aryl Grignard Reagents to Aryl Alkyl Ketones" Osakama, K.; *Nakajima, M. Org. Lett. 2016, 18 pp.236-239. DOI:10.1021/acs.orglett.5b0337 |
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"Concise Asymmetric Construction of C2-Symmetric 1,9-Diarylnonanoids Using Hypervalent Silicon Complex: Total Synthesis of (-)-Ericanone" *Kotani, S.; Kai, K.; Shimoda, Y.; Hu, H.; Gao, S.; Sugiura, M.; Ogasawara, M.; Sugiura, M.; *Nakajima, M. Chem. Asian J. 2016, 11 pp.376-379. DOI:10.1002/asia.201501080 |
小笠原正道 | |
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"Tertiary Amine as a Nucleophile Carrier: α-Aminonitrile in the Cyanation of Acetals and Orthoesters" *Kotani, S.; Sakamoto, M.; Osakama, K.; Nakajima, M. Eur. J. Org. Chem. 2015, 30 pp.6606-6609. DOI:10.1002/ejoc.201501084 |
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"Nitration of Indoxyl Sulfate Facilitates Its Cytotoxicity in Human Renal Proximal Tubular Cells via Expression of Heme Oxygenase-1" Ishima, Y.; Narisoko, T.; Kragh-Hansen, U.; Kotani, S.; Nakajima, M.; Otagiri, M.; *Maruyama, T. Biochem. Biophys. Res. Commun. 2015, 465 pp.481-487. DOI:10.1016/j.bbrc.2015.08.043 |
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"One-pot Synthesis of β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds using Sequential Ti-Aldol Addition to Ketones and Elimination." *Sugiura, M.; Ashigari, Y.; Nakajima, M. J. Org. Chem. 2015, 80 pp.8830-8835. DOI:10.1021/acs.joc.5b01217 |
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"Chiral Lithium
Binaphtholate for Enantioselective Michael Addition of Acyclic a-Alkyl-b-keto
Esters to Vinyl Ketones" *Kotani, S.; Moritani,
M.; *Nakajima, M. Asian J. Org. Chem. 2015, 4 pp.616-618. DOI:10.1002/ajoc.201500122 |
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"Conjugate Addition of
Diboron Catalyzed by O-Monoacyltartaric Acid
" *Sugiura, M.; Ishikawa, W.; Nakajima, M.
Synthesis 2015, 47 pp.2265-2269. DOI:10.1055/s-0034-1378 |
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|
"Lithium
Binaphtholate-catalyzed Asymmetric Addition of Lithium Acetylides to Carbonyl
Compounds" Kotani, S.; Kukita, K.;
Tanaka, K.; Ichibakase, T.; *Nakajima, M. J. Org. Chem. 2014, 79 (11), pp.4809-4816. DOI:10.1021/jo5005394 |
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|
"O-Monoacyltartaric
Acid-Catalyzed Enantioselective Conjugate Addition of a Boronic Acid to
Dienones: Application to the Synthesis of Optically Active Cyclopentenones" *Sugiura, M.; Kinoshita,
R.; Nakajima, M
Org. Lett. 2014, 16 (19), pp.5172-5175. DOI:10.1021/ol502526y |
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|
"Phosphine
Oxide-Catalyzed Enantioselective Intramolecular Aldol Reaction via
Regioselective Enolization of Unsymmetrical Diketones with Tetrachlorosilan" *Kotani, S.; Aoki, S.; Sugiura, M.; Ogasawara,
M.; *Nakajima, M. Org. Lett. 2014, 16 (18), pp.4802-4805. DOI:10.1021/ol502269w |
小笠原正道 | |
|
"Imino Ene-type Reaction of Enamines with N-Sulfonylimines and Application to Diastereoselective Synthesis of 1,3-Diamines" Itoh, M.; Kotani, S.; Nakajima, M.; *Sugiura, M. Tetrahedron Lett. 2014, 55 (30), pp.4082-4085. DOI:10.1016/j.tetlet.2014.05.123 |
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"Diastereoselective Synthesis of 1,3-Diamines by a Domino Reaction of Imines, Enamines, and Trichlorosilane" Kashiwagi, T.; Kotani, S.; *Nakajima, M.; *Sugiura, M. Tetrahedron Lett. 2014, 55 (11,12), pp.1924-1926. DOI:10.1016/j.tetlet.2014.01.152 |
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|
"Atropisomeric Chiral Diene in Asymmetric Catalysis: C2-Symmetric (Z,Z)-2, 3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as Highly Active Lewis Base Organocatalyst." *Ogasawara, M.; Kotani, S.; Nakajima, H.; Furusho, H.; Miyasaka, M.; Shimoda, Y.; Wu, W.-Y.; Sugiura, M.; Takahashi, T.; *Nakajima, M. Angew. Chem. Int. Ed. 2013, 52 (51), pp.13798-13802. DOI:10.1002/anie.201308112 |
小笠原正道 | |
|
"Enantioselective Morita–Baylis–Hillman Reaction Catalyzed by a Chiral Phosphine Oxide." *Kotani, S.; Itoh, M.; Sugiura, M.; Ogasawara, M.; *Nakajima, M. Tetrahedron Lett. 2014, 54 (48), pp.6430-6433. DOI:10.1016/j.tetlet.2013.09.067 |
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"Construction of Quaternary Carbon Centers by Base-catalyzed Enantioselective Aldol Reaction and Related Reaction of Trimethoxysilyl Enol Ethers" Ichibakase, T.; Kaneko, T.; Orito, Y.; Kotani, S.; *Nakajima, M. Tetrahedron 2012, 68 (22), pp.4210-4224. DOI:10.1016/j.tet.2012.03.096 |
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"Trichlorosilyl Triflate Mediated-Enantioselective Directed Cross-Aldol Reaction between Ketones using Chiral Phosphine Oxide as an Organocatalyst" Aoki, S.; *Kotani, S.: Sugiura, M.; *Nakajima, M. Chem. Commun. 2012, 48 (44), pp.5524-5526. DOI:10.1039/C2CC31543B |
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|
"Synthesis of Aryl Group-modified DIOP Dioxides (Ar-DIOPOs) and Their Application as Modular Lewis Base Catalysts" Ohmaru, Y.; Sato, N.; Mizutani, M.; Kotani, S.; *Sugiura, M.; *Nakajima, M. Org. Biomol. Chem. 2012, 10 (23), pp.4562-4570. DOI:10.1039/C2OB25338K |
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"Enantioselective Reductive Aldol Reaction using Teriary Amine as Hydride Donor" Osakama, K.; Sugiura, M.; *Nakajima, M.: *Kotani, S. Tetrahedron Lett. 2012, 53 (32), pp.4199-4201. DOI:10.1016/j.tetlet.2012.05.147 |
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"Efficient Preparation of 1,3-Diol Derivatives with Three Contiguous Stereocenters by an Enantioselective Direct Aldol-Tishchenko Reaction" Ichibakase, T.; *Nakajima, M. Synthesis 2012, 44 (20), pp.3145-3151. DOI:10.1055/s-0031-1291138 |
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|
"Interaction between Two Sulfate-Conjugated Uremic Toxins, p-Cresyl Sulfate and Indoxyl Sulfate, during Binding with Human Serum Albumin" *Watanabe, H.; Noguchi, T.; Miyamoto, Y.; Kadowaki. D.; Kotani, S.; Nakajima, M.; Miyamura, S.; Ishima, Y.; Otagiri, M.; Maruyama, T. Drug Metab. Dispos. 2012, 40 (7), pp.1423-1428. DOI:10.1124/dmd.112.045617 |
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|
"Facile Synthesis of Chiral 1,2-Chlorohydrins via the Ring-opening of meso-Epoxides Catalyzed by Chiral Phosphine Oxides" *Kotani, S.; Furusho, H.; Tokuoka, E. Nakajima, M. Tetrahedron 2013, 69 (14), pp.3075-3081. DOI:10.1016/j.tet.2013.01.066 |
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|
"Stereoselective Synthesis of Multiple Stereocenters by Using a Double Aldol Reaction" Shimoda, Y.; Kubo, T.; Sugiura, M.; *Kotani, S.; *Nakajima, M. Angew. Chem. Int. Ed. 2013, 52 (12), pp.3461-3464. DOI:10.1002/anie.201209848 |
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|
"p-Cresyl sulfate causes renal tubular cell damage by inducing oxidative stress by activation of NADPH oxidase" *Watanabe, H.; *Miyamoto, Y.; Honda, D.; Tanaka, H.; Wu, Q.; Endo, M.; Noguchi, T.; Kadowaki. D.; Ishima, Y.; Kotani, S.; Nakajima, M.; Kataoka, K.; Kim-Mitsuyama, S.; Tanaka, M.; Fukagawa, M.; Otagiri, M.; Maruyama, T. Kidney International 2013, 83 (4), pp.582-592. DOI:10.1038/ki.2012.448 |
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| Books |
「Comprehensive Chirality Vol. 6」 Carreira, E. M.; Yamamoto, H. "Organocatalytic Enantioselective Halogenation of meso Epoxides" Kotani, S.; Nakajima, M. Elsevier 2012, pp506-517. ISBN:978-0-08-095167-6 |
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「Comprehensive Chirality Vol. 6」 Carreira, E. M.; Yamamoto, H. "Allylations of C–O and C–N Double Bonds and Related Reactions" Sugiura, M.; Nakajima, M. Elsevier 2012, pp214-233. ISBN:978-0-08-095167-6 |
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|
「Comprehensive Chirality Vol. 4」 Carreira, E. M.; Yamamoto, H. "Enantioselective Aldol Reactions Catalyzed by Chiral Lewis Bases" Nakajima, M. Elsevier 2012, pp198-209. ISBN:978-0-08-095167-6 |
||
| Reviews / Accounts |
"Enantioselective Double Aldol Reactions Involving the Sequential Activation of Silicon Tetrachloride by Chiral Phosphine Oxides" Kotani, S.; Sugiura, M.; *Nakajima, M. Synlett 2014, 25 pp.631-640. DOI:10.1055/s-0033-1340600 |
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"Structure constructions utilizing continuous aldol reactions: deployment to stereoselective synthesis of polyols" *Kotani, S.; Sugiura, M.; *Nakajima, M. Kagaku 2013, 68 (12), pp.64-65. |
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|
"Enantioselective Aldol Reaction Catalyzed by Chiral Phosphine Oxides" Kotani, S.; Sugiura, M.; *Nakajima, M. Chem. Rec. 2013, 13 (4), pp.362-370. DOI:10.1002/tcr.201300004 |
||
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Phosphine oxide-catalyzed enantioselective cross-aldol reactions between ketones" ○Shunsuke Kotani, Shohei Aoki, Masaharu Sugiura, Masamichi Ogasawara, Makoto Nakajima PACIFICHEM2015, Honolulu (U.S.A.) 2015-12-15～2015-12-19 |
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口頭発表／ポスター発表 "Chiral lithium binaphtholate-catalyzed enantioselective Michael additions of acyclic alfa-alkyl-beta-keto esters" ○Miyuki Moritani, Shunsuke Kotani, Makoto Nakajima PACIFICHEM2015, Honolulu (U.S.A.) 2015-12-15～2015-12-19 |
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|
口頭発表／ポスター発表 "Activation of boron compounds by chiral alfa-hydroxy carboxylic acid catalysts" ○Masaharu Sugiura， Yukinobu Kuboyama， Wakoto Ishikawa， Mirai Tokudomi， Makoto Nakajima PACIFICHEM2015, Honolulu (U.S.A.) 2015-12-15～2015-12-19 |
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|
依頼講演 "Enantioselective Double Aldol Reaction Catalyzed by Chiral Phosphine Oxides" ○Makoto Nakajima the 39th Naito Conference on the Chemistry of Organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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|
口頭発表／ポスター発表 "Lewis base-catalyzed Tandem Reaaction of Imines, Enamine and Tichlorosilane: Stereoselective Synthesis of 1,3-Diamines" ○Kashiwagi, T.; Kotani, S.; Nakajima, M.; *Sugiura, M. International Kick-Off Symposium for ISMCBC, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 "Stereoselective Construction of Pyranone Ring Using Asymmetric Double Aldol Reaction" ○Miyazaki, S.; Shimoda, Y.; Kawahara, K.; Sugiura, M.; Kotani, S.; *Nakajima M. International Kick-Off Symposium for ISMCBC, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 "Enantioselective Alkynylation of Carbonyl Compounds Using Lithium Acetylides as Alkynylating Reagents" ○Kukita, K.; Osakama, K.; Tanaka, K.; Ichibakase, T.; Kotani, S.; *Nakajima, M.
10th International Symposium on Carbanion Chemistry (ISCC-10), Kyoto (Japan) 2013-09-23～2013-09-26 |
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|
口頭発表／ポスター発表 "Enantioselective synthesis of cyclopentenones via monoacyltartaric acid-catalyzed conjugate addition of a boronic acid to dienones and ring-closing methathesis" *○Sugiura., M.; Kinoshita, R.; Nakajima, M. International Symposium on Olefin Metathesis and Related Chemistry, Nara (Japan) 2013-07-14～2013-07-19 |
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|
口頭発表／ポスター発表 "Enantioselective Directed Cross-Aldol Reaction between Ketones Catalyzed by Chiral Phosphine Oxide" ○Aoki, S.; Kotani, S.; Sugiura, M.; *Nakajima, M. The Twelfth International Kyoto Conference on New Aspect of Organic Chemistry, Kyoto (Japan) 2012-11-11～2012-11-16 |
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口頭発表／ポスター発表 "Conjugate Reduction and Asymmetric Reductive Aldol Reaction Using Tertiary Amine as a Hydride Source" ○Osakama, K.; Kotani, S.; Sugiura, M.; *Nakajima, M. The Twelfth International Kyoto Conference on New Aspect of Organic Chemistry, Kyoto (Japan) 2012-11-11～2012-11-16 |
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口頭発表／ポスター発表 "Enantioselective direct aldol-type reaction between two ketones catalyzed by chiral phosphine oxide" ○Aoki, S.; Kotani, S.; Sugiura, M.; *Nakajima, M. Molecular Chirality Asia 2012, Fukuoka (Japan) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 "Asymmetric Phosphonylation Catalyzed by DMPP-DIOPO, a DIOP Dioxide Derivative Having a Phenoxaphosphine Ring" ○Ohmaru, Y.; Kotani, S.; Sugiura, M.; *Nakajima, M. Molecular Chirality Asia 2012, Fukuoka (Japan) 2012-05-17～2012-05-18 |
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|
口頭発表／ポスター発表 "Enantioselective allylation of aldehydes catalyzed by helically chiral phosphine oxide" ○Furusho, H.; Kotani, S.; Nakajima, H.; Miyasaka, M.; Shimoda, Y.; Sugiura, M.; Nakajima, K.; Takahashi, T.; *Nakajima, M.; Ogasawara, M. Molecular Chirality Asia 2012, Fukuoka (Japan) 2012-05-17～2012-05-18 |
Ogasawara, M. | |
| A02 荒井 孝義 | ||
| Original papers |
"Catalytic Asymmetric [3+2]-Cycloaddition for Stereodivergent Synthesis of Chiral Indolyl-pyrrolidines." *Arai, T.; Tokumitsu, C.; Miyazaki, T.; Kuwano, S.; Awata A. Org. Biomol. Chem. 2016, 14 pp.1831-1839. DOI:DOI: 10.1039/ c5ob02278a |
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"Synthesis of Highly Functionalized Chiral Benzopyrano[3,4-c]pyrrolidines Bearing Five Contiguous Stereogenic Centers" Sato, T.; Miyazaki, T.; *Arai, T. J. Org. Chem. 2015, 80 pp.10346-10352. DOI:10.1021/acs.joc.5b01445 |
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"Catalytic Asymmetric Iodocyclization of N-Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8-Oxa-6-Azabicyclo[3.2.1]octanes." *Arai, T.; Watanabe, O.; Yabe, S.; Yamanaka, M. Angew. Chem. Int. Ed. 2015, 54 pp.12767-12771. DOI:10.1002/anie.201505748 |
Yamanaka, M. | |
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"Recyclable poly-Zn3(OAc)4-3,3'-bis(aminoimino)binaphthoxide catalyst for asymmetric iodolactonization." *Arai, T.; Kojima, T.; Watanabe, O.; Itoh, T.; Kanoh, H. ChemCatChem. 2015, 7 pp.3234-3238. DOI:10.1002/cctc.201500842 |
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"Chiral Bis(imidazolidine)-derived NCN Pincer Rh Complex for Catalytic Asymmetric Mannich Reaction of Malononitrile with N-Boc Imines." *Arai, T.; Moribatake T.; Masu H. Chem. Eur. J. 2015, 21 pp.10671-10675. DOI:DOI: 10.1002/chem.201502097 |
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"PyBidine–NiCl2-Catalyzed Asymmetric Addition of Alcohols and Peroxides to Isatin-Derived Ketimines." *Arai, T.; Tsuchiya, K.; Matsumura E. Org. Lett. 2015, 17 pp.2416-2419. DOI:DOI: 10.1021/acs.orglett.5b00928 |
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|
"PyBidine-Cu(OTf)2-catalyzed
asymmetric [3+2] cycloaddition using
imino esters: Harmony of
Cu-Lewis acid and imidazolidine-NH
hydrogen-bonding in concerto
catalysis" *Arai, T.; Ogawa, H.; Awata, A.; Sato, M.; Watabe,
M.; *Yamanaka, M. 2015, 54 pp.1595-1599. DOI:10.1002/anie.201410782 |
Yamanaka, M. | |
|
"Design of a Chiral Secondary
Amine Ligand for Cu-catalyzed anti-Selective
Henry Reaction" *Arai, T.; Joko, A.
Sato, K. Synlett 2015, 26 pp.209-214. DOI:10.1055/s-0034-1379607 |
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"Imidazoline-aminophenol (IAP)-nickel complex: Structure and catalytic activity in 1,4-addition of 3-indolyl-3-oxindoles to nitroethylene" Awata, A.; Wasai, M.; Masu,
H.; Kado, S.; *Arai, T. 2014, pp.2470-2477. DOI:10.1002/chem.201304456 |
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|
"PyBidine/Copper Catalyst: Asymmetric exo′-Selective [3+2]
Cycloaddition using Imino Ester and Electrophilic Indole." Awata, A.; *Arai,
T. Angew. Chem. Int. Ed. 2014, 53 pp.10462-10465. DOI:10.1002/anie.201405223 |
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|
"Bis(imidazolidine)pyridine-NiCl2 Catalyst for Nitro-Mannich
Reaction of Isatin-Derived N-Boc Ketimines: Asymmetric Synthesis of
Chiral 3-Substituted 3-Amino-2-oxindoles" *Arai,
T.; Matsumura, E.; Masu, H. Org. Lett. 2014, 16 pp.2768-2771. DOI:10.1021/ol501085y |
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|
"Trinuclear Zn3(OAc)4-3,3’-bis(aminoimino)binaphthoxide
Complex for Highly Efficient Catalytic Asymmetric Iodolactonization" *Arai,
T.; Sugiyama, N.; Masu, H.; Kado, S.; Yabe, S.; Yamanaka, M. Chem. Commun. 2014, 42 pp.8287-8290. DOI:10.1039/C4CC02415J |
Yamanaka, M. | |
|
"Switching Enantioface
Selection in the Asymmetric Nitro-Mannich Reaction Using Single Chiral
Bis(imidazolidine)pyridine-metal Catalysts" *Arai, T.;
Matsumura, E. Synlett 2014, 25 pp.1776-1780. DOI:10.1055/s-0034-1378204 |
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|
"Diversity-Oriented Asymmetric
Catalysis (DOAC): Stereochemically Divergent Synthesis of Thiochromanes Using
an Imidazoline-Aminophenol-Nickel Catalyzed Michael/Henry Reaction" *Arai, T.; Yamamoto, Y Org. Lett. 2014, 16 pp.1700-1703. DOI:10.1021/ol500361w |
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"Chiral
Bis(oxazolidine)pyridine-Cu-Catalyzed Enantioselective Friedel-Crafts
Alkylation of Indole with Nitroalkenes" Sato, T.; *Arai, T. Synlett 2014, 25 pp.349-354. DOI:10.1055/s-0033-1340311 |
||
| Reviews / Accounts |
"高機能化する不斉ヨードラクトン化触媒(最新のトピックス)" 荒井孝義 化学 2015, 70 pp.66-67. |
|
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Development of chiral iodine-catalyst assisted with NH-hydrogen bonding" Arai, T. The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Diversity-oriented asymmetric catalysis (DOAC) for spirooxindoles" Arai, T. The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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招待講演 " Imidazoline-aminophenol(IAP)-metal Catalyzed Asymmetric Synthesis of Diversified Chiral Mixed 3,3’-bisindoles " Arai, T.The XXVI International Conference on Organometallic Chemistry （ICOMC2014）, 札幌 (日本) 2014-07-13～2014-07-18 |
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| Patent |
"光学活性なペルオキシド付加体およびその製造方法" 発明者：荒井孝義、土屋賢人 出願者：千葉大学 特願2015-089893号 2015-04-25, 2016-04, (国内) |
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"8-オキサ-6-アザビシクロ[3,2,1]オクタン誘導体およびその製造方法" 発明者：荒井孝義、渡辺旺嗣 出願者：千葉大学 2015-04-15, 特願2015-083791号 2016-04, (国内) |
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"アミノサリチルアルジミン配位子を金属に配位させた触媒およびこれを用いたヨード環化体の製造方法" 発明者：荒井孝義、渡辺旺嗣 出願者：千葉大学 特願2015-081322号 2015-04-12, 2016-04, (国内) |
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| A02 入江 亮 | ||
| Original papers |
"Synthesis, structure, and spin equilibrium properties of
[FeIIIX2L]BPh4⋅solvents (X = 1-methylimidazole and imidazole; L = N,
N′-bis(3-ethoxycarbonylsalicylidene)ethylenediamine)" Fujinami, T.; Hamada, D.; *Matsumotoa, N.; Sunatsuki, Y.; Irie, R. Inorganica Chimica Acta 2015, 430 pp.239-244. DOI:10.1016/j.ica.2015.03.008 |
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"Synthesis, Stereochemical Characteristics, and Coordination Behavior of 2,2’-Binaphtyl-1,1’-biisoquinoline as a New Axially Chiral Bidentate Ligand" Kawatsu, T.; Tokushima, H.; Takedomi, Y.; Imahori, T.; Igawa, K.; Tomooka, K.; *Irie, R. ARKIVOC 2015, 2015 pp.161-175. |
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| Reviews / Accounts |
"Katsuki Catalysts for Asymmetric Oxidation: Design Concepts, Serendipities for Breakthroughs, and Applications" *Irie, R.; Uchida, T.; Matsumoto, K. Chem. Lett. 2015, 44 (10), pp.1268-1283. DOI:10.1246/cl.150747 |
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"New Synthetic Approaches to Fused Polycyclic Compounds by Using Domino Cyclization Reactions of Aromatic Diyne and Enyne Systems" *Irie, R.; Furusawa, M.; Arita, K.; Igawa, K.; Tomookai. K J. Synth. Org. Chem. Jpn 2014, 72 (10), pp.1131-1142. DOI:10.5059/yukigoseikyokaishi.72.1131 |
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| Conference / Symposium / Lecture |
招待講演 "New Synthetic Approaches to Heterohelicenes" ○*Irie, R.; Furusawa, M.; Shigeta, Y.; Ueda, D.; Arae, S.; Fujimoto, H.; Sumimoto, M.; Igawa, K.; Tomooka, K. International Conference on Materials Science & Technology（ICMTech-2016), Delhi (India) 2016-03-01～2016-03-04 |
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口頭発表／ポスター発表 "New Synthetic Approach to Carbazol-Containing Chiral Azahelicenes by Pd-Catalyzed Cyclodehydrogenation and Their Stereochemical Behavior" ○Arae, S.; Ueda, D.; Shigeta, Y.; Hamamoto, S.; Sumimoto, M.; Fujimoto, H.; Igawa, K.; Tomooka, K.; *Irie, R. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Regio- and Enantioselective Catalytic Cycloisomerization of Aromatic Enyne Systems" ○*Irie, R.; Arita, K.; Beppu, S.; Arae, S.; Fujimoto, H.; Sumimoto, M.; Igawa, K.; Tomooka, K. The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC13), Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Chiral Base-catalyzed Enantio- and Regio-selective Domino Cycloisomerization of Aromatic Enyne Systems through Chiral Vinylidene o-Quinone Methide Intermediates" Arita, K.; Furusawa, M.; Beppu, S.; Yamaguchi, K.; Sumimoto, M.; Fujimoto, H.; Igawa, K.; Tomooka, K.; ○*Irie, R. The 39th Naito Conference, Sapporo (Japan) 2015-06-06～2015-06-09 |
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招待講演 "NEW SYNTHETIC APPROACHES TO HETEROHELICENES" ○*Irie, R.; Furusawa, M.; Shigeta, Y.; Ueda, D.; Arae, S.; Fujimoto, H.; Sumimoto, M.; Igawa, K.; Tomooka, K. International Congress on Science and Nature (ISNaC) 2015/MSA International Symposium on Organic Chemistry (ISOC) 2015, Kuala Lumpur (Malaysia) 2015-09-21～2015-09-23 |
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口頭発表／ポスター発表 "Chiral Base-catalyzed Enantioselective Cycloisomerization of Aromatic Enyne Systems" ○Arita, K.; Irie, R. The 9th ICAST 2014 Clemont-Ferrand (International Student Conference on Advanced Science and Technology), Clemont-Ferrand (France) 2014-12-11～2014-12-12 |
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招待講演 "Chiral Base-catalyzed Asymmetric Domino Cycloisomerization of Aromatic Diyne and Enyne Systems" Arita, K.; Furusawa, M.; Imahori, T.; Igawa, K.; Tomooka, K.; ○*Irie, R. Vietnam Malaysia International Chemical Congress (VMICC) 2014, Hanoi (Vietnam) 2014-11-07～2014-11-09 |
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招待講演 "Palladium-catalyzed Non-classical Dehydrogenative Bergman-Masamune Reactions of Enediyne Systems" Furusawa, M.; Shigeta, Y.; Imahori, T.; Igawa, K.; Tomooka, K.; ○*Irie, R. 18th Malaysian International Chemical Congress (18MICC) 2014, Kuala Lumpur (Malaysia) 2014-11-03～2014-11-05 |
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口頭発表／ポスター発表 "Synthesis, Dynamic Conformational Characteristics, and Coordination Behavior of New Binaphthyl-linked Biisoquinoline" ○Kawatsu, T.; Tokushima, H.; Takedomi, Y.; Igawa, K.; Tomooka, K.; *Irie, R. Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Palladium-catalyzed Dehydrogenative Cycloaromatization of Enediyne Systems for the Synthesis of Heterohelicenes" Furusawa, M.; Shigeta, Y.; Imahori, T.; Igawa, K.; Tomooka, K.; ○*Irie, R. ICOMS2014, Sapporo (Japan) 2014-07-13～2015-07-18 |
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| A02 尾野村 治 | ||
| Original papers |
"Chiral copper-catalyzed
asymmetric monoarylation of vicinal diols with diaryliodonium salts" Hamaguchi, N.; Kuriyama, M.; Onomura, O. Tetrahedron: Asymmetry 2016, 27 (4), pp.177-181. |
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"Simple
method for selective oxidation of 1,2-diols in water with KBrO3/KHSO4" William, J. M.; Kuriyama, M.; Onomura, O. Tetrahedron Lett. 2014, 55 (48), pp.6589-6592. DOI:10.1016/j.tetlet.2014.10.035 |
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" Palladium-Catalyzed Synthesis of Heterocycle-Containing Diarylmethanes through Suzuki–Miyaura Cross-Coupling " *Kuriyama, M.: Shinozawa, M.: Hamaguchi, N.: Matsuo, S.: Onomura O.J. Org. Chem. 2014, 79 (12), pp.5921-5928. DOI:10.1021/jo5009178 |
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"Diastereoselective synthesis of 3-fluoro-2-substituted piperidines and pyrrolidines" Gichuhi, P. N.; Kuriyama, M.; *Onomura, O. Heterocycles 2014, 88 (1), pp.331-346. DOI:10.3987/COM-13-S(S)27 |
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"Boronic Acid-Catalyzed Selective Oxidation of 1,2-Diols to α-Hydroxy Ketones in Water" William, J. M.; Kuriyama, M.; *Onomura, O. Adv. Synth. Catal. 2014, 356 (5), pp.934-940. DOI:10.1002/adsc.201300961 |
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| Books |
「有機合成実験法ハンドブック第2版」 有機合成化学協会 "ヒドロシラン＆スズヒドリド" Onomura, O. 丸善株式会社 (東京) 2015, pp887-895. |
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「Organic
Electrochemistry, Fifth Edition」 Speiser, B.; Hammerich, O. "Aliphatic Nitrogen-Containing Compounds Amines, Amino Alcohols, and Amino Acids" Onomura, O. CRC press ( New York) 2015, pp1103-1119. |
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「Encyclopedia
of Applied Electrochemistry」 Savinell, R. F.; Ota, K.; Kreysa, G. "Electrochemical Asymmetric Synthesis" Onomura, O. Springer (Heidelberg) 2014, pp452-458. |
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| Reviews / Accounts |
"官能基化されたNHC配位子の開発と触媒的アリール化反応への適用"
栗山正巳、白井隆一、尾野村治
J. Synth. Org. Chem. Jpn 2015, 73 (4), pp.361-371. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Metal-free Oxidation of Alkanes to Carboxylic Acids" Matsumoto, Y.; Kuriyama, M.; Onomura, O. 2nd International Conference & 7th Symposium on Organocatalysts, Tokyo (Japan) 2014-11-20～2014-11-21 |
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口頭発表／ポスター発表 "Monoarylation of Diols with Diaryliodonium Salts in the presence of a Copper(II) Catalyst
"
○Hamaguchi, H.; Kuriyama, M.; Onomura, O.
a Pre-symposium of ICOMC 2014, Fukuoka (Japan) 2014-07-11～2014-07-11 |
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| Patent |
"
光学活性α－アルキルセリン誘導体の製造方法 " 発明者：尾野村 治； 谷川 智子；岩崎 史哲 出願者：長崎大学＆株式会社トクヤマ2011-248573 2011-11-14, 特許第５７７３８５０号 2015-07-10, (国内) |
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"ヒドロキシシリルエーテル化合物の製造方法" 発明者：尾野村治、栗山正巳、竹市翼、岩崎史哲 出願者：長崎大学＆㈱トクヤマ 特願2011-051602 2011-03-09, 特許第5734032号 2015-04-24, (国内) |
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"Method for producing optically active compound or salt thereof" 発明者：Onomura, O.; Tsuda, Y.; Kuriyama, M.; Yanagi, T.; Kodama, K. 出願者：Nagasaki University PCT/JP2012/052176 2012-01-31, US 8,969,582 B2 2015-03-03, (国外) |
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"ピラノシドチオカルボニルエステル化合物の製造方法" 発明者：尾野村治、村松渉、岩崎史哲 出願者：長崎大学＆株トクヤマ 特願2011-065439 2011-03-24, 特許第5669643号 2014-12-26, (国内) |
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"α−ピラノシドチオカルボニルエステル化合物の製造方法" 発明者：尾野村治、村松渉、谷川智子、岩崎史哲 出願者：長崎大学＆㈱トクヤマ 特願2011-057746 2011-03-16, 特許第5669637号 2014-12-26, (国内) |
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"β－グルコピラノシドチオカルボニルエステルの製造方法" 発明者：尾野村治、村松渉、谷川智子、岩崎史哲 出願者：長崎大学＆㈱トクヤマ 特願2011-035931 2011-02-22, 特許第5669618号 2014-12-26, (国内) |
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"重水素化方法および重水素化触媒" 発明者：栗山正巳、尾野村治、佐藤香菜子、矢野玄馬 出願者：長崎大学 PCT/JP2015/055652 2015-02-26, 2015-02, (国外) |
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"新規化合物とその錯体並びに錯体の製造方法" 発明者：尾野村治、栗山正巳、松尾星来、高瀬一郎 出願者：㈱ダイセル 特願2011-079321 2011-03-31, 特許第5635443号 2014-10-24, (国内) |
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"光学活性な環状エーテルのエステル誘導体の製造方法" 発明者：尾野村治, 宮本圭輔, 伊藤雅章 出願者：㈱ダイセル 2014-09-11, 特願2014-184737 2014-11, (国内) |
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"１，２，３-トリオール化合物の光学活性モノエステル体の製造方法" 発明者：尾野村治、竹本祐樹、宮本圭輔、伊藤雅章 出願者：長崎大学＆㈱ダイセル PCT/JP2014/077862 2014-10-20, 2014-10, (国内) |
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| A02 上條 真 | ||
| Original papers |
"Two-directional carbon chain elongation via the consecutive 1,4-addition of allyl malononitrile and the Cope rearrangement on an alkynoate platform" *Kamijo, S.; Kamijo, K.; Magarifuchi, D.; Ozawa, R.; Tao, K.; Murafuji, T. Tetrahedron Lett. 2016, 57 pp.137-140. DOI:10.1016/j.tetlet.2015.11.081 |
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"Synthesis of Aliphatic Azides by Photoinduced C(sp3)–H Azidation" *Kamijo, S.; Watanabe, M.; Kamijo, K.; Tao, K.; Murafuji, T. Synthesis 2016, 48 pp.115-121. DOI:10.1055/s-0035-1560705 |
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"Photoinduced Oxidation of Secondary Alcohols Using 4-Benzoylpyridine as an Oxidant" *Kamijo, S.; Tao, K.; Takao, G.; Tonoda, H.: Murafuji, T. Org. Lett. 2015, 17 pp.3326-3329. DOI:10.1021/acs.orglett.5b01550. |
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"Ether derivatization via two-step protocol comprised of photochemical ethereal C–H chlorination and nucleophilic substitution " *Kamijo, S.; Tao, K.; Takao, G.; Murooka, H.; Murafuji, T. Tetrahedron Lett. 2015, 56 pp.1904-1907. DOI:10.1016/j.tetlet.2015.02.102 |
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"Photoinduced sulfonylation of cyclic ethers" *Kamijo, S.; Hirota, M.; Tao, K.; Watanabe, M.; Murafuji, T. Tetrahedron Lett. 2014, 55 pp.5551-5554. DOI:10.1016/j.tetlet.2014.08.011 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Photochemical Activation of C(sp3)–H Bond for One-Pot Functionalization of Cyclic Ethers" ○Takao, G.; Tao, K, Murafuji, T.; *Kamijo, S. Advanced Molecular Transformations by Organocatalysis, 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
|
| Prize |
"Thieme Chemistry Journal Award 2015" Shin Kamijo 2014-12 Thieme |
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| A02 西林 仁昭 | ||
| Original papers |
"Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage" Nakajima,K.; Nojima, S.; Sakata, K.; *Nishibayashi, Y. ChemCatChem. 2016, 8 (6), pp.1028-1032. DOI:10.1002/cctc.201600037 |
坂田健 |
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"Recent Progress in Transition Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions " Y. Nishibayashi Inorg. Chem. 2015, 54 pp.9234-9247. DOI:10.1021/acs.inorgchem.5b00881 |
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"Nitrogen Fixation Catalyzed by Ferrocene-Substituted Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes: Unique Behavior of Ferrocene Moiety as Redox Active Site" S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and *Y. Nishibayashi Chem. Sci. 2015, 6 pp.3940-3951. DOI:10.1039/C5SC00545K |
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"Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes" K. Nakajima, S. Takata, K. Sakata, and *Y. Nishibayashi Angew. Chem. Int. Ed. 2015, 54 pp.7597-7601. DOI:10.1002/anie.201502531 |
坂田 健 | |
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"Catalytic Reduction of Dinitrogen into Ammonia by Use of Molybdenum-Nitride Complexes Bearing Tridentate Triphosphine as Catalysts " K. Arashiba, E. Kinoshita, S. Kuriyama, A. Eizawa, K. Nakajima, H. Tanaka ,K. Yoshizawa, and *Y. Nishibayashi J. Am. Chem. Soc. 2015, 137 pp.5666-5669. DOI:10.1021/jacs.5b02579 |
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"Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions " R. Imayoshi, H. Tanaka, Y. Matsuo, M. Yuki, K. Nakajima, K. Yoshizawa, and *Y. Nishibayashi Chem. Eur. J. 2015, 21 pp.8905-8909. DOI:10.1002/chem.201501088 |
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"Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexex as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents " M. Yuki, K. Sakata, Y. Hirao, N. Nonoyama, K. Nakajima, and Y. Nishibayashi* J. Am. Chem. Soc. 2015, 137 pp.4173-4182. DOI:10.1021/jacs.5b00584 |
坂田 健 | |
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"Copper-Catalyzed Enantioselective Etherification of Propargylic Esters with Alcohols " K. Nakajima, M. Shibata, and Y. Nishibayashi* J. Am. Chem. Soc. 2015, 137 pp.2472-2475. DOI:10.1021/jacs.5b00004 |
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"Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands " E. Kinoshita, K. Arashiba, S. Kuriyama, A. Eizawa, K. Nakajima, and Y. Nishibayashi* Eur. J. Inorg. Chem. 2015, pp.1789-1794. DOI:DOI: 10.1002/ejic.201500017 |
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"Radical Addition to Corannulene Mediated by Visible Light-Photoredox Catalysts " K. Nakajima, Y. Ashida, S. Nojima, and Y. Nishibayashi* Chem. Lett. 2015, pp.545-547. DOI:10.1246/cl.150019 |
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"Cooperative Catalytic Reactions: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide Hybrid Catalysts" Y. Senda, K. Nakajima, and Y. Nishibayashi* Angew. Chem. Int. Ed. 2015, 54 pp.4060-4064. DOI:DOI: 10.1002/anie.201411601 |
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"Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand " K. Arashiba, K. Nakajima, and Y. Nishibayashi* Z. Anorg. Allg. Chem. 2015, 641 pp.100-104. DOI:10.1002/zaac.201400117 |
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"Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand " Y. Tanabe, S. Kuriyama, K. Arashiba, K. Nakajima, and *Y. Nishibayashi Organometallics 2014, 33 pp.5295-5600. |
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"Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine" T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, and *Y. Nishibayashi Angew. Chem. Int. Ed. 2014, 53 pp.11488-11492. |
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"Synthesis of Nitrogen Heterocycles via a-Aminoalkyl Radicals Generated from a-Silyl Secondary-Amines under Visible Light Irradiation " K. Nakajima, M. Kitagawa, Y. Ashida, *Y. Miyake, and *Y. Nishibayashi Chem. Commun. 2014, 50 pp.8900-8903. |
三宅由寛 | |
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"Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides " Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and *Y. Nishibayashi Org. Biomol. Chem. 2014, 12 pp.5594-5596. |
三宅由寛 | |
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"Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand " S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, N. Kamaru, K. Yoshizawa, and *Y. Nishibayashi J. Am. Chem. Soc. 2014, 136 pp.9719-9731. |
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"Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst" M. Shibata, K. Nakajima, and *Y. Nishibayashi Chem. Commun. 2014, 50 pp.7874-7877. |
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"Visible Light-Mediated Addition of a-Aminoalkyl Radicals to [60]Fullerene Using Photoredox Catalysts" Y. Miyake,* Y. Ashida, K. Nakajima, and *Y. Nishibayashi Chem. Eur. J. 2014, 20 pp.6120-6126. |
三宅由寛 | |
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"Unique Behavior of Dinitrogen-Bridged Dimolybdenum Complexes Bearing Pincer Ligand towards Catalytic Formation of Ammonia " H. Tanaka, K. Arashiba, S. Kuriyama, A. Sasada, K. Nakajima, K. Yoshizawa,* and *Y. Nishibayashi Nature Communications 2014, 5 pp.3737. |
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| Reviews / Accounts |
"Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes" Tanabe, Y.; *Nishibayashi, Y. Chemical Record 2016, |
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"有機分子触媒と遷移金属触媒とを協奏的に利用した分子変換反応" 三宅由寛、中島一成、西林仁昭* 有機分子触媒の最前線 (日本化学会 Current Review) 2016, |
三宅由寛 | |
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"常温常圧下での触媒的窒素固定法開発の最近の進展" 田邊資明、西林仁昭* 日本エネルギー学会誌 2016, |
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"遷移金属錯体を触媒として利用した触媒的アンモニア合成法の開発" 田邊資明、西林仁昭* ファインケミカル 2016, 45 pp.7-18. |
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"特集にあたって-ハーバー・ボッシュ法を超えるアンモニア合成法開発への挑戦-" 西林仁昭* ファインケミカル 2016, 45 pp.5-6. |
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"非白金分子触媒による触媒的水素酸化反応の開発" 結城雅弘、西林仁昭* ENEOS Technical Review 2016, 58 (1), pp.12-18. |
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"温和な反応条件下での触媒的窒素固定法に関する最近の進展" 荒芝和也、西林仁昭* 化学工業 2016, 67 (1), pp.1-5. |
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"白金触媒に匹敵するアノード分子触媒の開発" 結城雅弘、西林仁昭* エネルギーデバイス 2015, 2 (7), pp.92-96. |
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"常温常圧でのアンモニアの合成" 田邊資明、西林仁昭* アンモニアを用いた水素利用システム 2015, pp.87-101. |
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"Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions" Y. Nishibayashi* Comptes rendus Chimie 2015, 18 pp.776-784. DOI:10.1016/j.crci.2015.01.014 |
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"温和な反応条件下での遷移金属窒素錯体を分子触媒として用いた窒素分子からのアンモニア合成反応の開発" 西林仁昭* 触媒 2015, 57 pp.33-38. |
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"常温常圧下での触媒的アンモニア合成反応開発の現状と将来展望" 田邊資明、*西林仁昭 日本エネルギー学会誌 2014, pp.386-392. |
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"遷移金属窒素錯体を用いた触媒的窒素固定反応に関する最近の進展" *西林仁昭、荒芝和也、結城雅弘 有機合成化学協会誌 2014, 72 pp.529-537. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "
Theoretical Study on Cobalt-Catalyzed Transformation of Molecular
Dinitrogen into Silylamine " Tanaka, H.; Imayoshi, R.; Matsuo, Y.; Yuki, M.; Nakajima, K.; Yoshizawa, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Synthesis and Catalytic Activity of Dimolybdenum-Dinitrogen Complex Bearing PCP-Type Pincer Ligands " Eizawa, A.; Arashiba, K.; Kuriyama, S.; Nakajima, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with Dihydropyridines via Dual Carbon-Carbon Bond Cleavage " Nojima, S.; Nakajima, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "
Synthesis of Phosphabenzenes by Iron-Catalyzed
[2+2+2] Cycloaddition of Diynes with Phosphaalkyne " Nakajima, K.; Takata, S.; Sakata, K.; *Nishibayashi, Y. 2015 International Chemical Congress of Pacific Basin Societies, ホノルル (アメリカ合衆国) 2015-12-15～2015-12-20 |
坂田健 | |
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口頭発表／ポスター発表 "
Enantioselective Propargylic Alkylation of
Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide
Hybrid Catalysts " Nakajima, K.; Senda, Y.; *Nishibayashi, Y. The 39th Naito Conference on the Chemistry of Organocatalysts, 札幌 (日本) 2015-07-06～2015-07-09 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions " *Nishibayashi, Y. 80. The 2015 International Chemical Congress of Pacific Basin Societies, ハワイ (アメリカ合衆国) 2015-12-15～2015-12-20 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions " *Nishibayashi, Y. 76. 第10回日中クラスタ−会議, 福州 (中国) 2015-10-23～2015-10-27 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions
" *Nishibayashi, Y. The 2nd International Conference on Organometallics and Catalysis, 奈良 (日本) 2014-10-27～2014-10-29 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Ambient Conditions
" *Nishibayashi, Y. The JSPS Strasbourg Symposium, Strasbourg (France) 2014-10-15～2014-10-17 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Mild Reaction Conditions
" *Nishibayashi, Y. 41st International Conference on Coordination Chemistry, Singapore (Singapore) 2014-07-21～2014-07-25 |
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招待講演 "
Molybdenum-Catalyzed
Reduction of Molecular Dinitrogen into Ammonia under Mild Reaction Conditions
" *Nishibayashi, Y. The 26th International Conference on Organometallic Chemistry, 札幌 (日本) 2014-07-14～2014-07-14 |
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| Prize |
"有機合成化学協会企業冠賞受賞（日産化学・有機合成新反応⁄手法賞）" 西林仁昭 2016-02 有機合成化学協会 触媒的プロパルギル位置換反応の開発と不斉反応への展開 |
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| Media |
"フロントランナー 挑む 「常温常圧のアンモニア合成でエネルギー資源革命」" 西林仁昭 日経サイエンス 2015-12-25 食糧生産に不可欠で，水素エネルギー利用でも注目されるアンモニア 現在は高温高圧が必要だが，常温常圧で合成できるようになれば 世界レベルで省エネルギーが実現，新エネルギーの普及にも弾みがつく |
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"触媒分野の研究活性化" *西林仁昭 化学工業日報 2014-10-10 PDF 常温常圧でアンモニアを合成する触媒の機能を解明 |
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"Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst, M. Shibata, K. Nakajima, and Y. Nishibayashi, Chem. Commun., 50, 7874-7877 (2014).の内容が、Synfacts 誌 2014, 10に掲載. " *西林仁昭 Synfact 2014-11-11 |
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"
Photolytic N2 Splitting: A Road to Sustainable NH3 Production? " *西林仁昭 Angew. Chem.誌 ハイライト 2014-11-11The split up: Recent advances in photochemical dinitrogen splitting have been achieved. Demonstration of the reversibility of the N2 splitting and ammonia formation from a nitride has advanced the field of N2 fixation using a synthetic homogeneous system. |
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"触媒的アンモニア生成反応におけるピンサー型配位子を持つ窒素架橋２核モリブデン錯体の特異な挙動" *西林仁昭 Nature Communications誌 日本語サイト 注目の論文 2014-06-04 |
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"
アンモニア合成省エネ化 東大、モリブデン触媒利用 常温・常圧目指す エネルギー源の期待も
" 西林仁昭 日経産業新聞 2014-06-16 |
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"
触媒機構解明に成功 アンモニア常温常圧合成低コスト化に道
" 西林仁昭 日刊工業新聞 2014-04-30 |
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| A02 渕辺 耕平 | ||
| Original papers |
"Regioselective Synthesis of α,α-Difluorocyclopentanone Derivatives: Domino Nickel-Catalyzed Difluorocyclopropanation/Ring Expansion Sequence of Silyl Dienol Ethers" Aono, T.; Sasagawa, H.; Fuchibe, K.; *Ichikawa, J. Org. Lett. 2015, 17 (23), pp.5736-5739. DOI:10.1021/acs.orglett.5b02726 |
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"Pinpoint-Fluorinated Phenanthrene Synthesis based on C–F Bond Activation of Difluoroalkenes" Fuchibe, K.; Morikawa, T.; Ueda, R.; Okauchi, T.; *Ichikawa, J. J. Fluorine Chem. 2015, 179 (-), pp.106-115. DOI:10.1016/j.jfluchem.2015.06.008 |
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"
Pinpoint-Fluorinated Phenacenes: New Synthesis and Solubility
Enhancement Strategies" Fuchibe,
K.; Morikawa, T.; Shigeno, K.; Fujita, T.; *Ichikawa, J.
Org. Lett. 2015, 17 (5), pp.1126-1129. DOI:10.1021/ol503759d |
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"Organocatalytic, Difluorocarbene-Based S-Difluoromethylation of Thiocarbonyl Compounds" Fuchibe, K.; Bando, M.; Takayama, R.; *Ichikawa, J. J. Fluorine Chem. 2015, 171 pp.133-138. DOI:10.1016/j.jfluchem.2014.08.013 |
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"Indium(III)-Catalyzed Cationic Cyclization of 1,1-Difluoroallenes:
Regioselective Synthesis of 1-Fluoronaphthalenes" Fuchibe, K.; Mayumi, Y.; Yokota, M.; Aihara, H.; *Ichikawa, J. Bull. Chem. Soc. Jpn 2014, 87 (9), pp.942-949. DOI:10.1246/bcsj.20140128 |
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| Books |
「有機合成実験法ハンドブック」 中井武（編集代表） "19.2.8 バナジウム・ニオブ・タンタルの化合物" 渕辺耕平 丸善出版 (東京都) 2015, pp71-73. ISBN:978-4-621-08948-4 |
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「フッ素化学入門 2015」 （独）日本学術振興会・フッ素化学第１５５委員会 "II 有機フッ素化合物の合成反応（一部）" 渕辺耕平 他48名 三共出版 (東京都) 2015, pp199-207等. ISBN:978-4-7827-0727-2 |
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「Science of Synthesis Knowledge Updates 2014/2」 Brønsted Nielsen, M.; Krause, N.; Marek, I.; Shaumann, E.; Wirth, T. "1,1-Dihaloallenes (Update 2014)" Fuchibe, K.; Ichikawa, J. Thieme (Stuttgart) 2015, pp217-231. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Regioselective Synthesis of Fluorinated Cyclopentenonesvia Organocatalytic Generation of Difluorocarbene" ○Takayama, R.; Fuchibe, K.; *Ichikawa, J. INTERNATIONAL CONFERENCE ON FLUORINE CHEMISTRY 2014 TOKYO, Yokohama (Japan) 2014-05-28～2014-05-30 |
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口頭発表／ポスター発表 "Organocatalytic Generation of Difluorocarbene: Synthesis of Difluoromethyl Thioimidates" ○Fuchibe, K.; Bando, M.; Takayama, R.; *Ichikawa, J. The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Control of difluorocarbene generation by organocatalyst and its applications" ○Fuchibe, K.; Koseki,Y.; Aono, T.; Bando, M.; Takayama, R.; *Ichikawa, J. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Catalytic introduction of difluoromethyl and difluoromethylene groups with difluorocarbene and its complexes" ○Fuchibe, K.; Aono, T.; Hu, J.; Takayama, R.; Koseki, Y.; Bando, M.; *Ichikawa, J. The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu (USA) 2015-12-15～2015-12-20 |
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招待講演 "1,1-Difluoroallenes as Synthetic Platforms: Indium-Catalyzed Domino Synthesis of Pinpoint-Fluorinated PAHs" *Fuchibe, K. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, Sendai (Japan) 2015-09-06～2016-09-09 |
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招待講演 "1,1-Difluoroallenes as Synthetic Platforms: Preparation and Domino Reactions" *Fuchibe, K. ICOMC 2014 Sendai Pre-Symposium, Sendai (Japan) 2014-07-11～2014-07-11 |
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| A02 松谷 裕二 | ||
| Original papers |
"Synthesis of Substituted Pyrrolo[2,1-a]isoquinolines by Gold-catalyzed Domino Cyclization of Alkynyl Iminoesters." Sugimoto, K.; Hoshiba, Y.; Tsuge, K.; *Matsuya, Y. Synthesis 2016, in Press DOI:10.1055/s-0035-1561423 |
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"Construction of cis-Fused Hydrindane Skeleton with a Lactone Tether Utilizing Intramolecular Diels-Alder Reaction." Yin, S.; Takai, K.; Minato, D.; Sugimoto, K.; Ohtsu, H.; Tsuge, K.; *Matsuya, Y. Heterocycles 2016, in Press DOI:10.3987/COM-15-S(T)34 |
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"In vitro and in vivo Antiherpetic Effects of (1R,2R)-1-(5'-methylful-3'-yl)propane-1,2,3-triol." Sasaki, K.; Hayashi, K.; Matsuya, Y.; Sugimoto, K.; *Lee, J.-B.; Kurosaki, F.; Hayashi, T. J. Nat. Med. 2016, 70 (2), pp.217-224. DOI:10.1007/s11418-016-0964-6 |
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"Synthesis of Denosomin–Vitamin D3 Hybrids and Evaluation of their Anti-Alzheimer's Disease Activities." Sugimoto, K.; Yajima, H.; Hayashi, Y.; Minato, D.; Terasaki, S.; Tohda, C.; *Matsuya, Y. Org. Lett. 2015, 17 (23), pp.5910-5913. DOI:10.1021/acs.orglett.5b03138 |
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"Three-Component Domino Process for Pyrrolizine Skeleton via [3+2]-Cycloaddition–Enamine Cyclization Triggered by Gold Catalyst." Sugimoto, K.; Yamamoto, N.; Tominaga, D.; *Matsuya, Y. Org. Lett. 2015, 17 pp.1320-1323. DOI:10.1021/acs.orglett.5b00320 |
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"Synthesis and Evaluations of GLP-1 Secretion and Anti-Diabetic Effect in KKAy Mice of New Tricyclic Compounds." Minehira, D.; Takeda, D.; Miyawaki, S.; Kato, A.; Adachi, I.; Miyazaki, A.; Miyatake, R.; Umezaki, M.; Miura, K.; Kitahara, Y.; Sugimoto, K.; Matsuya, Y.; *Toyooka, N. Heterocycles 2015, 90 pp.372-404. DOI:10.3987/COM-14-S(K)29 |
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"Preparation of (2R,4S)/(2S,4S)-4-Hydroxypipecolinic Acid Derivatives from L-(–)-Malic Acid." Yin, S.; Taneda, H.; Li, B.; Zhou, D.; Minato, D.; Sugimoto, K.; *Matsuya, Y. Heterocycles 2015, 90 pp.928-938. DOI:10.3987/COM-14-S(K)52 |
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"Stereoselective Approach to Potential Scaffold of A-nor B-aromatic OSW-1 Analogues via [4+2] Cycloaddition of o-Quinodimethane." Li, B.; Masuda, S.; Minato, D.; Zhou, D.; Sugimoto, K.; Nemoto, H.; *Matsuya, Y. Tetrahedron 2014, 70 pp.3981-3987. DOI:10.1016/j.tet.2014.04.079 |
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"Synthesis of Long-chain Fatty Acid Derivatives as a Novel Anti-Alzheimer’s Agent." Zhang, H.-Y.; Yamakawa, Y.; Matsuya, Y.; *Toyooka, N.; Tohda, C.; Awale, S.; Li, F.; Kadota, S.; Tezuka, Y. Bioorg. Med. Chem. Lett. 2014, 24 pp.604-608. DOI:10.1016/j.bmcl.2013.12.008 |
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"Synthesis of 8-Amino-(dihydrofuran-fused perhydrophenanthrene) via Copper-Mediated Amination Reaction." Sugimoto, K.; Tamura, K.; Toyooka, N.; *Matsuya, Y. Heterocycles 2014, 88 pp.755-763. DOI:10.3987/COM-13-S(S)38 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Synthetic Studies toward (+)-CJ-12,950 for the Stereochemical Assignment and Structure Activity Relationship Studies." ○Oguma, Y.; Yamagishi, T.; Yamamoto, N.; Shinoda, S.; Sugimoto, K.; Toyooka, N.; Minato, D.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Three-component Domino Process for the Pyrrolizine Skeleton via [3+2]-Cycloaddition of Azomethine Ylide and Enamine Cyclization Triggered by a Gold Catalyst." ○Sugimoto, K.; Yamamoto, N.; Tominaga, D.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Novel NHC-catalyzed Synthesis of Silyl Dienol Ethers via 1,4-Brook Rearrangement." ○Amano, H.; Sugimoto, K.; *Matsuya, Y. 2015 International Congress of Pacific Basin Societies, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthetic Studies toward (+)-CJ-12,950 for the Stereochemical Assignment." ○Oguma, Y.; Yamagishi, T.; Yamamoto, N.; Shinoda, S.; Sugimoto, K.; Minato, D.; *Matsuya, Y. The 3rd International Symposium on Process Chemistry, Kyoto (Japan) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "NHC-catalyzed Transformation of β-Silylated Enones to Silyl Dienol Ethers via Silyl Migration." ○Sugimoto, K.; Amano, H.; *Matsuya Y. The 39th Naito Conference, The chemistry of organocatalysts, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Design, Synthesis, and Biological Evaluation of Promising Anti-Alzheimer’s Compounds Having Dihydropyrone Unit as a Key Component." Sugimoto, K.; Yajima, H.; Tohda, C.; ○*Matsuya Y. The XVI International Conference on Heterocycles in Bioorganic Chemistry, Metz (France) 2015-06-08～2015-06-11 |
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口頭発表／ポスター発表 "Domino process for concise synthesis of pyrrolizines via 3-component coupling reaction with gold catalysis." ○Sugimoto, K.; Yamamoto, N.; Tominaga, D.; Minato, D.; *Matsuya, Y. 15th Tetrahedron Symposium - Asian Edition, Singapore (Singapore) 2014-10-28～2014-10-31 |
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口頭発表／ポスター発表 "Synthesis and antitumor activity of simplified des-AB-type analogue of OSW-1." ○*Matsuya, Y.; Li, B.; Minato, D.; Sugimoto, K.; Zhou, D.; Nemoto, H. XXIII International Symposium on Medicinal Chemistry, Lisbon (Portugal) 2014-09-07～2014-09-11 |
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| Patent |
"Oral Therapeutic Agent Containing Diosgenins for Diseases Associated with Nerve Axon Dysfunction, Including Alzheimer's Disease." 発明者：Tohda, C.; Matsuya, Y.; Sugimoto, K. 出願者：Resilio Company Limited WO 2015-JP62094 2015-04-21, WO 2015163318 2015-10-29, (国外) |
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"神経変性疾患の治療薬" 発明者：東田千尋，松谷裕二，杉本健士． 出願者：レジリオ株式会社 特願2014-091718 2014-04-25, 2014-04, (国内) |
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| A02 南方 聖司 | ||
| Original papers |
"Synthesis and Structure of Hypervalent Iodine(III) Reagents Containing Phthalimidate and Application to Oxidative Amination Reactions" Kiyokawa, K.; Kosaka, T.; Kojima, T.; *Minakata, S. Angew. Chem. Int. Ed. 2015, 54 (46), pp.13719-13723. |
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"Iodine-Catalyzed Decarboxylative Amidation of β,γ-Unsaturated Carboxylic Acids with Chloramine Salts Leading to Allylic Amides" Kiyokawa, K.;Kojima, T.; Hishikawa, Y.; *Minakata, S. Chem. Eur. J. 2015, 21 (44), pp.15548-15552. |
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"A facile synthesis of functionalized 7,8-diaza[5]helicenes through an oxidative ring-closure of 1,1’-binaphthalene-2,2’-diamines (BINAMs)" Takeda, Y.; Okazaki, M.; Maruoka, Y.; Minakata, S. Beilstein J. Org. Chem. 2015, 11 pp.9-15. |
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"2-Halogenoimidazolium Salt Catalyzed Aza-Diels–Alder Reaction through Halogen-Bond Formation" Takeda, Y.; Hisakuni, D.; Lin, C.-H.; Minakata, S. Org. Lett. 2015, 17 pp.318-321. |
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"Revisiting Phosphorus Analogues of Phthalimides and Naphthalimides: Syntheses and Comparative Studies" Takeda, Y.; Nishida, T.; Hatanaka, K.; Minakata, S. Chem. Eur. J. 2015, 21 pp.1666-1672. |
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"Straightforward Synthesis of 1,2-Dicyanoalkanes from Nitroalkenes and Silyl Cyanide Mediated by Tetrabutylammonium Fluoride" Kiyokawa, K.; Nagata, T.; Hayakawa, J.; Minakata, S. Chem. Eur. J. 2015, 21 pp.1280-1285. |
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"Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β,γ-Unsaturated Carboxylic Acids" Kiyokawa, K.; Yahata, S.; Kojima, T.; Minakata, S. Org. Lett. 2014, 16 pp.4646-4649. |
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"Oxidative Skeletal Rearrangement of 1,1’-Binaphthalene-2,2’-Diamines (BINAMs) via C–C Bond Cleavage and Nitrogen Migration: A Versatile Synthesis of U-Shaped Azaacenes" Takada, Y.; Okazaki, M.; Minakata, S. Chem. Commun. 2014, 50 pp.10291-10294. |
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"2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with the Minimal Core Exhibiting High Electron-accepting Ability" Takeda, Y.; Nishida, T.; Minakata, S. Chem. Eur. J. 2014, 20 pp.10266-10270. |
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"Pd/NHC-Catalyzed Enantiospecific and Regioselective Suzuki-Miyaura Arylation of 2-Arylaziridines: Synthesis of Enantioenriched 2-Arylphenethylamine Derivatives" Takeda, Y.; Ikeda, Y.; Kuroda, A.; Tanaka, S.; Minakata, S. J. Am. Chem. Soc. 2014, 136 pp.8544-8547. |
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| Books |
「Cycloaddition Reactions in Organic Synthesis」 Nishiwaki, N. "N1 Unit Transfer Reaction to C-C Double Bonds" Minakata, S.; Takeda, Y.; Kiyokawa, K. Wiley (Hoboken) 2014, pp67-88. ISBN:978-1-118-29988-3 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Ritter-type C–H amination using N-hydroxyphthalimide and iodic acid" 〇Takemoto, K.; Kiyokawa, K.; *Minakata, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Hypervalent iodine(III)-mediated decarboxylative functionalization of β,γ-unsaturated carboxylic acids" 〇Kojima, T.; Kiyokawa, K.; *Minakata, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis and structure of hypervalent iodine(III) reagent containing phthalimidate and its application to oxidative amination reaction" 〇Kiyokawa, K.; Kosaka, T.; *Minakata, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Iodine-catalyzed diamination of olefins using haloamide salt" *Minakata, S.; 〇Hirayama, A.; Tanaka, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Diaziridination of cyclic secondary amines using haloamide salt" Tanaka, S.; *〇Minakata, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Straightforward synthesis of 1,2-dicyanoalkanes from nitroalkenes and silyl cyanide mediated by tetrabutylammonium fluoride" 〇Nagata, T.; Kiyokawa, K.; *Minakata, S. Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Regioselective Borylative Ring Opening of 2-Arylaziridines Catalyzed by Pd/Phosphine System" 〇Tanaka, S.; Kuroda, A.; Takeda, Y.; Minakata, S. The 1st International Symposium on Interactive Materials Science Cadet Program (iSIMSC), Suita (Japan) 2014-11-16～2014-11-19 |
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口頭発表／ポスター発表 "Straightforward Synthesis of 1,2-Dicyanoalkanes from Nitroalkenes and Silyl Cyanide Activated by TBAF" 〇Nagata, T.; Kiyokawa, K.; Minakata, S. The 1st International Symposium on Interactive Materials Science Cadet Program (iSIMSC), Suita (Japan) 2014-11-16～2014-11-19 |
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口頭発表／ポスター発表 "Synthesis and Physicochemical Properties of Phosphorus Analogues of Pyromellitic Diimides as Novel Electron-acceptors" 〇Takeda, Y.; Nishida, T.; Hatanaka, K.; Minakata, S. The 1st International Symposium on Interactive Materials Science Cadet Program (iSIMSC), Suita (Japan) 2014-11-16～2014-11-19 |
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口頭発表／ポスター発表 "Asymmetric Synthesis of 2-Arylphenetylamine Derivatives through a Pd-Catalyzed Enantiospecific Cross-coupling of 2-Arylaziridines with Arylboronic Acids" 〇Takeda, Y.; Kuroda, A.; Minakata, S. 15th Tetrahedron Symposium Asia Edition, Singapore (Singapore) 2014-10-28～2014-10-31 |
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口頭発表／ポスター発表 "Pd/Phosphine-Catalyzed Regioselective Borylation Reactions" 〇Kuroda, A.; Takeda, Y.; Minakata, S. The 2nd International Conference on Organometallics and Catalysis (OM&Cat-2014), Nara (Japan) 2014-10-26～2014-10-29 |
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口頭発表／ポスター発表 "Synthesis and Properties of Thieno[3,4-c]phospholedione-containing Oligothiophenes" 〇Hatanaka, K.; Takeda, Y.; Minakata, S. Suita (Japan) 2014-07-19～2014-07-19 |
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口頭発表／ポスター発表 "Pd/Phosphine-Catalyzed Regioselective Borylative Ring-Opening Reaction of Aziridines" 〇Kuroda, A.; Takeda, Y.; Minakata, S. Suita (Japan) 2014-07-19～2014-07-19 |
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口頭発表／ポスター発表 "Straightforward Synthesis of 1,2-Dicyanoalkanes from Nitroalkenes and Silyl Cyanide Mediated by TBAF" 〇Nagata, T.; Kiyokawa, K.; Minakata, S. ICOMC 2014 Post-Symposium in Osaka, Suita (Japan) 2014-07-19～2014-07-19 |
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口頭発表／ポスター発表 "NHC/Pd-catalyzed Stereospecific and Regioselective Suzuki–Miyaura Arylative Cross-coupling Reaction of 2-Arylaziridines" 〇Takeda, Y.; Kuroda, A.; Minakata, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014) , Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Pd/Phosphine-Catalyzed Regioselective Borylative Ring Opening Reaction of 2-Arylaziridines" 〇Kurida, A.; Takeda, Y.; Minakata, S. XXVI International Conference on Organometallic Chemistry (ICOMC 2014) , Sapporo (Japan) 2014-07-13～2014-07-18 |
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口頭発表／ポスター発表 "Lewis Acid Catalysis of 2-Halogenoimidazolium Salts in Aza-Diels–Alder Reaction of Aldimines with Danishefsky’s Diene" 〇Takada, Y.; Hisakuni, D.; Minakata, S. 1st International Symposium on Halogen Bonding (ISXB1), Porto Cesareo (Italy) 2014-06-18～2014-06-22 |
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口頭発表／ポスター発表 "〇Okumura, S.; Takeda, Y.; Minakata, S." 4th International Conference on Hypervalent Iodine Chemistry, Narita (Japan) 2014-07-02～2014-07-05 |
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口頭発表／ポスター発表 "Hypervalent Iodine(III)-Mediated Oxidative Decarbonylation of β,γ-Unsaturated Carboxylic Acids" 〇Kiyokawa, K.; Yahata, S.; Kojima, T.; Minakata, S. 4th International Conference on Hypervalent Iodine Chemistry, Narita (Japan) 2014-07-02～2014-07-05 |
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口頭発表／ポスター発表 "Dibenzo[a,j]phenazines: Synthesis and Properties of a New Class of Bent-type Aza PAHs" ◯Okazaki， M.; Takeda, Y.; Minakata, S. The International Conference on Science and Technology of Synthetic Metals, Turku (Finland) 2014-06-30～2014-07-05 |
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| A02 矢島 知子 | ||
| Original papers |
"Photoinduced double perfluoroalkylation of methylacenes" Nogami, E.; Washimi, Y.; Yamazaki, Y.; Kubota, T.; *Yajima, T. Tetrahedron Lett. 2016, 57 pp.2624-2627. DOI:10.1016 |
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"Helical Inversion of Gel Fibrils by Elongation of Perfluoroalkyl Chains as Studied by Vibrational Circular Dichroism" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi Chirality 2016, DOI:10.1002/chir.22592 |
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"Chiroptical Studies on Supramolecular Chirality of Molecular Aggregates" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi Chirality 2015, 27 (10), pp.659-666. DOI:10.1002/chir.22482 |
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"Perfluorinated gelators for solidifying fluorous solvents: effects of chain length and molecular chirality" *Tomoko Yajima, Erika Tabuchi, Emiko Nogami, Akihiko Yamagishi, *Hisako Sato RSC Adv. 2015, 5 pp.80542-80547. DOI:10.1039/C5RA12656H |
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"Stereochemical Investigation of the Products of the Photoinduced Perfluoroalkylation−Dimerization of Anthracene" Nogami, E.; Yamazaki, T.; Kubota, T.; *Yajima, T. J. Org. Chem. 2015, 80 pp.9208-9218. DOI:10.1021/acs.joc.5b01655 |
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"Facile synthetic protocols for perfluoroalkyl-substituteddiazapentaphenes" Shigeyuki Yamada, Shota Iwama, Keita Kinoshita, *Takashi Yamazaki, Toshio Kubota, Tomoko Yajima Tetrahedron 2014, 70 pp.6749-6756. DOI:10.1016/j.tet.2014.07.069 |
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"An Intermediate State in Gelation as Revealed by Vibrational Circular Dichroism Spectroscopy" *Hisako Sato, Tomoko Yajima, Akihiko Yamagishi RSC Adv. 2014, 4 (4), pp.25867-25870. DOI:10.1039/C4RA02526A |
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"Terminal Effects on Gelation by Low Molecular Weight Chiral Gelators" *Hisako Sato, Emiko Nogami, Tomoko Yajima, Akihiko Yamagishi RSC Adv. 2014, 4 (4), pp.1659-1665. DOI:10.1039/C3RA44070B |
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| Books |
「有機合成実験法ハンドブック 第二版」 有機合成化学協会 "フッ素化合物の合成法" Yamazaki, T.; Yajima, T. 丸善出版 (東京) 2015, pp1071-1098. ISBN:978-621-08948-4 |
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「フッ素化学入門2015」 独）日本学術振興会・フッ素化学第１５５委員会 "(R)-1-シクロヘキシル-2,2,2-トリフルオロエチルアミン" 矢島知子 他４８名 三共出版 (東京) 2015, pp235-237等. ISBN:978-4-7827-0727-2 |
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| Reviews / Accounts |
"ペルフルオロアルキル基を有するキラルα－アミノ酸の合成と応用" Yajima, T. オレオサイエンス 2015, 16 (3), pp.145-150. |
|
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "VCD
Application for Perfulorinated Gel Formation Mechanism" ○Sato, H.*; Sasaki, M., Tabuchi, , E.; Nogami, N.; Yajima, T.; Yamagishi, A. CD2015, Sapporo (Japan) 2015-08-30～2015-09-03 |
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口頭発表／ポスター発表 "Photoinduced
Radical Perfuloalkylation with Bromo Perfuloalkane Using Organocatalyst" ○Yajima, T.*; Ikegami, M.; Nogami, E. 21st ISFC & ISoFt ’15, Como (Italy) 2015-08-23～2015-08-28 |
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口頭発表／ポスター発表 "Synthesis
and crystallographic study of perfluoroalkylated naphtho[2,1-b:6,5-b']
dithiophene" ○Nogami, E.; Yajima, T.* Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Photoinduced radical perfluoroalkylation with bromo perfluoroalkane using acenes as catalysts" ○*Yajima, T.,; Ikegami, M.; Nishii, C.; Nogami, E. Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-22 |
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| Patent |
"含フッ素芳香族化合物およびその製造方法" 発明者：Yajima, T.; Yamamoto, K. 出願者：旭硝子株式会社 特願2012-033156 2012-02-17, 特許第5874744号 2016-05, (国外) |
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"ケイ素含有含フッ素化合物" 発明者：矢島知子、笹原佳奈、神原將、野口剛 出願者：お茶の水女子大学、ダイキン工業株式会社 特願2016-008651 2016-01-20, 2016-04, |
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"光学活性含フッ素アミン化合物の製造方法並びに光学活性含フッ素アミン化合物" 発明者：矢島知子、杉浦奈奈、香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2012-161056 2012-07-20, 特許第5902575号 2016-03-18, (国内) |
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"含フッ素化合物の製造法" 発明者：矢島知子.; 池上真子; 香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2016-008109 2016-01-19, 2016-04, |
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"含フッ素化合物の製造法" 発明者：矢島知子.; 池上真子; 香川巧 出願者：お茶の水女子大学、東ソー・エフテック株式会社 特願2015-179552 2015-09-11, 2016-04, (国内) |
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"エチレングリコール鎖とパーフルオロアルキレン鎖を主鎖骨格中に有するポリマー" 発明者：矢島知子、笹原佳奈、神原 將、辻本 伸幸 出願者：国立大学法人お茶の水女子大学、ダイキン工業株式会社 2015-03-10, 特願2015-047416 2015-05, (国内) |
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"光学活性含フッ素アミン化合物及びその製造方法" 発明者：矢島知子、佐野杏奈、香川巧 出願者：国立大学法人お茶の水女子大学、東ソー・エフテック株式会社 2015-01-28, 特願2015-014539 2015-05, (国内) |
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| A02 ユー ウージン | ||
| Original papers |
"Chelating Bis(1,2,3-triazole-5-ylidene) Rhodium Complexes: Versatile Catalysts for Hydrosilylation Reactions" Nguyen, T. V. Q.; Yoo, W.-J.; *Kobayashi, S. Adv. Synth. Catal. 2016, 358 (3), pp.452-458. |
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"Effective Formylation of Amines with Carbon Dioxide and Diphenylsilane Catalyzed by Chelating bis(tzNHC) Rhodium Complexes" Nguyen, T. V. Q.; Yoo, W.-J.; *Kobayashi, S. Angew. Chem. Int. Ed. 2015, 54 (32), pp.9209-9212. |
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"Visible Light-Mediated Ullmann-Type CN Coupling Reactions of Carbazole Derivatives and Aryl Iodides" Yoo, W.-J. ; Tsukamoto, T; * Kobayashi, S. Org. Lett. 2015, 17 (14), pp.3640-3642. |
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"Lithium tert-Butoxide-Mediated Carboxylation Reactions of Unprotected Indoles and Pyrroles with Carbon Dioxide" Yoo, W.-J.; Nguyen, T. V. Q.; Guiteras Capdevila, M.; *Kobayashi, S. Heterocycles 2015, 90 (2), pp.1196-1204. |
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"Visible-Light-Mediated Chan-Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives" Yoo, W.-J.; Tsukamoto, T.; *Kobayashi, S. Angew. Chem. Int. Ed. 2015, 54 (22), pp.6587-6590. |
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"Zinc(II) Hexachloroantimonate-Catalyzed Oxidative Allylation of Glycine Derivatives" Yoo, W.-J.; Tanoue, A.; *Kobayashi, S. Asian J. Org. Chem. 2014, 3 (10), pp.1066-1069. |
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"Synthesis of Isocoumarins through Three-Component Couplings of Arynes, Terminal Alkynes, and Carbon Dioxide Catalyzed by an NHC-Copper Complex" Yoo, W.-J.; Nguyen, T. V. Q.; *Kobayashi, S. Angew. Chem. Int. Ed. 2014, 53 (38), pp.10213-10217. |
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"Sulfuryl Chloride as an Efficient Initiator for Metal-Free Aerobic Cross-Dehydrogenative Coupling Reaction of Tertiary Amines" Tanoue, A.; Yoo, W.-J.; *Kobayashi, S. Org. Lett. 2014, 16 (9), pp.2346-2349. |
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"Efficient Visible Light-Mediated Cross-Dehydrogenative Coupling Reactions of Tertiary Amines Catalyzed by a Polymer-Immobilized Iridium-Based Photocatalyst" Yoo, W.-J.; *Kobayashi, S. Green Chem. 2014, 16 (5), pp.2438-2442. |
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| 分類 | 内容 | 共同研究者 |
|---|---|---|
| A03 岩渕 好治 | ||
| Original papers |
"
Total Synthesis of the Proposed Structure of
Turkiyenine " Kobayashi, H.; Sasano, Y.; Kanoh, N.; Kwon, E. *Iwabuchi, Y. Eur. J. Org. Chem. 2016, (2), pp.270-273. DOI:10.1002/ejoc.201501365 |
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"
Asymmetric Total Synthesis of Heronamides A-C:
Stereochemical Confirmation and Impact of LongrangeStereochemical Communication
of the Biological Activity " *Kanoh, N.; Itoh, S.; Fujita, K.; Sakanishi, K.; Sugiyama, R.; Terajima, Y.; Iwabuchi, Y.; Nishimura, S.; Kakeya, H. Chem. Eur. J. 2016, in press DOI:10.1002/chem.201600569 |
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|
"
Total Synthesis and Biological Evaluation of
Irciniastatin A (a.k.a. Psymberin) and Irciniastatin B"
Uesugi, S.; Watanabe, T.; Imaizumi, T.; Ota, Y.; Yoshida, K.; Ebisu, H.; Chinen, T.; Nagumo, Y.; Shibuya, M.; Kanoh, N.; Usui, T.; *Iwabuchi, Y. J. Org. Chem. 2016, 80 (24), pp.12333-12350. DOI:10.1021/acs.joc.5b02256 |
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|
"
An Enantiocontrolled Entry to the Tricyclic Polar
Segment of (+)-Fusarisetin A " Kohyama, A.; Kanoh, N.; Kwon, E.; *Iwabuchi, Y. Tetrahedron Lett. 2016, 57 (5), pp.517-519. DOI:10.1016/j.tetlet.2015.12.049 |
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|
"
Synthesis and Structure-activity Relationship Study
of FD-891: Importance of the Side Chain and C8-C9 Epoxide for Cytotoxic
Activity against Cancer Cells " Itagaki, T.; Kawamata, A.; Takeuchi, M.; Hamada, K.; Iwabuchi, Y.; Eguchi, T.; Kudo, F.;Usui, T.; *Kanoh, N. J. Antibiot. 2016, 69 (4), pp.287-293. DOI:10.1038/ja.2015.148 |
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"Third-Generation Photo-Cross-Linked Small-Molecule Affinity Matrix: A Photoactivatable and Photocleavable System Enabling Quantitative Analysis of the Photo-Cross-Linked Small Molecules and Their Target Purification" Suzuki, T.; Okamura, T.; Tomohiro, T.; Iwabuchi, Y.; *Kanoh, N. Bioconjugate Chem. 2015, 26 (3), pp.389-395. DOI:10.1021/bc500559e |
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"Highly Efficient Aerobic Oxidation of Alcohols Using Less-Hindered Nitroxyl-Radical/Copper Catalysis: Optimum Catalyst Combinations and Their Substrate Scope" Sasano, Y.; Kogure, N.; Nishiyama, T.; Nagasawa, S.; *Iwabuchi, Y. Chem. Asian J. 2015, 10 (4), pp.1004-1009. DOI:10.1021/asia.201403245 |
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"Development of Azanoradamantane-Type Nitroxyl Radical Catalyst for Class-SelectiveOxidation of Alcohols" Doi, R.; Shibuya, M.; Murayama, T.; Yamamoto, Y.; *Iwabuchi, Y. J. Org. Chem. 2015, 80 (1), pp.401-413. DOI:10.1021/jo502426p |
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"Highly Enantioselective Organocatalytic Oxidative Kinetic Resolution of Secondary Alcohols Using Chiral Alkoxyamines as Precatalysts: Catalyst Structure, Active Species, and Substrate Scope" Murakami, K.; Sasano, Y.; Tomizawa, M.; Shibuya, M.; Kwon, E.; *Iwabuchi, Y. J. Am. Chem. Soc. 2014, 136 (50), pp.17591-17600. DOI:10.1021/ja509766f |
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"Inhibition of b-Catenin and STAT3 with a Curcumin Analog Suppresses Gastric Cancerin vivo" Uehara, Y.; Inoue, M.; Fukuda, K.; Yamakoshi, H.; Hosoi, Y.; Kanda, H.; Oshima, M.; Iwabuchi, Y.; *Shibata, H. Gastric Cancer 2014, DOI:10.1007/s10120-014-0434-3 |
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"Mechanistic Insight into Aerobic Oxidation Using NOx-Nitroxide Catalysis Based on Catalyst-Activity Relationships" Shibuya, M.; Nagasawa, S.; Osada, Y.; *Iwabuchi, Y. J. Org. Chem. 2015, 79 (21), pp.10256-10268. DOI:10.1021/jo501826k |
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"A Concise and Unified Strategy for Synthesis of the C1-C18 Macrolactone Fragment of FD-891, FD-892 and Their Analogues: Formal Total Synthesis of FD-891" *Kanoh, N.; Kawamata, A.; Itagaki, T.; Miyazaki, Y.: Yahata, K.; Kwon, E.; Iwabuchi, Y. Org. Lett. 2015, 16 (19), pp.5216-5219. DOI:10.1021/ol502633j |
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"Eu(OTf)3-Catalyzed Highly Regioselective Nucleophilic Ring Opening of 2,3-epoxy Alcohols: An Efficient Entry to 3-Substituted 1,2-diol" Uesugi, S.; Watanabe, T.; Imaizumi, T.; Shibuya, M.; Kanoh, N.; Iwabuchi, Y. Org. Lett. 2014, 15 (17), pp.4408-4411. DOI:10.1021/ol502264y |
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"Highly Chemoselective Aerobic Oxidation of Amino Alcohols into Amino Carbonyl Compounds" Sasano, Y.; Nagasawa, S.; Yamazaki, M.; Shibuya, M.; Park, J. W.; *Iwabuchi, Y. Angew. Chem. Int. Ed. 2014, 53 (12), pp.3236-3240. |
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"Enantioselective Intramolecular Aza-Spiroannulation onto Benzofurans Using Chiral Rhodium Catalysis" Shibuta, T.; Sato, S.; Shibuya, M.; Kanoh, N.; Taniguchi, T.; Monde, K.; *Iwabuchi, Y. Heterocycles 2014, 89 (3), pp.631-639. |
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"Total Synthesis of the Proposed Structure of Heronamide C" Sakanishi, Y.; Ito, S.; Sugiyama, R.; Nishimura, S.; Kakeya, H.; Iwabuchi, Y.; *Kanoh, N. Eur. J. Org. Chem. 2014, (7), pp.1376-1380. |
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"An Improved Fluorogenic NAD(P)+ Detection Method Using 2-Acetylbenzofuran: Its Origin and Application" Moriya, T.; Kawamata, A.; Takahashi, Y.; Iwabuchi, Y.; *Kanoh, N. Chem. Commun. 2014, 49 (98), pp.11500-11502. |
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"3-Methyl-4-Oxa-5-Azahomoadamantane: Alkoxyamine-Type Organocatalyst for Alcohol Oxidation" Sasano, Y.; Murakami, K.; Nishiyama, T.; Kwon, E.; *Iwabuchi, Y. Angew. Chem. Int. Ed. 2013, 52 (25), pp.12624-12627. |
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|
"On the Origin of cine-Substitution in the Stille Coupling of Trisubstituted Iodoalkene and trans-Vinylstannane" *Kanoh, N.; Ohno, Y.; Itagaki, T.; Fukuda, H.; Iwabuchi, Y. Synlett 2013, pp.2660-2664. |
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"C-H Modification of 2-Azaadamantane: Synthesis of C5-Functionalized AZADOs for Advanced Use"
Sasano, Y.; Nishiyama, T.; Tomizawa, M.; Shibuya, M.; *Iwabuchi, Y. Heterocycles 2013, 87 (10), pp.2109-2118. |
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|
"
Concise Entry to Chiral
5-(4-Hydroxybutyl)-2(5H)-furanone via HIBT-Mediated Novel Oxidative
Fragmentation: Formal Total Synthesisi of (+)-Dubiusamine A
" Kawasumi, M.; *Iwabuchi, Y. Org. Lett. 2013, 14 pp.1788-1790. |
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|
"
Dual Structure-Activity
Relationship of Osteoclastogenesis Inhibitor Methyl Gerfelin Based on TEG
Scanning
" *Kanoh, N.; Suzuki, T.; Kawanami, M.; Katou, Y.; Osada, H.; *Iwabuchi, Y. Bioconjugate Chem. 2013, 24 pp.44-52. |
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|
"
Synthesis and
Structure-Activity Relationship of Vicenistatin, a Cytotoxic 20-Membered
Macrolactam Glycoside
" Fukuda, H.; Nishiyama, Y.; Nakamura, S.; Ohno, Y.; Eguchi, T.; Iwabuchi, Y.; *Kanoh, N Chem. Asian J. 2012, 7 pp.2872-2881. |
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"
Nitroxyl Radical/PhI(OAc)2:
One-pot Oxidative Cleavage of Vicinal Diols to (Di)carboxylic Acids
" Shibuya, M.; Shibuta, T.; Fukuda, H.; *Iwabuchi, Y. Org. Lett. 2012, 14 pp.5010-5013. |
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|
"
Organocatalytic One-pot
Oxidative Cleavage of Terminal Diols to Dehomologated Carboxylic Acids
" Shibuya, M.; Doi, R.; Shibuta, T.; Uesugi, S.; *Iwabuchi, Y. Org. Lett. 2012, 14 pp.5006-5009. |
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|
"Catalytic Oxidation of Silyl Enol Ethers to 1,2-Diketones Employing Nitroxyl Radicals" Hayashi, M.; Shibuya, M.; *Iwabuchi, Y. Synlett 2012, pp.1025-1031. |
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|
"
Oxidation of Alcohols to
Carbonyl Compounds with Diisopropyl Azodicarboxylate Catalyzed by Nitroxyl
Radicals
" Hayashi, M.; Shibuya, M.; *Iwabuchi, Y. J. Org. Chem. 2012, 77 pp.3005-3009. |
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|
"
Oxidation of Nitroxyl
Radicals: Electrochemical and Computational Studies
" Shibuya, M.; *Pichierri, F.; Tomizawa, M.; Nagasawa, S.; Suzuki, I.; *Iwabuchi,Y. Tetrahedron Lett. 2012, 53 pp.2070-2073. |
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|
"
Oxidative Conversion of Silyl
Enol Ethers to α,β-Unsaturated Ketones Employing Oxoammonium Salts
" Masaki, H.; Shibuya, M.; *Iwabuchi, Y. Org. Lett. 2012, 14 pp.154-157. |
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"9-Azanoradamantane N-Oxyl (Nor-AZADO): A Highly Active Organocatalyst for Alcohol Oxidation" Hayashi, M.; Sasano, Y.; Nagasawa, S.; Shibuya, M.; *Iwabuchi, Y. Chem. Pharm. Bull. 2011, 59 pp.1570-1573. |
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|
"
Practical Preparation Methods
for Highly Active Azaadamantane-nitroxyl-radical-type Oxidation catalysts
" Shibuya, M.; Sasano, Y.; Tomizawa, M., Hamada, T.; Kozawa, M.; Nagahama, N.; *Iwabuchi,Y. Synthesis 2011, pp.3418-3425. |
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|
"
Highly Efficient,
Organocatalytic Aerobic Alcohol Oxidation
"
Shibuya, M.; Osada, Y.;
Sasano, Y.; Tomizawa, M. *Iwabuchi, Y. J. Am. Chem. Soc. 2011, 113 pp.6497-6500. |
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|
"
Novel Curcumin Analogs,
GO-Y030 and GO-Y078, Are Multi-targeted Agents with Enhanced Abilities for
Multiple Myeloma
" Kudo, C.; Yamakoshi, H.; Sato, A.; Ohori, H.; Ishioka , C. Iwabuchi, Y.; *Shibata, H. Anticancer Res. 2011, 31 pp.3719-3726. |
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|
"
Detection of cytochrome P450
substrates using a small-molecule droplet array on an NADH-immobilized solid
surface
" Takayama, H.; Takahashi, S.; Moriya, T.; Osada, H.; Iwabuchi, Y.; *Kanoh, N. ChemBioChem 2011, 12 pp.2748-2752. |
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|
"High-Performance Liquid Chromatography with Photodiode Array Detection for Determination of Nobiletin Content in the Brain and Serum of Mice Administrated the Natural Compound" Saigusa, D.; Shibuya, M.; Jinno, D.; Yamakoshi, H.; Iwabuchi, Y.; Yokosuka, A.; Mimaki, Y.; Nganuma, A.; Ohizumi, Y.; Tomioka, Y.; *Yamaguni, T. Anal. Bioanal. Chem. 2011, 400 pp.3635-3641. |
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|
"
Targeting Colon Cancer Stem
Cells Using a New Curcumin Analogue, GO-Y030
" Lin, L.; Liu, Y.; Li, P-K.; Fuchs, J.; Shibata, H.; Iwabuchi, Y.; *Lin, J. British J. Cancer 2011, 105 pp.212-220. |
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|
"
Synthesis of 86 Species of
1,5-Diaryl-3-oxo-1,4-pentadienes Analogs of Curcumin can Yield a Good Lead in
Vivo
" Kudo, C.; Yamakoshi, H.; Sato, A.; Nanjo, H.; Ohori, H.; Ishioka, C.; Iwabuchi, Y.; *Shibata, H. BMC Pharmacology 2011, 11 pp.4. |
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|
"
Concise Entry to Both
Enatiomers of 8-Oxabicyclo[3.2.1]oct-3-en-2-one Based on Novel Oxidative
Etherification: Formal Synthesis of (+)-Sundiversifolide
" Kawasumi, M.; Kanoh, N.; *Iwabuchi, Y. Org. Lett. 2011, 13 pp.3620-3623. |
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|
"
Asymmetric Total Syhthesis of
(-)-Scabronine G via Intramolecular Double Michael Reaction and Prins
Cyclization
" *Kanoh,N.; Sakanishi, K.; Iimori, E.; Nishimura, S.; *Iwabuchi, Y. Org. Lett. 2011, 13 pp.2864-2867. |
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|
"
Curcumin Analog GO-Y030 is a Novel
Inhibitor of IKKβThat Suppresses NF-κB Signaling
and Induces Apoptosis
" Sato, A.; Kudo, C.; Yamakoshi, H.; Uehara, Y.; Ohori, H.; Ishioka, C.; Iwabuchi, Y.; *Shibata, H. Cancer Sci. 2011, 102 pp.1045-1051. |
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| Books |
「トップドラッグから学ぶ創薬化学」 有機合成化学協会 "複素環合成" 岩渕 好治 東京化学同人 (東京) 2013, pp179-192. ISBN:978-4-8079-0776-2 |
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「トップドラッグから学ぶ創薬化学」 有機合成化学協会 "TEMPO酸化" 岩渕 好治 東京化学同人 (東京) 2012, pp164-164. ISBN:978-4-8079-0776-2 |
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「トップドラッグから学ぶ創薬化学」 有機合成化学協会 "消化性潰瘍治療薬" 岩渕 好治 東京化学同人 (東京) 2012, pp48-52. ISBN:978-4-8079-0776-2 |
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「トップドラッグから学ぶ創薬化学」 有機合成化学協会 "PPARγ作動薬とα-グルコシダーゼ阻害薬" 岩渕 好治 東京化学同人 (東京) 2012, pp40-47. ISBN:978-4-8079-0776-2 |
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「トップドラッグから学ぶ創薬化学」 有機合成化学協会 "脂質異常賞治療薬ーHMG-CoA還元酵素阻害薬" 岩渕 好治 東京化学同人 (東京) 2012, pp34-39. ISBN:978-4-8079-0776-2 |
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「天然物合成で活躍した反応 実験のコツとポイント」 有機合成化学協会 "AZADO酸化" Iwabuchi, Y.; Shibuya, M. 化学同人 (京都) 2013, pp120-12. ISBN:978-4-7598-1479-8 |
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| Reviews / Accounts |
"高活性第１級アルコール酸化触媒：DMN-AZADO" 澁谷正俊、*岩渕好治 和光純薬時報 2016, 84 (1), pp.8-11. |
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"新薬開発を支える化学" 岩渕好治 化学と教育 2013, 43 (6), pp.518-521. |
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"新規高活性アルコール酸化触媒Nor-AZADOの有用性" 岩渕好治 Organic Square 2013, 45 pp.1-4. |
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|
"AZADO酸化：実用的な触媒的アルコール酸化反応" 岩渕好治 ファインケミカル 2014, 43 (6), pp.41-48. |
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|
"Discovery and Exploitation of AZADO: The Highly Active Catatalyst for Alcohol Oxidation" *Iwabuchi, Y. Chem. Pharm. Bull. 2013, 61 (12), pp.1197-1213. |
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|
"
Development of Simple and
Highly Efficient Aerobic Oxidation Method by Tuning Electrochemical and Steric
Properties of Nitroxyl Radical Catalysts
"
*Shibuya, M.; *Iwabuchi, Y. J. Synth. Org. Chem. Jpn 2013, 71 pp.515-525. |
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|
"
化学実験室における危機管理：M9.0巨大地震からの教訓
" *岩渕 好治 Med. Chem. News 2012, 22 pp.31-34. |
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"クリックケミストリー：世界を変える素反応" *岩渕 好治 ファルマシア 2012, 48 (7), pp.633-638. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "
Highly chemoselective aerobic oxidation of amino
alcohols into amino carbonyl compounds using AZADO/copper catalysis " ○ Sasano, Y.; Nagasawa, S.; Kogure, N.; Yamazaki, M.; Park, J.; *Iwabuchi, Y. Pacifichem 2015, Honoiulu (U.S.A.) 2016-12-15～2016-12-20 |
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口頭発表／ポスター発表 "
Aerobic Alcohol Oxidation Using AZADOs_NOx Catalysis " ○ Nagasawa, S.; Osada, Y.; Sasano, Y.; Shibuya, M.; *Iwabuchi, Y.Pacifichem 2015, Honoiulu (U.S.A.) 2016-12-15～2016-12-20 |
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招待講演 "
AZADO-CuCl/bpy/DMAP-Air Enables Highly
Chemoselective and Efficient Alcohol Oxidation " ○ *Iwabuchi, Y. The 10th International Conference On Cutting-Edge Organic Chemistry in Asia/The 1th Advanced Research Network On Cutting-Edge Organic Chemistry in Asia, Kaohsiung (Taiwan) 2016-11-02～2016-11-05 |
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招待講演 "
Discovery of Alkoxyamine-type Precatalysts for
Alcohol Oxidation " ○*Iwabuchi, Y. The 6th Japanese-Sino Smposium on Organic Chemistry for Young Scientists, 仙台 (日本) 2016-09-06～2016-09-09 |
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招待講演 "
Discovery of a Novel Alkoxyamine-type Precatalyst
for Alcohol Oxidation " ○ *Iwabuchi, Y. Kick-off Symposium on Advanced Research Network for Cutting- Edge Organic Chemistry in Asia, 仙台 (日本) 2015-08-25～2015-08-26 |
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招待講演 "
Discovery of 4-oxa-5-azahomoadamantanes: Novel alkoxyamine-type precatalysts for alcohol oxidation " ○ *Iwabuchi, Y.The 39th Naito Conference, 札幌 (日本) 2016-07-06～2016-07-09 |
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口頭発表／ポスター発表 "
Highly Efficient and Chemoselective Aerobic Oxidation of Alcohols Using AZADO-Copper Catalysis " ○ Nagasawa, S.; Sasano, Y.; Kogure, N.; Shibuya, M.; *Iwabuchi, Y.The 3rd International Symposium on Process Chemistry, 京都 (日本) 2016-07-13～2016-07-15 |
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口頭発表／ポスター発表 "
Optimized Conditions for the Aerobic Alcohol Oxidation Using Nitroxyl Radical/Copper Catalysis " ○ Kogure, M.; Sasano, Y.; Nishiyama, T.; Nagasawa, S.; *Iwabuchi. Y.The 3rd International Symposium on Process Chemistry, 京都 (日本) 2015-07-13～2015-07-15 |
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招待講演 "Aerobic Alcohol Oxidation using Nitroxyl Radical-NOx Catalysis" ○*Iwabuchi, Y. International Symposium on Activation of Dioxygen & Homogeneous Oxidation Catalysis, Madison (USA) 2015-06-21～2015-06-25 |
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招待講演 "Development of AZADO: The highly active organocatalyst for alcohol oxidation" ○*Iwabuchi, Y. The 24th French-Japanese Symposium on Medicinal and Fine Chemistry, Lyon (France) 2014-09-14～2014-09-17 |
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招待講演 "Organocatalytic Aerobic Oxidation of Alcohols" *Iwabuchi, Y. Advanced Molecular Transformations by Organocatalysts, First International Conference, Otsu (Japan) 2013-05-27～2013-05-28 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Mahidol University, Bangkok (Thailand) 2013-03-07～2013-03-07 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Chulalongkorn University, Bangkok (Thailand) 2013-03-06～2013-03-06 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Kastsart University, Bangkok (Thailand) 2013-03-05～2013-03-05 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Chulabhorn Research Institute, Bangkok (Thailand) 2013-03-04～2013-03-04 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Shanghai Institute of Organic Chemistry, Shanghai (China) 2012-12-27～2012-12-27 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Shanghai Institute of Materia Medica, Shanghai (China) 2012-12-26～2012-12-26 |
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受賞講演 "
Discovery of AZADOs: The Highly Active
Organocatalyts for Alcohol Oxidation
" *Iwabuchi, Y. Department Seminar at Nanjing University, Nanjing (China) 2012-12-25～2012-12-25 |
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受賞講演 "Discovery of AZADOs: The Highly Active Organocatalysts for Alcohol Oxidation" *Iwabuchi, Y. Department Seminar at University Science and Technology of China, Hefei (China) 2012-12-24～2013-06-13 |
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招待講演 "
Organocatalytic Synthesis of Chiral Cycloheptanoid
Building Blocks
" *Iwabuchi, Y. First Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-16～2012-12-18 |
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口頭発表／ポスター発表 "
Some
Useful Oxidative Transformations Offered by AZADOs
" *Iwabuchi, Y. ICCEOCA-7, Singapore (Singapore) 2012-12-11～2012-12-15 |
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招待講演 "The Discovery of AZADOs: The Highly Active Organocatalysts fof Alcohol Oxidation" *Iwabuchi, Y. The 6th Takeda Science Foundation Symposium on PharmaSciences “How Fascinating the Synthetic Organic Chemistry is!”, Osaka (Japan) 2012-09-13～2012-09-14 |
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招待講演 "Enantioselective Oxidative Kinetic Resolution of Racemic Secondary Alcohols using Chirally Modified AZADOs" *Iwabuchi, Y. 1st Germany-Japan Organocatalytic Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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| Patent |
"Method for oxidizing alcohols" 発明者：Iwabuchi, Y.; Hayashi, M. 出願者：Daiichi Sankyo Co. Ltd.; Tohoku University WO 2011-JP623214 2011-11-30, WO 2012008228 2012-01-19, (国外) |
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"Preparation of aldehydes, ketones, and/or carboxylic acids by oxidation of alcohols in the presence of azapolycyclic N-oxyls" 発明者：Iwabuchi, Y.; Shibuya, M.; Osada, Y. 出願者：Nissan Chemical Industries, Ltd., Tohoku Univeristy 2012-06, JP 2011153076 WO 2009145323 2011-08-11, (国内) |
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| Prize |
"日本薬学会学術振興賞" 岩渕 好治 2012-03 公益社団法人 日本薬学会 高活性アルコール酸化触媒AZADOの発見と展開 |
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"Asian Core Program Lectureship Award (China)" 岩渕 好治 2011-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Concise Synthesis of a Chiral Cycloheptanoid Building Block based on Novel Oxidative Etherification |
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"Asian Core Program Lectureship Award (Thailand)" *Iwabuchi, Y. 2011-12 New Phase Asian Core Program On Cutting-Edge Organic Chemistry in Asia Concise Synthesis of a Chiral Cycloheptanoid Building Block based on Novel Oxidative Etherification |
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| A03 砂塚 敏明 | ||
| Original papers |
" Organocatalytic Site-Selective Acylation of Avermectin B2a, a Unique Endectocidal Drug " Takeshi Yamada, Koh Suzuki, Tomoyasu Hirose, Takumi Furuta, Yoshihiro Ueda, Takeo Kawabata, Satoshi Ōmura and Toshiaki SunazukaChem. Pharm. Bull. 2016, in press DOI:http://doi.org/10.1248/cpb.c16-00205 |
Takeo Kawabata |
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" Organocatalytic Site-Selective Acylation of 10-Deacetylbaccatin III " Masanori Yanagi, Ryo Ninomiya, Yoshihiro Ueda, Takumi Furuta, Takeshi Yamada, Toshiaki Sunazuka and Takeo Kawabata Chem. Pharm. Bull. 2016, in press |
Takeo Kawabata | |
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" Towards the total synthesis of the anti-trypanosomal macrolide, Actinoallolides; construction of a key linear intermediate " Jun Oshita, Yoshihiko Noguchi, Akito Watanabe, Goh Sennari, Shogo Sato, Tomoyasu Hirose, Daiki Oikawa, Yuki Inahashi, Masato Iwatsuki, Aki Ishiyama, Satoshi Ōmura and Toshiaki SunazukaTetrahedron Lett. 2016, 57 pp.357-360. |
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" Macrolides sensitize EGFR-TKI-induced non-apoptotic cell death via blocking autophagy flux in pancreatic cancer cell lines. " Shuntaro Mukai, Shota Moriya, Masaki Hiramoto, Hiromi Kazama, Hiroko Kokuba, Xiao-Fang Che, Tomohisa Yokoyama, Satoshi Sakamoto, Akihiro Sugawara, Toshiaki Sunazuka, Satoshi Ōmura, Hiroshi Handa, Takao Itoi and Keisuke Miyazawa Int. J. Clin. Oncol. 2016, 48 pp.45-54. |
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" In situ Click Chemistry for the Identification of a Potent D-Amino Acid Oxidase Inhibitor " Shohei Toguchi, Tomoyasu Hirose, Kazuko Yorita, Kiyoshi Fukui, K. Barry Sharpless, Satoshi Ōmura, Toshiaki SunazukaChem. Pharm. Bull. 2015, in press |
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" The non-antibiotic macrolide EM900 inhibits rhinovirus infection and cytokine production in human airway epithelial cells "Nadine Lusamba Kalonji, Kazuhiro Nomura, Tetsuaki Kawase, Chiharu Ota, Hiroshi Kubo, Takeya Sato, Teruyuki Yanagisawa, Toshiaki Sunazuka, Satoshi Ōmura and Mutsuo Yamaya Physiological Reports 2015, 3 pp.e12557. |
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" Non-antibiotic 12-membered macrolides: design, synthesis and biological evaluation in a cigarette-smoking model. "Sugawara, A; Shima, H; Sueki, A; Hirose, T; Matsui, H; Nakano, H; Hanaki, H; Akagawa, S. K; Ōmura, S and *Sunazuka T J. Antibiot. 2015, in press DOI:10.1038/ja.2015.91. |
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" Asymmetric Total Synthesis of Indole Alkaloids Containing An Indoline Spiroaminal Framework. " Takeshi Yamada, Tetsuya Ideguchi-Matsushita, Tomoyasu Hirose, Tatsuya Shirahata, Rei Hokari, Aki Ishiyama, Masato Iwatsuki, Akihiro Sugawara, Yoshinori Kobayashi, Kazuhiko Otoguro, Satoshi Ōmura and *Toshiaki SunazukaChem. Eur. J. 2015, 21 pp.11855-11864. |
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" Creation of customised bioactivity within a 14-membered macrolide scaffold: design, synthesis, and biological evaluation using a family-18 chitinase. " Akihiro Sugawara, Nobuo Maita, Hiroaki Gouda, Tsuyoshi Yamamoto, Tomoyasu Hirose, Saori Kimura, Yoshifumi Saito, Hayato Nakano, Takako Kasai, Hirofumi Nakano, Kazuro Shiomi, Shuichi Hirono, Takeshi Watanabe, Hisaaki Taniguchi, Satoshi Ōmura and Toshiaki SunazukaJ. Med. Chem. 2015, 58 pp.4984-4997. |
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" Macrolides promote CCL2-mediated macrophage recruitment and clearance of nasopharyngeal pneumococcal colonies in mice. "Naoki Iwanaga, Shigeki Nakamura, Kazuhiro Oshima, Toshiki Kajihara, Takahiro Takazono, Taiga Miyazaki, Koichi Izumikawa, Katsunori Yanagihara, Akihiro Sugawara, Toshiaki Sunazuka, Satoshi Ōmura and Shigeru Kohno J. Infect. Dis 2015, 212 pp.1150-1159. |
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" Anti-inflammatory effects of a novel non-antibiotic macrolide, EM900, on mucus secretion of airway epithelium. "Ichiro Tojima, Shino Shimizu, Takao Ogawa, Hideaki Kouzaki, Satoshi Ōmura, Toshiaki Sunazuka and Takeshi Shimizu Auris Nasus Larynx 2015, 2015 (42), pp.332-336. |
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"An architectonic macrolide library based on a C2-symmetric macrodiolide toward pharmaceutical compositions" Nakano, H.; Sugawara, A.; Hirose, T.; Gouda, H.; Hirono, *S.; Ōmura, S. and *Sunazuka, T. Tetrahedron 2015, in press |
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"Cinatrins D and E, and virgaricin B, three novel compounds produced by a fungus, Virgaria boninensis FKI-4958" Ishii, T.; Nonaka, K.; Sugawara, A.; Iwatsuki, M.; Masuma, R.; Hirose, T.; Sunazuka, T.; Omura, S. and *Shiomi, K. J. Antibiot. 2015, in press |
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"Jietacins with potent nematocidal activity; efficient isolation of novel analogues and divergent total synthesis of jietacin A, B, C, and D" Sugawara, A.; Kubo, M.; Nakashima, T.; Hirose, T.; Tsunoda, N.; Yahagi, K.; Asami, Y.; Yamada, T.; Shiomi, K.; Takahashi, Y.; Ōmura, S.; Sunazuka, T. Tetrahedron 2015, 71 pp.2149-2157. |
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"Actinoallolides A–E, New Anti-trypanosomal Macrolides, Produced by an Endophytic Actinomycete, Actinoallomurus fulvus MK10-036" Inahashi, Y.; Iwatsuki, M.; Ishiyama, A.; Matsumoto, A.; Hirose, T.; Oshita, J.; Sunazuka, T.; Panbangred, W.; Takahashi, Y.; Kaiser, M.; Otoguro, K. and *Omura, S. Org. Lett. 2015, pp.864-867. |
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"Organocatalytic α-Addition of Isocyanides to Aldehydes" Yamada, T.; Hirose, T.; *Omura, S. and *Sunazuka, T. Eur. J. Org. Chem. 2015, pp.296-301. |
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"A concise total synthesis of puberulic acid, a potent antimalarial agent" Sennari, G.; Hirose, T.; Iwatsuki, M.; *Ōmura, S. and *Sunazuka, T Chem. Commun. 2014, 50 pp.8715-8718. DOI:10.1039/C4CC03134B |
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"Leucomycin A3, a 16-membered macrolide antibiotic, inhibits influenza A virus infection and disease progression" Sugamata, R.; Sugawara, A.; Nagao, T.; Suzuki, K.; Hirose, T.; Yamamoto, K.; Oshima, M.; Kobayashi, K.; Sunazuka, T.; Akagawa, K. S.; Ōmura, S.; Nakayama, T. and *Suzuki, K. J. Antibiot. 2014, 67 pp.213-222. DOI:10.1038/ja.2013.132 |
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"Observation of the controlled assembly of preclick components in the in situ click Chemistry generation of a chitinase inhibitor" Hirose, T.; Maita, N.; Gouda, H.; Koseki, J.; Yamamoto, T.; Sugawara, A.; Nakano, H.; Hirono, S.; Shiomi, K.; Watanabe, T.; Taniguchi, H.; Sharpless, K. B.; *Ōmura, S. and *Sunazuka, T. Proc. Natl. Acad. Sci. USA 2013, 110 pp.15892-15897. DOI:10.1073/pnas.1315049110 |
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"Asymmetric Total Synthesis of Neoxaline" Ideguchi, T.; Yamada, T.; Shirahata, T.; Hirose, T.; Sugawara, A.; Kobayashi, Y.; *Omura, S. and *Sunazuka, T. J. Am. Chem. Soc. 2013, 135 pp.12568-12571. |
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"Determination and total synthesis of (+)-16-hydroxy-16,22-dihydroapparicine" Hirose, T.; Noguchi, Y.; Furuya, Y.; Ishiyama, A.; Iwatsuki, M.; Otoguro, K.; *Omura, S.; *Sunazuka, T. Chem. Eur. J. 2013, in press DOI:10.1002/chem.201300292 |
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"Human acidic mammalian chitinase as a novel target for anti-asthma drug design using in silico screening" Wakasugi, M.; Gouda, H.; Hirose, T.; Sugawara, A.; Yamamoto, T.; Shiomi, K.; Sunazuka, T.; Omura, S.; *Hirono, S. Bioorg. Med. Chem. 2013, 21 (11), pp.3214-3220. DOI:10.1016/j.bmc.2013.03.047 |
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" Borrelidin analogues with antimalarial activity: design, synthesis and biological evaluation against Plasmodium falciparum parasites "Sugawara, A.; Tanaka, T.; Hirose, T.; Ishiyama, A.; Takahashi, Y.; Otoguro, K.; *Omura, S.; *Sunazuka, T. Bioorg. Med. Chem. Lett. 2013, 23 pp.2302-2305. DOI:10.1016/j.bmcl.2013.02.075 |
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" EM, EM703 inhibit NF-kB activation induced by oxidative stress from diesel exhaust particle in human bronchial epithelial cells: Importance in IL-8 transcription "Li, YJ.; Shimizu, T.; Hirata, Y.; Inagaki, H.; Takizawa, H.; Azuma, A.; Kawada, T.; Sugawara, I.; Kudoh, S.; Sunazuka, T.; Omura, S. Pulm. Pharmacol. Ther. 2013, 26 (3), pp.318-324. DOI:10.1016/j.pupt.2012.12.010 |
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" Antimalarial C-9 oxime derivatives from desmycosin, produced by click chemistry "Tsutsui, A.; Hirose, T.; Ishiyama, A.; Iwatsuki, M.; Yokota, A.; Maruyama, H.; Matsui, H.; Otoguro, K.; Hanaki, H.; *Omura, S.; *Sunazuka T. J. Antibiot. 2013, 66 pp.191-194. DOI:10.1038/ja.2012.113 |
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" Wickerols A and B: novel anti-influenza virus diterpenes produced by Trichoderma atroviride FKI-3849 "Yamamoto, T.; Izumi, N.; Ui, H.; Sueki, A.; Masuma, R.; Nonaka, K.; Hirose, T.; Sunazuka, T.; Nagai, T.; Yamada, H.; Omura, S.; *Shiomi K. Tetrahedron 2012, 68 (45), pp.9267-9271. DOI:10.1016/j.tet.2012.08.066 |
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" Novel 12-membered non-antibiotic macrolides, EM900 series with anti-inflammatory and/or immunomodulatory activity; synthesis, structure–activity relationships and in vivo study "Sugawara, A.; Sueki, A.; Hirose, T.; Shima, H.; Akagawa, K.S.; *Ōmura, S.; *Sunazuka T. J. Antibiot. 2012, 65 pp.487-490. DOI:10.1038/ja.2012.51 |
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" Makomotindoline from Makomotake, Zizania latifolia infected with Ustilago esculenta "Suzuki, T.; Choi, J-H.; Kawaguchi, T.; Yamashita, K.; Morita, A.; Hirai, H.; Nagai, K.; Hirose, T.; Omura, S.; Sunazuka, T.; *Kawagishi, H. Bioorg. Med. Chem. Lett. 2012, 22 (13), pp.4246-4248. DOI:10.1016/j.bmcl.2012.05.021 |
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" Toward the total synthesis of Luminamicin: construction of 14-membered lactone framework possessing versatile enol ether moiety "Kimishima, A.; Hirose, T.; Sugawara, A.; Matsumaru, T.; Nakamura, K.; Katsuyama, K.; Toda, M.; Takada, H.; Masuma, R.; *Ōmura, S.; *Sunazuka, T. Tetrahedron Lett. 2012, 53 (23), pp.2813-2816. DOI:10.1016/j.tetlet.2012.03.098 |
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" Three-dimensional solution structure of bottromycin A2: a potent antibiotic active against methicillin-resistant Staphylococcus aureus and vancomycin-resistant Enterococci. "Gouda, H.; Kobayashi, Y.; Yamada, T.; Ideguchi, T.; Sugawara, A.; Hirose, T.; Omura, S.; Sunazuka, T.; *Hirono, S. Chem. Pharm. Bull. 2012, 60 (2), pp.169-171. DOI:10.1248/cpb.60.169 |
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"The first total synthesis and reassignment of the relative stereochemistry of 16-hydroxy-16,22-dihydroapparicine" Noguchi, Y.; Hirose, T.; Furuya, Y.; Ishiyama, A.; Otoguro, K.; *Omura, S.; *Sunazuka, T. Tetrahedron Lett. 2012, 53 (14), pp.1802-1807. DOI:10.1016/j.tetlet.2012.01.110 |
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"Effects of a Novel Nonantibiotic Macrolide, EM900, on Cytokine and Mucin Gene Expression in a Human Airway Epithelial Cell Line" Otsu, K.; Ishinaga, H.; Suzuki, S.; Sugawara, A.; Sunazuka, T.; Ōmura, S.; Jono, H.; *Takeuchi, K. Pharmacology 2011, 88 pp.327-332. DOI:10.1159/000334339 |
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"Sequential one-pot glycosylation with glycosyl N-trichloroacetylcarbamate and trichloroacetate including dehydrative approach using 1-hydroxy sugars" Shirahata, T.; Kojima, A.; Teruya, S.; Matsuo, J.; Yokoyama, M.; Unagiike, S.; Sunazuka, T.; Makino, K.; Kaji, E.; *Ōmura, S.; *Kobayashi, Y. Tetrahedron 2011, 67 (35), pp.6482-6496. DOI:10.1016/j.tet.2011.06.006 |
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"Isolation, Total Synthesis and Determination of the Absolute Configuration of Guadinomines; Potent Inhibitors of a Bacterial Type III Secretion System" Hirose, T.; Iwatsuki, M.; *Ōmura, S.; *Sunazuka, T. J. Soc. Org. Chem. Jpn. 2011, 69 pp.775-788. DOI:10.5059/yukigoseikyokaishi.69.775 |
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"Solution-phase total synthesis of the hydrophilic natural product argifin using 3,4,5-tris(octadecyloxy)benzyl tag" Hirose, T.; Kasai, T.; Akimoto, T.; Endo, A.; Sugawara, A.; Nagasawa, K.; Shiomi, K.; *Ōmura, S.; *Sunazuka, T. Tetrahedron 2011, 67 (35), pp.6633-6643. DOI:10.1016/j.tet.2011.05.073 |
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"Novel 12-membered non-antibiotic macrolides from erythromycin A; EM900 series as novel leads for anti-inflammatory and/or immunomodulatory agents" Sugawara, A.; Sueki, A.; Hirose, T.; Shima, H.; Akagawa, K. S.; *Ōmura, S.; *Sunazuka, T. Bioorg. & Med. Chem. Lett. 2011, 21 (11), pp.3373-3376. DOI:10.1016/j.bmcl.2011.04.004 |
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"Spoxazomicins A-C, novel antitrypanosomal alkaloids produced by an endophytic actinomycete, Streptosporangium oxazolinicum K07-0460(T)" Inahashi, Y.; Iwatsuki, M.; Ishiyama, A.; Namatame, M.; Nishihara-Tsukashima, A.; Matsumoto, A.; Hirose, T.; Sunazuka, T.; Yamada, H.; Otoguro, K.; Takahashi, Y.; *Ōmura, S.; *Shiomi, K. J. Antibiot. 2011, 64 pp.303-307. DOI:10.1038/ja.2011.16 |
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"Borrelidin, a potent antimalarial: stage-specific inhibition profile of synchronized cultures of Plasmodium falciparum" Ishiyama, A.; Iwatsuki, M.; Namatame, M.; Nishihara-Tsukashima, A.; Sunazuka, T.; Takahashi, Y.; *Ōmura, S.; *Otoguro, K. J. Antibiotics 2011, 64 pp.381-384. DOI:10.1038/ja.2011.6 |
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| Reviews / Accounts |
" マクロライドをはじめとする微生物由来生物活性天然物の合成研究と創薬展開 "砂塚敏明 有機合成化学協会誌 2012, 70 (7), |
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"微生物由来生物活性天然物の合成と創薬への展開" *砂塚敏明 化学と工業 2011, 62 pp.621-627. |
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| Conference / Symposium / Lecture |
招待講演 " Development of organocatalyst and its application toward the synthesis of bioactive natural product " Takeshi Yamada; Tomoyasu Hirose; Satoshi Ōmura and Toshiaki SunazukaPacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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招待講演 " Isolation and total synthesis of microbial natural products "〇Sunazuka, T. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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招待講演 " Drug discovery based on microbial bioactive natural products "〇Sunazuka, T. Pacifichem 2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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招待講演 "" 〇Sunazuka, T. Symposium in Honor of Professor Amos B. Smith, III; The Recipient of the 2015 Allan R. Day Award, Philadelphia (USA) 2015-10-17～2015-10-17 |
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招待講演 "Total Synthesis of Novel Polycyclic Biological Active Indole Alkaloids" 〇Sunazuka, T. The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, 仙台 (日本) 2015-09-08～2015-09-08 |
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招待講演 " Total synthesis of unique polycyclic bioactive indole alkaloids "〇Sunazuka, T. 16th Tetrahedron Symposium, Berlin (Germany) 2015-06-18～2015-06-18 |
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招待講演 "Practical synthesis of bioactive natural products using organocatalysts" ○Sunazuka, T. 第２回国際会議（兼）第７回有機触媒シンポジウム, 東京 (日本) 2014-11-21～2014-11-22 |
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招待講演 "天然有機化合物を基盤とした新しい創薬研究" ○砂塚敏明 第２９回農薬デザイン研究会, 熱海市 (日本) 2014-11-06～2014-11-07 |
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招待講演 "創薬のための天然物化学と有機合成化学の連携" ○砂塚敏明 第４９回天然物化学談話会, 倉敷市 (日本) 2014-07-02～2015-07-04 |
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招待講演 "多環式含窒素生物活性天然物の効率的な分子骨格構築法の開発と全合成" ○砂塚敏明 第９回有機合成化学のフロンティア, 和光市 (日本) 2014-06-27～2014-06-27 |
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招待講演 "Harmonization between natural products and organic synthesis for drug discovery" ○Sunazuka, T. International conference on engineering science and technology, Beijing (China) 2014-06-02～2014-06-03 |
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招待講演 "Isolation and total synthesis of novel polycyclic biologically active indole alkaloids" ○Sunazuka, T. University of Pennsylvenia (USA) 2014-01-10～2014-01-10 |
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招待講演 "Isolation and total synthesis of novel polycyclic biologically active indole alkaloids" ○Sunazuka, T. The Mona Symposium (2014), Mona (Jamaica) 2014-01-06～2014-01-09 |
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招待講演 "Total synthesis of novel polycyclic bioactive indole alkaloids" ○Sunazuka, T. Gordon Research Conference, Newport (USA) 2013-06-16～2013-06-21 |
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招待講演 "Practical synthesis of bioactive natural products by organocatalysts" ○砂塚敏明 第一回国際会議（兼）第六回有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
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招待講演 "Total synthesis of novel polycyclic bioactive indole alkaloid" ○Sunazuka, T. 12th International Conference on the Chemistry of Antibiotics and other Bioactive, Berlin (Germany) 2011-09-11～2011-09-14 |
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招待講演 "Total synthesis of novel polycyclic bioactive indole alkaloids" ○Sunazuka, T. 14th Asian Chemical Congress 2011 (14 ACC), Bangkok (Thailand) 2011-09-05～2011-09-08 |
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| A03 長澤 和夫 | ||
| Original papers |
"Synthesis of diasteromers of 1,3-cis-25-dihydroxy-19-norvitamin D3" Usuda, K.; Biswas, T.; Yamaguchi, T.; Akagi, Y.; Yasui, K.; Uesugi, M.; Shimizu, I.; Hosokawa, S.; *Nagasawa, K. Chem. Pharm. Bull. 2016, accepted |
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"Design and synthesis of unsymmetric macrocyclic hexaoxazole compounds with ability to induce distinct G-quadruplex topologies in telomeric DNA" Sakuma, M.; Ma, Y.; Tsushima, Y.; Iida, K.; Hirokawa, T.; *Nagasawa, K. Org. Biomol. Chem. 2016, accepted DOI:10.1039/C6OB00437G |
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" Asymmetric α-amination of β-keto esters using guanidine-bisurea bifunctional organocatalyst " Odagi, M.; Yamamoto, Y.; *Nagasawa, K.Beilstein J. Org. Chem. 2016, (12), pp.198-203. DOI:10.3762/bjoc.12.22 |
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"Biosynthetic route towards saxitoxin and shunt pathway" Tsuchiya, S.; Cho, Y.; Konoki, K.; Nagasawa, K.; Oshima, Y.; *Yotsu-Yamashita, M. Science Report 2016, (Article number 20340), DOI:10.1038/srep20340 |
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"Synthesis of (+)-trans-dihydrolycoridine using orgacocatalytic enantioselective Friedel-Crafts reaction" Kato, M.; Yasui, K.; Yamanaka, M.; *Nagasawa, K. Asian J. Org. Chem. 2016, (5), pp.380-388. DOI:10.1002/ajoc.201500469 |
Yamanaka, M. | |
|
" Synthetic Studies of Oroidin-derived Pyrrole-imidazole Alkaloids " Iwata, M.; Kamijoh, Y.; *Nagasawa, K.J. Synth. Org. Chem., Japan 2015, (73), pp.1092-1098. DOI:10.5059/yukigoseikyokaishi.73.1092 |
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"Design, Synthesis and Evaluation of an L-Dopa-Derived Macrocyclic Hexaoxazole (6OTD) as a G-Quadruplex-Selective Ligand" Nakamura, T.; Ma, Y.; Iida, K.; Ohtake, T.; Seimiya, H.; *Nagasawa, K. Heterocycles 2015, (92), pp.305-315. DOI:10.3987/COM-15-13383 |
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|
"Entropy-driven 1,2-Type Friedel-Crafts Reaction of Phenols with N-Boc Aldimines" Kato, M.; Hirao, S.; Nakano, K.; Sato, M.; Yamanaka, M.; Sohtome, Y.; *Nagasawa, K. Chem. Eur. J. 2015, (21), pp.18606-18612. DOI:10.1002/chem.201503280 |
Yamanaka, M. | |
|
" Rif1 binds to G-quadruplex and suppresses replication over a long distance " Kanoh, Y.; Matsumoto, S.; Fukatsu, R.; Kakusho, N.; Kono, N.; Renard-Guilet, C.; Masuda, K.; Iida, K.; Nagasawa, K.; Shirahige, K.; *Masai, H.Nature Struct. Mol. Biol. 2015, (22), pp.889-897. DOI:10.1038/nsmb.3102. |
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|
"Development of Guanidine-Bisurea Bifunctional Organocatalyst with a Chiral Pyrrolidine Moiety and Application to α-Hydroxylation of Tetralone-Derived β-Keto Esters" Odagi, M.; Takayama, K.; Sato, M.; Yamanaka, M.; *Nagasawa, K. Molecules 2015, (20), pp.12590-12598. DOI:10.3390/molecules200712590 |
Yamanaka, M. | |
|
"Synthesis of a tricyclic bisguanidine compound structurally related to saxitoxin and its identification in paralytic shellfish toxins-producing microorganisms" Tsuchiya, S.; Cho, Y.; Konoki, K.; Nagasawa, K.; Oshima, Y.; *Yotsu-Yamashita, M. Chem. Eur. J. 2015, (21), pp.7835-7840. DOI:10.1002/chem.201500064 |
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"Development of Guanidine-Bisurea Bifunctinaol Organocatalyst Bearing Chirality at the Inner and Outer Sides of Urea Groups, and Application to Enantioselective α-Hydroxylation of Pyranoindolizine Intermediate for Camptothecin Synthesis" Odagi, M.; Watanabe, T.; *Nagasawa, K. Symmetry 2015, 7 pp.43-52. DOI:10.3390/sym7010043 |
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|
"Origin of stereocontorol in guanidine-bisurea bifunctional organocatalyst that promotes α-hydroxyaltion of tetralone-derived β-ketoesters: Asymmetric synthesis of β- or γ-substituted tetralone derivatives via organocatalytic oxidative kinetic resolution" Odagi, M.; Furukori, K.; Yamamoto, Y.; Sato, M.; Iida, K.; Yamanaka, M.; *Nagasawa, K. J. Am. Chem. Soc. 2015, 137 pp.1909-1915. DOI:10.1021/ja511149y |
Yamanaka Masahiro | |
|
"Guanidium Iodine-Catalyzed Oxidative α-Nitroalkylation of β-Ketoamides" Yasui, K.; Kato, T.; Kojima, K.; *Nagasawa, K. Chem. Commun. 2015, 51 pp.2290-2293. DOI:10.1039/C4CC08581G |
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|
"Conformational changes and cation ejection upon ligand binding to human telomeric DNA G-quadruplexes" Marchand, A.; Granzhan, A.; Iida, K.; Tsushima, Y.; Ma, Y.; Nagasawa, K.; Teulade-Fichou, M.-P.; *Gabelica, V.
J. Am. Chem. Soc. 2015, 137 pp.750-756. DOI:10.1021/ja5099403 |
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"2-(4-Hydroxy-3-methoxyphenyl)-benzothiazole suppresses tumor progression and metastatic potential of breast cancer cells by inducing ubiquitin ligase CHIP
" Hiyoshi, H.; Goto, N.; Tsuchiya, M.; Iida, K.; Nakajima, Y.; Hirata, N.; Kanda, Y.; Nagasawa, K.; *Yanagisawa, J. Sci.Rep. 2014, 4 (Article number), pp.7095. DOI:10.1038/srep07095 |
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"Direct Quantification of Loop Interaction and π-π Stacking for G-quadruplex Stability at the Sub-molecular Level" Ghimire, C.; Park, S.; Iida, K.; Yangyuoru, P.; Otomo, H.; Yu, Z.; Nagasawa, K.; Sugiyama, H.; *Mao, H. J. Am. Chem. Soc. 2014, 136 pp.15537-15544. DOI:10.1002/ja503585h |
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"Synthesis of an advance model of zetekitoxin AB focusing on N-acylisoxazolidine amide structure corresponding to C13~C17" Nishikawa, T.; Wang, C.; Akimoto, T.; Koshino, H.; *Nagasawa, K. Asian J. Org. Chem. 2014, 3 pp.1308-1311. DOI:10.1002/ajoc.201402206 |
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"Synthesis of Macrocyclic Penta- and Tetraoxazoles as G-Quadruplex Ligands" Masoud, S.; Tsushima, Y.; Iida, K.; *Nagasawa, K. Heterocycles 2014, 90 pp.866-873. DOI:10.3987/COM-14-S(K)90 |
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"Synthesis of 19-nor-vitamin D A-ring synthons via ring-closing olefin metathesis (RCM) reaction" Nagai, Y.; Tanami, T.; Abe, J.; Nagai, H.; Hamamizu, T.; Kominato, K.; Iida, K.; *Nagasawa, K. Asian J. Org. Chem. 2014, 3 pp.994-999. DOI:10.1002/ajoc.201402109 |
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|
"Total Synthesis of (+)-Cylindradine A" Iwata, M.; Kanoh, K.; Imaoka, T.; *Nagasawa, K. Chem. Commun. 2014, 50 pp.6991-6994. DOI:10.1039/C4CC00137K |
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"Development of Novel Guanidine-Bisurea Bifunctional Organocatalysts andTheir Application to Asymmetric alpha-Hydroxylation of Tetralone-Derived beta-Keto Esters" Odagi, M.; Takayama, K.; Furukori, K.: Watanabe, T.; *Nagasawa, K. Aust. J. Chem. 2014, 67 pp.1017-1020. DOI:10.1071/CH14144 |
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"Synthesis and Identification of Proposed Biosynthetic Intermediates of Saxitoxin in the Cyanobacterium Anabaena Circinalis (TA04) and the binoflagellate Alexandrium Tamarense (Axat-2)" Tsuchiya, S.; Cho, Y.; Konoki, K.; Nagasawa, K.; Oshima Y.; *Yotsu-Yamasshia, M. Org. Biomol. Chem. 2014, 12 pp.3016-3020. DOI:10.1039/C4OB00071D |
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"Asymmetric Michael Reaction of Nitroolefins with beta-Dicarbonyl Compounds Catalysed by 1,3-Diamine-tethered Guanidine-Thiourea Bifunctional Organocatalysts" Horitsugi, N.; Kojima, K.; Yasui, K.; Sohtome, Y.; *Nagasawa, K. Asian J. Org. Chem. 2014, 3 pp.445-448. DOI:10.1002/ajoc.2011402002R1 |
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|
"Identification of a Novel Compound That suppresses Brest Cancer Invasiveness by Inhibiting Transforming Growth Factor-beta Signaring via Estrogen Receptor alpha" Goto, N.; Hiyoshi, H.; Ito, I.; Iida, K.; Nakajima, Y.; Nagasawa, K.: *Yanagisawa, J. Journal of Cancer 2014, 5 pp.336-343. DOI:10.7150/jca.7202 |
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|
"Asymmetric alpha-Hydroxylation of Lactone with Vinylogous Pyridone using Guanidine-Urea Bifunctional Organocatalyst: Catalytic Enantioselective Synthesis of a Key Intermediate for(20S)-Camptothecin Analogues" Watanabe, T.; Odagi, M.; Furukori, K.; *Nagasawa, K. Chem. Eur. J. 2014, 20 pp.591-597. DOI:10.1002/chem.201303663 |
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|
"A nonclassical vitamin D receptor pathway suppresses renal fibrosis" Ito, I.; Waku, T.; Aoki, M.; Abe, R.; Nagai, Y.; Wtanabe, T.; Nakajima, Y.; Ohkido, I.; Yokoyama, K.; Miyachi, H.; Shimizu, T.; Murayama, A.; Kishimoto, H.; Nagasawa, K.; *Yanagisawa, J. J. Clin. Invest. 2013, 123 pp.4579-4594. DOI:10.1172/JCI67804 |
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|
"Fluorescent ligand-mediated screening of G-quadruplex structures using a DNA microarray" Iida, K.; Nakamura, T.; Yoshida, W.; Tera, M.; Nakabayashi, K.; Hata, K.; Ikebukuro, K.; *Nagasawa, K. Angew. Chem. Int. Ed. 2013, 52 pp.12052-12055. DOI:10.1002/anie.201305366 |
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|
"G-quadruplexes as a Potential Therapeutic Target for Embryonal Tumors" *Shalaby, T.; Fiaschetti, G.; Nagasawa, K.; Shin-ya, K.; Baumgartner, M.; Grotzed, M. Molecules 2013, 18 (10), pp.12500-12537. DOI:10.3390/molecules181012500 |
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|
"Asymmetric alpha-Hydroxylation of tetra lone Derived beta-Ketoesters using Guanidine-Urea Bifunctional Organocatalyst in the Presence of Cumene Hydroperoxide" Odagi, M.; Furugori, K.; Watanabe, T.; *Nagasawa, K. Chem. Eur. J. 2013, 19 pp.16740-16745. DOI:10.1002/chem.201303006 |
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|
"Synthesis of Macrocyclic Dimer of Cyclic Hexaoxazole and Examine of its Interaction with Telomeric Oligonucleotide" Iida, K.; Tsubouchi, G.; Nakamura, T.; *Nagasawa, K. Heterocycles 2013, 88 pp.1287-1298. DOI:10.3987/COM-13-S(S)97 |
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|
"Solution structure of an intramolecular (3+1) human telomeric G-quadruplex bound to a telomestatin derivative" Chung, W.-J.; Heddi, B.; Tera, M.; iida, K.; Nagasawa, K.; *Phan, T. J. Am. Chem. Soc. 2013, 135 pp.13495-13501. DOI:10.1021/ja405843r |
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|
"Synthesis of saxitoxin derivatives bearing guanidine and urea groups at C13 and evaluation of their inhibitory activity on voltage-gated sodium channel" Akimoto, T.; Masuda, A.; Yotsu-Yamashita, M.; Hirokawa, T.; *Nagasawa, K. Org. Biomol. Chem. 2013, 11 pp.6642-6649. DOI:10.1039/C3OB41398 |
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|
"Synthetic Approaches to Tetracyclic Pyrrole Imidazole Marine Alkaloids" Imaoka, T.; Iwata, M.; Akimoto, T.; *Nagasawa, K. Nat. Prod. Chemmun. 2013, 8 pp.961-964. |
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|
"
A tandem Friedel-Crafts based method for the construction
of tricyclic pyrroloquinoline skeleton and its application to the synthesis of
ammosamide B
" Takayama, Y.; Yamada, T.; Tatekabe, S.; *Nagasawa, K. Chem. Commun. 2013, 49 pp.6519-6521. DOI:10.1039/C3CC42463D |
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|
"Evaluation of interaction between long telomeric DNA and macrocyclic hexaoxazole (6OTD) dimer of a G-quadruplex ligand" Iida, K.; Nakamura, T.; Majima, S.; Simiya, H.; *Nagasawa, K. Molecules 2013, 18 pp.4328-4341. |
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|
"
Sequential Enantiodivergent Organocatalysis: Reversibility in
Enantioswitching Controlled by Conformationally Flexible Guanidine/Bisthiourea
Organocatalyst
" Sohtome, Y.; Yamaguchi, T.; Tanaka, S.; *Nagasawa, K. Org. Biomol. Chem. 2013, 11 pp.2780-2786. |
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|
"
Interaction of long telomeric DNAs with macrocyclic
hexaoxazole as G-quadruplex ligand
" Iida, K.; Tsubouchi, G.; Nakamura, T.; Majima, S.; Seimiya, H.; *Nagasawa, K. Med Chem Commun 2013, 4 pp.260-264. |
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|
"
Intramolecular 1,3-Dipolar Cycloaddition-mediated
Stereoselective Synthesis of Disubstituted Cyclopentane, a Simple Model for
Cyclopentane Ring System of Polycyclic Oroidine Alkaloids
" Fukahori, Y.; Takayama, Y.; Imaoka, T.; Iwamoto, O.; *Nagasawa, K. Chem. Asian J. 2013, 8 pp.244-250. |
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|
"
Dynamic asymmetric organocatalytsis: Cooperative effects
of weak interactions and conformational flexibility in asymmetric
organocatalysts
" Sohtome, Y.; *Nagasawa, K. Chem. Commun. 2012, 48 pp.7777-7789. |
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|
"
Synthesis of vitamin D3 derivatives with
nitrogen-linked substituents at A-ring C-2 and evaluation of their vitamin D
receptor-mediated transcriptional activity
" Abe, J.; Nagai, Y.; Higashikuni, R.; Iida, K.; Hirokawa, T.; Nagai, H.; Kominato, K.; Tsuchida, T.; Hirata, M.; Inada, M.; Miyaura, C.; *Nagasawa, K. Org. Biomol. Chem. 2012, 10 pp.7862-7839. |
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|
"
Caged Ligand for Telomeric G-quadruplex
" Nakamura, T.; Iida, K.; Tera, M.; Shin-ya, K.; Seimiya, H.; *Nagasawa, K. ChemBioChem 2012, 13 pp.774-777. |
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|
"
Synthesis of saxitoxins
" Iwamoto, O.; Akimoto, T.; *Nagasawa, K. Pure Appl. Chem. 2012, 84 pp.1445-1453. |
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|
"
Agrocybynes AeE from the culture broth of Agrocybe praecox
" Fushimi, K.; Anzai, K.; Tokuyama, S.; Kiriiwa, Y.; Matsumoto, N.; Sekiya, A.; Hashizume, D.; Nagasawa, K.; Hirai, H.; *Kawagishi, H. Tetrahedron 2012, 68 pp.1262-1265. |
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|
"
Design and Synthesis of
G-quadruplex Ligand bearing Macrocyclic Hexaoxazoles with Four-way Side chains
" Iida, K.; Majima, S.; Ohtake, T.; Tera, M.; Shin-ya, K.; *Nagasawa, K. Heterocycles 2012, 84 pp.401-411. |
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|
"
Synthesis of skeletal analogs of saxitoxin
derivatives and evaluation of their inhibitory activity on sodium ion channels
NaV1.4 and NaV1.5
" Shinohara, R.; Akimoto, T.; Iwamoto, O.; Hirokawa, T.; Yotsu-Yanakshita, M.; Yamaoka, K.; *Nagasawa, K. Chem. Eur. J. 2011, 17 pp.12144-12152. |
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|
"
Development of a novel
biosensing system based on the structural change of a polymerized
guanine-quadruplex DNA nanostructure
" Morita, Y.; Yoshida, W.; Savory, N.; Woong Han, S.; Tera, M.; Nagasawa, K.; Nakamura, C.; Sode, K.; *Ikebukuro, K. Biosensor and Bioelectronics 2011, 26 pp.4837-4841. |
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|
"
Osteoclast-forming suppressing compounds, gargalols A, B and C, from the
edible mushroom Grifola gargal
"
Wu, J.; Choi, J-H.; Yoshida, M.; Hirai, H.; Harada, E.; Masuda, K.;
Koyama, T.; Yazawa, K.; Noguchi, K.; Nagasawa,
K.; *Kawagishi, H.
Tetrahedron 2011, 67 pp.6576-6581. |
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|
"
Analysis of unbinding force
between telomestatin derivatives and human telomeric G-quadruplex by atomic
force microscopy
" Amemiya, Y.; Furunaga, Y.; Iida, K.; Tera, M.; Nagasawa, K.; Ikebukuro, K.; *Nakamura, C. Chem. Commun. 2011, 47 pp.7485-7487. |
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|
"
Design and Synthesis of Telomestatin Derivatives
Containing Methyl Oxazole and Their G-Quadruplex Stabilizing Activity
" Majima, S.; Tera, M.; Iida, K.; Shin-ya, K.; *Nagasawa, K. Heterocycles 2011, 82 pp.1345-1357. |
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|
"
(S)-Stereoisomer of
Telomestatin as a Potent G-quadruplex Binder and Telomerase Inhibitor
" *Doi, T.; Shibata, K.; Yoshida, M.; Takagi, M.; Tera, M.; Nagasawa, K.; Shin-ya, K.; Takahashi, T. Org. Biomol. Chem. 2011, 9 pp.387-393. |
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|
"
Enantioselective epoxidation of
alpha,beta-unsaturated ketones catalyzed by stapled helical L-Leu-based
peptides
" Demizu, Y.; Yamagata, N.; Nagayo, S.; Sato,Y.; Doi, M.; Tanaka, M.; Nagasawa, K.; Okuda, H.; *Kurihara, M. Tetrahedron 2011, 67 pp.6155-6165. |
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|
"
Organocatalytic Asymmetric Synthesis of
N,N-Bis(dihydrofuranyl)hydoxyamines: A cascade Reaction Involving
Friedel-Crafts Alkylation, Internal Redox Reaction and Umpoling
" Sohtome, Y.; Yamaguchi, T.; Shin, B.; *Nagasawa, K. Chem. Lett. 2011, 40 pp.843-845. |
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|
"
Enantioselective Phospha-Michael Reaction of Diphenyl Phosphite with
Nitroolefins Utilizing Conformationally Flexible Guanidinium/Bisthiourea
Organocatalyst: Assembly-State Tunablity in Asymmetric Organocatalysis
" Sohtome, Y.; Horitsugi, N.; Takagi, R.; *Nagasawa, K. Adv. Synth. Catal. 2011, 353 pp.2631-2636. |
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|
"
Linking the Conformational
Flexibility and Kinetics: Catalytic 1,4-Type Friedel-Crafts Reaction of Phenols
Utilizing 1,3-Diamine-Tethered-Guanidine/Bisthiourea Organocatalysts
" Sohtome, Y.; Shin, B.; Horitsugi, N.; Noguchi, K.; *Nagasawa K. Chem. Asian J. 2011, 6 pp.2463-2470. |
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|
"Design of a stabilized short helical peptide and its
application to catalytic enantioselective epoxidation of (E)-chalcone
"
Yamagata, N.; Demizu, Y.; Sato, Y.; Doi, M.; Tanaka, M.; Nagasawa, K.; Okuda, H.; *Kurihara, M. Tetrahedron Lett. 2011, 52 pp.798-801. |
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| Books |
「ビタミンDと疾患ー基礎と臨床からの考察」 岡野登志和 "ビタミンD誘導体開発の現状と将来展望" 長澤和夫 医薬ジャーナル社 (東京) 2013, pp印刷中-. |
|
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「 Stereoselective Synthesis of Drugs and Naturalproducts 」 Andrushko, V.; Andrushko N "Stereoselective Organocatalyzed C-C bond Forming Reaction" *Nagasawa, K.; Yasui, K. John Wiley and Sons (in press) 2014, |
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|
「 Science of Synthesis Asymmetric Organocatalysis 2」 Maruoka, K."Chiral Guanidine and Amidine Organocatalysts" *Nagasawa K.; Sohtome Y. Thieme 2013, pp1-40. |
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| Reviews / Accounts |
"Sequential stereodivergent organocatalysis and programmed organocascade" *Sohtome, Y.; *Nagasawa, K. Org. Biomol. Chem. 2014, 12 pp.1681-1685. DOI:10.1039/C3OB42310G |
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"Macrocyclic Polyoxazoles as G-Quadruplex Ligands" iida, K.; *Nagasawa, K. Chem. Rec. 2013, 13 pp.539-548. DOI:10.1002/tcr.201300015 |
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|
"核酸の特殊な高次構造と創薬" ＊長澤和夫 化学と教育 2013, 61 pp.104-107. |
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|
"
Dynamic Enantiodivergent Organocatalysis: Merging
Molecular Motors with Bifunctional Organocatalysts
" Sohtome, Y.; *Nagasawa, K. ChemPhysChem 2011, 12 pp.2217-2219. |
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|
"
Development of Macrocyclic Polyoxazoles and
Evaluation of Their G-quadruplex Stabilizing Activities
" Tera, M.; Iida, K.; Shin-ya, K.; *Nagasawa, K. J. Synth. Org. Chem. Jpn 2011, 69 pp.129-139. |
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| Conference / Symposium / Lecture |
招待講演 " Chemical Biology in Natural G-quadruplex Ligand of Telomestatin And its Derivatives " *Nagasawa, K.環太平洋化学国際会議, ハワイ (米国) 2015-12-18～2015-12-18 |
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招待講演 "Enantioselective Synthesis of Tetralone-derived Natural Products based on Organocatalytic Oxidative Kinetic Resolution" *Nagasawa, K. 環太平洋化学国際会議, ハワイ (米国) 2015-12-16～2015-12-16 |
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|
招待講演 "Natural Products Synthesis Based on Organocatalytic α-Hydroxylation of β-Ketoesters" *Nagasawa, K. 2nd International symposium of Organocatalyst, 東京 (日本) 2014-11-20～2014-11-21 |
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招待講演 "Chemical Biology in G-Quadruplex and Telomestatin" *Nagasawa, K. 3rd International Symposium of Chemical Biology and Natural Products, 大阪 (日本) 2014-10-28～2014-10-29 |
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|
招待講演 "Development of Topology-Selective Small Molecules for Telomeric G-quadruplex" *Nagasawa, K. 5th International Conference on Development of Biomedical Engineering, ホーチミン (ベトナム) 2014-06-16～2014-06-18 |
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|
招待講演 "
G-quadruplex ligands with macrocyclic polyoxazoles
" *Nagasaw, K 4th International Meeting on G-quadriplex Nucleic Acids, Nanyang (Singapore) 2013-07-01～2013-07-04 |
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|
依頼講演 "
Enantioselective hydroxylation of 1,3-dicarbonyls
by Guanidine-Urea bufuncrional organocatalysts
" *Nagasawa, K. 1st USA-Japan Organocatalyst symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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|
招待講演 "
Synthesis of Saxitoxins and its Analogs
" *Nagasawa, K. 7th US-Japan Marine Symposium, Okinawa (Japan) 2011-12-12～2011-12-16 |
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|
招待講演 "
Enantiodivergent Reaction with Conformationally
Flexible Guanidine-Thiourea Bifunctional Organocatalyst
" *Nagasawa, K. Germany-Japan Organocatalyst Symposium, Kyoto (Japan) 2011-10-14～2011-10-15 |
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|
招待講演 "
Synthesis
of Saxitoxins
" *Nagasawa, K. 27th International Symposium on the Chemistry of Natural Products (ISCNP27/ICOB7) and 7th International Conference on Biodiversity (ICOB7), Brisbane (Australia) 2011-07-10～2011-07-14 |
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| A03 林 雄二郎 | ||
| Original papers |
"16O/18O exchange of aldehydes and ketones caused by H218O in the mechanistic investigation of organocatalyzed Michael, Mannich, and Aldol reactions" *Hayashi, Y.; Mukaiyama, T.; Benohoud, M.; R Gupta, N.; Ono, T.; Toda, S. Chem. Eur. J. 2016, 22 DOI:10.1002/chem.201600280 |
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|
"Pot economy and one-pot synthesis" *Hayashi, Y. Chem. Sci. 2016, 7 pp.866-880. DOI:10.1039/C5SC02913A |
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|
"One-pot synthesis of (S)-baclofen via aldol condensation of acetaldehyde with diphenylprolinol silyl ether-mediated asymmetric Michael reaction as a key step" *Hayashi, Y.; Okamura, D.; Sakamoto, D. Org. Lett. 2016, 18 pp.4-7. DOI:10.1021/acs.orglett.5b02839 |
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"Formal synthesis of ezetimibe using a proline-mediated asymmetric, three-component Mannich reaction" Shimazaki, Y.; Koshino, S.; Hayashi, Y. Chem. Lett. 2016, 18 pp.30-32. DOI:10.1246/cl.150916 |
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"Asymmetric nitrocyclopropanation of α-substituted α，β-enals catalyzed by diphenylprolinol silyl ether for the construction of all-carbon quaternary stereogenic centers" *Hayashi, Ｙ.; Yamazaki, T.; Nakanishi, Y.; Ono, T.; Taniguchi, T.; Monde, K.; Uchimaru, T. Eur. J. Org. Chem. 2015, pp.5747-5754. DOI:10.1002/ejoc.201500838 |
Uchimaru, T. | |
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"Two reaction mechanisms via iminium ion intermediates: The different reactivity between diphenylprolinol silyl ether and trifluoromethyl-substituted diarylprolinol silyl ether" Gotoh, H.; Uchimaru, T.; *Hayashi, Y. Chem. Eur. J. 2015, DOI:10.1002/chem.201500326 |
Uchimaru, T. | |
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"Asymmetric Formal [3+2] Cycloaddition Reaction of Succinaldehyde and Nitroalkene Catalyzed by Diphenylprolinol Silyl Ether" Umemiya, S.; *Hayashi, Y. Eur. J. Org. Chem. 2015, pp.4320-4324. DOI:10.1002/ejoc.201500623 |
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"Asymmetric Aldol Reaction of α,α-Disubstituted Acetaldehydes Catalyzed by Diphenylprolinol Silyl Ether for the Construction of Quaternary Stereogenic Centers" *Hayashi, Y.; Shomura, H.; Xu, Q.; M. J. Lear.; Sato, I. Eur. J. Org. Chem. 2015, pp.4316-4319. DOI:10.1002/ejoc.201500585 |
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"Asymmetric Aldol Reaction of Chloral Catalyzed by Diarylprolinol" *Hayashi, Y.; Watanabe, S.; Yasui, Y.; Umemiya,S. ChemCatChem. 2015, 7 pp.1646-1649. DOI:10.1002/cctc.201500282 |
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"Asymmetric Organocatalyzed Epoxidation of 2-Oxoindoline-3-ylidene Acetaldehydes" Mukaiyama, T.; Ogata, K.; Ono, T.; *Hayashi, Y. ChemCatChem. 2015, 7 pp.155-159. DOI:10.1002/cctc.201402811 |
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"The Asymmetric Catalytic Mannich Reaction Catalyzed by Organocatalyst–A Personal Account–" *Hayashi, Y. J.Synth.Org.Chem.Jpn 2014, 72 pp.1228-1238. |
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"A Theoretical and Experimental Study of the Effects of Silyl Substituents in Enantioselective Reactions Catalyzed by Diphenylprolinol Silyl Ether" *Hayashi, Y.; Okamura, D.; Yamazaki, T.; Ameda, Y.; Gotoh, H.; Tsuzuki, S.; Uchimaru, T.; Seebach, D. Chem. Eur. J. 2014, 20 pp.17077-17088. DOI:10.1002/chem.201403514 |
Tsuzuki, S.; Uchimaru, T. | |
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"Nef reaction with molecular oxygen in absence of metal additives and its mechanistic insight" Umemiya, S.; Nishino, K.; Satoh, I.; *Hayashi, Y. Chem. Eur. J. 2014, 20 pp.15753-15759. DOI:10.1002/chem.201403475 |
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"Asymmetric Organocatalyzed Michael Addition of Nitrometane to 2-Oxoindoline-3-ylidene acetaldehyde and Three “One-pot” Sequential Synthesis of (–)-Horsfiline and (–)-Coerulescine" Mukaiyama, T.; Ogata, K.; Sato, I.; *Hayashi, Y. Chem. Eur. J. 2014, 20 pp.13583-13588. DOI:10.1002/chem201403932 |
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"Asymmetric Aldol Reaction of α-Acetoxyimino Aldehydes and its Application in the Synthesis of Substituted 1,2-Oxazine Derivatives" Yasui, Y.; Ogata, K.; Sato, I.; *Hayashi, Y. Adv. Synth. Catal. 2014, 356 pp.3106-3118. DOI:10.1002/adsc.201400294 |
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"Diphenylprolinol silyl ether catalyzed asymmetric Michael reaction of nitroalkanes and β,β-disubstituted α,β-unsaturated aldehydes for the construction of all-carbon quaternary stereogenic centers" *Hayashi, Y.; Kawamoto, Y.; Honda, M.; Okamura, D.; Umemiya, S.; Noguchi, Y.; Mukaiyama, T. Chem. Eur. J. 2014, 20 pp.12072-12082. DOI:10.1002/chem.201403588 |
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"Asymmetric Aldol Reaction of Formaldehyde Catalyzed by Diarylprolinol" Yasui, Y.; Benohoud, M.; Sato, I.; *Hayashi, Y. Chem. Lett. 2014, 43 pp.556-558. DOI:10.1246/cl.131199 |
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"Organocatalyst-Mediated Dehydrogenation of Aldehydes to α,β-Unsaturated Aldehydes,and Oxidative and Enantioselective Reaction of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether" *Hayashi, Y; Itoh, T; Ishikawa, H. Adv. Synth. Catal. 2013, 355 pp.3661-3669. DOI:10.1002/adsc.201300919 |
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"One-Pot Synthesis of (-)-Oseltamivir and Mechanistic Insights into the Organocatalyzed Michael Reaction" Mukaiyama, T; Ishikawa, H; Koshino, H; *Hayashi, Y. Chem. Eur. J. 2013, 19 pp.17789-17800. DOI:10.1002/chem.201302371 |
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"Remote 1,6-Stereocontrol by Iminium-mediated Organocatalytic Events" M, J, Lear; * Hayashi, Y. ChemCatChem. 2013, 5 pp.3499-3501. DOI:10.1002/cctc.201300590 |
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"Asymmetric Formal [3 + 2] Cycloaddition Reaction of Succinaldehyde via Diarylprolinol-mediated Domino Aldol–Acetalization Reaction for the Construction of Tetrahydrofuran" *Hayashi, Y; Nishino, K; Sato, I. Chem. Lett. 2013, 42 pp.1294-1296. DOI: 10.1246/cl.130544 |
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"Diarylprolinol in an Asymmetric, Direct Cross-Aldol Reaction with Alkynyl Aldehydes" *Hayashi, Y; Kojima, M; Yasui, Y; Kanda, Y; Mukaiyama, T; Shomura, H; Nakamura, D; L, Ritmaleni; Sato, I. ChemCatChem. 2013, 5 pp.2887-2892. DOI:10.1002/cctc.201300390 |
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"Asymmetric Aldol Reaction of Glyoxal Catalyzed by Diarylprolinol" *Hayashi, Y; Kojima, M. ChemCatChem. 2013, 5 pp.2883-2885. DOI:10.1002/cctc.201300247 |
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"Stoichiometric Reactions of Enamines Derived from Diphenylprolinol Silyl Ethers with Nitro Olefins and Lessons for the Corresponding Organocatalytic Conversions – a Survey " *Seebach, D.; Sun, X.; Ebert, M.-O.; Schweizer, W. B.; Purkayastha, N.; Beck, A. K.; Duschmale, J.; Wennemers, H.; Mukaiyama, T.; Benohoud, M.; *Hayashi, Y.; *Reiher, M. Helv. Chim. Acta 2013, 96 (5), pp.799-852. DOI:10.1002/hlca.201300079 |
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"Asymmetric Mannich Reaction of α-Keto Imines Catalyzed by Diarylprolinol Silyl Ether " *Hayashi, Y.; Sakamoto, D.; Shomura, H.; Hashizume, D. Chem. Eur. J. 2013, 19 pp.7678-7681. DOI:10.1002/chem.201300513 |
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"Pot-Economy in the Synthesis of Prostaglandin A1 and E1 Methyl Esters" *Hayashi, Y.; Umemiya, S. Angew. Chem. Int. Ed. 2013, 52 pp.3450-3452. DOI:10.1002/anie.201209380 |
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"Organocatalytic 1,4-Addition Reaction of α,β-γ,δ-Diunsaturated Aldehyde versus 1,6-Addition Reaction" *Hayashi, Y.; Okamura, D.; Umemiya, S.; *Uchimaru, T. ChemCatChem. 2012, 7 pp.959-962. DOI:10.1002/cctc.201200161 |
T. Uchimaru | |
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"Diarylprolinol in an asymmetric aldol reaction of an -alkyl--oxo aldehyde as an electrophile" *Hayashi, Y.; Yasui, Y.; Kojima, M.; Kawamura, T.; Ishikawa, H. Chem. Commun. 2012, 48 pp.4570-4572. DOI:10.1039/C2CC31230A |
H. Ishikawa | |
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"An Organocatalytic, Enantioselective Intramolecular [6+2] Cycloaddition Reaction for the Formation of Tricyclopentanoids and Insight on its Mechanism from a Computational Study" *Hayashi, Y.; Gotoh, H.; Honma, M.; Sankar, K.; Kumar, I.; Ishikawa, H.; Konno, K.; Yui, H.; Tsuzuki, S.; *Uchimaru, T. J. Am. Chem. Soc. 2011, 133 pp.20175-20185. DOI:10.1021/ja108516b |
H. Ishikawwa, T. Uchimaru | |
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"One-pot Synthesis of Chiral Aziridines by a Domino Reaction by Using Desulfonylative Formation on the N-Tosyl Imine of Chloroacetaldehyde with an Asymmetric Mannich Reaction as a Key Step" *Hayashi, Y.; Urushima, T.; Sakamoto, D.; Torii, K.; Ishikawa, H. Chem. Eur. J. 2011, 17 pp.11715-11718. DOI:10.1002/chem.201101668 |
H. Ishikawa | |
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"Synthesis of (-)-Oseltamivir using a microreactor in the Curtius rearrangement" Ishikawa, H.; Bondzic, B. P.; *Hayashi, Y. Eur. J. Org. Chem. 2011, pp.6020-6031. DOI:10.1002/ejoc.201100074 |
H.Ishikawa | |
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"Asymmetric Mannich Reaction of Imines Derived from Aliphatic and Aromatic Aldehydes Catalyzed by Diarylprolinol Silyl Ether" Urushima, T.; Ishikawa, H.; *Hayashi, Y. Chem. Eur. J. 2011, 17 pp.8273-8276. DOI:0.1002/chem.201101077 |
H. Ishikawa | |
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"Organocatalyzed Michael Addition of Aldehydes to Nitro Alkenes – Generally Accepted Mechanism Revisited and Revised" Patora-Komisarska, K.; Benohoud, M.; Ishikawa, H.; Seebach, D.; *Hayashi, Y. Helv. Chim. Acta 2011, 94 pp.719-745. DOI:10.1002/hlca.201100122 |
H. Ishikawa | |
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"Oxidative and Enantioselective Cross-Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether" *Hayashi, Y.; Itoh, T.; Ishikawa, H. Angew. Chem. Int. Ed. 2011, 50 pp.3920-3924. DOI:10.1002/anie.201006885 |
H. Ishikawa | |
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"Asymmetric One-Pot Four-Component Coupling Reaction: Synthesis of Substituted Tetrahydropyrans Catalyzed by Diphenylprolinol Silyl Ether" Ishikawa, H.; Sawano, S.; Yasui, Y.; Shibata, Y.; *Hayashi, Y. Angew. Chem. Int. Ed. 2011, 50 pp.3774-3779. DOI: 10.1002/anie.201005386 |
H.Ishikawa | |
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"One-Pot Synthesis of Chiral α-Substituted β,γ-Epoxy Aldehyde Derivatives through an Asymmetric Aldol Reaction of Chloroacetaldehyde" *Hayashi,Y.;Kawamura,T.;Kojima,m.;Ishikawa,H. Angew. Chem. Int. Ed. 2011, 50 pp.2804-2807. DOI:10.1002/anie.201005577 |
Ishikawa,H. | |
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"Diarylprolinol in the Direct Asymmetric Aldol Reaction of Trifluoromethylacetaldehyde Ethyl Hemiacetal with aldehyde" *Hayashi,Y.;Yasui,Y.;Kawamura,T.;Kojima,M.;Ishikawa,H. Synlett 2011, pp.485-488. DOI:10.1055/s-0030-1259543 |
Ishikawa,H. | |
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"One-pot High-Yielding Synthesis of the DPP4-Selective Inhibitor ABT-341 by a Four-Component Coupling Mediated by a Diphenylprolinol Silyl Ether" *Hayashi,Y.;Ishikawa,H.;Honma,M. Angew. Chem. Int. Ed. 2011, 50 pp.2824-2827. DOI:10.1002 |
H.Ishikawa | |
| Books |
「Comprehensive Organic Synthesis Vol.2」 Knochel, P.; Molander, G. A.; Mikami, K. "The Aldol Reaction: Organocatalysis Approach" Mase, N.; Hayashi, Y. Elsevier (Amsterdam) 2015, pp273-339. |
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「Asymmetric Synthesis II: More Methods and Applications」 Christmann, M.; Brase, S. "Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Tecgnology" Ishikawa, H.; Hayashi, Y. Wiley 2015, pp61-65. |
Ishikawa, H. | |
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「Suatainable Catalysis」 Dunn, P. J.; Hii, K. K.; Krische, M. J.; Williams, M. T. "Diarylprolinol Silyl Ethers: Development and Application as Organocatalysts" Gotoh, H.; Hayashi, Y. John Wiley & Sons, Inc. (Hoboken) 2015, pp287-316. ISBN:978-1-118-15542-4 |
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「Modern Tools for the Synthesis of Complex Bioactive Molecules」 Cossy,J.; Arseniyadis,S. "Enantioselective Organocatalysis: A Powerful Tool For the Synthesis of Bioactive Molecules" Hayashi,Y.; Shoji,M. A John Wiley & Sons, Inc. (New Jersey) 2015, pp189-212. |
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「Water in Organic Synthesis」 Kobayashi,S. "Mannich Reaction and Baylis-Hillman Reaction" Hayashi,Y.;Benohoud,M. George Thieme Verlag KG (Stuttgart) 2012, pp385-432. |
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「Asymmetric Organocatalysis 1: Lewis Base and Acid Catalysts」 List,B. "Enamine Catalysis of Mannich Reactions" Hayashi,Y.; Benohoud,M. Geoge Thieme Verlag KG (Stuttgart) 2015, pp73-134. |
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| Reviews / Accounts |
"超強力生物活性アンフィジノライドNのエピマー合成と短工程ポット合成" *Hayashi, Y. 化学同人 2016, 71 (4), pp.49-51. |
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"Mukaiyama Aldol Reaction - 40th Anniversary Symposium" *Hayashi, Y.; Sato, I. 有機合成化学協会誌 2014, 72 pp.309-313. |
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"ポッとエコノミーを指向した効率的天然物合成" Ishikawa, H.; *Hayashi, Y. シーエムシー出版 2014, 43 (2), pp.6-14. |
Ishikawa, H. | |
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"「ここまでできる！短工程合成」" Hayashi, Y.; Sato, I. 化学（化学同人） 2014, 69 (3), pp.64-65. |
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"有機触媒の医薬品合成への応用" *Hayashi, Y シーエムシー出版 2014, 43 (2), pp.6-14. |
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| Conference / Symposium / Lecture |
招待講演 "Pot-economy in Total Synthesis" *Hayashi, Y. Seoul National University, Seoul ( Korea) 2016-03-11～2016-03-11 |
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招待講演 "Pot-economy in Total Synthesis" *Hayashi, Y. Pohang University of Science and Technology, Pohang (Korea) 2016-03-10～2016-03-10 |
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招待講演 "Pot-economy in Total Synthesis" *Hayashi, Y. Sungkyunkwan University, Suwon (Korea) 2016-03-08～2016-03-08 |
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招待講演 "Pot-economy in Total Synthesis" *Hayashi, Y. Korea University, Seoul (Korea) 2016-03-07～2016-03-07 |
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招待講演 "Pot-economy and Organocatalysis in total synthesis" *Hayashi, Y. PacificChem 2015, Hawaii (USA) 2015-12-18～2015-12-18 |
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招待講演 "Organocatalyst and pot-economy in total synthesis of biologically active compounds" *Hayashi, Y. 14th International Conference on the Chemistry of Antibiotics and other Bioactive Compounds, Texas (USA) 2015-10-15～2015-10-15 |
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招待講演 "Pot Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Rice University, Houston (USA) 2015-10-13～2015-10-13 |
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招待講演 "Pot Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. University of Houston, Houston (USA) 2015-10-12～2015-10-12 |
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招待講演 "Pot Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. University of Konstanz, Konstanz (Germany) 2015-09-15～2015-09-15 |
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招待講演 "Pot Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Karlsruhe Institute of Technology, Karlsruhe (Germany) 2015-09-14～2015-09-14 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi, Y. Dominocat first Symposium, Aachen (Germany) 2015-09-10～2015-09-10 |
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招待講演 "Pot Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. University of Cologne, Cologne (Germany) 2015-09-17～2015-09-17 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi, Y. Gordon Research Conference Natural Products, NH (USA) 2015-07-26～2015-07-26 |
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招待講演 "Pot-Synthesis of medicinally important organic compound by organocatalyst" *Hayashi, Y. The 39th Naito Conference on The Chemistry of Organocatalysts, 札幌 (日本) 2015-07-09～2015-07-09 |
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口頭発表／ポスター発表 "Organocatalyst in Asymmetric Aldol Reaction" *Hayashi, Y. The 9th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-9) and The 5th New Phase International Conference on Cutting-Edge Organic Chemistry in Asia (NICCEOCA-5), Petaling Jaya (Malaysia) 2014-12-03～2014-12-03 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Univ. Manchester, Manchester (UK) 2014-11-07～2014-11-07 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Bristol University, Bristol (UK) 2014-11-06～2014-11-06 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Pfizer Neusentis, Cambridge (UK) 2014-11-04～2014-11-04 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Takeda Cambridge, Cambridge (UK) 2014-11-03～2014-11-03 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Oxford University, Oxford (UK) 2014-10-31～2014-10-31 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi, Y. Sapienza University of Rome, Rome (Italy) 2014-09-26～2014-09-26 |
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招待講演 "Metal-free catalyzed synthetic transformations" *Hayashi, Y. ISCHIA Advanced School of Organic Chemistry, Ischia Island (Italy) 2014-09-24～2014-09-24 |
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招待講演 "Pot-Economy in Total Synthesis" *Hayashi, Y. 4th RSC/SCI symposium on Challenges in Catalysis for Pharmaceuticals and Fine Chemicals, London (UK) 2014-11-05～2014-11-05 |
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招待講演 "Organocatalyst in Asymmetric Aldol Reaction" *Hayashi, Y. CHIRALITY 2014 (26th International Symposium on Chiral Discrimination, ISCD-26)Prague, Prague (Czech Republic) 2014-07-28～2014-07-28 |
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招待講演 "Diphenylprolinol silyl ether catalyzed asymmetric Michael reaction of nitroalkanes and β,β-disubstituted α,β-unsaturated aldehydes for the construction of all-carbon quaternary stereogenic centers" *Hayashi, Y. IGER International Symposium on Chemical Science in Asia, Nagoya (Japan) 2014-05-27～2014-05-27 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. Mitsui Chemicals Singapore R&D Centre and AMRI, Singapore (Singapore) 2014-01-24～2014-01-24 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. Novartis Institute for Tropical Diseses Pte Ltd., GSK, and A-star, Singapore (Singapore) 2014-01-22～2014-01-22 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. National University of Singapore, Singapore (Singapore) 2014-01-21～2014-01-21 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. Nanyang Technological University, Singapore (Singapore) 2014-01-20～2014-01-20 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. National Chiao Tung University, HsinChu (Taiwan) 2013-11-01～2013-11-01 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. National Tsing Hua University, HsinChu (Taiwan) 2013-10-30～2013-10-30 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. National Chung Cheng University, ChiaYi (Taiwan) 2013-10-29～2013-10-29 |
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招待講演 "Pot Economy in Total Synthesis" *Hayashi,Y. National Taiwan Normal University, Taipei (Taiwan) 2013-10-28～2013-10-28 |
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招待講演 "Pot-Economy in Total Synthesis" *Hayashi,Y. International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan, Sendai (Japan) 2013-09-30～2013-09-30 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y. University of the Basque Country, Bilbao (Spain) 2013-09-20～2013-09-20 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y. Universidad del País Vasco, San Sebastián (Spain) 2013-09-19～2013-09-19 |
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招待講演 "Pot-Economy in Total Synthesis" *Hayashi,Y. XXXIV Biennial Meeting of The Spanish Royal Society of Chemistry, Santander (Spain) 2013-09-16～2013-09-16 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y. University of Oviedo, Oviedo (Spain) 2013-09-13～2013-09-13 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y Institut Catala d’Investigacio Quimica, Tarragona (Spain) 2013-09-12～2013-09-12 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y． University of Valencia, Tarragona (Spain) 2013-09-11～2013-09-11 |
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招待講演 "Pot-Economy and Organocatalysis in Total Synthesis" *Hayashi,Y． Universidad Complutense in Madrid, Madrid (Spain) 2013-09-09～2013-09-09 |
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招待講演 "Pot-Economy in Total Synthesis, Jokichi Takamine" *Hayashi,Y． 130Years of Glasgow-Japan Collaboration symposium, Glasgow (Scottland) 2013-09-05～2013-09-05 |
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招待講演 "One-pot reaction in total synthesis" *Hayashi, Y. Gordon Research Conference on High-Throughput Chemistry & Chemical Biology, New London (USA) 2013-06-02～2013-06-07 |
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招待講演 "Three “One-Pot Synthesis of Prostaglandin E1 Methyl Ester via Organocatalyst" *Hayashi, Y. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 仙台 (日本) 2013-04-19～2013-04-19 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. University of Hawaii at Manoa, Manoa (USA) 2012-12-20～2012-12-20 |
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招待講演 "Asymmetric Aldol Reaction Catalyzed by Diarylprolinol" *Hayashi, Y. First Japan-USA Organocatalytic Symposium, Waikiki (USA) 2012-12-16～2012-12-16 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. the 7th International Conference on cutting-edge organic chemistry in Asia and the 3rd new phase international conference on cutting-edge organic chemistry in Asia (ICCEOCA-7/NICCEOCA-3), Singapore (Singapore) 2012-12-13～2012-12-13 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China, Shanghai (China) 2012-10-31～2012-10-31 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. Shanghai Institute of Materia Medica,Chinese Academy of Sciences, Shanghai (China) 2012-10-30～2012-10-30 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. Sapienza University of Rome, Rome (Italy) 2012-09-28～2012-09-28 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. ISCHIA Advanced School of Organic Chemistry, Napoli (Italy) 2012-09-23～2012-09-23 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. Università degli studi della Basilicata, Potenza (Italy) 2012-09-21～2012-09-21 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. University of Salerno, Salerno (Italy) 2012-09-19～2012-09-19 |
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招待講演 "Organocatalyst and Total Synthesis" *Hayashi, Y. University of Munnich, Munnich (Germany) 2012-09-17～2012-09-17 |
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招待講演 "Organocatalyst and Total Synthesis" *Hayashi, Y. Campus Asia Program, Summer School 2012, 仙台 (日本) 2012-08-21～2012-08-21 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y University College London, London (UK) 2012-04-25～2012-04-25 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. University of Oxford, Oxford (UK) 2012-04-23～2012-04-23 |
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招待講演 "Diphenylprolinol silyl ether in "One-Pot" Synthesis" *Hayashi, Y. University of California Berkley, Berkley (USA) 2012-02-22～2012-02-22 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi, Y. Università degli Studi di Roma "Tor Vergata", ローマ (イタリア) 2012-01-16～2012-01-16 |
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受賞講演 "rganocatalyst in Total Synthesis, Novartis Chemistry Lecture" *Hayashi,Y. Novartis Inc, バーゼル (スイス) 2012-01-11～2012-01-11 |
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招待講演 "Practical Asymmetric Synthesis Using Organocatalyst" *Hayashi,Y. 9th Symposium on Chemical Approaches to Chirality, 東京 (日本) 2011-12-14～2011-12-14 |
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招待講演 "Organocatalyst in Total Synthesis " *Hayashi,Y. 8th AFMC International Medicinal Chemistry Symposium (AIMECS11), 東京 (日本) 2011-11-30～2011-11-30 |
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受賞講演 "Diphenylprolinol silyl ether as an effective organocatalyst and its application to the one-pot synthesis" *Hayashi,Y. Novartis Chemistry Lecture, ケンブリッジ (アメリカ合衆国) 2011-10-04～2011-10-04 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi,Y. Harvard University, マサチューセッツ州ケンブリッジ市 (アメリカ合衆国) 2011-10-03～2011-10-03 |
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招待講演 "Organocatalyst in Total Synthesis" *Hayashi,Y. The University of Hong Kong, 香港 (中国) 2011-08-22～2011-08-22 |
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| Prize |
"Asian Core Program Lectureship Award, 2012 (Taiwan)" *Hayashi,Y.
2012-12 The New Phase Asian Core Program On Cutting-Edge Organic Chemistry (Taiwan) Organocatalyst in Total Synthesis |
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"Novartis Chemistry Lectureship Award" *Hayashi,Y. 2012-01 Novartis Phama Chemical & Analytical Development The Novartis Chemistry Lectureship is awarded to scientists in recognition of outstanding contributions to organic and conputational chemistry,including applications to biology. |
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"ＪＳＰＣ 2011 Award for Exellence " Ishikawa, H.; Honma, M.; *Hayashi, Y. 2011-11 日本プロセス化学会 実用的不斉有機触媒反応の開発および独創的天然有機化合物合成 |
Ishikawa, H. | |
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"井上学術賞" *Hayashi,Y. 2012-02 井上科学振興財団 環境調和型有機触媒反応の開発とその応用 |
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"Asian Core Program Lectureship Award, 2012 (Singapore)" *Hayashi,Y. 2012-12 The New Phase Asian Core Program On Cutting-Edge Organic Chemistry (Singapore) Organocatalyst in Total Synthesis |
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| A03 佐藤 敏文 | ||
| Original papers |
"Self-Assembly of Maltoheptaose-block-Polycaprolactone Copolymers: Carbohydrate-Decorated Nanoparticles with Tunable Morphology and Size in Aqueous Media" Isono, T.; Miyachi, K.; Satoh, Y.; Nakamura, R.; Zhang, Y.; Otsuka, I.; Tajima, K.; Kakuchi, T.; Borsali, R.; *Satoh, T. Macromolecules 2016, in press |
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"B(C6F5)3-Catalyzed Group Transfer Polymerization of N,N-Disubstituted Acrylamide Using Hydrosilane: Effect of Hydrosilane and Monomer Structures, Polymerization Mechanism, and Synthesis of α-End-Functionalized Polyacrylamides" Kikuchi, S., Chen, Y., Kitano, K., Sato, S.-i., Satoh, T., *Kakuchi, T. Macromolecules 2016, 49 (8), pp.3049-3060. DOI:10.1021/acs.macromol.6b00190 |
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"Donor-Acceptor Poly(3-hexylthiophene)-block-Pendent Poly(isoindigo) with Dual Roles of Charge Transporting and Storage Layer for High-Performance Transistor-Type Memory Applications" Wang, J.-T., Takashima, S., Wu, H.-C., Chiu, Y.-C., Chen, Y., Isono, T., Kakuchi, T., *Satoh, T., *Chen, W.-C. Adv. Funct. Mater. 2016, 26 (16), pp.2695-2705 . DOI:10.1002/adfm.201504957 |
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"Synthesis of Well-Defined Amphiphilic Star-Block and Miktoarm Star Copolyethers via t-Bu-P4-Catalyzed Ring-Opening Polymerization of Glycidyl Ethers" Satoh, Y., Miyachi, K., Matsuno, H., Isono, T., Tajima, K., Kakuchi, T., *Satoh, T. Macromolecules 2016, 49 (2), pp.499-509. DOI:10.1021/acs.macromol.5b02459 |
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"Sequential Mukaiyama-Michael reaction induced by carbon acids" *Yanai, H., Kobayashi, O., Takada, K., Isono, T., Satoh, T., *Matsumoto, T. Chem. Commun. 2016, 52 (16), pp.3280-3283. DOI:10.1039/c5cc10115h |
Yanai, H. | |
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"Advanced functionalization of polyhydroxyalkanoate via the UV-initiated thiol-ene click reaction" *Tajima, K., Iwamoto, K., Satoh, Y., Sakai, R., Satoh, T., *Dairi, T. Appl. Microbiol. Biotechnol. 2016, 100 (10), pp.4375-4383. DOI:10.1007/s00253-015-7252-3 |
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"Synthesis, morphology, and electrical memory application of oligosaccharide-based block copolymers with π-conjugated pyrene moieties and their supramolecules" Sun, H.-S., Chen, Y., Lee, W.-Y., Chiu, Y.-C., Isono, T., *Satoh, T., *Kakuchi, T., *Chen, W.-C. Polym. Chem. 2016, 7 (6), pp.1249-1263. DOI:10.1039/c5py01697e |
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"Synthesis of AB block and A2B2 and A3B3 miktoarm star-shaped copolymers using ω-end-functionalized poly(methyl methacrylate) with a hydroxyl group prepared by organocatalyzed group transfer polymerization" Eric, O.-T., Chen, Y., Takada, K., Sato, S.-i., Satoh, T.,*Kakuchi, T. Polym. Chem. 2015, 6 (45), pp.7841-7850. DOI:10.1039/c5py01112d |
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"Organic acids as efficient catalysts for group transfer polymerization of N,N-disubstituted acrylamide with silyl ketene acetal: polymerization mechanism and synthesis of diblock copolymers" Kikuchi, S., Chen, Y., Kitano, K., Takada, K., Satoh, T., *Kakuchi, T. Polym. Chem. 2015, 6 (38), pp.6845-6856. DOI:10.1039/C5PY01104C |
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"Rod-coil type miktoarm star copolymers consisting of polyfluorene and polylactide: precise synthesis and structure-morphology relationship" Saito, K., Isono, T., Sun, H.-S., Kakuchi, T., *Chen, W.-C., *Satoh, T. Polym. Chem. 2015, 6 (39), pp.6959-6972. DOI:10.1039/C5PY01031D |
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"Complex Thin Film Morphologies of Poly(n-hexyl isocyanate)(5k,10k)-Poly(ε-caprolactone)1-3(10k,17k) Miktoarm Star Polymers" Phinjaroenphan, R., Kim, Y. Y., Ree, B. J., Isono, T., Lee, J., Rugmai, S., Kim, H., Maensiri, S., Kakuchi, T., *Satoh, T., *Ree, M. Macromolecules 2015, 48 (16), pp.5816-5833. DOI:10.1021/acs.macromol.5b00875 |
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"Synthesis of Oligosaccharide-based Block Copolymers with Pendent π-Conjugated Oligofluorene Moieties and Their Electrical Device Applications" Sun, H. Chiu, Y; Lee, W Chen, Y; Hirao, A. Satoh, T. Kakuchi, T. *Chen, W Macromolecules 2015, 48 (12), pp.3907-3917. DOI:10.1021/acs.macromol.5b00651 |
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"Influence of Helical Structure on Chiral Recognition of Poly(phenylacetylene)s Bearing Phenylcarbamate Residues of L-Phenylglycinol and Amide Linage as Pendants" Zhang, C., Ma, R., Wang, H., Sakai, R., Satoh, T., Kakuchi, T., Liu, L., *Okamoto, Y. Chirality 2015, 27 (8), pp.500-506. DOI:10.1002/chir.22453 |
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"Diphenyl Phosphate-Catalyzed Ring-Opening Polymerization of 1,5-Dioxepan-2-one" Makiguchi, K., Asakura, C., Yanai, K., Satoh, T., *Kakuchi, T. Macromol. Symp. 2015, 349 (1, Ionic Polymerization, Part I), pp.74-84. DOI:10.1002/masy.201400011 |
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"Organophosphate-catalyzed bulk ring-opening polymerization as an environmentally benign route leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane" Saito, T., Aizawa, Y., Tajima, K., Isono, T., *Satoh, T. Polym. Chem. 2015, 6 (24), pp.4374-4384. DOI:10.1039/C5PY00533G |
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"Controlled/Living Ring-Opening Polymerization of Glycidylamine Derivatives Using t-Bu-P4/Alcohol Initiating System Leading to Polyethers with Pendant Primary, Secondary, and Tertiary Amino Groups" Isono, T., Asai, S., Satoh, Y., Takaoka, T., Tajima, K., Kakuchi, T., *Satoh, T. Macromolecules 2015, 48 (10), pp.3217-3229. DOI:10.1021/acs.macromol.5b00556 |
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"B(C6F5)3-catalyzed group transfer polymerization of alkyl methacrylates with dimethylphenylsilane through in situ formation of silyl ketene acetal by B(C6F5)3-catalyzed 1,4-hydrosilylation of methacrylate monomer" Chen, Y., Kitano, K., Tsuchida, S., Kikuchi, S., Takada, K., Satoh, T., *Kakuchi, T. Polym. Chem. 2015, 6 (18), pp.3502-3511. DOI:10.1039/C5PY00294J |
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"Synthesis and thermoresponsive properties of four-arm star-shaped poly(N-isopropylacrylamide)s bearing covalent and non-covalent cores" Chen, Y., Xiao, N., Fukuoka, M., Yoshida, K., Duan, Q., Satoh, T., *Kakuchi, T. Polym. Chem. 2015, 6 (19), pp.3608-3616. DOI:10.1039/C5PY00277J |
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"Luminescent Coordination Glass: Remarkable Morphological Strategy for Assembled Eu(III) Complexes" Hirai, Y., Nakanishi, T., Kitagawa, Y., Fushimi, K., Seki, T., Ito, H., Fueno, H., Tanaka, K., Satoh, T., *Hasegawa, Y. Inorg. Chem. 2015, 54 (9), pp.4364-4370. DOI:10.1021/acs.inorgchem.5b00145 |
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"Synthesis of multifunctional poly(1-pyrenemethyl methacrylate)-b-poly(N-isopropylacrylamide)-b-poly(N-methylolacrylamide)s and their electrospun nanofibers for metal ion sensory applications" Wang, J.-T., Chiu, Y.-C., Sun, H.-S., Yoshida, K., Chen, Y., Satoh, T., *Kakuchi, T., *Chen, W.-C. Polym. Chem. 2015, 6 (12), pp.2327-2336. DOI:10.1039/C4PY01773K |
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"Sub-10 nm Scale Nanostructures in Self-Organized Linear Di- and Triblock Copolymers and Miktoarm Star Copolymers Consisting of Maltoheptaose and Polystyrene" Otsuka, I., Zhang, Y., Isono, T., Rochas, C., Kakuchi, T., *Satoh, T., *Borsali, R. Macromolecules 2015, 48 (5), pp.1509-1517. DOI:10.1021/ma502295y |
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"Synthesis of Homopolymers, Diblock Copolymers, and Multiblock Polymers by Organocatalyzed Group Transfer Polymerization of Various Acrylate Monomers" Takada, K., Ito, T., Kitano, K., Tsuchida, S., Takagi, Y., Chen, Y., Satoh, T., *Kakuchi, T. Macromolecules 2015, 48 (3), pp.511-519. DOI:10.1021/ma502298v |
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"Synthesis and chiral recognition of helical poly(phenylacetylene)s bearing L-phenylglycinol and its phenylcarbamates as pendants" Zhang, C., Wang, H., Yang, T., Ma, R., Liu, L., Sakai, R., Satoh, T., Kakuchi, T., ＊Okamoto, Y. J. Polym. Sci., Part A Polym. Chem. 2015, 53 (6), pp.809-821. DOI:10.1002/pola.27506 |
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"Synthesis of end-functionalized poly(methyl methacrylate) by organocatalyzed group transfer polymerization using functional silyl ketene acetals and α-phenylacrylates" Chen, Y., Takada, K., Kubota, N., Eric, O.-T., Ito, T., Isono, T., Satoh, T., *Kakuchi, T. Polym. Chem. 2015, 6 (10), pp.1830-1837. DOI:10.1039/C4PY01564A |
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"Grazing incidence small-angle X-ray scattering studies of the thin film morphologies of miktoarm crystalline star polymers" Phinjaroenphan, R., Kim, Y. Y., Jung, S., Isono, T., Satoh, Y., Maensiri, S., Rugmai, S., Kakuchi, T., *Satoh, T., *Ree, M. Sci. Adv. Mater. 2014, 6 (11), pp.2526-2531. DOI:10.1166/sam.2014.2232 |
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"Hierarchical Structures in Thin Films of Miktoarm Star Polymers: Poly(n-hexyl isocyanate)(12K)-Poly(ε-caprolactone)1-3(5K)" Kim, Y. Y., Jung, S., Kim, C., Ree, B. J., Kawato, D., Nishikawa, N., Suemasa, D., Isono, T., *Kakuchi, T., *Satoh, T., *Ree, M. Macromolecules 2014, 47 (21), pp.7510-7524. DOI:10.1021/ma501695b |
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"Stereoblock-like Brush Copolymers Consisting of Poly(L-lactide) and Poly(D-lactide) Side Chains along Poly(norbornene) Backbone: Synthesis, Stereocomplex Formation, and Structure-Property Relationship" Isono, T., Kondo, Y., Ozawa, S., Chen, Y., Sakai, R., Sato, S.-i., Tajima, K., Kakuchi, T., *Satoh, T. Macromolecules 2014, 47 (20), pp.7118-7128. DOI:10.1021/ma501647m |
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"Synthesis of α-, ω-, and α,ω-End-Functionalized Poly(n-butyl acrylate)s by Organocatalytic Group Transfer Polymerization Using Functional Initiator and Terminator" Takada, K., Fuchise, K., Kubota, N., Ito, T., Chen, Y., Satoh, T., *Kakuchi, T. Macromolecules 2014, 47 (16), pp.5514-5525. DOI:10.1021/ma501106e |
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"Synthesis of star poly(N-isopropylacrylamide) with end-group of zinc-porphyrin via ATRP and its photocatalytic activity under visible light" Qiu, N., Li, Y., Han, S., Cui, G., Satoh, T., Kakuchi, T., *Duan, Q. J. Photochem. Photobiol., A 2014, 283 pp.38-44. |
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"B(C6F5)3-Catalyzed Group Transfer Polymerization of n-Butyl Acrylate with Hydrosilane through In Situ Formation of Initiator by 1,4-Hydrosilylation of n-Butyl Acrylate" Fuchise, K., Tsuchida, S., Takada, K., Chen, Y., Satoh, T., *Kakuchi, T. ACS Macro Lett. 2014, 3 (10), pp.1015-1019. DOI:10.1021/mz5004689 |
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"High-Performance Nonvolatile Organic Transistor Memory Devices Using the Electrets of Semiconducting Blends" Chiu, Y.-C., Chen, T.-Y., Chen, Y., Satoh, T., *Kakuchi, T., *Chen, W.-C. ACS Appl. Mater. Interfaces 2014, 6 (15), pp.12780-12788. DOI:10.1021/am502732d |
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"Binaphthol-derived phosphoric acids as efficient chiral organocatalysts for the enantiomer-selective polymerization of rac-lactide" Makiguchi, K., Yamanaka, T., Kakuchi, T., *Terada, M., *Satoh, T. Chem. Commun. 2014, 50 (22), pp.2883-2885. DOI:10.1039/C4CC00215F |
Terada, M. | |
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"A Model Chiral Graft Copolymer Demonstrates Evidence of the Transmission of Stereochemical Information from the Side Chain to the Main Chain on a Nanometer Scale" Shah, P. N., Chae, C.-G., Min, J., Shimada, R., Satoh, T., Kakuchi, T., *Lee, J.-S. Macromolecules 2014, 47 (9), pp.2796-2802. DOI:10.1021/ma500544b |
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"Thermoresponsive Properties of 3-, 4-, 6-, and 12-Armed Star-Shaped Poly[2-(dimethylamino)ethyl methacrylate]s Prepared by Core-First Group Transfer Polymerization" Kikuchi, S., Chen, Y., Fuchise, K., Takada, K., Kitakado, J., Sato, S., Satoh, T., *Kakuchi, T. Polym. Chem. 2014, 5 (16), pp.4701-4709. DOI:10.1039/C4PY00290C |
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"Synthesis of 3-, 4-, 5-, 6-, 7-, 8-, 9-, 10-, 11-, and 12-Armed Star-shaped Poly(styrene oxide) Ru(II) Complexes by Click-to-Chelate Approach" Chen, Y., Xiao, N., Satoh, T., *Kakuchi T. Polym. Chem. 2014, 5 (17), pp.4993-5001. DOI:10.1039/C4PY00314D |
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"Bis(4-nitrophenyl) phosphate as an efficient organocatalyst for ring-opening polymerization of β-butyrolactone leading to end-functionalized and diblock polyesters" Makiguchi, K., Saito, T., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2014, 52 (14), pp.2032-2039. DOI:10.1002/pola.27211 |
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"Synthesis of Linear, Cyclic, Figure-Eight-Shaped, and Tadpole-Shaped Amphiphilic Block Copolyethers via t-Bu-P4-Catalyzed Ring-Opening Polymerization of Hydrophilic and Hydrophobic Glycidyl Ethers" Isono, T., Satoh, Y., Miyachi, K., Chen, Y., Sato, S.-i., Tajima, K., Satoh, T., *Kakuchi, T., Macromolecules 2014, 47 (9), pp.2853-2863. DOI:10.1021/ma500494e |
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"Synthesis and Characterization of Aminoporphyrin-End-Functionalized Poly(N-isopropylacrylamide) with Photodynamic and Thermoresponsive Effects" Yang, Y., Li, Y., Qiu, N., Cui, G., Satoh, T., *Duan, Q. Chem. - Asian J. 2014, 9 (5), pp.1379-1387. DOI:10.1002/asia.201301513 |
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"Synthesis of end-functionalized poly(N-isopropyl acrylamide) with zinc porphyrin and its photocatalytic activity under visible light" Qiu, N., Li, Y., Han, S., Satoh, T., Kakuchi, T., *Duan, Q. J. Appl. Polym. Sci. 2014, 131 (15), pp.40523. DOI:10.1002/app.40523 |
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"Rod-Like Amphiphile of Diblock Polyisocyanate Leading to Cylindrical Micelle and Spherical Vesicle in Water" Sakai, N., Satoh, T., *Kakuchi, T., Macromolecules 2014, 47 (5), pp.1699-1704. DOI:10.1021/ma500097t |
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"Synthesis of Water-Soluble Polyisocyanate with Oligo(ethylene glycol) Side-Chain as a New Thermoresponsive Polymer" Sakai, N., Jin, M., Sato, S., Satoh, T., *Kakuchi, T. Polym. Chem. 2014, 5 (3), pp.1057-1062. DOI:10.1039/C3PY00972F |
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"Precise synthesis of rod-coil type miktoarm star copolymer containing poly(n-hexyl isocyanate) and aliphatic polyester" *Satoh, T., Nishikawa, N., Kawato, D., Suemasa, D., Jung, S., Kim, Y-y., Ree, M., Kakuchi, T., Polym. Chem. 2014, 5 (2), pp.588-599. DOI:10.1039/C3PY00985H |
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"Diphenyl phosphate/4-dimethylaminopyridine as an efficient binary organocatalyst system for controlled/living ring-opening polymerization of L-lactide leading to diblock and end-functionalized poly(L-lactide)s" Makiguchi, K., Kikuchi, S., Yanai, K., Ogasawara, Y., Sato, S.-i., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2014, 52 (7), pp.1047-1054. DOI:10.1002/pola.27089 |
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"Synthesis, Self-Assembly, and Thermal Caramelization of Maltoheptaose-Conjugated Polycaprolactones Leading to Spherical, Cylindrical, and Lamellar Morphologies" Isono, T., Otsuka, I., Suemasa, D., Rochas, C., *Satoh, T., *Borsali, R., *Kakuchi, T. Macromolecules 2013, 46 (22), pp.8932-8940. DOI:10.1021/ma4019526 |
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"Synthesis of Helical Poly(phenylacetylene)s with Amide Linkage Bearing L-Phenylalanine and L-Phenylglycine Ethyl Ester Pendants and Their Applications as Chiral Stationary Phases for HPLC" Zhang, C., Wang, H., Geng, Q., Yang, T., Liu, L., Sakai, R., Satoh, T., Kakuchi, T., *Okamoto, Y. Macromolecules 2013, 46 (21), pp.8406-8415. DOI:10.1021/ma4015802 |
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"Synthesis and Stereocomplex Formation of Star-Shaped Stereoblock Polylactides Consisting of Poly(L-lactide) and Poly(D-lactide) Arms" Isono, T., Kondo, Y., Otsuka, I., Nishiyama, Y., Borsali, R., Kakuchi, T., *Satoh, T. Macromolecules 2013, 46 (21), pp.8509-8518. DOI:10.1021/ma401375x |
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"Synthesis and characterization of novel thermoresponsive fluorescence complexes based on copolymers with rare earth ions" Cui, G., Chen, S., Jiang, B., Zhang, Y., Qiu, N., Satoh, T., Kakuchi, T., *Duan, Q. Opt. Mater. 2013, 35 (12), pp.2250-2256. DOI:10.1016/j.optmat.2013.06.010 |
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"Diphenyl Phosphate as an Efficient Acidic Organocatalyst for Controlled/Living Ring-Opening Polymerization of Trimethylene Carbonates Leading to Block, End-Functionalized, and Macrocyclic Polycarbonates" Makiguchi, K., Ogasawara, Y., Kikuchi, S., Satoh, T., *Kakuchi, T. Macromolecules 2013, 46 (5), pp.1772-1782. DOI:10.1021/ma4000495 |
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"Sub-10 nm Nano-Organization in AB2- and AB3-Type Miktoarm Star Copolymers Consisting of Maltoheptaose and Polycaprolactone" Isono, T., Otsuka, I., Kondo, Y., Halila, S., Fort, S., Rochas, C., Satoh, T., Borsali, R., Kakuchi, T. Macromolecules 2013, 46 (4), pp.1461-1469. DOI:10.1021/ma3026578 |
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"Synthesis of Star- and Figure-Eight-Shaped Polyethers by t-Bu-P4-Catalyzed Ring-Opening Polymerization of Butylene Oxide" Isono, T., Kamoshida, K., Satoh, Y., Takaoka, T., Sato, S.-i., Satoh, T., *Kakuchi, T. Macromolecules 2013, 46 (10), pp.3841-3849. DOI:10.1021/ma4006654 |
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"Synthesis and characterization of Eu(III) complexes of modified cellulose and poly(N-isopropylacrylamide)" Cui, G., Li, Y., Shi, T., Gao, Z., Qiu, N., Satoh, T., Kakuchi, T., *Duan, Q. Carbohydr. Polym. 2013, 94 (1), pp.77-81. |
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"Emulsified phosphatidylserine, simple and effective peptide carrier for induction of potent epitope-specific T cell responses" Ichihashi, T., Satoh, T., Sugimoto, C., *Kajino, K. PLoS One 2013, 8 (3), pp.e60068. |
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"Synthesis of block and end-functionalized polyesters by triflimide-catalyzed ring-opening polymerization of ε-caprolactone, 1,5-dioxepan-2-one, and rac-lactide" Makiguchi, K., Kikuchi, S., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2013, 51 (11), pp.2455-2463. DOI:10.1002/pola.26631 |
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"Influence of stereoregularity and linkage groups on chiral recognition of poly(phenylacetylene) derivatives bearing -leucine ethyl ester pendants as chiral stationary phases for HPLC" *Zhang, C., Liu, F., Li, Y., Shen, X., Xu, X., Sakai, R., Satoh, T., Kakuchi, T., Okamoto J. Polym. Sci., Part A Polym. Chem. 2013, 51 (10), pp.2271-2278. |
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"Synthesis of miktoarm star copolymer Ru(II) complexes by click-to-chelate approach" Xiao, N., Chen, Y., Shen, X., Zhang, C., Yano, S., Gottschaldt, M., Schubert, U. S., Kakuchi, T., *Satoh, T. Polym. J. 2013, 45 (2), pp.216-225. DOI:10.1038/pj.2012.100 |
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"Synthesis and conformation effects of poly(phenylacetylene)s having chiral and racemic polylactide pendants" *Zhang, C., Wang, H., Su, G., Li, R., Shen, X., Zhang, S., Geng, Q., Liu, F., Otsuka, I., Satoh, T., Kakuchi, T. Polym. Int. 2012, 61 (7), pp.1158-1162. DOI:10.1002/pi.4194 |
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"Helicity Inversion": Linkage Effects of Chiral Poly(n-hexyl isocyanate)s" Shah, P. N., Min, J., Chae, C.-G., Nishikawa, N., Suemasa, D., Kakuchi, T., Satoh, T., *Lee, J.-S. Macromolecules 2012, 45 (22), pp.8961-8969. DOI:10.1021/ma301930s |
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"Colorimetric Detection of Anions in Aqueous Solution Using Poly(phenylacetylene) with Sulfonamide Receptors Activated by Electron Withdrawing Group" Sakai, R., Barasa, E. B., Sakai, N., Sato, S.-i., Satoh, T., *Kakuchi, T. Macromolecules 2012, 45 (20), pp.8221-8227. DOI:10.1021/ma301767g |
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"Fluorescence Turn-On Sensing of Anions Based on Disassembly Process of Urea-Functionalized Poly(phenylenebutadiynylene) Aggregates" Sakai, R., Nagai, A., Tago, Y., Sato, S.-i., Nishimura, Y., Arai, T., Satoh, T., *Kakuchi, T. Macromolecules 2012, 45 (10), pp.4122-4127. DOI:10.1021/ma300481j |
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"Synthesis of star-shaped poly(N-isopropylacrylamide) via atom transfer radical polymerization and its photocatalytic oxidation of Rhodamine B" Gao, Z., Liang, J., Tao, X., Cui, Y., Satoh, T., Kakuchi, T., *Duan, Q. Macromol. Res. 2012, 20 (5), pp.508-514. DOI:10.1007/s13233-012-0046-x |
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"Precise synthesis of clickable poly(n-hexyl isocyanate)" *T. Satoh, R. Ihara, D. Kawato, N. Nishikawa, D. Suemasa, Y. Kondo, K. Fuchise, R. Sakai, T. Kakuchi Macromolecules 2012, 45 (9), pp.3677-3686. DOI:10.1021/ma300555v |
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"Synthesis of end-functionalized polyethers by phosphazene base-catalyzed ring-opening polymerization of 1,2-butylene oxide and glycidyl ether" Misaka, H., Tamura, E., Makiguchi, K., Kamoshida, K., Sakai, R., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2012, 50 (10), pp.1941-1952. DOI:10.1002/pola.25969 |
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"Synthesis of syndiotactic-rich star-shaped poly(methyl methacrylate) by core-first group transfer polymerization using N-(trimethylsilyl)bis(trifluoromethanesulfonyl)imide" Chen, Y., Takada, K., Fuchise, K., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2012, 50 (16), pp.3277-3285. DOI:10.1002/pola.26123 |
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"Controlled polymerization of methyl acrylate for high-molecular-weight polymers by pentafluorophenylbis(triflyl)methane-promoted group transfer polymerization using triisopropylsilyl ketene acetal" Takada, K., Fuchise, K., Chen, Y., Satoh, T., *Kakuchi, T. J. Polym. Sci., Part A Polym. Chem. 2012, 50 (17), pp.3560-3566. DOI:10.1002/pola.26140 |
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"Effect of Counter Anions on Kinetics and Stereoregularity for the Strong Bronsted Acid-Promoted Group Transfer Polymerization of N,N-Dimethylacrylamide" Fuchise, K., Chen, Y., Takada, K., Satoh, T., *Kakuchi, T. Macromol. Chem. Phys. 2012, 213 (15), pp.1604-1611. DOI:10.1002/macp.201200146 |
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"Diphenyl Phosphate as an Efficient Acidic Organocatalyst for Controlled/Living Ring-Opening Polymerization of Trimethylene Carbonates Leading to Block, End-Functionalized, and Macrocyclic Polycarbonates" Makiguchi, K., Ogasawara, Y., Kikuchi, S., Satoh, T., *Kakuchi, T. Macromolecules 2013, 46 (5), pp.1772-1782. DOI:10.1021/ma4000495 |
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"Sub-10 nm Nano-Organization in AB2- and AB3-Type Miktoarm Star Copolymers Consisting of Maltoheptaose and Polycaprolactone" Isono, T., Otsuka, I., Kondo, Y., Halila, S., Fort, S., Rochas, C., Satoh, T., Borsali, *R.,Kakuchi, T. Macromolecules 2013, 46 (4), pp.1461-1469. DOI:10.1021/ma3026578 |
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"10 nm Scale Cylinder-Cubic Phase Transition Induced by Caramelization in Sugar-Based Block Copolymers" Otsuka, I., Isono, T., Rochas, C., Halila, S., Fort, S., Satoh, T., Kakuchi, T.,*Borsali, R ACS Macro Lett. 2012, 1 (12), pp.1379-1382. DOI:10.1021/mz300543u |
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"Well-Defined Functional Linear Aliphatic Diblock Copolyethers: A Versatile Linear Aliphatic Polyether Platform for Selective Functionalizations and Various Nanostructures" Kwon, W., Rho, Y., Kamoshida, K., Kwon, K. H., Jeong, Y. C., Kim, J., Misaka, H., Shin, T. J., Kim, J., Kim, K.-W., Jin, K. S., Chang, T., Kim, H., *Satoh, T., *Kakuchi, T., *Ree, M. Adv. Funct. Mater. 2012, 22 (24), pp.5194-5208. DOI:10.1002/adfm.201201101 |
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| Books |
「Encyclopedia of Polymeric Nanomaterials」 Kobayashi, S., Müllen, K. "Poly(cyclic olefin)s" Isono, T., Satoh, T. Springer (Verlag Berlin Heidelberg) 2015, pp1677-1683. ISBN:978-3-642-29647-5 |
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「Encyclopedia of Polymeric Nanomaterials」 Kobayashi, S., Müllen, K. "Organocatalytic Polymerization" Satoh, T. Springer (Verlag Berlin Heidelberg) 2015, pp1485-1497. ISBN:978-3-642-29647-5 |
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「Encapsulation Technologies」 Vikas Mittal "Tunable Encapsulation Property of Amphiphilic Polymer Based on Hyperbranched Polyethylenimine" Wan, D., *Satoh, T. Scrivener Publishing (Beverly, MA, USA) 2013, pp225-253. |
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| Reviews / Accounts |
"Polyacetylenes as Colorimetric and Fluorescent Chemosensor for Anions" Sakai, R.; *Satoh, T.; *Kakuchi, T. Polymer Reviews 2016, in press |
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"Sub-20 nm microphase-separated structures in hybrid block copolymers consisting of polycaprolactone and maltoheptaose" Isono, T., Otsuka, I., Halila, S., Borsali, R., Kakuchi, T., *Satoh, T. J. Photopolym. Sci. Technol. 2015, 28 (5), pp.635-642. DOI:10.2494/photopolymer.28.635 |
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"フォスファゼン塩基を触媒に用いた置換エポキシドのリビング開環重合系の開発" 磯野拓也、佐藤悠介、覚知豊次、佐藤敏文 高分子論文集 2015, 72 pp.295-305. |
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"Precise polymerization by organic molecular catalysts. Development of metal catalyst changed polymerization catalyst" Satoh, T. Kagaku to Kogyo 2014, 67 (6), pp.483-485. |
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"Organocatalytic ring-opening polymerization of cyclic esters, cyclic carbonates, and epoxides" Makiguchi, K., *Kakuchi, T., *Satoh, T. Yuki Gosei Kagaku Kyokaishi 2013, 71 (7), pp.706-715. DOI:DOI:10.5059/yukigoseikyokaishi.71.706 |
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"Recent Progress in Organocatalytic Group Transfer Polymerization" Fuchise, K., Chen Y., Satoh, T., *Kakuchi, T. Polym. Chem. 2013, DOI:10.1039/C3PY00278K |
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"Synthesis of hyperbranched polymer using slow monomer addition method" *Satoh, T. Int. J. Polym. Sci 2012, 2012 pp.816163. DOI:10.1155/2012/816163 |
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| Conference / Symposium / Lecture |
招待講演 "Sub-10 nm Scale Nano-Organization in AnBm-Type Miktoarm Star Copolymers Consisting of Polycaprolactone and Maltoheptaose" *Satoh, T. Japan-Korea Joint Seminar 2015, Kitakyushu (Japan) 2015-10-28～2015-10-31 |
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招待講演 "Organophosphate-catalyzed bulk ring-opening polymerization leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane" *Satoh, T. France-Japan Joint Seminar On Functional Block Copolymer 2015, Grenoble (France) 2015-09-21～2015-09-22 |
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招待講演 "Synthesis of Amphiphilic Cyclic, Figure-Eight-Shaped, and Tadpole-Shaped Block Copolyethers Using Click Cyclization" *Satoh, T. Japan-Taiwan Bilateral Polymer Symposium 2015, Sapporo (Japan) 2015-09-02～2015-09-06 |
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招待講演 "Sub-20 nm microphase-separated structures in hybrid block copolymers consisting of polycaprolactone and maltoheptaose" Isono, T., Otsuka, I., Halila, S., Borsali, R., Kakuchi, T., *Satoh, T. The 32nd International Conference of Photopolymer Science and Technology (ICPST-32), Chiba (Japan) 2015-06-24～2015-06-26 |
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招待講演 "Sub-10 nm Scale Nano-Organization in AnBm-Type Miktoarm Star Oligosaccharides based-Copolymers" *Satoh, T. Japan-France Joint Seminar On Functional Block Copolymer 2015, Sapporo (Japan) 2015-05-31～2016-06-02 |
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招待講演 "Synthesis and Morphological Characterization of Hybrid Block Copolymers Consisting of Maltoheptaose and Polycaprolactone" Isono, T., Kakuchi, T., ○*Satoh, T. Taiwan-Japan Bilateral Polymer Symposium 2014, Tainan (Taiwan) 2014-11-19～2014-11-22 |
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招待講演 "Synthesis and Self-Assembly of Hybrid Block Copolymers Consisting of Maltoheptaose and Polycaprolactone" Isono, T., Otsuka, I., Halila, S., Borsali, R., Kakuchi, T. ○*Satoh, T. 4th Franch-Brazilian Meeting on Polymers, Florianopolis (Brazil) 2014-11-24～2014-11-28 |
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招待講演 "Precise Synthesis of End-Functional Polymers for Preparing Functional Block Copolymers" ○*Satoh, T. France-Japan Joint Seminar on Functional Block Copolymer 2014, Grenoble (France) 2014-09-14～2014-09-17 |
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招待講演 "Synthesis of cyclic and figure-eight-shaped amphiphilic block copolyether via ring-opening polymerization and click reaction" Satoh, Y., Isono, T., Kakuchi, T., ○*Satoh, T. Korea - Japan Joint Polymer Symposium 2014, Daejeon (Korea) 2014-10-29～2014-10-31 |
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招待講演 "Synthesis of Complex Macromolecular Architecture Using Clickable Polymer" ○*Satoh, T., Isono, T., Chen, Y., Kakuchi, T. MACRO2014, Chiang Mai (Thailand) 2014-07-06～2014-07-11 |
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招待講演 "Enantiomer-Selective Polymerization of rac-Lactide using Chiral Phosphoric acid as an Efficient Organocatalyst" ○*Satoh, T. Japan-Korea Joint symposium 2013(JKJS 2013), Tokyo (Japan) 2013-10-31～2014-11-01 |
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招待講演 "Synthesis and Morphological Characterization of Miktoarm star Polymers Consisting of Maltoheptaose and Polycaprolactone" ○*Satoh, T. 2013 SNU-HU Chemistry symposium on , Seoul (South Korea) 2014-12-13～2013-12-13 |
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招待講演 "Synthesis and Characterization of Stereo-Miktoarm Star-Shaped Polylactide" ○*Satoh, T., Isono, T., Kondo, Y., Otsuka, I., Nishiyama, Y., Borsali, R., Kakuchi, T. The 13th Pacific Polymer Conference (PPC13), Kaohsiung (Taiwan) 2013-11-17～2014-11-22 |
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依頼講演 "Synthesis of Clickable Rigid Rod Polymer" ○*Satoh, T. 2012 Hokkaido University & Peking University Joint Symposium on Organic and Organometallic chemistry, Sapporo (Japan) 2012-07-17～2012-07-17 |
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招待講演 "Precise synthesis of clickable branched polymers" ○*Satoh, T 2012 Japan-Taiwan Bilateral polymer symposium, Seoul (Korea) 2013-11-07～2013-11-10 |
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口頭発表／ポスター発表 "Precise synthesis of Clickable Chiral Poly(n-hexyl isocyanate)s" ○*Satoh, T. The 5th Synposium on Molecular Chirality of Chinese Chemical Society & International Chiral Meeting, Zhangjiajie (China) 2013-08-01～2013-08-04 |
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招待講演 "Fabrication of Biodegradable Microstructure Using Rod-coil Block Copolymer" ○*Satoh, T. 2012 Japan-Taiwan Bilateral polymer symposium, 北九州 (日本) 2013-09-05～2013-09-08 |
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招待講演 "Preparation of biodegradable nanoporous film using rod-coil block copolymer as a compatibilizing agent" ○*Satoh, T., Suemasa, D., Nishikawa, N., Kawato, D., Kakuchi, T. X1 Brazilian Materials Research Society Meeting, Florianopolis (Brazil) 2012-09-23～2013-09-27 |
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依頼講演 "Synthesis and Characteristic of Hyperbranched Carbohydrate Polymer" ○*Satoh, T. 17th Malaysian Chemical Congress (17MCC) 2012, Kuala Lumpur (Malaysia) 2012-10-15～2012-10-17 |
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| Patent |
"半導体材料、有機太陽電池、環状共役高分子化合物およびその製造方法" 発明者：Kaji, H. Ishibashi, H. Fukushima, T. Satoh, T. 出願者：京都大学、北海道大学、関西TLO 特願2014-109558 2014-05-27, 2016-05, (国内) |
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| Prize |
" 平成27年度北海道大学研究総長賞奨励賞 " *Satoh, T. 2016-02 北海道大学北海道大学の発展に寄与する優れた研究業績(論文・著書等)を発表し、将来、世界的に発展の期待される教員 |
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| A03 岡 夏央 | ||
| Original papers |
"Stereocontrolled solid-phase synthesis of PO/PS chimeric oligodeoxyribonucleotides on an automated synthesizer using an oxazaphospholidine–phosphoramidite method" Nukaga, Y.; Oka, N.; *Wada, T. J. Org. Chem. 2016, 81 pp.2753-2762. DOI:10.1021/acs.joc.5b02793 |
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"Enhancement of affinity of 2′-O-Me-oligonucleotides for complementary RNA by incorporating a stereoregulated boranophosphate backbone" Nukaga, Y.; Takemura, T.; Iwamoto, N.; Oka, N.; *Wada, T. RSC Adv. 2015, 5 pp.2392-2395. DOI:10.1039/c4ra11335g |
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"α-Selective ribofuranosylation of alcohols with ribofuranosyl iodides and triphenylphosphine oxide" *Oka, N, Kajino, R.; Takeuchi, K.; Nagakawa, H.; Ando, K. J. Org. Chem. 2014, 79 pp.7656-7664. DOI:10.1021/jo500632h |
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"Solid-phase Synthesis of P-Boronated Oligonucleotides by the H-Boranophosphonate Method" Uehara, S.; Hiura, S.; Higashida, R.; Oka, N.; *Wada, T. J. Org. Chem. 2014, 79 (8), pp.3465-3472. DOI:10.1021/jo500185b |
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"Synthesis of inosine 6-phosphate diesters via phosphitylation of carbonyl oxygen" *Oka, N.; Morita, Y.; Itakura, Y.; Ando, K. Chem. Commun. 2013, 49 (98), pp.11503-11505. DOI:10.1039/C3CC46617E |
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"Glycosylation of alcohols using glycosyl boranophosphates as glycosyl donors" Tatsumi, S.; Matsumura, F.; Oka, N.; *Wada, T. Tetrahedron Lett. 2013, 54 pp.3731-3734. DOI:10.1016/j.tetlet.2013.04.032 |
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"Stereocontrolled synthesis of dinucleoside phosphorothioates using a fluorous tag" Oka, N.; Murakami, R.; Kondo, T.; *Wada, T. J. Fluorine Chem. 2013, 150 pp.85-91. DOI:10.1016/j.jfluchem.2013.03.013 |
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"Purification and comparison of native and recombinant tRNA-guanine transglycosylases from Methanosarcina acetivorans" Nomura, Y.; Onda, Y.; Ohno, S.; Taniguchi, H.; Ando, K.; Oka, N.; Nishikawa, K.; *Yokogawa, T. Protein Expr. Purif. 2013, 88 (1), pp.13-19. DOI:10.1016/j.pep.2012.11.009 |
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"Synthesis of nucleoside 5'-boranophosphorothioate derivatives using an H-boranophosphonate monoester as a precursor" *Oka, N.; Takayama, Y.; Ando, K.; Wada, T. Bioorg. Med. Chem. Lett. 2012, 22 (14), pp.4571-4574. DOI:10.1016/j.bmcl.2012.05.093 |
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"Synthesis of 2-pyridylphosphinate and thiophosphinate derivatives by nucleophilic aromatic substitution of N-methoxypyridinium tosylates" *Oka, N.; Ito, K.; Tomita, F.; Ando, K. Chem. Lett. 2012, 41 (12), pp.1630-1632. DOI:10.1246/cl.2012.1630 |
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"Stereocontrolled solid-phase synthesis of phosphorothioate oligoribonucleotides using 2'-O-(2-cyanoethoxymethyl)-nucleoside 3'-O-oxazaphospholidine monomers" Nukaga, Y.; Yamada, K.; Ogata, T.; Oka, N.; *Wada, T. J. Org. Chem. 2012, 77 (18), pp.7913-7922. DOI:10.1021/jo301052v |
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"Stereocontrolled synthesis of oligodeoxyribonucleoside boranophosphates by an oxazaphospholidine approach using acid-labile N-protecting groups" Iwamoto, N.; Oka, N.; *Wada, T. Tetrahedron Lett. 2012, 53 (33), pp.4361-4364. DOI:10.1016/j.tetlet.2012.06.015 |
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| Reviews / Accounts |
"Stereocontrolled synthesis of phosphate-modified oligonucleotides" *Oka, N.; Wada, T. J. Synth. Org. Chem. Jpn 2016, 74 (1), pp.31-44. |
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"Recent progress in the synthesis of glycosyl phosphate derivatives" *Oka, N.; Sato, K.; Wada, T. Trends Glycosci. Glycotechnol. 2012, 24 (138), pp.152-168. DOI:10.4052/tigg.24.152 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "α-Selective ribofuranosylation using ribofuranosyl iodides as glycosyl donors" ○*Oka, N.; Kajino, R.; Ando, K. Pacifichem 2015, Honolulu (U.S.A.) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric synthesis of phosphite triesters using chiral Brønsted acid catalysts" ○*Oka, N.; Oshima, T.; Ori, K.; Sakai, T.; Seo, N.; Ando, K. Pacifichem 2015, Honolulu (U.S.A.) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis of 7-ethynyl-7-deazaguanine and its incorporation into tRNA" ○*Oka, N.; Fukuta, A.; Shimizu, Y.; Ando, K.; Nomura, Y.; Ohno, S.; Yokogawa, T. The 42th International Symposium on Nucleic Acid Chemistry, Himeji (Japan) 2015-09-23～2015-09-25 |
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口頭発表／ポスター発表 "Asymmetric synthesis of phosphite triesters using chiral Brønsted acids" ○*Oka, N.; Ori, K.; Ohshima, T.; Sakai, T.; Ando, K. 新学術領域「有機分子触媒」第2回国際会議（兼）第7回有機触媒シンポジウム, Tokyo (Japan) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Synthesis of 7-ethynyl-7-deazaguanine and its application" ○*Oka, N.; Shimizu, Y.; Fukuta, A.; Ando, K.; Nomura, Y.; Ohno, S.; Yokogawa, T. The 41th International Symposium on Nucleic Acid Chemistry, Kokura (Japan) 2014-11-05～2014-11-07 |
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口頭発表／ポスター発表 "Synthesis of O6-phosphoryl inosine derivatives by phosphitylation of carbonyl oxygen" ○*Oka, N.; Morita, Y.; Itakura, Y.; Ando, K. The 40th International Symposium on Nucleic Acids Chemistry, Yokohama (Japan) 2013-11-13～2013-11-15 |
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口頭発表／ポスター発表 "α-Selective ribofuranosylation of alcohols using a ribofuranosyl iodide as a glycosyl donor" ○*Oka, N.; Takeuchi, K.; Nagakawa, H.; Kajino, R.; Ando, K. Nagoya Symposium 2013, Nagoya (Japan) 2013-05-23～2013-05-23 |
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口頭発表／ポスター発表 "Efficient synthesis of borano-nucleotides and α-ribofuranosides towards therapeutic applications" ○*Oka, N. Biotech 2013 in Japan, 12th International Technology Exhibition & Conference, Tokyo (Japan) 2013-05-08～2013-05-10 |
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口頭発表／ポスター発表 "Synthesis of nucleoside 5'-(P-borano)phosphate derivatives using nucleoside 5'-H-boranophosphonates as precursors" ○*Oka, N.; Takayama, Y.; Ando, K.; Wada, T. The 39th International Symposium on Nucleic Acid Chemistry, Nagoya (Japan) 2012-11-15～2012-11-17 |
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| Prize |
"有機合成化学協会 味の素研究企画賞" 岡 夏央 2013-02 有機合成化学協会 |
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| Media |
"核酸医薬の開発、工学部から" 岡 夏央 岐阜新聞 2012-06-05 PDF |
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| A03 間瀬 暢之 | ||
| Original papers |
" Scientia Pharmaceutica 2016, pp.191-202. |
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"Synthesis of a self-assembling gold Tetrahedron 2016, 72 (16), pp.1984-1990. DOI:10.1016/j.tet.2016.02.065 |
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"Characteristic Fluctuations in Glycosidically Bound Volatiles during Tea Processing and Identification of Their Unstable Derivatives" Cui, J.; Katsuno, T.; Totsuka, K.; Ohnishi, T.; Takemoto, H.; Mase, N.; Toda, M.; Narumi, T.; Sato, K.; Matsuo, T.; Mizutani, K.; Yang, Z.; *Watanabe, N.; *Tong, H. Journal of Agricultural and Food Chemistry 2016, 64 (5), pp.1151-1157. DOI:10.1021/acs.jafc.5b05072 |
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"Synthesis and Characterization of Quantum Dot Nanoparticles Bound to the Plant Volatile Precursor of Hydroxy- J. Org. Chem. 2014, 79 (15), pp.6808-6815. DOI:10.1021/jo500605c |
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"Characterization
of flower-inducing compound in Lemna paucicostata exposed to drought stress" Murata,
A.; Akaike, R.; Kawahashi, T.; Tsuchiya, R.; Takemoto, H.; Ohnishi, T.;
Todoroki, Y.; Mase, N.; Yokoyama, M.; Takagi, K.; Winterhalter, P.; Watanabe,
N. Tetrahedron 2014, 70 (33), pp.4969-4976. DOI:10.1016/j.tet.2014.03.099 |
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"Discrimination
of Green, Oolong, and Black Teas by GC-MS Analysis of Characteristic Volatile
Flavor Compounds" Baldermann,
S.; Yang, Z.; Katsuno, T.; Tu, V. A.; American Journal of Analytical Chemistry 2014, 5 (9), pp.620-632. DOI:10.4236/ajac.2014.59070 |
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"Characterization of odorant compounds and their biochemical formation in green tea with a low temperature storage process" Katsuno, T.; Kasuga, H.; Kusano, Y.; Yaguchi, Y.; Tomomura, M.; Cui, J.; Yang, Z.; Baldermann, S.; Nakamura, Y.; Ohnishi, T.; Mase, N.; *Watanabe, N. Food Chemistry 2014, 148 pp.388-395. |
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"Determination of volatile compounds in four commercial samples of Japanese green algae using solid phase microextraction gas chromatography mass spectrometry" Yamamoto, M.; Baldermann, S.; Yoshikawa, K.; Fujita, A.; Mase, N.; *Watanabe, N. The Scientific World Journal 2014, Article ID 289780 |
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" Fluorogenic aldehydes bearing arylethynyl groups: turn-on aldol reaction sensors for evaluation of organocatalysis in DMSO " *Mase, N.; Ando, T.; Shibagaki, F.; Sugita, A.; Narumi, T.; Toda, M.; Watanabe, N.; Tanaka, F.Tetrahedron Lett. 2014, 55 (11), pp.1946-1948. |
Tanaka, F. | |
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"Micro and Nanobubble Based Strategy for Gas-Liquid-Solid Multiphase Reactions: Palladium-Catalysed Hydrogenation of Carbon-Carbon Unsaturated Bonds" *Mase, N.; Isomura, S.; Toda, M.; Watanabe, N. Synlett 2013, 24 (17), pp.2225-2228. DOI:10.1055/s-0033-1339798 |
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"Fluorogenic probes for chemical transformations: 9-anthracene derivatives for monitoring reaction progress by an increase in fluorescence" *Mase, N.; Takabe, K.; *Tanaka, F. Tetrahedron Lett. 2013, 54 (32), pp.4306-4308. |
Fujie Tanaka | |
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"Organocatalytic Knoevenagel Condensations by Means of Carbamic Acid Ammonium Salts" *Mase, N.; Horibe, T. Org. Lett. 2013, 15 (8), pp.1854-1857. DOI:10.1021/ol400462d |
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| Books |
「ナノバイオ・テクノロジー」 静岡大学ナノバイオ科学研究分野編 "第2章 分子でみる、花が咲き、香る仕組み" 渡邉修治, 間瀬暢之 株式会社ITSC 2016, pp29-56. ISBN:978-4864740616 |
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「マイクロバブル（ファインバブル）のメカニズム・特性制御と実際応用のポイント」 "第三章 マイクロバブル（ファインバブル）応用のポイント 第1節 物質製造・化学工学プロセス 第2項 ファインバブル/ウルトラファインバブルの有機合成・反応への応用" 間瀬暢之 情報機構 2015, pp188-199. ISBN:978-4-86502-079-3 |
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「Comprehensive Organic Synthesis, 2nd Edition」 Paul Knochel and Gary A. Molander "2.07 The Aldol reaction: organocatalysis approach" Mase, N.; Hayashi, Y. Elsevier 2014, pp273-339. |
Hayashi, Y. | |
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「Science of Synthesis Knowledge Updates」 Shibasaki, M.; North, M. "Synthesis from Nitriles with Retention of the Cyano Group (Update 2013)" Mase, N. Thieme 2013, pp311-458. |
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「Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications」 Dalko, P. I. "Aldol and Mannich-Type Reactions" Mase, N.; Barbas, C. F., III Wiley-VCH 2013, pp793-835. ISBN:9783527332366 |
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「 Science of Synthesis; Water in Organic Synthesis 」 Kobayashi, S."3.4 Conjugate Addition Reactions" Mase, N. Thieme 2013, pp155-210. ISBN:9783131693518 |
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「Science of Synthesis; Asymmetric Organocatalysis 1: Lewis Base and Acid Catalysts」 List, B. "1.1.4 Enamine Catalysis of Michael Reactions" Mase, N. Thieme 2012, pp135-216. ISBN:9783131693617 |
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「Comprehensive Chirality」 Yamamoto, H.; Carreira, E. M. "Volume 6: Synthetic Methods V - Organocatalysis; 6.4 C–C Bond Formation: Aldol Reaction with Proline Derivatives" Mase, N. Elsevier 2012, pp97-124. ISBN:9780080951676 |
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| Reviews / Accounts |
"マイクロバブル・ナノバブル（MNB） 手法による有機合成" 間瀬暢之 化学と工業 2015, 67 (9), pp.786-786. |
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"マイクロバブル・ナノバブルを活用した新規有機合成手法の開発" 間瀬暢之 JACIニュースレター 2014, 53 (7), pp.7-7. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Green organic synthesis in gas-related multiphase reactions using micro- and nanobubbles strategy" *○Mase, Nobuyuki; Nishina, Yuki; Sato, Kohei; Narumi, Tetsuo; Watanabe, Naoharu the Pacifichem 2015, Honolulu (USA) 2015-11-15～2015-12-20 |
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口頭発表／ポスター発表 " the Pacifichem 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Identification of superior the 3rd International Symposium on Process Chemistry (ISPC 2015), Kyoto (Japan) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Efficient gas-related photo reactions using micro- and the 3rd International Symposium on Process Chemistry (ISPC 2015), Kyoto (Japan) 2015-07-13～2015-07-15 |
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口頭発表／ポスター発表 "Development of green organic synthesis in the GSC-7 and 4th JACI/GSC Symposium, Tokyo (Japan) 2015-07-05～2015-07-08 |
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口頭発表／ポスター発表 "High-quality The 39th Naito Conference, Sapporo (Japan) 2015-07-06～2015-07-09 |
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口頭発表／ポスター発表 "Synthesis of Self-Assembling GNP-Supported Organocatalysts:
Application for Asymmetric Synthesis" ○Péter Lajos Sóti, Tetsuo Narumi, Naoharu Watanabe, Nobuyuki Mase 2015 International Symposium toward the Future of Advanced Researches in Shizuoka University, Hamamatsu (Japan) 2015-01-27～2015-01-27 |
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口頭発表／ポスター発表 "Development of High-quality Polylactide Synthesis via
Organocatalytic Ring-Opening Polymerization in Supercritical Carbon Dioxide" ○Shoji Yamamoto, Tetsuo Narumi, Naoharu Watanabe, Nobuyuki Mase 2015 International Symposium toward the Future of Advanced Researches in Shizuoka University, Hamamatsu (Japan) 2015-01-27～2015-01-27 |
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口頭発表／ポスター発表 "Studies on Flower-Inducing Compounds in Lemna
paucicostata Exposed to Drought Stress" ○Ryo Tsuchiya, Tetsuo Narumi, Nobuyuki Mase, Naoharu Watanabe 2015 International Symposium toward the Future of Advanced Researches in Shizuoka University, Hamamatsu (Japan) 2015-01-27～2015-01-27 |
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口頭発表／ポスター発表 "Development of Environmentally-Friendly Organic
Synthesis Using Micro- and Nanobubble Strategy in Multiphase Reactions" ○Yuki Nishina, Takuya Tsuboi, Tetsuo Narumi, Naoharu Watanabe, Nobuyuki Mase Directions in Interdisciplinary Domain Research through Japan-Indonesia Partnership, Shizuoka (Japan) 2014-12-01～2014-12-01 |
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口頭発表／ポスター発表 "Development of GNP-Supported Organocatalyst for
Asymmetric Aldol Reaction" ○Péter Lajos Sóti, Tetsuo Narumi, Naoharu Watanabe, Nobuyuki Mase Directions in Interdisciplinary Domain Research through Japan-Indonesia Partnership, Shizuoka (Japan) 2014-12-01～2014-12-01 |
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依頼講演 "Organic Synthetic Methodology Based on Process and
Green Chemistry" Global Green Challenge, Kuala Lumpur (Malasya) 2014-12-15～2014-12-15 |
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依頼講演 "Organic Synthetic Methodology Based on Process and
Green Chemistry" Directions in Interdisciplinary Domain Research through Japan-Indonesia Partnership, Shizuoka (Japan) 2014-11-01～2014-12-01 |
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依頼講演 "High-quality Polylactide Synthesis via Organocatalytic
Ring-Opening Polymerization in Supercritical Carbon Dioxide" Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-21 |
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口頭発表／ポスター発表 "Synthesis and application of self-assembling GNP
supported ○Péter Lajos Sóti, Tetsuo Narumi, Naoharu Watanabe, Nobuyuki Mase Advanced Molecular Transformations by Organocatalysts 2nd International Conference & 7th Symposium on Organocatalysis, Tokyo (Japan) 2014-11-21～2014-11-21 |
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招待講演 "Development of Honorable Symposium between BPPT and Shizuoka University, Jakarta (Indonesia) 2014-09-15～2014-09-15 |
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口頭発表／ポスター発表 "2-Aminopyridine Catalyzed Selective Deprotonation of 1,3-Dicarbonyl Compounds: Organocatalytic Carbon-Carbon Bond Forming Reactions of (E)-form Enolate" ○Mase, N.; Kato, T.; Sasaki, A. 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, Otsu (Japan) 2013-05-27～2013-05-28 |
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| Media |
"静岡発の新技術紹介 静大准教授ら講演－清水産業・情報プラザ" 間瀬暢之 静岡新聞 2013-07-31 |
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"金属触媒用いず低温重合" 間瀬暢之 化学工業日報 2012-02-17 |
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| A03 原口 直樹 | ||
| Original papers |
"Synthsis of main-chain ionic polymer of Chiral Imidazolidinone Organicatalysts and Their Application to Asymmetric Diels-Alder Reaction" *Haraguchi, N.; Takenaka, N.; Najwa, A.; Takahara, Y.; Itsuno, S. Adv. Synth. Catal. 2016, 358 (in press.), |
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"Synthesis of Chiral Polyethers Containing Imidazolidinone Repeating Units and Application as Catalyst in Asymmetric Diels-Alder Reaction" *Itsuno, S.; Oonami, T.; Takenaka, N.; Haraguchi, N. Adv. Synth. Catal. 2015, 357 (18), pp.3995-4002. DOI:10.1002/adsc.201500539 |
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"Highly active polymeric organocatalyst: Chiral ionic polymers prepared from 10, 11‐didehydrogenated cinchonidinium salt" Hassan, M. M.; Haraguchi, N.; *Itsuno, S. J. Polym. Sci. Part A: Polym. Chem. 2016, 54 (5), pp.621-627. DOI:10.1002/pola.27905 |
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"Synthesis of chiral polymers containing thioetherified cinchonidium repeating units and their application to asymmetric catalysis" Islam, M. R.; Ahamed, P.; Haraguchi, N.; *Itsuno, S. Tetrahedron: Asymmetry 2015, 25 (18-19), pp.1309-1315. DOI:10.1016/j.tetasy.2014.08.013 |
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"Synthesis of Chiral Iridium Complexes Immobilized on Amphiphilic Polymers and their Application to Asymmetric Catalysis" *Itsuno, S.; Hashimoto, Y.; Sugie, H.; Haraguchi, N. J. Polym. Sci. Part A: Polym. Chem. 2014, 52 (21), pp.3037-3044. DOI:10.1002/pola.27351 |
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"Synthesis of Cinchona Alkaloid-derived Chiral Polymers by Mizoroki-Heck Polymerization and Their Application to Asymmetric Catalysis" Parvez, M. M.; Haraguchi, N.; *Itsuno, S. Macromolecules 2014, 47 (6), pp.1922-1928. DOI:10.1021/ma5001018 |
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"Synthesis of polymer-immobilized TsDPEN ligand and its application in asymmetric transfer hydrogenation of cyclic sulfonimine" Sugie, H.; Hashimoto, Y.; Haraguchi, N.; *Itsuno, S. J. Organomet. Chem. 2013, 751 pp.711-716. DOI:10.1016/j.jorganichem.2013.09.008 |
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"Synthesis of Main-chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Using Quaternization Polymerization" *Haraguchi, N.; Ahamed, P.: Parvez, M. M.; Itsuno, S. Molecules 2012, 17 (7), pp.7569-7583. DOI:10.3390/molecules17067569 |
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"Synthesis of chiral quaternary ammonium polymers for asymmetric organocatalysis application" Ahamed, P.; Haque, M. A.; Ishimoto, M.; Parvez, M. M.; Haraguchi, N.; *Itsuno, S. Tetrahedron 2013, 69 (19), pp.3978-3983. DOI:10.1016/j.tet.2013.03.018 |
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"Synthesis of Chiral Ionic Polymers Containing Quaternary Ammonium Sulfonate Structure and their Catalytic Activity in Asymmetric Alkylation" Parvez, M. M.; Salam, M. A.; Haraguchi, N.; *Itsuno, S. J. Chinese Chem. Soc. 2012, 59 (7), pp.815-821. DOI:10.1002/jccs.201100724 |
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"Design of Main-chain Polymer of Chiral Imidazolidinone for Asymmetric Organocatalysis Application" *Haraguchi, N.; Kiyono, H.; Takemura, Y.; Itsuno, S. Chem. Commun. 2012, 48 (33), pp.4011-4013. DOI:10.1039/C2CC18115K |
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"Molecular Design of Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Application" Parvez, M. M.; Haraguchi, N.; *Itsuno, S. Org. Biomol. Chem. 2012, 10 pp.2870-2877. DOI:10.1039/C2OB06909A |
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| Books |
「Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis」 Itsuno, S. "Polymer-Immobilized Chiral Organocatalyst" Haraguchi, N.; Itsuno, S. Wiley (Singapore) 2013, pp17-61. ISBN:978-0-470-56820-0 |
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「Science of Synthesis, Asymmetric Organocatalysis 2」 Maruoka, K. "Polymer-Immobilized Chiral Organocatalyst" Itsuno, S.; Haraguchi, N. Thieme (New York) 2013, pp673-695. ISBN:9783131693716 |
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| Reviews / Accounts |
"有機分子触媒の高分子固定化" *原口 直樹、伊津野 真一 有機分子触媒の化学 2016, in press |
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"高分子固定化有機分子触媒の開発" 原口 直樹 化学工業 2015, 66 pp.589-596. |
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"有機分子触媒の新たな高分子固定化法" *原口 直樹、伊津野 真一 ファインケミカル 2014, 43 pp.49-57. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "IONIC MAIN‐CHAIN POLYMER OF CHIRAL IMIDAZOLIDINONE AND ITS APPLICATION TO ASYMMETRICORGANOCATALYSIS" ◯*Haraguchi, N. POC16, Crete (Greece) 2016-06-13～2016-06-16 |
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口頭発表／ポスター発表 "Synthesis of Main-Chain Polymers of Chiral Imidazolidinone Salt and Their Application for Asymmetric Organocatalysis" ◯*Haraguchi, N.; Takenaka, N.; Takahara, Y.; Itsuno, S. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Synthesis of Cinchona Alkaloid Polymers Containing Squaramide Structure and Their Application to Asymmetric Reaction" ◯Zawanie, N.; Haraguchi, N.; *Itsuno, S. Molecular Chirality Asia 2016, Osaka (Japan) 2016-04-20～2016-04-22 |
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口頭発表／ポスター発表 "Development of main-chain polymer of chiral organocatalyst for asymmetric reaction" ◯*Haraguchi, N.; Itsuno, S. Pacifichem2015, Hawaii (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Design of Novel Main-chain Polymers of Chiral Imidazolidinone and Their Application to Organocatalysis" ○*Haraguchi, N.; Takenaka, N.; Onami, T.; Itsuno, S. Chirality 2014, Prague 2014 (Czech Republic) 2014-07-27～2014-07-30 |
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口頭発表／ポスター発表 "Chiral Polymers Containing Quaternary Ammonium Salt of Cinchona Alkaloid for Asymmetric Catalysis Application" ○*Itsuno, S.; Parvez, M. M.; Hassan, M. M.; Haraguchi, N. 2014 International Symposium on Polymer Materials at Harbin, Harbin (China) 2014-07-01～2014-07-01 |
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口頭発表／ポスター発表 "Polymeric organocatalysts derived from cinchona alkaloid quaternary ammonium salt" ○*Itsuno, S.; Hassan, M. M.; Haraguchi, N. 15th Tetrahedron Symposium, London (UK) 2014-06-24～2014-06-27 |
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口頭発表／ポスター発表 "Asymmetric catalytic activity of ionic chiral polymers synthesized from disulfonate and quaternary ammonium salt of cinchona alkaloid dimers containing acetylenic moiety" Hassan, M. M.; Haraguchi, N.; ○*Itsuno, S. The Every Nation Asia Campus Conference (Ignite 2013), Penang (Malaysia) 2013-12-05～2013-12-05 |
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招待講演 "Design and Synthesis of Novel Polymeric Chiral Organocatalysts" ○*Haraguchi, N. Advanced Molecular Transformation by Organicatalysts 1st International Conferene & 6th Symposium on Organocatalysis, Otsu (Japan) 2013-05-27～2013-05-28 |
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招待講演 "Molecular Design of Polymer-supported Chiral Organocatalyst for Asymmetric Reaction" ○*Haraguchi, N. First Japan-USA Organocatalytic Symposium, Waikiki (USA) 2012-12-15～2012-12-18 |
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口頭発表／ポスター発表 "Asymmetric Transfer Hydrogenation of Imines Catalyzed by Amphiphilic Polymer-supported Chiral Catalyst" ○*Haraguchi, N.; Hashimoto, Y.; Itsuno, S. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Synthesis of main-chain chiral quaternary ammonium salt polymers containing 10,11-didehydrocinchona alkaloid and their applications to asymmetric reactions" ○Hassan, M. M.; *Haraguchi, N.; Shinichi Itsuno 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Main-chain chiral polymers as catalyst in asymmetric benzylation of glycine derivative" ○Parvez, M. M.; Haraguchi, N.; *Itsuno, S. The 9th SPSJ International Polymer Conference (IPC2012), Kobe (Japan) 2012-12-11～2012-12-14 |
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口頭発表／ポスター発表 "Polymer design for asymmetric catalyst immobilization" ○*Itsuno, S, Hashimoto, Y.; Sugie, H.; Haraguchi, N. Porous polymer-based systems (EUPOC 2012), Gargnano (Italy) 2012-06-03～2012-06-07 |
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口頭発表／ポスター発表 "Synthesis of main-chain polymers for asymmetric organocatalysis application" ○*Haraguchi, N.; Kiyono, H.; Parvez, M. M.; Ahamed, P.; Itsuno, S. Chirality 2012, Texas (USA) 2012-06-10～2012-06-13 |
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口頭発表／ポスター発表 "Synthesis of Main-chain Polymer of Chiral Imidazolidinone for Asymmetric Diels-Alder Reaction" ○*Haraguchi, N.; Kiyono, H.; Najwa, A.; Itsuno, S. Symposium on Molecular Chirality ASIA 2012, Hakata (Japan) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 "Cinchona based main-chain polymeric organocatalyst using Mizoroki-Heck coupling reaction and their application to asymmetric reactions" ○Parvez, M. M.; Haraguchi, N.; *Itsuno, S. Symposium on Molecular Chirality ASIA 2012, Hakata (Japan) 2012-05-17～2012-05-18 |
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口頭発表／ポスター発表 "Development of Novel Polymer-supported MacMillan Catalysts with Ionic Bond for Asymmetric Reaction" ○*Haraguchi, N.; Kiyono, H.; Takemura, Y.; Kaneko, M.; Itsuno, S. 14th IUPAC Conference on Polymers and Organic Chemistry (POC2012), Doha (Qater) 2012-01-06～2012-01-09 |
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口頭発表／ポスター発表 "Molecular Design of Main-chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Application" ○*Itsuno, S.; Parvez, M. M.; Haraguchi, N. 14th IUPAC Conference on Polymers and Organic Chemistry (POC2012), Doha (Qater) 2012-01-06～2012-01-09 |
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| Prize |
"第48回（平成24年度）東海化学工業会 学術賞" *Haraguchi, N. 2013-05 東海化学工業会 新規高分子固定化型キラル触媒の開発 |
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"Poster Award" *Haraguchi, N. 2012-05 Molecular Chirality Research Organization Synthesis of Main-chain Polymer of Chiral Imidazolidinone for Asymmetric Diels-Alder Reaction |
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| Media |
"未来を拓く新しい触媒" Haraguchi, N. FMラジオ広報「天伯之城 ギカダイ」 2013-05-19 |
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"Novel main-chain polymer of chiral organocatalyst: Effective polymeric chiral organocatalyst for asymmetric reactions" Haraguchi, N. e-Newsletter 2012-11-01 |
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| A03 小槻 日吉三 | ||
| Original papers |
"Asymmetric Michael Addition Reaction of α-Aryl-substituted Lactams Catalyzed by Chiral Quaternary Ammonium Salts Derived from Cinchona Alkaloids: A New Short Synthesis of (+)-Mesembrine" Nunokawa, S.; Minamisawa, M.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Synlett 2015, 26 (16), pp.2301-2305. DOI:10.1055/s-0035-1560090 |
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"Biomimetic Approaches Employing the Ugi Five-Center Four-Component Reaction for Synthesis of the Right-Hand Portion of Halichonadin Q and the Central Part of Halichonadin M" Mimura R.; Kitamori A.; Ikeda A.; Matsuda T.; Nakano K.; Kotsuki H.; *Ichikawa Y. Synthesis 2015, 47 (19), pp.3043-3048. DOI:10.1055/s-0034-1380438 |
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"Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through the Primary Amine-catalyzed Michael Addition Reaction of α-Substituted Cyclic Ketones at High Pressure" Horinouchi, R.; Kamei, K.; Watanabe, R.; Hieda, N.; Tatsumi, N.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Eur. J. Org. Chem. 2015, (20), pp.4457-4463. DOI:10.1002/ejoc.201500411 |
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"A New Strategy for Synthesis of the Dinucleotide pdCpA: A Convenient Method for the Deprotection of Cyanoethyl, TBDMS, and Benzoyl Groups in One Step at High Pressure" *Kataoka, M.; Fukui, C.; Mimoto, A.; Kuge, H.; Honke, K.; *Kotsuki, H. Heterocycles 2015, 91 (6), pp.1164-1169. DOI:10.3987/COM-15-13223 |
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"Protecting Group Free Synthesis of Urea-linked Glycoconjugates: Efficient Synthesis of β-Urea Glycosides in Aqueous Solution" Ichikawa, Y.; Minami, T.; Kusaba, S.; Saeki, N.; Tonegawa, Y.; Tomita, Y.; Nakano, K.; Kotsuki, H. Org. Biomol. Chem. 2014, 12 pp.3924-3931. DOI:10.1039/C3OB42452A |
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"Asymmetric Organocatalytic Desymmetrization of 4,4-Disubstituted Cyclohexadienones at High Pressure: a New Powerful Strategy for the Synthesis of Highly Congested Chiral Cyclohexenones" Miyamae, N.; Watanabe, N.; Moritaka, M.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Org. Biomol. Chem. 2014, 12 (31), pp.5847-5855. DOI:10.1039/C4OB00733F |
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"Organocatalytic Friedel-Crafts Benzylation of Heteroaromatic and Aromatic Compounds via an SN1 Pathway" Watanabe, N.; Matsugi, A.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Synlett 2014, 25 (3), pp.438-442. DOI:10.1055/s-0033-1340343 |
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"Formylation of Amines through Catalyst- and Solvent-free Transamidation Reaction" Lebleu, T.; Kotsuki, H.; Maddaluno, J.; *Legros, J. Tetrahedron Lett. 2014, 55 (2), pp.362-364. DOI:10.1016/j.tetlet.2013.11.029 |
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"A Biomimetic Approach to the Synthesis of the Core Structure of the Marine Sponge Terpene Halichonadin G" Saito, K.; Nishimori, A.; Mimura, R.; Nakano, K.; Kotsuki, H.; Masuda, T.; *Ichikawa, Y. Eur. J. Org. Chem. 2013, (31), pp.7041-7043. DOI:10.1002/ejoc.201301206 |
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"Efficient Organocatalytic Michael Addition Reaction of β-Ketoesters under High Pressure" Moritaka, M.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Heterocycles 2013, 87 (11), pp.2351-2360. DOI:10.3987/COM-13-12818 |
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"A Biomimetic Approach to Terpenes Isolated from Marine Sponges: a Ugi Coupling Reaction in a Hypothetical Biosynthesis" Saito, K.; Nishimori, A.; Kotsuki, H.; Nakano, K.; *Ichikawa, Y. Synlett 2013, 24 (6), pp.757-761. DOI:10.1055/s-0032-1318305 |
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"Highly Efficient Asymmetric Michael Addition Reaction of Malonates to α,β-Unsaturated Ketones Promoted by a Chiral Thiourea/PPY Dual-Catalyst System" Moritaka, M.; Miyamae, N.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Synlett 2012, 23 (17), pp.2554-2558. DOI:10.1055/s-0032-1317317 |
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"A New Environmentally Friendly Method for the Baeyer-Villiger Oxidation of Cyclobutanones Catalyzed by Thioureas Using H2O2 as an Oxidant" Sasakura, N.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. RSC Adv. 2012, 2 (15), pp.6135-6139. DOI:10.1039/C2RA20898A |
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"Aminohydroxyacetone Synthons: Versatile Intermediates for the Organocatalytic Asymmetric Aldol Reaction" Komatsu, Y.; Watanabe, R.; Nakano, K.; Ichikawa, Y.; *Kotsuki, H. Org. Biomol. Chem. 2012, 10 (15), pp.2993-3001. DOI:10.1039/C2OB07107J |
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"High Pressure Promoted Aza-Michael Addition of Primary and Secondary Amines to α-Substituted Acrylates" Rulev, A. Yu.; Kotsuki, H.; *Maddaluno, J. Green Chem. 2012, 14 (2), pp.503-508. DOI:10.1039/C2GC16220B |
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"Synthesis of Manzacidin A and C: Efficient Construction of Quaternary Carbon Stereocenters Bearing Nitrogen Substituents" *Ichikawa, Y.; Okumura, K.; Matsuda, Y.; Hasegawa, T.; Nakamura, M.; Fujimoto, A.; Masuda, H.; Nakano, K.; Kotsuki, H. Org. Biomol. Chem. 2012, 10 (3), pp.614-622. DOI:10.1039/C1OB06559A |
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| Books |
「化学研究最前線―土佐で夢追う研究者たち」 "キラリと光るキラルなものの作り方―不斉合成化学の魅力" 高知大学化学系教員，小槻日吉三 飛鳥出版室 2015, pp44-50. ISBN:978-4882551515 |
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「最新 マイクロ波エネルギーと応用技術」 吉川・佐野・竹内・福島・堀越・和田 編 "第５章 2.3, 天然物合成への応用" 小槻日吉三 産業技術サービスセンター 2014, pp476-478. |
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「Comprehensive Enantioselective Organocatalysis, Vol. 1」 Dalko, P. "Part 1. Proline-related Secondary Amine Catalysts and Applications" Kotsuki, H.; Sasakura, N. Wiley-VCH (Weinheim) 2013, pp3-31. ISBN:978-3-527-33236-6 |
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「New and Future Developments in Catalysis – Catalysis for Remediation and Environmental Concerns」 Suib, S. L. "Chapter 19. Asymmetric Organocatalysis for the Construction of Quaternary Carbon Stereogenic Centers" Kotsuki, H.; Sasakura, N. Elsevier (Amsterdam) 2013, pp563-603. ISBN:978-0-444-53870-3 |
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| Reviews / Accounts |
"海洋天然物アゲラスタチンＡの合成" 山岡具倫、*市川善康、小槻日吉三 J. Synth. Org. Chem. Jpn 2012, 70 (6), pp.615-628. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Thiourea-Catalyzed Generation of Trityl Cation Species: Application to Carbonyl-Ene Cyclization Reaction" Nishiyama, N.; ◯Horinouchi. R.; *Kotsuki, H. 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Efficient Enantioselective Synthesis of All-Carbon- Substituted Quaternary Carbon Stereogenic Centers through the Pripary Amine-Based Organocatalytic Michael Addition Reaction of α-Substituted Cyclic Ketones at High Pressure" ◯Horinouchi, R.; Kamei, K.; Watanabe, R.; Hieda, N.; Tatsumi, N.; *Kotsuki, H. 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Asymmetric Organocatalytic Michael Addition Reaction of α-Aryl-substituted Lactams by Phase Transfer Catalyst: A New Short Synthesis of (+)-Mesembrine" ◯Nunokawa, S.; Minamisawa, M.; *Kotsuki, H. 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015), Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "An Organocatalytic Asymmetric Diels-Alder Strategy for the Enantioselective Synthesis of Spirocyclic Oxindole- Cyclohexenones" Matsugi, A.; ○Watanabe, N.; *Kotsuki, H. 2nd International Conference & 7th Symposium on Organocatalysis, 東京都文京区 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Efficient Enantioselective Synthesis of All-carbon-substituted Quaternary Carbon Stereogenic Centers through the Primary Amine-based Organocatalytic Michael Addition Reaction of α-Substituted Cyclic Ketones at High Pressure" ○Horinouchi, R.; Kamei, K.; Watanabe, R.; Hieda, N.; Tatsumi, N.; *Kotsuki, H. 2nd International Conference & 7th Symposium on Organocatalysis, 東京都文京区 2014-11-21～2015-11-22 |
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口頭発表／ポスター発表 "Chiral Thiourea/PPY-catalyzed Asymmetric Michael Addition Reaction-1. Diastereoselective Reaction" ○Watanabe, N.; Miyamae, N.; Moritaka, M.; *Kotsuki, H. The 24th International Society of Heterocyclic Chemistry Congress (ISHC-24), Shanghai (China) 2013-09-08～2013-09-13 |
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口頭発表／ポスター発表 "Chiral Thiourea/PPY-catalyzed Asymmetric Michael Addition Reaction-2. Chiral Discriminative Reaction" ○Miyamae, N.; Watanabe, N.; Moritaka, M.; *Kotsuki, H. The 24th International Society of Heterocyclic Chemistry Congress (ISHC-24), Shanghai (China) 2013-09-08～2013-09-13 |
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招待講演 "Synthetic Study of Biologically Interesting Natural Products Based on Organocatalytic Asymmetric Transformations" ○Kotsuki, H. U de Bordeaux (France) 2013-09-26～2013-09-26 |
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口頭発表／ポスター発表 "Asymmetric Organocatalytic Desymmetrization of 4,4-Disubstituted Cyclohexadienones" ○Miyamae, N.; Watanabe, N.; Moritaka, M.; *Kotsuki, H. 4th UK/Japan Conference in Catalytic Asymmetric Synthesis, Sendai (Japan) 2013-04-19～2013-04-20 |
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口頭発表／ポスター発表 "Asymmetric Michael Addition Reaction of Malonates to α,β-Unsaturated Ketones Using a Chiral Thiourea/PPY Catalytic System" ○Miyamae, N.; Watanabe, N.; Moritaka, M.; KOTSUKI, H. The 12th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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口頭発表／ポスター発表 "Chiral Thiourea-Catalyzed Diels-Alder Reaction for the Asymmetric Synthesis of Spiro-Oxindole Derivatives" ○Matsugi, A.; Yamauchi, T.; KOTSUKI, H. The 12th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12), Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "Synthetic Study of Biologically Interesting Natural Products Based on Organocatalytic Asymmetric Transformations" Kotsuki, H. U de Nice Sofia Antipolis (France) 2012-09-24～2012-09-24 |
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招待講演 "Synthetic Study of Biologically Interesting Natural Products Based on Organocatalytic Asymmetric Transformations" Kotsuki, H. U de Montpellier (France) 2012-09-20～2012-09-20 |
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招待講演 "Synthetic Study of Biologically Interesting Natural Products Based on Organocatalytic Asymmetric Transformations" Kotsuki, H. U de Caen (France) 2012-09-18～2012-09-18 |
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招待講演 "Synthetic Study of Biologically Interesting Natural Products Based on Organocatalytic Asymmetric Transformations" Kotsuki, H. IRCOF/U de Rouen (France) 2012-09-17～2012-09-17 |
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| Patent |
"アミノ基含有アセトン誘導体、及びそれを用いた炭素－炭素結合形成方法" 発明者：小槻 日吉三・小松 巧征 特願2010-032898 2014-07, 特許第5574480号 2014-07-11, (国内) |
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"アミノアシルヌクレオチド化合物の製造方法" 発明者：本家孝一・小槻日吉三・片岡正典・福井千春 特願2014－048194 2014-03-11, 2014-03, (国内) |
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"N-グリコシル酸アミドアミノ酸―核酸誘導体およびその製造方法" 発明者：本家孝一・小槻日吉三・片岡正典・福井千春 特願2013－073744 2013-12, 2013-12, (国内) |
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"不斉反応触媒及びそれを用いた不斉合成方法" 発明者：小槻日吉三・猪子石洋吾 特願2009－240020 2013-12, 特許第5392614号 2013-10-25, (国内) |
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"縮合多環化合物の製造方法" 発明者：小槻 日吉三 特願２００６－１５９３４７ 2012-12, 特許第５０２３３２２号 2012-06-29, (国内) |
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| A03 畑山 範 | ||
| Original papers |
"Process Development for the Practical Production of Eldecalcitol by Linear, Convergent and Biomimetic Syntheses" *Kubodera, N.; Hatakeyama, S. Anticancer Res. 2012, 32 (1), pp.303-310. |
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" Total Synthesis of (-)-Cinatrin C1 Based on an In(OTf)3-Catalyzed Conia-Ene Reaction "Urabe, F.; Nagashima, S.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. J. Org. Chem. 2013, 78 (8), pp.3847-3857. DOI:10.1021/jo400263w |
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"Unified Synthesis of Tirandamycins and Streptolydigins" Yoshimura, H.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S Chem. Commun. 2015, 51 (95), pp.17004-17007. DOI:10.1039/C5CC07749D |
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"An enantioselective organocatalyzed aza-Morita-Baylis-Hillman reaction of isatin-derived
ketimines with acrolein
" Yoshida, Y.; Sako, M.; Kishi, K.; Sasai, H.; Hatakeyama, S.; *Takizawa, S.
Org. Biomol. Chem. 2015, 13 (34), pp.9022-9028. DOI:10.1039/C5oB00874C |
Takizawa, S. | |
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"Total Synthesis of (–)-N-Methylwelwitindolinone C Isothiocyanate Based on a Pd-Catalyzed Tandem Enolate Coupling Strategy" Komine, K.; Nomura, Y.; Ishihara, J.; *Hatakeyama, S. Org. Lett. 2015, 17 (15), pp.3918-3921. DOI:10.1021/acs.orglett.5b01952 |
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"Lewis Acid Template-Catalyzed Asymmetric Diels–Alder Reaction" Ishihara, J.; Nakadachi, S.; Watanabe, Y.; *Hatakeyama, S. J. Org. Chem. 2015, 80 (4), pp.2037-2041. DOI:10.1021/acs.joc.5b00055 |
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"Stereoselective Approach toward Ophiodilactones Based on an Intramolecular [2+2]
Cycloaddition Reaction" Matsubara, T.; Ishihara, J.; *Hatakeyama, S. Heterocycles 2015, 90 (1), pp.405-424. DOI:10.3987/COM-14-S(K)32 |
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"Total Synthesis of Biologically Active Natural Products Based on Highly Selective Synthetic
Methodologies
" *Hatakeyama, S. Chem. Pharm. Bull. 2014, 62 (11), pp.1045-1061. DOI:10.1248/cpb.c14-00474 |
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"Total Synthesis of Oxazolomycins, Ishihara, J.; Hatakeyama, S. Chem. Rec., 2014, 14 (4), 663-677." Ishihara, J.; *Hatakeyama, S. The Chemical Reccord 2014, 14 (4), pp.663-677. DOI:10.1002/tcr.201402009 |
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"Total Synthesis of Marinomycin A Based on a Direct Dimerization Strategy" Nishimaru, T.; Kondo, M.; Takeshita, K.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. Angew. Chem. Int. Ed. 2014, 53 (32), pp.8459-8462. DOI:10.1002/anie.201404408 |
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"The Absolute Configuration for Inthomycin C: Revision of Previously Published Work with a Reinstatement of the (3R)-Configuration for (－)-Inthomycin C" Hale, K. J.; *Hatakeyama, S.; Urabe, F.; Ishihara, J.; Manaviazar, S.; Grabski, M.; Maczka, M. Org. Lett. 2014, 16 (13), pp.3536-3539. DOI:10.1021/ol501484t |
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"Total Synthesis of (–)-Dihydrosporothriolide Utilizing an Indium-Mediated Reformatsky-Claisen Rearrangement" Ishihara, J.; Tsuru, H.; * Hatakeyama, S. J. Org. Chem. 2014, 79 (12), pp.5908-5913. DOI:10.1021/jo5008948 |
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"Formal [4 + 1]-Cycloaddition of Homopropargyl Alcohols to Diazo Dicarbonyl Compounds Giving Substituted Tetrahydrofurans" Urabe, F.; Miyamoto, S.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S.
Org. Lett. 2014, 16 (3), pp.1004-1007. DOI:10.1021/o1403746r |
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"Total Synthesis of (–)-Ophiodilactone A and (–)-Ophiodilactone B
" Matsubara, T.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S.
Angew. Chem. Int. Ed. 2014, 53 (3), pp.757-760. DOI:10.1002/anie.201307835 |
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"Synthesis of Heterocycles Based on Rhodium-Catalyzed C–H Amination" Takahashi, K.; Yamaguchi, D.; Ishihara, Jun.; *Hatakeyama, S. Synlett 2014, 25 (1), pp.133-137. DOI:10.1055/s-0033-1340159 |
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"α-Isocupreine, an Enantiocomplementary Catalyst of β-Isocupreidine
" Nakamoto,Y.; Urabe, F.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. Chem. Eur. J. 2013, 19 (38), pp.12653-12656. DOI:10.1002/chem.201302665 |
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"Process Development for the Practical Production of Eldecalcitol by Linear,Convergent
and Biomimetic Syntheses" Kubodera, N.; Hatakeyama, S. Anticancer Res. 2012, 32 pp.303-310. |
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"Total Synthesis of (-)-Kaitocephalin Based on a Rh-Catalyzed C-H Amination
" Takahashi, K.; Yamaguchi, D.; Ishihara, J.; *Hatakeyama, S.
Org. Lett. 2012, 14 (6), pp.1644-1647. DOI:10.1021/ol300431n |
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"Total Synthesis of (−)-Cinatrin C1 Based on an In(OTf)3-Catalyzed Conia-Ene Reaction" Urabe, F.; Nagashima, S.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S.
J. Org. Chem. 2013, 78 (8), pp.3847-3857. DOI:10.1021/jo400263w |
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"Stereocontrolled Total Synthesis of (−)-Englerin A
" Takahashi, K.; Komine, K.; Yokoi, Y.; Ishihara, J.; *Hatakeyama, S. J. Org. Chem. 2012, 77 (17), pp.7364-7370. DOI:10.1021/jo301145r |
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"Organocatalytic asymmetric syntheses of inthomycins A, B and C" Yoshino, M.; Eto, K.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. Org. Biomol. Chem. 2012, 10 (40), pp.8164-8174. DOI:10.1039/c2ob26084k |
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"A New Method for the Protection of Carboxylic Acids with a Triisopropylsiloxymethyl Group.
" Yoshimura, H.; Eto, K.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. Chem. Pharm. Bull. 2012, 60 (10), pp.1334-1339. DOI:10.1248/cpb.c12-00490 |
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"Recent Developments in the Reformatsky-Claisen Rearrangement" Ishihara, J.; *Hatakeyama, S. Molecules 2012, 17 (12), pp.14249-14259. DOI:10.3390/molecules171214249 |
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"Sereoselective Synthesis of the Fused γ-Lactone/δ-Lactone Core of Ophiodilactones" Matsubara, T.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S.
Heterocycles 2012, 86 (1), pp.155-158. DOI:10.3987/COM-12-S(N)46 |
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| Books |
「Science of Synthesis, Asymmetric Organocatalysis 1
Lewis Base and Acid Catalysts」 List, B. "(Aza)-Morita-Baylis-Hillman Reactions" Hatakeyama, S. Georg Thieme Verlarg KG 2012, pp673-721. |
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| Conference / Symposium / Lecture |
招待講演 "Organocatalytic Asymmetric Synthesis of Tirandamycins" *Hatakeyama､ S. 第2回有機分子触媒国際会議兼第7回有機触媒シンポジウム, 東京 (日本) 2014-11-21～2014-11-22 |
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口頭発表／ポスター発表 "Concise Synthesis of Dihydrosporothriolide Utilized by Indium-mediated Refromatslaisen Rearrangement" Thuru､ H.； Ishihara､ J; *Hatakeyama, S 第24回日仏医薬精密化学会議, リヨン (フランス) 2014-09-14～2014-09-17 |
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招待講演 "Concise Synthesis of Dihydrosporothriolide
Utilized by Indium-mediated Reformatsky-Claisen Rearrangement
" ○Ishihara, J.; *Hatakeyama, S. The 11th Internaional Symposium on Organic Reaction(ISOR-11), 台北 (台湾) 2013-11-19～2013-11-22 |
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招待講演 "α-Isocupreine, a New Cinchona Alkaloid Catalyst" *Hatakeyama, S. The 11th Internaional Symposium on Organic Reaction(ISOR-11), 台北 (台湾) 2013-11-19～2013-11-22 |
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口頭発表／ポスター発表 "Formal [4+1] Cycloaddition via Tandem O-H Insertion/Conia-ene Reaction" ○Urabe, F.; Miyamoto, S.; Takahashi, K.; Ishihara, J .; *Hatakeyama, S. 10th International Symposium on Carbanion Chemistry (ISCC-10), 京都 (日本) 2013-09-23～2013-09-26 |
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口頭発表／ポスター発表 "Total Synthesis of Cinatrin C1 Based on an In(OTf)3-catalyzed Conia-ene Reaction" ○Takahashi, K.; Urabe, F.; Ishihara, J.; *Hatakeyama, S. The 15th Asian Chemical Congress, (Singapore) 2013-08-19～2014-08-23 |
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招待講演 "New Pyrrlidine Synthosis Based on a Rh-catalyzed C-H Amination: Total syntesis of Kaitocephalin" *Hatakayama, S. The 15th Asian Chemical Congress, (Singapore) 2013-08-19～2013-08-23 |
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口頭発表／ポスター発表 "Synthetic Study of Tirandamycin B Utilizing Cinchona Alkaloid-catalyzed Baylis-Hillman Reactions " ○Yoshimura, H.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. 1st International Conference of Advanced Molecular Transformations by Organocatalysts, Otsu (Japan) 2013-05-27～2013-05-28 |
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口頭発表／ポスター発表 "Syntetic studies on ophiodilactones
" ○Matsubara, T.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S.
23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "New entry to hererocycles based on a tandem O-H insertion/Conia-ene reaction
" ○Urabe, F.; Miyamoto, S.; Takahashi, K.; Ishihara, J.; *Hatakeyama, S. 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "Total Synthesis of Marinomycin A " ○Nishimaru, T.; Takeshita, k.; Kondo, M.; Takahashi, k.; Ishihara, J.; *Hatakayama, S. 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-12～2013-05-15 |
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口頭発表／ポスター発表 "New Entry
to Substituted Pyrrolidines Based on a Rh-Catalyzed C-H Amination:Syntesis of
Kaitocephalin" ○Takahashi, K.; Yamaguchi, D.; Ishihara, J; *Hatakeyama, S. The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2012-11-12～2012-11-16 |
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招待講演 "α-lsocupreine,an Enantiocomplementary Catalyst of β-
lsocupreidine" *Hatakeyama, S. First Japan-USA Organocatalytic Symposium, Hawaii (USA) 2012-12-15～2012-12-18 |
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| Prize |
"日本薬学会賞" *畑山 範 2013-11 公益社団法人日本薬学会 |
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| A03 石川 勇人 | ||
| Original papers |
"Redox Switching of Orthoquinone-Containing Aromatic Compounds with Hydrogen and Oxygen Gas" Urakawa, K.; Sumimoto, M.; Arisawa, M.; *Matsuda, M.; *Ishikawa, H. Angew. Chem. Int. Ed. 2016, published on web DOI:DOI: 10.1002/anie.201601906 |
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"
tert-Bytyl Diethyl Phosphonoacetate " Ishikawa, H; *Hayashi, Y.e-EROS(Encyclopedia of Reagents for Organic Synthesis 2014, DOI:DOI: 10.1002/047084289X.rn01708 |
林雄二郎 | |
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"
Collective Synthesis and Biological Evaluation of Tryptophan-based Dimeric Diketopiperazine Alkaloids " Tadano, S.; Sugimachi, Y.; Sumimoto, M.; Tsukamoto, S.; *Ishikawa, H.Chem. Eur. J. 2015, DOI:10.1002/chem.201503417 |
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"Efficient Organocatalytic Construction of C4-Alkyl Substituted Piperidines and Their Application to the Synthesis of (+)-α-Skytanthine" Shiomi, S; Sugahara, E; *Ishikawa, H Chem. Eur. J. 2015, 21 (42), pp.14758-14763. DOI:10.1002/chem.201503117 |
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"pH-driven, Reversible Epoxy Ring Opening/Closing in Graphene Oxide" *Taniguchi, T.; Kurihara, S.; Tateishi, H.; Hatakeyama, K.; Konimura, M.; Yokoi, M.; Hara, M.; Ishikawa, H.; *Matsumoto, Y. Carbon 2015, 84 pp.560-566. DOI:10.1016/j.carbon.2014012.054 |
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"Organocatalyst-Mediated Dehydrogenation of Aldehydes to α, β-Unsaturated Aldehydes and Oxidative and Enantioselective Reaction of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether" Hayashi, Y.*; Itoh, T.; Ishikawa, H. Adv. Synth. Catal. 2013, 355 (18), pp.3661-3669. DOI:10.1002/adsc.201300919 |
Yujiro Hayashi | |
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" One Pot Synthesis of (–)-Oseltamivir and Mechanistic Insights into the Organocatalytic Michael Reaction " Mukaiyama, T.; Ishikawa, H.; Koshino, H.; *Hayashi, Y.Chem. Eur. J. 2013, pp.17789-17800. DOI:10.1002/chem.201302371 |
Yujiro Hayashi | |
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"Diarylprolinol in an asymmetric aldol reaction of an α-alkyl-α-oxoaldehyde as an electrophile" *Hayashi, Y.; Yasui, Y.; Kojima, M.; Kawamura, T.; Ishikawa, H. Chem. Commun. 2012, 48 pp.4570-4572. DOI:10.1039/C2CC31230A |
林雄二郎 | |
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"Bio-inspired Dimerization Reaction of Tryptophan Derivatives in Aqueous Acidic Media: Three-step Synthesis of (+)-WIN 64821, (–)-Ditryptophenaline and (+)-Naseseazine B" Tadano, S,; Mukaeda, Y.; *Ishikawa, H. Angew. Chem. Int. Ed. 2013, 52 pp.7990-7994. DOI:DOI: 10.1002/anie.201303143 |
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| Books |
「Asymmetric Synthesis II: More Methods and Applications」 Christmann, M; Bräse, S "Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Technology" Ishikawa, H.; Hayashi, Y. WILEY-VCH 2013, pp61-65. |
Yujiro Hayashi |
| Reviews / Accounts |
"Unified Total Synthesis of Tryptophan-Based Dimeric Diketopiperazine alkaloids" *Ishikawa, H. J. Synth. Org. Chem. Jpn 2016, 74 pp.104-116. |
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"
Alkaloid Synthesis using Chiral Secondary Amine Organocatalysts " *Ishikawa, H.; Shiomi, S.Org. Biomol. Chem. 2016, 14 pp.409-424. DOI:10.1039/C5OB02021B |
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"生物に倣うインドール酸化反応を用いた生物活性アルカロイドの全合成" 石川勇人 YAKUGAKU ZASSHI 2015, 135 pp.383-390. |
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"ポットエコノミーを指向した効率的天然物合成" Ishikawa, H.; Hayashi, Y. ファインケミカル 2014, 43 (2), pp.6-12. |
林雄二郎 | |
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" Synthesis of Tryptophan-Based Dimeric Diketopiperazine Alkaloids Using Bioinspired Reactions " Tadano, S.; *Ishikawa, H.Synlett 2014, 25 (2), pp.157-162. DOI:10.1055/s-0033-1340160 |
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| Conference / Symposium / Lecture |
招待講演 "Synthetic Study of Biologically Active Piperidine Alkaloids using Asymmetric Organocatalytic Reactions " ○*Ishikikawa, H. Pacifichem 2015, ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 " Synthesis and Structure Determination of Ditryptoleucines and Cristatumin C " ◯Tadano, S.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Indoline Alkaloids Using Bio-Inspired Indole Oxidation " ◯Tanaka, R.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Geissochizal: the Key Intermediate on Biosynthesis of Monoterpenoid Indole Alkaloids " ◯Nakashima, R.; Ushijima, D.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Lundurine B " ◯Maeda, S.; Shiomi, S.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Antimalarial Decursivine " ◯Urakawa, K.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Antifungal Substance Parnafungins " ◯Haruta, T.; *Ishikawa, H.International Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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口頭発表／ポスター発表 " Synthetic Study of Decursivine using cis-Oriented Conformation of Hydroxamic Acid " ◯Urakawa, K.; *Ishikawa, H.The 8th ICAST 2013, Kumamoto (Japan) 2013-12-12～2013-12-13 |
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招待講演 " Synthetic Study of Biologically Active Natural Products " *Ishikawa, HInternational Kick-Off Symposium For ”ISMCBC”, Kumamoto (Japan) 2013-12-02～2013-12-02 |
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招待講演 "Three-Step Synthesis of WIN 64821, Ditryptophenaline and Naseseazine B via Bio-inspired Reaction in Water" *Ishikawa, H. The First Asian Conference for “MONODUKURI” Strategy by Synthetic Organic Chemistry, Okinawa (Japan) 2013-07-17～2013-07-19 |
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口頭発表／ポスター発表 " Bio-inspired Dimerization Reaction of Tryptophan Derivatives in Aqueous Acidic Media: Three-Step Synthesis of (+)-WIN 64821, (–)-Ditryptophenaline and (+)-Naseseazine B " ○Ishikawa, H; Tadano, S; Mukaeda, Y.The 23rd French-Japanese Symposium on Medicinal and Fine Chemistry, Nagasaki (Japan) 2013-05-13～2013-05-15 |
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| Prize |
"平成２７年度 熊本大学 研究企画表彰" 石川勇人 2015-11 国立大学法人 熊本大学 熊本大学教員の中で特に優れた業績を上げた教員が表彰される |
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"有機合成化学奨励賞" 石川勇人 2014-02 有機合成化学協会 受賞業績は「直接的骨格構築反応を利用する生物活性化合物の短段階合成」であり、有用な生物活性物質をポットエコノミーという新たな概念のもと短段階にて全合成した業績が評価された。有機合成化学奨励賞は、有機合成化学の分野で優れた研究を行った40歳以下の若手研究者に対して、毎年5名（以下）に授与される。 |
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"Thieme Chemistry Journal Award 2014" Hayato Ishikawa 2013-12 Thieme Chemistry 化学分野の若手研究者に送られる賞であり、2014年度は全世界から70名がThieme Chemistryの雑誌の編集委員により選出された。 |
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"平成２５年度 国立大学法人熊本大学 研究業績表彰" 石川勇人 2013-11 国立大学法人 熊本大学 研究業績表彰は熊本大学内の若手教員（４５歳以下）のなかで、過去3年以内の研究業績において、特に顕著な功績又は模範として推奨するにふさわしい業績があった職員に対して行う |
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| A03 濱島 義隆 | ||
| Original papers |
"Practical Total Syntheses of Acromelic Acids A and B" Inai, M.; Ouchi, H.; Asahina, A.; Asakawa, T.; *Hamashima, Y.; *Kan, T. Chem. Pharm. Bull. 2016, DOI:DOI/org/10.1248/cpb.c16-00009 |
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"Highly Enantioselective Bromocyclization of Allylic Amides with a P/P=O Double-site Lewis Base Catalyst" Kawato, Y.; Ono, H.; Kubota, A.; Nagao, Y.; Morita, N.; Egami, H.; *Hamashima, Y. Chem. Eur. J. 2016, 22 pp.2127-2133. DOI:DOI/10.1002/chem.201503153 |
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"Benzylic C–H Trifluoromethylation of Phenol Derivatives" Egami, H.; Ide, T.; Kawato, Y.; *Hamashima, Y. Chem. Commun. 2015, 51 pp.16675-16678. DOI:DOI: 10.1039/C5CC07011B |
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"2-[(Neopentyl glycolato)boryl]phenyl Triflates and Halides for Fluoride-Ion-Mediated Generation of Functionalized Benzynes" *Ikawa,T.; Yamamoto, R.; Takagi, A.; Ito, T.; Shimizu, K.; Goto, M.; Hamashima, Y.; *Akai, S. Adv. Synth. Catal. 2015, 357 pp.2287-2300. DOI:DOI: 10.1002/adsc.201500315 |
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"Asymmetric Fluorolactonization with a Bifunctional Hydroxyl Carboxylate Catalyst" Egami, H.; Asada, J.; Sato, K.; Hashizume, D.; Kawato, Y.; *Hamashima, Y. J. Am. Chem. Soc. 2015, 137 pp.10132-10135. DOI:DOI: 10.1021/jacs.5b06546 |
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"Stereocontrolled Total Syntheses of Optically Active Furofuran Lignans" Inai, M.; Ishikawa, R.; Yoshida, N.; Shirakawa, N.; Akao, Y.; Kawabe, Y.; Asakawa, T.; Egi, M.; *Hamashima, Y.; *Kan, T. Synthesis 2015, 47 pp.3513-3521. |
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"
Enantioselective Bromocyclization of Allylic Amides Catalyzed by BINAP Derivatives " Kawato, Y.; Kubota, A.; Ono, H.; Egami, Y.; *Hamashima, Y.Org. Lett. 2015, 17 pp.1244-1247. DOI:10.1021/acs.orglett.5b00220 |
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"
Advanced dress-up chiral columns: New removable chiral stationary phases for enantioseparation of chiral carboxylic acids "Analytical Chimica Acta 2015, |
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"
Concise synthesis of binaphthol-derived chiral
dicarboxylic acids " Egami, H.; Sato, K.; Asada, J.; Kawato, Y.; *Hamashima, Y. Tetrahedron 2015, DOI:10.1016/j.tet.2015.05.041 |
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"
Development of a Highly Efficient Single-mode Microwave Applicator with a Resonant Cavity and Its Application to Continuous Flow Syntheses " Yokosawa, S.; Ohneda, N.; Muramatsu, K.; Okamoto, T.; Odashima, H.; Ikawa, T.; Sugiyama, J.; Fujita, M.; Sawairi, T.; Egami, H.; *Hamashima, Y.; Egi, M.; *Akai, S.RSC Advances 2015, 5 pp.10204-10210. DOI:10.1039/C4RA12428F |
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"
Practical synthesis of natural plant-growth regulator 2-azahypoxanthine, its derivatives, and biotin-labeled probes " Ikeuchi, K.; Fujii, R.; Sugiyama, S.; Asakawa, T.; Inai, M.; Hamashima, Y.; Choi, J.-H.; Suzuki, T.; Kawagishi, H.; *Kan, T.Org. Biomol. Chem. 2014, 12 pp.3813-3815. DOI:10.1039/C4OB00705K |
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"
Total Syntheses of (+)-Sesamin and (+)-Sesaminol " Ishikawa, R.; Yoshida, N.; Akao, Y.; Kawabe, Y.; Inai, M.; Asakawa, T.; *Hamashima, Y.; *Kan, T.Chem. Lett. 2014, 43 pp.1572-1574. DOI:10.1246/cl.140613 |
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"
Dual Catalysis with Copper and Rhenium for Trifluoromethylation of Propargylic Alcohols: Efficient Synthesis of α-Trifluoromethylated Enones "
Egami, H.; Ide, T.; Fujita, M.; Tojo, T.; *Hamashima, Y.; *Sodeoka, M. Chem. Eur. J. 2014, 20 pp.12061-12065. DOI:10.1002/chem.201403447 |
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"Practical Total Syntheses of Acromelic Acids A and B" Ouchi, H.; Asahina, A.; Asakawa, T.; Inai, M.; *Hamashima, Y.; *Kan, T. Org. Lett. 2014, 16 (7), pp.1980-1983. DOI:10.1021/ol500529w |
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"Stereocontrolled Total Synthesis of Hedyotol A" Kawabe, Y.; Ishikawa, R.; Akao, Y.; Yoshida, A.; Inai, M.; Asakawa, T.; *Hamashima, Y.; *Kan, T. Org. Lett. 2014, 16 (7), pp.1976-1979. DOI:10.1021/ol500524y |
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"Practical Synthesis of Kainoids: A New Chemical Probe Precursor and a Fluorescent Probe" Sasaki, S.; Suzuki, H.; Ouchi, H.; Asakawa, T.; Inai, M.; Sakai, R.; Shimamoto, K.; *Hamashima, Y.; *Kan, T. Org. Lett. 2014, 16 (2), pp.564-567. DOI:10.1021/ol403434e |
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"Synthetic Studies of Fisetin, Myricetin and Nobiletin Analogs and Related Probe Molecules" Hiza, A.; Tsukaguchi, Y.; Ogawa, T.; Inai, M.; Asakawa, T.; Hamashima, Y.; *Kan, T. Heterocycles 2014, 88 (2), pp.1371-1396. DOI:10.3987/COM-13-S(S)107 |
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"Stereocontrolled total synthesis of sphingofungin E" Ikeuchi, K.; Hayashi, M.; Yamamoto, T.; Inai, M.; Asakawa, T.; *Hamashima, Y.; *Kan T. Eur. J. Org. Chem. 2013, 30 pp.6789-6792. DOI:10.1002/ejoc.201301065 |
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"
A Short-step Asymmetric
Synthesis of Dehydrodiconifery Alcohol (DCA) via C-H Insertion Reaction"
Matsumoto, S.; Asakawa, T.; Hamashima, Y.; *Kan, T. Synlett 2012, (7), pp.1082-1084. DOI:10.1055/s-0031-1290658 |
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"
Copper-Catalyzed
Trifluoromethylation of Allylsilanes
"
Shimizu, R.; Egami, H.; Hamashima, Y.; *Sodeoka, M.
Angew. Chem. Int. Ed. 2012, 51 (19), pp.4577-4580. DOI:10.1002/anie.201201095 |
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"
Catalytic Asymmetric
Mono-fluorination of a-Keto Ester: Synthesis of Optically Active a-Hydroxy-b-fluoro
Esters and a-Amino-b-fluoro Esters
"
Suzuki, S.; Kitamura, Y.; Lectard, S.; Hamashima, Y.; *Sodeoka, M.
Angew. Chem. Int. Ed. 2012, 51 (19), pp.4581-4585. DOI:10.1002/anie.201201303 |
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"
Catch & release of
alkyne-tagged molecules in water by polymer-supported cobalt complex
"
Egami, H.; Kamisuki,
S.; Dodo, K.; Asanuma, M.; Hamashima, Y.; *Sodeoka, M.
Org. Biomol. Chem. 2011, 9 pp.7667-7670. DOI:10.1039/C1OB06123B |
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"
Total syntheses of chaetocin and ent-chaetocin" Iwasa, E.; Fujishiro, S.; Hamashima, Y.; *Sodeoka, M. Tetrahedron 2011, 67 (35), pp.6587-6599. DOI:10.1016/j.tet.2011.05.081 |
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"
Catalytic Asymmetric a-Chlorination of
3-Acyl-oxazolidin-2-one with a Trinary Catalytic System" Hamashima, Y.; Nagi, T.; Shimizu, R.; Tsuchimoto, T.; *Sodeoka, M. Eur. J. Org. Chem. 2011, 20-21 pp.3675-3678. DOI:10.1002/ejoc.201100453 |
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"
Scope and Mechanism of
Tandem Aza-Michael Reaction/Enantioselective Protonation Using a Pd-m-Hydroxo Complex under Mild Conditions Buffered with Amine Salts"
Hamashima, Y.; Suzuki, S.; Tamura,
T.; Somei, H.; *Sodeoka, M. Chem. Asian J. 2011, 6 (2), pp.658-668. DOI:10.1002/asia.201000740 |
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"
Total Synthesis of (-)-Lemonomycin
"
Yoshida, A.; Akaiwa, M.; Asakawa, T.; Hamashima, Y.; Yokoshima, S.; Fukuyama, T.; *Kan, T.
Chem. Eur. J. 2012, 18 (36), pp.11192-11195. DOI:10.1002/chem.201202073 |
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"
Stereocontrolled
Total Synthesis of (+)- UCS1025A"
Uchida, K.; Ogawa, T.; Yasuda, Y.; Mimura, H.; Fujimoto, T.; Fukuyama, T.; Wakimoto,
T.; Asakawa, T.; Hamashima, Y.; *Kan, T. Angew. Chem. Int. Ed. 2012, 51 (51), pp.12850-12853. DOI:10.1002/anie.201207800 |
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"
Catalytic
Desymmetrization of Cyclohexadienes via Asymmetric Bromolactonization"
Ikeuchi, K.; Ido, K.; Yoshimura, S.; Asakawa, T.; Inai, M.; *Hamashima, Y.; *Kan, T. Org. Lett. 2012, 14 (23), pp.6016-6019. DOI:10.1021/ol302908a |
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"
Epidithiodiketopiperazine
as a pharmacophore for protein lysine methyltransferase G9a inhibitors:
Reducing cytotoxicity by structural simplification
"
Fujishiro, S.; Dodo, K.; Iwasa, E.; Sohtome, Y.; Hamashima, Y.; Ito, A.; Yoshida, M.; *Sodeoka, M. Bioorg. Med. Chem. Lett. 2013, 23 (3), pp.733-736. DOI:bmcl.2012.11.087 |
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"
Synthesis of Theaflavin
via Biomimetic Oxidative Coupling Reaction" Kawabe, Y.; Aihara, Y.; Hirose, Y.; Sakurada, A.; Yoshida, A.; Inai, M.; Asakawa, T.; Hamashima, Y.; *Kan, T. Synlett 2013, (4), pp.479-482. DOI:10.1055/s-0032-1318131 |
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"
Chemoselective Hydrogenation Reaction of
Unsaturated Bonds in the Presence of o-Nitrobenzenesulfonyl
Group
"
Kawanishi, A.; Miyamoto, C.; Yabe, Y.; Inai, M.; Asakawa, T.; Hamashima, Y.; Sajiki, H.; *Kan, T.
Org. Lett. 2013, 15 (6), pp.1306-1309. DOI:ol4002448 |
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| Books |
「
From C-H to C-C Bonds: Cross-Dehydrogenative-Coupling (RSC Green Chemistry) 」 Li, C.-L."Asymmetric cross-dehydrogenative-coupling reactions" Hamashima, Y.; Sodeoka, M. Royal Society of Chemistry 2014, pp133-152. |
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| Reviews / Accounts |
"Asymmetric cross-dehydrogenative-coupling reactions" Hamashima, Y.; Sodeoka, M. RSC Green Chemistry Series 2015, 26 pp.133-152. |
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"Chemical synthesis of tea polyphenols and related compounds" Asakawa, T.; Hamashima, Y.; *Kan, T. Current Pharmaceutical Design 2013, 19 pp.6207-6217. |
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"
Synthesis and Biological
Activities of Chaetocin and its Derivatives" Sodeoka, M.; Dodo, K.; Teng, Y.; Iuchi, K.; Hamashima, Y.; Iwasa, E.; Fujishiro, S. Pure Appl. Chem. 2012, 84 (6), pp.1369-1378. DOI:10.1351/PAC-CON-11-10-31 |
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| Conference / Symposium / Lecture |
依頼講演 "Asymmetric halofunctionalization of olefins with novel bifunctional organocatalysts" *Hamashima, Y. The International Chemical Congress of Pacific Basin Societies 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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依頼講演 "Continuous flow synthesis using a new type of microwave applicator" *Hamashima, Y. The United Kingdom Automated Synthesis Forum, Nottingham (United Kingdom) 2015-11-12～2015-11-13 |
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口頭発表／ポスター発表 "Asymmetric Fluorolactonization with a Bifunctional Hydroxyl Carboxylate Catalyst" Asada, J.; Egami, H.; Sato, K.; Hashizume, D.; Kawato, Y.; *Hamashima, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2015-11-09～2015-11-13 |
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口頭発表／ポスター発表 "Benzylic C-H Trifluoromethylation of Phenols" Ide, T.; Egami, H.; Kawato, Y.; *Hamashima, Y. The 13th International Kyoto Conference on New Aspects of Organic Chemistry, Kyoto (Japan) 2015-11-09～2015-11-13 |
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招待講演 "
Asymmetric
bromolactonization and its application to natural product synthesis
" Hamashima, Y. Japan-USA Organocatalytic Symposium, Honolulu (USA) 2012-12-15～2012-12-18 |
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| A03 鈴木 由美子 | ||
| Original papers |
"Microwave-assisted organic syntheses: microwave effect on intramolecular reactions – the Claisen rearrangement of allylphenyl ether and 1-allyloxy-4-methoxybenzene" Horikoshi, S.; Watanabe, T.; Kamata, M.; Suzuki, Y.: Serpone, N. RSC Advances 2015, 5 pp.90272-90280. DOI:10.1039/c5ra18039b |
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"Synthesis and Structure−Activity Relationship Study of 1‑Phenyl-1-(quinazolin-4-yl)ethanols as Anticancer Agents" Kuroiwa K.; Ishii, H.; Matsuno, K.; Asai, K.; Suzuki, Y ACS Med. Chem. Lett. 2015, 6 pp.287-291. |
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"Imidazolium-based chiral ionic liquids: Synthesis and
application" *Suzuki, Y.; Wakatsuki, J.; Tsubaki, M.; Sato, M Tetrahedron 2013, 69 pp.9690-9700. |
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"One-pot synthesis of unsymmetrical benzils and N-heteroarenes
through nucleophilic aroylation catalyzed by N-heterocyclic carbene" Suzuki, Y.; Murofushi, M.; Manabe, K. Tetrahedron 2013, 69 (2), pp.470-473. DOI:10.1016/j.tet.2012.11.039 |
Kei Manabe | |
| Reviews / Accounts |
" 最新のトピックス 脂肪族カルボニル化合物のβ炭素活性化 ―有機分子触媒による有用物質の合成反応 " 鈴木由美子化学 2014, 69 (1), pp.72-73. |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Regioselective synthesis of substituted quinoxalines via iminoethanones prepared by N-heterocyclic carbene catalysis" Takehara, R.; Shinozaki, M.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthesis of 5 to 8-aroylquinazolines by NHC-catalysis" Nakagawa, M.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthetic study of termicarcicolanone B using NHC-catalysis" Kitahara, Y.; Tsunoi, A.; Utsunomiya, T.; Tazawa, K.; Manabe, K.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "N-heterocyclic carbenes for nucleophilic acylation" Dobashi, K.; Iwata, N.; Ishitsubo, E.; Hiroski, T.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Development of a new set of quinazolines: Strong fluorophores for solution and solid state" Motoyama, M.; Lukarska, M.; Doan, T.-H.; Witulski, B.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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口頭発表／ポスター発表 "Synthetic study of antibacterial natural product citreamicin δ" Sugimura, R.; Takeuchi, E.; *Suzuki, Y. PACIFICHEM 2015, Honolulu (USA) 2015-12-15～2015-12-20 |
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|
招待講演 "Challenges to Organocatalytic Asymmetric Synthesis
of Chiral Alcohols" *Suzuki, Y. 5th UK-Japanese Symposium on Asymmetric Catalysis, Manchester (United Kingdom) 2016-03-14～2016-03-15 |
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招待講演 "N-Heterocyclic
Carbenes as Organocatalysts in Synthesis of Bioactive Compounds" *Suzuki, Y. ENSICAN-LCMT semina, Caen (France) 2016-11-23～2016-11-23 |
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招待講演 "Organic SYnthesis Using Nucleophilic Singlet Carbenes as Catalysts" Suzuki, Y. SOFEX 2014, Seoul (Korea) 2014-11-06～2014-11-08 |
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口頭発表／ポスター発表 "Exprerimental and Theoretical Analysis of NHC-Catalyzed Nucleophilic Aroylation" Dobashi, K.; Iwata, N.; Ishitsubo, E.; Tokiwa, H.; Suzuki, Y.* 第2回 国際会議 (兼) 第7回 有機触媒シンポジウム, Tokyo (Japan) 2014-11-21～2014-11-22 |
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基調講演 "Organocatalysis in Synthesis of Bioactive Compounds" Suzuki, Y. Science Week 2015 Science Symposium, Manila (Philippines) 2015-04-13～2015-04-17 |
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基調講演 "N-Heterocyclic carbenes as Organocatalysts for the Syntheses of Bioactive Compounds" Suzuki, Y 30th Philippine Chemistry Congress, Davao (Philippines) 2015-04-15～2015-04-17 |
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口頭発表／ポスター発表 "Synthesis of N-heteroarenes through nucleophilic aroylation catalyzed by N-heterocyclic carbene" ○Maki Shinozakia, Mai Murofushib, Kei Manabeb, Yumiko Suzuki 第1回 国際会議 (兼) 第6回 有機触媒シンポジウム, 大津 (日本) 2013-05-27～2013-05-28 |
Kei Manabe | |
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招待講演 "Synthesis of Nitrogen-Containing Organic Compounds Uisng Organocatalysis" ○Suzuki, Y. First Japan – USA Organocatalytic Symposium, ホノルル (アメリカ合衆国) 2012-12-15～2012-12-18 |
Kei Manabe | |
| Prize |
"第6回資生堂女性研究者サイエンスグラント
" Suzuki, Y. 2013-06 資生堂 有機化学の分野で大変優秀な研究活動をしており、これから指導的女性研究者となることが期待されるため、第６回資生堂女性研究者サイエンスグラント受賞者（未来の指導的女性研究者トップ１０）として選出された。 |
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| Media |
"「上智大学と四谷界隈の100年」" 東京人 12月増刊号 2013-12-08 「今、リケジョが熱い！女性研究者の活躍に注目」として紹介された。 |
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"第６回「資生堂 女性研究者セイエンスグラント」授賞式を開催" 国際商業 2013-09-01 鈴木由美子受賞挨拶「グラントを利用して研究者を志す研究者を育成」 |
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"静岡新聞記事" 静岡新聞 2013-07-22 PDF 静岡新聞の「とうきょう便ウィークリー」欄で化学研究者として紹介された。 |
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"きらめくソフィアン" Suzuki, Y. 上智学院 男女共同参画推進室 NEWSLETTER 2013-06-07 第6回「資生堂女性研究者サイエンスグラント」受賞 研究テーマ「有機触媒反応を用いた医薬品候補化合物の合成」 |
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"理工学部 物質生命理工学科の鈴木由美子准教授が「第6回資生堂女性研究者サイエンスグラント」受賞者として選出されました" Suzuki, Y. 上智学院 男女共同参画推進室 ウェブサイト 2013-04-10 |
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"第 6 回 「資生堂 女性研究者サイエンスグラント」10 名の受賞者決定" Suzuki, Y. 資生堂プレスリリース 2013-06-05 |
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"第6回資生堂女性研究者サイエンスグラント 理工学部 鈴木由美子准教授が受賞" Suzuki, Y. 上智大学通信 2013-04-30 自然科学分野において指導的役割を担う女性研究者の育成を目指し、株式会社資生堂が2007年に創設した研究助成事業である「資生堂女性研究者サイエンスグラント」を受賞した。 |
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"鈴木由美子准教授が第6回「資生堂女性研究者サイエンスグラント」を受賞しました" 上智大学公式ウェブサイト 2013-04-11 研究テーマ「有機触媒反応を用いた医薬品候補化合物の合成」にて第6回「資生堂女性研究者サイエンスグラント」を受賞した。 URL (English) http://www.sophia.ac.jp/eng/info/campusinfo/2013/4/campusinfo_298/ 20130422ci?kind=2 |
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| A03 澁谷 正俊 | ||
| Original papers |
"Reagents for diverse iodosilane-mediated transformations" *Masatoshi Shibuya, Masanori Abe, Shoji Fujita, Yoshihiko Yamamoto Org. Biomol. Chem. 2016, DOI:10.1039/c6ob00900 |
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"Synthesis of 4-Aryl-2-Quinolones via Copper-Catalyzed Hydroarylation of (o-Aminophenyl)propiolates with Arylboronates" Tsukasa Murayama, Masatoshi Shibuya, *Yoshihiko Yamamoto Adv. Synth. Catal. 2016, 358 (2), pp.166-171. DOI:10.1002/adsc.201500837 |
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"Ruthenium-Catalyzed Transfer Oxygenative [2 + 2 + 1] Cycloaddition of Silyldiynes Using Nitrones as Adjustable Oxygen Atom Donors. Synthesis of Bicyclic 2-Silylfurans" Kazuma Matsui, Masatoshi Shibuya, *Yoshihiko Yamamoto ACS Catalysis 2015, 5 (11), pp.6468-6472. DOI:10.1021/acscatal.5b01855 |
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" CF3-Substituted semisquarate: a pluripotent building block for the divergent synthesis of trifluoromethylated functional molecules" *Y. Yamamoto, T. Kurohara, M. Shibuya Chem. Commun. 2015, 51 pp.16357-16360. DOI:10.1039/C5CC06920C |
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"A Combined Transition-Metal-Catalyzed and Photopromoted Process: Synthesis of 2,3-Fused 4-Phenylnaphthalen-1-yl Carboxylates from 1,7-Diaryl-1,6-diynes" *Yoshihiko Yamamoto, Shota Mori, Masatoshi Shibuya Chem. Eur. J. 2015, 21 (25), pp.9093-9100. DOI:10.1002/chem.201500978 |
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"A Combined Experimental and Computational Study on the Cycloisomerization of 2-Ethynylbiaryls Catalyzed by Dicationic Arene Ruthenium Complexes" *Yoshihiko Yamamoto, Kazuma Matsui, Masatoshi Shibuya Chem. Eur. J. 2015, 21 (19), pp.7245-7255. DOI:10.1002/chem.201500248 |
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"Synthesis of 3,4-Fused 2-Quinolones from an (ortho-Aminophenyl)propiolate via Sequential Cycloaddition/Lactam Formation" Tsukasa Murayama, Masatoshi Shibuya, and *Yoshihiko Yamamoto Adv. Synth. Catal. 2015, 357 (4), pp.690-694. DOI:10.1002/adsc.201401069 |
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"Synthesis of β-Allylbutenolides via One-Pot Copper-Catalyzed Hydroallylation/Cyclization of γ-Hydroxybutynoate Derivatives" *Yoshihiko Yamamoto, Shinya Shibano, Takashi Kurohara, and Masatoshi Shibuya J. Org. Chem. 2014, 79 (10), pp.4503-4511. DOI:10.1021/jo500536b |
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"Tandem Ruthenium-Catalyzed Transfer-Hydrogenative Cyclization/Intramolecular Diels-Alder Reaction of Enediynes Affording Dihydrocoumarin-Fused Polycycles" *Yoshihiko Yamamoto, Kazuma Matsui, and Masatoshi Shibuya Org. Lett. 2014, 16 (6), pp.1806-1809. DOI:10.1021/ol500548x |
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"Intramolecular Hydroalkoxylation of Unactivated Alkenes Using Silane–Iodine Catalytic System" Fujita, S.; Abe, M.; *Shibuya, M.; Yamamoto, Y. Org. Lett. 2015, 17 (15), pp.3822-3825. DOI:10.1021/acs.orglett.5b01797 |
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"Lactone-fused cyclohexadiene as versatile platform for diversified synthesis of 5,6,5-tricyclic scaffolds" *Shibuya, M.; Sudoh, T.; Kawamura, T.; *Yamamoto, Y. Org. Biomol. Chem. 2015, 13 (21), pp.5862-5866. DOI:10.1039/C5OB00729A |
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"Chemoselective Catalytic Oxidation of 1,2-Diols to α-Hydroxy Acids Conrolled by TEMPO-ClO2 Charge-Transfer Complex" Furukawa, K.; *Shibuya, M.; Yamamoto, Y. Org. Lett. 2015, 17 (9), pp.2282-2285. DOI:10.1021/acs.orglett.5b01003 |
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"Highly Enantioselective Organocatalytic Oxidative Kinetic Resolution of Secondary Alcohols Using Chiral Alkoxyamines as Precatalysts: Catalyst Structure, Active Species, and Substrate Scope" Keiichi Murakami, Yusuke Sasano, Masaki Tomizawa, Masatoshi Shibuya, Eunsang Kwon, *Yoshiharu Iwabuchi J. Am. Chem. Soc. 2015, 136 (50), pp.17591-17600. DOI:10.1021/ja509766f |
澁谷正俊 | |
|
"Development of an Azanoradamantane-Type Nitroxyl Radical Catalyst for Class-Selective Oxidation of Alcohols" Ryusuke Doi, *Masatoshi Shibuya, Tsukasa Murayama, Yoshihiko Yamamoto, *Yoshiharu Iwabuchi J. Org. Chem. 2015, 80 (1), pp.401-413. DOI:10.1021/jo502426p |
澁谷正俊 | |
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"Mechanistic Insight into Aerobic Alcohol Oxidation Using NOx-Nitroxide Catalysis Based on Catalyst Structure-Activity Relationships" Masatoshi Shibuya, Shota Nagasawa, Yuji Osada, *Yoshiharu Iwabuchi J. Org. Chem. 2014, 79 (21), pp.10256-10268. DOI:10.1021/jo501862k |
岩渕好治 | |
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"Eu(OTf)3-Catalyzed Highly Regioselective Nucleophilic Ring Opening of 2,3-Epoxy Alcohols: An Efficient Entry to 3-Substituted 1,2-Diol Derivatives" Shun-ichiro Uesugi, Tsubasa Watanabe, Takamichi Imaizumi, Masatoshi Shibuya, Naoki Kanoh, *Yoshiharu Iwabuchi Org. Lett. 2014, 26 (17), pp.4408-4011. DOI:10.1021/ol502264y |
岩渕好治 | |
| Reviews / Accounts |
"高活性第1級アルコール酸化触媒：DMN-AZADO" 澁谷正俊，岩渕好治 和光純薬時報 2016, 84 (1), pp.8-11. |
岩渕好治 |
| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Chemoselective catalytic oxidation of 1,2-diols to α-hydroxy acids" ○Shibuya, M.; Furukawa, K.; Yamamoto, Y. Pacifichem2016, Hawaii 2016-12-15～2016-12-21 |
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| Prize |
"有機合成化学協会 奨励賞" 澁谷正俊 2015-12 有機合成化学協会 |
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| A03 瀧川 紘 | ||
| Original papers |
"Pleospdione, A Tricyclic Natural Product with Dense Oxygenation at the A Ring: Total Synthesis and Incongruity of the Originally Assigned Structure and its C3-Epimer" *Takikawa, H.; Ishikawa, Y.; Yoshinaga, Y.; Hashimoto, Y.; Kusumi, T.; *Suzuki, K.
Bull. Chem. Soc. Jpn 2016, DOI:10.1246/bcsj.20160134 |
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"Concise Total Syntheses of Amphidinolide C and Amphidinolide F" Valot, G.; Mailhol, D.; Regens, C. S.; O’Malley, D. P.; Godineau, E.; Takikawa, H.; *Fürstner, A. Chem. Eur. J. 2015, (21), pp.2398-2408. |
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"Isoxazole Platform for Polyketide Assembly: Cycloaddition of Stable Benzonitrile Oxides to Stable ortho-Quinone Mono-acetals and Dehydrogenation" Takikawa, H.; Hashimoto, Y.; *Suzuki, K. Chem. Lett. 2014, (43), pp.1607-1609. |
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| Books |
「有機合成実験法ハンドブック 第2版」 "第18章 不安定中間体の合成と反応" 鈴木啓介、瀧川 紘 丸善出版株式会社 (東京) 2015, ISBN:978-4-621-08948-4 |
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| Conference / Symposium / Lecture |
口頭発表／ポスター発表 "Total Synthesis of Tetracenomycin C" ○Takikawa, H.; Sato, S.; Hashimoto, Y.; Suzuki, K The 39th Naito Conference, The chemistry of organocatalysts, 札幌 (日本) 2016-07-06～2016-07-09 |
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口頭発表／ポスター発表 "Total Synthesis of Tetracenomycin C" ○Sato, S.; Hashimoto, Y.; Takikawa, H.; Suzuki, K. Pacifichem 2015, ホノルル (アメリカ) 2015-12-15～2015-12-20 |
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| A03 根本 哲宏 | ||
| Original papers |
"
Synthetic Study of Pactamycin:
Enantioselective Construction of the Pactamycin Core with Five Contiguous
Stereocenters " Yamaguchi, M.; Hayashi, M.; *Hamada, Y.; *Nemoto, T. Org. Lett. 2016, 18 pp.2347-2350. |
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Formal Enantioselective Total Symthesis of (–)-Allosamizoline Uisng an Organocatalytic
Asymmetric Aziridination " *Nemoto, T.; Muramoto, R.; Ruengsatra, T.; Hamada, Y. Tetrahedron 2016, 72 pp.1991-1997. |
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Platinum-Catalyzed Friedel-Crafts-Type C–H Coupling–Allylic Amination
Cascade to Synthesize 3,4-Fused Tricyclic Indoles " Suzuki, Y.; Tanaka, Y.; Nakano, S.; Dodo, K.; Yoda, N.; Shinohara, K.; Kita, K.; Kaneda, A.;Sodeoka, M.; Hamada, Y.; *Nemoto, T. Chem. Eur. J. 2016, 22 pp.4418-4421. |
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Formal Amide Insertion Strategy for the Synthesis of Anatoxin-a Using
Rhodium Catalysis " Kono, M.; Harada, S.; Hamada, Y.; *Nemoto, T. Tetrahedron 2016, 72 pp.1395-1399. |
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Diastereoselective Synthesis of Tri-substituted Cyclopropanes Using a
Pd-Catalyzed Intramoelcular Allylic Alkylation of alpha-Aryl Esters " *Nemoto, T.; Tsuruda, K.; Yoshida, M.; Kono, M.; Hamada, Y. Synthesis 2015, 47 pp.3914-3924. |
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Diastereoselective Synthesis of Quinolizidin-4-one and Indolizidin-3-one
Derivatives with a Spirocyclic Motif via Cascade Cyclization Using a Gold(I) /
Brønsted Acid Relay Catalysis " Harada, S.; Moriguchi, E.; Kono, M.; Hamada, Y.; *Nemoto, T. Tetrahedron Lett. 2015, 56 pp.6266-6268. |
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General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed
Formal Carbenoid Insertion into an Amide C–N Bond " Harada, S.; Kono, M.; Nozaki, T.; Menjo, Y.; *Nemoto, T.; *Hamada, Y. J. Org. Chem. 2015, 80 pp.10317-10333. |
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Pd-Catalyzed Cascade Cyclization by Intramolecular Heck Insertion of an
Allene–Allylic Aminaiton Sequence: Application to the Synthesis of 3,4-Fused
Tricyclic Indoles " Nakano, S.; Inoue, N.; Hamada, Y.; *Nemoto, T. Org. Lett. 2015, 17 pp.2622-2625. |
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Enantioselective Total Synthesis of (+)-Gephyrotoxin 287C" *Nemoto, T.; Yamaguchi, M.; Kakugawa, K.; Harada, S.; *Hamada, Y. Adv. Synth. Catal. 2015, 357 pp.2547-2555. |
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Synthesis of 4,5-Fused
Tricyclic Quinolines via an Acid-Promoted Intramolecular Friedel–Crafts Allenylation
of Aniline Derivatives " Suzuki, Y.; Nemoto, T.; Nakano, S.; Zhao, Z.; Yoshimatsu, Y.; *Hamada, Y. Tetrahedron Lett. 2014, 55 pp.6726-6728. |
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Synthesis of
Nitrogen-Containing Fused-Polycyclic Compounds from Tyramine Derivatives Using
Phenol Dearomatization and Cascade Cyclization " Yokosaska, T.; Nemoto, T.; Nakayama, H.; Shiga, N.; *Hamada, Y. Chem. Commun. 2014, 50 pp.12775-12778. |
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Gold-Catalyzed
Carbocyclization of Phenols with a Terminal Alkyne via an Intramolecular ipso-Friedel–Crafts Alkenylation " Nemoto, T.; Matsuo, N.; *Hamada, Y. Adv. Synth. Catal. 2014, 356 pp.2417-2421. |
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Scandium-Catalyzed Cascade
Cyclization to Produce Cyclobutane-Fused
Tetrahydroquinoline, Chromane, Thiochromane, and Tetrahydronaphthalene
Derivatives " Nakano, S.; Kakugawa, K.; Nemoto, T.; *Hamada, Y. Adv. Synth. Catal. 2014, 356 pp.2088-2096. |
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Enantioselective Synthesis
of (R)-Sumanirole Using Organocatalytic
Asymmetric Aziridination of an a,b-Unsaturated Aldehyde " Nemoto, T.; Hayashi, M.; Xu, D.; Hamajima, A.; *Hamada, Y. Tetrahedron: Asymmetry 2014, 25 pp.1133-1137. |
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Construction of
Divergent Fused-Heterocycles via an Acid-Promoted Intramolecular ipso-Friedel–Crafts Alkylation of Phenol
Derivatives " Yokosaka, T.; Shiga, N.: Nemoto, T.; *Hamada, Y. J. Org. Chem. 2014, 79 pp.3866-3875. |
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Synthesis of Fused-Tricyclic
Indole Derivatives through an Acid-Promoted Skeletal Rearrangement " Yokosaka, T.; Kanehira, T.; Nakayama, H.; Nemoto, T.; *Hamada, Y. Tetrahedron 2014, 70 pp.2151-2160. |
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| Reviews / Accounts |
"Synthesis of Spirocyclic and Fused-Cyclic Compounds Using Transition Metal-Catalyzed Intramolecular Frieden-Crafts-type Reactions of Phenol Derivatives " *Nemoto, T.; Hamada, Y. Synlett 2016, in press. |
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"遷移金属触媒を用いるフェノール類の脱芳香化反応を利用したスピロ環、縮環骨格合成法の開発" *根本哲宏、*濱田康正 J. Synth. Org. Chem. Jpn 2015, 73 (10), pp.977-986. |
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