業績

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2014

“Copper-Catalyzed Cascade Transformation of O-Propargylic Oximes with Sulfonyl Azides to α,β-Unsaturated N-Acylamidines” Dong Zhang, Itaru Nakamura, and Masahiro Terada, Org. Lett. 2014, 16(19) 5184-5187 DOI: 10.1021/ol502541w.

2014

“Efficient Synthesis of N-Alkylated α,β-Unsaturated Ketonitrones via Cu-Catalyzed Rearrangement” Itaru Nakamura, Toshiki Onuma, Ryo Kanazawa, Yuki Nishigai, and Masahiro Terada Organic Letters 2014, 16(16) 4198-4200, DOI: 10.1021/ol501889g

2014

“Synthesis of Bulky Aryl Group-substituted Chiral Bis(guanidino)iminophosphoranes as Uncharged Chiral Organosuperbase Catalysts” Tadahiro Takeda and Masahiro Terada, Australian Journal of Chemistry 67(7) 1124-1128 DOI: 10.1071/CH14195

2014

“Efficient Synthesis of Eight-Membered Nitrogen Heterocycles from O-Propargylic Oximes by Rhodium-Catalyzed Cascade Reactions” Itaru Nakamura, Yoshinori Sato, Keisuke Takeda and Masahiro Terada, Chem. Eur. J. 2014, 20, 10214-10219, DOI: 10.1002/chem.201403637


Highlighted at Frontispiece

2014

“N-​Allenylnitrone acts as 2-​azadiene in the Cu-​catalyzed cascade reaction of O-​propargylic oximes with azodicarboxylates” Itaru Nakamura, Takeru Jo, Dong Zhang and Masahiro Terada, Org. Chem. Front., 2014, 1(8) 914-918 DOI: 10.1039/C4QO00156G

2014

Highlighted at Front Cover

2014

“Intramolecular Cyclization of Alkynyl α-Ketoanilide Utilizing [1,2]-Phospha-Brook Rearrangement Catalyzed by Phosphazene Base” Azusa Kondoh, Takuma Aoki, and Masahiro Terada, Org. Lett. Article 2014, 16 (13) 3528-3531, DOI: 10.1021/ol501479t

2014

“Secondary Stereocontrolling Interactions in Chiral Brønsted Acid Catalysis: Study of a Petasis-Ferrier-Type Rearrangement Catalyzed by Chiral Phosphoric Acids” Kyohei Kanomata, Yasunori Toda, Yukihiro Shibata, Masahiro Yamanaka, Seiji Tsuzuki, Ilya Gridnev and Masahiro Terada Chem. Sci., 2014, 5, 3515-3523 , DOI: 10.1039/C4SC00611A

2014

“Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis-Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid” Masahiro Terada, Takazumi Komuro, Yasunori Toda, and Toshinobu Korenaga J. Am. Chem. Soc., 136(19), 7044-7057, DOI: 10.1021/ja5017206

2014

“Cu-Catalyzed Skeletal Rearrangement of O-Propargylic Electron-Rich Arylaldoximes into Amidodienes” Itaru Nakamura, Yasuhiro Ishida, and Masahiro Terada, Org. Lett., 2014, 16 (9), pp 2562–2565 DOI: 10.1021/ol5009608

2014

“Heterocyclic Synthesis by π-Acidic Metal Catalyzed Reactions via N-O Bond Cleavage” Itaru Nakamura and Masahiro Terada, Heterocycles, 2014, 89(4), 845-868, DOI: 10.3987/REV-13-791

2014

“Synthesis of 1,6-dihydropyrimidines via copper-catalyzed multistep cascade reactions between O-propargylic aldoximes and isocyanates” Itaru Nakamura, Toshiki Onuma, Dong Zhang, Masahiro Terada, Tetrahedron Letters, 2014, 55(6), 1178-1182, DOI: 10.1016/j.tetlet.2013.12.105.

2014

“Chiral Silver Phosphate Catalyzed Transformation of ortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence” Masahiro Terada, Feng Li, Yasunori Toda, Angew. Chem., Int. Ed. 2014, 53, 235-239, DOI: 10.1002/anie.201307371.

2014

2013

“Design and Synthesis of Helically Chiral Spirocyclic P3 Phosphazenes and Characterization of Their Onium Salts” Masahiro Terada, Kengo Goto, Masafumi Oishi, Tadahiro Takeda, Eunsang Kwon, Azusa Kondoh, Synlett 2013; 24(19): 2531-2534 DOI: 10.1055/s-0033-1340058

2013

“Phosphazene-catalyzed intramolecular cyclization of nitrogen-tethered alkynyl esters” Azusa Kondoh, Kenichi Ando and Masahiro Terada, Chem. Commun. 2013, 49, 10254-10256, DOI: 10.1039/c3cc46100a

2013

“Chiral Anion Catalysis in the Enantioselective 1,4-Reduction of the 1-Benzopyrylium Ion as a Reactive Intermediate” Masahiro Terada, Takuto Yamanaka, Yasunori Toda, Chemistry – A European Journal 2013, 19 (41) 13658–13662 DOI: 10.1002/chem.201302486

2013

“Development of a Chiral Bis(guanidino)iminophosphorane as an Uncharged Organosuperbase for the Enantioselective Amination of Ketones” Tadahiro Takeda and Masahiro Terada J. Am. Chem. Soc., 2013, 135(41) 15306-15309 DOI: 10.1021/ja408296h

2013

“Brønsted Base Catalyzed [2,3]-Wittig/Phospha-Brook Tandem Rearrangement Sequence” Azusa Kondoh, Masahiro Terada Org. Lett., 2013, 15 (17), pp 4568–4571 DOI: 10.1021/ol402144q

2013

“Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reactions between O-Propargylic Oximes and Dipolarophiles” Itaru Nakamura, Yu Kudo, Masahiro Terada, Angew. Chem., Int. Ed. 2013, 52(29), 7536-7539. DOI: 10.1002/anie.201302751

2013

“Relay Catalysis by a Ruthenium Complex-Chiral Brønsted Acid Binary Sytem for Ternary Reaction Sequence Involving Enantioselective Pictet-Spengler-Type Cyclization as the Key Step” Yasunori Toda, Masahiro Terada, Synlett, 2013, 24(6), 752-756, DOI: 10.1055/s-0032-1318302

2013

2012

“Synthesis of Azepine Derivatives by Rhodium-Catalyzed Tandem 2,3-Rearrangement/Heterocyclization” Itaru Nakamura,, Masashi Okamoto, Yoshinori Sato, Masahiro Terada, Angewandte Chemie International Edition 2012, 51(43), 10816–10819, DOI: 10.1002/anie.201205285 (Highlighted at front cover)

2012
2012

“Guanidine/Azole Binary System as an Efficient Catalyst for Morita–Baylis–Hillman Reaction” Prof. Dr. Masahiro Terada, Satoko Fukuchi, Kei Amagai, Dr. Megumi Nakano, Dr. Hitoshi Ube, ChemCatChem, 2012, 4(7), 963–967, DOI: 10.1002/cctc.201200149

2012

“Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Aryloximes into Four-Membered Cyclic Nitrones – Chirality Transfer and Mechanistic Insight” Itaru Nakamura, Yu Kudo, Toshiharu Araki, Dong Zhang, Eunsang Kwon, Masahiro Terada, Synthesis 2012; 44(10): 1542-1550 DOI: 10.1055/s-0031-1290819

2012

“Synthesis of Unsymmetrically Substituted 2,2’-Dihydroxy-1,1’-biaryl Derivatives Using Organic-Base-Catalyzed Ferrier-Type Rearrangement as the Key Step” Masahiro Terada and Katsunori Dan Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC31594G

2012

“Relay Catalysis Using a Rhodium Complex/Chiral Brønsted Acid Binary System: Enantioselective Reduction of a Carbonyl Ylide as the Reactive Intermediate” Masahiro Terada, Yasunori Toda, Angew. Chem. Int. Ed. 2012, 51, 2093 –2097. DOI: 10.1002/anie.201107805

2012

“Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Alkylaldoximes via N–O Bond Cleavage” Itaru Nakamura, Tomoki Iwata, Dong Zhang, and Masahiro Terada, Org. Lett., 2012, 14 (1), pp 206–209 DOI: 10.1021/ol203001w

2012

2011

“Design of Chiral Bis-phosphoric Acid Catalyst Derived from (R)-3,3′-Di(2-hydroxy-3-arylphenyl)binaphthol: Catalytic Enantioselective Diels–Alder Reaction of α,β-Unsaturated Aldehydes with Amidodienes” Norie Momiyama, Tohru Konno, Yuichi Furiya, Takeaki Iwamoto, and Masahiro Terada J. Am. Chem. Soc., 2011, 133 (48), pp 19294–19297 DOI: 10.1021/ja2081444

2011

“Direct Enantioselective Amination of α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base” Masahiro Terada, Kei Amagai, Kenichi Ando, Eunsang Kwon, Hitoshi Ube, Chem. Eur. J. 2011, 17, 9037 – 9041. DOI: 10.1002/chem.201101076

2011

“Thermally-induced skeletal rearrangement of (Z)-O-propargylic α,β-unsaturated aldoximes to multisubstituted pyridine oxides” Itaru Nakamura, Dong Zhang, Masahiro Terada, Tetrahedron Letters 2011, 52(48), 6470-6472 doi:10.1016/j.tetlet.2011.09.107

2011

“Chiral Brønsted Acid Catalyzed Stereoselective Addition of Azlactones to 3-Vinylindoles for Facile Access to Enantioenriched Tryptophan Derivatives” Masahiro Terada, Kenichi Moriya, Kyohei Kanomata, Keiichi Sorimachi, Angewandte Chemie International Edition 2011, 50(52), 12586–12590, DOI: 10.1002/anie.201105562

2011

“Platinum-Catalyzed Cycloisomerization of 1,4-Enynes via 1,2-Alkenyl Rearrangement” Takuma Sato, Toshiki Onuma, Itaru Nakamura, and Masahiro Terada Org. Lett., 2011, 13 (19), pp 4992–4995 DOI: 10.1021/ol202104c .

2011

“Metal-Free Chiral Phosphoric Acid or Chiral Metal Phosphate as Active Catalyst in the Activation of N-Acyl Aldimines” Masahiro Terada, Kyohei Kanomata, Synlett 2011(9): 1255-1258 DOI: 10.1055/s-0030-1260545.

2011

“Regioselective Transformation of O-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement” Itaru Nakamura, Toshiharu Araki, Dong Zhang, Yu Kudo, Eunsang Kwon, and Masahiro Terada Org. Lett., 2011, 13 (14), pp 3616–3619, DOI:10.1021/ol2012583

2011

“Five-Bond Cleavage in Copper-Catalyzed Skeletal Rearrangement of O-Propargyl Arylaldoximes to β-Lactams (Additions and Corrections)” Itaru Nakamura, et al. J. Am. Chem. Soc., 2011, 133 (17), p 6861 DOI: 10.1021/ja201074e


“Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes (Additions and Corrections)” Itaru Nakamura*, Dong Zhang, and Masahiro Terada J. Am. Chem. Soc., 2011, 133 (17), p 6862 DOI: 10.1021/ja201076c


“Chiral Brønsted Acid Catalysis for Enantioselective Hosomi−Sakurai Reaction of Imines with Allyltrimethylsilane” Norie Momiyama, Hayato Nishimoto, and Masahiro Terada, Org. Lett. 2011, 13, 2126-2129, DOI:10.1021/ol200595b

2011

“Enantioselective Direct Vinylogous Michael Addition of Functionalized Furanones to Nitroalkenes Catalyzed by an Axially Chiral Guanidine Base” Masahiro Terada and Kenichi Ando, Org. Lett. 2011, 13, 2026-2029, DOI:10.1021/ol200415u

2011

“Highly Stereoselective [4+2] Cycloaddition of Azlactones to β,γ-Unsaturated α-Ketoesters Catalyzed by an Axially Chiral Guanidine Base” Masahiro Terada and Hiroyuki Nii, Chem. Eur. J. 2011, 17, 1760-1763, DOI:10.1002/chem.201003015

2011

2010

“Synthesis of Bis(benzo[b]thiophenyl)methanes by Gold-Catalyzed Double Carbothiolation”
Itaru Nakamura, Masashi Okamoto, Takuma Sato and Masahiro Terada Heteocycles, 2010, 82, 689-697, DOI:10.3987/COM-10-S(E)44

2010

「キラルBronsted酸触媒による不斉合成」、寺田眞浩、ファインケミカル(シーエムシー出版)、2010年8月号

“Copper-Catalyzed Rearrangement of (Z)-Propynal Hydrazones via N−N Bond Cleavage” Itaru Nakamura, Naozumi Shiraiwa, Ryo Kanazawa and Masahiro Terada Org. Lett., 2010, 12, 4198-4220, DOI: 10.1021/ol1017504

2010

“Enantioselective aza-Friedel-Crafts reaction catalyzed by a water
inclusion complex of O,O’-diacyl tartaric acid” Hitoshi Ube, Satoko
Fukuchi and Masahiro Terada  Tetrahedron: Asymmetry, 2010, 9-10, 1203-1205,
DOI: 10.1016/j.tetasy.2010.04.012

2010

“Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective
Transformations” Masahiro Terada  Synthesis (Review), 2010, 1929-1982, DOI: 10.1055/s-0029-1218801

Reprint version is available: PDF

2010

“Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes” Itaru Nakamura, Dong Zhang and Masahiro Terada J. Am. Chem. Soc., 132, 7884-7886, DOI: 10.1021/ja102436z

2010

“Gold-Catalyzed Cyclization and Subsequent Arylidene Group Transfer of O-Propioloyl Oximes” Itaru Nakamura, Masashi Okamoto and Masahiro Terada Org. Lett., 12, 2453-2455, DOI: 10.1021/ol100581m

2010

M. Terada, N. Momiyama, Enantioselective Synthesis of Amines by Chiral
Bronsted Acid Catalysts. In Chiral Amine Synthesis, Methods, Developments
and Applications, T. C. Nugent Ed.; Wiley-VCH: Weinheim, 2010, 75-129.

“Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Carbon–Carbon Bond Forming Reactions” Masahiro Terada, Bulletin of the Chemical Society of Japan, 2010, 83, 101-119, DOI:10.1246/bcsj.20090268

2010

“Asymmetric Direct Vinylogous Aldol Reaction of Furanone Derivatives Catalyzed by an Axially Chiral Guanidine Base” Hitoshi Ube, Naoki Shimada, Masahiro Terada Angew. Chem., Int. Ed., 2010, 49, 1858-1861, DOI: 10.1002/anie.200906647

2010